Catalyst Or Precursor Therefor Patents (Class 502/100)
  • Patent number: 11932538
    Abstract: The invention relates to a process for reforming a hydrocarbon feed stream comprising a hydrocarbon gas and steam, said process comprising the steps of: a) in a synthesis gas generation reactor carrying out a reforming reaction of the hydrocarbon feed stream over a first catalyst, thereby forming a first synthesis gas; b) providing a heated CO2 rich stream to a post converter comprising a second catalyst; and c) in said post converter carrying out a methanation, steam reforming and reverse water gas shift reactions of the first synthesis gas and the heated CO2 rich stream to produce a product synthesis gas, wherein said second catalyst is heated electrically by means of an electrical power source. The invention moreover relates to a system arranged to carry out the process of the invention.
    Type: Grant
    Filed: November 15, 2018
    Date of Patent: March 19, 2024
    Assignee: Haldor Topsøe A/S
    Inventors: Peter Mølgaard Mortensen, Martin Østberg
  • Patent number: 11826734
    Abstract: Provided is a catalyst structure for a liquid organic hydrogen carrier (LOHC) dehydrogenation reactor, including a support, a plurality of channels formed on the support in such a manner that the LOHC may flow therethrough, and an LOHC dehydrogenation catalyst that is coated on the inner surfaces of the channels and is in contact with the LOHC to carry out LOHC dehydrogenation, wherein the hydrogen gas generated from the dehydrogenation is discharged along the channels so that the contact area between the LOHC and the LOHC dehydrogenation catalyst may be increased.
    Type: Grant
    Filed: December 1, 2021
    Date of Patent: November 28, 2023
    Assignee: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Joongmyeon Bae, Sanghun Lee, Taehong Kim, Jaemyung Lee, Gwangwoo Han
  • Patent number: 11763965
    Abstract: An oxide superconducting thin film material includes: a metal substrate having a surface with a biaxially oriented crystal orientation structure; an intermediate layer biaxially oriented and formed on the metal substrate; and an oxide superconducting thin film formed on the intermediate layer and composed of a RE123-based oxide superconductor represented by REBa2Cu3Oy. The oxide superconducting thin film includes Br (bromine).
    Type: Grant
    Filed: October 31, 2017
    Date of Patent: September 19, 2023
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takanori Motoki, Jun-ichi Shimoyama, Genki Honda, Tatsuoki Nagaishi
  • Patent number: 11293317
    Abstract: A honeycomb filter includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells and a plugging portion, wherein the partition wall is composed of a material containing cordierite as a main component thereof, porosity of the partition wall measured by a mercury press-in method is 55 to 65%, an average pore diameter of the partition wall measured by a mercury press-in method is 5 to 10 ?m, and in a pore diameter distribution indicating a cumulative pore volume of the partition wall measured by a mercury press-in method, with a pore diameter (?m) on an abscissa axis and a log differential pore volume (cm3/g) on an ordinate axis, a first peak including a maximum value of the log differential pore volume has a pore diameter value of 8 ?m or less, the pore diameter value corresponding to a ? value width of the maximum value.
    Type: Grant
    Filed: January 18, 2021
    Date of Patent: April 5, 2022
    Assignee: NGK Insulators, Ltd.
    Inventors: Fumihiko Yoshioka, Nozomu Hirai, Kyohei Kato
  • Patent number: 11118045
    Abstract: Provided area perfluoroelastomer composition containing a perfluoroelastomer and a compound having a perylene skeleton, in which the compound having a perylene skeleton is a compound other than perylene and 3,4,9,10-perylenetetracarboxylic acid diimide; and a sealing material containing a crosslinked product of the perfluoroelastomer composition.
    Type: Grant
    Filed: May 24, 2017
    Date of Patent: September 14, 2021
    Assignee: VALQUA, LTD.
    Inventors: Naoki Osumi, Kana Hirai
  • Patent number: 10857499
    Abstract: The plugged honeycomb structure includes a plurality of honeycomb segments, a bonding layer, and plugging portions which plug open ends of cells of each honeycomb segment, and in the honeycomb segment, at least two types of cells having different sectional shapes are formed to constitute predetermined repeated arrangement patterns, and in rim circumferential wall cells including rims of the cells surrounded with partition walls and segment circumferential walls, an inflow open area of each corner rim circumferential wall cell disposed in each corner portion of the honeycomb segment is 1.1 times or more as large as an average inflow open area of non-corner rim circumferential wall cells arranged in portions other than the corner portions, or an outflow open area of the corner rim circumferential wall cell is 1.1 times or more as large as an average outflow open area of the non-corner rim circumferential wall cells.
