Plural Distinct Serial Combustion Stages Patents (Class 502/43)
  • Patent number: 10967108
    Abstract: A low-profile reduced pressure treatment apparatus and system are provided. The apparatus includes a moldable conduit holder, a conduit through the conduit holder, and a flexible base. The conduit holder has first and second bulkhead surfaces, a convex top surface, and a bottom surface adapted to conform to a tissue contact region adjacent to a tissue site. An end of the conduit is substantially flush with the first bulkhead surface and a longitudinal axis of the conduit is substantially perpendicular to the first and second bulkhead surfaces. The base is connected on a first side to the bottom surface of the conduit holder, and extends beyond the first bulkhead surface to form an overlay zone adjacent the first bulkhead surface. An adhesive is disposed on a second side of the flexible base to secure the flexible base to the tissue contact region.
    Type: Grant
    Filed: February 15, 2018
    Date of Patent: April 6, 2021
    Assignee: KCI Licensing, Inc.
    Inventor: Robert Peyton Wilkes
  • Patent number: 9045814
    Abstract: The instant invention discloses a method for the valorization of spent catalyst from hydrocarbon processing slurry reactors as well as slurry flakes.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: June 2, 2015
    Assignee: TOTAL RAFFINAGE MARKETING
    Inventors: Delphine Gotteland, Katell Le Lannic-Dromard, Marie Ropars, Gloria Vendrell, Maxime Lacroix, Didier Borremans
  • Patent number: 8822363
    Abstract: This disclosure relates to a process for regenerating a catalyst composition, wherein the catalyst composition comprising a molecular sieve and at least 10 wt. % coke having a C/H molar ratio in the range of 0.26 to 5, the process comprising (a) contacting the catalyst composition with a first oxidative medium having oxygen and water at first conditions sufficient to form a first regenerated catalyst composition having at least 50 wt.
    Type: Grant
    Filed: November 4, 2008
    Date of Patent: September 2, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Doron Levin, James Harding Beech, Jr., Selma SheungNam Lawrence, Julia Elizabeth Steinheider
  • Patent number: 8815762
    Abstract: Disclosed is a catalyst distributor and process for mixing spent catalyst and recycled regenerated catalyst in a regenerator vessel. Mixing is conducted in a confined space to which catalyst is delivered from catalyst conduits protruding through the wall of the regenerator.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: August 26, 2014
    Assignee: UOP LLC
    Inventors: Paolo Palmas, Daniel R. Johnson
  • Patent number: 8791038
    Abstract: The object of the present invention is to provide a catalyst regeneration process which can improve catalyst selectivity. A first aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a first fluidized bed regenerator and contacted with an oxygen-containing gas stream and optional steam to carry out a coke combustion reaction, wherein the resultant mixture of the partially regenerated catalyst and flue gas is introduced into a second fluidized bed regenerator and contacted with steam and an optional oxygen-containing gas stream to carry out a further regeneration reaction, and then the regenerated catalyst is introduced into the reactor. A second aspect of the invention is characterized in that a spent catalyst from a reactor is introduced into a fluidized dense bed regenerator and contacted with an oxygen-containing gas stream and steam to carry out a coke combustion reaction, and then the regenerated catalyst is introduced into the reactor.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: July 29, 2014
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Youhao Xu, Shouye Cui, Zhigang Zhang, Weimin Lu
  • Patent number: 8680000
    Abstract: The invention concerns a process for regenerating a catalyst for the production of aromatic hydrocarbons or for reforming, comprising a step for combustion in a zone A comprising at least 2 beds A1 and A2, a step for oxychlorination in a zone B, and a step for calcining in a zone C. A portion of the effluent gas from the oxychlorination zone is recycled via at least one scrubbing section D to the inlet to beds A1 and A2. Further, a portion of the effluent gas from zone B is recycled to the combustion bed A2, passing via a blower but without passing via said scrubbing section D, and a portion is recycled to the inlet to zone B, passing via said blower but not via said scrubbing section. The invention also concerns the vessel in which said process is carried out.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: March 25, 2014
    Assignee: IFP Energies nouvelles
    Inventors: Xavier Decoodt, Sebastien Durand, Pierre Yves Le-Goff, Stephane Wermester
  • Patent number: 8673801
    Abstract: The invention concerns a process for regenerating a catalyst for the production of aromatic hydrocarbons or for reforming. Said process comprises a step for combustion in a zone A comprising at least 2 beds A1 and A2, a step for oxychlorination in a zone B, and a step for calcining in a zone C. A portion of the effluent gas from the oxychlorination zone is recycled via at least one scrubbing section D to the inlet to beds A1 and A2. Further, a portion of the effluent gas from zone B is recycled, passing via a blower and without passing via said scrubbing section D, to the combustion bed A2.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: March 18, 2014
    Assignee: IFP Energies nouvelles
