Nitrate Patents (Class 502/201)
  • Patent number: 12286747
    Abstract: A reactive fiber, a method of manufacturing the reactive fiber, and an outer shell of chemical, biological and radiological (CBR) protective clothing including the reactive fiber are provided. The reactive fiber includes a fiber, a plurality of reactive projections formed on a surface of the fiber, and a plurality of hydrophobic projections formed on the fiber and surfaces of the reactive projections.
    Type: Grant
    Filed: April 29, 2020
    Date of Patent: April 29, 2025
    Assignee: Agency for Defense Development
    Inventors: Hyun Sook Jung, Min Kun Kim, Seong On Jang, Jun O Lee, Hee Soo Jung
  • Patent number: 11439984
    Abstract: A supported oxidative coupling of methane (OCM) catalyst comprising a support and an OCM catalytic composition characterized by the general formula AaZbEcDdOx; wherein A is an alkaline earth metal; wherein Z is a first rare earth element; wherein E is a second rare earth element; wherein D is a redox agent or a third rare earth element; wherein the first rare earth element, the second rare earth element, and the third rare earth element, when present, are not the same; wherein a is 1.0; wherein b is from about 0.1 to about 10.0; wherein c is from about 0.1 to about 10.0; wherein d is from about 0 to about 10.0; and wherein x balances the oxidation states.
    Type: Grant
    Filed: March 17, 2020
    Date of Patent: September 13, 2022
    Assignee: Sabic Global Technologies, B.V.
    Inventors: Wugeng Liang, Luanyi Li, Hector Perez, Jae Hyung Kim, Pankaj Gautam, Vidya Sagar Reddy Sarsani, David West
  • Patent number: 10668453
    Abstract: The present invention relates to a process for producing a composite material and also the composite material itself. The composite material contains a bismuth-molybdenum-nickel mixed oxide or a bismuth-molybdenum-cobalt mixed oxide and a specific SiO2 as pore former. The present invention also relates to the use of the composite material according to the invention for producing a washcoat suspension and also a process for producing a coated catalyst using the composite material according to the invention. Furthermore, the present invention also relates to a coated catalyst which has a catalytically active shell comprising the composite material according to the invention on a support body. The coated catalyst according to the invention is used for preparing [alpha],[beta]-unsaturated aldehydes from olefins.
    Type: Grant
    Filed: April 24, 2018
    Date of Patent: June 2, 2020
    Assignee: CLARIANT INTERNATIONAL LTD
    Inventors: Inga Walzel, Gerhard Mestl, Silvia Neumann, Magdalena Pritzl, Gabriele Donabauer, Robert K. Grasselli
  • Patent number: 9975111
    Abstract: The present invention relates to a process for producing a composite material and also the composite material itself. The composite material contains a bismuth-molybdenum-nickel mixed oxide or a bismuth-molybdenum-cobalt mixed oxide and a specific SiO2 as pore former. The present invention also relates to the use of the composite material according to the invention for producing a washcoat suspension and also a process for producing a coated catalyst using the composite material according to the invention. Furthermore, the present invention also relates to a coated catalyst which has a catalytically active shell comprising the composite material according to the invention on a support body. The coated catalyst according to the invention is used for preparing [alpha],[beta]-unsaturated aldehydes from olefins.
    Type: Grant
    Filed: March 20, 2014
    Date of Patent: May 22, 2018
    Assignee: Clariant International Ltd.
    Inventors: Inga Walzel, Gerhard Mestl, Silvia Neumann, Magdalena Pritzl, Gabriele Donabauer, Robert K. Grasselli
  • Patent number: 9950315
    Abstract: The present invention provides a process and catalyst for the production of synthesis gas (a mixture of CO and H2) by reforming of methane with carbon dioxide. The process provides a direct single step selective vapor phase dry reforming of methane with carbon dioxide to produce synthesis gas over Ni—MgO—ZnO catalyst between temperature range of 600° C. to 800° C. at 1 atmospheric pressure. The process provides a methane conversion of 5-95% with H2 to CO mole ratio of 0.83-1.2.
    Type: Grant
    Filed: September 1, 2015
    Date of Patent: April 24, 2018
    Assignee: Council of Scientific & Industrial Research
    Inventors: Rajaram Bal, Rajib Kumar Singha, Chandrashekar Pendem, Laxmi Narayan Siva Kumar Konathala, Ankur Bordoloi, Sandeep Saran
  • Patent number: 9669390
    Abstract: A method for controllably producing a hematite-containing Fischer-Tropsch catalyst by combining an iron nitrate solution with a precipitating agent solution at a precipitating temperature and over a precipitation time to form a precipitate comprising iron phases; holding the precipitate from at a hold temperature for a hold time to provide a hematite containing precipitate; and washing the hematite containing precipitate via contact with a wash solution and filtering, to provide a washed hematite containing catalyst. The method may further comprise promoting the washed hematite containing catalyst with a chemical promoter; spray drying the promoted hematite containing catalyst; and calcining the spray dried hematite containing catalyst to provide a calcined hematite-containing Fischer-Tropsch catalyst.
