Of Iron Patents (Class 502/338)
  • Patent number: 7935653
    Abstract: A metal oxide nanoporous material comprises two or more kinds of first metal oxides selected from the group consisting of alumina, zirconia, titania, iron oxide, rare-earth oxides, alkali metal oxides and alkaline-earth metal oxides. The metal oxide nanoporous material has nanopores, each with a diameter of 10 nm or smaller, in which the metal oxides are dispersed homogeneously in the wall forming the nanopores.
    Type: Grant
    Filed: June 9, 2005
    Date of Patent: May 3, 2011
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Takashi Shimazu, Ryusuke Tsuji, Hideo Sobukawa, Yoshiki Seno, Yoriko Hasegawa
  • Publication number: 20110091367
    Abstract: The present invention is directed to a granulate having photocatalytic activity, comprising particles of an inorganic particulate material coated with a photocatalytically active compound for introducing photocatalytic activity into or on building materials. The invention is further related to the manufacture of such a granulate and its use into or on building materials such as cement, concrete, gypsum and/or limestone and water-based coatings or paints for reducing an accumulation and growth of microorganisms and environmental polluting substances on these materials and thus reducing the tendency of fouling, while the brilliance of the colour is maintained and the quality of the air is improved.
    Type: Application
    Filed: March 31, 2008
    Publication date: April 21, 2011
    Inventors: Marino Sergi, Christian Egger
  • Patent number: 7928049
    Abstract: The present invention relates to the use of metal complex compounds having hydrazide ligands as oxidation catalysts. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands. The metal complex compounds are used especially for enhancing the action of peroxides, for example in the treatment of textile material, without at the same time causing any appreciable damage to fibers and dyeings. There is also no appreciable damage to fibers and dyeings if these metal complexes are used in combination with an enzyme or a mixture of enzymes.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: April 19, 2011
    Assignee: BASF SE Ludwigshafen
    Inventors: Barbara Wagner, Hauke Rohwer, Marie-Josée Dubs, Nicole End, Menno Hazenkamp, Sophie Marquais-Bienewald
  • Patent number: 7923615
    Abstract: The present invention relates to a catalyst system for the selective conversion of hydrocarbons into multi-walled carbon nanotubes and hydrogen comprising a compound of the formula: (Ni,Co)FeyOz(Al2O3)w wherein ‘y’ represents the molar fraction of Fe relative to Co and Ni and wherein 0.11?y?9.0, 1.12?z?14.5, and 1.5?w?64.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: April 12, 2011
    Assignee: Nanocyl S.A.
    Inventors: Ricardo Prada Silvy, Christophe Pirlot, Benedicte Culot
  • Patent number: 7923408
    Abstract: Diesel particulate filter that can lower the particulate matter (PM) combustion start temperature and use material containing silicon (Si) for a carrier. The carrier, which has a filter function, is allowed to support a perovskite-type complex oxide expressed by formula (1) as follows, wherein 0<x<0.7 and 0?y?1: formula (1)=La1-xBaxMnyFe1-yO3.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: April 12, 2011
    Assignees: Mitsubishi Jidosha Kogyo Kabushiki Kaisha, Dowa Electronics Materials Co., Ltd.
    Inventors: Masashi Takahashi, Hiroshi Tanada, Takuya Yano
  • Publication number: 20110081290
    Abstract: A gasifier for organic matter is provided in which a layer of ceramic balls function to both mill clinkers and catalyse hydrogen gas production. The ceramic balls comprise at least one catalyst suitable for lowering the activation energy of the various reactions involved in producing hydrogen gas. A process for production of a product gas comprising hydrogen is also provided.