    Inventors: Xavier Decoodt, Sébastien Durand, Pierre-Yves Le-Goff, Stéphane Wermester
  • Patent number: 8647998
    Abstract: The present invention relates to a continuous catalyst regeneration device comprising at least one burning zone formed by at least one annular combustion zone (3), centered along a longitudinal axis (A), in which the catalyst circulates, an inlet conduit of the catalyst (4) and an outlet conduit of the catalyst (4?), an external zone (11) for circulation of a combustive gas disposed around the annular combustion zone (3) and an internal circulation zone (15) disposed inside the annular combustion zone (3), wherein the burning zone is divided into sectors (14) by hermetic longitudinal plates (10) disposed radially relative to the longitudinal axis (A) of the regenerator. The invention also relates to the process using this device.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: February 11, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Beatrice Fischer, Eric Sanchez, Gilles Ferschneider
  • Patent number: 8618012
    Abstract: Systems and methods for regenerating a spent catalyst are provided. The method can include mixing a spent catalyst with a carrier fluid to provide a mixture. The spent catalyst can include carbon deposited on at least a portion thereof. The carrier fluid can include an oxygen containing gas. The mixture can be introduced to or above an upper surface of a dense phase catalyst zone disposed within a regenerator. A gas can be introduced to a lower zone of the dense phase catalyst zone. At least a portion of the carbon deposited on the catalyst can be combusted to provide a flue gas, heat, and a regenerated catalyst.
    Type: Grant
    Filed: April 9, 2010
    Date of Patent: December 31, 2013
    Assignee: Kellogg Brown & Root LLC
    Inventors: Phillip K. Niccum, Alan M. Claude, Robert B. Peterson
  • Patent number: 8618011
    Abstract: Systems and methods for regenerating a spent catalyst are provided. The method can include heating a hydrocarbon and a coke precursor in the presence of catalyst particles to provide a cracked hydrocarbon product and coked catalyst particles. The cracked hydrocarbon product and the coked catalyst particles can be selectively separated to provide a hydrocarbon product and coked catalyst particles. The coked catalyst particles can be mixed with a carrier fluid to provide a mixture. The mixture can be introduced to an upper surface of a dense phase catalyst zone disposed within a regenerator. A gas can be introduced to a lower zone of the dense phase catalyst zone. At least a portion of the carbon deposited on the coked catalyst particles can be combusted to provide a flue gas, heat, and a regenerated catalyst.
    Type: Grant
    Filed: April 9, 2010
    Date of Patent: December 31, 2013
    Assignee: Kellogg Brown & Root LLC
    Inventors: Phillip K. Niccum, Alan M. Claude, Robert B. Peterson
  • Patent number: 8563455
    Abstract: Disclosed is a catalyst distributor and process for mixing spent catalyst and recycled regenerated catalyst in a regenerator vessel. Mixing is conducted in a confined space to which catalyst is delivered from catalyst conduits protruding through the wall of the regenerator.
    Type: Grant
    Filed: September 30, 2010
    Date of Patent: October 22, 2013
    Assignee: UOP LLC
    Inventors: Paolo Palmas, Daniel R. Johnson
  • Patent number: 8551326
    Abstract: This invention describes a two-stage regeneration zone that has a regenerated catalyst circuit such as the one that results from the mixing of a partially regenerated catalyst with a residual coke rate of between 0.3 and 0.7% and a totally regenerated catalyst with a coke rate that is less than 0.15%. All things being equal, this double-population regenerated catalyst enables the maximization of the LCO yield.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: October 8, 2013
    Assignee: IFP Energies Nouvelles
    Inventors: Romain Roux, Thierry Gauthier
  • Patent number: 8372770
    Abstract: This invention is directed to a process for regenerating a deactivated reforming catalyst by circulating a first oxygen-containing gas stream from a gas compressor to a catalyst bed in a reforming reaction zone in order to remove at least a portion of the carbonaceous deposits on the reforming catalyst. Then, a second oxygen-containing gas stream is further circulated from the gas compressor to the reforming catalyst bed, for oxidizing the reforming catalyst, and an inert gas stream is passed from the gas compressor through the reforming catalyst bed to purge a substantial portion of the oxygen contained therein for a time sufficient to reduce the oxygen content of an exiting purge gas stream to less than about 2% by volume oxygen.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: February 12, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Lawrence E. Lew
  • Patent number: 8022002
    Abstract: Regeneration flue gas streams containing unacceptable levels of CO can be effectively combusted (i.e., for more complete combustion or oxidation of CO to CO2) by contact with a second catalyst undergoing regeneration, for example in a second regenerator. While the second catalyst may also be regenerated by contact with an oxygen-containing gas stream, this second catalyst additionally comprises a noble metal, or is present in combination with a combustion comprising a noble metal. Representative catalysts used in an integrated regeneration process are those used for oxygenate conversion and olefin cracking, both for the purpose of producing light olefins (e.g., ethylene and propylene).
