Abstract: A method for producing a core-shell hybrid material made of an activated carbon core surrounded by a mesoporous silica sol-gel shell, the method including the formation of a mesoporous silica sol-gel shell around activated carbon particles. Also, the core-shell hybrid material formed by the method, and its use as a filtering material in filtering systems.

Abstract: There is provided herein a method for preparing a graphene oxide (GO) hydrogel. The method comprises the steps of adding vitamin C (VC) to a dispersion GO in a ratio GO:VC varying from 1:50 to 1:300; and incubating at a temperature above 45° C., preferably at 95° C. the dispersion for a time sufficient for a porous hydrogel to be self-assembled from the dispersion. CNPs can also be added to the hydrogel in a ratio GO:CNPs from 4:1 to 1:1. There is also provided the hydrogel so obtained and its use for removing contaminants from a fluid. The hydrogel can also be used as a filter for such decontamination.

Abstract: A method of forming a structured adsorbent sheet is provided. The method includes, combining a nano-adsorbent powder and a binder material to form an adsorbent material, and sandwiching a porous electrical heating substrate between two layers of adsorbent material. The nano-adsorbent powder may be a nano-particle adsorbent. The nano-adsorbent powder may be selected from the group consisting of crystal zeolite, activated carbon, activated alumina, silica gel, and metal organic framework (MOF).

Abstract: An adsorbent for removing compounds from a fluid comprising chitosan and one or more additional materials to enable selectivity of compounds removed. A chitosan based adsorbent is functionalized and cross linked to a predetermined degree to enhance its capacity and selectivity for various molecules and/or ions.

Abstract: Provided is a chromatographic medium capable of separating and detecting target substances without the use of other components. A chromatographic medium having a separating agent layer, which is used to separate target substances, a filling agent layer, which is used to fix the target substances before the target substances are separated, and a permeation layer, which is used to enable permeation of the target substances separated by the separating agent layer, wherein the filling agent layer comes into contact with the separating agent layer via a plane that intersects the direction of development of the target substances in the chromatographic medium and is positioned on the upstream side in the direction of development, the separating agent layer exhibits separability of the target substances and exhibits optical responsiveness to ultraviolet rays, and the permeation layer exhibits optical responsiveness that are different from those of the target substances and the separating agent layer.

Abstract: Provided is a chromatographic medium having a separating agent layer, which is used to separate target substances, and a permeation layer, which is laminated so as to face the separating agent layer and which is used to enable permeation of the target substances separated by the separating agent layer, wherein a region in which the permeation layer is not laminated is present on a part of the separating agent layer, the separating agent layer exhibits separating property for the target substances and exhibits optical responsiveness to ultraviolet rays, and the permeation layer exhibits optical responsiveness that are different from those of the target substances and the separating agent layer.

Abstract: Disclosed are porous-shell particles, methods of making the particles, and uses thereof. In one aspect, the porous-shell particles are superficially porous particles.

Abstract: The invention is directed to shaped composite adsorbent material, comprising particulate activated carbon material, bound by a suitable binder, preferably selected from the group of sodium alginate calcium alginate, chitosan, polyacrylamide, polyethylene oxide and mixtures thereof, more in particular a combination of chitosan and alginate, whereby the activation of the carbon material has taken place before binding the material.

Abstract: A scavenger support and a process for removing metal from solution by contacting the solution with the scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution. The scavenger support is a functionalised support having pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof having a structure according to formula 1, wherein a number of the pendant groups are reacted with an amine: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group.

Abstract: The present invention relates to a cryogel which contains a polyol selected from polyvinyl alcohol or galactomannan and a co-polymer of Formula I: The cryogel is formed by mixing the monomers of the co-polymer of Formula I at a temperature of less about 5 degrees C. with the polyol and a free radical initiator in an aqueous solution and polymerizing the solution to form the cryogel. The cryogel is used for culturing cells and can be decomposed by contact with a monosaccharide.

Abstract: Provided in one embodiment is a method of making an aerogel, comprising: (A) increasing a concentration of a suspension comprising a gel precursor under a condition that promotes formation of a gel, wherein the gel precursor comprises particulates having an asymmetric geometry; and (B) removing a liquid from the gel to form the aerogel, wherein the aerogel and the gel have substantially the same geometry. An aerogel comprising desirable properties are also provided.

Abstract: Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.

Abstract: Improved polisiloxane composite barrier to control, preventing the ingress, limiting the level of H2O within devices sensitive to its presence, method for its production, sensitive devices employing such barriers for the control of the H2O level within.

Abstract: Interlayer insulating films 5,7 (insulating films) provided in a memory capacitor cell 8 are formed between a gate electrode 3 and a counter electrode 8C formed on a silicon wafer 1. The interlayer insulating films 5,7 comprise a borazine-based resin, having a specific dielectric constant of no greater than 2.6, a Young's modulus of 5 GPa or greater and a leak current of no greater than 1×10?8 A/cm2.

