Silicon Containing Patents (Class 502/407)
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Publication number: 20090247394Abstract: A honeycomb structure includes adhesive layers and plural honeycomb units bonded to each other by interposing the adhesive layers between the plural honeycomb units. Each of the honeycomb units has partition walls extending along a longitudinal direction of the honeycomb units to define plural through holes. The plural honeycomb units include a SOx absorbent, inorganic particles, and an inorganic binder. An expression Y??0.3X+1.55 (about 1.0?X?about 2.5) is satisfied, in which X represents a content (mol/L) of the SOx absorbent in the partition walls and Y represents a ratio B/A in which A represents a Young's modulus of the honeycomb units and B represents a Young's modulus of the adhesive layers.Type: ApplicationFiled: October 7, 2008Publication date: October 1, 2009Applicant: IBIDEN CO., LTD.Inventors: Masafumi KUNIEDA, Mari Kitajima
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Patent number: 7595276Abstract: The present invention provides a catalytic composition for oxychlorination excellent in the fluidity, the capability of suppressing lowering of the fluidity, and the attrition resistance as well as in the selectivity for EDC and the capability of suppressing combustion of ethylene. The catalytic composition for oxychlorination contains silica alumina particles in the range from 5 to 40 wt % when expressed as an oxide thereof, copper in the range from 5 to 20 wt % when expressed as an oxide thereof (CuO), and alumina as a carrier in the range from 40 to 90 wt % when expressed as that of Al2O3. The silica alumina particles are prepared by coating silica particles with alumina, and have the average particle diameter in the range from 3 to 100 nm. A content of alumina in the silica alumina particles is in the range from 0.1 to 10 wt %.Type: GrantFiled: July 29, 2008Date of Patent: September 29, 2009Assignee: JGC Catalysts and Chemicals Ltd.Inventors: Takashi Kodama, Tsuguo Koyanagi
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Patent number: 7588630Abstract: A carbon dioxide absorbent includes lithium silicate containing lithium orthosilicate and lithium metasilicate, the lithium metasilicate being contained in an amount of 5% by weight or more to 40% by weight or less with respect to the total amount of lithium orthosilicate and lithium metasilicate, where the lithium metasilicate produced by reaction of the lithium orthosilicate and carbon dioxide is excluded.Type: GrantFiled: March 15, 2007Date of Patent: September 15, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Toshihiro Imada, Yasuhiro Kato, Masahiro Kato
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Patent number: 7585808Abstract: The present invention is directed to processes for preparing supported metal catalysts comprising one or more catalytically active metals applied to a porous catalyst support and to processes that use such catalysts. The process requires the formation of an organic complex during the manufacture of the catalyst which after its formation is either partially or fully decomposed before reduction if the metal to form the catalyst. The catalysts have high levels of metal dispersion and uniform distribution of catalytically active metals on the support. The catalysts obtained form the processes are particularly effective in catalysing Fischer-Tropsch reactions and as adsorbants for the removal or organosulfur compounds from hydrocarbons.Type: GrantFiled: November 18, 2003Date of Patent: September 8, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Andrzel Malek, James Clarke Vartuli, Stuart Leon Soled, Sabato Miseo, Jennifer Schaefer Feeley, Gary L. Casty, Gabor Kiss, Jeffrey M. Dysard, Joseph Ernest Baumgartner, Christine E. Kliewer, Steven T Ragomo
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Patent number: 7585359Abstract: A filtration system including a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment is provided. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. Also included is the presence of an oxidizing agent on the gel materials to aid in capturing nitrogen dioxide and preventing conversion of such a product to NO. Methods of using and the application within specific filter apparatuses are also encompassed within this invention.Type: GrantFiled: December 27, 2006Date of Patent: September 8, 2009Assignee: J.M. Huber CorporationInventors: Michael C. Withiam, Fitzgerald A. Sinclair, David Friday, Terry Nassivera
