Plural Distinct Serial Combustion Stages Patents (Class 502/43)
  • Patent number: 5106799
    Abstract: A process and apparatus for fluidized bed combustion using a dense phase combustion zone over a dilute phase combustion zone. When used to regenerate FCC catalyst containing coke with relatively large amounts of NO.sub.x precursors, the catalyst is added to and partially regenerated in the dense phase zone and then falls down into the dilute phase zone. Most of the combustion air is added to the dilute phase and rises into and fluidizes the dense phase zone. NO.sub.x formed in the dilute phase is reduced to N.sub.2 in the dense phase.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: April 21, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Gary J. Green, Tsoung Y. Yan
  • Patent number: 5077251
    Abstract: A process for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor. Second stage catalyst regeneration occurs in the second fluidized bed. The amount of combustion air added to, and conditions in, the coke combustor are controlled to limit CO combustion, while the second stage of regeneration, in the second fluidized bed, achieves complete CO combustion. Controlled multi-stage regeneration reduces steaming or deactivation of catalyst during regeneration, increase coke burning capacity, and reduces NOx emissions.
    Type: Grant
    Filed: July 17, 1990
    Date of Patent: December 31, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5077252
    Abstract: A process and apparatus for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor. Second stage catalyst regeneration occurs in the second fluidized bed. The amount of combustion air added to both regeneration stages is set to maintain partial CO combustion in both stages. Controlled multi-stage regeneration reduces the steaming or deactivation of catalyst during regeneration, maximizes coke burning capacity of the regenerator, and minimizes or eliminates NOx emissions.
    Type: Grant
    Filed: July 17, 1990
    Date of Patent: December 31, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5066627
    Abstract: A process for simultaneously heating and cooling of spent FCC catalyst during regeneration in a high efficiency FCC regenerator, one using a fast fluidized bed coke combustor. The coke combustor burns coke from spent catalyst in a turbulent or fast fluidized bed, and discharges catalyst and flue gas up into a dilute phase transport riser. Catalyst is separated into flue gas and a bubbling dense bed of catalyst. The coke combustor is heated by recycling hot catalyst from the bubbling dense bed and simultaneously cooled by a backmixed heat exchanger. Catalyst flows from the combustor to the cooler and is displaced back into the combustor by adding air to the catalyst in the cooler. Heating promotes rapid coke combustion, while cooling reduces thermal and hydrothermal deactivation of the spent catalyst.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: November 19, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5059302
    Abstract: The present invention features the use of a particulate sorbent and a particulate FCC catalyst, which are physically separable, sequentially in the same FCC riser, followed by separation of commingled spent catalyst and sorbent particles from vapors, and the subsequent primary partial regeneration and heat up of spent sorbent particles and catalysts particles in an oxygen deficient burning zone, followed by physical separation of partially regenerated catalyst and sorbent particles, preferably using a cyclonic classifier to effect the separation. This is followed by secondary regeneration of the resulting segregated partially regenerated sorbent and catalyst streams in oxygen rich combustion zones to fully regenerate sorbent and catalyst particles.
    Type: Grant
    Filed: April 26, 1990
    Date of Patent: October 22, 1991
    Assignee: Engelhard Corporation
    Inventors: Harold N. Weinberg, W. Benedict Johnson, Michael F. Raterman, Barry K. Speronello, William J. Reagan, Larry G. Sherman
  • Patent number: 5047140
    Abstract: A process and apparatus are disclosed for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added alongside an existing regenerator vessel, and spent catalyst is discharged into a transfer pot beneath the existing dense bed, then into the coke combustor. Catalyst is regenerated in a turbulent or fast fluidized bed, and discharged into the dilute phase region above the existing bubbling dense bed. The discharge line preferably encompasses, and is in a heat exchange relationship with, the spent catalyst standpipe. Discharge catalyst is collected in the bubbling dense bed surrounding the coke combustor, and may be given an additional stage of regeneration. Catalyst may be recycled from the dense bed to the transfer pot.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: September 10, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5043055
    Abstract: A process and apparatus for achieving multistage, hot catalyst stripping of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. Hot catalyst stripping is achieved by lifting regenerated catalyst into the conventional stripper or to a secondary catalyst stripper under the primary stripper. Spent catalyst is heated by direct contact heat exchange with hot regenerated catalyst. Three different types of lift gas may be used to transport catalyst from the regenerator to the hot stripper, a light reactive hydrocarbon, an inert, or steam.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: August 27, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5034115
