And Zinc Or Zirconium Patents (Class 501/67)
  • Publication number: 20140274655
    Abstract: A constitution of cover glass, the compositions consist in terms of weight % on the oxide basis, of from 64 to 69 wt. % of SiO2; from 7 to 11.5 wt. % of Al2O3; from 1.5 to 2.5 wt. % of B2O3; from 4.5 to 7.5 wt. % of MgO; 0%<CaO?2.5%; 0%<ZnO?2%; 0%<ZrO2?0.2%; 0%<TiO2?1%; from 14.5 to 16.5 wt. % of Na2O; from 1 to 4 wt. % of K2O; and 0%<SnO2?0.4%. The constitution then can be melted to form cover glass. Thereafter, the cover glass is dipped in KNO3 solution so that sodium ions, which is smaller in volume, contained in certain depth from the surface layer of the cover glass can be substituted by potassium ions, which is larger in volume. In this manner, squeezing effect is generated on the surface layer so as to form cover glass having high strength and resistance in both abrasion and scratch.
    Type: Application
    Filed: March 18, 2013
    Publication date: September 18, 2014
    Inventor: FORTUNE TECHNOLOGY CORP.
  • Patent number: 8835335
    Abstract: An alkali-free glass of the present invention comprises, as a glass composition expressed in terms of oxides by mass %, 45 to 70% of SiO2, 10 to 30% of Al2O3, 11 to 20% of B2O3, less than 0.1% of As2O3, less than 0.1% of Sb2O3, and less than 0.1% of an alkali metal oxide, and has a thermal expansion coefficient (30 to 380° C.) of 30 to 35×10?7/° C.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: September 16, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Takashi Murata, Shinkichi Miwa
  • Patent number: 8828545
    Abstract: The invention provides a silica-alumina-sodium oxide glass easy to melt and suitable for a low temperature ion exchange process. The glass is suitable for chemical tempering and consists of 55-60 wt % of SiO2, 0.1-2.5 wt % of B2O3, 11-16 wt % of Al2O3, 14-17 wt % of Na2O, 1-8 wt % of K2O, 0-8 wt % of ZrO2, 0-5 wt % of CaO, 0-5 wt % of MgO and 0-1 wt % of Sb2O3. By reasonably setting the composition, the difficulty in glass production decreases and the glass melting temperature is reduced obviously, which is favorable to reduce energy consumption and improve yield of products. Under the condition that tempering temperature is 380?-500? and tempering time is 4-12 h, the surface compressive stress can be 610-1100 Mpa, the depth of a stress layer can be 31-80 ?m, and the glass is reinforced and has high shock resistance. The glass of the invention has high wear resistance and can be used as a protective glass material of high-grade electronic display products such as mobile phones and PDAs.
    Type: Grant
    Filed: July 16, 2009
    Date of Patent: September 9, 2014
    Assignee: CDGM Glass Co., Ltd.
    Inventors: Wei Sun, Chuncai Song, Xiaoli Chen, Ning Chen, Jun Xiao, Chang Li
  • Publication number: 20140249019
    Abstract: A glass substrate for p-Si TFT flat panel displays that is composed of a glass comprising 52-78 mass % of SiO2, 3-25 mass % of Al2O3, 3-15 mass % of B2O3, 3-25 mass % of RO, wherein RO is total amount of MgO, CaO, SrO, and BaO, 0.01-1 mass % of Fe2O3, and 0-0.3 mass % of Sb2O3, and substantially not comprising As2O3, the glass having a mass ratio (SiO2+Al2O3)/B2O3 in a range of 7-30 and a mass ratio (SiO2+Al2O3)/RO equal to or greater than 6. A method for manufacturing a glass substrate involves: a melting step of obtaining a molten glass by melting, by employing at least direct electrical heating, glass raw materials blended so as to provide the aforementioned glass composition; a forming step of forming the molten glass into a flat-plate glass; and an annealing step of annealing the flat-plate glass.
    Type: Application
    Filed: May 15, 2014
    Publication date: September 4, 2014
    Applicant: AvanStrate Inc.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Publication number: 20140249018
    Abstract: A flat panel display glass substrate according to the present invention includes a glass comprising, as expressed in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, 3-25% RO (the total amount of MgO, CaO, SrO, and BaO), and substantially no As2O3, and Sb2O3. The devitrification temperature of the glass is 1250° C. or less. The glass substrate has a heat shrinkage rate of 75 ppm or less. The heat shrinkage rate is calculated from the amount of shrinkage of the glass substrate measured after a heat treatment which is performed at a temperature rising and falling rate of 10° C./min and at 550° C. for 2 hours by the heat shrinkage rate (ppm)={the amount of shrinkage of the glass substrate after the heat treatment/the length of the glass substrate before the heat treatment}×106.
