Calcium Oxide Containing Patents (Class 501/70)
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Patent number: 11919802Abstract: An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages 51.0-57.5% SiO2, 11.0-17.0% Al2O3, >4.5% and ?6.4% B2O3, 19.5-24.8% CaO, 0.1-1.9% MgO, 0.05-1.2% R2O=Na2O+K2O+Li2O, 0.05-0.8% Fe2O3, 0.01-1.0% TiO2, and 0.01-1.0% F2. A weight percentage ratio C1=SiO2/B2O3 is 8.1-12.7, a weight percentage ratio C2=B2O3/(R2O+MgO) is 1.7-6.3, and a total weight percentage of the above components is greater than or equal to 99%.Type: GrantFiled: October 30, 2019Date of Patent: March 5, 2024Assignee: JUSHI GROUP CO., LTD.Inventors: Guorong Cao, Wenzhong Xing, Lin Zhang, Zhonghua Yao, Hongya Zhou
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Patent number: 11707409Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, RITUXAN (rituximab), AVASTIN (Bevacizumab), LUCENTIS (Ranibizumab) or HERCEPTIN (trastuzumab).Type: GrantFiled: October 25, 2012Date of Patent: July 25, 2023Assignee: CORNING INCORPORATEDInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 11707410Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, HUMALOG (insulin lispro), HUMALOG MIX 75-25 (insulin lispro), HUMALOG MIX 50-50 (insulin lispro), HUMILIN 70-30 (insulin), HUMILIN N (insulin), HUMULIN R (insulin) or GEMZAR (gemcitabine).Type: GrantFiled: October 25, 2012Date of Patent: July 25, 2023Assignee: CORNING INCORPORATEDInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 11697611Abstract: Glass compositions suitable for fiber forming having low levels of Li2O and glass fibers having high-modulus are disclosed. The glass composition may include SiO2 from about 59 to about 63 weight percent, Al2O3 from about 13.7 to about 16 weight percent, CaO from about 14 to about 16.5 weight percent, MgO from about 6 to about 8.5 weight percent, Fe2O3 less than 1 weight percent, and TiO2 less than 1 weight percent. In some cases, the composition may be substantially free of Li2O. In some cases, the composition may include Li2O up to 0.5 weight percent. In some cases, RE2O3 may be present in the composition in an amount up to 1.5 weight percent. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.Type: GrantFiled: March 5, 2019Date of Patent: July 11, 2023Assignee: Electric Glass Fiber America, LLCInventor: Hong Li
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Patent number: 11643360Abstract: An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages: 54.2-60% SiO2, 11-17.5% Al2O3, 0.7-4.5% B2O3, 18-23.8% CaO, 1-5.5% MgO, less than or equal to 24.8% CaO+MgO, less than 1% Na2O+K2O+Li2O, 0.05-0.8% TiO2, 0.05-0.7% Fe2O3, and 0.01-1.2% F2. The weight percentage ratio C1=SiO2/(RO+R2O) is greater than or equal to 2.20, and the total weight percentage of the above components is greater than or equal to 98.5%.Type: GrantFiled: October 30, 2019Date of Patent: May 9, 2023Assignee: JUSHI GROUP CO., LTD.Inventors: Wenzhong Xing, Guorong Cao, Lin Zhang, Xiucheng Hong, Shuangbao Zuo, Zhonghua Yao
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Patent number: 11492286Abstract: The disclosure relates to highly temperable colored glass compositions. The colored glass compositions have high coefficients of thermal expansion and high Young's moduli that advantageously absorb in the ultraviolet and/or blue wavelength ranges. Methods of making such glasses are also provided.Type: GrantFiled: November 30, 2018Date of Patent: November 8, 2022Assignee: Corning IncorporatedInventors: Timothy James Kiczenski, Peter Joseph Lezzi, Michelle Diane Pierson-Stull, Jingshi Wu
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Patent number: 11292742Abstract: A glass composition includes a base glass portion comprising: 65-75 wt % SiO2; 5-15 wt % CaO; 0-5 wt % MgO; 0-5 wt % K2O; 10-14 wt % Na2O; and 1-5 wt % Al2O3; wherein the glass composition has a ratio of Na2O to Al2O3 is in the range of 9.5-12.5 wt %/wt %.Type: GrantFiled: June 26, 2019Date of Patent: April 5, 2022Assignee: Vitro Flat Glass LLCInventors: John Rich, Alan Miller, José Guadalupe Cid-Aguilar
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Patent number: 11247933Abstract: An alkali-free glass substrate which is a glass substrate includes, as represented by molar percentage based on oxides, 0.1% to 10% of ZnO. The alkali-free glass substrate has an average coefficient of thermal expansion ?50/100 at 50 to 100° C. of from 2.70 ppm/° C. to 3.20 ppm/° C., an average coefficient of thermal expansion ?200/300 at 200 to 300° C. of from 3.45 ppm/° C. to 3.95 ppm/° C., and a value ?200/300/?50/100 obtained by dividing the average coefficient of thermal expansion ?200/300 at 200 to 300° C. by the average coefficient of thermal expansion ?50/100 at 50 to 100° C. of from 1.20 to 1.30.Type: GrantFiled: February 1, 2019Date of Patent: February 15, 2022Assignee: AGC INC.Inventors: Shuhei Nomura, Kazutaka Ono