    Type: Application
    Filed: February 17, 2010
    Publication date: April 7, 2011
    Inventor: Lyle E. Carnegie
  • Publication number: 20110076225
    Abstract: A hydrogen generator capable of operating in any orientation and having no moving parts includes a catalyst retaining structure. The catalyst retaining structure is disposed in a housing and serves to separate the housing into a fuel holding portion and a hydrogen chamber. The catalyst retaining structure also includes one or more pores, each pore being in communication with the fuel holding and hydrogen chambers. A catalyst, that promotes the generation of hydrogen gas upon contact with the fuel, is disposed within the pores. The fuel enters the pores and thereupon generates hydrogen gas which passes into the hydrogen chamber. Contact of the fuel with the catalyst in the pores may be controlled and the position of the fuel-hydrogen interface within the pore may be moved so as to regulate the generation of hydrogen. The catalyst retaining structure can take different forms, including one or more hollow elongated members or plates, and may further incorporate hydrophobic and/or hydrophilic membranes.
    Type: Application
    Filed: November 19, 2007
    Publication date: March 31, 2011
    Inventors: Shailesh A. Shah, Michael T. Kelly
  • Patent number: 7915196
    Abstract: A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: March 29, 2011
    Assignee: Alliance for Sustainable Energy, LLC
    Inventors: Yves O. Parent, Kim Magrini, Steven M. Landin, Marcus A. Ritland
  • Patent number: 7910518
    Abstract: A geometrically shaped solid carrier is provided that improves the performance and effectiveness of an olefin epoxidation catalyst for epoxidizing an olefin to an olefin oxide. In particular, improved performance and effectiveness of an olefin epoxidation catalyst is achieved by utilizing a geometrically shaped refractory solid carrier in which at least one wall thickness of said carrier is less than 2.5 mm.
    Type: Grant
    Filed: March 10, 2008
    Date of Patent: March 22, 2011
    Assignee: SD Lizenzverwertungsgesellschaft mbH & Co. KG
    Inventors: Serguei Pak, Andrzej Rokicki, Howard Sachs
  • Publication number: 20110058999
    Abstract: According to one embodiment, described herein is an exhaust gas after-treatment system that is coupleable in exhaust gas stream receiving communication with an internal combustion engine. The exhaust gas after-treatment system includes a low temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature below a temperature threshold. The system also includes a normal-to-high temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature above the temperature threshold.
    Type: Application
    Filed: September 10, 2010
    Publication date: March 10, 2011
    Applicant: CUMMINS IP, INC
    Inventors: Padmanabha Reddy Ettireddy, Matthew Henrichsen
  • Patent number: 7902104
    Abstract: This invention relates to a solid divided composition comprising grains whose mean size is greater than 25 ?m and less than 2.5 mm, wherein each grain is provided with a solid porous core and a homogeneous continuous metal layer consisting of at least one type of transition non-oxidised metal and extending along a gangue coating the core in such a way that pores are inaccessible. A method for the production of said composition and for the use thereof in the form of a solid catalyst is also disclosed.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 8, 2011
    Assignees: Arkema France, Institut National Polytechnique de Toulouse
    Inventors: Philippe Kalck, Philippe Serp, Massimiliano Corrias
  • Publication number: 20110053020
    Abstract: Nanostructured catalysts and related methods are described. The nanostructured catalysts have a hierarchical structure that facilitates modification of the catalysts for use in particular reactions. Methods for generating hydrogen from a hydrogen-containing molecular species using a nanostructured catalyst are described. The hydrogen gas may be collected and stored, or the hydrogen gas may be collected and consumed for the generation of energy. Thus, the methods may be used as part of the operation of an energy-consuming device or system, e.g., an engine or a fuel cell. Methods for storing hydrogen by using a nanostructured catalyst to react a dehydrogenated molecular species with hydrogen gas to form a hydrogen-containing molecular species are also described.
    Type: Application
    Filed: November 7, 2008
    Publication date: March 3, 2011
    Applicants: WASHINGTON STATE UNIVERSITY RESEARCH FOUNDATION, IDAHO RESEARCH FOUNDATION, INC.
    Inventors: M. Grant Norton, David N. McIlroy
  • Publication number: 20110039689
    Abstract: The present invention relates to a shaped catalyst body comprising a core and a first catalytically active layer arranged on sections of the core, characterized in that the total density of the core is greater than the total density of the catalytically active layer. The invention further relates to the use of said shaped catalyst body as an oxidation catalyst in the cleaning of exhaust gases or for reducing and decomposing nitrogen oxides and nitrous oxide.