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: September 20, 2011
    Assignee: UOP LLC
    Inventor: Andrea G. Bozzano
  • Patent number: 7915191
    Abstract: This invention is directed to a method and apparatus for regenerating a catalyst used in an FCC unit, including providing a spent catalyst into an upper portion of a regenerator, maintaining a calcination phase, a gasification phase, and a combustion phase of fluidized catalyst in the regenerator, combusting carbon in the combustion phase and producing a combustion flue gas, reacting carbon in the gasification phase with the combustion flue gas to form a carbon monoxide rich flue gas, and calcining the spent catalyst with the carbon monoxide rich flue gas.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: March 29, 2011
    Assignee: UOP LLC
    Inventor: Brian W. Hedrick
  • Patent number: 7816294
    Abstract: A catalyst regenerator (100) has a first section (110) and a second section (120) and is operated such that carbon from a carbon-contaminated catalyst (140) is converted to carbon monoxide in the first section (110) and that carbon monoxide is converted to carbon dioxide in the second section (120). The residence time of the oxygen-containing gas in the first and second sections (110, 120) is regulated in preferred configurations by the shape (e.g., diameter) of the first and second sections (110, 120).
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: October 19, 2010
    Assignee: Fluor Technologies Corporation
    Inventor: Humbert Chu
  • Publication number: 20100248943
    Abstract: Regeneration flue gas streams containing unacceptable levels of CO can be effectively combusted (i.e., for more complete combustion or oxidation of CO to CO2) by contact with a second catalyst undergoing regeneration, for example in a second regenerator. While the second catalyst may also be regenerated by contact with an oxygen-containing gas stream, this second catalyst additionally comprises a noble metal, or is present in combination with a combustion comprising a noble metal. Representative catalysts used in an integrated regeneration process are those used for oxygenate conversion and olefin cracking, both for the purpose of producing light olefins (e.g., ethylene and propylene).
    Type: Application
    Filed: March 24, 2009
    Publication date: September 30, 2010
    Inventor: Andrea G. BOZZANO
  • Patent number: 7744744
    Abstract: An apparatus and process for regenerating cracking catalyst may include a regenerator, a distributor penetrating the bottom of the regenerator, a spent catalyst conduit, a return standpipe, and a recirculating standpipe, wherein the return standpipe and the recirculating standpipe are connected to the upper half of the regenerator. An apparatus for regenerating cracking catalyst may include a spent catalyst standpipe and a recirculation standpipe positioned on an inner side of the regenerator vessel.
    Type: Grant
    Filed: December 30, 2005
    Date of Patent: June 29, 2010
    Assignee: UOP LLC
    Inventors: Paolo Palmas, Frank S. Rosser, Jr., Patrick D. Walker
  • Publication number: 20090264279
    Abstract: This invention is directed to a method and apparatus for regenerating a catalyst used in an FCC unit, including providing a spent catalyst into an upper portion of a regenerator, maintaining a calcination phase, a gasification phase, and a combustion phase of fluidized catalyst in the regenerator, combusting carbon in the combustion phase and producing a combustion flue gas, reacting carbon in the gasification phase with the combustion flue gas to form a carbon monoxide rich flue gas, and calcining the spent catalyst with the carbon monoxide rich flue gas.