    Type: Grant
    Filed: February 11, 2014
    Date of Patent: June 6, 2017
    Assignee: RES USA, LLC
    Inventors: Dawid J. Duvenhage, Christine Schmidt, Mark Still, Khalid Azzam, Karl C. Kharas, Sara Hunegnaw, Olga Ionkina, Ray J. Huang, Harold A. Wright
  • Patent number: 9511359
    Abstract: A method of making a selective hydrogenation catalyst comprising contacting a support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with an organophosphorus compound and a weak acid to form a catalyst composition; and reducing the catalyst composition to form the catalyst. A method of making a selective hydrogenation catalyst comprising contacting an alumina support with a palladium-containing compound to form a supported-palladium composition; contacting the supported-palladium composition with silver nitrate and potassium fluoride to form a mixture; contacting the mixture with an organophosphorus compound and a weak acid to form a catalyst precursor; and reducing the catalyst precursor to form the catalyst.
    Type: Grant
    Filed: November 14, 2014
    Date of Patent: December 6, 2016
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Tin-Tack Peter Cheung, Zongxuan Hong, Joseph Bergmeister, III
  • Patent number: 9267220
    Abstract: Inorganic nanofibers comprise an inorganic matrix material surface functionalized with at least one metal oxide in crystalline form. Crystal growth on external surfaces may occur in substantial alignment with a longitudinal axis of the nanofibers, and the crystals are typically between about 10.0 nm and 30.0 nm in size. The nanofibers may be hollow (i.e., nanotubes) or they may be randomly dispersed together in the form of a nanofiber mat. Methods for making the nanofibers comprise spinning a dispersion comprising linear polymers and metal oxide precursors.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: February 23, 2016
    Assignee: Cornell University
    Inventors: Yong L. Joo, Jeanne E. Panels
  • Patent number: 9018126
    Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and deposited on the carrier, silver, a promoting amount of one or more promoters selected from the group consisting of alkali metals and rhenium and a promoting amount of nickel, wherein the nickel is added as a nickel compound or nickel complex during the initial impregnation along with the silver and other promoters; including a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: April 28, 2015
    Assignee: Shell Oil Company
    Inventor: Marek Matusz
  • Patent number: 8999882
    Abstract: A process for treating a carrier, or a precursor thereof, to at least partly remove impurities from the carrier, or the precursor thereof, comprising: contacting the carrier, or the precursor thereof, with a treatment solution comprising a salt in a concentration of at most 0.05 molar, wherein the salt comprises a cation and an anion, and wherein the cation is selected from ammonium, phosphonium, organic cations and combinations thereof, and wherein the anion is selected from organic anions, inorganic carboxylates, oxyanions of elements from Groups IIIA through VIIA of the Periodic Table of Elements, and combinations thereof; and separating at least part of the treatment solution from the carrier, or the precursor thereof.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: April 7, 2015
    Assignee: Shell Oil Company
    Inventors: John Robert Lockemeyer, Randall Clayton Yeates
  • Patent number: 9000207
    Abstract: A method for producing a silica-supported catalyst comprising Mo, V. Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of proprane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water; (II) obtaining a dry powder by drying the raw material mixture solution; and (III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.
    Type: Grant
    Filed: May 22, 2014
    Date of Patent: April 7, 2015
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yusuke Ishii, Takaaki Kato
  • Patent number: 8946108
    Abstract: A structurally promoted, precipitated, Fischer-Tropsch catalyst that exhibits an RCAI-10 of 0-2.8 and/or produces less than 6 wt % fines after 5 hours ASTM Air Jet Attrition testing, due to formation via: preparing a nitrate solution by forming at least one metal slurry and combining the at least one metal slurry with a nitric acid solution; combining the nitrate solution with a basic solution to form a precipitate; structurally promoting the precipitate with at least one source of silicon to form a promoted mixture, wherein promoting comprises combining the precipitate with (a) silicic acid and one or more component selected from the group consisting of non-crystalline silicas, crystalline silicas, and sources of kaolin or (b) a component selected from the group consisting of non-crystalline silicas and sources of kaolin, in the absence of silicic acid; and spray drying the promoted mixture to produce catalyst having a desired particle size.
    Type: Grant
    Filed: June 2, 2014
    Date of Patent: February 3, 2015
    Assignee: RES USA, LLC.