    Abstract: A process and apparatus are disclosed for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A coke combustor vessel is immersed in, and in open fluid communication with, the bubbling dense bed of the existing regenerator vessel. Spent catalyst is discharged into the coke combustor, mixes with hot regenerated catalyst which flows into the coke combustor, and regenerated with combustion air in a turbulent or fast fluidized bed. Catalyst and flue gas are discharged up into a dilute phase transport riser, preferably into cyclone which separate hot regenerated catalyst from flue gas. Regenerated catalyst is collected in the bubbling dense bed surrounding the coke combustor, and some is recycled by flowing into the coke combustor for direct contact heat exchange.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: July 23, 1991
    Assignee: Mobil Oil Corporation
    Inventor: Amos A. Avidan
  • Patent number: 5032252
    Abstract: A process and apparatus for achieving multistage, hot catalyst stripping of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A secondary or hot catalyst stripper is placed under the primary stripper and within the existing regenerator vessel. Spent catalyst from the primary stripper is heated in the secondary stripper by at least one of immersion in the bubbling dense bed of hot regenerated catalyst, addition of hot regenerated catalyst recovered from the discharged into the coke combustor and regenerated in a turbulent or fast fluidized bed, and discharged up into a dilute phase transport riser which preferably encompasses, and is in a countercurrent heat exchange relationship with, the spent catalyst standpipe. Regenerated catalyst is discharged from the dilute phase transport riser, and collected in the bubbling dense bed surrounding the coke combustor.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: July 16, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5032251
    Abstract: A process and apparatus for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added to the existing regenerator vessel, and spent catalyst is discharged into the coke combustor and regenerated in a turbulent or fast fluidized bed, and discharged up into a dilute phase transport which preferably encompasses, and is in a countercurrent heat exchange relationship with, the spent catalyst standpipe. Regenerated catalyst is discharged from the dilute phase transport riser, and collected in the bubbling dense bed surrounding the coke combustor. Catalyst may be recycled from the dense bed to the coke combustor for direct contact heat exchange. Catalyst coolers may be used on catalyst recycle lines to the coke combustor, or on the line returning regenerated catalyst to the cracking reactor.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: July 16, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5021144
    Abstract: A process is disclosed wherein a regenerator is operated in an incomplete mode of combustion to regenerate FCC catalyst to burn coke contained thereon in the presence of a CO oxidation promoter. The quantity of the CO oxidation promoter is regulated so that there is at least two and preferably at least three times the minimum quantity of CO oxidation promoter present than necessary to prevent temperature excursions in the dilute phase caused by afterburn combustion of CO to CO.sub.2. The regeneration zone is maintained in an incomplete mode of combustion defined by having a CO content greater than 1.0 percent and preferably from 1 to 10 percent.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: June 4, 1991
    Assignee: Shell Oil Company
    Inventor: Diana M. Altrichter
  • Patent number: 5013425
    Abstract: A method of converting a side by side FCC arrangement adds a new reactor vessel and uses the regenerator vessel and reactor vessel to provide a regeneration section having at least three stages of regeneration that is used as part of an enlarged FCC process. In simplest form, the conversion method calls for the use of the regeneration vessel as a first-stage regeneration zone, the use of the reactor vessel as a second-stage regeneration zone, and the use of the spent catalyst stripper as a third stage of regeneration. This arrangement provides a second stage of regeneration that is positioned to facilitate the addition of partially regenerated catalyst to the stripping zone to facilitate the operation of a hot catalyst stripping section.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: May 7, 1991
    Assignee: UOP
    Inventor: Ismail B. Cetinkaya
  • Patent number: 5011592
    Abstract: A process for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor, at full CO oxidation conditions. The second stage of catalyst regeneration occurs in the second fluidized bed, at partial CO combustion conditions. The process permits regeneration of spent FCC catalyst while minimizing NOx exmissions and achieving significant reduction of SOx.