    Type: Application
    Filed: June 23, 2009
    Publication date: October 22, 2009
    Inventor: Brian W. Hedrick
  • Patent number: 7585803
    Abstract: A method of operating a continuous system for a catalyst regeneration process wherein the regeneration section includes a combustion zone, at least one oxygen boost zone, a halogenation zone and a drying zone in serial progression.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: September 8, 2009
    Assignee: UOP LLC
    Inventors: Scott J. Price, Paul R. Cottrell
  • Patent number: 7405174
    Abstract: A process for regeneration of a catalyst that comprises at least one EUO-structural-type zeolite in acid form and at least one hydro-dehydrogenating metal, used in a process for isomerization of a hydrocarbon feedstock that comprises aromatic compounds with eight carbon atoms, comprising at least a) a stage for eliminating a majority of the coke, deposited on said catalyst, by combustion in the presence of a gas that contains oxygen at a temperature that is less than or equal to 600° C., and b) a stage for oxychlorination of the product that is obtained from stage a), carried out between 200 and 550° C. in the presence of at least one gas mixture that contains at least oxygen, water and chlorine and/or at least one chlorinated compound, is described.
    Type: Grant
    Filed: September 1, 2005
    Date of Patent: July 29, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Sylvie Lacombe, Julia Magne-Drisch, Eric Sanchez
  • Patent number: 6780809
    Abstract: A particulate, modified chromium oxide catalyst for the polymerisation of ethylene or ethylene with &agr;-olefins, comprising: a) a chromium-oxide catalyst, b) a transition metal compound, and c) a catalyst activator. A method for the preparation of the catalyst comprises the steps of: a) subjecting a chromium oxide catalyst precursor, which comprises a chromium oxide compound combined with an inorganic support, to a temperature in the range of from 400 to 950° C.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: August 24, 2004
    Assignee: Borealis Technology Oy
    Inventors: Arild Follestad, Vidar Almquist, Ulf Palmqvist, Harri Hokkanen
  • Patent number: 6685681
    Abstract: A bandage for use with a vacuum source includes a wound dressing member to be placed in contact with a wound surface and a suction port associated with the wound dressing member. The member is configured with spacers contacting the wound surface to define suction space between the member and the wound surface. The member also includes holes in communication with the suction space. Passageways of the bandage are provided between the suction port and the holes.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: February 3, 2004
    Assignee: Hill-Rom Services, Inc.
    Inventors: Jeffrey S. Lockwood, Robert Petrosenko, James Robert Risk, Jr.
  • Patent number: 6579820
    Abstract: A process for regenerating a spent catalyst having coke deposits thereon in a catalyst regeneration vessel having a dense phase and a dilute phase, wherein the process comprises the steps of: (a) contacting the spent catalyst with a primary oxygen-containing gas in the dense phase, thereby combusting the coke, resulting in the formation of a combustion gas comprising nitrogen oxides and carbon monoxide which further reacts, thus reducing a majority of the nitrogen oxides to form elemental nitrogen; and (b) contacting the combustion gas with a secondary oxygen-containing gas, and typically a shield gas, at a location just above the interface between the dense phase and the dilute phase and also in the dilute phase, thereby oxidizing the remaining CO to CO2 without significant temperature rise in the dilute phase due to the after burn.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: June 17, 2003
    Assignee: The BOC Group, Inc.
    Inventors: Satish S. Tamhankar, Kirk Walton Limbach, Subodh Ganguly
  • Patent number: 6506702
    Abstract: The invention concerns a process for regenerating a catalyst in a fixed bed, for example a catalyst for reforming or for aromatic compound production, including a step for monitoring and controlling combustion completion which is carried out after the catalyst has undergone all of the combustion steps of the process. The monitoring and control step is carried out by injecting an oxygen-containing gas into the zone where monitoring and control takes place, the monitoring and control step being carried out under conditions which are more severe than those in the combustion steps. The monitoring and control step is carried out with an oxygen consumption of less than 10%. The temperature advantageously remains substantially constant.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: January 14, 2003
    Assignee: Institut Francais du Petrole
    Inventors: François-Xavier Brunet, Emmanuelle Bromet, Jean-Marie Deves, Dominique Humeau, Eric Sanchez
  • Patent number: 6133183
    Abstract: The invention concerns a process for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, comprising combustion (A), oxychlorination (B) and calcining (C) steps, in which at least one chlorinating agent (conduit 19), at least one oxygen-containing gas (conduit 18), and water (conduit 20) are introduced into the oxychlorination step such that the H.sub.2 O/HCl molar ratio is 3 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600.degree. C.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: October 17, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Marianne Capelle, Jean-Marie Deves, Frede ricfmann, Michel Thery
  • Patent number: 6121180
    Abstract: A method for regenerating a hydrocarbon conversion catalyst wherein at least a portion of a halogen-containing compound is precombusted in a precombustion zone, and the catalyst is regenerated in the presence of the halogen. By precombusting the halogen-containing compound in a precombustion zone rather than in the regeneration zone, this invention decreases the risk of permanent catalyst deactivation and of costly equipment damage in the regeneration zone. This method is adaptable to many processes for the catalyst conversion of hydrocarbons in which deactivated catalyst particles are regenerated in a moving bed.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: September 19, 2000