    Inventors: Dawid J. Duvenhage, Belma Demirel
  • Patent number: 8946112
    Abstract: An embodiment relates to a photocatalytic composite material comprising (a) a first component that generates a photoexcited electron and has at least a certain minimum bandgap to absorb visible light and a structure that substantially prevents the recombination of the photoexcited electron and a hole; (b) a second component that adsorbs/absorbs an oxide of carbon; and (c) a third component that splits the oxide of carbon into carbon and oxygen using the photoexcited electron.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: February 3, 2015
    Assignee: Empire Technology Development LLC
    Inventor: Thevasahayam Arockiadoss
  • Patent number: 8932979
    Abstract: A catalyst composition comprising a support having a surface area of at least 500 m2/kg, and deposited on the support: silver metal, a metal or component comprising rhenium, tungsten, molybdenum or a nitrate- or nitrite-forming compound, and a Group IA metal or component comprising a Group IA metal having an atomic number of at least 37, and in addition potassium, wherein the value of the expression (QK/R)+QHIA is in the range of from 1.5 to 30 mmole/kg, wherein QHIA and QK represent the quantities in mmole/kg of the Group IA metal having an atomic number of at least 37 and potassium, respectively, present in the catalyst composition, the ratio of QHIA to QK is at least 1:1, the value of QK is at least 0.01 mmole/kg, and R is a dimensionless number in the range of from 1.5 to 5, the units mmole/kg being relative to the weight of the catalyst composition.
    Type: Grant
    Filed: August 14, 2008
    Date of Patent: January 13, 2015
    Assignee: Shell Oil Company
    Inventors: Marek Matusz, Michael Alan Richard, Martin Lysle Hess
  • Patent number: 8932978
    Abstract: A solid solution photocatalyst composition and its preparation method are provided in the present invention. The solid solution photocatalyst can utilize its solid solution structure to regulate the conduction band position, valence band position, conduction band range and valence band range of the different response properties of the photocatalyst, so that oxidoreductive reaction is performed to remove the foul-smelling substances.
    Type: Grant
    Filed: March 21, 2012
    Date of Patent: January 13, 2015
    Assignee: National Tsing Hua University
    Inventors: Yong-Chien Ling, Jen-Yu Liu
  • Publication number: 20140369915
    Abstract: Provided are a catalyst for hydrolysis and use of a titanium dioxide-based composition which are capable of removing COS and HCN simultaneously at high degradation percentages. The catalyst for hydrolysis is a catalyst for hydrolysis of carbonyl sulfide and hydrogen cyanide, having at least: an active component containing, as a main component, at least one metal selected from the group consisting of barium, nickel, ruthenium, cobalt, and molybdenum; and a titanium dioxide-based support supporting the active component.
    Type: Application
    Filed: February 14, 2013
    Publication date: December 18, 2014
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Masanao Yonemura, Toshinobu Yasutake, Shuji Fujii, Koji Higashino, Makoto Susaki, Kaori Yoshida
  • Publication number: 20140357470
    Abstract: The present invention is a metal colloid solution comprising: colloidal particles consisting of metal particles consisting of one or two or more metal(s) and a protective agent bonding to the metal particles; and a solvent as a dispersion medium of the colloidal particles, wherein: a chloride ion concentration per a metal concentration of 1 mass % is 25 ppm or less; and a nitrate ion concentration per a metal concentration of 1 mass % is 7500 ppm or less. In the present invention, adsorption performance can be improved with adjustment of the amount of the protective agent of the colloidal particles. It is preferable to bind the protective agent of 0.2 to 2.5 times the mass of the metal particles.
    Type: Application
    Filed: February 8, 2013
    Publication date: December 4, 2014
    Applicant: Tanaka Kikinzoku Kogyo K.K.
    Inventors: Yuusuke Ohshima, Hitoshi Kubo, Tomoko Ishikawa, Noriaki Nakamura, Junichi Taniuchi, Yoshiteru Tsuchiya, Hiroaki Takahashi, Hidenori Takanezawa, Kenichi Inoue, Syunsuke Kato, Hirokazu Shiraishi
  • Patent number: 8859452
    Abstract: A metal cyanide complex catalyst and its preparation and application are disclosed. The formula of this catalyst is M1a[M2(CN)bL1c]d(X)m(L2)n.xSu.yL3.zH2O and its preparation method comprises: (A) adjusting pH of a mixed solution I? of L3, M3e[M2(CN)bL1c]f, de-ionized water I, alcohol and/or ether solvent to less than 7.0, and adding it into a mixed solution II? of M1(X)g salt, Su or Su precursor, de-ionized water II, stirring for reaction under 20° C.-120° C. for 0.5-200 hours, separating and drying to obtain a solid product; and (B) repeatedly dispersing the solid into an anhydrous organic solvent containing L2 to form a slurry, distilling, separating and drying to obtain the metal cyanide complex catalyst. The catalyst is useful in preparing polyethers, polycarbonates and polyesters by homopolymerization of epoxides, or copolymerization of epoxides with carbon dioxide or anhydrides.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: October 14, 2014
    Assignee: Zhejiang University
    Inventors: Xinghong Zhang, Guorong Qi, Binyang Du, Renjian Wei, Xueke Sun
  • Publication number: 20140294989
    Abstract: The Cu- and Ti-containing composition of the present invention contains titanium oxide including rutile-crystal-type titanium oxide, and a divalent copper compound, wherein the rutile-crystal-type titanium oxide exhibits the most intense diffraction peak attributed to rutile-type titanium oxide having a full width at half maximum of 0.65° or less, in a Cu—K? line X-ray diffraction pattern, which is obtained by plotting intensity of diffraction line with respect to diffraction angle 2?. The composition exhibits excellent anti-viral property under light and in the dark, and excellent organic compound degradability under light.
