And Zinc Or Zirconium Patents (Class 501/67)
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Patent number: 10494293Abstract: A thermally tempered glass element is provided made of glass with two opposite faces that are under compressive stress of at least 40 MPa. The glass has a working point at which the glass has a viscosity of 104 dPa·s of at most 1350° C. The glass has a viscosity versus temperature profile and a coefficient of thermal expansion versus temperature profile of the glass are such that a variable (750° C.?T13)/(CTELiq?CTESol) has a value of at most 5*106 K2. The CTELiq is a coefficient of linear thermal expansion of the glass above a glass transition temperature Tg, the CTESol is a coefficient of linear thermal expansion of the glass in a temperature range from 20° C. to 300° C., and the T13 is a temperature at which the glass has a viscosity of 1013 dPa·s.Type: GrantFiled: November 23, 2016Date of Patent: December 3, 2019Assignee: SCHOTT AGInventors: Michael Schwall, Christian Mlx, Jochen Alkemper, Peter Thomas
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Patent number: 10450217Abstract: A glass for pharmaceutical containers, which is resistant to delamination and has excellent processibility, is provided. The glass for pharmaceutical containers comprises, in mol % on an oxide basis, 69 to 81% of SiO2, 4 to 12% of Al2O3, 0 to 5% of B2O3, to 20% of Li2O+Na2O+K2O, 0.1 to 12% of Li2O, and 0 to 10% of MgO+CaO+SrO+BaO. The glass has a hydrolytic resistance of Class 1 in a test in accordance with the European pharmacopoeia.Type: GrantFiled: May 8, 2018Date of Patent: October 22, 2019Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Kazuyuki Yamamoto, Ken Choju
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Patent number: 10377656Abstract: A method includes contacting a second layer of a glass sheet with a forming surface to form a shaped glass article. The glass sheet includes a first layer adjacent to the second layer. The first layer includes a first glass composition. The second layer includes a second glass composition. An effective viscosity of the glass sheet during the contacting step is less than a viscosity of the second layer of the glass sheet during the contacting step. A shaped glass article includes a first layer including a first glass composition and a second layer including a second glass composition. A softening point of the first glass composition is less than a softening point of the second glass composition. An effective 108.2 P temperature of the glass article is at most about 900° C.Type: GrantFiled: May 7, 2015Date of Patent: August 13, 2019Assignee: Corning IncorporatedInventors: Thierry Luc Alain Dannoux, Vladislav Yuryevich Golyatin, John Richard Ridge, Ljerka Ukrainczyk, Butchi Reddy Vaddi, Natesan Venkataraman
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Patent number: 9802857Abstract: Substantially alkali free glasses are disclosed with can be used to produce substrates for flat panel display devices, e.g., active-matrix liquid crystal displays (AMLCDs). The glasses have high annealing temperatures and etch rates. Methods for producing substantially alkali free glasses using a downdraw process (e.g., a fusion process) are also disclosed.Type: GrantFiled: February 19, 2016Date of Patent: October 31, 2017Assignee: Corning IncorporatedInventors: Bradley Frederick Bowden, Adam James Ellison, Timothy James Kiczenski
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Patent number: 9782949Abstract: Laminated articles and layered articles, for example, low alkali glass laminated articles and layered articles useful for, for example, electrochromic devices are described.Type: GrantFiled: April 21, 2009Date of Patent: October 10, 2017Assignee: Corning IncorporatedInventors: David Francis Dawson-Elli, Steven Edward DeMartino, Laura L Hluck
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Patent number: 9540273Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.Type: GrantFiled: November 17, 2015Date of Patent: January 10, 2017Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi Tokunaga, Tomoyuki Tsujimura, Manabu Nishizawa, Akio Koike