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Publication number: 20090220557Abstract: The present invention relates to intensely coloured and light-stable effect pigments based on transparent, undoped SiO2 flakes, which are distinguished by the fact that they are covered with an iron-oxide layer having a thickness of 30-150 nm, and all SiO2 flakes have an identical thickness, and the thickness of the SiO2 flakes is 250-400 nm, and to the use thereof in pigment mixtures, in cosmetic formulations and for colouring foods and pharmaceutical products.Type: ApplicationFiled: November 7, 2006Publication date: September 3, 2009Inventors: Gerhard Pfaff, Johann Dietz, Cornelia Foerderer, Xenia Petsitis, Doreen Warthe, Veronika Hochstein
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Publication number: 20090211981Abstract: A dry product that permanently removes oil and oil stains from liquid or dry surfaces and is environmentally safe. The dry product is formed by mixing efficacious proportions of untreated amorphous silica with a dry, inert organic, inorganic or synthetic carrier, or combinations of said carriers. Suitable inert carriers include, but are not limited to, (a) inert inorganic carriers including, but not limited to, clays, perlite, vermiculite, crushed glass, volcanic ash and sand; (b) inert organic carriers, including, but not limited to, peat moss, straw, hay, sawdust, ground corncobs, flours, and coconut coir, and (c) inert synthetic carriers, including, but not limited to, polyurethane, polyethylene and polypropylene. The dry product can be applied directly to oil stains either on a hard surface, such as concrete or asphalt, or to oil spills on water.Type: ApplicationFiled: February 21, 2008Publication date: August 27, 2009Applicant: Rousseau Research, Inc.Inventor: Joseph D. Russo
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Patent number: 7579299Abstract: The invention relates to a process of processing an acid suspension containing at least one solid, wherein (a) the suspension containing at least one solid is mixed with an alkali metal silicate solution, the pH of the mixture being adjusted to a pH of more than 4, and (b) the resulting precipitate which contains the alkali metal silicate and the at least one solid is separated and optionally washed, dried and ground. The mixture according to (a) after aging may be acidified further by the addition of an acid. Furthermore, there are disclosed an adsorbent obtainable according to the preceding process, and the use thereof.Type: GrantFiled: November 30, 2005Date of Patent: August 25, 2009Assignee: Sud-Chemie AGInventors: Uwe Flessner, José Antonio Ortiz Niembro, Klaus Schurz, Werner Zschau
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Patent number: 7575629Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. The methods include mixing fly ash particles with a sulfide salt and a metal salt to form a metal sulfide on the outer surface of the fly ash particles.Type: GrantFiled: November 30, 2005Date of Patent: August 18, 2009Assignee: BASF Catalysts LLCInventors: Xiaolin David Yang, Pascaline Harrison Tran, Lawrence Shore, Stanley Scott Mack, James Eugene Staudt
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Patent number: 7566393Abstract: Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets (14) and placed inside a fuel filter housing (12) for removing organosulfur contaminants from a hydrocarbon fuel stream.Type: GrantFiled: April 26, 2005Date of Patent: July 28, 2009Assignee: NanoScale CorporationInventors: Kenneth Klabunde, Bill R. Sanford, P. Jeevanandam
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Patent number: 7563744Abstract: The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.Type: GrantFiled: August 8, 2002Date of Patent: July 21, 2009Assignee: Umicore AG & Co. KGInventors: Harald Klein, Ulrich Neuhausen, Egbert Lox, Jürgen Gieshoff, Thomas Kreuzer
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Patent number: 7563743Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).Type: GrantFiled: September 8, 2005Date of Patent: July 21, 2009Assignee: Institute Francais du PetroleInventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