    Type: Application
    Filed: May 13, 2014
    Publication date: September 4, 2014
    Applicant: AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Manabu ICHIKAWA
  • Publication number: 20140247848
    Abstract: The invention relates to a Nd-doped, aluminate-based or silicate-based, laser glass having a peak emission wavelength that is longer than 1059.7 nm, an emission cross section (?em) of ?1.5×10?20 cm2, and/or an emission bandwidth (??eff) of ?28 nm, while maintaining properties that render the glass suitable for commercial use, such as low glass transition temperature Tg and low nonlinear index, n2.
    Type: Application
    Filed: April 14, 2014
    Publication date: September 4, 2014
    Applicant: SCHOTT CORPORATION
    Inventors: Simi GEORGE, Nathan CARLIE, Sally PUCILOWSKI, Joseph HAYDEN
  • Publication number: 20140235425
    Abstract: A glass substrate contains specific contents of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, Na2O, K2O and Li2O. The glass substrate has a glass transition temperature of 580 to 720° C., an average coefficient of thermal expansion at 50 to 350° C. of 65×10?7 to 85×10?7/° C., a compaction (C) of 15 ppm or less, a glass surface devitrification temperature Tc of 900 to 1,300° C., a glass internal devitrification temperature Td of 900 to 1,300° C., a temperature T4 at which a viscosity reaches 104 dPa·s of 1,100 to 1,350° C., a relationship (T4?Tc) of ?50 to 350° C. and a relationship (T4?Td) of ?50 to 350° C.
    Type: Application
    Filed: April 30, 2014
    Publication date: August 21, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventor: Manabu NISHIZAWA
  • Publication number: 20140227523
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).
    Type: Application
    Filed: May 28, 2013
    Publication date: August 14, 2014
    Applicant: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 8796165
    Abstract: The present disclosure relates to glass articles for use as a touchscreen substrate or cover glass article for use in a portable electronic device, particularly an aluminoborosilicate glass being substantially free of alkalis, comprising at least 55 mol % SiO2, at least 5 mol % Al2O3 and at least one alkaline earth RO component. The alkali-free aluminoborosilicate exhibits an Al2O3+B2O3 to RO mol % ratio which exceeds 1 and an Al2O3 to RO mol % ratio which exceeds 0.65. The aluminoborosilicate glasses disclosed herein exhibits high damage resistance as evidenced by a Vickers median/radial crack initiation load which is greater than than 1000 gf, as well as a high scratch resistance of at least 900 gf, as measured by the lack of the presence of lateral cracks when a load is applied by a moving Knoop indenter.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: August 5, 2014
    Assignee: Corning Incorporated
    Inventors: Adam James Ellison, Timothy Michael Gross
  • Publication number: 20140209169
    Abstract: A glass substrate for a CdTe solar cell includes a base composition includes, in terms of mol % on a basis of following oxides: from 60 to 75% of SiO2; from 1 to 7.5% of Al2O3; from 0 to 1% of B2O3; from 8.5 to 12.5% of MgO; from 1 to 6.5% of CaO; from 0 to 3% of SrO; from 0 to 3% of BaO; from 0 to 3% of ZrO2; from 1 to 8% of Na2O; and from 2 to 12% of K2O, wherein MgO+CaO+SrO+BaO is from 10 to 24%, Na2O+K2O is from 5 to 15%, MgO/Al2O3 is 1.3 or more, (2Na2O+K2O+SrO+BaO)/(Al2O3+ZrO2) is 3.3 or less, Na2O/K2O is from 0.2 to 2.0, Al2O3??0.94MgO+11, and CaO?0.48MgO+6.5.
    Type: Application
    Filed: March 28, 2014
    Publication date: July 31, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yu HANAWA, Yutaka KUROIWA, Tetsuya NAKASHIMA, Yuki KONDO
  • Patent number: 8785336
    Abstract: Provided is an alkali-free glass, comprising, as a glass composition in terms of mass %, 55 to 80% of SiO2, 10 to 25% of A12O3, 2 to 5.5% of B2O3, 3 to 8% of MgO, 3 to 10% of CaO, 0.5 to 5% of SrO, and 0.5 to 7% of BaO, having a molar ratio MgO/CaO of 0.5 to 1.5, being substantially free of alkali metal oxides, and having a Young's modulus of more than 80 GPa.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: July 22, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Takahiro Kawaguchi, Shinkichi Miwa
  • Publication number: 20140193643
    Abstract: A method of bonding a first substrate to a second substrate includes providing a glass, applying the glass in a layer between the first and second substrates to form an assembly, and heating the assembly to a bonding temperature above a glass transition temperature of the devitrifying glass, selected to cause the glass to bond the first substrate to the second substrate. The devitrifying glass has constituents that include various amounts of group A in a molar concentration of 70-95%, group B in a molar concentration of 5-20%, group C in a molar concentration of 1-20%, group D in a molar concentration of 0-6%; and group E in a molar concentration of 0-10%. The group A, B, C, D and E groups are disclosed herein.