    Type: Grant
    Filed: September 14, 2017
    Date of Patent: December 8, 2020
    Assignee: NGK Insulators, Ltd.
    Inventors: Kazuya Mori, Mitsuhiro Ito
  • Patent number: 10765986
    Abstract: The plugged honeycomb structure includes a plurality of honeycomb segments, a bonding layer, and plugging portions which plug open ends of cells of each honeycomb segment, and in the honeycomb segment, at least two types of cells having different sectional shapes are formed to constitute predetermined repeated arrangement patterns, and a ratio of a value R2s obtained by dividing an average sectional area S2in of inflow cells by an average sectional area S2out of outflow cells in a partial rim circumferential wall cell region is in a range of 1.7 times or more and 2.0 times or less to a value R1s obtained by dividing an average sectional area S1in of the inflow cells by an average sectional area S1out of the outflow cells in a whole rim partition wall cell region.
    Type: Grant
    Filed: September 14, 2017
    Date of Patent: September 8, 2020
    Assignee: NGK Insulators, Ltd.
    Inventors: Kazuya Mori, Mitsuhiro Ito
  • Patent number: 10737230
    Abstract: The invention relates to a reactor for the catalytic production of methanol, in which at least two catalyst layers are arranged. The first catalyst layer is arranged upstream and the second catalyst layer is arranged downstream. The activity of the first catalyst layer is higher than the activity of the second catalyst layer.
    Type: Grant
    Filed: February 13, 2018
    Date of Patent: August 11, 2020
    Assignees: CLARIANT INTERNATIONAL LTD, L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE
    Inventors: Hannsjoerg Freund, Robert Frind, Tobias Henkel, Markus Kaiser, Timm Schuhmann, Wolfgang Seuffert, Sebastian Werner
  • Patent number: 10692634
    Abstract: An oxide superconductor of an embodiment includes an oxide superconductor layer having a continuous Perovskite structure including rare earth elements, barium (Ba), and copper (Cu). The rare earth elements include a first element which is praseodymium, at least one second element selected from the group consisting of neodymium, samarium, europium, and gadolinium, at least one third element selected from the group consisting of yttrium, terbium, dysprosium, and holmium, and at least one fourth element selected from the group consisting of erbium, thulium, ytterbium, and lutetium. When the number of atoms of the first element is N(PA), the number of atoms of the second element is N(SA), and the number of atoms of the fourth element is N(CA), 1.5×(N(PA)+N(SA))?N(CA) or 2×(N(CA)?N(PA))?N(SA) is satisfied.
    Type: Grant
    Filed: March 1, 2017
    Date of Patent: June 23, 2020
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takeshi Araki, Hirotaka Ishii, Nao Kobayashi
  • Patent number: 10679779
    Abstract: An oxide superconductor of an embodiment includes an oxide superconductor layer having a continuous Perovskite structure containing rare earth elements, barium (Ba), and copper (Cu). The rare earth elements contain a first element which is praseodymium (Pr), at least one second element selected from the group consisting of neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd), at least one third element selected from the group consisting of yttrium (Y), terbium (Tb), dysprosium (Dy), and holmium (Ho), and at least one fourth element selected from the group consisting of erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).
    Type: Grant
    Filed: February 21, 2017
    Date of Patent: June 9, 2020
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takeshi Araki, Hirotaka Ishii, Nao Kobayashi
  • Patent number: 10669247
    Abstract: A method for lowering the sodium content of different carriers which may have different physical properties as well as varying degrees of sodium is provided. The method, which lowers the sodium content from the surface, subsurface as well as the binding layer of the carrier, includes contacting a carrier with water. A rinse solution is recovered from the contacting. The rinse solution includes leached sodium from the carrier. The sodium content in the rinse solution is then determined. The contacting, recovering and determining are repeated until a steady state in the sodium content is achieved.
    Type: Grant
    Filed: September 11, 2017
    Date of Patent: June 2, 2020
    Assignee: Scientific Design Company, Inc.
    Inventors: Nabil Rizkalla, Andrzej Rokicki
  • Patent number: 10632496
    Abstract: A method of applying a non-homogenous catalyst coating to a surface is provided. The method may include partially masking the surface with a first template; applying a first washcoat slurry to those parts of the surface not masked by the first template; partially masking the surface with a second template; and applying a second washcoat slurry to those parts of the surface not masked by the second template.
    Type: Grant
    Filed: October 4, 2017
    Date of Patent: April 28, 2020
    Assignee: Ford Global Technologies, LLC
    Inventors: Paul Lindsey Rounce, Jon O'Neill
  • Patent number: 10607753
    Abstract: A method and composition for doped HTS tapes having directional flux pinning and critical current.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: March 31, 2020
    Assignees: University of Houston System, SuperPower, Inc.
