And Zinc Or Zirconium Patents (Class 501/67)
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Patent number: 12227449Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: GrantFiled: August 11, 2023Date of Patent: February 18, 2025Assignee: CORNING INCORPORATEDInventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Patent number: 12221378Abstract: The present invention relates to a glass for a pharmaceutical container that is excellent in ultraviolet shielding ability, and is also excellent in chemical durability. The glass for a pharmaceutical container of the present invention includes as a glass composition, in terms of mass %, 67% to 81% of SiO2, more than 4% to 7% of Al2O3, 7% to 14% of B2O3, 3% to 12% of Na2O+K2O, 0% to 1.8% of CaO+BaO, 0.5% to less than 2% of Fe2O3, and 1% to 5% of TiO2, and satisfies a relationship of CaO/BaO?0.5.Type: GrantFiled: September 28, 2023Date of Patent: February 11, 2025Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Satoshi Arai
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Patent number: 12162801Abstract: Glass-based articles comprise stress profiles providing improved drop performance. A glass-based substrate comprises: a glass transition temperature (Tg), a liquid fragility index (m), and fictive temperature (Tf), wherein Tg is less than or equal to 650° C., a value of Tf minus Tg is greater than or equal to ?30° C., and m is greater than or equal to 25. A stress relaxation rate is greater than or equal to 10%, or 20% or more. The articles can comprise a lithium-based aluminosilicate composition and a fracture toughness that is greater than or equal to 0.75 MPa*m0.5. The stress profiles comprise: a spike region extending from the first surface to a knee; and a tail region extending from the knee to a center of the glass-based article, the tail region comprising: a negative curvature region wherein a second derivative of stress as a function of depth is negative; a depth of compression (DOC) that is greater than or equal to 0.Type: GrantFiled: September 21, 2021Date of Patent: December 10, 2024Assignee: CORNING INCORPORATEDInventors: Xiaoju Guo, Jason Thomas Harris, Kevin Barry Reiman
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Patent number: 12122703Abstract: Glass-based articles comprise stress profiles providing improved drop performance. A glass-based substrate comprises: a glass transition temperature (Tg), a liquid fragility index (m), and fictive temperature (Tf), wherein Tg is less than or equal to 650° C., a value of Tf minus Tg is greater than or equal to ?30° C., and m is greater than or equal to 25. A stress relaxation rate is greater than or equal to 10%, or 20% or more. The articles can comprise a lithium-based aluminosilicate composition and a fracture toughness that is greater than or equal to 0.75 MPa*m0.5. The stress profiles comprise: a spike region extending from the first surface to a knee; and a tail region extending from the knee to a center of the glass-based article, the tail region comprising: a negative curvature region wherein a second derivative of stress as a function of depth is negative; a depth of compression (DOC) that is greater than or equal to 0.Type: GrantFiled: September 21, 2021Date of Patent: October 22, 2024Assignee: CORNING INCORPORATEDInventors: Xiaoju Guo, Jason Thomas Harris, Kevin Barry Reiman
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Patent number: 12049424Abstract: In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO2; from about 2 wt. % to about 20 wt. % Al2O3; from about 5 wt. % to about 20 wt. % Li2O; greater than 0 wt % to about 3 wt. % Na2O; a non-zero amount of P2O5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO2. In embodiments, ZrO2 (wt. %)+P2O5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.Type: GrantFiled: March 1, 2024Date of Patent: July 30, 2024Assignee: CORNING INCORPORATEDInventors: George Halsey Beall, Qiang Fu, Charlene Marie Smith
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Patent number: 12006255Abstract: A chemically toughenable or toughened glass has, before chemical toughening, a thickness t of at most 1100 ?m. The glass comprises the following components: 45-75 mol-% SiO2; 10-25 mol-% Al2O3; >1-11 mol-% Li2O; 0-15 mol-% P2O5; 0-8 mol-% B2O3; and 0-5 mol-% TiO2. The average number of bridging oxygen per polyhedron (BO) calculated as 2*4?2*(cmol(O)/(cmol(Si)+cmol(Al)+cmol(B)+cmol(P)+cmol(Ti))) is higher than 3.55. Upon chemical toughening, the linear dimension variation in the unit of percentage (V1) is so low that the overall geometry variation (OGV) calculated as (DoL/t)/V1 is higher than 0.8. DoL is the total depth of all ion-exchange layers on one side of the glass and DoL is more than 1 ?m, when the glass is chemically toughened with NaNO3 only, KNO3 only or with both KNO3 and NaNO3.Type: GrantFiled: August 27, 2019Date of Patent: June 11, 2024Assignee: SCHOTT Glass Technologies (Suzhou) Co. Ltd.Inventors: Junming Xue, Feng He, Jose Zimmer, Ning Da
