And Boron Patents (Class 501/77)
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Patent number: 7737064Abstract: Optical glass having a refractive index (nd) of 1.75 or greater, and an Abbe number (?d) falling within the range of 15 to 40, which is suitable for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 10 to 70%, Bi2O3 in an amount of 5% or more and less than 25%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 520° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 550 nm, for a thickness of 10 mm.Type: GrantFiled: April 27, 2006Date of Patent: June 15, 2010Assignee: O'Hara, Inc.Inventor: Jie Fu
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Publication number: 20100136314Abstract: A dopant host containing, in terms of mole %, 20 to 50% SiO2, 30 to 60% (exclusive of 30%) Al2O3, 10 to 40% B2O3, and 2 to 10% RO, wherein R represents an alkaline earth metal, or including a laminate including a boron component volatilization layer containing, in terms of mole %, 30 to 60% SiO2, 10 to 30% Al2O3, 15 to 50% B2O3, 2 to 10% RO, wherein R represents an alkaline earth metal, and a heat resistant layer containing, in terms of mole %, 8 to 30% SiO2, 50 to 85% Al2O3, 5 to 20% B2O3, and 0.5 to 7% RO, wherein R represents an alkaline earth metal. A process for producing a boron dopant for a semiconductor includes the steps of slurrying a starting material powder containing a boron-containing crystalline glass powder, forming the slurry to prepare a green sheet, and sintering the green sheet.Type: ApplicationFiled: October 28, 2008Publication date: June 3, 2010Applicant: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Yoshio Umayahara, Ryota Suzuki, Yoshikatsu Nishikawa, Masaru Ikebe, Hiroki Mori, Yoshinori Hasegawa
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Patent number: 7699999Abstract: The invention is directed to a screen-printable getter composition comprising: (a) glass frit; dispersed in (b) organic medium. The invention is further directed to a screen-printable thick film getter composition comprising: (a) glass frit; and (b) desiccant material; dispersed in (c) organic medium. The present invention further relates to a getter composition utilizing low-softening temperature glasses comprising, based on weight %, 1-50% SiO2, 0-80% B2O3, 0-90% Bi2O3, 0-90% PbO, 0-90% P2O5, 0-60% Li2O, 0-30% Al2O3, 0-10% K2O, 0-10% Na2O, and 0-30% MO where M is selected from Ba, Sr, Ca, Zn, Cu, Mg and mixtures thereof. The glasses described herein may contain several other oxide constituents that can substitute glass network-forming elements or modify glass structure.Type: GrantFiled: September 15, 2008Date of Patent: April 20, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Yong Cho, Terri Cardellino, James Daniel Tremel
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Publication number: 20100093512Abstract: There is provided a glass ceramic material for plasma display, in which glass fine grains (A) having a softening point of 570-640° C. are in 40-70 wt %, and glass fine grains (B) having a softening point of 480-540° C. are in 30-60 wt %, the glass ceramic material for plasma display being characterized in that the glass fine grains (A) comprise 2-12 wt % of SiO2, 50-58 wt % of B2O3, 10-20 wt % of Al2O3, 0-6 wt % of ZnO, 0-2.8 wt % of Li2O, and 10-22 wt % of at least one selected from MgO, CaO, SrO and BaO and that refractive index of the glass fine grains (A) is 1.53-1.56.Type: ApplicationFiled: December 20, 2007Publication date: April 15, 2010Applicant: CENTRAL GLASS COMPANY, LIMITEDInventors: Kazuhiro Nishikawa, Koji Tominaga
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Patent number: 7696113Abstract: Alkali-free glasses are disclosed which can be used to produce substrates for flat panel display devices, e.g., active matrix liquid crystal displays (AMLCDs). The glasses contain iron and tin as fining agents, and preferably are substantially free of arsenic and antimony. In certain embodiments, the glasses are also substantially free of barium. Methods for producing alkali-free glass sheets using a downdraw process (e.g., a fission process) are also disclosed.Type: GrantFiled: December 1, 2008Date of Patent: April 13, 2010Assignee: Corning IncorporatedInventor: Adam James Gillmar Ellison
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Patent number: 7691288Abstract: The invention is directed to a process for making screen-printable getter composition comprising: (a) glass frit; and (b) pre-hydrated desiccant material; dispersed in (c) organic medium. The present invention further relates to a getter composition utilizing low-softening temperature glasses comprising, based on weight %, 1-50% SiO2, 0-80% B2O3, 0-90% Bi2O3, 0-90% PbO, 0-90% P2O5, 0-60% Li2O, 0-30% Al2O3, 0-10% K2O, 0-10% Na2O, and 0-30% MO where M is selected from Ba, Sr, Ca, Zn, Cu, Mg and mixtures thereof. The glasses described herein may contain several other oxide constituents that can substitute glass network-forming elements or modify glass structure. The desiccant material is pre-hydrated to reach its saturation level of moisture absorption. The process of pre-hydration can be done by exposing the desiccant in a normal temperature/humidity environment of for example, 25° C. and 50-60% RH. For 24 to 48 hours or up to the time when weight gain (due to moisture absorption) stops increasing.Type: GrantFiled: June 23, 2009Date of Patent: April 6, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Carl B. Wang, Christopher John Roach, Fong-Pei Chang