    Inventors: Venkat Selvamanickam, Yimin Chen
  • Patent number: 10541073
    Abstract: A superconducting coil of an embodiment includes a superconducting wire including an oxide superconductor layer. The oxide superconductor layer has a continuous Perovskite structure including rare earth elements, barium (Ba), and copper (Cu). The rare earth elements include a first element which is praseodymium (Pr), at least one second element selected from the group consisting of neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd), at least one third element selected from the group consisting of yttrium (Y), terbium (Tb), dysprosium (Dy), and holmium (Ho), and at least one fourth element selected from the group consisting of erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).
    Type: Grant
    Filed: March 1, 2017
    Date of Patent: January 21, 2020
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takeshi Araki, Kenji Tasaki, Hirotaka Ishii
  • Patent number: 10386740
    Abstract: A resin binder composition for a toner, containing a polyester resin, which is a polycondensate of a polyethylene terephthalate, a carboxylic acid component, and an alcohol component, wherein the polyethylene terephthalate contains a polyethylene terephthalate having a IV value of 0.40 or more and 0.75 or less, and wherein the alcohol component contains an aliphatic diol having a hydroxyl group bonded to a secondary carbon atom having 2 or more carbon atoms and 4 or less carbon atoms in an amount of 40% by mol or more and 100% by mol or less, a method for producing a polyester resin contained in the resin binder composition, and a toner for electrophotography containing the resin binder composition. The resin binder composition for a toner of the present invention is suitably used in the toner for electrophotography usable in development or the like of latent images formed in, for example, method for electrostatic image development, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: August 2, 2016
    Date of Patent: August 20, 2019
    Assignee: Kao Corporation
    Inventor: Takashi Kubo
  • Patent number: 10287260
    Abstract: Provided is a material that, when compared with SAPd, exhibits the similar activity in cross-coupling (CC) reactions, can decrease the amount of catalytic metal that is mixed into the reaction product, and increases the number of times use can be repeated. Provided are a catalyst and a catalyst precursor that use a catalytic metal other than Pd and that exhibit the CC reaction activity similar to when Pd is used. Provided are a catalyst and a catalyst precursor that exhibit the similar CC reaction activity when using Pd or a catalytic metal other than Pd, without using a carrier such as metal and without using piranha solution. A composite wherein catalytic metal nanoparticles are dispersed in a continuous phase comprising a polymer having C2-6 alkylene group units and phenylene group units (an alkylene group unit being bonded to at least the first and fourth position of the phenylene group unit). The particle diameter of the catalytic metal nanoparticles is at most 20 nm.
    Type: Grant
    Filed: March 28, 2014
    Date of Patent: May 14, 2019
    Assignees: Japan Science and Technology Agency, Furuya Metal Co., Ltd.
    Inventors: Mitsuhiro Arisawa, Satoshi Shuto, Naoyuki Hoshiya, Satoshi Arai
  • Patent number: 10233091
    Abstract: The present invention is in the field of processes for the production of tantalum oxide particles. In particular the present invention relates to a process for producing crystalline tantalum oxide nanoparticles comprising heating a water-free solution containing (a) a tantalum alkoxide, (b) an acid, and (c) a solvent.
    Type: Grant
    Filed: January 26, 2016
    Date of Patent: March 19, 2019
    Inventors: Isabel van Driessche, Katrien De Keukeleere, Jonathan De Roo, Hens Zeger
  • Patent number: 10201805
    Abstract: A exhaust gas purification apparatus is provided with; a substrate having a wall-flow structure and including entry-side cells, exit-side cells, and a porous partition; a first catalyst region formed in small diameter pores having relatively small pore diameters among internal pores in the partition; and a second catalyst region formed in large diameter pores having relatively large pore diameters among the internal pores in the partition. The first catalyst region contains a support and any one or two species of precious metal selected from Pt, Pd, and Rh loaded on the support, while the second catalyst region contains a support and any one or two species of precious metal selected from Pt, Pd, and Rh loaded on the support and other than at least the precious metal present in the first catalyst region.
    Type: Grant
    Filed: October 6, 2015
    Date of Patent: February 12, 2019
    Assignee: CATALER CORPORATION
    Inventors: Tatsuya Ohashi, Shingo Sakagami, Tsuyoshi Ito, Ryota Onoe, Naoto Miyoshi, Masahiko Takeuchi, Akemi Sato
  • Patent number: 10183253
    Abstract: The exhaust gas purification device is provided with a wall flow structure substrate that has an entry-side cell, an exit-side cell and a porous partition, first catalyst parts which are formed in small pores having a relatively small pore diameter among internal pores in the partition, and second catalyst parts which are formed in large pores having a relatively large pore diameter among the internal pores in the partition. The first catalyst parts and the second catalyst parts each contain a carrier and at least one type of noble metal from among Pt, Pd and Rh supported on the carrier. The noble metal content in the first catalyst parts is smaller than the noble metal content in the second catalyst parts per 1 liter of substrate volume.