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Patent number: 11952312Abstract: Glass compositions are provided with low Young's modulus and compatibility with slot drawing techniques, due at least in part to liquidus viscosity and liquidus temperature. When ion-exchanged the resulting glass articles are capable of exhibiting a ratio of a peak compressive stress value in MPa to a Young's modulus value in GPa of 13.0 or more. The glass articles may have a peak compressive stress value in a range of 850 MPa to 1400 MPa. The glass articles are suitable for various high-strength applications, including cover glass applications that experience significant bending stresses during use, for example, cover glasses for flexible displays.Type: GrantFiled: February 2, 2022Date of Patent: April 9, 2024Assignee: Corning IncorporatedInventors: Binghui Deng, Xiaoju Guo, Peter Joseph Lezzi
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Patent number: 11884583Abstract: The present invention relates to a method of producing a colored glass for a pharmaceutical container by which the transmittance of a glass to be obtained is easily controlled so as to satisfy the standards of the Japanese Pharmacopoeia.Type: GrantFiled: June 4, 2018Date of Patent: January 30, 2024Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Yuki Yokota
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Patent number: 11814316Abstract: According to one embodiment, a glass article may include SiO2, Al2O3, Li2O and Na2O. The glass article may have a softening point less than or equal to about 810° C. The glass article may also have a high temperature CTE less than or equal to about 27×10?6/° C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 ?m after ion exchange in a salt bath comprising KNO3 at a temperature in a range from about 390° C. to about 450° C. for less than or equal to approximately 15 hours.Type: GrantFiled: September 15, 2021Date of Patent: November 14, 2023Assignee: Corning IncorporatedInventors: Marie Jacqueline Monique Comte, Melinda Ann Drake, Karen Leslie Geisinger, Sinue Gomez, Robert Michael Morena, Charlene Marie Smith, Randall Eugene Youngman
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Patent number: 11807573Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about ?30 MPa/?m.Type: GrantFiled: August 23, 2022Date of Patent: November 7, 2023Assignee: Corning IncorporatedInventors: Yuhui Jin, Joshua James McCaslin, Jong Se Park, Vitor Marino Schneider, Wei Sun
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Patent number: 11807575Abstract: The present invention relates to a glass for a pharmaceutical container that is excellent in ultraviolet shielding ability, and is also excellent in chemical durability. The glass for a pharmaceutical container of the present invention includes as a glass composition, in terms of mass %, 67% to 81% of SiO2, more than 4% to 7% of Al2O3, 7% to 14% of B2O3, 3% to 12% of Na2O+K2O, 0% to 1.8% of CaO+BaO, 0.5% to less than 2% of Fe2O3, and 1% to 5% of TiO2, and satisfies a relationship of CaO/BaO?0.5.Type: GrantFiled: November 29, 2022Date of Patent: November 7, 2023Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Satoshi Arai
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Patent number: 11765846Abstract: Disclosed are device display screen protectors comprising a first strengthened substrate sized to cover a display screen of an electronic device, the first strengthened substrate having a central tension value in the range greater than 0 MPa and less than 20 MPa, a surface having a Knoop lateral cracking scratch threshold of at least 3 N.Type: GrantFiled: February 8, 2021Date of Patent: September 19, 2023Assignee: CORNING INCORPORATEDInventors: Jaymin Amin, Joshua Michael Jacobs, Jonathan David Pesansky, Kevin Barry Reiman, Ananthanarayanan Subramanian
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Patent number: 11702360Abstract: A chemically temperable borosilicate glass article has a low boron content and a corresponding Na2O content. The articles have good diffusivities and hydrolytical resistance values. When chemically tempered, the borosilicate glass article exhibits a compressive stress CS >400 MPa and a penetration depth DoL >20 ?m. A pharmaceutical primary packaging including the borosilicate glass article is also disclosed.Type: GrantFiled: June 18, 2019Date of Patent: July 18, 2023Assignee: Schott AGInventors: Malte Grimm, Christof Kass, Rainer Eichholz
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Patent number: 11629094Abstract: Bulk paint and ceramic powder systems, methods of forming same, and methods of forming a flexible ceramic coating on a metal substrate are disclosed. The systems may include a ceramic composition having between 2 to 30 weight percent of an alkali metal oxide, such as K2O, Na2O, and Li2O or mixtures thereof, between 10 to 74 weight percent SiO2, and between 23 to 79 weight percent B2O3. Additives that are nonwetting with molten metals, such as boron nitride, provide durable coatings for metal processing operations. The ceramic composition may include less than 5 weight percent additional metal oxides. The bulk paint system further may include water and a cellulosic suspension agent to form a bulk paint. The ceramic powder system may be processed to form a uniform powder. The bulk paint or uniform powder may be applied to a metal substrate, such as a ferrous metal substrate, dried, and heated to form a flexible coating on the metal substrate.Type: GrantFiled: February 27, 2018Date of Patent: April 18, 2023Assignee: ZYP Coatings, Inc.Inventors: William Brent Webb, Cressie E. Holcombe, Jr.