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Patent number: 11214508Abstract: A colored glass sheet of aluminosilicate composition chemically strengthened by ion exchange, includes the following oxides in the weight content ranges defined below: SiO2 between 59.20 and 68.00%; Al2O3 between 2.00 and 8.00%; MgO between 6.00 and 9.00% when the Al2O3 content is between 5.00 and 8.00% and when the SiO2/Al2O3 ratio is greater than or equal to 7.8 or between 8.00 and 10.00% when the Al2O3 content is between 2.00 and 5.00% and when the SiO2/Al2O3 ratio is greater than or equal to 24; Na2O between 9.00 and 16.00%; K2O between 5.00 and 11.00%; B2O3 between 0 and 3.00%; CaO between 0 and 1.00%; and the following coloring agents in the weight content ranges defined below: Fe2O3 total between 0.05 and 6.00%; CoO between 0 and 2.00%; NiO between 0 and 1.00%; Se between 0 and 0.10%, and the glass having a redox factor of between 0.10 and 0.65.Type: GrantFiled: December 16, 2016Date of Patent: January 4, 2022Assignee: SAINT-GOBAIN GLASS FRANCEInventors: Corinne Claireaux, Carole Fredy, Octavio Cintora-Gonzalez
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Patent number: 11180408Abstract: Embodiments relate to a glass composition which can allow for realizing beautiful bluish green colors therein even upon the use of a trace amount of a colorant such as Ti, Co, and Cr, securing high visible light transmittance suitable for window glass, and effectively reducing transmittance of solar heat radiation to help reduce a cooling load in buildings and vehicles.Type: GrantFiled: March 29, 2017Date of Patent: November 23, 2021Assignee: KCC Glass CorporationInventors: Yongyi Kim, Younmin Cho, Seongyeob Yoo
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Patent number: 10773991Abstract: In a soda lime glass, a content of total iron calculated as Fe2O3, expressed in mass % on an oxide basis, is 0.25 to 1%, a mass proportion of divalent iron calculated as Fe2O3 in the total iron calculated as Fe2O3 is 30 to 50%, a content of total sulfur calculated as SO3, expressed in mass % on an oxide basis, is 0.003 to 0.1%, and a content of Se is 3 mass ppm or more. In the soda lime glass, visible light transmittance Tv_D65 is 30 to 55% calculated as 6 mm thickness of a glass sheet, solar direct transmittance Te is 20 to 40% calculate as 6 mm thickness of a glass sheet, and excitation purity Pe is 8.0% or less calculated as 6 mm thickness of a glass sheet.Type: GrantFiled: April 20, 2018Date of Patent: September 15, 2020Assignee: AGC Inc.Inventors: Hiroyuki Hijiya, Kensuke Nagai, Eriko Maeda
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Patent number: 10737970Abstract: A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe2O3 in the range of greater than zero to 0.10 weight percent, e.g. selected from the group of total iron as Fe2O3 in the range of greater than zero to 0.02 weight percent and total iron as Fe2O3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent; redox ratio in the range of 0.2 to 0.6, and tin and/or tin compounds, e.g. SnO2 greater than 0.000 to 5.0 weight percent. In one embodiment of the invention, the glass has a tin side and an opposite air side, wherein the tin side of the glass is supported on a molten tin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the tin concentration in “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the tin side and terminating short of the tin side of the glass.Type: GrantFiled: February 18, 2016Date of Patent: August 11, 2020Assignee: Vitro Flat Glass LLCInventors: Mark O. Naylor, Lawrence E. Jansen, Larry J. Shelestak
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Patent number: 10727429Abstract: An electronic device includes a first electrode 31, a light emitting/light receiving layer 20 formed on the first electrode 31, and a second electrode 32 formed on the light emitting/light receiving layer 20. The light emitting/light receiving layer 20 and/or the second electrode 32 is covered by an insulating layer 40 including a metal oxide that contains, as a main component, zinc oxide, while containing, as accessory components, at least two materials selected from the group consisting of aluminum oxide, magnesium oxide, niobium oxide, titanium oxide, molybdenum oxide and hafnium oxide.Type: GrantFiled: June 20, 2016Date of Patent: July 28, 2020Assignee: Sony CorporationInventors: Toshiki Moriwaki, Mari Ichimura