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Patent number: 9051214Abstract: Certain example embodiments relate to an improved method of strengthening glass substrates (e.g., soda lime silica glass substrates). In certain examples, a glass substrate may be chemically strengthened by creating an electric field within the glass. In certain cases, the chemical tempering may be performed by surrounding the substrate by a plasma including certain ions, such as Li+, K+, Mg2+, and/or the like. In some cases, these ions may be forced into the glass substrate due to the half-cycles of the electric field generated by the electrodes that formed the plasma. This may advantageously chemically strengthen a glass substrate on a substantially reduced time scale. In other example embodiments, an electric field may be set in a float bath such that sodium ions are driven from the molten glass ribbon into the tin bath, which may advantageously result in a stronger glass substrate with reduced sodium content.Type: GrantFiled: September 2, 2011Date of Patent: June 9, 2015Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Xuequn Hu, Glenn A. Cerny
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Publication number: 20150147575Abstract: Alkali aluminosilicate glasses that are ion exchangeable to high compressive stresses, have fast ion exchange kinetics, and high intrinsic damage resistance. The glasses achieve all of the above desired properties either with only small amounts of P2O5 (<1 mol %) or without addition of any P2O5.Type: ApplicationFiled: November 18, 2014Publication date: May 28, 2015Inventors: Matthew John Dejneka, John Christopher Mauro
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Publication number: 20150140325Abstract: Embodiments of glass composition including at least about 65 mol % SiO2, Al2O3 in the range from about 7 mol % to about 11 mol %, Na2O in the range from about 13 mol % to about 16 mol %; and a non-zero amount of one or more alkali earth metal oxides selected from MgO, CaO and ZnO, wherein the sum of the alkali earth metal oxides is up to about 6 mol %, are disclosed. The glass compositions can be processed using fusion forming processes and float forming processes and are ion exchangeable. Glass articles including such glass compositions and methods of forming such glass articles are also disclosed. The glass articles of one or more embodiments exhibit a Vickers indentation crack initiation load of at least 8 kgf.Type: ApplicationFiled: November 14, 2014Publication date: May 21, 2015Inventors: Timothy Michael Gross, Xiaoju Guo, Charlene Marie Smith
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Publication number: 20150118497Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: ApplicationFiled: January 7, 2015Publication date: April 30, 2015Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Publication number: 20150093561Abstract: The present invention relates to an alkali-free glass having a strain point of from 680 to 735° C., an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., and a specific gravity of 2.60 or less, and containing, indicated by mol % on the basis of oxides, SiO2 65 to 69%, Al2O3 11.5 to 14%, B2O3 3 to 6.5%, MgO 1 to 5%, CaO 7.5 to 12%, SrO 0 to 1%, BaO 0.5 to 6%, and ZrO2 0 to 2%.Type: ApplicationFiled: December 8, 2014Publication date: April 2, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi Tokunaga, Manabu Nishizawa, Akio Koike
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Publication number: 20150087494Abstract: The present invention relates to an alkali-free glass having a strain point of 710° C. or higher, an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1,710° C. or lower, and a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1,320° C. or lower, containing, indicated by % by mass on the basis of oxides: SiO2 58.5 to 67.5, Al2O3 18 to 24, B2O3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5, and ZrO2 0 to 4.0, containing 0 to 0.35% by mass of Cl, 0.01 to 0.15% by mass of F, and 0.01 to 0.3% by mass of SnO2, and having a ?-OH value of the glass of from 0.15 to 0.60 mm?1.Type: ApplicationFiled: December 4, 2014Publication date: March 26, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi TOKUNAGA, Akio Koike, Manabu Nishizawa, Tomoyuki Tsujimura