    Type: Grant
    Filed: July 17, 1990
    Date of Patent: April 30, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Hartley Owen, Paul H. Schipper
  • Patent number: 5009769
    Abstract: An improved process and apparatus is provided for simultaneously, independently catalytically cracking dissimilar hydrocarbon feedstocks at elevated temperatures in separate riser reactors and under respective operating parameters which permit selective conversion to desired products, wherein catalyst regeneration is conducted in two steps comprising separate relatively lower and higher temperature regeneration stages.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: April 23, 1991
    Assignee: Stone & Webster Engineering Corporation
    Inventor: Alan R. Goelzer
  • Patent number: 5006495
    Abstract: An FCC catalyst regeneration technique in which the catalyst is regenerated in a dense bed regenerator. Regenerator effluent gases are collected from different parts of the regenerator vessel in a common collection zone and passed through the catalyst separation cyclones from the common collection zone. Removal of nitrogen oxides from the regeneration effluent gases is enhanced by passing spent cracking catalyst through the effluent gases from a secondary spent catalyst inlet in the upper part of the regeneration vessel. Coke on the spent catalyst effects a reduction of nitrogen oxide (NOx) species in the effluent gases to nitrogen.
    Type: Grant
    Filed: February 26, 1990
    Date of Patent: April 9, 1991
    Assignee: Mobil Oil Corporation
    Inventors: David A. Pappal, Michael S. Sarli
  • Patent number: 4973398
    Abstract: A method and apparatus are disclosed to reduce the amount of coke and unstripped hydrocarbon flowing to the regenerator in an FCC unit. The catalyst stripper section is heated by indirect heat exchange with hot regenerator flue gas.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: November 27, 1990
    Assignee: Mobil Oil Corp.
    Inventors: David A. Pappal, Paul H. Schipper
  • Patent number: 4968404
    Abstract: In a fluid catalytic cracking process, coke is burned from spent catalyst at elevated temperature in a vertically arranged regenerator vessel. The regenerator vessel contains a lower, dense phase oxidation zone to which spent catalyst is introduced and an upper, dilute phase oxidation zone. Catalyst is fluidized and oxidized by means of air which is introduced in an amount of 5 vol % to 15 vol % to a lower air distributor at the bottom of the dense phase zone. Spent catalyst is discharged above the lower air distributor. The balance of the air is distributed in a horizontal plane in the dense phase above the catalyst discharge. As a result, a substantial proportion of the coke and carbon monoxide is burned in the dense phase zone at a lower temperature. A reduced amount of carbon monoxide is carried over to the dilute phase where higher temperature oxidation occurs.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: November 6, 1990
    Assignee: Texaco Inc.
    Inventors: Henry C. Chan, Gary E. Collier
  • Patent number: 4965232
    Abstract: A catalyst regeneration process effected in an apparatus which comprises two regeneration chambers, a heat exchanger, means for withdrawing from the second chamber a controlled fraction of hot catalyst for the purpose of maintaining the temperature in that chamber substantially at a first desirable value of less than 950.degree. C., and preferably at 910.degree. C., means for transferring this fraction of hot catalyst to the heat exchanger for the purpose of cooling it, means for the discharge of the cooled catalyst from the heat exchanger and the reinjection of the cooled catalyst into the first chamber, and means, controlled by the means for measuring the temperature in the first chamber, for regulating the supply of combustion fluid to the first chamber for the purpose of maintaining said temperature substantially at a second desired value lower than 730.degree. C. and preferably ranging from 650.degree. to 710.degree. C.
    Type: Grant
    Filed: March 9, 1989
    Date of Patent: October 23, 1990
    Assignees: Compagnie de Raffinage et de Distribution Total France, Institut Francais du Petrole
    Inventors: Jean-Louis Mauleon, Jean-Bernard Siguad, Renaud Pontier, Frederic Hoffmann
  • Patent number: 4959334
    Abstract: A process for the regeneration of a catalyst by combustion of the coke deposited thereon during a hydrocarbon conversion reaction in which process more than 50 percent of the coke is burned in at least one regeneration chamber operating with a fluidized bed, wherein the upper portion of the fluidized bed the suspension of catalyst particles in said chamber is slowed down due to a substantial increase in the diameter of the regeneration chamber so that the superficial velocity of the rising fluids which no longer contain any oxygen is reduced to a value ranging from 0.5 to 1.5 meters/second, that is, to a value corresponding to the fluidization conditions in a dense fluidized bed.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: September 25, 1990
    Assignee: C. Compagnie de Raffinage et de Distribution
    Inventors: Jean-Louis Mauleon, Jean-Bernard Sigaud
  • Patent number: 4904372
    Abstract: An improved fluidized catalytic cracking-catalyst regeneration process for catalytically cracking heavy hydrocarbon feedstocks is provided which comprises first and second, relatively lower and higher temperature, catalyst regeneration zones, wherein CO-rich effluent flue gas from the first regeneration zone is combusted in a CO-incinerator/combustor means to substantially convert all CO present therein to CO.sub.2. The effluent gas from the CO-incinerator/combustor is then combined with the effluent flue gas from the second regeneration zone, with the combined streams thereafter being sent to an expansion turbine-compressor means to recover the work energy therefrom and to provide at least all the compressed air requirements of the first and second regeneration zones, and preferably in addition the compressed air requirements of the CO-incinerator/combustor means.