    Type: Application
    Filed: December 17, 2012
    Publication date: October 2, 2014
    Applicant: SHOWA DENKO K.K.
    Inventors: So Miyaishi, Yasushi Kuroka, Yasuhiro Hosogi, Ding Li
  • Patent number: 8828544
    Abstract: A process for depositing nanostructured material onto a particulate substrate material comprising the steps of: a) preparing a precursor material; b) forming an atomized dispersion containing nanophased material when subjecting said precursor material to elevated temperature; and c) contacting the atomized dispersion with the substrate material to deposit the nanophased material on the substrate material. The substrate material is in mobile and particulate form for contacting step (c). An apparatus for carrying out the process is also disclosed.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: September 9, 2014
    Assignee: Commonwealth Scientific And Industrial Research Organisation
    Inventors: Kok Seng Lim, Jonian Ivanov Nikolav
  • Patent number: 8791041
    Abstract: A method of producing a Fischer-Tropsch catalyst by preparing a nitrate solution, wherein preparing comprises forming at least one metal slurry and combining the at least one metal slurry with a nitric acid solution; combining the nitrate solution with a basic solution to form a precipitate; promoting the precipitate to form a promoted mixture, wherein promoting comprises combining the precipitate with (a) silicic acid and one or more selected from the group consisting of non-crystalline silicas, crystalline silicas, and sources of kaolin or (b) at least one selected from non-crystalline silicas and sources of kaolin, in the absence of silicic acid; and spray drying the promoted mixture to produce catalyst having a desired particle size. Catalyst produced by the disclosed method is also described.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: July 29, 2014
    Assignee: RENTECH, Inc.
    Inventors: Dawid J. Duvenhage, Belma Demirel
  • Patent number: 8772195
    Abstract: To produce a silica-supported catalyst having an excellent yield of a target product and excellent catalyst attrition resistance. A method for producing a silica-supported catalyst comprising Mo, V, Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of propane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water; (II) obtaining a dry powder by drying the raw material mixture solution; and (III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.
    Type: Grant
    Filed: January 21, 2010
    Date of Patent: July 8, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Yusuke Ishii, Takaaki Kato
  • Publication number: 20140005039
    Abstract: A process for preparing a catalyst for production of an olefin oxide containing (a) a copper oxide and (b) a ruthenium oxide, which comprises the step of drying a mixture containing a copper component, a ruthenium component, water, and at least one ion selected from the group consisting of a nitrate ion having a molar ratio to the copper of 3 or more and a halide ion having a molar ratio to the ruthenium of 9 or more, and calcining.
    Type: Application
    Filed: June 28, 2013
    Publication date: January 2, 2014
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Yoshihiko OHISHI, Anusorn Seubsai, Selim Senkan
  • Patent number: 8598309
    Abstract: This invention relates to a Salen type ligand including three or more quaternary ammonium salts of nitrate anions, to a trivalent metal complex compound prepared from this ligand and a method of preparing the same, to a method of preparing polycarbonate by copolymerizing an epoxide compound and carbon dioxide using the complex compound as a catalyst, and to a method of separating and collecting the catalyst from the copolymer after copolymerization. This catalyst used to copolymerize an epoxide compound and carbon dioxide can be more simply prepared, and has lower catalyst preparation and recovery costs, and higher activity, compared to conventional catalysts.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: December 3, 2013
    Assignee: SK Innovation Co., Ltd.
    Inventors: Ji Su Jeong, Sujith Sudevan, Myung Ahn Ok, Sung Jae Na, Yong Gyu Han, Kwang Jin Chung, Bun Yeoul Lee, Kodiyan Varghese Jobi
  • Publication number: 20130288889
    Abstract: A visible light sensitive photocatalyst including: a composite including a first metal oxide, a second metal oxide, and a heterojunction therebetween, wherein the first and second metal oxides each include a Group 11 metal, wherein a first bond between metal atoms of the first metal oxide has a length that is smaller than a Van der Waals distance between the metals of the first bond, wherein a second bond between metal atoms of the second metal oxide has a length that is smaller than a Van der Waals distance between the metals of the second bond, and, wherein the composite has a band gap energy of about 1.0 eV to about 2.5 eV.