Abstract: The oxine ligands 5-chloro-8-hydroxyquiniline and 5-sulfoxyl-8-hydroxyquinoline are covalently bound, using, for example, the Mannich reaction, to a silica gel polyamine composite made from a silanized amorphous silica xerogel and polyallylamine. The resulting modified composites, termed CB-1 (X?Cl) and SB-1 (X?SO3H), respectively, show a clear selectivity for trivalent over divalent ions and selectivity for gallium over aluminum. The compounds of the invention can be applied for the sequestration of metals, such as heavy metals, from contaminated mine tailing leachates.

Abstract: Provided is a composite adsorbent material and a method for preparing the same. The composite adsorbent material comprises a porous host material of activated carbon impregnated with silica-gel and calcium chloride, and is useful for adsorbing high levels of water vapor. The composite adsorbent material is used in low temperature heat driven adsorption cooling and dehumidification systems.

Abstract: A silicate-resistant sorbent composition, as well as a method of making and using the same, is provided. The sorbent composition generally comprises a support component comprising one or more silicate-resistant silica-containing components that have been treated one or more silicate-inhibiting metals. The inventors have discovered that sorbent compositions made and used according to embodiments the present invention exhibit a surprisingly low in situ silicate generation rate when exposed to oxidative regeneration conditions.

Abstract: A phosphorus compound adsorbent; a phosphorus compound adsorption system, wherein the phosphorus compound adsorbed can be desorbed in a neutral solvent; and a method of using the phosphorus compound adsorbent are provided. The phosphorus compound adsorbent includes a nitrogen-containing compound having an amino group at an end of the molecular structure, a support carrying the nitrogen-containing compound, and at least one metal ion selected from the group consisting of a zinc ion, a copper ion, an iron ion, and a zirconium ion, which is fixed to the nitrogen-containing compound.

Abstract: A solid air filtration medium includes an impregnate with an organic amine and an inorganic metal salt. The medium has from about 0.1 to about 25% by weight of impregnate. The impregnate contains from about 0.1 to about 5% by weight organic amine, and the organic amine includes aqueous urea, solid urea, melamine or mixtures thereof. The impregnate contains from about 0.1 to about 5% by weight metal salt, and the metal salt includes magnesium oxide, calcium oxide or mixtures thereof. The impregnate optionally further includes a surfactant such as polyacrylic acid. Methods for forming a solid air filtration medium having an impregnate containing an organic amine and an inorganic metal salt and methods for removing contaminants from a fluid stream are also provided.

Abstract: Disclosed herein are manganese, iron, cobalt, or nickel complexes containing terdentate pyridine diimine ligands and their use as efficient and selective hydrosilylation catalysts.

Abstract: An air purification device that is decorative and effective in removing contaminants from indoor air. The air purification device includes a carbon matrix composite.

Abstract: Methods of making unique water treatment compositions are provided. In one embodiment, a method of making a doped metal oxide or hydroxide for treating water comprises: disposing a metal precursor solution and a dopant precursor solution in a reaction vessel comprising water to form a slurry; and precipitating the doped metal oxide or hydroxide from the slurry.

Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.

Abstract: A pressed sorbent form includes a sorbent and a binder. The sorbent is chosen from the group including silica gel, molecular sieve, activated carbon, and clay. The binder is powdered ethyl vinyl acetate.

Abstract: An air purification device that is decorative and effective in removing contaminants from indoor air. The air purification device includes a carbon matrix composite.

Abstract: The present invention relates to a structure having a core-shell configuration. The core comprises a predetermined adsorber solid material, and the shell at least partially surrounding the core comprises a predetermined humidity controlling material, thereby enabling using said adsorber solid material for interacting with and thus storing therein a predetermined adsorbable gas under desired environmental conditions. The invention also discloses a pressure vessel for use in storing at least one gas.

Abstract: The disclosed sorbents are for adsorbing sulfur compounds, particularly sulfur-containing aromatic compounds, from liquid hydrocarbon fuels such as gasoline, cracked gasoline, diesel, high sulfur liquid fossil fuels, ultra-low sulfur fuel (ULSF) in fuel cell applications, and mixtures thereof. The sorbent compositions comprise one or more silicates having one or more metal nitrates admixed together. The one or more metal nitrates include iron (II) or (III), zinc (II), cadmium (II) and mercury (II) nitrate. The method of preparing and using the sorbents is also provided.

Abstract: A reduced puffing needle coke is formed, which includes a lesser amount of nitrogen within the coke so that carbon articles produced from such coke experience minimal expansion upon heating to graphitization temperatures.

Abstract: A reduced puffing needle coke is formed, which includes a reduced nitrogen content within the coke so that the coke particles do not experience as much puffing during the formation of graphitized carbon articles produced from such coke upon heating to graphitization temperatures.

