Abstract: The present disclosure provides hydrocarbon absorbent granules, comprising granulated particles each including a mixture of hydrophobic non-self associating raw cotton sorbent fibers and a binding agent. The granules have an average diameter in a range from about 1 to about 7 cm and have a density in a range from about 0.03 to 0.1 grams per cubic centimeter. The binding agent constitutes from about 0.5 to about 70 percent by weight of granule. The granules are characterized in that they exhibit a sorbency ratio in a range from about 7 to about 30.

Abstract: A reclaiming apparatus 106 includes: a sealed container 106a that is an absorbent reservoir for storing therein a part of an absorbent that has absorbed CO2 in flue gas, and a heater that heats the absorbent stored in the sealed container 106a. The reclaiming apparatus 106 distributes a part of the absorbent stored in the sealed container 106a, and brings the distributed absorbent into counter-current contact with steam. Because a part of the absorbent stored in the absorbent reservoir is brought into counter-current contact with the steam, absorbent component contained therein becomes volatilized, and is separated from depleted materials. In this manner, the absorbent component can be extracted from the depleted materials, and a loss of the absorbent can be reduced.

Abstract: A process for the regeneration of deactivated catalyst from a Fischer-Tropsch synthesis reactor, the catalyst being a supported cobalt catalyst. The process comprises the following steps: a withdrawal step, in which a portion of deactivated catalyst together with liquid hydrocarbon is withdrawn from the reactor; a concentration step, in which the concentration of the catalyst in the liquid hydrocarbon is increased; a calcination step, in which the deactivated catalyst composition is subjected to an oxidizing gas to oxidize carbonaceous material contained in the deactivated catalyst in to gaseous oxides of the components of the carbonaceous material; and a reactivation step, in which the deactivated catalyst composition is reactivated to produced a regenerated catalyst.

Abstract: The present invention describes a combustion zone for a regenerative catalytic unit for the continuous regeneration of catalyst, said combustion zone having an annular shape and being divided into at least two combustion stages, each stage being divided into a number N of radial sectors, which are substantially equal, the catalyst flowing under gravity from one sector of the first combustion stage to the sector located in vertical alignment with the second combustion stage by means of drop legs, and the movement of the combustion gas being such that the combustion gas passes in succession through all of the sectors of the first combustion stage in any order, then all of the sectors of the second stage in any order.

Abstract: An aggregate composition and process for making the aggregate composition. The aggregate composition includes an insoluble rare earth-containing compound and a polymer binder. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from cerium carbonate or a cerium salt. In a specific embodiment, the aggregate composition consists essentially of one or more cerium oxides, the polymer binder and optionally a flow aid. A process for making the composition includes mixing the insoluble rare earth-containing compound with a polymer binder to form a mixture, and subjecting the mixture to mechanical, chemical and/or thermal treatment to adhere the rare earth compound to the polymer binder. The aggregate composition can be used in a variety of fluid treatment applications to remove one or more chemical and biological contaminants in a fluid.

Abstract: The process involves the use of specifically selected coke precursor compounds from the front end of oil distillate fractions that contain C11 to C14 hydrocarbons and their use as additives in the processing of naphtha in a catalytic reformer. The C11 to C14 compounds additives enhance coke make in continuous catalytic regeneration (CCR) reformers to levels higher than those which are usually produced in low coke naphtha reforming operations. With the increase of ethanol blending in gasoline and low reformate octane severity operations, reformers do not produce the necessary amount of coke to permit sustaining steady state white burn operations.

Abstract: An aggregate composition and process for making the aggregate composition. The aggregate composition includes an insoluble rare earth-containing compound and a polymer binder. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from cerium carbonate or a cerium salt. In a specific embodiment, the aggregate composition consists essentially of one or more cerium oxides, the polymer binder and optionally a flow aid. A process for making the composition includes mixing the insoluble rare earth-containing compound with a polymer binder to form a mixture, and subjecting the mixture to mechanical, chemical and/or thermal treatment to adhere the rare earth compound to the polymer binder. The aggregate composition can be used in a variety of fluid treatment applications to remove one or more chemical and biological contaminants in a fluid.