    Type: Grant
    Filed: October 6, 2015
    Date of Patent: January 22, 2019
    Assignee: CATALER CORPORATION
    Inventors: Ryota Onoe, Shingo Sakagami, Tsuyoshi Ito, Tatsuya Ohashi, Naoto Miyoshi, Masahiko Takeuchi, Akemi Sato
  • Patent number: 10179876
    Abstract: A nanocrystal particle including: a semiconductor material; boron and optionally fluorine, wherein the particle has an organic ligand bound to a surface thereof, the boron is present as being doped in the particle or as a metal boride and the fluorine is present as being doped in the particle or as a metal fluoride.
    Type: Grant
    Filed: February 4, 2015
    Date of Patent: January 15, 2019
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Shin Ae Jun, Yuho Won, Hyo Sook Jang, Eun Joo Jang
  • Patent number: 10173169
    Abstract: An electrocatalytic device for carbon dioxide conversion includes a cathode with a Catalytically Active Elementa metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO?, H2CO, (HCOO)?, HCOOH, CH3OH, CH4, C2H4, CH3CH2OH, CH3COO?, CH3COOH, C2H6, (COOH)2, (COO?)2, and CF3COOH.
    Type: Grant
    Filed: October 4, 2017
    Date of Patent: January 8, 2019
    Assignee: Dioxide Materials, Inc
    Inventor: Richard I. Masel
  • Patent number: 10124318
    Abstract: A precursor mixture for producing a porous body, wherein the precursor mixture comprises: (i) milled alpha alumina powder having a particle size of 0.1 to 6 microns, (ii) boehmite powder that functions as a binder of the alpha alumina powders, and (iii) burnout materials having a particle sizes of 1-10 microns. In some embodiments, an unmilled alpha alumina powder having a particle size of 10 to 100 microns is also included in said precursor mixture. Also described herein is a method for producing a porous body in which the above-described precursor mixture is formed to a given shape, and subjected to a heat treatment step in which the formed shape is sintered to produce the porous body.
    Type: Grant
    Filed: June 2, 2016
    Date of Patent: November 13, 2018
    Assignee: Scientific Design Company, Inc.
    Inventors: Wojciech L. Suchanek, Matthew Julian
  • Patent number: 9702676
    Abstract: Munitions structures comprising one or more high strength reactive alloys, in particular reactive bulk metallic glasses, have significant amounts of inherent chemical energy. This energy may be discharged by subjection of the munitions structure to rapid impulsive loading and fragmentation in the presence of oxygen and/or nitrogen. A munitions structure can be configured in both large and small penetrators, e.g. warheads and bullets, with increased lethality. The lethality of these munitions structures is augmented by means of rapidly and simultaneously imparting both mechanical energy (kinetic energy through impact and fragmentation) and chemical energy (blast and/or fireball) to a target. A high-strength reactive alloy can substitute at least in part one or both of explosives and inert structural materials in conventional munitions systems to improve performance and reduce parasitic weight of structural casing.
    Type: Grant
    Filed: October 14, 2016
    Date of Patent: July 11, 2017
    Assignee: Washington State University
    Inventors: Yogendra M. Gupta, Atakan Peker
  • Patent number: 9640689
    Abstract: The invention provides a polyester film for the protection of a back surface of a solar cell which, when applied to a silicon thin film solar cell, exhibits excellent durability even under high-temperature and high-humidity conditions and long term thermal stability. The polyester film (a) contains a polyester, as a main constituent, obtained by polymerization using a polycondensation catalyst containing aluminum and/or its compound as well as a phosphorus compound having an aromatic group in the molecule; (b) has a whiteness degree of 50 or higher; (c) contains 3 to 50% by mass of fine particles with a mean particle diameter of 0.1 to 3 ?m; and (d) has an acid value from not lower than 1 (eq/ton) and not higher than 30 (eq/ton).