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Patent number: 7563739Abstract: The invention relates to a desiccant based on clay-bound zeolite which is characterized in that it comprises hygroscopic salt and optionally further conventional additives. Preferably, it is present in the form of granules, the hygroscopic salt being arranged in the pores of the granular particles. Furthermore the invention relates to a process for the preparation of the desiccant as well as its use, in particular in insulating glass windows and spacers for insulating glass windows.Type: GrantFiled: August 20, 2002Date of Patent: July 21, 2009Assignee: Grace GmbH & Co. KG.Inventors: Fritz Kilthau, Thomas E. W. Niessen, Heide Wetzel
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Patent number: 7560414Abstract: An adsorbent for organic compounds including filler granules, which contain 20 to 99.9 wt. % of fillers and a binder. The adsorbent is produced by mixing at least one binder with at least one filler and performing granulation in a mixing or granulation apparatus. The adsorbent may be used for adsorbing and/or absorbing organic and/or inorganic substances from a liquid or gaseous phase.Type: GrantFiled: August 22, 2002Date of Patent: July 14, 2009Assignee: Degussa AGInventors: Matthias Schmitt, Martin Kuge, Reinhard Stober, Udo Görl, Jürgen Leimann, Susanne Esser, Jan Kopietz, Silke Teike
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Patent number: 7559981Abstract: An environmental control for use in air handling systems that are required to provide highly effective filtration of noxious gases is provided. In one embodiment, a filtration system utilizes a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove such undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. The novel combination of such gels and zeolites permits highly effective noxious gas filtration over a wide range of known toxic industrial chemicals such that excellent breakthrough results are attained, particularly in comparison with prior media filtration products.Type: GrantFiled: July 6, 2006Date of Patent: July 14, 2009Assignee: J.M. Huber CorporationInventors: David K. Friday, Fitzgerald A. Sinclair, Michael C. Withiam
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Publication number: 20090173225Abstract: A fluid storage and dispensing apparatus including a fluid storage and dispensing vessel having a rectangular parallelepiped shape, and an integrated gas cabinet assembly including such fluid storage and dispensing apparatus and/or a point-of-use ventilation gas scrubber in the vented gas cabinet. By the use of physical adsorbent and chemical sorbent media, the gas cabinet can be enhanced in safety of operation, e.g., where the process gas supplied from the gas cabinet is of a toxic or otherwise hazardous character.Type: ApplicationFiled: March 10, 2009Publication date: July 9, 2009Applicant: Advanced Technology Materials, Inc.Inventors: Dennis Brestovansky, Michael J. Wodjenski, Jose I. Arno, J. Donald Carruthers, Philip A. Moroco, Judith A. Moroco
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Patent number: 7557064Abstract: Organic ligands that contain at least one aryl group are immobilized on a solid support. The organic ligands are of the type used to form a catalyst complex suitable for carrying out a catalytic reaction, preferably an asymmetric reaction. To immobilize the organic ligands, a tethering group is bonded to the ligand using, for example, a Friedel-Crafts acylation or alkylation reaction. The immobilization of the organic ligand can be carried out using a single reaction with the organic ligand.Type: GrantFiled: August 13, 2007Date of Patent: July 7, 2009Assignee: Headwaters Technology Innovation, LLCInventors: Bing Zhou, Changkun Liu
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Publication number: 20090155528Abstract: There is provided a silicon carbide-based porous body which can avoid excessive temperature elevation when it is used as a filter and the captured particulate matter (PM) is burnt for removal and which is low in strength reduction caused by heat cycle. The silicon carbide-based porous body comprises a plurality of silicon carbide (SiC) particles as an aggregate and a plurality of binding phases which bind the silicon carbide particles to each other, wherein of the binding phases, the phase having the largest volume is either of a Si phase and a phase (a metal silicide phase) made of at least one member selected from the group consisting of a Ti silicide, a Zr silicide, a Mo silicide and a W silicide, all having a linear thermal expansion coefficient at 40 to 800° C., higher than that of Si by at least 3×10?6 (° C.Type: ApplicationFiled: December 8, 2008Publication date: June 18, 2009Applicant: NGK INSULATORS, LTD.Inventor: Masaaki KAWAI