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Patent number: 10597322Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.Type: GrantFiled: March 3, 2017Date of Patent: March 24, 2020Assignee: CORNING INCORPORATEDInventors: Paul Stephen Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
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Patent number: 10591652Abstract: The present disclosure provides a coated glass or glass-ceramic substrate, wherein at least two coating layers are applied to each side of the substrate. Each of the coating layers comprises one or more metal oxides, and optionally a dopant. The dopant can be a halogen or post transition metal. The coated substrate can have two coating layers on each side, three coating layers on each side, or two coating layers on one side and three coating layers on the other side. The properties of each of the coating layers are adjusted so that the coated substrate can reflect infrared light in targeted wavelength ranges. The properties that can be adjusted include the number of coating layers, the coating layer thickness, the coating layer composition, the index of refraction of each coating layer, and the location of each coating layer according to their index of refraction.Type: GrantFiled: November 18, 2016Date of Patent: March 17, 2020Assignee: SCHOTT GEMTRON CORP.Inventor: Adam O' Ryan
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Patent number: 10577275Abstract: The invention relates to a glass sheet having high transmission of infrared (IR) radiation. More specifically, the invention relates to a glass sheet having a composition which comprises, in a content expressed as percentages by total weight of glass: SiO2 55-85% AI2O3 0-30% B2O3 0-20% Na2O 0-25% CaO 0-20% MgO 0-15% K2O 0-20% BaO 0-20% total iron (expressed in the form of Fe2O3) 0.002-1%, Cr2O3 0.001-0.5% Co 0.0001-0.5% Se 0.0003-0.5%. By virtue of its high transmission of IR radiation, said glass sheet can advantageously be used in a device using a technology requiring very good transmission of IR radiation, whether through the main faces or starting from their edge (for example, a screen or panel or pad) The invention thus also relates to the use of such a glass sheet in a device using infrared radiation propagating essentially inside said sheet.Type: GrantFiled: June 10, 2016Date of Patent: March 3, 2020Assignee: AGC GLASS EUROPEInventors: Thomas Lambricht, Audrey Dogimont, Aline Degand
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Patent number: 10358378Abstract: It is an object of the present invention to provide near infrared cutoff filter glass having a high transmittance in a visible light range and a low transmittance in a near infrared light range and being excellent in the devitrification resistance, even though the concentration of Cu components in the glass is high for forming a thin plate. A near infrared cutoff filter glass, which comprises, as represented by cation percentage: P5+ 30 to 50%, Al3+ 5 to 20%, R+ 20 to 40% (wherein R+ is the total amount of Li++Na++K+), R?2+ 5 to 30% (wherein R?2+ is the total amount of Mg2++Ca2++Sr2++Ba2++Zn2+), Cu2+ 3 to 15% and comprises, as represented by anion percentage: O2? 30 to 90% and F? 10 to 70%, wherein (Li++Na++K+)/(P5++Al3+) is from 0.45 to 1.0, and (Sr2++Ba2++Cu2+)/(Al3++Mg2++Ca2+) is from 0.5 to 1.0.Type: GrantFiled: November 20, 2017Date of Patent: July 23, 2019Assignee: AGC Inc.Inventor: Makoto Shiratori
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Patent number: 10315948Abstract: A pharmaceutical packaging is provided including a glass, comprising at least the following components (given in mol % on oxide basis): SiO2: 5 9-84, Al2O3: 7-18.5, CaO: 1-25, SrO: 0-6.5, BaO: 0-5, ZrO2: 0-3, TiO2: 0-5, B2O3: 0-1, wherein the ratio (CaO+SrO+BaO)/Al2O3<2.8, wherein the ratio (CaO+SrO+BaO)/SiO2?0.39, wherein the hydrolytic resistance according to DIN ISO 720 is class HGA 1, and wherein the glass, apart from unavoidable contaminations, is free of alkali oxides and magnesium oxides.Type: GrantFiled: May 4, 2017Date of Patent: June 11, 2019Assignee: SCHOTT AGInventors: Michael Schwall, Christof Kass, Stephan Tratzky, Rainer Eichholz, Peter Nass
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Patent number: 10288792Abstract: The present disclosure relates to substrates having laser-induced scattering features located either on the surface of the substrate or within the substrate, along with methods of making such scattering substrates. The disclosed scattering substrates provide improved light extraction properties and may be useful in a variety of applications, such as lighting and electronic displays.Type: GrantFiled: January 29, 2015Date of Patent: May 14, 2019Assignee: Corning IncorporatedInventors: Kirk Richard Allen, Daniel Ralph Harvey, Vasudha Ravichandran