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Patent number: 11629093Abstract: Strengthened glass substrates with glass fits and methods for forming the same are disclosed. According to one embodiment, the present invention provides a glass frit with a coefficient of thermal expansion less than or equal to the coefficient of thermal expansion of the glass substrate where it is going to be painted. The glass frit of the present invention has similar ion exchange properties to the glass substrate that is going to be used to paint with the glass frit allowing the glass substrate to be ion-exchanged. The glass frit of the present invention is mixed with an organic carrier.Type: GrantFiled: September 29, 2018Date of Patent: April 18, 2023Assignee: AGP America S.A.Inventors: Mario Arturo Mannheim Astete, Ivan Arturo Cornejo
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Patent number: 11572304Abstract: An alkali-free glass of the present invention includes as a glass composition, in terms of mass %, 55% to 70% of SiO2, 15% to 25% of Al2O3, 0% to 5% of B2O3, 3% to 10% of MgO, 7% to 20% of SrO, and 0% to 5% of BaO, is substantially free of an alkali metal oxide, and has a strain point of more than 720° C.Type: GrantFiled: November 21, 2017Date of Patent: February 7, 2023Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventor: Atsuki Saito
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Patent number: 11554984Abstract: An article comprises a glass substrate. The glass substrate has a first surface having a plurality of vias therein, and a second surface parallel to the first surface. At least one of the first surface and the second surface is an etched surface having a surface roughness (Ra) of 0.75 nm or less. The glass substrate comprises, in mol percent on an oxide basis: 65 mol %?SiO2?75 mol %; 7 mol %?Al2O3?15 mol %; 26.25 mol %?RO+Al2O3?B2O3; 0 mol %?R2O?2 mol %. RO=MgO+CaO+SrO+BaO+ZnO. R2O=Li2O+Na2O+K2O+Rb2O+Cs2O.Type: GrantFiled: February 11, 2019Date of Patent: January 17, 2023Assignee: Corning IncorporatedInventors: Timothy Michael Gross, Yuhui Jin, Ruchirej Yongsunthon, Liying Zhang
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Patent number: 11548266Abstract: Scratch and damage resistant laminated glass articles are disclosed. According to one aspect, a laminated glass article may include a glass core layer formed from an ion exchangeable core glass composition and includes a core glass elastic modulus EC and at least one glass clad layer fused directly to the glass core layer. The at least one glass clad layer may be formed from an ion exchangeable clad glass composition different than the ion exchangeable core glass composition and includes a clad glass elastic modulus ECL. The laminated glass article may have a total thickness T and the at least one glass clad layer may have a thickness TCL that is less than 30% of the total thickness T. EC may be at least 5% greater than ECL.Type: GrantFiled: March 19, 2020Date of Patent: January 10, 2023Assignee: Corning IncorporatedInventors: Timothy Michael Gross, Charlene Marie Smith
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Patent number: 11548265Abstract: Scratch and damage resistant laminated glass articles are disclosed. According to one aspect, a laminated glass article may include a glass core layer formed from core glass composition and includes a core glass elastic modulus EC and at least one glass clad layer fused directly to the glass core layer. The at least one glass clad layer may be formed from an ion exchangeable clad glass composition different than the core glass composition and includes a clad glass elastic modulus ECL. The laminated glass article may have a total thickness T and the at least one glass clad layer may have a thickness TCL that is greater than or equal to 30% of the total thickness T. EC may be at least 5% greater than ECL.Type: GrantFiled: March 19, 2020Date of Patent: January 10, 2023Assignee: Corning IncorporatedInventors: Timothy Michael Gross, Charlene Marie Smith
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Patent number: 11453610Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.Type: GrantFiled: June 28, 2021Date of Patent: September 27, 2022Assignee: CORNING INCORPORATEDInventors: Ryan Claude Andrews, Jill Marie Hall, Pascale Oram, Rostislav Vatchev Roussev, Vitor Marino Schneider, Ljerka Ukrainczyk
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Patent number: 11434167Abstract: A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about ?30 MPa/?m.Type: GrantFiled: May 12, 2021Date of Patent: September 6, 2022Assignee: Corning IncorporatedInventors: Yuhui Jin, Joshua James McCaslin, Jong Se Park, Vitor Marino Schneider, Wei Sun