    Type: Application
    Filed: April 21, 2008
    Publication date: February 17, 2011
    Inventors: Arno Tissler, Hans-Christoph Schwarzer, Roderik Althoff
  • Patent number: 7888283
    Abstract: A composition for catalyzing the auto-thermal reformation of ethanol, including a porous refractory substrate with a nickel-iron-aluminum oxide material at least partially filling the pores. The substrate is typically an alumina-based ceramic, such as gamma alumina or mullite. The catalyst composition is typically produced by identifying a refractory substrate having a relatively high surface area, such as through the existence of a pore network, infiltrating the refractory substrate with iron oxide and nickel oxide precursors, and combining the iron oxide and nickel oxide precursors with aluminum oxide to form a hybrid nickel-iron-aluminum oxide material at least partially coating the refractory substrate.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: February 15, 2011
    Inventors: Lihong Huang, Jian Xie
  • Publication number: 20110034329
    Abstract: A surface of a substrate comprising microcavities leading out of the substrate is placed in contact with an aqueous solution comprising a plurality of suspended particles and a fabric. Perpendicular pressure is applied the expanse of the substrate between the fabric and the surface of the substrate, and relative movement of the fabric and the surface is applied to the expanse of the substrate. At least one particle is thus fed into each microcavity, therein forming a porous material that is a catalyst material for nanothread or nanotube growth.
    Type: Application
    Filed: March 30, 2009
    Publication date: February 10, 2011
    Applicants: Commissariat A L'Energie Atomique Et Aux Energies Alternatives, STMicroelectronics (Crolles 2 ) SAS
    Inventors: Jean-Christophe Coiffic, Maurice Rivoire
  • Publication number: 20110028308
    Abstract: A method includes a providing a molten glass fiber core and disposing a plurality of nanoparticles that include a transition metal oxide on the molten glass fiber core at or above the softening temperature of the glass fiber core, thereby forming a nanoparticle-laden glass fiber. The plurality of nanoparticles are embedded at the surface of said glass fiber core. A method includes providing a mixture of molten glass and a plurality of nanoparticles. The plurality of nanoparticles include a transition metal. The method further includes forming nanoparticle-laden glass fibers, in which the plurality of nanoparticles are embedded throughout the glass fibers.
    Type: Application
    Filed: July 29, 2010
    Publication date: February 3, 2011
    Applicant: Lockheed Martin Corporation
    Inventors: Tushar K. SHAH, Harry C. Malecki
  • Publication number: 20110028311
    Abstract: A visible light activatable mesoporous titanium dioxide photocatalyst having a surface area of from 100 m2/g to 400 m2/g. The photocatalyst may have a rate of decomposition greater than 0.005 min?1. The photocatalyst may have a band gap width less than 2.95 eV. The photocatalyst may comprise undoped titanium dioxide or doped titanium dioxide. A hydrothermal process for synthesising a photocatalyst is also described.
    Type: Application
    Filed: March 9, 2009
    Publication date: February 3, 2011
    Applicant: DUBLIN INSTITUTE OF TECHNOLOGY
    Inventors: Vinodkumar Etacheri, Surresh C. Pillai, John Colreavy
  • Patent number: 7879756
    Abstract: A method of producing an iron catalyst for catalyzing the hydrogenation of carbon monoxide is disclosed. The method comprises using a reduced amount of acid for iron dissolution compared to certain previous methods. The resulting acidic iron mixture is heated without boiling to obtain a nitrate solution having a Fe2+:Fe3+ ratio in the range of about 0.01%:99.99% to about 100%:0% (wt:wt). Iron phases are precipitated at a lower temperature compared to certain previous methods. The recovered catalyst precursor is dried and sized to form particles having a size distribution between 10 microns and 100 microns. In embodiments, the Fe2+:Fe3+ ratio in the nitric acid solution may be in the range of from about 3%:97% to about 30%:70% (wt:wt) and the calcined catalyst may comprise a maghemite:hematite ratio of about 1%:99% to about 70%:30%.