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Patent number: 10252937Abstract: A vitreous frit comprising the following by weight percentage ranges: SiO2 40-60 Al2O3 ?5-20 Na2O 10-35 Li2O 0-6 CaO ?0-10 SrO 0-5 BaO 0-5 CeO2 0-5 TiO2 ?0-9.Type: GrantFiled: June 21, 1988Date of Patent: April 9, 2019Assignee: Raytheon CompanyInventor: Alvin R. Stetson
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Patent number: 10243171Abstract: Provided is a laminate for a light emitting device. The laminate for a light emitting device includes a glass substrate having potassium or a glass substrate coated with a mineral layer containing potassium, and an internal light extraction layer formed from a glass frit on the glass substrate. The internal light extraction layer includes an interface void layer at an interface with the glass substrate or the mineral layer. The laminate has an interface void layer inducing the scattering of light for effectively extracting light, which is lost at the interface between the substrate and the internal light extraction layer, to the outside. The laminate is suitable for the fields of optical devices such as organic light emitting diodes (OLEDs), backlights, lighting industry, etc.Type: GrantFiled: July 16, 2014Date of Patent: March 26, 2019Assignee: SAINT-GOBAIN GLASS FRANCEInventors: Jin-Woo Han, Young-Seong Lee
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Patent number: 10065885Abstract: A glass sheet for pigment printing contains, as represented by mass percentage on the basis of oxides, from 60% to 75% of SiO2, from 2% to 12% of Al2O3, from 2% to 11% of MgO, from 0% to 10% of CaO, from 0% to 3% of SrO, from 0% to 3% of BaO, from 10% to 18% of Na2O, from 0% to 8% of K2O, and from 0% to 4% of ZrO2, or contains, from 60% to 75% of SiO2, from 1.5% to 12% of Al2O3, from 6% to 12% of MgO, from 0% to 4.5% of CaO, from 0% to 3% of SrO, from 0% to 3% of BaO, from 10% to 18% of Na2O, from 0% to 8% of K2O, and from 0% to 4% of ZrO2.Type: GrantFiled: December 28, 2016Date of Patent: September 4, 2018Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Junichiro Kase, Kazutomo Mori, Thomas Lambricht
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Patent number: 9988298Abstract: The present invention provides a high-transparency glass having a high fining action at a low temperature and capable of achieving redox lowering more than before. The present invention relates to a glass containing 1 to 500 ppm of a total iron oxide (t-Fe2O3) in terms of Fe2O3, having a redox ([divalent iron (Fe2+) in terms of Fe2O3]/[total (Fe2++Fe3+) of divalent iron (Fe2+) and trivalent iron (Fe3+) in terms of Fe2O3]) of 0% or more and 25% or less, containing, as expressed by mass percentage based on oxides, 50 to 81% of SiO2, 1 to 20% of Al2O3, 0 to 5% of B2O3, 5 to 20% of Li2O+Na2O+K2O, and 5 to 27% of MgO+CaO+SrO+BaO, and having a bubble disappearance-starting temperature (TD) of 1485° C. or lower.Type: GrantFiled: January 18, 2017Date of Patent: June 5, 2018Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Yusaku Matsuo, Yutaka Kuroiwa, Yusuke Arai, Hiroyuki Hijiya, Yuki Kondo
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Patent number: 9919954Abstract: An inorganic fiber containing silica and magnesia as the major fiber components and which further includes an intended iron oxide additive to improve the dimensional stability of the fiber. The inorganic fiber exhibits good thermal insulation performance at 1400° C. and greater, retains mechanical integrity after exposure to the use temperature, and which remains non-durable in physiological fluids. Also provided are thermal insulation product forms comprising a plurality of the inorganic fibers, methods of preparing the inorganic fiber and of thermally insulating articles using thermal insulation prepared from a plurality of the inorganic fibers.Type: GrantFiled: January 16, 2017Date of Patent: March 20, 2018Assignee: UNIFRAX I LLCInventors: Bruce K. Zoitos, Michael J. Andrejcak
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Patent number: 9862636Abstract: A heat-absorbing glass plate containing iron, tin and sulfur, where, as represented by mass % based on oxides, the amount of total iron as calculated as Fe2O3 is at least 0.3%, the amount of total tin as calculated as SnO2 is less than 0.4%, and the ratio (SnO2/SO3) of the amount of total tin to the amount of total sulfur as calculated as SO3 is from 0.2 to 100.Type: GrantFiled: October 11, 2016Date of Patent: January 9, 2018Assignee: Asahi Glass Company, LimitedInventors: Yuya Shimada, Yusuke Arai, Yuki Kondo