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Publication number: 20150087495Abstract: The present invention relates to an alkali-free glass having a strain point of 680 to 735° C., an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa.s of 1,710° C. or lower, and a temperature T4 at which the glass viscosity reaches 104 dPa.s of 1,310° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 63 to 74, Al2O3 11.5 to 16, B2O3 exceeding 1.5 to 5, MgO 5.5 to 13, CaO 1.5 to 12, SrO 1.5 to 9, BaO 0 to 1, and ZrO2 0 to 2, in which MgO+CaO+SrO+BaO is from 15.5 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.35 or more, CaO/(MgO+CaO+SrO+BaO) is 0.50 or less, and SrO/(MgO+CaO+SrO+BaO) is 0.50 or less.Type: ApplicationFiled: December 5, 2014Publication date: March 26, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Manabu NISHIZAWA, Hirofumi Tokunaga, Akio Koike
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Publication number: 20150068595Abstract: A glass substrate for a Cu—In—Ga—Se solar cell. The glass substrate includes the specific amounts of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O and K2O. In the glass substrate, MgO+CaO+SrO+BaO is from 10 to 30%, Na2O+K2O is from 8 to 20%, Na2O/K2O is from 0.7 to 2.0, and (2×Na2O-2×MgO—CaO)×(Na2O/K2O) is from 3 to 22. The glass substrate has a glass transition temperature of from 640 to 700° C., an average coefficient of thermal expansion of from 60×10?7 to 110×10?7/° C., and a density of from 2.45 to 2.9 g/cm3.Type: ApplicationFiled: March 5, 2013Publication date: March 12, 2015Applicant: Asahi Glass Company, LimitedInventors: Yutaka Kuroiwa, Shinichi Amma, Reo Usui, Tomomi Abe, Takeshi Tomizawa
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Patent number: 8969226Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.Type: GrantFiled: November 25, 2008Date of Patent: March 3, 2015Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
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Publication number: 20150051060Abstract: Alkali-doped boroaluminosilicate glasses are provided. The glasses include the network formers SiO2, B2O3, and Al2O3. The glass may, in some embodiments, have a Young's modulus of less than about 65 GPa and/or a coefficient of thermal expansion of less than about 40×10?7/° C. The glass may be used as a cover glass for electronic devices, a color filter substrate, a thin film transistor substrate, or an outer clad layer for a glass laminate.Type: ApplicationFiled: August 8, 2014Publication date: February 19, 2015Inventors: Adam James Ellison, Jason Sanger Frackenpohl, John Christopher Mauro, Douglas Miles Noni, JR., Natesan Venkataraman
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Publication number: 20150045203Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×107 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102dPa.s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPd.s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.Type: ApplicationFiled: October 27, 2014Publication date: February 12, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi TOKUNAGA, Tomoyuki TSUJIMURA, Manabu NISHIZAWA, Akio KOIKE
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Publication number: 20150038315Abstract: To provide a method for producing chemically tempered glass, whereby frequency of replacement of the molten salt can be reduced. A method for producing chemically tempered glass, which comprises repeating ion exchange treatment of immersing glass in a molten salt, wherein the glass comprises, as represented by mole percentage, from 61 to 77% of SiO2, from 1 to 18% of Al2O3, from 3 to 15% of MgO, from 0 to 5% of CaO, from 0 to 4% of ZrO2, from 8 to 18% of Na2O and from 0 to 6% of K2O; SiO2+Al2O3 is from 65 to 85%; MgO+CaO is from 3 to 15%; and R calculated by the following formula by using contents of the respective components, is at least 0.66: R=0.029×SiO2+0.021×Al2O3+0.016×MgO?0.004×CaO+0.016×ZrO2+0.029×Na2O+0×K2O?2.Type: ApplicationFiled: October 21, 2014Publication date: February 5, 2015Applicant: Asahi Glass Company, LimitedInventors: Jun Endo, Shusaku Akiba, Kazutaka Ono, Shigeki Sawamura