    Type: Grant
    Filed: August 11, 2008
    Date of Patent: February 1, 2011
    Assignee: Rentech, Inc.
    Inventors: Belma Demirel, Charles B. Benham, Jesse W. Taylor, Pandurang V. Nikrad, Sara L. Rolfe, Olga P. Ionkina, Dawid J. Duvenhage, Harold A. Wright
  • Patent number: 7879759
    Abstract: DeNOx catalysts for the reduction of NOx compounds and porous catalyst support materials are provided. The inventive catalysts comprise an active metal catalyst component and mixed TiO2/ZrO2 porous support particles that comprise a) a crystalline phase comprising titanium dioxide and/or a titanium/zirconium mixed oxide, b) an amorphous phase comprising zirconium, and c) a small amount of one or more metal oxide(s) or metalloid oxide(s) deposited on the amorphous outer layer. The inventive catalysts exhibit superior activity and ammonia selectivity.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: February 1, 2011
    Inventors: Steve M. Augustine, Guoyi Fu, Mark Watson
  • Patent number: 7875251
    Abstract: An ozone-decomposing agent including a first iron compound and a second iron compound is provided. The second iron compound may have a spinel type structure. The first iron compound of the ozone-decomposing agent may include an oxide selected from Fe2O3, FeO(OH) or Fe(OH)3. The second iron compound of the ozone-decomposing agent may include an oxide selected from MnFe2O4, ZnFe2O4, NiFe2O4, CuFe2O4 or CoFe2O4.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: January 25, 2011
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventor: Kazuhiro Ueda
  • Publication number: 20100316547
    Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
    Type: Application
    Filed: May 20, 2010
    Publication date: December 16, 2010
    Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
  • Patent number: 7846864
    Abstract: New types of photocatalyst materials are disclosed together with methods for preparing and using these materials, as well as air treatment systems incorporating such materials. The photocatalyst materials of this invention consist essentially of very small particles of a first-metal oxide, the first-metal being a metal that exhibits photo-induced semiconductor properties, having ions of a second-metal dispersed throughout its lattice structure, the second-metal being selected from the group of dopant metals. Such photocatalyst materials are prepared by the steps of mixing first-metal and second-metal precursors, removing nonessential ions from the mixture, drying the resulting product, and calcinating the dried product to produce the completed photocatalyst material.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: December 7, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Dong Seok Ham, Son Ki Ihm, Joo Il Park, Kwang Min Choi, Kwang Eun Jeong
  • Patent number: 7846977
    Abstract: The present invention relates to a catalyst comprising a preferably oxidic, core material, a shell of zinc oxide around said core material, and a catalytically active material in or on the shell, based on one or more of the metals cobalt, iron, ruthenium and/or nickel, preferably a Fischer-Tropsch catalyst, to the preparation of such a catalyst and the use thereof in GTL processes.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: December 7, 2010
    Assignee: BASF Corporation
    Inventors: Cornelis Roeland Baijense, Geoffrey Johnson, Ahmad Moini
  • Publication number: 20100300984
    Abstract: Embodiments of the present disclosure relate to nanostructured carbon supported catalysts, methods of making nanostructured carbon supported catalysts, and methods of using nanostructured carbon supported catalysts.