    Type: Application
    Filed: January 4, 2014
    Publication date: July 10, 2014
    Applicant: LILLIPUTIAN SYSTEMS, INC.
    Inventors: Mohammad Masyood Akhtar, Samuel B. Schaevitz, Michael C. Bradford, Zachary Byars, Joseph C. Tucker
  • Publication number: 20140186632
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least 10 kilogram force (kgf).
    Type: Application
    Filed: March 5, 2014
    Publication date: July 3, 2014
    Applicant: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 8765262
    Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.
    Type: Grant
    Filed: November 15, 2012
    Date of Patent: July 1, 2014
    Assignee: Corning Incorporated
    Inventor: Timothy Michael Gross
  • Publication number: 20140179510
    Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess excellent compaction and stress relaxation properties.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 26, 2014
    Applicant: Corning Incorporated
    Inventors: Douglas Clippinger Allan, Bradley Frederick Bowden, Adam James Ellison, Timothy James Kiczenski, Marcel Potuzak
  • Patent number: 8759239
    Abstract: Transparent, essentially colorless ?-quartz glass-ceramic materials, the composition of which is free of As2O3 and of Sb2O3, where said composition contains a specific combination of three nucleating agents: TiO2, ZrO2 and SnO2; TiO2 being present in low quantity.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: June 24, 2014
    Assignee: Eurokera
    Inventors: Marie Jacqueline Monique Comte, Lothar Wondraczek
  • Patent number: 8748002
    Abstract: A tempered glass of the present invention includes, as a glass composition, in terms of mass %, 45 to 75% of SiO2, 0 to 30% of Al2O3, and 0 to 30% of Li2O+Na2O+K2O and has a ?-OH value of 0.3 to 1/mm.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: June 10, 2014
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takashi Murata
  • Patent number: 8741794
    Abstract: A glass substrate for a display, which is formed of a glass having a light weight and having high refinability with decreasing environmental burdens, the glass comprising, by mass %, 50 to 70% of SiO2, 5 to 18% of B2O3, 10 to 25% of Al2O3, 0 to 10% of MgO, 0 to 20% of CaO, 0 to 20% of SrO, 0 to 10% of BaO, 5 to 20% of RO (in which R is at least one member selected from the group consisting of Mg, Ca, Sr and Ba), and over 0.20% but not more than 2.0% of R?2O (in which R? is at least one member selected from the group consisting of Li, Na and K), and containing, by mass %, 0.05 to 1.5% of oxide of metal that changes in valence number in a molten glass, and substantially containing none of As2O3, Sb2O3 and PbO.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: June 3, 2014
    Assignee: Avanstrate Inc.
    Inventors: Junji Kurachi, Akihiro Koyama, Yoichi Hachitani
  • Publication number: 20140141285
    Abstract: It is an object of the present invention to provide a crystallized glass which has various properties required for employing the substrate for information recording medium of the next generation, and also has significantly low specific gravity; and a crystallized glass substrate for information recording medium. A crystallized glass containing, as a crystal phase, one or more selected from RAl2O4 and R2TiO4 (wherein R is one or more selected from Mg and Fe), the crystallized glass comprising the components of SiO2 of 50% to 70%, Al2O3 of 10% to 26%, TiO2 of 1 to 15%, MgO of 2.5% to 25%, FeO of 0% to 8%, and ZnO of 0% to less than 2%, expressed in terms of mass percentage on an oxide basis, wherein the value of (Al2O3+MgO)/SiO2 is 0.30 or more and 0.65 or less, and a specific gravity is less than 2.63.
    Type: Application
    Filed: November 15, 2013
    Publication date: May 22, 2014
    Applicant: OHARA INC.
    Inventors: Kiyoyuki Momono, Katsuhiko Yamaguchi, Toshitaka Yagi, Naoyuki Goto
  • Publication number: 20140106172
    Abstract: An ion exchangeable glass having a high degree of resistance to damage caused by abrasion, scratching, indentation, and the like. The glass comprises alumina, B2O3, and alkali metal oxides, and contains boron cations having three-fold coordination. The glass, when ion exchanged, has a Vickers crack initiation threshold of at least about 30 kilogram force.
    Type: Application
    Filed: May 28, 2013
    Publication date: April 17, 2014
    Applicant: Corning Incorporated
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 8697592
    Abstract: Disclosed are a glass substrate for an information recording medium, having excellent scratch resistance and a light weight and having high fracture toughness, the glass substrate having a fragility index value, measured in water, of 12 ?m?1/2 or less or having a fragility index value, measured in an atmosphere having a dew point of ?5° C. or lower, of 7 ?m?1/2 or less, or the glass substrate comprising, by mol %, 40 to 75% of SiO2, 2 to 45% of B2O3 and/or Al2O3 and 0 to 40% of R?2O in which R? is at least one member selected from the group consisting of Li, Na and K), wherein the total content of SiO2, B2O3, Al2O3 and R?2O is at least 90 mol %, and a magnetic information recording medium comprising a magnetic recording layer formed on the glass substrate.