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Patent number: 11401198Abstract: Provided is a silicate article comprising SiO2, Al2O3, Na2O, K2O, MgO and ZrO2, wherein the content of Al2O3 is 15-28 parts by weight, the content of Na2O is 13-25 parts by weight, the content of K2O is 6-15 parts by weight, the content of MgO is 7-16 parts by weight, and the content of ZrO2 is 0.1-5 parts by weight, relative to 100 parts by weight of SiO2; and M is 5-13, as calculated by the following formula: M=P1*wt (Na2O)+P2*wt (K2O)+P3*wt (MgO)+P4*wt (ZrO2)?P5*wt (Al2O3)*wt (Al2O3). In the formula, P1 has a value of 0.53, P2 has a value of 0.153, P3 has a value of 0.36, P4 has a value of 0.67, and P5 has a value of 0.018.Type: GrantFiled: August 10, 2017Date of Patent: August 2, 2022Assignee: TUNGHSU GROUP CO., LTD.Inventors: Debao Li, Qing Li, Zihan Shen, Feng Guo, Ruhua Gong, Zhonghua Wang, Jiajia Chen
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Patent number: 11319241Abstract: The invention discloses a composition for preparing glass, a glass article and a use thereof, and a glass article made from the composition. The glass article is preferably a glass substrate made from a composition with an M value of from about 1 to about 10 as calculated by the empirical equation: M=0.13×wt (B2O3)×wt (B2O3)+0.42×wt (CaO)+0.55×wt (MgO)+0.75×wt (SrO)?0.05×wt (Al2O3)×wt (Al2O3). A use of the glass article (especially the glass substrate) for manufacturing a display device is disclosed herein, wherein the glass article has better properties, such as lowered content of solid inclusions and gas inclusions, lowered thickness range and lowered warpage.Type: GrantFiled: November 10, 2017Date of Patent: May 3, 2022Assignee: TUNGHSU GROUP CO., LTD.Inventors: Debao Li, Qing Li, Guangtao Zhang, Zhonghua Wang, Feng Guo, Dongcheng Yan
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Patent number: 11066325Abstract: To provide an alkali-free glass having a high specific elastic modulus, a suitable strain point, a low density, a not too low thermal expansion coefficient, a good clarity and a good solubility. An alkali-free glass, which comprises, as represented by mol % based on oxides, SiO2: 62 to 70%, Al2O3: 11 to 14%, B2O3: 3 to 6%, MgO: 7 to 10%, CaO: 3 to 9%, SrO: 1 to 5% and BaO: 0 to 1%, wherein [SiO2]+0.7[Al2O3]+1.2[B2O3]+0.5[MgO]+0.4[CaO]?0.25[SrO]?0.88[BaO] is at least 85, [SiO2]+0.45[Al2O3]+0.21[B2O3]?0.042[MgO]+0.042[CaO]+0.15[SrO]+0.38[BaO] is from 72 to 75, 0.4[SiO2]+0.4[Al2O3]+0.25[B2O3]?0.7[MgO]?0.88[CaO]?1.4[SrO]?1.7[BaO] is at most 19, the specific modulus is at least 32 MN·m/kg, the strain point is from 690 to 710° C., the density is at most 2.54 g/cm3, the average thermal expansion coefficient at from 50 to 350° C. is at least 35×10?7/° C., and the temperature T2 at which the glass viscosity reaches 102 dPa·s is from 1,610 to 1,680° C.Type: GrantFiled: October 16, 2018Date of Patent: July 20, 2021Assignee: AGC Inc.Inventors: Hirofumi Tokunaga, Kazutaka Ono
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Patent number: 11021389Abstract: A supporting glass substrate has a ratio of a Young's modulus (GPa) to a density (g/cm3) that is 37.0 (GPa·cm3/g) or more and the ratio has a value larger than a ratio calculation value, the ratio calculation value being a ratio of a Young's modulus (GPa) calculated from a composition to a density (g/cm3). The ratio calculation value is represented by the following expression: ?=2·?{(Vi·Gi)/Mi·Xi}, where, in the expression, Vi is a filling parameter of a metal oxide contained in the supporting glass substrate, Gi is a dissociation energy of a metal oxide contained in the supporting glass substrate, Mi is a molecular weight of a metal oxide contained in the supporting glass substrate, and Xi is a molar ratio of a metal oxide contained in the supporting glass substrate.Type: GrantFiled: July 29, 2020Date of Patent: June 1, 2021Assignee: AGC Inc.Inventors: Seiji Inaba, Yasunari Saito, Kiyoshi Tamai, Kazutaka Ono, Yuha Kobayashi