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Publication number: 20150030827Abstract: Glass compositions and glass articles comprising the glass compositions are disclosed. In one embodiment, a glass composition includes from about 65 mol. % to about 70 mol. % SiO2; from about 9 mol. % to about 14 mol. % Al2O3; and from about 0 mol. % to about 11 mol. % B2O3 as glass network formers. The glass composition also includes from about 5 mol. % to less than 10 mol. % alkali oxide R2O, wherein R is at least one of Li, Na, and K. The glass composition also includes from about 3 mol. % to about 11 mol. % of divalent oxide MO, wherein M is at least one of Mg, Ca, Ba, SrO and Zn. The glass composition has a coefficient of thermal expansion which is less than or equal to 55×10-7/° C. and is amenable to strengthening by ion-exchange. The glass composition is well suited for use as the glass cladding layers of a laminated glass article.Type: ApplicationFiled: February 27, 2013Publication date: January 29, 2015Applicant: One IncorporatedInventors: Sinue Gomez, Timothy James Kiczenski, John Christopher Mauro, Robert Anthony Schaut, Morten Mattrup Smedskjaer, Natesan Venkataraman
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Publication number: 20150024210Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.Type: ApplicationFiled: August 11, 2014Publication date: January 22, 2015Inventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
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Patent number: 8937027Abstract: A glass composition and its use for producing glass tubes is provided. The glass tubes having the provided composition are particularly suitable for the outer tubes of fluorescent lamps in the case of which a phosphor layer is baked at temperatures of up to 700° C. The tubes composed of the glass of the provided composition have a lower tendency to deform or stick together when processed at high temperatures. To obtain the observed effects, the molar ratio of Na2O/(Na2O+K2O), inter alia, is greater than 0.4 and not more than 0.72.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Schott AGInventors: Erhard Dick, Joerg Hinrich Fechner
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Patent number: 8927444Abstract: A constitution of cover glass, the compositions consist in terms of weight % on the oxide basis, of from 64 to 69 wt. % of SiO2; from 7 to 11.5 wt. % of Al2O3; from 1.5 to 2.5 wt. % of B2O3; from 4.5 to 7.5 wt. % of MgO; 0%<CaO?2.5%; 0%<ZnO?2%; 0%<ZrO2?0.2%; 0%<TiO2?1%; from 14.5 to 16.5 wt. % of Na2O; from 1 to 4 wt. % of K2O; and 0%<SnO2?0.4%. The constitution then can be melted to form cover glass. Thereafter, the cover glass is dipped in KNO3 solution so that sodium ions, which is smaller in volume, contained in certain depth from the surface layer of the cover glass can be substituted by potassium ions, which is larger in volume. In this manner, squeezing effect is generated on the surface layer so as to form cover glass having high strength and resistance in both abrasion and scratch.Type: GrantFiled: March 18, 2013Date of Patent: January 6, 2015Assignee: Fortune Technology Corp.Inventor: Allen Yu
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Patent number: 8916487Abstract: The present invention relates to the glass substrate for an information recording medium comprising the following glass components: SiO2: 52 to 67; Al2O3: 8 to 20; B2O3: 0 to 6, with these three oxides FMO: 70 to 85; Li2O: 0.5 to 4; Na2O: 1 to 8; K2O: 0 to 5; and with these three oxides R2O: 5 to 15; MgO: 2 to 9; CaO: 0.1 to 5; BaO: 0 to 3; SrO: 0 to 3; ZnO: 0 to 5; and with these five oxides: 5 to 15; Y2O3: 0 to 4; La2O3: 0 to 4; Gd2O3: 0 to 4; CeO2: 0 to 4; TiO2: 1 to 7; HfO2: 0 to 2; ZrO2: 0 to 5; Nb2O5: 0.2 to 5; and Ta2O5: 0 to 5, and satisfies Li2O/R2O: 0.05 to 0.35; Li2O/FMO: 0.005 to 0.035; Li2O/(MgO+ZnO): less than 2 and Nb2O5/SiO2: 0.01 to 0.075.Type: GrantFiled: June 21, 2011Date of Patent: December 23, 2014Assignee: Hoya CorporationInventors: Hideki Kawai, Hiroshi Kajita, Akio Oogaki, Toshiharu Mori
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Publication number: 20140356576Abstract: Described herein are various glass compositions, glass articles, and information storage devices that comprise the glass articles as substrates therefor, along with methods for their manufacture and use.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Inventors: Matthew John Dejneka, John Christopher Mauro, Morten Mattrup Smedskjaer