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Patent number: 7670973Abstract: Lead and arsenic free, and preferably gadolinium and further preferably also fluorine free, optical glasses for the application fields mapping, projection, telecommunication, optical communication engineering, mobile drive, laser technology and/or micro lens arrays have a refractive index of 1.91?nd?2.05, an Abbe number of 19??d?25 and have a low transformation temperature, namely of less than or equal to 470° C. and preferably of less than or equal to 450° C., as well as good producability and processability and crystallization stability.Type: GrantFiled: October 25, 2006Date of Patent: March 2, 2010Assignee: Schott AGInventors: Simone Monika Ritter, Ute Woelfel, Bianca Schreder, Stefanie Hansen
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Publication number: 20100041539Abstract: An optical glass is provided that includes a refractive index (nd) of no less than 1.75 and an Abbe number (vd) of no less than 10 as optical constants. A Bi2O3 content is no less than 10% by weight to no more than 80% by weight. The content of SiO2 is lower than the content of B2O3. The total content of SiO2+B2O3 is from no less than 1% by weight to no more than 60% by weight. The content of RO is from no less than 0.1% by weight to no more than 50% by weight. R represents one or more elements selected from the group consisting of Zn, Ba, Sr, Ca, and Mg. The optical glass has at least one of the properties of being substantially free from opacification and/or being substantially devitrified within the glass body under the conditions of a reheating testing.Type: ApplicationFiled: October 22, 2009Publication date: February 18, 2010Applicant: OHARA, INC.Inventors: Atsushi Nagaoka, Jie Fu, Michiko Ogino
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Patent number: 7648931Abstract: The present invention relates to a sealing glass composition that excludes Pb, i.e., an environmentally harmful material, and a flat panel display apparatus using the same. A sealing glass composition of the present invention comprises Sb2O3 of 20 mol % to 50 mol %, B2O3 of 30 mol % to 70 mol %, SiO2 of 5 mol % to 15 mol % and Al2O3 of 0 mol % to 15 mol %. The flat display apparatus of the present invention has a front panel and a rear panel, which are combined together with a sealing glass composition with a predetermined distance therebetween.Type: GrantFiled: November 1, 2005Date of Patent: January 19, 2010Assignee: LG Electronics Inc.Inventors: Jong Heo, Sungho Woo, Hyunwook Kim, Byungjun Mun
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Patent number: 7638450Abstract: The lead-free, fluorine-free and arsenic-free optical glass, which is useful in mapping, projection, telecommunication, optical communication engineering, and mobile drive and laser technology, has a refractive index of 1.75?nd?1.83, an Abbe number of 34?Vd?44, and Tg?560° C. The glass is free of WO3 and TeO2and has a composition in percent by weight based on oxide content of: SiO2, 0.5-8; B2O3, 10-25; ZnO, 10-22; La2O3, 23-34; Ta2O5, >15-25; Nb2O5, 0.5-15; Al2O3, 0-2; and can include optional ingredients, e.g. alkali and/or alkaline-earth oxides. In addition, a sum of B2O3 and ZnO is 33 to 41% by weight and preferably a sum of La2O3+Ta2O5+Nb2O5+Y2O3+ZrO2 is greater than 50% by weight.Type: GrantFiled: April 27, 2006Date of Patent: December 29, 2009Assignee: Schott AGInventors: Simone Monika Ritter, Ute Woelfel, Stefanie Hansen
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Patent number: 7638449Abstract: This invention provides an optical glass including, by mass %: 30 to 40% of B2O3; 2.5 to 6% of Li2O; 10 to 17% of ZnO; 12 to 22% of La2O3; 15 to 25% of Gd2O3; 0 to 5% of SiO2; 0 to 5% of Bi2O3; 0 to 15% of Al2O3; 0 to 3% of ZrO2; 0 to 5% of WO3; 0 to 5% of Ta2O5; 0 to 3% of TiO2; 0 to 5% of Y2O3; and 0 to 5% of MgO+CaO+SrO+BaO.Type: GrantFiled: August 15, 2008Date of Patent: December 29, 2009Assignee: Asahi Glass Company, LimitedInventors: Kenji Imakita, Jun Sasai, Naoki Sugimoto