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Patent number: 10494293Abstract: A thermally tempered glass element is provided made of glass with two opposite faces that are under compressive stress of at least 40 MPa. The glass has a working point at which the glass has a viscosity of 104 dPa·s of at most 1350° C. The glass has a viscosity versus temperature profile and a coefficient of thermal expansion versus temperature profile of the glass are such that a variable (750° C.?T13)/(CTELiq?CTESol) has a value of at most 5*106 K2. The CTELiq is a coefficient of linear thermal expansion of the glass above a glass transition temperature Tg, the CTESol is a coefficient of linear thermal expansion of the glass in a temperature range from 20° C. to 300° C., and the T13 is a temperature at which the glass has a viscosity of 1013 dPa·s.Type: GrantFiled: November 23, 2016Date of Patent: December 3, 2019Assignee: SCHOTT AGInventors: Michael Schwall, Christian Mlx, Jochen Alkemper, Peter Thomas
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Patent number: 10450217Abstract: A glass for pharmaceutical containers, which is resistant to delamination and has excellent processibility, is provided. The glass for pharmaceutical containers comprises, in mol % on an oxide basis, 69 to 81% of SiO2, 4 to 12% of Al2O3, 0 to 5% of B2O3, to 20% of Li2O+Na2O+K2O, 0.1 to 12% of Li2O, and 0 to 10% of MgO+CaO+SrO+BaO. The glass has a hydrolytic resistance of Class 1 in a test in accordance with the European pharmacopoeia.Type: GrantFiled: May 8, 2018Date of Patent: October 22, 2019Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Kazuyuki Yamamoto, Ken Choju
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Patent number: 10377656Abstract: A method includes contacting a second layer of a glass sheet with a forming surface to form a shaped glass article. The glass sheet includes a first layer adjacent to the second layer. The first layer includes a first glass composition. The second layer includes a second glass composition. An effective viscosity of the glass sheet during the contacting step is less than a viscosity of the second layer of the glass sheet during the contacting step. A shaped glass article includes a first layer including a first glass composition and a second layer including a second glass composition. A softening point of the first glass composition is less than a softening point of the second glass composition. An effective 108.2 P temperature of the glass article is at most about 900° C.Type: GrantFiled: May 7, 2015Date of Patent: August 13, 2019Assignee: Corning IncorporatedInventors: Thierry Luc Alain Dannoux, Vladislav Yuryevich Golyatin, John Richard Ridge, Ljerka Ukrainczyk, Butchi Reddy Vaddi, Natesan Venkataraman
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Patent number: 9802857Abstract: Substantially alkali free glasses are disclosed with can be used to produce substrates for flat panel display devices, e.g., active-matrix liquid crystal displays (AMLCDs). The glasses have high annealing temperatures and etch rates. Methods for producing substantially alkali free glasses using a downdraw process (e.g., a fusion process) are also disclosed.Type: GrantFiled: February 19, 2016Date of Patent: October 31, 2017Assignee: Corning IncorporatedInventors: Bradley Frederick Bowden, Adam James Ellison, Timothy James Kiczenski
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Patent number: 9782949Abstract: Laminated articles and layered articles, for example, low alkali glass laminated articles and layered articles useful for, for example, electrochromic devices are described.Type: GrantFiled: April 21, 2009Date of Patent: October 10, 2017Assignee: Corning IncorporatedInventors: David Francis Dawson-Elli, Steven Edward DeMartino, Laura L Hluck
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Patent number: 9540273Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.Type: GrantFiled: November 17, 2015Date of Patent: January 10, 2017Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi Tokunaga, Tomoyuki Tsujimura, Manabu Nishizawa, Akio Koike
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Patent number: 9051214Abstract: Certain example embodiments relate to an improved method of strengthening glass substrates (e.g., soda lime silica glass substrates). In certain examples, a glass substrate may be chemically strengthened by creating an electric field within the glass. In certain cases, the chemical tempering may be performed by surrounding the substrate by a plasma including certain ions, such as Li+, K+, Mg2+, and/or the like. In some cases, these ions may be forced into the glass substrate due to the half-cycles of the electric field generated by the electrodes that formed the plasma. This may advantageously chemically strengthen a glass substrate on a substantially reduced time scale. In other example embodiments, an electric field may be set in a float bath such that sodium ions are driven from the molten glass ribbon into the tin bath, which may advantageously result in a stronger glass substrate with reduced sodium content.Type: GrantFiled: September 2, 2011Date of Patent: June 9, 2015Assignee: Guardian Industries Corp.Inventors: Vijayen S. Veerasamy, Xuequn Hu, Glenn A. Cerny