    Assignee: UOP LLC
    Inventor: Thomas John Gevelinger
  • Patent number: 6103652
    Abstract: The invention concerns a process for moving bed regeneration of a reforming or aromatic hydrocarbon production catalyst. The catalyst includes a support, at least one noble metal and at least one halogen. The process includes a combustion step in which the catalyst is treated in at least two successive combustion zones. Also, the process includes each combustion zone separated from adjacent combustion zones allowing catalyst to pass and preventing passage of gas, at least one oxygen-containing gas introduced into each zone and produced gases extracted from each zone, and the severity of the operating conditions in each zone increasing in the direction of catalyst flow. Advantageously, the combustion step ends in a zone for monitoring and controlling combustion completion characterized by a low or zero oxygen consumption.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: August 15, 2000
    Assignee: Institut Francois du Petrole
    Inventors: Fran.cedilla.ois-Xavier Brunet, Emmanuelle Bromet, Jean-Marie Deves
  • Patent number: 6048814
    Abstract: The invention concerns a process and unit for regenerating a catalyst for the production of aromatic compounds, in particular for reforming, the catalyst being in a moving bed, comprising combustion, oxychlorination and calcining steps, in which at least one chlorinating agent, at least one oxygen-containing gas, and water are introduced into the oxychlorination step such that the H.sub.2 O/HCl molar ratio is 1 to 50, the oxychlorination step being carried out in the presence of an oxychlorination gas containing less than 21% of oxygen and at least 50 ppm by weight of chlorine (based on HCl), and at a temperature of 350-600.degree. C., and in which the combustion step is carried out in at least two combustion zones, each zone being separated from the adjacent zones, and at least one gas charged with oxygen is introduced into each zone, the gases produced being extracted from each zone, and in which the severity of the operating conditions increases in the direction of flow of the catalyst.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: April 11, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Marianne Capelle, Jean-Marie Deves, Frederic Hoffmann, Michel Thery, Fran.cedilla.ois-Xavier Brunet, Emmanuelle Bromet
  • Patent number: 5837637
    Abstract: The present invention provides a process for continuously regenerating a catalyst or an adsorbent which comprises the steps of:(a) establishing an ebullating or expanded bed by passing a gaseous stream upwardly through a plurality of particles confined in a regeneration zone,(b) providing a looped pathway in said ebullating bed,(c) passing a spent catalyst into said ebullating bed and moving said spent catalyst along said multi-looped pathway, and(d) removing a regenerated catalyst from said ebullating bed.In the process of this invention, the looped pathway requires substantially all of the particles to traverse a pathway that varies in direction by about 180.degree. from beginning to end of each loop in the pathway. In this process, the particles may be regenerated by lowering the carbon deposited thereon from a range of from about 8 to about 17 wt. % to a range of from about 0.3 to 1.5 wt. %, and the sulfur content of from about 6 to 9 wt. % to a range of from about 0.4 to 1.4 wt. %.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: November 17, 1998
    Assignee: Tricat Industries, Inc.
    Inventors: Cloyd P. Reeg, Phillip K. Maher, David K. Morash, James J. Prosser
  • Patent number: 5547910
    Abstract: A method and system for cracking hydrocarbons and regeneration of the catalyst is described with particular emphasis directed to partially restoring the activity of the catalyst after an initial hydrocarbon conversion use by heat soaking the catalyst at an elevated temperature before use in a second hydrocarbon conversion zone.This case is a division of application Ser. No. 595,833, filed Jul. 14, 1975.
    Type: Grant
    Filed: February 6, 1986
    Date of Patent: August 20, 1996
    Assignee: Mobil Oil Corporation
    Inventors: Edward J. Demmel, Hartley Owen
  • Patent number: 5348921
    Abstract: The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: September 20, 1994
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Larry A. Bissett, Larry D. Strickland, John M. Rockey
  • Patent number: 5346610
    Abstract: A process and apparatus for regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator. Spent catalyst is regenerated in a fast fluidized bed coke combustor heated by direct contact heat exchange with catalyst recycled to the coke combustor via an internal "trough" trap. Catalyst recycle flow to the combustor is controlled by varying gas flow in the trough trap.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: September 13, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5324696
    Abstract: A catalyst, e.g., a cracking catalyst, and a part of the regeneration fumes are drawn off from the dense catalytic bed of a second regenerator (9) and are introduced by force of gravity into an external exchanger (21) at a junction point beneath the level of the dense bed of the second regenerator. The heat exchange takes place in the bottom part of the exchanger below the junction point. Between the bottom end of the exchanger and the region above the junction point a dense bed zone is formed at a level which is substantially at the height of the dense bed in the regenerator and a discharge zone (27), of suitable size, for the regeneration gases and fluidization gas. The gases and fumes from the exchanger are removed in the diluted fluidized phase from the second regenerator through a conduit (28), while the catalyst is recycled in to the bed of the first regenerator through a conduit (34).