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Patent number: 9764980Abstract: A glass composition of the present invention includes, in mol %, 66 to 72% SiO2, 1 to 4% Al2O3, 8 to 15% MgO, 1 to 8% CaO, 12 to 16% Na2O, and 0 to 1% K2O. A total content of MgO and CaO is in a range of 12 to 17%, and a molar ratio of CaO to the total content of MgO and CaO is in a range of 0.1 to 0.4. The glass composition of the present invention is suitable for production by the float process, and is suitable for chemical strengthening.Type: GrantFiled: March 13, 2014Date of Patent: September 19, 2017Assignee: NIPPON SHEET GLASS COMPANY, LIMITEDInventors: Yutaka Senshu, Junji Kurachi
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Patent number: 9658437Abstract: A low infrared absorbing lithium glass includes FeO in the range of 0.0005-0.015 wt %, more preferably 0.001-0.010 wt %, and a redox ratio in the range of 0.005-0.15, more preferably in the range of 0.005-010. The glass can be chemically tempered and used to provide a ballistic viewing cover for night vision goggles or scope. A method is provided to change a glass making process from making a high infrared absorbing lithium glass having FeO in the range of 0.02 to 0.04 wt % and a redox ratio in the range of 0.2 to 0.4 to the low infrared absorbing lithium glass by adding additional oxidizers to the batch materials. A second method is provided to change a glass making process from making a low infrared absorbing lithium glass to the high infrared absorbing lithium glass by adding additional reducers to the batch material. In one embodiment of the invention the oxidizer is CeO2. An embodiment of the invention covers a glass made according to the method.Type: GrantFiled: February 15, 2013Date of Patent: May 23, 2017Assignee: PPG Industries Ohio, Inc.Inventors: George B. Goodwin, Mehran Arbab, Caroline S. Harris, Larry J. Shelestak
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Patent number: 9624125Abstract: The embodiments described herein relate to chemically and mechanically durable glass compositions and glass articles formed from the same. In another embodiment, a glass composition may include from about 70 mol. % to about 80 mol. % SiO2; from about 3 mol. % to about 13 mol. % alkaline earth oxide; X mol. % Al2O3; and Y mol. % alkali oxide. The alkali oxide may include Na2O in an amount greater than about 8 mol. %. A ratio of Y:X may be greater than 1 and the glass composition may be free of boron and compounds of boron. In some embodiments, the glass composition may also be free of phosphorous and compounds of phosphorous. Glass articles formed from the glass composition may have at least a class S3 acid resistance according to DIN 12116, at least a class A2 base resistance according to ISO 695, and a type HGA1 hydrolytic resistance according to ISO 720.Type: GrantFiled: November 24, 2014Date of Patent: April 18, 2017Assignee: CORNING INCORPORATEDInventors: Paul Stephen Danielson, Steven Edward DeMartino, Melinda Ann Drake, Robert Michael Morena, Santona Pal, Robert Anthony Schaut
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Patent number: 9474689Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, PROCRIT (epoetin alfa), REMICADE (Infliximab) or DORIBAX (doripenem).Type: GrantFiled: October 25, 2012Date of Patent: October 25, 2016Assignee: Corning IncorporatedInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 9474688Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient.Type: GrantFiled: October 25, 2012Date of Patent: October 25, 2016Assignee: Corning IncorporatedInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 9434633Abstract: Transparent glass sheets having increased mechanical strength include an inner layer surrounded by surface compressive layers wherein the difference of the coefficient of thermal expansion of the inner layer and the surface compressive layer is greater than 50×10?7° C.?1 and wherein the surface compressive layer has a compressive stress of at least about 300 MPa.Type: GrantFiled: June 28, 2011Date of Patent: September 6, 2016Assignee: CORNING INCORPORATEDInventors: Dana Craig Bookbinder, Keith Leonard House, Pushkar Tandon
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Patent number: 9249047Abstract: Disclosed is an ultraviolet and infrared absorptive glass characterized by that its coloring component contains, based on mass of the ultraviolet and infrared absorptive glass, 0.05-0.9 mass % of CeO2, 0.50-1.20 mass % of of total iron oxide in terms of Fe2O3, 0.08-0.30 mass % of FeO, 0.1-1.5 mass % of TiO2, 10-25 mass ppm of CoO, and 0.1-50 mass ppm of Cr2O3, that mass ratio (Fe2+/Fe3+) of divalent iron to trivalent iron is 0.20-0.45, and that dominant wavelength measured by using illuminant D65 of JIS Z 8701 is 510-560 nm. This glass has satisfactory optical characteristics, even though the content of CeO2 has been reduced.Type: GrantFiled: March 14, 2013Date of Patent: February 2, 2016Assignee: Central Glass Company, LimitedInventors: Naoki Mitamura, Tatsuya Tsuzuki