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Publication number: 20150147575Abstract: Alkali aluminosilicate glasses that are ion exchangeable to high compressive stresses, have fast ion exchange kinetics, and high intrinsic damage resistance. The glasses achieve all of the above desired properties either with only small amounts of P2O5 (<1 mol %) or without addition of any P2O5.Type: ApplicationFiled: November 18, 2014Publication date: May 28, 2015Inventors: Matthew John Dejneka, John Christopher Mauro
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Publication number: 20150140325Abstract: Embodiments of glass composition including at least about 65 mol % SiO2, Al2O3 in the range from about 7 mol % to about 11 mol %, Na2O in the range from about 13 mol % to about 16 mol %; and a non-zero amount of one or more alkali earth metal oxides selected from MgO, CaO and ZnO, wherein the sum of the alkali earth metal oxides is up to about 6 mol %, are disclosed. The glass compositions can be processed using fusion forming processes and float forming processes and are ion exchangeable. Glass articles including such glass compositions and methods of forming such glass articles are also disclosed. The glass articles of one or more embodiments exhibit a Vickers indentation crack initiation load of at least 8 kgf.Type: ApplicationFiled: November 14, 2014Publication date: May 21, 2015Inventors: Timothy Michael Gross, Xiaoju Guo, Charlene Marie Smith
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Publication number: 20150118497Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).Type: ApplicationFiled: January 7, 2015Publication date: April 30, 2015Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
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Publication number: 20150093561Abstract: The present invention relates to an alkali-free glass having a strain point of from 680 to 735° C., an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., and a specific gravity of 2.60 or less, and containing, indicated by mol % on the basis of oxides, SiO2 65 to 69%, Al2O3 11.5 to 14%, B2O3 3 to 6.5%, MgO 1 to 5%, CaO 7.5 to 12%, SrO 0 to 1%, BaO 0.5 to 6%, and ZrO2 0 to 2%.Type: ApplicationFiled: December 8, 2014Publication date: April 2, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi Tokunaga, Manabu Nishizawa, Akio Koike
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Publication number: 20150087495Abstract: The present invention relates to an alkali-free glass having a strain point of 680 to 735° C., an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa.s of 1,710° C. or lower, and a temperature T4 at which the glass viscosity reaches 104 dPa.s of 1,310° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 63 to 74, Al2O3 11.5 to 16, B2O3 exceeding 1.5 to 5, MgO 5.5 to 13, CaO 1.5 to 12, SrO 1.5 to 9, BaO 0 to 1, and ZrO2 0 to 2, in which MgO+CaO+SrO+BaO is from 15.5 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.35 or more, CaO/(MgO+CaO+SrO+BaO) is 0.50 or less, and SrO/(MgO+CaO+SrO+BaO) is 0.50 or less.Type: ApplicationFiled: December 5, 2014Publication date: March 26, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Manabu NISHIZAWA, Hirofumi Tokunaga, Akio Koike
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Publication number: 20150087494Abstract: The present invention relates to an alkali-free glass having a strain point of 710° C. or higher, an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102 dPa·s of 1,710° C. or lower, and a temperature T4 at which the glass viscosity reaches 104 dPa·s of 1,320° C. or lower, containing, indicated by % by mass on the basis of oxides: SiO2 58.5 to 67.5, Al2O3 18 to 24, B2O3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5, and ZrO2 0 to 4.0, containing 0 to 0.35% by mass of Cl, 0.01 to 0.15% by mass of F, and 0.01 to 0.3% by mass of SnO2, and having a ?-OH value of the glass of from 0.15 to 0.60 mm?1.Type: ApplicationFiled: December 4, 2014Publication date: March 26, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi TOKUNAGA, Akio Koike, Manabu Nishizawa, Tomoyuki Tsujimura