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: June 28, 1994
    Assignee: Institut Francais du Petrole
    Inventors: Regis Bonifay, Frederic Hoffmann, Renaud Pontier, Thierry Gauthier
  • Patent number: 5275990
    Abstract: A method is provided for regenerating a molecular sieve-free resid hydroprocessing catalyst for use with an ebullated bed reaction process comprising at least one hydrogenation metal and at least one Group IIA metal deposited on an inorganic oxide support wherein the catalyst contains a pore volume of pores having a diameter greater than 1200 Angstroms of at least 0.05 cc/gm. The method comprises the steps of contacting the molecular sieve-free resid hydroprocessing catalyst with a contaminant metal-containing hydrocarbon feedstream in a first contacting step at conditions sufficient to deposit contaminant metals and coke onto the catalyst; and contacting the coke-deactivated, contaminant metal-containing, molecular sieve-free catalyst with an oxygen-containing gas in a second contacting step at oxidation conditions sufficient to remove a substantial amount of the coke from the coke-deactivated, contaminant metal-containing, molecular sieve-free catalyst.
    Type: Grant
    Filed: October 2, 1992
    Date of Patent: January 4, 1994
    Assignee: Amoco Corporation
    Inventors: Frederick T. Clark, Albert L. Hensley, Jr.
  • Patent number: 5268089
    Abstract: Oxides of nitrogen (NO.sub.x) emissions from an FCC regenerator are reduced by forcing the regenerator to operate between full and partial CO burn mode. Operating with less than 1 mole % O2 and up to 1 or 2% CO in the flue gas creates conditions which oxidize nitrogen compounds in coke on spent catalyst to NOx, and simultaneously convert NOx in the regenerator to nitrogen. A downstream CO boiler can burn this low CO flue gas without producing large amounts of NOx. Most NOx emissions can be eliminated. An apparatus, with the regenerator air:coke ratio controlled by both CO and O2 analyzers monitoring regenerator flue gas, is also disclosed.
    Type: Grant
    Filed: June 24, 1992
    Date of Patent: December 7, 1993
    Assignee: Mobil Oil Corporation
    Inventors: Amos A. Avidan, Mark F. Mathias, Raghu K. Menon, Joseph F. Sodomin, III, Scott A. Stevenson, Gerald J. Teitman
  • Patent number: 5245093
    Abstract: A process for reacting a fluid phase (gaseous and/or liquid phase) in contact with a solid phase in a reaction zone, wherein the improvement in said process comprises reacting the fluid phase in contact with the solid phase in a horizontally-oriented fluidized bed vessel. The vessel includes at least two compartments or stages, and includes means for vibrating the vessel. The process of the present invention enables one to effect fluidization of the solid phase independently of the flow rate or velocity of the fluid phase, thus enabling proper contact time of the fluid phase with the solid phase and minimizing the amount of fluid phase reactant to be recycled.
    Type: Grant
    Filed: January 26, 1989
    Date of Patent: September 14, 1993
    Assignee: ABB Lummus Crest Inc.