    Type: Grant
    Filed: June 7, 2012
    Date of Patent: April 15, 2014
    Assignee: Hoya Corporation
    Inventors: Mikio Ikenishi, Atsuko Morita, Xuelu Zou
  • Publication number: 20140099501
    Abstract: There is provided a glass for chemical strengthening having a black color tone and excelling in characteristics preferred for the purposes of housing or decoration of an electronic device, that is, bubble quality, strength, and light transmittance characteristics. A glass for chemical strengthening contains, in mole percentage based on following oxides, 55% to 80% of SiO2, 3% to 16% of Al2O3, 0% to 12% of B2O3, 5% to 16% of Na2O, 0% to 4% of K2O, 0% to 15% of MgO, 0% to 3% of CaO, 0% to 18% of ?RO (where R represents Mg, Ca, Sr, Ba or Zn), 0% to 1% of ZrO2, and 0.1% to 7% of a coloring component having at least one metal oxide selected from the group consisting of oxides of Co, Mn, Fe, Ni, Cu, Cr, V and Bi.
    Type: Application
    Filed: September 17, 2013
    Publication date: April 10, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Hiroyuki YAMAMOTO, Kazuhide KUNO
  • Publication number: 20140057092
    Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit ?-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li2O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ? O + Na 2 ? O + K 2 ? O + MgO + ZnO ] [ Al 2 ? O 3 + B 2 ? O 3 ] between 0.7 to 1.5; b. a ? ? ratio ? : ? [ TiO 2 + SnO 2 ] [ SiO 2 + B 2 ? O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.
    Type: Application
    Filed: October 31, 2013
    Publication date: February 27, 2014
    Applicant: CORNING INCORPORATED
    Inventors: George Halsey Beall, Marie Jacqueline Monique Comte, George Owen Dale, Linda Ruth Pinckney, Charlene Marie Smith, Ronald Leroy Stewart, Steven Alvin Tietje
  • Publication number: 20140023865
    Abstract: According to one embodiment, a glass article may include SiO2, Al2O3, Li2O and Na2O. The glass article may have a softening point less than or equal to about 810° C. The glass article may also have a high temperature CTE less than or equal to about 27×10?6/° C. The glass article may also be ion exchangeable such that the glass has a compressive stress greater than or equal to about 600 MPa and a depth of layer greater than or equal to about 25 ?m after ion exchange in a salt bath comprising KNO3 at a temperature in a range from about 390° C. to about 450° C. for less than or equal to approximately 15 hours.
    Type: Application
    Filed: July 10, 2013
    Publication date: January 23, 2014
    Inventors: Marie Jacqueline Monique Comte, Melinda Ann Drake, Karen Leslie Geisinger, Sinue Gomez, Robert Michael Morena, Charlene Marie Smith, Randall Eugene Youngman
  • Patent number: 8623776
    Abstract: A fusion formable and ion exchangeable silicate glass having a seed concentration of less than about 1 seed/cm3.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: January 7, 2014
    Assignee: Corning Incorporated
    Inventors: Matthew John Dejneka, Sinue Gomez
  • Publication number: 20130345042
    Abstract: The present invention provides a lead-free glass for semiconductor encapsulation, which can encapsulate semiconductor devices at a low temperature, has an excellent acid durability and hardly precipitates crystals when forming a glass tube, and an encapsulator for semiconductor encapsulation made of the glass. The glass comprises, as a glass composition, from 45 to 58% of SiO2, from 0 to 6% of Al2O3, from 14.5 to 30% of B2O3, from 0 to 3% of MgO, from 0 to 3% of CaO, from 4.2 to 14.2% of ZnO, from 5 to 12% of Li2O, from 0 to 15% of Na2O, from 0 to 7% of K2O, from 15 to 30% of Li2O+Na2O+K2O, and from 0.1 to 8% of TiO2, in terms of % by mol, wherein a ratio of ZnO to Li2O is in the range from 0.84 to 2.
    Type: Application
    Filed: October 31, 2011
    Publication date: December 26, 2013
    Applicant: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Koichi Hashimoto, Kumiko Kondo
  • Patent number: 8609559
    Abstract: Disclosed are a glass composition and a dielectric composition enabling low temperature sintering, and a high capacitance multilayer ceramic capacitor using the same. In the glass composition used for sintering, the glass composition may be formed of a formula, aR2O-bCaO-cZnO-dBaO-eB2O3-fAl2O3-gSiO2, and the formula may satisfy a+b+c+d+e+f+g=100, 0?a?7, 1?b?3, 1?c?15, 10?d?20, 3?e?10, 0?f?3, and 55?g?72. Through this, when manufacturing the high capacity multilayer ceramic capacitor, the dielectric substance may enable the lower temperature sintering, thereby enhancing a capacitance and a reliability of the high capacitance multilayer ceramic capacitor.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: December 17, 2013
    Assignee: Samhwa Capacitor Co., Ltd.