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Publication number: 20090314033Abstract: A glass material for mold pressing, comprising a core portion comprised of an optical glass with a degree of abrasion FA of 200 or higher and a covering portion comprised of a second glass covering at least a portion of the surface of said core portion. A method for manufacturing an optical glass element, wherein a glass material that has been preformed to a prescribed shape is heat softened and press molded with a pressing mold and the outer perimeter portion of the molded product obtained is removed by mechanical processing. The above-mentioned glass material for mold pressing is used as the glass material. To provide a means whereby an optical element does not bear scratches on optically functional surfaces through contact during handling after the press molding of press molded glass products despite being comprised of a glass material with a high degree of abrasion, and a means whereby even when scratched, the function of the optical element finally obtained is unaffected.Type: ApplicationFiled: March 28, 2007Publication date: December 24, 2009Inventors: Xuelu Zou, Yasuhiro Fujiwara
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Publication number: 20090318278Abstract: A powder composition for forming a highly expansible crystallized glass substantially free of alkali metals is disclosed, which composition can provide, through its firing at a temperature of not more than 900° C., a seal between metal and ceramic. The powder composition is a powder composition for the formation of a sealing crystallized glass which is substantially free of alkali metals and consists of the powder of a glass containing, calculated as oxides, SiO2: 10-30% by mass, B2O3: 20-30% by mass, CaO: 10-40% by mass, MgO: 15-40% by mass, BaO+SrO+ZnO: 0-10% by mass, La2O3: 0-5% by mass, Al2O3: 0-5% by mass, and RO2: 0-3% by mass (wherein R represents Zr, Ti, or Sn), wherein the crystallized glass that is formed by firing the powder composition at 900±50° C. has a coefficient of thermal expansion of 90-120×10?7/° C. at 50-550 ° C.Type: ApplicationFiled: June 19, 2008Publication date: December 24, 2009Applicant: NIHON YAMAMURA GLASS CO., LTD.Inventors: Yoshitaka Mayumi, Hideyuki Kuribayashi
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Patent number: 7615507Abstract: An optical glass having a remarkably high refractive index and excellent stability can be give without being based on PbO, and the optical glass contains, as essential components, at least one oxide selected from La2O3, Gd2O3, Y2O3, Yb2O3, TiO2, Nb2O5 or WO3, at least one oxide selected from MgO, CaO, SrO or BaO and B2O3 and optionally containing SiO2, wherein on the basis of mass, the total content of B2O3 and SiO2 is from 1 to 25%, the ratio of (B2O3+SiO2)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.05 to 0.3 and the ratio of (MgO+CaO+SrO+BaO)/(La2O3+Gd2O3+Y2O3+Yb2O3+TiO2+Nb2O5+WO3) is from 0.1 to 0.4, the optical glass having a refractive index (nd) of 2.000 or more and an Abbe's number (vd) of 27 or less.Type: GrantFiled: July 10, 2006Date of Patent: November 10, 2009Assignee: Hoya CorporationInventor: Michio Endo
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Publication number: 20090275460Abstract: An optical glass having optical constants of a refractive index (nd) within a range from 1.50 to 1.65 and an Abbe number (? d) within a range from 50 to 65 and a glass transition temperature (Tg) of 400° C. or below wherein the shortest wavelength (? 80) at which transmittance is 80% is 370 nm or below.Type: ApplicationFiled: November 22, 2006Publication date: November 5, 2009Applicant: OHARA INC.Inventor: Masaaki Miyata
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Patent number: 7605101Abstract: A laminate includes a first green sheet and a second green sheet. The first green sheet includes a first glass including Al and M which is at least one of Sr and Ba. A relationship between Al content and M content is so defined that a position represented by percent by mass of Al in terms of Al2O3 and percent by mass of M in terms of MO on a coordinate system are on or in a range defined by straight lines connecting point A (1, 21), point B (1, 35), point C (9, 45), point D (20, 45), point E (20, 35), and point F (9, 21) on the coordinate system. The second green sheet includes a second glass including Si and B. The first green sheet is integrally laminated with the second green sheet.Type: GrantFiled: March 27, 2007Date of Patent: October 20, 2009Assignee: KYOCERA CorporationInventors: Shinya Kawai, Tatsuji Furuse, Mieko Yashima, Kouji Yamamoto
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Patent number: 7598192Abstract: The invention relates to optical glasses intended for the application fields of imaging, sensors, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, and for telecommunication, optical communication engineering and optics/lighting in the automotive sector, having a refractive index of 1.60?nd?1.80 and/or an Abbe number of 30??d?40 with a pronounced short flint character, good chemical stability, excellent crystallization stability, good solarization stability and the following composition (in wt. % based on oxide): SiO2 19-45 B2O3 ??3-7.5 Nb2O5 25-31 K2O 2-8 TiO2 0.1-2?? ZrO2 ?6-10 Ta2O5 0.5-8.Type: GrantFiled: December 8, 2006Date of Patent: October 6, 2009Assignee: Schott AGInventors: Silke Wolff, Goran Sabljic, Ute Woelfel