    Type: Grant
    Filed: November 18, 1988
    Date of Patent: February 27, 1990
    Assignee: Stone & Webster Engineering Corporation
    Inventor: Alan R. Goelzer
  • Patent number: 4875994
    Abstract: A process and apparatus for cracking heavy hydrocarbons using a mixture of fluid cracking catalyst and a demetallizing additive differing in physical characteristics from the cracking catalyst is described. A heavy, metals containing feed such as a resid contacts demetallizing additive in the base of a riser reactor. The demetallized resid is cracked by contact with a stream of hot, regenerated catalyst. A mixture of metal containing additive, deactivated cracking catalyst, and cracked products is discharged from the riser. The metal containing additive and deactivated catalyst are stripped, preferably with steam, and charged to a two-stage regenerator. The first stage of the regenerator partially regenerates the cracking catalyst and separates it by elutriation from the demetallizing additive, which accumulates as a dense phase fluidized bed in a lower portion of the first stage regenerator.
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: October 24, 1989
    Inventors: James H. Haddad, Hartley Owen, Klaus W. Schatz
  • Patent number: 4868144
    Abstract: A multistage process for reducing NO.sub.x in flue gas from fluid catalytic cracking catalyst regeneration. Flue gas is preferably removed after each stage. NO.sub.x formed in each regeneration stage is converted to N.sub.2 prior to discharge from a stage by operating at least the downstream ends of each regeneration stage at oxygen-lean conditions. Staged regeneration can be achieved by passing spent catalyst through a transport reactor in plug type flow and sequentially contacting the catalyst with a plurality of oxygen-containing streams.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: September 19, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Joseph A. Herbst, Hartley Owen, Paul H. Schipper
  • Patent number: 4851374
    Abstract: A continuous regenerator for the two-stage regeneration of hot coked fluid catalytic cracking catalyst, and a method for regenerating coked catalyst by combustion with air and with reduced emissions of nitrogen oxides, or with reduced emissions of any two or more of the pollutants which include nitrogen oxides, sulfur oxides and carbon monoxide.
    Type: Grant
    Filed: May 29, 1987
    Date of Patent: July 25, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Tsoung Y. Yan, Gary J. Green
  • Patent number: 4843051
    Abstract: An FCC catalyst regeneration technique in which the catalyst is regenerated in a dense bed regenerator. Regeneration effluent gases are collected from different parts of the regenerator vessel in a common collection zone and passed through the catalyst separation cyclones from the common collection zone. The cyclones may be arranged with their inlet horns adajcent one another in the common collection zone or a cyclone inlet manifold with a common inlet may be connected to the cyclone inlets. The inlet port to the manifold may be extended to form an elongated vertical duct through which regeneration effluent gases and entrained catalyst pass from the dilute phase of the dense bed to the cyclone so that mixing of the effluent gases is promoted to ensure combustion in residual quantities of oxygen present in the effluent gases before the gases enter the cyclones. Improved operating flexibility is obtained together with a reduced likelihood of cyclone damage as a result of localized high temperature excursions.
    Type: Grant
    Filed: July 9, 1987
    Date of Patent: June 27, 1989
    Assignee: Mobil Oil Corporation
    Inventors: Richard C. Kovacs, Frederick J. Krambeck, Michael S. Sarli
  • Patent number: 4822761
    Abstract: A process for upgrading residual portions of crude oils comprising metal contaminants and Conradson Carbon contributing components by the combination of thermal visbreaking with fluid inert solids and catalytic upgrading of naphtha and higher boiling components of thermal visbreaking in separate systems of riser conversion and solids regeneration is discussed. Heat management of the regeneration systems is restricted in substantial measure by a novel external solids heat exchange apparatus arrangement utilized to partially cool hot regenerated solids utilized in the solids regeneration systems.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: April 18, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, Lloyd E. Busch, Oliver J. Zandona
  • Patent number: 4789459
    Abstract: The invention concerns a process for recovering power in a fluid catalytic cracking unit used particularly for the treatment of heavy charges, wherein at least a portion of the power available in the gas flows withdrawn from two catalyst regenerators (4) and (21) of a fluid bed catalytic cracking unit are recovered.According to the invention the fumes from regenerator (4) are fed to one of the stages of a turbine (35), the pressure in this stage being lower than the pressure of the fumes from regenerator (4) and the fumes from regenerator (21) (whose pressure is lower than that prevailing in the first regenerator (4)) are fed to another stage of the same turbine (35) whose pressure is lower than that of the stage to which the fumes of regenerator (4) are supplied.