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Patent number: 7544285Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.Type: GrantFiled: February 20, 2004Date of Patent: June 9, 2009Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
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Patent number: 7541310Abstract: This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.Type: GrantFiled: October 12, 2004Date of Patent: June 2, 2009Assignee: ConocoPhillips CompanyInventors: Rafael L. Espinoza, Kandaswamy Jothimurugesan, Kevin L. Coy, James Dale Ortego, Jr., Nithya Srinivasan, Olga P. Ionkina
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Patent number: 7538065Abstract: An improved noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework suitable for use in the hydroprocessing of hydrocarbonaceous feeds, which is directed at a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof on a mesoporous support having aluminum incorporated into its framework and an average pore diameter of about 15 to less than about 40 ?.Type: GrantFiled: August 17, 2005Date of Patent: May 26, 2009Assignee: International Business Machines CorporationInventors: Stephen J. McCarthy, Wenyih F. Lai, Sylvain S. Hantzer, Ian A. Cody
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Patent number: 7538068Abstract: A carbon dioxide gas absorbent includes a porous body containing a lithium complex oxide. The porous body includes pores having a pore diameter distribution such that main pores which consist of first pores with a diameter of 10 to 100 ?m and second pores with a diameter larger than 100 ?m and 500 ?m or smaller occupy 80 to 100%, third pores with a diameter smaller than 10 ?m occupy 0 to 10% and fourth pores with a diameter larger than 500 ?m occupy 0 to 10%, the main pores have a pore diameter distribution such that the first pores occupy 15 to 85% and second pores occupy 15 to 85%.Type: GrantFiled: March 16, 2006Date of Patent: May 26, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Masahiro Kato, Toshihiro Imada, Kenji Essaki
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Patent number: 7538067Abstract: A silica xerogel, a process for making it, and a process for using it to reduce chill haze in beer includes incorporation in the xerogel of one or more alkali metals, optionally in combination with one or more alkaline earth metals. The pH of the xerogel is between 8.0 and 10.5, preferably between 8.5 and 10.0.Type: GrantFiled: May 14, 2007Date of Patent: May 26, 2009Assignee: PQ CorporationInventors: Yatao Hu, Larissa Ding, Robert E. Patterson
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Publication number: 20090120872Abstract: The invention relates to a novel composition and a novel method for the in situ bioremediation of water polluted by hydrocarbons, in particular oil. To remove, for example, an oil slick that is floating on the surface of a body of water, the new composition can be dispersed in powder form over said oil slick. The inventive composition binds spontaneously with the oil, sinking together with the latter below the surface of the water to finally settle as a fine sediment on the bottom. Within a few hours the toxic hydrocarbons have been eliminated from the water, in such a way that in the case of freshwater, drinking-water quality can be restored. The microbiological degradation takes place in situ. The composition contains silicon carbide and/or silicon dioxide in powder form and preferably additives including granite dust, silica-lime dust and calcium. Said new composition permits a simple, cost-effective bioremediation of oil pollution on the surface of bodies of water.Type: ApplicationFiled: November 1, 2006Publication date: May 14, 2009Applicant: SWISSTECH HOLDING AGInventor: Werner Kroh
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Publication number: 20090114093Abstract: A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.Type: ApplicationFiled: June 17, 2008Publication date: May 7, 2009Inventors: Liyu Li, David L. King, Jun Liu, Qisheng Huo