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Publication number: 20090203513Abstract: There is provided a glass member for optical parts that represents a greater absolute value |?n| of refractive index difference ?n of visual light between base glass and heterogeneous phase region. In the glass member for optical parts, the heterogeneous phase region distinguishable by a different refractive index is formed at an intended location inside a glass by focused irradiation of a pulsed laser. When a multicomponent optical glass of SiO2, Rn2+RO, and TiO2 is used, |?n| of no less than 0.005 can be attained under a lower irradiation intensity. It is suitable for optical parts such as optical low-pass filters, diffractive optical parts, optical diffusion parts, optical filters, lenses and microlens arrays.Type: ApplicationFiled: January 22, 2009Publication date: August 13, 2009Inventor: Tomohiro Hashimoto
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Publication number: 20090197755Abstract: An optical glass having optical constants of a refractive index (nd) of 1.78 or over, an Abbe number (v d) of 30 or below, and a partial dispersion ratio (? g, F) of 0.620 or below comprises SiO2 and Nb2O5 as essential components, wherein an amount of Nb2O5 in mass % is more than 40%. The optical glass further comprising, in mass % on oxide basis, less than 2% of K2O and one or more oxides selected from the group consisting of B2O3, TiO2, ZrO2, WO3, ZnO, SrO, Li2O and Na2O wherein a total amount of SiO2, B2O3, TiO2, ZrO2, Nb2O5, WO3, ZnO, SrO, Li2O and Na2O is more than 90% and TiO2/(ZrO2+Nb2O5) is less than 0.32.Type: ApplicationFiled: January 9, 2009Publication date: August 6, 2009Applicant: OHARA INC.Inventor: Susumu UEHARA
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Patent number: 7563293Abstract: Al2O3-rare earth oxide-ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.Type: GrantFiled: August 2, 2002Date of Patent: July 21, 2009Assignee: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Patent number: 7563294Abstract: Abrasive particles comprising ceramic (including glasses, crystalline ceramics, and glass-ceramics) comprising (on a theoretical oxide basis) Al2O3 and at least one other metal oxide (e.g., REO and; REO and at least one of ZrO2 or HfO2) and methods of making the same. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.Type: GrantFiled: August 2, 2002Date of Patent: July 21, 2009Assignee: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Publication number: 20090160334Abstract: A glass composition of the present invention is an oxide glass, in which the percentages of elements except for oxygen (O) contained therein are as follows, in terms of atom %: the amount of boron (B) exceeds 72% but does not exceed 86%, the total amount of lithium (Li), sodium (Na), and potassium (K) is 8% to 20%, the total amount of magnesium (Mg), calcium (Ca), strontium (Sr), and barium (Ba) is 1% to 8%, the amount of silicon (Si) is from 0% to less than 15%, and the amount of zinc (Zn) is from 0% to less than 2%. This glass composition further may contain molybdenum (Mo) and/or tungsten (W) in the range of more than 0% but not more than 3%.Type: ApplicationFiled: November 2, 2006Publication date: June 25, 2009Applicant: MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.Inventors: Osamu Inoue, Shinya Hasegawa, Yasuhiko Nakada, Tsutomu Koshizuka
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Publication number: 20090158776Abstract: Disclosed herein is an article having: coalesced first and second glasses, wherein: the first glass has at least two different metal oxides, wherein the first glass has a Tg1 and Tx1, and wherein the difference between the Tg1 and the Tx1 is at least 5K, the first glass having less than 20% by weight SiO2, less than 20% by weight B2O3, and less than 40% by weight P2O5; and the second glass has at least two different metal oxides, wherein the second glass has a Tg2 and Tx2, and wherein the difference between the Tg2 and the Tx2 is at least 5K, the second glass having less than 20% by weight SiO2, less than 20% by weight B2O3, and less than 40% by weight P2O5.Type: ApplicationFiled: March 4, 2009Publication date: June 25, 2009Inventor: Anatoly Z. Rosenflanz