    Inventor: George Ember
  • Patent number: 5212129
    Abstract: The provision and operation of backmix coolers is facilitated by a cooler arrangement that has the backmix portion of the cooler in an inverted position. In this position the heat exchange portion of the cooler is located above the source of hot catalyst. Hot catalyst for heat exchange in the cooler enters and leaves the heat exchange zone from below the location of the heat exchange tubes. The inverted position prevents any collection of debris in the bottom of the cooler, eliminates high velocity impingement of fluidizing medium on the tube, and facilitates the incorporation of the cooler in FCC units by avoiding interference with other equipment.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: May 18, 1993
    Assignee: UOP
    Inventor: David A. Lomas
  • Patent number: 5202294
    Abstract: A process and apparatus for the regeneration of spent FCC catalyst in a single vessel are disclosed. In one embodiment, catalyst is at least partially regenerated in a primary stage comprising a fast or turbulent fluidized bed. The flue gas is discharged up, with some and preferably most of the catalyst discharged laterally, through windows, into a second fluidized bed, preferably disposed as an annulus about the first. In another embodiment a cyclone separator is closely coupled to, but spaced from, the primary regeneration stage, to rapidly separate catalyst from first stage flue gas, and minimize thermal stress.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: April 13, 1993
    Assignee: Mobil Oil Corporation
    Inventor: Michael F. Raterman
  • Patent number: 5198397
    Abstract: A process and apparatus for multi-stage fluidized bed regeneration of spent FCC catalyst in a single vessel. At least two isolated relatively dense phase fluidized beds are disposed beneath a common dilute phase region. Spent catalyst discharged into a primary regeneration stage is regenerated to produce flue gas and partially regenerated catalyst, which preferably overflows into the second stage. Flue gas and entrained catalyst from each fluidized bed are processed in two trains of separation means, preferably cyclones. The inlets of each train are disposed above the isolated fluidized beds, and are effectively separated although sharing an open dilute phase region.
    Type: Grant
    Filed: November 25, 1991
    Date of Patent: March 30, 1993
    Assignee: Mobil Oil Corporation
    Inventor: Michael F. Raterman
  • Patent number: 5183558
    Abstract: A process and apparatus for fluidized catalytic cracking of heavy oils is disclosed using a modified high efficiency catalyst regenerator. A fast fluidized bed coke combustor, which is essentially free of gas/catalyst separation means, partially regenerates catalyst and discharges a steam laden flue gas and catalyst into a dilute phase transport riser. Closed cyclones separate catalyst from steam laden flue gas exiting the transport riser outlet. This flue gas is isolated from a second fluidized bed of catalyst maintained in a vessel containing the transport riser and closed cyclones. Coke combustion in the drier region of the second fluidized bed is possible. Catalyst deactivates less in the second fluidized bed because it is drier.
    Type: Grant
    Filed: December 31, 1990
    Date of Patent: February 2, 1993
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5160426
    Abstract: A process and apparatus for achieving hot catalyst stripping of spent FCC catalyst in a stripper mounted over a bubbling bed regenerator. Hot catalyst stripping is achieved by indirect transfer of heat from the regenerator to the stripper. Heat pipes, surface modifications such as fins on the stripper vessel, or use of a stripper in, or connective with, a heat exchange tube bundle may be used to heat spent catalyst with heat from the regenerator dilute phase, without transferring catalyst from the regenerator. The benefits of hotter catalyst stripping are achieved, without increasing catalyst traffic in the regenerator.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: November 3, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Amos A. Avidan
  • Patent number: 5158919
    Abstract: A process and apparatus for fluidized bed catalyst regeneration. A mixture of spent catalyst, recycled hot regenerated catalyst and regeneration gas are charged to a riser having an outlet connective with a coke combustor immersed in a fluidized bed of catalyst. The coke combustor outlet is covered by the dense phase fluidized bed. Additional combustion air may be added to the fluidized bed of catalyst covering the coke combustor outlet for additional catalyst regeneration. Indirect heat exchange may heat spent catalyst in the riser and/or the coke combustor.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: October 27, 1992
    Assignee: Mobil Oil Corporation
    Inventors: James H. Haddad, Hartley Owen, Mark S. Ross
  • Patent number: 5143874
    Abstract: A process and apparatus for high efficiency regeneration of spent FCC catalyst in an existing, single dense bed FCC regenerator is disclosed. Spent catalyst is added to a coke combustor immersed within the existing regenerator vessel catalyst bed. A dilute phase transport riser, above and connective with the coke combustor discharges a mixture of regenerated catalyst and flue gas. Regenerated catalyst collects around and under the coke combustor. The spent catalyst inlet, and combustion air inlet, are preferably immersed in, and in a heat exchange relationship with, the bed of hot regenerated catalyst. Heat pipes, or fins may be used to increase heat transfer into the coke combustor from the dense bed. Heating the coke combustor by indirect heat exchange, rather than recycle of hot regenerated catalyst, reduces particulates emissions and saves the energy needed to recycle catalyst in the regenerator.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: September 1, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Mark S. Ross
  • Patent number: 5139649
    Abstract: A process and apparatus for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A coke combustor vessel, which may be partially or totally open to the dilute phase above the bubbling bed, is added to the existing regenerator vessel. Spent catalyst is discharged into the coke combustor, regenerated in a turbulent or fast fluidized bed, then discharged into the dilute phase region above the bubbling bed, either via a deflector or by simply overflowing the combustor. Regeneration of catalyst is completed in the bubbling dense bed, and/or an annular fast fluidized bed surrounding the coke combustor. Catalyst may be recycled from the dense bed to the coke combustor either by a flow line, or by adjusting relative heights of bubbling to fast fluidized bed.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: August 18, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5130012
    Abstract: A fluidized catalytic cracking process using a high efficiency regenerator comprising a coke combustor, a dilute phase transport riser, and a second fluidized bed with catalyst recirculation to the coke combustor, is operated to reduce NO.sub.x emissions in the regenerator flue gas. The amount of catalyst recirculation from the second fluidized bed to the coke combustor or combustion air addition or preferably both are adjusted based on continuous or periodic measurement of a process parameter of the FCC regenerator which directly or indirectly measures the NO.sub.x content of regenerator flue gas. Operation with restricted air or catalyst recirculation degrades coke combustor operation, shifts some regeneration to downstream portions of the regenerator, and reduces NO.sub.x emissions.