    Type: Grant
    Filed: October 17, 1986
    Date of Patent: December 6, 1988
    Assignee: Institut Francais du Petrole
    Inventors: Daniel Lumbroso, Jean-Paul LePage
  • Patent number: 4786400
    Abstract: A dual riser cracking operation in combination with sequential stages of catalyst regeneration in which the second regeneration stage is a riser regenerator is described in combination with deep solvent deasphalting a vacuum resid. The deasphalted resid is subjected to hydrogenation treatment prior to cracking thereof in a riser cracking zone in admixture with a heavy vacuum gas oil which may or may not be hydrogenated prior to cracking thereof. Lower boiling fractions of the crude oil are subjected to catalytic cracking in a separate riser cracking zone. Partially regenerated catalyst of dense fluid bed regeneration may be employed in the heavy oil feed riser cracking operation charged with deasphalted oil. The partially regenerated catalyst may be used alone or in combination with more completely regenerated catalyst of the riser regeneration operation.
    Type: Grant
    Filed: September 10, 1984
    Date of Patent: November 22, 1988
    Inventor: Carl D. Farnsworth
  • Patent number: 4780195
    Abstract: The invention is particularly concerned with controlling the two stage regeneration temperatures of the RCC residual oil cracking unit below 760.degree. C. (1400.degree. F.) by effecting a first stage regeneration with direct injection of water in an oxygen lean atmosphere to product CO rich flue gases under temperature conditions restricted not to substantially exceed 732.degree. C. (1350.degree. F.) preferably less than 732.degree. C. (1350.degree. F.) thereby partially regenerating the catalyst. The partially regenerated catalyst is withdrawn and directly cooled with boiler feed water to produce steam in an external catalyst cooler before passing the catalyst to a second stage catalyst regeneration for contact with an oxygen rich atmosphere restricted not to exceed 760.degree. C. (1400.degree. F.) and preferably maintain less than 760.degree. C. (1400.degree. F.). The catalyst regenerated by this technique comprising residual coke less than 0.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Charles B. Miller
  • Patent number: 4755282
    Abstract: This process discloses a reduction in the content of ammonia in a regeneration zone off gas of a fluid catalytic cracking unit by the select recycle of certain sized ammonia decomposition catalyst particles. The ammonia decomposition may be aided by injection of NO.sub.x into the off gas. The particles are acquired from a separation means through which is passed the regeneration zone off gas. A solid-free regeneration zone off gas and a stream of solid particles, including a noble metal dispersed on an inorganic support, having a size of from 10 to 40 microns, are acquired. The latter segregated particles are then injected into the regeneration zone at a predetermined make-up rate to insure a very short residence time in the dense phase of the regeneration zone and to provide a relatively constant concentration of the NH.sub.3 decomposition catalyst in the dilute phase of the regeneration zone to convert NH.sub.3 to N.sub.2 and water vapor.
    Type: Grant
    Filed: July 22, 1987
    Date of Patent: July 5, 1988
    Assignee: Shell Oil Company
    Inventors: Norman C. Samish, John E. Gwyn
  • Patent number: 4744962
    Abstract: A regeneration zone for fluid catalytic cracking contains ammonia (NH.sub.3) when the regeneration zone is operated in a partial combustion mode as defined by a content of CO of between 1 and 6 percent by volume. If the ammonia is not removed from the regeneration zone off gass, the same will be passed to a CO combustion zone where, in the presence of oxygen, CO is oxidized to CO.sub.2 and some of the ammonia will undesirably be oxidized to NO.sub.x. This invention reduces the presence of ammonia in the feed gas to a CO combustion zone of an FCC process by the introduction of a NO.sub.x -containing gas to dilute phase of a regeneration zone or to a regeneration zone off gas. Ammonia, NO.sub.x and oxygen present in the regeneration zone off gas of the regeneration zone, will tend to react to produce nitrogen and water vapor, which then is passed to the CO combustion zone for CO oxidation to CO.sub.2. Where the addition of NO.sub.x is made at temperatures greater than 1700.degree. F.