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Publication number: 20090163343Abstract: The present invention provides a blue-violet light blocking glass containing copper (I) halide fine particles that satisfactorily transmits light having a wavelength of 450 nm to 600 nm and sharply blocks light having a wavelength shorter than 450 nm. Specifically, the present invention provides a blue-violet light blocking glass containing a copper (I) halide and silver; for example, 20 to 85% by weight of SiO2; 2 to 75% by weight of B2O3; not more than 10% by weight of Al2O3; 2 to 30% by weight of at least one member selected from the group consisting of Li2O, Na2O, K2O, Rb2O and Cs2O; 1 to 15% by weight of at least one member selected from the group consisting of MgO, CaO, SrO, BaO and ZnO; not more than 10% by weight of at least one member selected from the group consisting of PbO, Nb2O5, ZrO2, La2O3, Y2O3, Ta2O3 and Gd2O3; not more than 5% by weight of at least one member selected from the group consisting of Sb2O3 and As2O3; not more than 5% by weight of SnO2; 0.Type: ApplicationFiled: November 15, 2006Publication date: June 25, 2009Applicants: ISUZU GLASS CO., LTD., NATIONAL INSTITUTE ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGYInventors: Naoto Yamashita, Kazuhisa Kimura, Tatsuya Suetsugu, Toshihiko Einishi, Kohei Kadono
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Patent number: 7550645Abstract: The present invention provides processes to immobilize radioactive and/or hazardous waste in a borosilicate glass, the waste containing one or more of radionuclides, hazardous elements, hazardous compounds, and/or other compounds. The invention also provides borosilicate glass compositions for use in immobilizing radioactive and/or hazardous waste.Type: GrantFiled: January 18, 2006Date of Patent: June 23, 2009Assignee: Geomatrix Solutions, Inc.Inventors: Anatoly Chekhmir, Arthur Gribetz
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Patent number: 7541302Abstract: Optical glass which is suitable for press molding does not substantially contain a compound of lead or arsenic, and has intermediate refractive index, low dispersion properties, low Tg and small density. Concretely, the optical glass includes the glass components of SiO2: 20 to 45%, B2O3: 15 to 40%, Al2O3: 4 to 15%, MgO: 0 to 10% (including 0), CaO: 13 to 25%, MgO+CaO: 13 to 25%, Li2O: 12.5 to 25%, Na2O: 0 to 10% (including 0), K2O: 0 to 10% (including 0), Li2O+Na2O+K2O: 12.5 to 25%, SrO: 0 to 10% (including 0), BaO: 0 to 5% (including 0), and Sb2O3: 0 to 1% (including 0).Type: GrantFiled: April 13, 2005Date of Patent: June 2, 2009Assignee: Konica Minolta Opto, Inc.Inventor: Manabu Izuki
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Publication number: 20090135542Abstract: Provided are a glass composition, a dielectric composition and a multi-layer ceramic capacitor embedded low temperature co-fired ceramic substrate using the same. The multi-layer ceramic capacitor embedded low temperature co-fired ceramic substrate is sinterable at a low temperature while showing a high dielectric constant. The glass composition includes a composition component expressed by a composition formula of aBi2O3-bB2O3-cSiO2-dBaO-eTiO2, where a+b+c+d+e=100, and a, b, c, d, and e are 40?a?89, 10?b?50, 1?c?20, O?d?10, and O?e?10, respectively.Type: ApplicationFiled: November 14, 2008Publication date: May 28, 2009Inventors: Ho Sung Choo, Jong Myeon Lee, Eun Tae Park, Myung Whun Chang, Soo Hyun Lyoo, Beom Joon Cho
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Publication number: 20090131239Abstract: A glass composition suitable for producing a graded-refractive-index rod lens having an angular aperture of 16-20° without containing lead or thallium and a graded-refractive-index rod lens produced from the composition are provided. The composition is a base glass composition for graded-refractive-index rod lenses, characterized by comprising, in terms of % by mole, 20?SiO2?52, 1?B2O3?30, 12?Li2O?18, 8?Na2O?15, 0?MgO?15, 0?SrO?10, 0?BaO?10, 0?ZnO?15, 0?TiO2?15, 0?Nb2O5?5, 0?Ta2O5?5, and 3<Bi2O3?13, provided that 45?SiO2+B2O3?65, 9?MgO+ZnO+TiO2?25, and 0?Nb2O5+Ta2O5?5, and by containing substantially no lead and substantially no thallium.Type: ApplicationFiled: March 2, 2007Publication date: May 21, 2009Inventors: Tsuyoshi Kotake, Koichi Sakaguchi, Teruhide Inoue
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Patent number: 7524783Abstract: Titanium is added in the form of atoms, a colloid, or ions to a glass to be subjected to laser processing in which the ablation or vaporization caused by the energy of an absorbed laser light is utilized. Since titanium can be incorporated into the glass through melting, the threshold value for processing can be easily regulated by changing the amount titanium to be added and a material having evenness in processability can be obtained.Type: GrantFiled: October 3, 2002Date of Patent: April 28, 2009Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hirotaka Koyo, Tadashi Koyama, Keiji Tsunetomo