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Patent number: 7528087Abstract: A porous mullite composition is made by Forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.Type: GrantFiled: April 23, 2004Date of Patent: May 5, 2009Assignee: Dow Global Technologies, Inc.Inventors: Chandan Saha, Sharon Allen, Chan Han, Robert T. Nilsson, Arthur R. Prunier, Jr., Aleksander J. Pyzik, Sten A. Wallin, Robin Ziebarth, Timothy J. Gallagher
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Patent number: 7528089Abstract: The present invention includes a microporous or mesoporous composition of matter in which the composition is formed continuously or semi-continuously in a heated reactor zone, including a rotary calciner or a rotary screw as a means for conveying the synthesis mixture, at a temperature between 200° C. and 500° C. with a residence time less than 24 hours. The reagents are solid and liquid reagents in which the solid reagents have a weight percent between 45% and 98% of the total reagents. The invention also includes a continuous or semi-continuous process for the hydrothermal manufacture of the microporous or mesoporous composition.Type: GrantFiled: October 15, 2004Date of Patent: May 5, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Ivy D. Johnson, Kirk D. Schmitt, Steven T. Ragomo, Stephen G. Casmer
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Patent number: 7524794Abstract: Perlite, particularly, perlite in powdered form, is employed to adsorb metals and metal compounds from a fluid flow. In select embodiments, the perlite is treated to expand its surface area and injected into a fluid stream, such as flue gas, held for a specific retention period, and removed for subsequent disposal. In other embodiments the perlite is provided in a fixed adsorption bed and the fluid flow permitted to pass through the bed until the perlite surface is exhausted. The perlite in the fixed bed is then replaced, with the exhausted perlite disposed of as appropriate. Treatment of perlite by boiling with sulfuric acid or suspending in a suspension of sulfur in carbon disulfide has been shown to significantly expand the surface area of perlite.Type: GrantFiled: September 1, 2004Date of Patent: April 28, 2009Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Veera M. Boddu, Kent James Hay, Tushar K. Ghosh, Dabir S. Viswanath
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Patent number: 7521391Abstract: A photocatalytic coating composition comprising a photocatalyst, a silicon alkoxide, a zirconium compound, colloidal silica, and a liquid medium, wherein a content of the zirconium compound in terms of zirconium atoms is 0.3 to 3 times by mole a content of the silicon alkoxide in terms of silicon atoms, which can form a coating film of a photocatalyst with a high adhesion strength to a substrate.Type: GrantFiled: March 16, 2005Date of Patent: April 21, 2009Assignees: Sumitomo Chemical Company, Limited, Asahi Chemical Company, LimitedInventors: Yoshiaki Sakatani, Seiichi Sakaguchi
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Patent number: 7510602Abstract: An environmental control for use in air handling systems that are required to provide highly effective filtration of noxious gases is provided. In one embodiment, a filtration system utilizes a novel combination of at least one metal-doped silica-based gel and zeolite materials to trap and/or modify, and remove such undesirable gases (such as ammonia, ethylene oxide, formaldehyde, and nitrous oxide, as examples) from an enclosed environment. The gel component exhibits specific porosity requirements and density measurements; the zeolite component is generally acidic and is preferably not reacted with any salts or like substances. The novel combination of such gels and zeolites permits highly effective noxious gas filtration over a wide range of known toxic industrial chemicals such that excellent breakthrough results are attained, particularly in comparison with prior media filtration products.Type: GrantFiled: July 6, 2006Date of Patent: March 31, 2009Assignee: J.M. Huber CorporationInventors: David K. Friday, Fitzgerald A. Sinclair, Michael C. Withiam