    Inventors: Young Joo Oh, Jung Rag Yoon
  • Patent number: 8598055
    Abstract: Disclosed are alkali-free glasses having a liquidus viscosity of greater than or equal to about 90,000 poises, said glass comprising SiO2, Al2O3, B2O3, MgO, CaO, and SrO such that, in mole percent on an oxide basis: 64?SiO2?68.2; 11?Al2O3?13.5; 5?B2O3?9; 2?MgO?9; 3?CaO?9; and 1?SrO?5. The glasses can be used to make a display glass substrates, such as thin film transistor (TFT) display glass substrates for use in active matrix liquid crystal display devices (AMLCDs) and other flat panel display devices.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: December 3, 2013
    Assignee: Corning Incorporated
    Inventor: Adam James Ellison
  • Publication number: 20130306145
    Abstract: A glass substrate for a CIGS solar cell containing specific amounts of SiO2, Al2O3, B2O3, MgO, CaO, SrO, BaO, ZrO2, TiO2, Na2O and K2O, respectively. The glass substrate satisfies the specific requirements regarding MgO+CaO+SrO+BaO, Na2O+K2O, MgO/Al2O3, (2Na2O+K2O+SrO+BaO)/(Al2O3+ZrO2), Na2O/K2O, the relation of Al2O3 and MgO, and the relation of CaO and MgO, respectively. The glass substrate has a glass transition temperature of 640° C. or higher, an average coefficient of thermal expansion within a range of 50 to 350° C. of 70×10?7 to 90×10?7/° C., the temperature (T4) of 1,230° C. or lower, the temperature (T2) of 1,650° C. or lower, and a density of 2.7 g/cm3 or less. The glass substrate satisfies the relationship of T4?TL??30° C.
    Type: Application
    Filed: July 29, 2013
    Publication date: November 21, 2013
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yu HANAWA, Yutaka Kuroiwa, Tetsuya Nakashima, Reo Usui, Takeshi Tomizawa, Tomomi Sekine
  • Publication number: 20130296157
    Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs) and active matrix organic light emitting diode displays (AMOLEDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature. The glasses comprise in mol percent on an oxide basis: 70-74.5 SiO2, 10.5-13.5 AL2O3, 0-2.5 B2O3, 3-7 MgO, 3-7 CaO, 0-4 SrO, 1.5-6 BaO, 0-0.3 SnO2, 0-03 CeO2, 0-0.5 As2O3, 0-0.5 Sb2O3, 0.01-0.08 Fe2O3 and F+Cl+BrRO/Al2O31.7 and 0.2MgO/RO0.45, RO being the sum of MgO, BaO, SrO and CaO.
    Type: Application
    Filed: January 25, 2012
    Publication date: November 7, 2013
    Inventors: Adam J. Ellison, Timothy J. Kiczenski
  • Patent number: 8575050
    Abstract: Provided is a glass composition suitable for a glass substrate for a flat panel display such as a liquid crystal display. This glass composition has high thermal stability, and is substantially free of BaO but has a low devitrification temperature. It is suitable for the production of a glass substrate by a downdraw process. This glass composition contains, in terms of mass %; 54 to 62% of SiO2; 4 to 11% of B2O3; 15 to 20% of Al2O3; 2 to 5% of MgO; 0 to 7% of CaO; 0 to 13.5% of SrO; 0 to 1% of K2O; 0 to 1% of SnO2; and 0 to 0.2% of Fe2O3, and is substantially free of BaO. In this glass composition, the total content of alkaline earth metal oxides (MgO+CaO+SrO) is 10 to 18.5 mass %. The devitrification temperature of the glass composition is 1200° C. or lower.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: November 5, 2013
    Assignee: AvanStrate Inc.