    Type: Application
    Filed: March 18, 2013
    Publication date: October 31, 2013
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Tae-gon KIM, Seoung-jae IM, Tae-hyung KIM, Jeong-hee LEE
  • Patent number: 8569198
    Abstract: An exhaust gas-purifying catalyst includes first particles of oxygen storage material, second particles of one or more alkaline-earth metal elements and/or compounds thereof interposed between the first particles, and third particles of one or more precious metal elements interposed between the first particles. A spectrum of a first characteristic X-ray intensity for one of the one or more alkaline-earth metal elements and a spectrum of a second characteristic X-ray intensity for one of the one or more precious metal elements that are obtained by performing a line analysis using energy-dispersive X-ray spectrometry along a length of 500 nm have a correlation coefficient ?(AE,PM) of 0.70 or more.
    Type: Grant
    Filed: February 22, 2012
    Date of Patent: October 29, 2013
    Assignee: Cataler Corporation
    Inventors: Sho Hoshino, Akimasa Hirai, Kenichi Taki, Keiichi Narita, Satoshi Matsueda, Asuka Hori, Masahiro Kusaka
  • Publication number: 20130274091
    Abstract: Present disclosure provides a process for the synthesis of doped titania nanoparticle having photocatalytic activity greater than 90% at 2 hours under sunlight irradiation. The process involves step a) milling a mixture containing anatase titania and a precursor compound, the compound selected from the group consisting of metal and non-metal salts, in the presence of water and oxide milling media, at a temperature in the range of 20 to 50° C. for a period of 60-120 minutes, to form a slurry, wherein the amount of water is in the range of 15 to 25% by weight of the total mixture; and b) filtering the slurry to separate the oxide milling media and obtain a filtrate containing doped titania nanoparticles.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 17, 2013
    Applicant: Tata Consultancy Services Limited
    Inventors: Auhin Kumar MAPARU, Beena RAI, Vivek GANVIR
  • Publication number: 20130274094
    Abstract: Catalysts for dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity, short residence time, and without significant conversion to undesired side products, such as, for example, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed condensed phosphates. Methods of preparing the catalysts are also provided.
    Type: Application
    Filed: February 6, 2013
    Publication date: October 17, 2013
    Applicant: THE PROCTER & GAMBLE COMPANY
    Inventors: Juan Estaban Velasquez, Janette Villalobos Lingoes, Jane Ellen Godlewski, Dimitris Ioannis Collias, Fred C. Wireko, Marc Andrew Mamak, Nancy Lee Redman-Furey
  • Patent number: 8546293
    Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V?, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V? are comminuted and recycled into the obtaining of the finely divided mixture.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: October 1, 2013
    Assignee: BASF SE
    Inventors: Andreas Raichle, Holger Borchert, Klaus Joachim Mueller-Engel, Catharina Horstmann, Josef Macht
  • Publication number: 20130210940
    Abstract: The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.
    Type: Application
    Filed: February 13, 2013
    Publication date: August 15, 2013
    Applicant: BASF SE
    Inventor: BASF SE
  • Publication number: 20130210616
    Abstract: Provided is a liquid combustion catalyst composition comprising an ionized metal compound, and more particularly, to a liquid combustion catalyst composition comprising an ionized metal compound, in which the ionic metal compound is added to fuel burning in a combustion engine to quickly achieve a chemical thermal equilibrium condition required for the combustion of fuel such as hydrocarbon fuel, fossil fuel and biomass, and to optimize the amount of air which contains oxygen required for the equilibrium condition in terms of chemical equivalence, thereby improving thermal efficiency and the efficiency of the combustion engine so that fuel consumption for a heat source can be reduced, and optimizing the combustion performed by the combustion device by controlling the generation of sludge, clinker and fouling which may be generated due to an inorganic substance so that a combustion rate per unit area and the productivity of the combustion device can be improved.
    Type: Application
    Filed: October 20, 2011
    Publication date: August 15, 2013
    Inventors: Mi Hye Oh, Na Hyeon Ryu, Yeon Seok Ryu, Hwan Woo Ryu
  • Patent number: 8501664
    Abstract: A process for treating a carrier, or a precursor thereof, to at least partly remove impurities comprising contacting the carrier, or the precursor thereof, with a treatment solution comprising a salt; a process for preparing a catalyst; the catalyst; a process for preparing an olefin oxide by reacting an olefin with oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether or an alkanolamine.