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Patent number: 7510996Abstract: A hydrogen storage material is expressed by a composition formula, (Ca1-xAx)1-z(Si1-yBy)z, wherein “A” is at least one member selected from the group consisting of alkali metal elements, alkaline-earth metal elements, rare-earth elements, the elements of groups 3 through 6, Ni, Au, In, Tl, Sn, Fe, Co, Cu and Ag; “B” is at least one member selected from the group consisting of the elements of groups 7 through 17, rare-earth elements, Hf and Be; 0?x<1 by atomic ratio; 0?y<1 by atomic ratio; and 0.38?z?0.58 by atomic ratio. It is lightweight as well as less expensive. In principle, neither high-temperature nor high-pressure activation is required, because it exhibits a high initial activity. The operation temperature can be lowered and the hydrogen absorption content can be enlarged by controlling the kind and substitution proportion of the substituent elements appropriately.Type: GrantFiled: June 10, 2004Date of Patent: March 31, 2009Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Masakazu Aoki, Nobuko Oba, Shin-ichi Towata, Tatsuo Noritake
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Publication number: 20090081092Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%.Type: ApplicationFiled: September 24, 2007Publication date: March 26, 2009Inventors: Xiaolin David Yang, Pascaline Harrison Tran, Lawrence Shore
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Publication number: 20090078157Abstract: The invention is directed to a synthetic inorganic material, comprising inorganic compounds based on elementary particles with a sheet (phyllosilicate) structure, the elementary particles consisting of a central layer of octahedrally coordinated divalent metal ions between two layers of tetrahedrally surrounded silicon ions, which particles are substantially free of aluminum, free silica and salts and hydroxides of the divalent metal ions, the material not containing any metal ions that can be reduced to the corresponding metals at temperatures of 700° C. or less.Type: ApplicationFiled: May 1, 2006Publication date: March 26, 2009Applicant: Eurosupport B.V.Inventors: John Wihelm Geus, Jacobus Berend Dirksen
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Publication number: 20090075131Abstract: The invention provides a desulfurizing agent which attains effective removal of sulfur from a hydrocarbon feedstock and/or an oxygen-containing hydrocarbon feedstock so as to attain a considerably low sulfur level and which has a long service life; a process for producing hydrogen for fuel cells, which process includes steam-reforming, partial-oxidation-reforming, or autothermal-reforming of a hydrocarbon feedstock and/or an oxygen-containing hydrocarbon feedstock which has been desulfurized by use of the desulfurizing agent; a fuel cell system employing hydrogen produced through the process. The desulfurizing agent for removing a sulfur compound from a hydrocarbon feedstock and/or an oxygen-containing hydrocarbon feedstock, the agent containing nickel, or a combination of nickel and copper, and silicon, and having a bulk density of 0.95 to 2.0 g/cm3, a pore volume of 0.10 to 0.40 mL/g, a micropore surface area of 100 to 250 m2/g, and an external surface area of 100 m2/g or less.Type: ApplicationFiled: March 20, 2006Publication date: March 19, 2009Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Hisashi Katsuno, Kazuhito Saito
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Patent number: 7504357Abstract: A catalyst composition having the formula: Mo1VaSbbNbcMdOx wherein M is gallium, bismuth, silver or gold, a is 0.01 to 1, b is 0.01 to 1, c is 0.01 to 1, d is 0.01 to 1 and x is determined by the valence requirements of the other components. Other metals, such as tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, platinum, boron, arsenic, lithium, sodium, potassium, rubidium, calcium, beryllium, magnesium, cerium, strontium, hafnium, phosphorus, europium, gadolinium, dysprosium, holmium, erbium, thulium, terbium, ytterbium, lutetium, lanthanum, scandium, palladium, praseodymium, neodymium, yttrium, thorium, tungsten, cesium, zinc, tin, germanium, silicon, lead, barium or thallium may also be components of the catalyst. This catalyst is prepared by co-precipitation of metal compounds which are calcined to form a mixed metal oxide catalyst that can be used for the selective conversion of an alkane to an unsaturated carboxylic acid in a one-step process.Type: GrantFiled: May 24, 2007Date of Patent: March 17, 2009Assignee: Saudi Basic Industries CorporationInventors: Paulette N. Hazin, Paul E. Ellis, Jr.