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: May 2, 2017
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shiro Hamamoto, Yoshitomo Ikehata, Katsuya Ito, Jun Inagaki
  • Patent number: 9522389
    Abstract: Photocatalytic materials are described herein which include thin nanostructures. For example, the catalytic material can include a nanostructure that has a thin structure of a photocatalytic composition, wherein the thin structure is defined by a first surface and a second surface on opposite sides of the thin structure of the photocatalytic composition. The photocatalytic composition may include an inorganic compound, such as a titanium and/or stannous oxide. The first surface and a second surface may be relatively large as compared to the thickness of the thin structure, or the thickness of the nanostructure.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: December 20, 2016
    Assignee: NITTO DENKO CORPORATION
    Inventors: Ekambaram Sambandan, Rajesh Mukherjee, Takuya Fukumura, Amane Mochizuki
  • Patent number: 9388085
    Abstract: A titanium compound-containing core-shell powder includes a plurality of core-shell particles, each of which includes a core body and a shell layer encapsulating said core body. The core body is electrically conductive. The shell layer includes a crystal that is selected from titanate oxides having a perovskite structure and titanate oxides having a spinel structure. The core body and the shell layer are chemically bonded to each other.
    Type: Grant
    Filed: August 29, 2014
    Date of Patent: July 12, 2016
    Assignee: YAGEO CORPORATION
    Inventor: Masayuki Fujimoto
  • Patent number: 9331340
    Abstract: A catalytic ink preparation method comprises mixing a first ion conducting body and a catalyst, preparing a first ink, and concentrating the first ink. The method is characterized by further comprising a step of adding a second ion conducting body to the concentrated first ink. With such a catalytic ink preparation method, the quantity of solvent in the first ion conducting body is reduced by concentration. In other words, the first ion conducting body adheres to the catalyst, and re-dissolution is not prone to occurring with the first ion conducting body when the second ion conducting body is added. Thus, it is possible to efficiently manufacture an electrode catalyst in which a significant part of the surface of the catalyst is covered with two ionomer layers, and there is almost no portion which is covered with only one ionomer layer.
    Type: Grant
    Filed: August 14, 2012
    Date of Patent: May 3, 2016
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Kenichi Toyoshima, Norifumi Horibe, Takayuki Terasaki
  • Patent number: 9266095
    Abstract: A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of a catalyst comprising a modified support having cobalt and an alkaline earth support modifier. The active metals may include a first metal of palladium, platinum, and combinations thereof and a second metal of copper, iron, nickel, zinc, silver, chromium, tin, and combinations thereof.
    Type: Grant
    Filed: January 27, 2014
    Date of Patent: February 23, 2016
    Assignee: CELANESE INTERNATIONAL CORPORATION
    Inventors: Heiko Weiner, Zhenhua Zhou, Dick Nagaki
  • Patent number: 9040443
    Abstract: Catalysts and processes for forming catalysts for use in hydrogenating acetic acid to form ethanol. In one embodiment, the catalyst comprises a first metal, a silicaceous support, and at least one metasilicate support modifier. Preferably, the first metal is selected from the group consisting of copper, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium, platinum, titanium, zinc, chromium, rhenium, molybdenum, and tungsten. In addition the catalyst may comprise a second metal preferably selected from the group consisting of copper, molybdenum, tin, chromium, iron, cobalt, vanadium, tungsten, palladium, platinum, lanthanum, cerium, manganese, ruthenium, rhenium, gold, and nickel.
    Type: Grant
    Filed: June 12, 2013
    Date of Patent: May 26, 2015
    Assignee: Celanese International Corporation
    Inventors: Victor J. Johnston, Barbara F. Kimmich, John L. Potts, Heiko Weiner, Radmila Wollrab, James H. Zink, Josefina T. Chapman, Laiyuan Chen
  • Publication number: 20150140317
    Abstract: The present invention relates to the field of catalysts, and more specifically to nanoparticle catalysts. Materials with high porosity which contain nanoparticles can be created by various methods, such as sol-gel synthesis. The invention provides catalytic materials with very high catalytically active surface area, and methods of making and using the same. Applications include, but are not limited to, catalytic converters for treatment of automotive engine exhaust.