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Publication number: 20090105061Abstract: The present invention provides a glass composition that has good formability and tends not to cause electric-field breakdown when formed into a spacer for an electron beam-excited display. The present invention relates to a glass composition that contains the following components, in terms of mass %: 20?SiO2<40, 6<B2O3?30, 0?Al2O3?20, 45?(SiO2+B2O3+Al2O3)?74, 0?MgO?15, 5?CaO?40, 0?SrO?30, 0?BaO?25, 0<(SrO+BaO)?50, 20?(MgO+CaO+SrO+BaO)?60, 0?ZnO?10, 0?ZrO2<10, 0?La2O3?20, 0?Y2O3?10, 0?TiO2?3, 1?Fe2O3?12, 0?Nb2O5?10, 0?Ta2O5?10, and 1?TiO2+Fe2O3+Nb2O5+Ta2O5?12 and that is substantially free of alkali metal oxide.Type: ApplicationFiled: April 27, 2007Publication date: April 23, 2009Applicant: Nippon Sheet Glass Company, LimitedInventors: Kosuke Fujiwara, Akihiro Koyama, Hiroshi Kambayashi
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Patent number: 7521387Abstract: A sealant composition for use in sealing solid oxide fuel cells is provided which comprises a glass component which comprises a mixture of alkali-free inorganic oxides, and an optional filler component dispersed in the glass component, said filler component being up to 40% by weight of the composition. The glass component can include, on a mole basis, 20 to 50% BaO, 1 to 10% Y2O3, 5 to 20% B2O3, 10 to 30% SiO2, 3 to 35% MgO, 2 to 20% CaO, 1 to 10% ZnO, and 0 to 5% ZrO2, and exemplary filler components include zirconia, alumina, barium titanate, strontium titanate, and combinations thereof.Type: GrantFiled: September 21, 2004Date of Patent: April 21, 2009Assignee: General Electric CompanyInventors: Liang A. Xue, Jean Yamanis, James Piascik, Estela T. Ong
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Patent number: 7514093Abstract: A vitreous antimicrobial agent that can exhibit excellent antimicrobial properties when added to various types of resins, that has excellent discoloration resistance and hot water resistance, and that can easily be produced at a commercial scale. The vitreous antimicrobial agent includes, relative to 100 mass % of total glass components, 0.1 to 2 mass % of Ag2O, 40.5 to 49 mass % of ZnO, 6 to 9.5 mass % of SiO2, 30.5 to 39.5 mass % of B2O3, 2 to 10 mass % of an alkaline earth metal oxide, and 6 to 7.5 mass % of Na2O; the vitreous antimicrobial agent comprising, in addition to these, 0.01 to 5 mass % of CeO2 as necessary. An antimicrobial resin composition and an antimicrobial product including the vitreous antimicrobial agent.Type: GrantFiled: January 26, 2004Date of Patent: April 7, 2009Assignee: Toagosei Co., Ltd.Inventor: Koji Sugiura
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Publication number: 20090088310Abstract: There is provided an optical glass with a high refractive index and a low dispersion having a refractive index (nd) of not less than 1.75 and an Abbe's number (?d) of not less than 35 where the image formation characteristic is hardly affected by changes in temperature of the using environment. SiO2, B2O3 and La2O3 are contained as essential components and the ratio of the constituting components are adjusted whereby an optical glass in which a product of ? and ? where ? is an average linear expansion coefficient at ?30 to +70° C. and ? is an optical elasticity constant at the wavelength of 546.1 nm is not more than 130×10?12° C.?1×nm×cm?1×Pa?1 is able to be achieved.Type: ApplicationFiled: April 10, 2008Publication date: April 2, 2009Applicant: OHARA INC.Inventors: Junko SUZUKI, Michiko OGINO, Msahiro ONOZAWA
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Patent number: 7510989Abstract: The invention is directed to a silver-containing polarizing boroaluminosilicate glass composition that has been doped with a noble metal selected from the group consisting of Pt, Pd, Os, Ir, Rh and Ru, including mixtures thereof, to nucleate and precipitate silver ions to silver metal without the need for a reducing atmosphere step. The invention is further directed to a method for making the glass composition of the invention. Using the composition and method of the invention, one can prepare a glass having a selected null transmission range.Type: GrantFiled: October 20, 2006Date of Patent: March 31, 2009Assignee: Corning IncorporatedInventors: Nicholas Francis Borrelli, George Bigelow Hares, Sasha Marjanovic, David John McEnroe, Katherine Rose Rossington, Joseph Francis Schroeder, III
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Patent number: 7507268Abstract: Al2O3—Y2O3—ZrO2/HfO2 ceramics (including glasses, crystalline ceramics, and glass-ceramics) and methods of making the same. Ceramics according to the present invention can be made, formed as, or converted into glass beads, articles (e.g., plates), fibers, particles, and thin coatings. The particles and fibers are useful, for example, as thermal insulation, filler, or reinforcing material in composites (e.g., ceramic, metal, or polymeric matrix composites). The thin coatings can be useful, for example, as protective coatings in applications involving wear, as well as for thermal management. Certain ceramic particles according to the present invention can be are particularly useful as abrasive particles.Type: GrantFiled: August 2, 2002Date of Patent: March 