Abstract: A reduced puffing needle coke is formed from decant oil, which includes a lesser amount of nitrogen within the coke so that carbon articles produced from such coke experience minimal expansion upon heating to graphitization temperatures.

Abstract: Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Abstract: A column 1 for removing an interfering substance to an analysis of polychlorinated biphenyls contained in an oily liquid such as an electric insulating oil from the oily liquid, includes a first column 10 packed with a multilayer silica gel 13 in which an upper layer 14 of a sulfuric acid silica gel is stacked on a lower layer 15 of a nitrate silica gel and a second column 20 connected to the lower layer 15 side of the column 10 and packed with an alumina layer 23. The nitrate silica gel of the lower layer 15 is produced by treating an activated silica gel with a mixed aqueous solution of copper nitrate and silver nitrate, wherein the ratio by mole of the copper element to the silver element (the copper element : the silver element) is preferably from 1:0.5 to 2.0.

Abstract: The invention relates to an adsorber element and to a method for the production thereof, comprising a carrier material (1) on which adsorbent particles (3) are arranged as the adsorber layer using a binding agent (2). According to the invention, the adsorber layer comprises inorganic fibers (4) and the binding agent (2) is designed as a colloid.

Abstract: Formulations useful for preparing hydrous cerium oxide gels contain a metal salt including cerium, an organic base, and a complexing agent. Methods for preparing gels containing hydrous cerium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including cerium, an organic base, and a complexing agent.

Abstract: Formulations useful for preparing hydrous hafnium oxide gels contain a metal salt including hafnium, an acid, an organic base, and a complexing agent. Methods for preparing gels containing hydrous hafnium oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including hafnium, an acid, an organic base, and a complexing agent.

Abstract: A separation membrane complex where a carbon membrane is formed directly on a porous body (surface layer) and an intermediate layer has a thickness of 10 to 100 ?m can be used as a filter having improved flux and selectivity in comparison with a conventional one.

Abstract: A composite sorbent material is disclosed which comprises A) a housing of a dense, insoluble material having openings therein and B) a porous polymer gel housed within said housing, said housing being provided with openings therein for fluid communication between said porous monolithic polymer gel and the surroundings, and said porous monolithic polymer gel occupying the inner space of said housing and being kept on place within said housing by mechanical means. Processes for the preparation of composite sorbent materials by cryoprecipitation are also disclosed as well as the use of the composite sorbent material according to the invention e.g. for the removal of pollutants from gases or liquids, for the enrichment or separation of molecules and for cell culture.

Abstract: Disclosed is a novel adsorbent for use in a 99Mo/99mTc generator, which is a medical diagnostic radioisotope generator, and in a 188W/188Re generator, which is a therapeutic radioisotope generator. The adsorbent composed of sulfated alumina or alumina-sulfated zirconia exhibits adsorption capacity superior to that of conventional adsorbents, and is stable and is thus loaded in a dry state in an adsorption column so that the radioisotope 99Mo or 188W can be adsorbed. Thus, it is possible to miniaturize the column, and such a miniaturized column is small, convenient to use, and highly efficient, and extracts a radioisotope satisfying the requirements for pharmaceuticals, and thus can be useful for radioisotope generators extracting 99mTc or 188Re.

Abstract: A nanopore reactive adsorbent composite material, which may be a porous adsorbent comprising a chemically surface face modified gel, has a composition and micro structure, which integrals ion exchange components such as hydroxy apatite.

Abstract: A mesoporous silica thick-film comprising a layer of mesoporous silica formed in a thickness of 10 ?m to 1 mm, and a process for producing a mesoporous silica thick-film, which comprises disposing a substrate in a solution containing mesoporous silica suspended therein and subsequently applying a voltage thereby to form a film having a thickness of 10 ?m to 1 mm by the electrophoretic deposition of the mesoporous silica on a surface of the substrate is provided.

Abstract: The formation of cracks is suppressed in a drying process for a water-containing wet gel without modifying the gel and without using a reagent. A water-containing wet gel is dried by removing water and then removing the remaining solvent. For example, a wet-gel container storing water-containing wet gel, containing a wet gel and a solvent, is heated. The solvent is vaporized into an upper space of the wet-gel container. The solvent-containing gas diffuses into a dehydrating agent container, and water is removed by a dehydrating agent. This state is maintained for one to two days to remove almost all amount of water from the solvent. Thereafter, the dehydrating agent container is detached and the wet gel, from which water has been removed, is heated to almost completely remove the solvent, and further heated at a higher temperature to completely remove the solvent to obtain a crack-free dry gel.