    Type: Grant
    Filed: November 15, 2007
    Date of Patent: August 6, 2013
    Assignee: Shell Oil Company
    Inventors: John Robert Lockemeyer, Randall Clayton Yeates
  • Patent number: 8461072
    Abstract: This invention relates to a series of novel late transition metal catalysts for olefin oligomerization, the catalysts demonstrating high activity and selectivity for linear ?-olefins. The catalysts contain a Group-8, -9, or -10 transition metal, M, excluding palladium; an ancillary ligand comprising: a terminal amine comprising two independently selected hydrocarbyl radicals, R1 and R2; a terminal phosphine comprising two independently selected hydrocarbyl radicals, R3 and R4; and a hydrocarbyl bridge, Y, comprising a backbone wherein the hydrocarbyl bridge connects between the terminal amine and the terminal phosphine and wherein the backbone comprises a chain that is four or more carbon atoms long; and an abstractable ligand, X. For example this invention relates to a composition of matter with the following formula: wherein M, R1, R2, R3, and R4, Y, and X are as defined above.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: June 11, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Baiyi Zhao, Smita Kacker, Jo Ann Marie Canich
  • Patent number: 8450234
    Abstract: The present invention relates to a catalyst used for producing dimethylether, a method of producing the same, and a method of producing dimethylether using the same. More particularly, the present invention relates to a catalyst used for producing dimethylether comprising a methanol synthesis catalyst produced by adding one or more promoters to a main catalyst comprised of a Cu—Zn—Al metal component and a dehydration catalyst formed by mixing Aluminum Phosphate (AlPO4) with gamma alumina, a method of producing the same, and a method of producing dimethylether using the same, wherein a ratio of the main catalyst to the promoter in the methanol synthesis catalyst is in a range of 99/1 to 95/5, and a mixing ratio of the methanol synthesis catalyst to the dehydration catalyst is in a range of 60/40 to 70/30.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: May 28, 2013
    Assignee: Korea Gas Corporation
    Inventors: Young Soon Baek, Won Jun Cho, Yun Bin Yan, Yong Gi Mo, Kyung Hae Lee, Eun Mee Jang
  • Publication number: 20130104698
    Abstract: The proposed methods are exemplarily utilized in uranium hydrometallurgy for selective extraction of uranium out of ore by in situ or heap leaching. According to the disclosure, the methods encompass catalytic oxidation of U4+ to U6+ using a proposed oxidizing catalyst “Muhamedzhan-1”, filtration of this solution through ore, transferring hexavalent uranium, trivalent iron, and other metal ions into a production solution, extraction of uranium yielding a barren solution and re-circulation of this solution back for ore leaching. The methods essentially improve known technologies by employing “Muhamedzhan-1”, being a solution of d- and f-mixed valence metal salts (MLn, wherein M=Fe, U, Cu, Mn, and L=NO3?, SO42?Cl?, Br?, I?) and alkali metal halogenides (MX, wherein M=Na+, Na+, K+, and X=Cl?, Br?, I?) used as an oxidizing agent, with the weight ratio of MLn: 0.01-25.0%, MX: 0.01-12.5%, and solvent: balance.
    Type: Application
    Filed: November 1, 2011
    Publication date: May 2, 2013
    Inventors: Yerkin Aibassov, Saltanat Aibassova, Gizatulla Aibassov, Zhaken Aibassov, Mukhamejan Aibassov, Bakhyt Abenov
  • Publication number: 20130035228
    Abstract: The present invention is directed to improving a catalyst applied to a reaction layer having a structure (PFF structure) in which a polymer electrolyte phase surrounds a periphery of a catalyst with a hydrophilic region interposed therebetween and reducing the amount of catalyst metal particles used. A method for producing a catalyst for a fuel cell, in which a catalyst metal particle is supported on a carrier, includes the steps of: preparing an unmodified catalyst in which a catalyst metal particles is supported on a carrier; and modifying the catalyst metal particle in the unmodified catalyst with at least one type of modifying group selected from a nitric acid group, an amino group, a sulfonic acid group, a hydroxy group, and halogen groups.
    Type: Application
    Filed: March 30, 2011
    Publication date: February 7, 2013
    Applicant: KABUSHIKIKAISHA EQUOS RESEARCH
    Inventor: Taizo Yamamoto
  • Publication number: 20120322648
    Abstract: A visible light sensitive photocatalyst including a compound represented by Formula 1: Aa-xM1xSib-yM2yOc??Formula 1 wherein A is one or more metals selected from Ag, Cu, and Au; M1 is one or more metals selected from Li, Na, K, Rb, and Cs; M2 is one or more metals selected from Ge, Sn, Ti, Zr, and Hf, and 1.7?a?2.3, 0.7?b?1.3, 2.7?c?3.3, 0?x<a, and 0?y<b.
    Type: Application
    Filed: June 14, 2012
    Publication date: December 20, 2012
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Tae-gon KIM, Tae-hyung KIM, Seoung-jae IM
  • Patent number: 8304030
    Abstract: A bi-laterally surfaced substrate in which the first surface consists of one or more than one of cerium oxide, aluminum oxide, tin oxide manganese oxide, copper oxide, cobalt oxide, nickel oxide, praseodymium oxide, terbium oxide, ruthenium, rhodium, palladium, silver, iridium, platinum and gold and the second surface consists of one or more than one of ruthenium, rhodium, palladium, silver, iridium, platinum and gold and micro channel micro component reactors including such substrates in a predetermined formed shape and methods for making the same utilizing a thermal spray on one side and a physical deposition process on the other side.