    Inventors: Akihiro Koyama, Mikiko Hashimoto
  • Patent number: 8546282
    Abstract: A glass for a light guide fiber GA1 is used in a core of a fiber 10 of a light guide, and has a refractive index nd between 1.56 and 1.74. The glass for a light guide fiber GA1 has the following composition: (A) SiO2: 20 to 55 wt %, (B11) B2O3: 0 to 2.0 wt %, (B2) does not contain P2O5 and GeO2, (C1) (BaO+SrO+La2O3+Lu2O3+Ta2O5+Gd2O3+WO3): 39 to 46 wt %, (D1) ZnO: 4 to 16 wt %, (E) does not contain Al2O3, (F) does not contain ZrO2, (G) does not contain PbO and As2O3, (H1) (Na2O+K2O): 4 to 10 wt %, (I) Sb2O3: 0 to 0.050 wt %, and (J1) (Na2SO4+K2SO4): 0.32 to 0.78 wt %.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: October 1, 2013
    Assignees: Olympus Medical Systems Corp., Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
    Inventors: Hiroaki Kinoshita, Anne Jans Faber, Mathi Rongen, Atsushi Goto, Makoto Tanabe, Yuko Katahira
  • Publication number: 20130233386
    Abstract: A glass substrate for a Cu—In—Ga—Se solar cell. The glass substrate contains specific oxides with the specific amounts, respectively. The glass substrate has a glass transition temperature of from 650 to 750° C., an average coefficient of thermal expansion within a range of from 50 to 350° C. of from 75×10?7 to 95×10?7/° C., a relationship between a temperature (T4), at which a viscosity reaches 104 dPa·s, and a devitrification temperature (TL) of T4?TL??30° C., a density of 2.6 g/cm3 or less, and a brittleness index of less than 7,000 m?1/2.
    Type: Application
    Filed: April 22, 2013
    Publication date: September 12, 2013
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Yu HANAWA, Yutaka KUROIWA, Tetsuya NAKASHIMA, Reo USUI
  • Publication number: 20130230692
    Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0.1 to 60% of SiO2+Al2O3+B2O3, having a mass ratio (BaO+La2O3+Nb2O5+TiO2+ZrO2)/(SiO2+Al2O3+B2O3) of 0.1 to 50, amass ratio (MgO+CaO+SrO+BaO)/(BaO+La2O3+Nb2O5+TiO2+ZrO2) of 0 to 10, and a mass ratio (TiO2+ZrO2)/(BaO+La2O3+Nb2O5) of 0.001 to 40, and having a refractive index nd of 1.55 to 2.3.
    Type: Application
    Filed: December 7, 2011
    Publication date: September 5, 2013
    Inventors: Tomoki Yanase, Takashi Murata
  • Publication number: 20130225388
    Abstract: Provided is a Li2O—Al2O3—SiO2-based crystallizable glass characterized by comprising, as a glass composition in terms of mass %, 55 to 75% of SiO2, 19 to 24% of Al2O3, 3 to 4% of Li2O, 1.5 to 2.8% of TiO2, 3.8 to 4.8% of TiO2+ZrO2, and 0.1 to 0.5% of SnO2, and satisfying a relationship of 4?Li2O+0.741MgO+0.367ZnO?4.5.
    Type: Application
    Filed: November 4, 2011
    Publication date: August 29, 2013
    Applicant: Nippon Electric Glass Co., Ltd.
    Inventors: Shingo Nakane, Kosuke Kawamoto
  • Publication number: 20130224491
    Abstract: Glass compositions that may be used to produce chemically strengthened glass sheets by ion exchange. The glass compositions are chosen to promote simultaneously high compressive stress and deep depth of layer or, alternatively, to reduce the time needed to ion exchange the glass to produce a predetermined compressive stress and depth of layer.
    Type: Application
    Filed: February 29, 2012
    Publication date: August 29, 2013
    Inventors: Morten Mattrup Smedskjaer, Marcel Potuzak, John Christopher Mauro
  • Publication number: 20130217561
    Abstract: An alkali-free glass for flat panel display consists of, by weight, 54-68% SiO2, 10.8-17.1% Al2O3, 7.6-12.5% B2O3, 0.2-1.8% MgO, 4.2-8% CaO, 0.6-7.1% SrO, 0.1-5% BaO, 0.2-1% ZnO, 0.01-1.54% ZrO2 and 0.1-1.3% SnO+SnO2. The boroaluminosilicate glass of the present invention does not contain As and Sb which contribute to serious environmental pollution. The quality of the glass is improved by the specific process which reduces the content of the gas inclusions in the glass.
    Type: Application
    Filed: November 9, 2010
    Publication date: August 22, 2013
    Inventors: Guohong Yang, Zifa Duan, Dacheng Wang
  • Publication number: 20130207058
    Abstract: Titanium oxide containing borosilicate glasses, which have been produced without the use of arsenic and antimony compounds, are provided. An environmentally friendly refining method for providing titanium oxide containing borosilicate glass is also provided. The method includes using oxygen containing selenium compounds as refining agents to provide glasses with good transmittance values in the infrared range and show no disturbing discolorations. The glasses of the present disclosure are particularly suitable for the production of IR light conductors, cover glasses for photo sensors, and UV filters.