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Patent number: 9241869Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, LEVEMIR, NOVOLOG, NOVOLIN 70-30, NOVOLIN R, NOVOLIN N, NOVOLOG MIX 70-30 and NOVOLIN L.Type: GrantFiled: October 25, 2012Date of Patent: January 26, 2016Assignee: Corning IncorporatedInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 9198829Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, NEUPOGEN® (filgrastim), NEULASTA® (pegfilgrastim), (epoetin alfa) or ENBREL® (etanercept).Type: GrantFiled: October 25, 2012Date of Patent: December 1, 2015Assignee: Corning IncorporatedInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 9193621Abstract: To provide a heat-absorbing glass plate which satisfies both low solar transmittance and high visible light transmittance, presents a green color as transmitted light and contains a small number of coloring components. The heat-absorbing glass plate of the present invention has a solar transmittance of at most 42% calculated as 4 mm thickness, has a visible light transmittance (by illuminant A, 2° visual field) of at least 70% calculated as 4 mm thickness, and provides a transmitted light having a dominant wavelength of from 492 to 520 nm, and it is made of soda lime silica glass having substantially the following composition, as represented by mass % based on oxides. SiO2: 65 to 75%, Al2O3: more than 3% and at most 6%, MgO: at least 0% and less than 2%, CaO: 7 to 10%, total iron as calculated as Fe2O3: 0.45 to 0.65%, and TiO2: 0.2 to 0.Type: GrantFiled: July 25, 2013Date of Patent: November 24, 2015Assignee: Asahi Glass Company, LimitedInventors: Yuya Shimada, Tomoyuki Kobayashi, Yuki Kondo
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Patent number: 9186295Abstract: The present invention is based, at least in part, on the identification of a pharmaceutical container formed, at least in part, of a glass composition which exhibits a reduced propensity to delaminate, i.e., a reduced propensity to shed glass particulates. As a result, the presently claimed containers are particularly suited for storage of pharmaceutical compositions and, specifically, a pharmaceutical solution comprising a pharmaceutically active ingredient, for example, LANTUS (insulin glargine [rDNA]), LOVENOX (Enoxaparin), PENTACT-HIB (Hemophilus influenzae type b polysaccharide conjugated to tetanus protein, diphtheria, tetanus, pertussis and inactivated poliovirus vaccines) or FLUZONE or VAXIGRIP (influenza virus vaccine).Type: GrantFiled: October 25, 2012Date of Patent: November 17, 2015Assignee: Corning IncorporatedInventors: Wendell Porter Weeks, Robert Anthony Schaut, Steven Edward DeMartino, John Stephen Peanasky
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Patent number: 9187361Abstract: A method of forming high strength glass fibers in a refractory-lined glass meter, products made there from and batch compositions suited for use in the method are disclosed. The glass composition for use in the method of the present invention is up to about 64-75 weight percent SiO2, 16-24 weight percent Al2O3, 8-12 weight percent MgO and 0.25-3 weight percent R2O, where R2O equals the sum of Li2O and Na2O, has a fiberizing temperature less than about 2650° F., and a ?T of at least 80° F. By using oxide-based refractory-lined furnaces the cost of production of glass fibers is substantially reduced in comparison with the cost of fibers produced using a platinum-lined melting furnace. High strength composite articles including the high strength glass fibers are also disclosed.Type: GrantFiled: March 13, 2009Date of Patent: November 17, 2015Assignee: OCV Intellectual Capital, LLCInventors: Peter B. McGinnis, Douglas A. Hofmann
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Patent number: 9108879Abstract: The present invention relates to an alkali-free glass having a strain point of 735° C. or higher, an average thermal expansion coefficient at from 50 to 350° C. of from 30×10?7 to 40×10?7/° C., a temperature T2 at which a glass viscosity is 102 dPa·s of 1,710° C. or lower, a temperature T4 at which a glass viscosity is 104 dPa·s of 1,340° C. or lower, and a devitrification temperature of 1,330° C. or lower, the alkali-free glass including, in terms of mol % on the basis of oxides: SiO2 66 to 69, Al2O3 12 to 15, B2O3 0 to 1.5, MgO 6 to 9.5, CaO 7 to 9, SrO 0.5 to 3, BaO 0 to 1, and ZrO2 0 to 2, in which MgO+CaO+SrO+BaO is from 16 to 18.2, MgO/(MgO+CaO+SrO+BaO) is 0.35 or more, MgO/(MgO+CaO) is 0.40 or more and less than 0.52, and MgO/(MgO+SrO) is 0.45 or more.Type: GrantFiled: June 27, 2013Date of Patent: August 18, 2015Assignee: ASAHI GLASS COMPANY, LIMITEDInventors: Tomoyuki Tsujimura, Manabu Nishizawa, Akio Koike