    Type: Grant
    Filed: October 9, 2007
    Date of Patent: November 6, 2012
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Ting He, Eisuke Kimura, Tadashi Nomura
  • Patent number: 8298980
    Abstract: A process for producing geometric shaped catalyst bodies K whose active material is a multielement oxide which comprises the element Mo, the elements Bi and/or V and one or more of the elements Co, Ni, Fe, Cu and alkali metals, in which sources of the different elements are used to obtain a finely divided mixture which is coarsened to a powder by press agglomeration, the coarsened powder is used to form, by press agglomeration, shaped bodies V which are separated into undamaged shaped bodies V+ and into damaged shaped bodies V?, the undamaged shaped bodies V+ are converted by thermal treatment to the shaped catalyst bodies K, and the damaged shaped bodies V? are comminuted and recycled into the obtaining of the finely divided mixture.
    Type: Grant
    Filed: December 9, 2009
    Date of Patent: October 30, 2012
    Assignee: BASF SE
    Inventors: Andreas Raichle, Holger Borchert, Klaus Joachim Mueller-Engel, Catharina Horstmann, Josef Macht
  • Patent number: 8298981
    Abstract: An improved process to produce high surface area nanoparticle vanadium phosphorus oxide catalysts comprises the steps of reducing vanadium-containing compounds in an alcohol solution selected from the group consisting of isobutanol and benzyl alcohol and any combination derives thereof under reflux for 4 to 6 hours to form a suspended mixture; reacting dopants and phosphorus-containing compounds to the suspended mixture under reflux for 30 minutes to 3 hours to form precursors of the vanadium phosphorus oxide catalysts; drying the formed precursors; and calcining the dried precursors in a flow of gaseous n-butane/air mixture at 400 to 460° C. to form activated vanadium phosphorus oxide catalysts.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: October 30, 2012
    Assignee: Universiti Putra Malaysia
    Inventors: Yun Hin Taufiq-Yap, Ali Asghar Rownaghi
  • Publication number: 20120264592
    Abstract: The invention relates to composition and methods of using described compositions as oxidative catalysis. In certain embodiments, the invention relates to a composition having a nitrogen oxide species, bromide ion, a metal, and oxygen. In certain embodiments, the composition catalyzes sulfides.
    Type: Application
    Filed: September 8, 2010
    Publication date: October 18, 2012
    Applicant: EMORY UNIVERSITY
    Inventors: Zhen Luo, Daniel A. Hillesheim, Iourii V. Gueletii, Craig L. Hill
  • Publication number: 20120215047
    Abstract: Cellulose and hemicellulose from biomass can be broken down to C6 and C5 sugars and further converted to corresponding sugar alcohols. It is now found that a new catalyst, MoS2, is active for the hydrogenation of sugar alcohols to hydrocarbons. Combining the technologies listed above allows us to convert the cellulose/hemicellulose to liquid hydrocarbons.
    Type: Application
    Filed: September 15, 2011
    Publication date: August 23, 2012
    Applicant: CONOCOPHILLIPS COMPANY
    Inventors: Madhu ANAND, Jianhua YAO, Edward L. SUGHRUE, II
  • Publication number: 20120178972
    Abstract: A process for depositing nanostructured material onto a particulate substrate material comprising the steps of: a) preparing a precursor material; b) forming an atomised dispersion containing nanophased material when subjecting said precursor material to elevated temperature; and c) contacting the atomised dispersion with the substrate material to deposit the nanophased material on the substrate material. The substrate material is in mobile and particulate form for contacting step (c). An apparatus for carrying out the process is also disclosed.
    Type: Application
    Filed: April 19, 2010
    Publication date: July 12, 2012
    Applicant: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Kok Seng Lim, Jonian Ivanov Nikolav
  • Patent number: 8182679
    Abstract: The present invention, provides novel silicon compounds, methods for making these novel silicon compounds, compositions comprising these novel silicon compounds attached to substrates, methods for attaching the novel silicon compounds to substrates and methods for using the compositions in a variety of chromatographic applications.
    Type: Grant
    Filed: April 28, 2008
    Date of Patent: May 22, 2012
    Assignee: Dionex Corporation
    Inventors: Xiaodong Liu, Christopher A. Pohl, Andrei V. Bordunov, Nebojsa Avdalovic
  • Publication number: 20120088655
    Abstract: An exhaust gas-purifying catalyst includes a substrate, and a catalytic layer supported by the substrate. The catalytic layer includes a support made of alumina, an oxygen storage material, an alkaline earth metal and/or a compound of alkaline-earth metal selectively supported by a surface of the support and dispersed on the surface of the support, and a precious metal supported by the surface of the support. A ratio of a number of moles of the alkaline-earth metal in the catalytic layer with respect to a volumetric capacity of the exhaust gas-purifying catalyst falls within a range of 0.0004 mol/L to 0.35 mol/L.