    Type: Application
    Filed: August 13, 2012
    Publication date: August 15, 2013
    Applicant: SCHOTT AG
    Inventors: Holger WEGENER, Rainer SCHWERTFEGER, Lenka GRYGAROVA, Reinhard KASSNER
  • Publication number: 20130196159
    Abstract: Disclosed are a glass composition and a dielectric composition enabling low temperature sintering, and a high capacitance multilayer ceramic capacitor using the same. In the glass composition used for sintering, the glass composition may be formed of a formula, aR2O-bCaO-cZnO-dBaO-eB2O3-fAl2O3-gSiO2, and the formula may satisfy a+b+c+d+e+f+g=100, 0?a?7, 1?b?3, 1?c?15, 10?d?20, 3?e?10, 0?f?3, and 55?g?72. Through this, when manufacturing the high capacity multilayer ceramic capacitor, the dielectric substance may enable the lower temperature sintering, thereby enhancing a capacitance and a reliability of the high capacitance multilayer ceramic capacitor.
    Type: Application
    Filed: March 13, 2013
    Publication date: August 1, 2013
    Applicant: SAMHWA CAPACITOR CO., LTD.
    Inventor: Samhwa Capacitor Co., Ltd.
  • Patent number: 8492297
    Abstract: A device including a glass substrate made of a soda lime silica glass composition of: SiO2 (50˜75 wt %); Na2O (1˜8 wt %); K2O (1˜12 wt %); CaO (1˜12 wt %); ZrO2 (0˜8 wt %); SrO (0˜15 wt %); BaO (0˜12 wt %); MgO (0˜10 wt %); Al2O3 (0˜12 wt %); B2O3 (0˜3 wt %), wherein the total amount of Na2O and K2O is in the range of 5˜15 wt %, the total amount of CaO, MgO, SrO and BaO is in the range of 10˜25 wt %.
    Type: Grant
    Filed: August 31, 2010
    Date of Patent: July 23, 2013
    Assignee: SAGE Electrochromics, Inc.
    Inventors: Jun-Young Lee, Sei-Woong Yoo, Doo-Sang Ko, Marc Maurer
  • Publication number: 20130154064
    Abstract: A glass composition for protecting a semiconductor junction contains at least SiO2, Al2O3, MO, and nickel oxide, and substantially contains none of Pb, P, As, Sb, Li, Na and K (M in MO indicates one of alkali earth metals).
    Type: Application
    Filed: August 29, 2011
    Publication date: June 20, 2013
    Applicant: SHINDENGEN ELECTRIC MANUFACTURING CO., LTD.
    Inventors: Atsushi Ogasawara, Kazuhiko Ito, Koji Ito
  • Patent number: 8455378
    Abstract: An alkali-free glass characterized by having a glass composition being substantially free of an alkali metal oxide, As2O3 and Sb2O3 and including, in terms of mol %, 55 to 75% of SiO2, 7 to 15% of Al2O3, 7 to 12% of B2O3, 0 to 3% of MgO, 7 to 12% of CaO, 0 to 5% of SrO, 0 to 2% of BaO, 0 to 5% of ZnO and 0.01 to 1% of SnO2 and has a liquidus viscosity of 105.2 dPa·s or higher and a temperature corresponding to a viscosity of 102.5 dPa·s of 1,550° C. or lower.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: June 4, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Tomoki Yanase, Shinkichi Miwa
  • Patent number: 8445394
    Abstract: Aluminoborosilicate glasses which may be useful in photovoltaic, photochromic, electrochromic, or Organic Light Emitting Diode (OLED) lighting applications are described.
    Type: Grant
    Filed: October 5, 2009
    Date of Patent: May 21, 2013
    Assignee: Corning Incorporated
    Inventors: Bruce Gardiner Aitken, Adam James Ellison, Timothy J Kiczenski
  • Patent number: 8426327
    Abstract: A technical object of the present invention is to satisfy various properties required in glass for liquid crystal displays and the like, in particular, fusibility, devitrification resistance, and like properties, and then to design a glass composition in which components harmful to the environment are reduced or substantially not contained, thereby obtaining a glass substrate that takes the environment into consideration. An alkali-free glass of the present invention contains the following glass composition in percent by weight based on oxide: 50 to 70% of SiO2, 10 to 20% of Al2O3, 8 to 12% of B2O3, 0 to 3% of MgO, 4 to 15% of CaO, 0 to 10% of SrO, 0 to 1% of BaO, and 0 to 5% of ZnO, and substantially free of alkali metal oxide and As2O3.
    Type: Grant
    Filed: May 22, 2007
    Date of Patent: April 23, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Tomoki Yanase, Shinkichi Miwa
  • Patent number: 8413466
    Abstract: A glass for a display substrate composed of 50 to 70% SiO2, 10 to 25% Al2O3, 8.4 to 20% B2O3, 0 to 10% MgO, 6 to 15% CaO, 0 to 10% BaO, 0 to 10% SrO, 0 to 10% ZnO, 0 to 5% TiO2, 0 to 5% P2O5, 0.01 to 0.2% alkali metal, and from 0.01% to less than 0.4% ZrO2, as expressed in % by mass. The glass can have a ?-OH value of 0.20/mm or more and an area of 0.1 m2 or more. The glass is produced by mixing raw materials to provide the SiO2, Al2O3, B2O3, MgO, CaO, BaO, SrO, ZnO, TiO2, P2O5 and alkali metal contents, electrically melting the raw materials in a melting furnace constructed of a high zirconia refractory; and refining, homogenizing and forming the glass melt.