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Patent number: 8877663Abstract: This invention relates to a crystal glass having a refractive index higher than 1.53 and a high mechanical strength, free of any content of compounds of lead, barium and arsenic and guaranteeing maximum safety for health, which consists in that it comprises by weight: 55-70% SiO2, 0.05-3.5% Li2O, 2-15% Na2O, more than 3% and less than 5% or more than 15% and less than 19% K2O, 5 to 10% CaO, more than 1% and less than 4% or more than 7% and less than 8% ZnO, 0.1-3.5% B2O3, 0.1-3.5% Al2O3, 0.1-3.5% TiO2, less than 3.5% ZrO2, 0.05-1.5% Gd2O,3 0.05-1% P2O5, 0.1-1% Sb2O3.Type: GrantFiled: September 1, 2011Date of Patent: November 4, 2014Assignee: Preciosa A.S.Inventors: Miroslav Rada, Kv{hacek over (e)}ta Sázavová, Jan Ko{hacek over (r)}enský, Ji{hacek over (r)}i Vav{hacek over (r)}ena
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Publication number: 20140323287Abstract: Borosilicate glasses, preferably for use in the pharmaceutical sector, are provided. The borosilicate glasses are outstandingly suitable for the use as pharmaceutical primary packaging, such as phials or ampoules, since the aqueous or water-containing medicaments kept in the containers do not attack the glass significantly, and so the glass releases no, or only few, ions. The borosilicate glasses have the following composition in % by weight or consist thereof: SiO2 71-77; B2O3 9-12; Al2O3 5.5-8; Na2O 6-8; K2O 0.1-0.9; Li2O 0-0.3; CaO 0-1.5; BaO 0-1; F 0-0.3; Cl- 0-0.3; and MgO + CaO + BaO + SrO 0-2.Type: ApplicationFiled: April 28, 2014Publication date: October 30, 2014Applicant: SCHOTT AGInventors: Stephan Tratzky, Christof Kass, Rainer Eichholz, Peter Nass
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Publication number: 20140309097Abstract: A glass element is provided that is made of a glass having SiO2, Al2O3, B2O3, and Na2O. The glass has a scratch tolerance that when scratches of 1 mm length are introduced using a Knoop diamond indenter which presses upon a surface of the glass with a force of 4 Newton and is displaced along the surface with a traverse speed of 0.4 mm/s, not more than 20% of the scratches have a noticeable width including visible chipping of more than 25 ?m. In some embodiments, the glass, after chemical tempering, has sodium ions that are at least partially exchanged for potassium ions so that a compressive stress zone is provided at the surface of the glass. The compressive stress is at least 700 MPa and an exchange depth of alkali ions is at least 25 ?m.Type: ApplicationFiled: April 10, 2014Publication date: October 16, 2014Applicant: Schott AGInventors: Oliver Hochrein, Inge Burger, Irmgard Westenberger, Jochen Alkemper, Gerd Rudas, Katharina Alt, Gordon Kissl, Gunther Paulus
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Publication number: 20140308525Abstract: A glass and a glass composition are provided that, following chemical tempering, not only exhibit high values of compressive stress and depth of ion exchange, but also excellent scratch tolerance. The glass composition includes SiO2, Al2O3, B2O3, ZrO2, and Na2O.Type: ApplicationFiled: April 10, 2014Publication date: October 16, 2014Applicant: Schott AGInventors: Oliver Hochrein, Inge Burger, Irmgard Westenberger, Jochen Alkemper, Gerd Rudas, Katharina Alt, Gordon Kissl, Gunther Paulus
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Patent number: 8852764Abstract: To provide a substrate for information recording medium having various properties, in particular higher fracture toughness, required for application of the substrate for information recording medium of the next generation such as perpendicular magnetic recording system, etc. and a material with excellent workability for such purpose. A crystallized glass substrate for information recording medium, consisting of a crystallized glass which comprises one or more selected from RAl2O4 and R2TiO4 as a main crystal phase, in which R is one or more selected from Zn, Mg and Fe, and in which the main crystal phase has a crystal grain size in a range of from 0.5 nm to 20 nm, a degree of crystallinity of 15% or less, and a specific gravity of 3.00 or less.Type: GrantFiled: July 18, 2012Date of Patent: October 7, 2014Assignee: Ohara Inc.Inventors: Toshitaka Yagi, Naoyuki Goto
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Publication number: 20140284577Abstract: Thin glasses having high refractive index (nd), a layer composite assembly made from these thin glasses, a method for the production of the thin glasses, and the uses of the thin glasses are provided. The thin glasses are processed in an in line manufacturing process and have the optical properties of a classical optical glass. The thin glasses are highly transparent, crystallization-resistant, chemically resistant and highly refractive. The viscosity/temperature behavior of the thin glasses is adjusted to the manufacturing process via in line flat glass methods.Type: ApplicationFiled: March 18, 2014Publication date: September 25, 2014Applicant: Schott AGInventors: Karl Mennemann, Uwe Kolberg, Holger Wegener, Monika Gierke, Ute Woelfel, Joerg Fechner