Abstract: A silicate-resistant sorbent composition, as well as a method of making and using the same, is provided. The sorbent composition generally comprises a support component comprising one or more silicate-resistant silica-containing components that have been treated one or more silicate-inhibiting metals. The inventors have discovered that sorbent compositions made and used according to embodiments the present invention exhibit a surprisingly low in situ silicate generation rate when exposed to oxidative regeneration conditions.

Abstract: The subject of the present invention is to provide a method for producing a silica gel supporting a derivatizing agent for a carbonyl compound that hardly collects carbonyl compounds during production thereof, and a silica gel supporting a derivatizing agent for a carbonyl compound produced by said production method, in order to lower a blank value in measurement of carbonyl compounds.

Abstract: The invention provides a modified adsorbent material impregnated with a metal oxide, which can be used in a filter element adapted for use in a smoking article. The modified adsorbent material exhibits increased filtration efficiency with respect to certain gas phase species of mainstream cigarette smoke. Exemplary adsorbent materials that can be modified according to the invention include activated carbon, molecular sieves, clays, ion exchange resins, activated aluminas, silica gels, meerschaum, and mixtures thereof. One example of a metal oxide is cerium oxide. Impregnation with a metal oxide can be accomplished by directly treating the adsorbent with a metal oxide or impregnating the adsorbent with a metal oxide precursor, such as cerium nitrate, followed by calcining the impregnated material to convert the precursor to the desired metal oxide. Methods of forming the modified adsorbent material and smoking article filters incorporating the modified adsorbent material are also provided.

Abstract: The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof.

Abstract: A column 1 is formed which includes a first column 10 in which an upper layer 14 made of sulfuric acid silica gel and a lower layer 15 made of silver nitrate silica gel are stacked and packed and a second column 20 packed with an alumina layer 23 and connected detachably to the lower end part of the first column 10. An oily liquid containing polychlorinated biphenyls, such as an electric insulating oil, is added to the upper layer 14 and then kept for a predetermined time in a state heated to at least 35° C. An aliphatic hydrocarbon solvent such as n-hexane is supplied to the upper layer 14 having been cooled to ordinary temperature. As a result, polychlorinated biphenyls captured by the first column 10 are dissolved in the aliphatic hydrocarbon solvent and then flows to the second column 20. The polychlorinated biphenyls are captured by that part of the alumina layer 23 which is located near the inlet of the second column 20. The second column 20 is then detached from the first column 10.

Abstract: An insert for sports gear and footwear has a compliant casing formed of fabric sheeting that incorporates regions of fused or otherwise integral regions of activated carbon. A desiccant such as silica gel in the form of spheroidal beads or other granules is loosely enclosed inside of the casing. The activated carbon has an affinity for odor-causing constituents such as organic compounds, and extracts airborne odor-causing constituents as air enters the casing. Inside the casing, the desiccant extracts airborne water vapor. The two-stage removal of odor-causing constituents and water vapor rapidly and effectively extracts moisture and odors. The silica gel and activated carbon are porous and have high surface areas available for adsorption, whereby the insert is adapted to maintain moisture and odors at low levels during long-term storage.

Abstract: Disclosed herein are a method of preparing Li-doped silica nanotubes using an anodic aluminum oxide (AAO) template, and a method of storing energy using the prepared Li-doped silica nanotubes. Unlike prior methods for preparing metal nanotubes, according to the disclosed preparation method, the Li-doped silica nanotubes having a uniform size can be easily obtained in mild conditions using a lithium precursor, a silica sol and an anodic aluminum oxide template. The preparation method comprises adsorbing the lithium precursor and the silica sol on the surface of the AAO template, drying the lithium precursor and the silica sol, adsorbed onto the AAO template, in a vacuum, to form nanotubes, and then drying the nanotubes. The Li-doped silica nanotubes prepared according to the disclosed method can be used as economical hydrogen storage materials, electrode materials for lithium secondary batteries, or energy storage sources for automobiles or other transportation means.

Abstract: Media for selectively removing radium ions from water where manganese oxide (DMO) has been dispersed in a cation ion exchange resin (gel or macroporous) to adsorb radium ions. The media is manufactured by precipitating a soluble manganese (II) salt such as manganous sulfate with a permanganate salt such as sodium permanganate inside a strong acid cation (SAC) to form a resin containing highly dispersed manganese oxides. The resin is then post treated with a reducing agent such as sodium metabisulfite (Na2S2O2) to prevent the leaching of soluble manganese from the resin. The reducing treatment ensures that soluble manganese species will be converted into an insoluble oxide form.

Abstract: A method of preparing an ionic conducting gel in solid form, known as ionogel. The method includes a step of mixing an ionic liquid with at least one molecular precursor containing at least one hydrolyzable group, if necessary in the presence of an acid, such as a carboxylic acid. The mixture is subsequently left to stand for one or more days until a gel is formed by polycondensation of the molecular precursor(s). The gel contains the aforementioned ionic liquid and can be set, in particular in transparent monolithic solid form.