    Type: Application
    Filed: May 27, 2010
    Publication date: December 2, 2010
    Inventors: James R. Kastner, Praveen Kolar
  • Patent number: 7842636
    Abstract: Compositions and methods for depositing one or more metal or metal alloy films on substrates. The compositions contain a catalyst, one or more carrier particles and one or more water-soluble or water-dispersible organic compounds. Metal or metal alloys may be deposited on the substrates by electroless or electrolytic deposition.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: November 30, 2010
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Peter R. Levey, Nathaniel E. Brese
  • Patent number: 7842634
    Abstract: A useful partial oxidation catalyst element includes a catalyst component, a support component, and a substrate. The catalyst component is formed by combining a catalytically active metal with a first support material to form a mixture and calcining the mixture. The support component is formed by calcining a second support material, not containing the active metal. The first and second support materials include particles having an average particle diameter of less than 20 microns. A catalyst material is formed by combining the catalyst component and the support component, wherein the catalyst material contains less than 20% of the catalyst component by weight. The catalyst material is applied to a substrate configured for gas flow therethrough, thereby formulating the partial oxidation catalyst element. The partial oxidation catalyst element is especially useful for fuel reforming and fuel cell applications.
    Type: Grant
    Filed: September 11, 2006
    Date of Patent: November 30, 2010
    Assignee: Umicore AG & Co. KG
    Inventors: Jeffrey G. Weissman, Ming-Cheng Wu
  • Patent number: 7838459
    Abstract: The present invention is related to single and/or multiple-wall carbon nanotubes which may contain interstitial metals obtainable by a preparation process, comprising a catalytic step using a catalytic system, said catalytic system comprising a catalyst and a support, said support comprising hydroxides and/or carbonates or mixtures thereof with or without metal oxides. The present invention is also related to carbon fibers obtainable by said preparation process. The present invention also pertains in particular to said catalytic system and to said preparation process. Another aspect concerns the use of the nanotubes and of the catalytic system according to the invention.
    Type: Grant
    Filed: July 20, 2009
    Date of Patent: November 23, 2010
    Assignee: Facultes Universitaires Notre-Dame De La Paix
    Inventors: Janos B. Nagy, Narasimaiah Nagaraju, Isabelle Willems, Antonio Fonseca
  • Patent number: 7833934
    Abstract: A hydrocarbon reforming catalyst, a method of preparing the same, and a fuel processor including the same includes the hydrocarbon reforming catalyst having an active catalyst component impregnated in a oxide carrier and a thermally conductive material having higher thermal conductivity than that of the oxide carrier, the method of preparing the same, and a fuel processor including the same. The hydrocarbon reforming catalyst has excellent catalytic activity and thermal conductivity, and thus can easily transfer heat required in a hydrocarbon reforming reaction. Accordingly, by using the hydrocarbon reforming catalyst above, a high hydrogen production rate can be obtained.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: November 16, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yulia Potapova, Soon-ho Kim, Doo-hwan Lee, Hyun-chul Lee
  • Patent number: 7833935
    Abstract: The present invention is directed to a process for the manufacture of iron oxide particles coated with crystalline titanium dioxide, wherein the process comprises the steps of adding an aqueous solution of at least one titanyl salt to an iron oxide dispersion to form a reaction mixture, precipitating titanium dioxide on said iron oxide particles by adding an alkali, wherein the titanium dioxide is at least partially in a crystalline form, and isolating the resulting titanium dioxide-containing iron oxide particles from the reaction mixture. The invention is further related to iron oxide particles comprising precipitated crystalline titanium dioxide and the use of the resulting photocatalytically active material.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: November 16, 2010
    Assignee: Rockwood Italia S.p.A.
    Inventors: Claudia Menini, Marino Sergi
  • Publication number: 20100284876
    Abstract: Low temperature activity and high temperature ammonia selectivity of a vanadium-free selective catalytic reduction catalyst are controlled with a mixed oxide support containing oxides of titanium and zirconium, and a plurality of alternating layers respectively formed of a metal compound and titanium oxide present on the surface of the mixed oxide support. The metal compound is selected from the group consisting of manganese oxide, iron oxide, cerium oxide, tin oxide, and mixtures thereof.