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Publication number: 20090065435Abstract: Biogenic silica is produced by combusting a biogenic source material such as rice hulls to give rich hull ash (RHA), and the combusted biogenic silica may be subsequently treated to improve the filtration or adsorption properties thereof e.g. by changing the surface charge, the surface tension, the surface area, the average pore size, the pore size distribution, particle size distribution, and/or the permeability thereof. Such biogenic silica is useful to remove a species, such as an impurity, from a fluid to purify the fluid and/or to recover the species therefrom. RHA may be used to remove species including organic, inorganic or microbial particulates, surfactants, metal ions, non-metallic anions, organic compounds, color bodies, odor-producing species, chlorinated compound, pigment, free fatty acids, phospholipids, peroxides, oil and/or grease different from the non-aqueous fluid, algae, bacteria, and combinations thereof.Type: ApplicationFiled: September 8, 2008Publication date: March 12, 2009Applicant: Powell Intellectual Property Holdings, LLCInventors: Wenping Li, Carl E. Kiser
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Publication number: 20090053829Abstract: Providing an absorption pad which shows remarkable water absorptivity and can shorten a detection time when employed for an immunoassay apparatus. A water absorption pad for the immunoassay apparatus, containing 50% by weight or more of silicon-containing particles wherein a moisture absorptivity is 30% or less at a humidity of 60% or less and a moisture absorptivity is 40% or more at a humidity of 90% or more, a strip for an immunoassay using said absorption pad as a suction part, and an immunoassay apparatus including said strip for the immunoassay.Type: ApplicationFiled: September 15, 2008Publication date: February 26, 2009Applicant: FUJIREBIO INC.Inventors: Chisato OKAMURA, Minoru Sato
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Patent number: 7494533Abstract: Methods and apparatus for purifying gases having organic impurities, including the use of granulated porous glass. A system for purifying an impure gas includes a source of an impure gas, a purification element operatively associated with the source of impure gas for purifying the impure gas, and a conduit operatively associated with the purification element for receiving a flow of purified impure gas from the purification element and directing the purified impure gas to a container or point of use. The impure gas includes a first gas and an organic compound. The purification element includes a vessel containing a packed bed of granulated porous glass.Type: GrantFiled: December 29, 2005Date of Patent: February 24, 2009Assignee: American Air Liquide, Inc.Inventor: Frederick W. Giacobbe
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Publication number: 20090045136Abstract: The invention relates to a combined process for the adsorption of metals in a liquid and for the neutralisation of metal-containing waste acids. The adsorption material used in the process is in the form of a geological mineral containing at least one alkali metal and/or alkaline earth metal, e.g. wollastonite (CaSiO3) , magnesite (MgCO3) or burnt magnesite (MgO). The spent adsorption material that has been used in the adsorption process is thereafter used as neutralisation agent for the neutralisation of waste acids, such as spent pickling baths. The application moreover relates to an adsorption material comprising a geological mineral containing at least one alkali metal and/or alkaline earth metal, which mineral has been concentrated by crushing, milling and shake sieving in a dry state.Type: ApplicationFiled: March 3, 2006Publication date: February 19, 2009Inventor: Rob Hellingwerf
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Patent number: 7491674Abstract: A catalyst body including a catalytic material containing an alkali metal and/or an alkaline earth metal, a carrier carrying the catalytic material, and a method of manufacturing the catalyst body are provided. The carrier has a cordierite binder phase and aggregate phases dispersed in the cordierite binder phase.Type: GrantFiled: October 29, 2002Date of Patent: February 17, 2009Assignee: NGK Insulators, Ltd.Inventors: Misako Fujii, Kenji Morimoto, Shinji Kawasaki
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Patent number: 7488533Abstract: The present invention relates to amorphous silica particles having high oil absorbance capabilities, a process for their preparation and use thereof. The amorphous silica particles of the invention, wherein oil absorption measured by JISK 6217-4 is more than 400 ml/100 g can be obtained by baking at least 200 to 990° C.Type: GrantFiled: July 30, 2004Date of Patent: February 10, 2009Assignee: DSL Japan Co., Ltd.Inventors: Shugo Nishi, Tatsuya Tokunaga
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Patent number: 7485594Abstract: A porous mullite composition is made by forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.Type: GrantFiled: May 1, 2007Date of Patent: February 3, 2009Assignee: Dow Global Technologies, Inc.Inventors: Chandan Saha, Sharon Allen, Chan Han, Robert T. Nilsson, Arthur R. Prunier, Jr., Aleksander J. Pyzik, Sten A. Wallin, Robin Ziebarth, Timothy J. Gallagher