    Type: Grant
    Filed: January 24, 1991
    Date of Patent: July 14, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Michael S. Edwards, David A. Land, Catherine L. Markham, Joseph R. Misiewicz, John P. Schields
  • Patent number: 5126036
    Abstract: A process and apparatus for regeneration of coked catalyst used in the fluidized cracking of heavy oils is disclosed. A high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed is used but modified so that at least some coked catalyst is added directly to the second fluidized bed. The coked catalyst can be heated by direct contact heat exchange in the second fluidized bed and then charged to the coke combustor, or the coked catalyst can be regenerated in the second fluidized bed, or some combination of both. Adding catalyst to the second fluidized bed increases the coke burning capacity of these regenerators, and/or permits a drier regeneration.
    Type: Grant
    Filed: November 5, 1991
    Date of Patent: June 30, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Hartley Owen
  • Patent number: 5120691
    Abstract: A process and apparatus for the heat regulation of fluidized or fluid catalyst beds are described, the apparatus having a fluid bed heat exchanger. According to the invention, a pulverulent solid is made to flow essentially from the base of an enclosure (1) into a heat exchanger (6) having an internal separating partition (22) which defines two elongated, adjacent compartments (23, 24) communicating at their lower part. In the compartment in which the pulverulent solid flows downwards, the fluidization speed or rate is between 0.1 cm to 2 m/s, whereas in the compartment wherein the pulverulent solid rises again into the heat exchanger (6), the fluidization speed is between 0.1 and 6 m/s. The invention can be used for refining reaction (e.g., catalytic reforming), for the regeneration of a fluidized bed catalytic cracking catalyst of a petroleum or oil charge, or for the combustion of coal.
    Type: Grant
    Filed: June 18, 1990
    Date of Patent: June 9, 1992
    Assignee: Institut Francais du Petrole
    Inventors: Renaud Pontier, Frederic Hoffmann
  • Patent number: 5110775
    Abstract: A two-stage process and apparatus for the regeneration of fluidized catalytic cracking (FCC) catalyst is disclosed. A primary regenerator, a single dense bed with a spent catalyst inlet, a source of oxygen-containing gas, a flue gas outlet and a regenerated catalyst outlet, is supplemented with a secondary regenerator. The secondary regenerator has its own source of air for combustion and takes particles from a lower portion of the dense bed in the primary regenerator. Combustion gases, and some solids, are discharged from the secondary regenerator into the primary regenerator. Hot, decoked material is withdrawn from the base of the secondary regenerator for use in the catalytic cracking reaction. Preferably, a dense, fast settling additive is used with a conventionally sized FCC catalyst. These two materials can be added together to the primary regenerator and separated by elutriation therein into two catalyst phases.
    Type: Grant
    Filed: December 28, 1990
    Date of Patent: May 5, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Hartley Owen
  • Patent number: 5108968
    Abstract: A process for treating catalytic particles in a vertical chamber is disclosed. The catalytic particles comprise spent catalysts from such hydroprocesses as hydrocracking and hydroreforming. The process comprises suspending the catalytic particles in a gaseous atmosphere of a vertical chamber for a time sufficient to remove the waste products from the catalytic particles. The process can be used to remove carbonaceous and sulfur deposits from the surface of the particles as well as volatile hydrocarbons and hydrates.
    Type: Grant
    Filed: April 6, 1990
    Date of Patent: April 28, 1992
    Assignee: Recat, Inc.
    Inventors: Robert E. Ellingham, James W. Barnes