Abstract: The present disclosure relates to a fluid purification device that has a deactivation resistant photocatalyst having nanocrystallites of less than 14 nanometers (nm) in diameter with at least 200 m2 surface area/cm3 of skeletal volume in cylindrical pores of 5 nm in diameter or larger, with the mode of the pore size distribution 10 nm or more.

Abstract: A method of regenerating adsorbent material includes providing a spent adsorbent material and contacting the adsorbent material with a solvent composition to facilitate removing oil and impurities from the spent solvent material.

Abstract: A process to upgrade heavy oil and convert the heavy oil into lower boiling hydrocarbon products is provided. The process employs a catalyst slurry comprising catalyst particles with an average particle size ranging from 1 to 20 microns. In the upgrade process, spent slurry catalyst in heavy oil is generated as an effluent stream, which is subsequently recovered/separated from the heavy oil via membrane filtration. Residual hydrocarbons, i.e., heavy oil and solvent employed in the filtration for the heavy oil extraction are removed from the catalyst particles in a drying zone which employs at least two drying apparatuses to volatize residual hydrocarbons in the catalyst. Valuable metals can be recovered from catalyst particles for subsequent re-use in a catalyst synthesis unit, generating a fresh slurry catalyst.

Abstract: Disclosed is a process for disengaging regenerated catalyst from flue gas in a catalyst regenerator so as to avoid re-entrainment of catalyst that has settled into a bed in the catalyst regenerator using a disengaging device. A disengaging arm of the disengaging device has an outer shell that encloses the arm, an inner shell with a slot for allowing catalyst and flue gas to exit the arm and an outer baffle having a lower edge located below the opening in the outer wall. The baffle directs the catalyst and flue gas downwardly and limits radial flow. Catalyst and flue gas enter the disengaging arm through an opening in an outer wall of a riser section at a first superficial velocity and exits through a slot in a bottom of the disengaging arm at no more than 1.33 the first superficial velocity.

Abstract: A hydrocarbon trap comprises an Ag-zeolite which is heated by a unique steaming regimen.

Abstract: A system and method including a radially non-uniformly plugged flow-through honeycomb substrate positioned upstream of a wall-flow particulate filter for controlled thermal regeneration of the wall-flow particulate filter, the flow-through honeycomb substrate having a flow-through region including a first portion of parallel channels and a flow-control region including a second portion of parallel channels, the first portion of the parallel channels including unplugged channels and the second portion of the parallel channels including plugged channels, with the flow-control region adjusting flow distribution through the flow-through honeycomb substrate.

Abstract: The present invention relates to new crystalline molecular sieve SSZ-74 prepared using a hexamethylene-1,6-bis-(N-methyl-N-pyrrolidinium) dication as a structure-directing agent, and its use in gas separations.

Abstract: A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO4.2H2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

Abstract: The invention relates to a process of coating inorganic particles with organic compositions, and agglomerating, compacting and heating of the coated particles into granules. Coating and compacting the agglomeration may be conducted continuously, and may be used to form granules having sizes ranging from about 1 to about 200 mesh. In one embodiment, these particles can be used to purify drinking water by removing heavy metals such as arsenic, lead and mercury and to remove or kill microorganisms in the drinking water, air and gas.

Abstract: A process for regenerating spent zeolite composites. The process involves contacting the composite, either as a shaped article or a fine powder, with a caustic solution, e.g., sodium hydroxide at treating condition. Once the contacting is completed, the composite is isolated, washed with water, dried and calcined to give a regenerated composite.

Abstract: This process controls the magnetic separation of high metals catalyst by influencing the magnetic susceptibility by carbon levels on catalyst. In an FCC/RCC.RTM. operation employing magnetic separation of catalyst, particularly where the catalyst has enough metals to exhibit a high magnetic susceptibility, e.g., 110.times.10.sup.-6 emu/g or higher, all of the catalyst may be attracted to the magnet and go to the magnetic reject side. By controlling the amount of carbon, coke, or graphite present on the catalyst after partial regeneration, the magnetic properties of the catalyst can be diminished and separation can occur. Varying the amount of carbon affects the magnetic metals, the higher the magnetic susceptibility, and yet the catalyst particles will have a lower carbon level. The lower the magnetic susceptibility, the less metals, the higher the activity, and the higher the coke/carbon content.