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Patent number: 7479265Abstract: This invention relates to ?-SiC foam parts with a specific surface area preferably equal to at least 5 m2/g and with at least two zones A and B with a different cellular porosity distribution, wherein the parts were made by chemical transformation of a porous precursor medium comprising at least two blocks A? and B?, each having a different cellular porosity distribution, and in that the at least two zones A and B are derived from the chemical transformation of the two blocks A? and B?. This foam, optionally after deposition of an active layer, may be used as a filter medium in cartridges designed for the purification of exhaust gases. The invention also relates to manufacturing processes for preparing such a filter medium.Type: GrantFiled: October 14, 2004Date of Patent: January 20, 2009Assignees: SICAT, Entre National de la Recherche Scientifigue, Universite Louis Pasteur de StrasbourgInventors: Charlotte Pham, Laurie Pesant, Pierre Bernhardt, Michel Wolf, Cuong Pham-Huu, Marc-Jacques Ledoux, Michel Kartheuser, Estelle Vanhaecke
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Patent number: 7473663Abstract: Process for the preparation of an additive-containing anionic clay comprising the steps of (a) preparing a physical mixture of a divalent and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C. without performing a prior aging or shaping step, thereby forming a product containing at least 5 wt % of a rehydratable compound, and (c) rehydrating the calcined mixture in aqueous suspension containing an additive to form the additive-containing anionic clay. This process provides a simple and cost-effective way of preparing additive-containing anionic clays. The process does neither require aging or reaction steps before calcination, nor does it require precipitation of metal salts or the handling of inhomogeneous slurries.Type: GrantFiled: April 26, 2005Date of Patent: January 6, 2009Assignee: Albemarle Netherlands B.V.Inventors: William Jones, Dennis Stamires, Paul O'Connor, Michael F. Brady
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Publication number: 20090000192Abstract: Method and apparatus for storing hydrogen. One embodiment of such a method comprises providing a storage apparatus having a substrate and a nanostructure mat on at least a portion of a side of the substrate. The nanostructure mat comprises a plurality of nanostructures having a surface ionization state which causes more than one layer of hydrogen to adsorb onto the nanostructures. The method can also include exposing the nanostructure mat to hydrogen such that more than one layer of hydrogen adsorbs onto the nanostructures.Type: ApplicationFiled: December 20, 2007Publication date: January 1, 2009Applicants: Washington State University Research Foundation, Idaho Research Foundation, Inc.Inventors: Grant Norton, David McllRoy
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Patent number: 7470645Abstract: A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.Type: GrantFiled: February 8, 2006Date of Patent: December 30, 2008Assignee: Lummus Technology Inc.Inventors: Zhiping Shan, Peter Wilhelm, Bowden George Maingay, Philip J. Angevine, Jacobus Cornelis Jansen, Chuen Y. Yeh, Thomas Maschmeyer, Frits M. Dautzenberg, Leonardo Marchese, Heloise de Oliveira Pastore
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Patent number: 7468342Abstract: As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining.Type: GrantFiled: May 7, 2002Date of Patent: December 23, 2008Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoshinori Kanamori, Shuji Ebata, Kengo Tsukahara, Yasushi Hiramatsu
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Publication number: 20080311288Abstract: The present invention relates to methods and compositions for removal of arsenic and heavy metals from water.Type: ApplicationFiled: December 29, 2006Publication date: December 18, 2008Inventor: Liangjie Dong
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Publication number: 20080302730Abstract: The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.Type: ApplicationFiled: May 7, 2008Publication date: December 11, 2008Applicant: AMCOL International CorporationInventors: Zhen Wang, Robert Abraham
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Publication number: 20080302731Abstract: The use of two mercury and arsenic removal media: A) a sulfur-impregnated organoclay; and B) a coupling agent-reacted organoclay, wherein the coupling agent preferably contains a mercapto, disulfide, tretrasulfide and/or polysulfide end group provides mercury removal media having increased reactivity, stability, and synergistic mercury removal ability. The preferred mercury removal media described herein is prepared by reacting an organophilic clay containing onium ions A) with elemental sulfur; and B) with a sulfur-containing coupling agent, preferably containing a mercapto, disulfide, tetrasulfide, and/or polysulfide moiety.Type: ApplicationFiled: May 7, 2008Publication date: December 11, 2008Applicant: AMCOL International CorporationInventors: ZHEN WANG, Robert Abraham