    Type: Application
    Filed: May 11, 2009
    Publication date: November 11, 2010
    Inventor: Steven M. Augustine
  • Publication number: 20100279012
    Abstract: A method for adsorbing a catalyst, including: a step of applying, to a substrate, a photocurable composition which contains a compound having a polymerizable group and a group that is interactive with a plating catalyst or a precursor thereof, and that, when photo-cured, forms a surface-hydrophobic cured material satisfying the following Requirements 1 and 2; a step of curing the curable composition by pattern-wise exposure, a step of removing uncured materials by development; and a step of bringing an aqueous plating catalyst solution containing a plating catalyst or a precursor thereof and an organic solvent into contact with the substrate, wherein when a palladium-containing test liquid is brought into contact with the substrate having the patterned surface-hydrophobic cured material layer formed thereon, A mg/m2 and B mg/m2, which respectively refer to a palladium adsorption in an area having the surface-hydrophobic cured material layer formed thereon and a palladium adsorption in an area not having the s
    Type: Application
    Filed: December 5, 2008
    Publication date: November 4, 2010
    Applicant: FUJIFILM CORPORATION
    Inventor: Masataka Sato
  • Patent number: 7825065
    Abstract: Particles for catalyst which have a function of absorbing and desorbing oxygen, the particles comprising an iron compound in which an element, other than Fe, having two valences is solid-soluted in an oxide of Fe having three valences, and a method for producing the particles for catalyst which comprises precipitating a precipitate containing Fe having three valences and an element, other than Fe, having two valences from a solution containing ions of Fe having three valences and ions of the element, other than Fe, having two valences, and drying and firing the precipitate to produce the particles.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: November 2, 2010
    Assignee: Denso Corporation
    Inventors: Miho Ito, Yasushi Hayashi
  • Patent number: 7825058
    Abstract: Compositions and methods for depositing one or more metal or metal alloy films on substrates. The compositions contain a catalyst, one or more carrier particles and one or more water-soluble or water-dispersible organic compounds. Metal or metal alloys may be deposited on the substrates by electroless or electrolytic deposition.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: November 2, 2010
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Peter R. Levey, Nathaniel E. Brese
  • Patent number: 7825064
    Abstract: A process for making a porous catalyst, comprises a) providing an aqueous solution containing a nanoparticle precursor, b) forming a composition containing nanoparticles, c) adding a first catalytic component or precursor thereof and a pore-forming agent to the composition containing nanoparticles and allowing the first catalytic component, the pore-forming agent, and the nanoparticles form an organic-inorganic structure, d) removing water from the organic-inorganic structure; and e) removing the pore-forming agent from the organic-inorganic structure so as to yield a porous catalyst.
    Type: Grant
    Filed: June 3, 2004
    Date of Patent: November 2, 2010
    Assignee: William Marsh Rice University
    Inventors: Michael S. Wong, Israel E. Wachs, William V. Knowles
  • Patent number: 7820583
    Abstract: A nanocomposite particle, its use as a catalyst, and a method of making it are disclosed. The nanocomposite particle comprises titanium dioxide nanoparticles, metal oxide nanoparticles, and a surface stabilizer. The metal oxide nanoparticles are formed hydrothermally in the presence of the titanium dioxide nanoparticles. The nanocomposite particle is an effective catalyst support, particularly for DeNOx catalyst applications.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: October 26, 2010
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Guoyi Fu, Steven M. Augustine
  • Patent number: 7816299
    Abstract: A stacked bed catalyst system comprising at least one first catalyst selected from conventional hydrotreating catalyst having an average pore diameter of greater than about 10 nm and at least one second catalyst comprising a bulk metal hydrotreating catalyst comprised of at least one Group VIII non-noble metal and at least one Group VIB metal and optionally a binder material.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: October 19, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gary P. Schleicher, Kenneth L. Riley
  • Patent number: 7811963