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Patent number: 9061938Abstract: Provided is an alkali-free glass, comprising, as a glass composition in terms of mass %, 58 to 70% of SiO2, 15.5 to 20% of Al2O3, 0 to 1% of B2O3, 0 to 5% of MgO, 3.5 to 16% of CaO, 0.5 to 6.5% of SrO, and 5 to 15% of BaO, being substantially free of alkali metal oxides, and having a strain point of more than 725° C.Type: GrantFiled: October 26, 2011Date of Patent: June 23, 2015Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Takahiro Kawaguchi, Shinkichi Miwa
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Publication number: 20150140325Abstract: Embodiments of glass composition including at least about 65 mol % SiO2, Al2O3 in the range from about 7 mol % to about 11 mol %, Na2O in the range from about 13 mol % to about 16 mol %; and a non-zero amount of one or more alkali earth metal oxides selected from MgO, CaO and ZnO, wherein the sum of the alkali earth metal oxides is up to about 6 mol %, are disclosed. The glass compositions can be processed using fusion forming processes and float forming processes and are ion exchangeable. Glass articles including such glass compositions and methods of forming such glass articles are also disclosed. The glass articles of one or more embodiments exhibit a Vickers indentation crack initiation load of at least 8 kgf.Type: ApplicationFiled: November 14, 2014Publication date: May 21, 2015Inventors: Timothy Michael Gross, Xiaoju Guo, Charlene Marie Smith
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Patent number: 9029279Abstract: A glass composition including SiO2 in an amount from 74.5 to 80.0% by weight, Al2O3 in an amount from 5.0 to 9.5%>> by weight, MgO in an amount from 8.75 to 14.75% by weight, CaO in an amount from 0.0 to 3.0% by weight, Li2O in an amount from 2.0 to 3.25% by weight, Na2O in an amount from 0.0 to 2.0% by weight is provided. Glass fibers formed from the inventive composition may be used in applications that require high strength, high stiffness, and low weight. Such applications include woven fabrics for use in forming wind blades, armor plating, and aerospace structures.Type: GrantFiled: June 30, 2011Date of Patent: May 12, 2015Assignee: OCV Intellectual Capital, LLCInventors: Douglas Alan Hofmann, Peter Bernard McGinnis
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Patent number: 9028967Abstract: The present invention relates to a chemically strengthened glass for a display device, having a visible light transmittance Tva of 50% or more and less than 91% at a thickness of 1 mm using A light source, and an excitation purity Pe of less than 0.5% at a thickness of 1 mm.Type: GrantFiled: September 18, 2013Date of Patent: May 12, 2015Assignee: Asahi Glass Company, LimitedInventors: Akio Koike, Yuya Shimada, Isao Saito
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Publication number: 20150126354Abstract: To provide glass to be used for chemically tempered glass, of which the strength is less likely to be reduced even when indentations are formed thereon. Glass for chemical tempering, which comprises, as represented by mole percentage based on oxides, from 62 to 68% of SiO2, from 6 to 12% of Al2O3, from 7 to 13% of MgO, from 9 to 17% of Na2O, and from 0 to 7% of K2O, wherein the difference obtained by subtracting the content of Al2O3 from the total content of Na2O and K2O is less than 10%, and when ZrO2 is contained, its content is at most 0.8%. Chemically tempered glass obtained by chemically tempering such glass for chemical tempering. Such chemically tempered glass has a compressive stress layer formed on the glass surface, which has a thickness of at least 30 ?m and a surface compressive stress of at least 550 MPa.Type: ApplicationFiled: January 15, 2015Publication date: May 7, 2015Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Jun ENDO, Shusaku AKIBA, Kazutaka ONO, Tetsuya NAKASHIMA
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Patent number: 9023745Abstract: A photovoltaic cell, for example a thin-film photovoltaic cell, having a substrate glass made of aluminosilicate glass, has a glass composition which has SiO2 and Al2O3 as well as the alkali metal oxide Na2O and the alkaline earth oxides CaO, MgO, and BaO, and optionally further components. The glass composition includes 10 to 16 wt.-% Na2O, >0 to <5 wt.-% CaO, and >1 to 10 wt.-% BaO, and the ratio of CaO:MgO is in the range of 0.5 to 1.7. The aluminosilicate glass used is crystallization stable because of the selected quotient of CaO/MgO and has a transformation temperature >580° C. and a processing temperature <1200° C. Therefore, it represents a more thermally stable alternative to soda-lime glass. The aluminosilicate glass is used as a substrate glass, superstrate glass, and/or cover glass for a photovoltaic cells, for example for thin-film photovoltaic cells, in particular those based on semiconductor composite material, such as CdTe, CIS, or CIGS.Type: GrantFiled: July 27, 2012Date of Patent: May 5, 2015Assignee: Schott AGInventors: Jörg Hinrich Fechner, Christof Kass, Franz Ott