    Type: Grant
    Filed: March 19, 2012
    Date of Patent: April 9, 2013
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventors: Tatsuya Takaya, Masahiro Tomamoto
  • Publication number: 20130075873
    Abstract: Provided is a glass composition for protecting a semiconductor junction which contains at least SiO2, Al2O3, ZnO, CaO and 3 mol % to 10 mol % of B2O3, and substantially contains none of Pb, P, As, Sb, Li, Na and K. It is preferable that a content of SiO2 falls within a range of 32 mol % to 48 mol %, a content of Al2O3 falls within a range of 9 mol % to 13 mol %, a content of ZnO falls within a range of 18 mol % to 28 mol %, a content of CaO falls within a range of 15 mol % to 23 mol %, and a content of B2O3 falls within a range of 3 mol % to 10 mol %.
    Type: Application
    Filed: May 26, 2011
    Publication date: March 28, 2013
    Applicant: SHINDENGEN ELECTRIC MANUFACTURING CO., LTD.
    Inventors: Atsushi Ogasawara, Kazuhiko Ito, Koji Ito
  • Patent number: 8399370
    Abstract: A glass composition which is reduced in the amount of residual bubbles and is produced using smaller amounts of an environmentally unfriendly component such as arsenic oxide and antimony oxide. This glass composition comprises, in terms of mass %; 40-70% SiO2; 5-20% B2O3; 10-25% Al2O3; 0-10% MgO; 0-20% CaO; 0-20% SrO; 0-10% BaO; 0.001-0.5% Li2O; 0.01-0.5% Na2O; 0.002-0.5% K2O; and 0-1.0%, excluding 0%, Cl.
    Type: Grant
    Filed: May 2, 2011
    Date of Patent: March 19, 2013
    Assignee: AvanStrate Inc.
    Inventors: Haruki Niida, Akihiro Koyama, Yukihito Nagashima, Satoshi Furusawa
  • Publication number: 20130065748
    Abstract: A flat panel display glass substrate includes a glass comprising, in mol %, 55-80% SiO2, 3-20% Al2O3, 3-15% B2O3, and 3-25% RO (the total amount of MgO, CaO, SrO, and BaO). The contents in mol % of SiO2, Al2O3, and B2O3 satisfy a relationship (SiO2+Al2O3)/(B2O3)=7.5-17. The strain point of the glass is 665° C. or more. The devitrification temperature of the glass is 1250° C. or less. The substrate has a heat shrinkage rate of 75 ppm or less. The rate of heat shrinkage is calculated from the amount of shrinkage of the substrate measured after a heat treatment which is performed at a rising and falling temperature rate of 10° C./min and at 550° C. for 2 hours by the rate of heat shrinkage (ppm)={the amount of shrinkage of the substrate after the heat treatment/the length of the substrate before the heat treatment}×106.
    Type: Application
    Filed: June 29, 2012
    Publication date: March 14, 2013
    Applicant: AvanStrate Inc.
    Inventors: Akihiro KOYAMA, Satoshi Ami, Manabu Ichikawa
  • Publication number: 20130059716
    Abstract: The invention relates to an alumino-silicate glass which has a thermal expansion coefficient in the range of 8 to 10×10?6/K in a temperature range of 20 to 300° C., a transformation temperature Tg in a range of 580° C. to 640° C., and a processing temperature VA in a range of 1065° C. to 1140° C. and which can therefore be used as an alternative for soda lime glasses. An object of the invention is also the use of the inventive glasses in applications where a high temperature stability of the glasses is advantageous, in particular as substrate glass, superstrate glass and/or cover glass in the field of semiconductor technology, preferably for Cd—Te or for CIS or CIGS photovoltaic applications and for other applications in solar technology.
    Type: Application
    Filed: February 29, 2012
    Publication date: March 7, 2013
    Inventors: Jörg H. Fechner, Franz Ott, Erhard Dick, Christof Kass
  • Publication number: 20130047672
    Abstract: Transparent, essentially colorless ?-quartz glass-ceramic materials, the composition of which is free of As2O3 and of Sb2O3, where said composition contains a specific combination of three nucleating agents: TiO2, ZrO2 and SnO2; TiO2 being present in low quantity.
    Type: Application
    Filed: October 25, 2012
    Publication date: February 28, 2013
    Inventors: Marie Jacqueline Monique Comte, Lothar Wondraczek