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Publication number: 20150068595Abstract: A glass substrate for a Cu—In—Ga—Se solar cell. The glass substrate includes the specific amounts of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O and K2O. In the glass substrate, MgO+CaO+SrO+BaO is from 10 to 30%, Na2O+K2O is from 8 to 20%, Na2O/K2O is from 0.7 to 2.0, and (2×Na2O-2×MgO—CaO)×(Na2O/K2O) is from 3 to 22. The glass substrate has a glass transition temperature of from 640 to 700° C., an average coefficient of thermal expansion of from 60×10?7 to 110×10?7/° C., and a density of from 2.45 to 2.9 g/cm3.Type: ApplicationFiled: March 5, 2013Publication date: March 12, 2015Applicant: Asahi Glass Company, LimitedInventors: Yutaka Kuroiwa, Shinichi Amma, Reo Usui, Tomomi Abe, Takeshi Tomizawa
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Patent number: 8969226Abstract: A silicate glass that is tough and scratch resistant. The toughness is increased by minimizing the number of non-bridging oxygen atoms in the glass. In one embodiment, the silicate glass is an aluminoborosilicate glass in which ?15 mol %?(R2O+R?O—Al2O3—ZrO2)—B2O3?4 mol %, where R is one of Li, Na, K, Rb, and Cs, and R? is one of Mg, Ca, Sr, and Ba.Type: GrantFiled: November 25, 2008Date of Patent: March 3, 2015Assignee: Corning IncorporatedInventors: Matthew John Dejneka, Adam James Ellison, Sinue Gomez, Robert Michael Morena
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Publication number: 20150051060Abstract: Alkali-doped boroaluminosilicate glasses are provided. The glasses include the network formers SiO2, B2O3, and Al2O3. The glass may, in some embodiments, have a Young's modulus of less than about 65 GPa and/or a coefficient of thermal expansion of less than about 40×10?7/° C. The glass may be used as a cover glass for electronic devices, a color filter substrate, a thin film transistor substrate, or an outer clad layer for a glass laminate.Type: ApplicationFiled: August 8, 2014Publication date: February 19, 2015Inventors: Adam James Ellison, Jason Sanger Frackenpohl, John Christopher Mauro, Douglas Miles Noni, JR., Natesan Venkataraman
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Publication number: 20150045203Abstract: The present invention relates to a non-alkali glass having a strain point of from 710° C. to lower than 725° C., an average thermal expansion coefficient at from 50 to 300° C. of from 30×107 to 43×10?7/° C., a temperature T2 at which glass viscosity reaches 102dPa.s of 1710° C. or lower, a temperature T4 at which the glass viscosity reaches 104 dPd.s of 1320° C. or lower, and containing, indicated by mol % on the basis of oxides, SiO2 66 to 70, Al2O3 12 to 14, B2O3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2.Type: ApplicationFiled: October 27, 2014Publication date: February 12, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Hirofumi TOKUNAGA, Tomoyuki TSUJIMURA, Manabu NISHIZAWA, Akio KOIKE
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Publication number: 20150038315Abstract: To provide a method for producing chemically tempered glass, whereby frequency of replacement of the molten salt can be reduced. A method for producing chemically tempered glass, which comprises repeating ion exchange treatment of immersing glass in a molten salt, wherein the glass comprises, as represented by mole percentage, from 61 to 77% of SiO2, from 1 to 18% of Al2O3, from 3 to 15% of MgO, from 0 to 5% of CaO, from 0 to 4% of ZrO2, from 8 to 18% of Na2O and from 0 to 6% of K2O; SiO2+Al2O3 is from 65 to 85%; MgO+CaO is from 3 to 15%; and R calculated by the following formula by using contents of the respective components, is at least 0.66: R=0.029×SiO2+0.021×Al2O3+0.016×MgO?0.004×CaO+0.016×ZrO2+0.029×Na2O+0×K2O?2.Type: ApplicationFiled: October 21, 2014Publication date: February 5, 2015Applicant: Asahi Glass Company, LimitedInventors: Jun Endo, Shusaku Akiba, Kazutaka Ono, Shigeki Sawamura
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Publication number: 20150030827Abstract: Glass compositions and glass articles comprising the glass compositions are disclosed. In one embodiment, a glass composition includes from about 65 mol. % to about 70 mol. % SiO2; from about 9 mol. % to about 14 mol. % Al2O3; and from about 0 mol. % to about 11 mol. % B2O3 as glass network formers. The glass composition also includes from about 5 mol. % to less than 10 mol. % alkali oxide R2O, wherein R is at least one of Li, Na, and K. The glass composition also includes from about 3 mol. % to about 11 mol. % of divalent oxide MO, wherein M is at least one of Mg, Ca, Ba, SrO and Zn. The glass composition has a coefficient of thermal expansion which is less than or equal to 55×10-7/° C. and is amenable to strengthening by ion-exchange. The glass composition is well suited for use as the glass cladding layers of a laminated glass article.Type: ApplicationFiled: February 27, 2013Publication date: January 29, 2015Applicant: One IncorporatedInventors: Sinue Gomez, Timothy James Kiczenski, John Christopher Mauro, Robert Anthony Schaut, Morten Mattrup Smedskjaer, Natesan Venkataraman