    Abstract: An elongated-shaped particle having two protrusions; each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, in which each of the six circles touches two neighboring circles and two alternating circles are equidistant to the central circle and may be attached to the central circle, and the two circles adjacent to the two alternating circles (but not the common circle) touching the central circle, minus the space occupied by the four remaining outer circles and including four remaining interstitial regions.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Hilbrand Klaver, Carolus Matthias Anna Maria Mesters, Gerardus Petrus Lambertus Niesen, Guy Lode Magda Maria Verbist
  • Patent number: 7811966
    Abstract: A catalyst, catalyst precursor, or catalyst carrier formed as an elongated shaped particle having a cross section comprising three protrusions each extending from and attached to a central position. The central position is aligned along the longitudinal axis of the particle. The cross-section of the particle occupies the space encompassed by the outer edges of six outer circles around a central circle, each of the six outer circles contacting two neighbouring outer circles, the particle occupying three alternating outer circles equidistant to the central circle and the six interstitial regions, the particle not occupying the three remaining outer circles which are between the alternating occupied outer circles. The ratio of the diameter of the central circle to the diameter of the outer occupied circle is more than 1, and the ratio of the diameter of the outer unoccupied circle to the diameter of the outer occupied circle is more than 1.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Hans Peter Alexander Calis, Guy Lode Magda Maria Verbist
  • Patent number: 7811967
    Abstract: A method of preparing, preferably recycling, a catalyst support material is disclosed and is particularly applicable to recycling a titania support. The invention includes crushing the used catalyst support that is obtained by leaching catalytic components from a used supported catalyst and preferably combining it with new catalyst support in order to provide the required average particle size and ratio of crystal phases. The invention has a number of benefits including making use of used catalyst support materials which have been conventionally disposed of and also providing a method to more efficiently recycle the active component. Where the support is recycled for a similar application, less promoter may be required.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Marinus Johannes Reynhout, Guy Lode Magda Maria Verbist
  • Publication number: 20100249252
    Abstract: Disclosed are solid titanium-free Fischer-Tropsch catalysts including iron homogeneously modified with a zirconium promoter/stabilizer. The homogeneously mixed solid catalysts can be formed through co-precipitation of iron and zirconium precursors followed by calcination and reduction to form the active catalyst materials. The catalysts can optionally include additional materials such as copper, potassium, and silicon promoters.
    Type: Application
    Filed: June 12, 2008
    Publication date: September 30, 2010
    Inventors: James G. Goodwin, JR., Edgar Lotero, Nattaporn Lohitharn
  • Patent number: 7803737
    Abstract: Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.
    Type: Grant
    Filed: June 6, 2008
    Date of Patent: September 28, 2010
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Paul R. Coronado, Sabre J. Coleman, Robert D. Sanner, Victoria L. Dias, John G. Reynolds
  • Patent number: 7803734
    Abstract: The present invention relates to a metal catalyst containing fine metal particles, characterized in that the fine metal particles have a particle diameter of 3 nm or less and also have a proportion of metallic bond state of 40% or more, which is ascribed by subjecting to waveform separation of a binding energy peak peculiar to the metal as measured by using an X-ray photoelectron spectrometer. The fine metal particles are preferably fine platinum particles. The fine metal particles are preferably supported on the surface of carrier particles by reducing ions of metal to be deposited through the action of a reducing agent in a reaction system of a liquid phase containing the carrier particles dispersed therein, thereby to deposit the metal on the surface of carrier particles in the form of fine particles. The proportion of metallic bond state of the fine metal particles is adjusted within the above range by reducing after deposition thereby to decrease the oxidation state.
    Type: Grant
    Filed: May 20, 2005
    Date of Patent: September 28, 2010
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Masatoshi Majima, Kohei Shimoda, Kouji Yamaguchi
  • Publication number: 20100239707
    Abstract: The present methods and compounds relate to increasing meat tenderness by inducing post-mortem breakdown in muscle tissue. This is achieved by the use of beta-blockers in the pre-mortem period, which results in higher calpastatin levels, and reduced hyperplasia. This is also achieved by the use of agents immediately before slaughter that induce apoptosis in muscle tissue. This is further achieved by administering agents that induce muscle fiber fission.