    Type: Grant
    Filed: July 22, 1987
    Date of Patent: May 17, 1988
    Assignee: Shell Oil Company
    Inventors: Gregory L. Johnson, Norman C. Samish, Diana M. Altrichter
  • Patent number: 4744883
    Abstract: In a reduced crude conversion the catalyst is regenerated with mixture of oxygen-enriched gas and H.sub.2 O either as steam or preferably as water to provide additional expansion and facilitate fluidization, while converting coke on catalyst to CO and H.sub.2 with minimum CO.sub.2 formation. The CO can be combined with hydrogen to produce methane, methanol or Fischer-Tropsch liquid hydrocarbons or can be passed through the reduced crude conversion operation as lift gas, or as cooling medium or subjected to water-gas shift to produce additional H.sub.2.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: May 17, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4708785
    Abstract: Heat balance in a residual oil conversion unit can be controlled as a function of Conradson carbon of the feed, water added to the feed, hydrogen in the coke produced, CO.sub.2 /CO ratio, etc. Preferably, riser outlet temperature can be controlled to less than about 538.degree. C. (1000.degree. F.) at CO.sub.2 /CO flue gas ratios of 3/1 or less. Especially preferred are operations in a two-stage regenerator with cracking catalyst comprising at least 5000 ppm of Ni+V and residual carbon on regenerated catalyst of at least 0.1 wt. %. The contact time in the second stage of the regenerator being less than about 1/2 of that employed in the first stage, and with oxygen-lean gas being employed in the first stage. The heat transferred by the catalyst to the residual oil feed is preferably limited to about 500 to 1200 btu per pound of oil feed.
    Type: Grant
    Filed: March 20, 1985
    Date of Patent: November 24, 1987
    Assignee: Ashland Oil, Inc.
    Inventor: George D. Myers, deceased
  • Patent number: 4666586
    Abstract: A method and arrangement of apparatus is provided for catalytically cracking liquid hydrocarbons to form gaseous and liquid fuel products and effect regeneration of the used catalyst particles whereby means are provided which improve separation of formed suspensions in a substantially reduced time frame and combustion of substantial hydrocarbonaceous deposits is accomplished under restricted temperature conditions contributing to catalyst life in a two stage catalyst regeneration operation of restricted elevation. The apparatus combination of the present invention is preferably of low vertical profile by restricting the vertical length of the riser contact zone in one embodiment by providing a substantial horizontal section thereof in a downstream portion of the riser.
    Type: Grant
    Filed: January 5, 1984
    Date of Patent: May 19, 1987
    Inventor: Carl D. Farnsworth
  • Patent number: 4664778
    Abstract: An improved process for hydrocarbon conversion-catalyst regeneration processes particularly useful for residual oil, especially high carbon content residual oil conversion. The process generally comprises cooling the compressed air which is introduced into the second stage catalyst regeneration vessel in order to allow processing of feeds which typically produce high coke loading of catalyst in the conversion zone. The cooling process described can be installed and maintained with minimal expense in existing facilities and generally comprises a refrigeration unit and a heat exchange means installed in the conduit transporting air from a compressor unit to the second stage catalyst regenerator air distributor means.
    Type: Grant
    Filed: April 5, 1985
    Date of Patent: May 12, 1987
    Assignee: Total Engineering and Research Company
    Inventor: Leo R. Reinkemeyer
  • Patent number: 4615992
    Abstract: The present invention provides for a process and associated apparatus for limiting the vertical mixing of catalyst in a fluidized catalyst regenerator so that spent catalyst entering the regenerator will remain at the top of the fluidized bed for a longer period of time. This is accomplished by employing a generally horizontally placed baffle device located between 2 ft.-4 ft. below the catalyst bed level in the regenerator.
    Type: Grant
    Filed: April 2, 1985
    Date of Patent: October 7, 1986
    Assignee: Air Products and Chemicals, Inc.