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Publication number: 20140274655Abstract: A constitution of cover glass, the compositions consist in terms of weight % on the oxide basis, of from 64 to 69 wt. % of SiO2; from 7 to 11.5 wt. % of Al2O3; from 1.5 to 2.5 wt. % of B2O3; from 4.5 to 7.5 wt. % of MgO; 0%<CaO?2.5%; 0%<ZnO?2%; 0%<ZrO2?0.2%; 0%<TiO2?1%; from 14.5 to 16.5 wt. % of Na2O; from 1 to 4 wt. % of K2O; and 0%<SnO2?0.4%. The constitution then can be melted to form cover glass. Thereafter, the cover glass is dipped in KNO3 solution so that sodium ions, which is smaller in volume, contained in certain depth from the surface layer of the cover glass can be substituted by potassium ions, which is larger in volume. In this manner, squeezing effect is generated on the surface layer so as to form cover glass having high strength and resistance in both abrasion and scratch.Type: ApplicationFiled: March 18, 2013Publication date: September 18, 2014Inventor: FORTUNE TECHNOLOGY CORP.
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Publication number: 20140264356Abstract: Described herein are aluminoborosilicate glass compositions that are substantially alkali-free and exhibit desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs). The glass compositions can be formed into glass sheets by, for example, the float process. When used as substrates, the glass sheets exhibit dimensional stability during processing and damage resistance during cutting.Type: ApplicationFiled: March 11, 2014Publication date: September 18, 2014Applicant: Corning IncorporatedInventor: Adam James Ellison
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Patent number: 8835335Abstract: An alkali-free glass of the present invention comprises, as a glass composition expressed in terms of oxides by mass %, 45 to 70% of SiO2, 10 to 30% of Al2O3, 11 to 20% of B2O3, less than 0.1% of As2O3, less than 0.1% of Sb2O3, and less than 0.1% of an alkali metal oxide, and has a thermal expansion coefficient (30 to 380° C.) of 30 to 35×10?7/° C.Type: GrantFiled: March 19, 2010Date of Patent: September 16, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventors: Takashi Murata, Shinkichi Miwa
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Patent number: 8828545Abstract: The invention provides a silica-alumina-sodium oxide glass easy to melt and suitable for a low temperature ion exchange process. The glass is suitable for chemical tempering and consists of 55-60 wt % of SiO2, 0.1-2.5 wt % of B2O3, 11-16 wt % of Al2O3, 14-17 wt % of Na2O, 1-8 wt % of K2O, 0-8 wt % of ZrO2, 0-5 wt % of CaO, 0-5 wt % of MgO and 0-1 wt % of Sb2O3. By reasonably setting the composition, the difficulty in glass production decreases and the glass melting temperature is reduced obviously, which is favorable to reduce energy consumption and improve yield of products. Under the condition that tempering temperature is 380?-500? and tempering time is 4-12 h, the surface compressive stress can be 610-1100 Mpa, the depth of a stress layer can be 31-80 ?m, and the glass is reinforced and has high shock resistance. The glass of the invention has high wear resistance and can be used as a protective glass material of high-grade electronic display products such as mobile phones and PDAs.Type: GrantFiled: July 16, 2009Date of Patent: September 9, 2014Assignee: CDGM Glass Co., Ltd.Inventors: Wei Sun, Chuncai Song, Xiaoli Chen, Ning Chen, Jun Xiao, Chang Li
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Publication number: 20140249019Abstract: A glass substrate for p-Si TFT flat panel displays that is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6. A method for manufacturing a glass substrate involves: a melting step of obtaining a molten glass by melting, by employing at least direct electrical heating, glass raw materials blended so as to provide the aforementioned glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.Type: ApplicationFiled: May 15, 2014Publication date: September 4, 2014Applicant: AvanStrate Inc.Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