    Type: Application
    Filed: October 9, 2008
    Publication date: September 23, 2010
    Inventors: David Goldberg, Keith E. Belk, Phillip D. Bass, Hyungchul Han, Joseph D. Tatum, Gary L. Mason
  • Patent number: 7799729
    Abstract: In one embodiment, a reforming catalyst can include indium, tin, and a catalytically effective amount of a group VIII element for one or more reforming reactions. Typically, at least about 25%, by mole, of the indium is an In(3+) species based on the total moles of indium after exposure for about 30 minutes in an atmosphere including about 100% hydrogen, by mole, at a temperature of about 565° C. Usually, no more than about 25%, by mole, of the tin is a Sn(4+) species based on the total moles of tin after exposure for about 30 minutes in an atmosphere including about 100% hydrogen, by mole, at a temperature of about 565° C.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: September 21, 2010
    Assignee: UOP LLC
    Inventors: Gregory J. Gajda, Mark Paul Lapinski, Jeffry Thurston Donner, Simon Russell Bare
  • Patent number: 7799732
    Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: September 21, 2010
    Assignee: Showa Denko K.K.
    Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi, Hiroyuki Hagihara
  • Patent number: 7799727
    Abstract: A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: September 21, 2010
    Assignee: UOP LLC
    Inventors: Dean E. Rende, James E. Rekoske, Jeffery C. Bricker, Jeffrey L. Boike, Masao Takayama, Kouji Hara, Nobuyuki Aoi
  • Publication number: 20100233053
    Abstract: A method is provided. The method comprises reacting a reactive solution and a templating agent to form a gel; and calcining the gel to form a catalyst composition comprising homogeneous solid mixture. The homogenous solid mixture contains (i) at least one catalytic metal and (ii) at least one metal inorganic network. The templating agent comprises an octylphenol ethoxylate having a structure [I]: wherein “n” is an integer having a value of about 8 to 20. A catalyst composition prepared using the templating agent having a structure [1] is also provided.
    Type: Application
    Filed: May 28, 2010
    Publication date: September 16, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Ashish Balkrishna Mhadeshwar, Ming Yin
  • Publication number: 20100234211
    Abstract: A method of manufacturing a catalyst for catalyzing hydrogen releasing reaction includes following steps. First, a solution with metal catalyst ions is provided. Next, several catalyst supports are provided. Each catalyst support includes several chelating units. Then, the catalyst supports are mixed with the solution, so that the metal catalyst ions in the solution chelate with the chelating units on the surface of each catalyst support. Subsequently, the metal catalyst ions chelating with the surface of the catalyst supports are reduced, so that metal catalyst nano-structures and/or metal catalyst atoms are coated on the surface of the catalyst supports, for forming catalysts.
    Type: Application
    Filed: May 27, 2009
    Publication date: September 16, 2010
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Chan-Li Hsueh, Jie-Ren Ku, Shing-Fen Tsai, Ya-Yi Hsu, Cheng-Hong Liu, Ming-Shan Jeng, Fanghei Tsau
  • Patent number: 7790648
    Abstract: The invention relates to a process for preparing a catalyst. The process allows the delamination of layered crystals which are used as a starting material for a catalyst. The starting material is subsequently converted into an active portion of a catalyst with an increased dispersion resulting in a higher activity. Preferred delaminating agents are di-carboxylic acids and one particular example is citric acid. Preferably at least 0.75 wt %, more preferably at least 1.5 wt % of a delaminating agent is added to the catalyst starting material.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: September 7, 2010
    Assignee: Shell Oil Company
    Inventors: Ronald Jan Dogterom, Robert Martijn Van Hardeveld, Marinus Johannes Reynhout, Bastiaan Anton Van De Werff
  • Publication number: 20100222214
    Abstract: A process and apparatus for producing chain agglomerations of nano-scale metal particles includes feeding at least one decomposable moiety selected from the group consisting of organometallic compounds, metal complexes, metal coordination compounds and mixtures thereof into a reactor vessel; exposing the decomposable moiety to a source of energy sufficient to decompose the moiety and produce nano-scale metal particles; and deposit or collection of chain agglomerations of nano-scale metal particles.
    Type: Application
    Filed: May 14, 2010
    Publication date: September 2, 2010
    Inventor: Robert A Mercuri