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Patent number: 9023474Abstract: A plurality of soda-lime glass batch materials are formed into granules that include a core and a shell surrounding the core. The core comprises a first portion of the plurality of glass batch materials, and the shell comprises a remaining portion of the plurality of glass batch materials. These core-shell granules can be melted in a glass furnace to produce molten soda-lime glass in less time and at a lower temperature than conventional soda-lime glass batch preparations.Type: GrantFiled: March 15, 2013Date of Patent: May 5, 2015Inventors: Witold W. Mastek, Desikan Sundararajan, Terence J. Clark, Melisa Y. Zambrano Becerra
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Patent number: 9016092Abstract: A glass for a magnetic recording medium substrate permitting the realization of a magnetic recording medium substrate affording good chemical durability and having an extremely flat surface, a magnetic recording medium substrate comprised of this glass, a magnetic recording medium equipped with this substrate, and methods of manufacturing the same. The glass is an oxide glass not including As or F.Type: GrantFiled: March 18, 2009Date of Patent: April 28, 2015Assignee: Hoya CorporationInventors: Yoichi Hachitani, Kinobu Osakabe
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Patent number: 9012342Abstract: The invention relates to a melt composition for the production of man-made vitreous fibers and man-made vitreous fibers comprising the following oxides, by weight of composition: SiO2 39-43 weight % Al2O3 20-23 weight % TiO2 up to 1.5 weight % Fe2O3 5-9 weight %, preferably 5-8 weight % CaO 8-18 weight % MgO 5-7 weight % Na2O up to 10 weight %, preferably 2-7 weight % K2O up to 10 weight %, preferably 3-7 weight % P2O5 up to 2% MnO up to 2% R2O up to 10 weight % wherein the proportion of Fe(2+) is greater than 80% based on total Fe and is preferably at least 90%, more preferably at least 95% and most preferably at least 97% based on total Fe.Type: GrantFiled: October 12, 2012Date of Patent: April 21, 2015Assignee: Rockwool International A/SInventors: Mette Solvang, Svend Grove-Rasmussen, Mathilde Rosendahl Foldschack
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Patent number: 9007878Abstract: An aspect of the present invention relates to glass for a magnetic recording medium substrate, which includes essential components in the form of SiO2, Li2O, Na2O, and one or more alkaline earth metal oxides selected from the group consisting of MgO, CaO, SrO, and BaO, wherein a molar ratio of a content of MgO to a combined content of MgO, CaO, SrO, and BaO (MgO/(MgO+CaO+SrO+BaO)) is equal to or greater than 0.80, and which has a Young's modulus of equal to or greater than 80 GPa, and a glass transition temperature of equal to or greater than 620° C.Type: GrantFiled: July 25, 2014Date of Patent: April 14, 2015Assignee: Hoya CorporationInventors: Naomi Matsumoto, Kazuaki Hashimoto
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Patent number: 8999870Abstract: A vitreous or glass-ceramic jointing material, which has a coefficient of thermal expansion ?(20-750) of ?7·10?6 K?1 and is free of BaO and SrO except for at the most impurities and is suitable for producing joint connections between chromium-containing alloys or chromium-containing steels.Type: GrantFiled: March 27, 2013Date of Patent: April 7, 2015Assignee: Schott AGInventors: Dieter Goedeke, Jens Suffner
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Patent number: 8998790Abstract: A method for sequestrating arsenic oxides, comprising forming an insoluble and stable glass incorporating a fully oxidized form of arsenic generated by oxidation of an initial lower oxide of arsenic and stabilization by calcium salt formation. The glass composition for sequestration of arsenic comprises from 50 to 75% silica; from 0.5 to 3% Al2O3; from 1 to 15% MnO; from 5 to 15% CaO; from 1 to 20% As2O5 and from 8 to 14% Na2O, less than four percent of iron oxides, magnesium oxide and other oxides.Type: GrantFiled: September 4, 2013Date of Patent: April 7, 2015Assignee: Dundee, Technologies Durables Inc.Inventors: Jean-Marc Lalancette, Bertrand Dubreuil, David Lemieux