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Publication number: 20140249018Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.Type: ApplicationFiled: May 13, 2014Publication date: September 4, 2014Applicant: AVANSTRATE INC.Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
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Publication number: 20140247848Abstract: The invention relates to a Nd-doped, aluminate-based or silicate-based, laser glass having a peak emission wavelength that is longer than 1059.7 nm, an emission cross section (?em) of ?1.5×10?20 cm2, and/or an emission bandwidth (??eff) of ?28 nm, while maintaining properties that render the glass suitable for commercial use, such as low glass transition temperature Tg and low nonlinear index, n2.Type: ApplicationFiled: April 14, 2014Publication date: September 4, 2014Applicant: SCHOTT CORPORATIONInventors: Simi GEORGE, Nathan CARLIE, Sally PUCILOWSKI, Joseph HAYDEN
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Publication number: 20140235425Abstract: A glass substrate contains specific contents of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O, K2O and Li2O. The glass substrate has a glass transition temperature of 580 to 720° C., an average coefficient of thermal expansion at 50 to 350° C. of 65×10?7 to 85×10?7/° C., a compaction (C) of 15 ppm or less, a glass surface devitrification temperature Tc of 900 to 1,300° C., a glass internal devitrification temperature Td of 900 to 1,300° C., a temperature T4 at which a viscosity reaches 104 dPa·s of 1,100 to 1,350° C., a relationship (T4?Tc) of ?50 to 350° C. and a relationship (T4?Td) of ?50 to 350° C.Type: ApplicationFiled: April 30, 2014Publication date: August 21, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: Manabu NISHIZAWA
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Publication number: 20140227523Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: ApplicationFiled: May 28, 2013Publication date: August 14, 2014Applicant: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Patent number: 8796165Abstract: The present disclosure relates to glass articles for use as a touchscreen substrate or cover glass article for use in a portable electronic device, particularly an aluminoborosilicate glass being substantially free of alkalis, comprising at least 55 mol % SiO2, at least 5 mol % Al2O3 and at least one alkaline earth RO component. The alkali-free aluminoborosilicate exhibits an Al2O3+B2O3 to RO mol % ratio which exceeds 1 and an Al2O3 to RO mol % ratio which exceeds 0.65. The aluminoborosilicate glasses disclosed herein exhibits high damage resistance as evidenced by a Vickers median/radial crack initiation load which is greater than than 1000 gf, as well as a high scratch resistance of at least 900 gf, as measured by the lack of the presence of lateral cracks when a load is applied by a moving Knoop indenter.Type: GrantFiled: November 8, 2011Date of Patent: August 5, 2014Assignee: Corning IncorporatedInventors: Adam James Ellison, Timothy Michael Gross
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Publication number: 20140209169Abstract: A glass substrate for a CdTe solar cell includes a base composition includes, in terms of mol % on a basis of following oxides: from 60 to 75% of SiO2; from 1 to 7.5% of Al2O3; from 0 to 1% of B2O3; from 8.5 to 12.5% of MgO; from 1 to 6.5% of CaO; from 0 to 3% of SrO; from 0 to 3% of BaO; from 0 to 3% of ZrO2; from 1 to 8% of Na2O; and from 2 to 12% of K2O, wherein MgO+CaO+SrO+BaO is from 10 to 24%, Na2O+K2O is from 5 to 15%, MgO/Al2O3 is 1.3 or more, (2Na2O+K2O+SrO+BaO)/(Al2O3+ZrO2) is 3.3 or less, Na2O/K2O is from 0.2 to 2.0, Al2O3??0.94MgO+11, and CaO?0.48MgO+6.5.Type: ApplicationFiled: March 28, 2014Publication date: July 31, 2014Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Yu HANAWA, Yutaka KUROIWA, Tetsuya NAKASHIMA, Yuki KONDO
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Patent number: 8785336Abstract: Provided is an alkali-free glass, comprising, as a glass composition in terms of mass %, 55 to 80% of SiO2, 10 to 25% of A12O3, 2 to 5.5% of B2O3, 3 to 8% of MgO, 3 to 10% of CaO, 0.5 to 5% of SrO, and 0.5 to 7% of BaO, having a molar ratio MgO/CaO of 0.5 to 1.5, being substantially free of alkali metal oxides, and having a Young's modulus of more than 80 GPa.Type: GrantFiled: March 9, 2012Date of Patent: July 22, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventors: Takahiro Kawaguchi, Shinkichi Miwa