24, 2009Assignee: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Publication number: 20090075804Abstract: A method of making a glass-ceramic from at least two different metal oxides is disclosed. The method includes providing the two different metal oxides as a glass, heating the glass above the glass transition temperature of the glass to form a coalesced shape; and heating the coalesced shape to a temperature above the crystallization onset temperature of the glass, thereby forming a glass-ceramic comprising at least 1% by volume crystallites, wherein the crystallites have an average size of less than 1 micrometer. The difference between the glass transition temperature and the crystallization onset temperature is at least 25K.Type: ApplicationFiled: November 26, 2008Publication date: March 19, 2009Inventor: Anatoly Z. Rosenflanz
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Publication number: 20090075803Abstract: A method of making an article from an aluminum oxide glass is disclosed. The aluminum oxide glass includes zirconium oxide and either calcium oxide or strontium oxide. The aluminum oxide glass has a glass transition temperature and a crystallization temperature, and these temperatures differ by at least 25K. The method includes: providing a glass in a form comprising particles, beads, microspheres, or fibers; heating the glass above the Tg such that the particles, beads, microspheres, or fibers coalesce to form a coalesced shape; and cooling the coalesced shape to form the article.Type: ApplicationFiled: November 26, 2008Publication date: March 19, 2009Inventor: Anatoly Z. Rosenflanz
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Publication number: 20090075807Abstract: A method of making an article from an aluminum oxide glass is disclosed. The aluminum oxide glass includes a rare earth oxide. The aluminum oxide glass has a glass transition temperature and a crystallization temperature, and these temperatures differ by at least 25K. The method includes: providing a glass in a form comprising particles, beads, microspheres, or fibers; heating the glass above the Tg such that the particles, beads, microspheres, or fibers coalesce to form a coalesced shape; and cooling the coalesced shape to form the article.Type: ApplicationFiled: November 26, 2008Publication date: March 19, 2009Inventor: Anatoly Z. Rosenflanz
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Publication number: 20090069166Abstract: Optical glass having a refractive index (nd) of 1.85 or greater, and an Abbe number (?d) falling within the range of 10 to 30, which is suited for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 3 to 60%, Bi2O3 in an amount of 25 to 80%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole percentage, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 480° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 600 nm for a thickness of 10 mm.Type: ApplicationFiled: April 27, 2006Publication date: March 12, 2009Inventor: Jie Fu
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Publication number: 20090069165Abstract: Optical glass having a refractive index (nd) of 1.75 or greater, and an Abbe number (?d) falling within the range of 15 to 40, which is suitable for molding by precision mold press is provided. The optical glass is characterized by including B2O3+SiO2 in an amount of 10 to 70%, Bi2O3 in an amount of 5% or more and less than 25%, RO+Rn2O in an amount of 5 to 60% (wherein R represents one or more selected from a group consisting of Zn, Ba, Sr, Ca, and Mg; and Rn represents one or more selected from a group consisting of Li, Na, K, and Cs), with each component in the range expressed in oxide-based mole, and is characterized in that transparency in the visible region is high, and that the transition point (Tg) is 520° C. or lower. The optical glass is characterized by having a spectral transmittance of 70% or greater at a wavelength of 550 nm, for a thickness of 10 mm.Type: ApplicationFiled: April 27, 2006Publication date: March 12, 2009Inventor: Jie Fu
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Patent number: 7501001Abstract: Abrasive particles and methods of making the same. Embodiments of the invention can be used to make abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.Type: GrantFiled: August 2, 2002Date of Patent: March 10, 2009Assignee: 3M Innovative Properties CompanyInventors: Anatoly Z. Rosenflanz, Ahmet Celikkaya, Thomas J. Anderson
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Patent number: 7494604Abstract: The invention is directed to a thick film getter composition comprising: (a) desiccant material; dispersed in (b) organic medium comprising (1) curable organic polymeric binder; (2) monomer; and (3) photoinitiator.Type: GrantFiled: March 24, 2008Date of Patent: February 24, 2009Assignee: E.I. du Pont de Nemours and CompanyInventors: Yong Cho, Jay Robert Dorfman