    Type: Application
    Filed: September 23, 2014
    Publication date: May 21, 2015
    Inventors: MAXIMILIAN A. BIBERGER, Bryant Kearl, Xiwang Qi, Qinghua Yin, David Leamon
  • Patent number: 9034274
    Abstract: The present invention relates to a vehicular air cleaner. A DOR (Direct Ozone Reduction) system for suppressing deterioration of a purifying function of an ozone purifying material is provided. Active oxygen is produced by an ozone purifying function of activated carbon. The probability that the active oxygen contacts with a fin of a radiator on a rear surface side is higher than that on a front surface side of the radiator. Accordingly, the activated carbon on the rear surface side of the radiator is easily oxidized as compared with the activated carbon on the front surface side. Therefore, in the fin, a coating amount of the activated carbon on the front surface side of the radiator is adjusted to be larger than a coating amount of the activated carbon on the rear surface side. Thus, the probability that the active oxygen contacts with the activated carbon can be reduced.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: May 19, 2015
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Yoshihisa Shinoda, Kazuhiro Sugimoto, Hiroaki Katsumata
  • Patent number: 9034787
    Abstract: A ceramic article may comprise a sintered phase ceramic composition comprising aluminum titanate (Al2TiO5), zirconium titanate (ZrTiO4), and a niobium-doped phase.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: May 19, 2015
    Assignee: Corning Incorporated
    Inventors: Heather Debra Boek, Matthew John Dejneka, Mark Owen Weller
  • Publication number: 20150118599
    Abstract: A method of fabricating composite filaments is provided. An initial composite filament including a core and a cladding (such as a Pt-group metal) is cut into smaller pieces (or is first mechanically reduced and then cut into smaller pieces). The smaller pieces of the filaments are inserted into a metal matrix, and the entire structure is then further reduced mechanically in a series of reduction steps. The process can be repeated until the desired cross sectional dimension of the filaments is achieved. The matrix can then be chemically removed to isolate the final composite filaments with the cladding thickness down to the nanometer range. The process allows the organization and integration of filaments of different sizes, compositions, and functionalities into arrays suitable for various applications.
    Type: Application
    Filed: February 24, 2014
    Publication date: April 30, 2015
    Inventor: Joze Bevk
  • Patent number: 9018122
    Abstract: The present invention includes a nanostructure, a method of making thereof, and a method of photocatalysis. In one embodiment, the nanostructure includes a crystalline phase and an amorphous phase in contact with the crystalline phase. Each of the crystalline and amorphous phases has at least one dimension on a nanometer scale. In another embodiment, the nanostructure includes a nanoparticle comprising a crystalline phase and an amorphous phase. The amorphous phase is in a selected amount. In another embodiment, the nanostructure includes crystalline titanium dioxide and amorphous titanium dioxide in contact with the crystalline titanium dioxide. Each of the crystalline and amorphous titanium dioxide has at least one dimension on a nanometer scale.
    Type: Grant
    Filed: March 3, 2010
    Date of Patent: April 28, 2015
    Assignee: The Regents of the University of California
    Inventors: Samuel S. Mao, Xiaobo Chen
  • Patent number: 9012345
    Abstract: Electrocatalysts for carbon dioxide conversion include at least one catalytically active element with a particle size above 0.6 nm. The electrocatalysts can also include a Helper Catalyst. The catalysts can be used to increase the rate, modify the selectivity or lower the overpotential of electrochemical conversion of CO2. Chemical processes and devices using the catalysts also include processes to produce CO, HCO?, H2CO, (HCO2)?, H2CO2, CH3OH, CH4, C2H4, CH3CH2OH, CH3COO?, CH3COOH, C2H6, (COOH)2, or (COO?)2, and a specific device, namely, a CO2 sensor.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: April 21, 2015
    Assignee: Dioxide Materials, Inc.
    Inventors: Richard I. Masel, Amin Salehi-Khojin
  • Patent number: 9006131
    Abstract: A composite oxide for an exhaust gas purification catalyst is provided which can burn PM in diesel engine exhaust gas at low temperatures and has a good S desorption property. The composite oxide for an exhaust gas purification catalyst is composed of Ce, Bi, Pr, R, and oxygen in a molar ratio of Ce:Bi:Pr:R=(1?x?y?z):x:y:z. The ratios of Ce, Bi, Pr, and R satisfy 0<x+y+z?0.5 and preferably 0<x?0.1, 0<y?0.25, and 0<z?0.3. Particularly, when R is Zr, the composite oxide exhibits a good S desorption property at a temperature of about 600° C. and can recover its catalytic activity at low temperatures. Therefore, the exhaust gas purification catalyst is suitable as a PM combustion catalyst.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: April 14, 2015
    Assignee: Dowa Electronics Materials Co., Ltd.