    Type: Application
    Filed: December 15, 2011
    Publication date: April 12, 2012
    Inventors: Yuji Yabuzaki, Akimasa Hirai, Kenichi Taki, Tomohito Mizukami, Satoshi Matsueda
  • Publication number: 20120016143
    Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and deposited on the carrier, silver, a promoting amount of one or more promoters selected from the group consisting of alkali metals and rhenium and a promoting amount of nickel, wherein the nickel is added as a nickel compound or nickel complex during the initial impregnation along with the silver and other promoters; including a process for preparing the catalyst; a process for preparing an olefin oxide by reacting a feed comprising an olefin and oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine.
    Type: Application
    Filed: July 11, 2011
    Publication date: January 19, 2012
    Applicant: SHELL OIL COMPANY
    Inventor: Marek MATUSZ
  • Patent number: 8093175
    Abstract: The invention relates to a composition capable of trapping hydrogen comprising: (a) at least one mineral compound of formula (I) below: MX(OH)??(I) in which: M represents a divalent transition element; O represents an oxygen atom; X represents an atom chosen from S, Se, Te, Po; and H represents a hydrogen atom; and (b) at least one nitrate salt of formula (II) below: ZNO3??(II) in which Z is a monovalent cation. Use of these compositions either in pulverulent form for trapping gaseous hydrogen by direct interaction, or in the form of an adjuvant in a containment material for, for example, trapping hydrogen released by radiolysis in radioactive waste packages.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: January 10, 2012
    Assignee: Commissariat a l'Energie Atomique
    Inventor: Chantal Riglet-Martial
  • Publication number: 20110301021
    Abstract: A polyacid-promoted, zirconia catalyst or catalyst support having a high crush strength, surface area and pore volume is described. The polyacid-promoted, zirconia catalyst or catalyst support may be made by combining a zirconium compound with a polyacid/promoter material that includes the group 6 metals (i.e., chromium (Cr), molybdenum (Mo), tungsten (W)), as well as phosphoric acids, sulfuric acids, and polyorganic acids. The zirconyl-promoter precursor may be extruded in the absence of any binder or extrusion aid. The polyacid-promoted, zirconia catalyst or catalyst support is hydrothermally stable in aqueous phase hydrogenation or hydrogenoloysis reactions.
    Type: Application
    Filed: March 3, 2010
    Publication date: December 8, 2011
    Applicant: SUD-CHEMIE INC.
    Inventors: Aiguo Liu, Todd J. Cole, II, Wayne Turbeville
  • Publication number: 20110288325
    Abstract: Disclosed is a silica-supported catalyst having excellent wear resistance, by which an object product can be obtained with excellent yield. Specifically disclosed is a method for producing a silica-supported catalyst which contains Mo, V, Nb and component X (that is Sb and/or Te), and is used in a vapor-phase catalytic oxidation reaction or vapor-phase catalytic ammoxidation reaction of propane. The method for producing a silica-supported catalyst comprises: (I) a step wherein Mo, V, Nb, component X, a silica sol and water are mixed, thereby preparing a starting material blended solution; (II) a step wherein the starting material blended solution is dried, thereby obtaining a dried powder; and (III) a step wherein the dried powder is tired, thereby obtaining a silica-supported catalyst. In the method for producing a silica-supported catalyst, the silica sol contains 10-270 ppm by weight of nitrate ions relative to SiO2.
    Type: Application
    Filed: January 21, 2010
    Publication date: November 24, 2011
    Inventors: Yusuke Ishii, Takaaki Kato
  • Publication number: 20110236284
    Abstract: Disclosed are a photocatalyst-coated body that can realize a good weather resistance, a photocatalyst-coated body that, in removing NOx, particularly in removing NOx in air, can suppress the production of an intermediate product such as NO2 while increasing the NOx removed, and a photocatalytic coating liquid for use in the formation of the photocatalyst-coated body. The photocatalyst-coated body comprises a photocatalyst layer provided on a substrate. The photocatalyst layer comprises at least photocatalytic titanium oxide particles, silica particles, and a product obtained by drying water soluble zirconium compound.
    Type: Application
    Filed: March 24, 2011
    Publication date: September 29, 2011
    Applicant: TOTO LTD.
    Inventors: Makoto HAYAKAWA, Koji OMOSHIKI, Satoru KITAZAKI, Hiroyuki FUJII, Mitsuyoshi KANNO, Junji KAMESHIMA