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Publication number: 20140193643Abstract: A method of bonding a first substrate to a second substrate includes providing a glass, applying the glass in a layer between the first and second substrates to form an assembly, and heating the assembly to a bonding temperature above a glass transition temperature of the devitrifying glass, selected to cause the glass to bond the first substrate to the second substrate. The devitrifying glass has constituents that include various amounts of group A in a molar concentration of 70-95%, group B in a molar concentration of 5-20%, group C in a molar concentration of 1-20%, group D in a molar concentration of 0-6%; and group E in a molar concentration of 0-10%. The group A, B, C, D and E groups are disclosed herein.Type: ApplicationFiled: January 4, 2014Publication date: July 10, 2014Applicant: LILLIPUTIAN SYSTEMS, INC.Inventors: Mohammad Masyood Akhtar, Samuel B. Schaevitz, Michael C. Bradford, Zachary Byars, Joseph C. Tucker
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Publication number: 20140186632Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: ApplicationFiled: March 5, 2014Publication date: July 3, 2014Applicant: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Patent number: 8765262Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.Type: GrantFiled: November 15, 2012Date of Patent: July 1, 2014Assignee: Corning IncorporatedInventor: Timothy Michael Gross
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Publication number: 20140179510Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess excellent compaction and stress relaxation properties.Type: ApplicationFiled: December 19, 2013Publication date: June 26, 2014Applicant: Corning IncorporatedInventors: Douglas Clippinger Allan, Bradley Frederick Bowden, Adam James Ellison, Timothy James Kiczenski, Marcel Potuzak
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Patent number: 8759239Abstract: Transparent, essentially colorless ?-quartz glass-ceramic materials, the composition of which is free of As2O3 and of Sb2O3, where said composition contains a specific combination of three nucleating agents: TiO2, ZrO2 and SnO2; TiO2 being present in low quantity.Type: GrantFiled: October 25, 2012Date of Patent: June 24, 2014Assignee: EurokeraInventors: Marie Jacqueline Monique Comte, Lothar Wondraczek
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Patent number: 8748002Abstract: A tempered glass of the present invention includes, as a glass composition, in terms of mass %, 45 to 75% of SiO2, 0 to 30% of Al2O3, and 0 to 30% of Li2O+Na2O+K2O and has a ?-OH value of 0.3 to 1/mm.Type: GrantFiled: December 8, 2009Date of Patent: June 10, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventor: Takashi Murata
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Patent number: 8741794Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R?2O (in which R? is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.Type: GrantFiled: January 18, 2013Date of Patent: June 3, 2014Assignee: Avanstrate Inc.Inventors: Junji Kurachi, Akihiro Koyama, Yoichi Hachitani
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Publication number: 20140141285Abstract: It is an object of the present invention to provide a crystallized glass which has various properties required for employing the substrate for information recording medium of the next generation, and also has significantly low specific gravity; and a crystallized glass substrate for information recording medium. A crystallized glass containing, as a crystal phase, one or more selected from RAl2O4 and R2TiO4 (wherein R is one or more selected from Mg and Fe), the crystallized glass comprising the components of SiO2 of 50% to 70%, Al2O3 of 10% to 26%, TiO2 of 1 to 15%, MgO of 2.5% to 25%, FeO of 0% to 8%, and ZnO of 0% to less than 2%, expressed in terms of mass percentage on an oxide basis, wherein the value of (Al2O3+MgO)/SiO2 is 0.30 or more and 0.65 or less, and a specific gravity is less than 2.63.Type: ApplicationFiled: November 15, 2013Publication date: May 22, 2014Applicant: OHARA INC.Inventors: Kiyoyuki Momono, Katsuhiko Yamaguchi, Toshitaka Yagi, Naoyuki Goto