    Inventor: James R. Murphy
  • Patent number: 4606811
    Abstract: In a reduced crude conversion the catalyst is regenerated with mixture of oxygen-enriched gas and H.sub.2 O either as steam or preferably as water to provide additional expansion and facilitate fluidization, while converting coke on catalyst to CO and H.sub.2 with minimum CO.sub.2 formation. The CO can be combined with hydrogen to produce methane, methanol or Fischer-Tropsch liquid hydrocarbons or can be passed through the reduced crude conversion operation as lift gas, or as cooling medium or subjected to water-gas shift to produce addition H.sub.2.
    Type: Grant
    Filed: October 2, 1984
    Date of Patent: August 19, 1986
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger
  • Patent number: 4605636
    Abstract: The present invention is concerned with the method of regenerating the fluidizable, catalytic, particulate solids in the regenerator section of an FCC process, and RCC process or a metals removal system or "ART" type process. It is directed to the use of a conduit means for charging fluidizing gaseous material to a vertical cylindrical vessel for cooling fluidizable particulate solids flowing through said vertical cylindrical vessel, which conduit means comprises a horizontal header means having suspended therefrom a plurality of vertical and horizontally spaced apart conduits, each conduit having near its open end a restriction orifice. The header means is located near the top of the cylindrical cooling vessel. One portion of the vertical conduits has lower ends located in the upper half of the vessel and a second portion of the vertical conduits has lower ends located in a lower half of the vessel.
    Type: Grant
    Filed: September 27, 1985
    Date of Patent: August 12, 1986
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, H. Anthony Raiche, Lloyd E. Busch
  • Patent number: 4600499
    Abstract: In a reduced crude conversion the catalyst is regenerated with mixture of oxygen-enriched gas and H.sub.2 O either as steam or preferably as water to provide additional expansion and facilitate fluidization, while converting coke on catalyst to CO and H.sub.2 with minimum CO.sub.2 formation. The CO can be combined with hydrogen to produce methane, methanol or Fischer-Tropsch liquid hydrocarbons or can be passed through the reduced crude conversion operation as lift gas, or as cooling medium or subjected to water-gas shift to produce addition H.sub.2.
    Type: Grant
    Filed: July 30, 1984
    Date of Patent: July 15, 1986
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4584090
    Abstract: A method for catalytically cracking different fractions of crude oil with a zeolite containing catalyst in separate riser regeneration zone followed by sequential regeneration of catalyst particles in separate riser regeneration zones is described wherein the hydrocarbon vapor-catalyst suspension of hydrocarbon conversion is discharged downwardly from a half circle centrifugal separation conduit comprising the riser upper discharge section, second stage riser regeneration of catalyst is discharged downwardly from a half circle centrifugal separation section into the top of a high temperature catalyst recovery zone provided with cyclone separation zones external thereto. The first stage upflow riser regeneration zone is effected with oxygen lean gas and steam in an amount equal to, more or less, than the oxygen containing gas whereby the regeneration temperature is restricted from exceeding a desired upper temperature limit with or without promoting the water gas shift reaction.
    Type: Grant
    Filed: September 7, 1984
    Date of Patent: April 22, 1986
    Inventor: Carl D. Farnsworth
  • Patent number: 4561968
    Abstract: A catalyst nominally containing zeolite, clay and silica-alumina gel is disclosed. The zeolite is preferably partially exchanged with high La/Ce ratio solution in a wetting step. The catalyst and processes for its manufacture and use are disclosed. The catalyst is excellent for processing heavy oils, generally produces higher LCO/slurry oil ratio and has high metals tolerance.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: December 31, 1985
    Assignee: Ashland Oil, Inc.
    Inventors: H. Wayne Beck, James D. Carruthers, Edward B. Cornelius, Ronald A. Kmecak, Stephen M. Kovach, William P. Hettinger, Jr.
  • Patent number: 4556540
    Abstract: A method and apparatus for separating regenerated catalyst from gaseous combustion products within a regenerator. The apparatus comprises a downcomer within the regenerator vessel through which the catalyst and gaseous combustion products flow. Means are provided at the lower end of the downcomer for utilizing the momentum of the catalyst particles to separate them from the gaseous combustion products.
    Type: Grant
    Filed: August 15, 1983
    Date of Patent: December 3, 1985
    Assignee: Ashland Oil, Inc.