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Publication number: 20090042711Abstract: [Object] To provide a high-refractivity high-dispersion optical glass having excellent stability [Solution Means] An optical glass which is formed of an oxide glass containing 30 to 70 cationic % of Bi3+ and has a liquidus temperature of 800° C. or lower.Type: ApplicationFiled: August 5, 2008Publication date: February 12, 2009Applicant: HOYA CORPORATIONInventors: Xuelu Zou, Yasuhiro Fujiwara, Yoshio Nojima
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Publication number: 20090039758Abstract: An adhesive agent for fluorescent dyes for adhering a fluorescent layer on a substrate, wherein the adhesive agent contains or consists of a glass composition.Type: ApplicationFiled: April 10, 2008Publication date: February 12, 2009Applicant: SCHOTT AGInventors: Jorg Hinrich Fechner, Franz Ott
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Patent number: 7482296Abstract: The invention is directed to an aluminoborosilicate glass containing alkali metals for the production of optical components with refractive index gradients which are generated by ion exchange of monovalent metal ions in a base glass comprising at least silicon oxide, boron oxide, aluminum oxide and an alkali metal oxide, particularly for the production of gradient index lenses (GRIN lenses).Type: GrantFiled: December 17, 2004Date of Patent: January 27, 2009Assignee: Grintech GmbHInventors: Bernhard Messerschmidt, Christian Ruessel, Sandra Hornschuh, Torsten Possner, Ulf Possner
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Publication number: 20090004369Abstract: A conductor paste for a ceramic substrate contains a) a conductive metal powder comprising a silver powder and a palladium powder; b) a glass powder; and c) an organic solvent, wherein the conductive metal powder has an average particle diameter of not more than 1.2 ?m, and the glass powder is a Bi2O3—SiO2—B2O3 type glass powder, and the content of the glass powder is in a range of from 1 to 6 wt % based on the weight of the paste.Type: ApplicationFiled: June 29, 2007Publication date: January 1, 2009Inventors: Akira Inaba, Naoto Nakajima
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Patent number: 7452607Abstract: Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 15-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O 1-15%, Li2O+Na2O+K2O 2-25% and others, and which comprises ZnO 0-15%. Provided is a nonlead glass for covering an electrode, which comprises, in mol %, B2O3 25-65%, SiO2 2-38%, MgO 2-30%, MgO+CaO+SrO+BaO 5-45%, Li2O+Na2O+K2O 2-25%, Al2O3 0-30, TiO 0-10% and ZnO 0-15%.Type: GrantFiled: November 21, 2007Date of Patent: November 18, 2008Assignee: Asahi Glass Company, LimitedInventors: Hitoshi Onoda, Yu Goshima, Yumiko Aoki
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Publication number: 20080280748Abstract: A dielectric ceramic-forming composition capable of being sintered at a temperature lower than that in the known art and to be formed into a dielectric ceramic material having a high dielectric constant; and a dielectric ceramic material obtained from the dielectric ceramic-forming composition are provided. The dielectric ceramic-forming composition includes a perovskite (ABO3) ceramic material powder having an average particle size of 0.01 to 0.5 ?m and a glass powder having an average particle size of 0.1 to 5 ?m, wherein the content of the glass powder is 3 to 12 percent by weight. The perovskite (ABO3) ceramic material powder is preferably a perovskite (ABO3) ceramic material powder prepared by a wet reaction.Type: ApplicationFiled: March 20, 2006Publication date: November 13, 2008Applicant: NIPPON CHEMICAL INDUSTRIAL CO., LTD.,Inventors: Kyouichi Nishigaki, Shinji Tanabe, Naoaki Narishige
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Publication number: 20080269038Abstract: The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.Type: ApplicationFiled: April 23, 2008Publication date: October 30, 2008Inventors: Meike SCHNEIDER, Thilo ZACHAU, Friedrich SIEBERS, Wolfgang SCHMIDBAUER
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Publication number: 20080261797Abstract: The optical glass for press molding of the present invention contains 35 to 45% by weight of SiO2, 15 to 30% by weight of B2O3, and 18 to 33% by weight of CaO so that the total amount is 75 to 96% by weight. Also, the glass has an index of refraction (nd) of 1.55 to 1.63, an optical constant value ranging from 55 to 63 by the Abbe number (?d), a specific gravity of not more than 2.75, and a glass transition temperature (Tg) of not more than 550° C. According to the present invention, it is possible to provide inexpensive optical glass for press molding which exerts intended optical performance while realizing further reduction in size and weight of optical devices.Type: ApplicationFiled: December 28, 2007Publication date: October 23, 2008Inventors: Takashi Tsutsumi, Risa Suzuki