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Publication number: 20150024210Abstract: A glass that is down-drawable and ion exchangeable. The glass has a temperature T35kp which the viscosity is 35 kilopoise. T35kp is less than the breakdown temperature Tbreakdown of zircon.Type: ApplicationFiled: August 11, 2014Publication date: January 22, 2015Inventors: Matthew John Dejneka, Adam James Ellison, Benjamin Zain Hanson
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Patent number: 8937027Abstract: A glass composition and its use for producing glass tubes is provided. The glass tubes having the provided composition are particularly suitable for the outer tubes of fluorescent lamps in the case of which a phosphor layer is baked at temperatures of up to 700° C. The tubes composed of the glass of the provided composition have a lower tendency to deform or stick together when processed at high temperatures. To obtain the observed effects, the molar ratio of Na2O/(Na2O+K2O), inter alia, is greater than 0.4 and not more than 0.72.Type: GrantFiled: August 27, 2012Date of Patent: January 20, 2015Assignee: Schott AGInventors: Erhard Dick, Joerg Hinrich Fechner
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Patent number: 8927444Abstract: A constitution of cover glass, the compositions consist in terms of weight % on the oxide basis, of from 64 to 69 wt. % of SiO2; from 7 to 11.5 wt. % of Al2O3; from 1.5 to 2.5 wt. % of B2O3; from 4.5 to 7.5 wt. % of MgO; 0%<CaO?2.5%; 0%<ZnO?2%; 0%<ZrO2?0.2%; 0%<TiO2?1%; from 14.5 to 16.5 wt. % of Na2O; from 1 to 4 wt. % of K2O; and 0%<SnO2?0.4%. The constitution then can be melted to form cover glass. Thereafter, the cover glass is dipped in KNO3 solution so that sodium ions, which is smaller in volume, contained in certain depth from the surface layer of the cover glass can be substituted by potassium ions, which is larger in volume. In this manner, squeezing effect is generated on the surface layer so as to form cover glass having high strength and resistance in both abrasion and scratch.Type: GrantFiled: March 18, 2013Date of Patent: January 6, 2015Assignee: Fortune Technology Corp.Inventor: Allen Yu
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Patent number: 8916487Abstract: The present invention relates to the glass substrate for an information recording medium comprising the following glass components: SiO2: 52 to 67; Al2O3: 8 to 20; B2O3: 0 to 6, with these three oxides FMO: 70 to 85; Li2O: 0.5 to 4; Na2O: 1 to 8; K2O: 0 to 5; and with these three oxides R2O: 5 to 15; MgO: 2 to 9; CaO: 0.1 to 5; BaO: 0 to 3; SrO: 0 to 3; ZnO: 0 to 5; and with these five oxides: 5 to 15; Y2O3: 0 to 4; La2O3: 0 to 4; Gd2O3: 0 to 4; CeO2: 0 to 4; TiO2: 1 to 7; HfO2: 0 to 2; ZrO2: 0 to 5; Nb2O5: 0.2 to 5; and Ta2O5: 0 to 5, and satisfies Li2O/R2O: 0.05 to 0.35; Li2O/FMO: 0.005 to 0.035; Li2O/(MgO+ZnO): less than 2 and Nb2O5/SiO2: 0.01 to 0.075.Type: GrantFiled: June 21, 2011Date of Patent: December 23, 2014Assignee: Hoya CorporationInventors: Hideki Kawai, Hiroshi Kajita, Akio Oogaki, Toshiharu Mori
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Publication number: 20140356576Abstract: Described herein are various glass compositions, glass articles, and information storage devices that comprise the glass articles as substrates therefor, along with methods for their manufacture and use.Type: ApplicationFiled: May 29, 2013Publication date: December 4, 2014Inventors: Matthew John Dejneka, John Christopher Mauro, Morten Mattrup Smedskjaer
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Patent number: 8877663Abstract: This invention relates to a crystal glass having a refractive index higher than 1.53 and a high mechanical strength, free of any content of compounds of lead, barium and arsenic and guaranteeing maximum safety for health, which consists in that it comprises by weight: 55-70% SiO2, 0.05-3.5% Li2O, 2-15% Na2O, more than 3% and less than 5% or more than 15% and less than 19% K2O, 5 to 10% CaO, more than 1% and less than 4% or more than 7% and less than 8% ZnO, 0.1-3.5% B2O3, 0.1-3.5% Al2O3, 0.1-3.5% TiO2, less than 3.5% ZrO2, 0.05-1.5% Gd2O,3 0.05-1% P2O5, 0.1-1% Sb2O3.Type: GrantFiled: September 1, 2011Date of Patent: November 4, 2014Assignee: Preciosa A.S.Inventors: Miroslav Rada, Kv{hacek over (e)}ta Sázavová, Jan Ko{hacek over (r)}enský, Ji{hacek over (r)}i Vav{hacek over (r)}ena