    Inventor: Roger M. Benslay
  • Patent number: 4556479
    Abstract: A process for the clean-up of particulate containing gases is provided wherein a difference in pressures between the pressure of particulate-containing gases in the inlet to cyclone separation means and the pressure in an underflow exit is maintained and controlled. In a preferred embodiment, the particulate-containing gases comprise flue gas from a catalyst regeneration process comprising two separate regeneration zones comprising a low temperature regeneration zone followed by a higher temperature regeneration zone. A CO rich flue gas is recovered from the low temperature regeneration zone and a CO.sub.2 rich flue gas is recovered from the higher temperature regeneration zone. The high temperature CO.sub.2 rich flue gas is passed through a heat exchanger to produce steam and cool the CO.sub.2 rich flue gas. The cooled CO.sub.2 rich flue gas is passed through cyclone separators to capture catalyst particles.
    Type: Grant
    Filed: April 10, 1984
    Date of Patent: December 3, 1985
    Assignee: Total Engineering and Research Company
    Inventors: Jean-Louis Mauleon, Robert J. Newman, Alan J. Black
  • Patent number: 4477335
    Abstract: A method and apparatus for separating regenerated catalyst from gaseous combustion products within a regenerator. The apparatus comprises a downcomer within the regenerator vessel through which the catalyst and gaseous combustion products flow. Means are provided at the lower end of the downcomer for utilizing the momentum of the catalyst particles to separate them from the gaseous combustion products.
    Type: Grant
    Filed: May 17, 1982
    Date of Patent: October 16, 1984
    Assignee: Ashland Oil, Inc.
    Inventor: Roger M. Benslay
  • Patent number: 4471063
    Abstract: The present invention is directed to a method and sequence of processing steps within an apparatus arrangement comprising two separate fluidized relatively dense catalyst beds undergoing regeneration to remove carbonaceous deposits wherein catalyst particles are circulated between catalyst beds to transfer heat from one bed to another and transfer partially regenerated catalyst from one bed to a second heat generating catalyst bed, said catalyst regeneration system arranged to maintain a desired heat balanced temperature restriction less than 787.degree. C. (1450.degree. F.) and the generation of a CO.sub.2 rich flue gas with utilization thereof to achieve reaction with carbon form carbon monoxide under endothermic reaction temperature conditions.
    Type: Grant
    Filed: October 21, 1982
    Date of Patent: September 11, 1984
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger
  • Patent number: 4464250
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F. and material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalents of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.degree. F., and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 50% to 90% while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.
    Type: Grant
    Filed: July 30, 1981
    Date of Patent: August 7, 1984
    Assignee: Ashland Oil, Inc.
    Inventors: Virginia K. Myers, Bill E. McKay, Jr., Lloyd E. Busch
  • Patent number: 4430201
    Abstract: A method and apparatus for regeneration of coked catalyst resulting from a hydrocarbon conversion reaction in which catalyst regeneration is carried out in a plurality of superposed regeneration zones comprising the combination of a first dense phase fluidized bed regeneration zone, an entrained catalyst dilute phase regeneration zone superposed on said first regeneration zone, and a second dense phase fluid bed regeneration zone superposed on said dilute phase regeneration zone. Catalyst is regenerated by combustion of coke from the surface of the catalyst at an elevated temperature in the range of 675.degree. to 800.degree. C. with an excess of oxygen supplied by an oxygen-containing regeneration gas part of which is introduced into the first fluidized bed regeneration zone and part into said dilute phase regeneration zone, including a novel means of control of the rate of catalyst recirculated from said second dense phase regeneration zone to said first regeneration zone.
    Type: Grant
    Filed: October 27, 1981
    Date of Patent: February 7, 1984
    Assignee: Texaco, Inc.
    Inventors: Leonce F. Castagnos, Jr., Roy E. Pratt
  • Patent number: 4424116
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F.+ material which is characterized by a carbon residue on pyrolysis of at least about 1 and a Nickel Equivalents of heavy metals content of at least about 4 parts per million. This process comprises flowing the carbo-metallic oil together with particulate cracking catalyst through a progressive flow type reactor having an elongated reaction chamber, which is at least in part vertical or inclined, for a predetermined vapor riser residence time in the range of about 0.5 to about 10 seconds, at a temperature of about 900.degree. to about 1400.degree. F., and under a pressure of about 10 to about 50 pounds per square inch absolute sufficient for causing a conversion per pass in the range of about 40% to 90% while producing coke in amounts in the range of about 6 to about 14% by weight based on fresh feed, and laying down coke on the catalyst in amounts in the range of about 0.
    Type: Grant
    Filed: March 25, 1982
    Date of Patent: January 3, 1984
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.