Abstract: The gasification of coal and other carbonaceous materials by an endothermic gasification reaction is achieved in the presence of a catalyst in a down-flow, moving-bed gasifier. Catalyst is removed along with ash from the gasifier and is then sufficiently heated in a riser/burner by the combustion of residual carbon in the ash to volatilize the catalyst. This volatilized catalyst is returned to the gasifier where it uniformly contacts and condenses on the carbonaceous material. Also, the hot gaseous combustion products resulting from the combustion of the carbon in the ash along with excess air are introduced into the gasifier for providing heat energy used in the endothermic reaction.

Abstract: A fluid bed catalyst which has lost activity or fluidization quality through agglomeration, contamination, or a physical or chemical change on the surface of the catalyst is deagglomerated and/or its surface re-exposed, by contacting the fluidized catalyst with a high velocity gas sufficient to cause multiple collisions among the catalyst particles and thereby deagglomerating the particles and/or abrading the surface of the particles to expose fresh catalyst.

Abstract: A mixture of shaped catalysts, catalyst supports or sorbents comprising generally cylindrical, free flowing particles of regular geometric shape having substantially the same diameter and of varying length are length graded into a first group of particles having a length below a predetermined length, L.sub.1, in the range of fromn 0.8 to about 24 millimeters and an L/D greater than one, and a second group of particles having a length greater than L.sub.1, by feeding the mixture into a rotating cylindrical drum having inwardly opening indentations in its cylindrical wall having a transverse diameter of substantially L.sub.1. The drum is rotated about its longitudinal axis at speeds sufficient to entrap in the indentations and convey particles having a length below L.sub.1 comprising the first group upwardly to a height permitting the particles to fall into a fixed, upwardly opening trough, while retaining the second group of particles having a length above L.sub.

Abstract: A solid catalyst composition which has undergone a partial loss of catalytic activity due to the accumulation of reaction product residue is treated in a chemical conversion process reaction zone in the presence of feedstock(s) with ultrasonic energy of a magnitude and a duration sufficient to restore at least a significant percentage of the lost activity.

Abstract: A process for recovering Platinum Group metals from material comprising one or more Platinum Group metals and one or more Group IA metals supported on carbon comprises heating at a temperature between 700.degree. C. and 1150.degree. C. in a stream of an inert gas or vacuum then in a stream of carbon dioxide.

Abstract: Industrial exhaust polyaromatic hydrocarbons are readily absorbed by flowing through a bed of dry porous pellets consisting of a mixture of natural magnesium silicate selected from short chrysotile asbestos fibers, attapulgite and mixtures thereof with a cementitious clay binder, the latter representing from 1 to 20% by weight of the dry pellets, whereby substantially all the particulate and gaseous pollutants present in the exhaust material are adsorbed by the dry porous pellets.

Abstract: A process in which coke is reduced and volatile products yield increased in a catalytic cracking system wherein spent cracking catalyst is stripped in the presence of a hydrogen donor.

Abstract: A novel catalytic process is provided for the controlled degradation of organic materials into environmentally compatible products comprising at least carbon dioxide. The process employs a solid catalyst comprising at least one transition element and a peroxide to form a reaction mixture with the organic material which is degraded in the presence of photoenergy absorbable by the catalyst. The catalytic process has multiple applications including the purification of organic solvents; the regeneration of granular activated carbon; the purification of potable water and industrial waste water; and the elimination of organic hazardous and/or toxic substances from collected wastes.

Abstract: A spent zeolite-containing catalytic cracking catalyst composition is reactivated by a process comprising the steps of contacting the catalyst composition with a solution of a suitable ammonium compound (preferably an aqueous solution of NH.sub.4 NO.sub.3) and thereafter contacting the ammonium-exchanged cracking catalyst composition with a suitable fluorine compound (preferably a aqueous solution of NH.sub.4 F). A catalytic cracking process employs the reactivated cracking catalyst composition.

Abstract: A novel method is provided for regenerating deactivated crystalline zeolite catalysts at low temperature. The organic residue is contacted with a source of alkali or alkaline earth metal cations, or a source of ammonia, and the organic residue, including nitrogenous compounds, is extracted with an organic solvent. The method is particularly useful with deactivated ZSM-5 type dewaxing catalyst.