    Inventors: Yoshiyuki Michiaki, Yoshichika Horikawa
  • Patent number: 9005552
    Abstract: Provided is a new catalyst capable of removing carbon monoxide economically without adding particular reaction gas externally. Also provided are a process for producing and an apparatus using such a catalyst. Impregnation of a Ni—Al composite oxide precursor of a nonstoichiometric composition prepared by the solution-spray plasma technique with a ruthenium salt to be supported and performing reduction treatment allows CO methanation reaction to selectively proceed even in the high-temperature range in which CO2 methanation reaction and reverse water-gas-shift reaction proceed preferentially with conventional catalysts. Selective CO methanation reaction occurs reproducibly with another Ni—Al composite oxide precursor or an additive metallic species.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: April 14, 2015
    Assignee: University of Yamanashi
    Inventors: Masahiro Watanabe, Hisao Yamashita, Kazutoshi Higashiyama, Toshihiro Miyao, Aihua Chen
  • Patent number: 8999874
    Abstract: Provided is a carbon catalyst having an improved catalytic activity, a production method therefor, and an electrode and a battery which use the carbon catalyst. The carbon catalyst is obtained by carbonizing a raw material including an organic substance containing a nitrogen atom and metals, and includes iron and/or cobalt, and copper as the metals. Further, the carbon catalyst has a crystallinity of 41.0% or less, which is determined by X-ray diffractometry, a nitrogen atom-to-carbon atom ratio of 0.7 or more, which is determined by X-ray photoelectronic spectrometry, and an oxygen reduction-starting potential of 0.774 V (vs. NHE) or more.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: April 7, 2015
    Assignees: National University Corporation Gunma University, Nisshinbo Holdings Inc.
    Inventors: Takeaki Kishimoto, Mayumi Mizushiri, Jun-ichi Ozaki, Yusuke Sudo, Naokatsu Kannari
  • Patent number: 8999878
    Abstract: According to the present invention, an exhaust gas purifying catalyst is provided. The catalyst comprises a porous silica support comprising silica having a pore structure, and a perovskite-type composite metal oxide particle supported in the pore structure of the porous silica support. Further, the peak attributable to the space between silica primary particles is in the range of 3 to 100 nm in the pore distribution of the porous silica support.
    Type: Grant
    Filed: July 3, 2007
    Date of Patent: April 7, 2015
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Takeshima, Akio Koyama
  • Publication number: 20150093323
    Abstract: A system and methods for forming carbon allotropes are described. The system includes a reactor configured to use a catalyst to form a carbon allotrope from a feed stock in a Bosch reaction. The catalyst includes a roughened metal surface.
    Type: Application
    Filed: April 10, 2013
    Publication date: April 2, 2015
    Inventors: Russell J. Koveal, JR., Dallas B. Noyes, Terry A. Ring
  • Patent number: 8992879
    Abstract: A method of producing carbon fibers, in which the producing method comprises allowing a supported type catalyst and a carbon atom-containing compound to come in contact with each other in a heating zone, wherein the supported type catalyst is prepared by a method comprising impregnation of a powdery carrier with colloid containing catalyst to support particles of the catalyst on the powdery carrier having a specifically developed crystal plane such as a powdery carrier being 4 or more in the ratio (I1/I2) of the intensity I1 of the strongest peak to the intensity I2 of the second strongest peak observed in X-ray diffraction, or a powdery carrier having the ratio (I1/I2) of the intensity I1 of the strongest peak to the intensity I2 of the second strongest peak observed in X-ray diffraction of 1.5 times or more the ratio (I1s/I2s) of the intensity I1s of the strongest peak to the intensity I2s of the second strongest peak described in JCPDS.
    Type: Grant
    Filed: March 2, 2011
    Date of Patent: March 31, 2015
    Assignee: Showa Denko K.K.
    Inventors: Daisuke Miyamoto, Eiji Kambara
  • Patent number: 8987166
    Abstract: The preparation of bimetallic gold-silver cerium dioxide-supported catalysts and the process of oxidation of carbon monoxide (CO) in air to remove CO using the gold-silver cerium dioxide-supported catalysts are disclosed. The gold loading is between 0.5 and 5 wt. %. Gold and silver particle sizes are between 1 and 3 nm, and Au/Ag weight ratio is between 1 and 10. Oxidation of CO in air over these catalysts is carried out in a fixed bed reactor to remove CO.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: March 24, 2015
    Assignee: National Central University
    Inventors: Yu-Wen Chen, Wen-Ching Cheng
  • Publication number: 20150080605
    Abstract: What is described is a catalyst for preparation of an ?,?-unsaturated carboxylic acid by gas phase oxidation of an ?,?-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q ) ? S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an ?,?-unsaturated carboxylic acid by gas phase oxidation of an ?,?-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
    Type: Application
    Filed: September 16, 2014
    Publication date: March 19, 2015
    Applicant: BASF SE
    Inventors: Cathrin Alexandra WELKER-NIEUWOUDT, Cornelia Katharina Dobner, Holger Borchert, Ulrich Hammon, Josef Macht, Andrey Karpov, Christian Walsdorff
  • Patent number: 8980183
    Abstract: An apparatus for producing a catalyst comprising a tank configured to prepare an aqueous mixed solution containing a Mo compound, a V compound and a Nb compound, a dryer configured to spray-dry the aqueous mixed solution, and a pipe for connecting the tank with the dryer so that the aqueous mixed solution can be supplied from the tank to the dryer, wherein a heater configured to heat the aqueous mixed solution is provided in the tank and/or the pipe, and a filter configured to filtrate the aqueous mixed solution is provided in the pipe.
    Type: Grant
    Filed: December 13, 2011
    Date of Patent: March 17, 2015
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Takaaki Kato, Satoshi Endo, Minoru Kadowaki
  • Publication number: 20150064070
    Abstract: A catalyst filling apparatus is for a bubble column slurry bed reactor for the FT synthesis reaction. The apparatus includes: a slurry preparation tank installed adjacent to the reactor and configured to prepare a slurry S from a FT synthesis reaction catalyst and a slurry preparation oil; an upper part communication line configured to direct the slurry from the reactor to the slurry preparation tank; a lower part communication line configured to direct the slurry in the slurry preparation tank to the reactor; and a pressure equalizing line configured to communicate the reactor with the slurry preparation tank. The upper part communication line is downwardly inclined from the reactor toward the slurry preparation tank, and the lower part communication line is upwardly inclined from the reactor toward the slurry preparation tank. An inert gas introduction device is provided on the slurry preparation tank.
    Type: Application
    Filed: March 27, 2013
    Publication date: March 5, 2015
    Inventor: Kazuhiko Tasaka
  • Patent number: 8961892
    Abstract: Devices for selective hydrogenation of azide and peroxide compounds include at least one porous element, for example a solid metallic structure positioned within a reaction tube of a tubular housing. The porous element includes a framework of interconnected elements establishing a plurality of shells respectively defining a plurality of hollow spaces of predetermined geometrical configuration. Each of the shells includes holes that fluid-connect adjacent ones of the spaces to thereby allow a cross-flow of the azide or peroxide compounds through the porous element.
    Type: Grant
    Filed: June 14, 2010
    Date of Patent: February 24, 2015
    Assignee: DSM IP Assets B.V.
    Inventors: Cédric Hutter, Francesco Mascarello, Philipp Von Rohr Rudolf, David Ruppen
  • Publication number: 20150051369
    Abstract: The present invention provides methods for reducing induction periods in epoxide-CO2 copolymerizations. In certain embodiments, the methods include the step of contacting an epoxide with CO2 in the presence of two catalysts: an epoxide hydrolysis catalyst and an epoxide CO2 copolymerization catalyst. In another aspect, the invention provides catalyst compositions comprising a mixture of an epoxide hydrolysis catalyst and an epoxide CO2 copolymerization catalyst.
    Type: Application
    Filed: December 20, 2012
    Publication date: February 19, 2015
    Inventors: Scott D. Allen, Christopher A. Simoneau, William D. Keefe, Jeff R. Conuel
  • Patent number: 8956994
    Abstract: A composition is described that includes zirconium oxide, cerium oxide and yttrium oxide, or zirconium oxide, cerium oxide and at least two oxides of two rare earths different from cerium in a mass proportion of at least 20% of zirconium oxide and of at most 70% of cerium oxide, wherein the composition further includes, after calcination at 900° C. for 4 hours, two populations of pores having respective diameters centered, for the first population, about a value of 20 nm to 40 nm and, for the second, about a value of 80 nm to 200 nm. The composition can be used for processing exhaust gases of internal combustion engines.
    Type: Grant
    Filed: May 2, 2011
    Date of Patent: February 17, 2015
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Olivier Larcher
  • Patent number: 8952170
    Abstract: An improved catalytic process for the production of pyridine carboxylic acid amides, by catalytic hydration reaction of pyridine nitriles with solid heterogeneous catalyst wherein the process involve effective utilization and recycling of the catalytic components, and reactants.
    Type: Grant
    Filed: April 14, 2012
    Date of Patent: February 10, 2015
    Assignee: Jubilant Life Sciences, Ltd.
    Inventors: Mahendra Kumar, Shailendra Kumar Singh, Ashutosh Agarwal
  • Patent number: 8951932
    Abstract: A method of manufacturing a perovskite catalyst composed of perovskite oxide includes mixing step, firing step and acid-treating step. In the mixing step, an A-site material and a B-site material are mixed at a stoichiometric ratio such that the A-site is increased, compared to that of a theoretical composition ABO3 of perovskite oxide in which a ratio of A-site and B-site is 1:1. In the firing step, the obtained mixed powder is fired. In the acid-treating step, the obtained fired powder is acid-treated with acid of pH 2 or more and less than pH 7.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: February 10, 2015
    Assignee: Denso Corporation
    Inventors: Takeshi Yoshii, Tomohiko Nakanishi