Abstract: The present disclosure provides hydrocarbon absorbent granules, comprising granulated particles each including a mixture of hydrophobic non-self associating raw cotton sorbent fibers and a binding agent. The granules have an average diameter in a range from about 1 to about 7 cm and have a density in a range from about 0.03 to 0.1 grams per cubic centimeter. The binding agent constitutes from about 0.5 to about 70 percent by weight of granule. The granules are characterized in that they exhibit a sorbency ratio in a range from about 7 to about 30.

Abstract: The present invention describes a combustion zone for a regenerative catalytic unit for the continuous regeneration of catalyst, said combustion zone having an annular shape and being divided into at least two combustion stages, each stage being divided into a number N of radial sectors, which are substantially equal, the catalyst flowing under gravity from one sector of the first combustion stage to the sector located in vertical alignment with the second combustion stage by means of drop legs, and the movement of the combustion gas being such that the combustion gas passes in succession through all of the sectors of the first combustion stage in any order, then all of the sectors of the second stage in any order.

Abstract: This invention relates to a lignin sorbent, a lignin removal unit, a biorefinery, a process for removing lignin, a process for binding lignin, and a renewable material. The lignin sorbent includes a substrate, and a lignin binding material dispersed with respect to the substrate. The lignin binding process includes the step of adding a lignin binding material to an input stream, and the step of converting the input stream into a renewable material.

Abstract: A method for eliminating silicon or silicon compounds in alumina based materials without destroying such alumina based materials enabling reutilization particularly in catalysts for hydrotreating processes, comprising: a) mixing alumina based solid material which contains silicon with an alcohol extraction agent at a temperature between 10 and 300° C., for 10 minutes to 96 hours to form a mixture; b) separating solids from the mixture by centrifugation, decantation or filtration to obtain separated solids; c) washing the separated solids with at least one of water, alcohol or an ammonium hydroxide solution to form washed solids; and d) drying the washed solids to obtain regenerated alumina based solid material.

Abstract: A method of saturating reversible ammonia storage materials inside a container for the purpose of achieving high volumetric ammonia storage capacity and containers filled with the materials are disclosed.

Abstract: The present disclosure relates to a fluid purification device that has a deactivation resistant photocatalyst having nanocrystallites of less than 14 nanometers (nm) in diameter with at least 200 m2 surface area/cm3 of skeletal volume in cylindrical pores of 5 nm in diameter or larger, with the mode of the pore size distribution 10 nm or more.

Abstract: An arsenic sorbent includes monohydrocalcite that has been precipitated by mixing an aqueous solution of a soluble carbonate or a carbonate with an aqueous solution that includes an Mg2+ ion and a Ca2+ ion in a ratio “Mg/Ca” of 0.3 or more, the monohydrocalcite having a molar ratio “Mg/(Ca+Mg)” of 0.1 or less. The arsenic sorbent exhibits a high arsenic sorption ability, and can stably retain a sorbate. A purification method using the same is also disclosed.

Abstract: A method of regenerating adsorbent material includes providing a spent adsorbent material and contacting the adsorbent material with a solvent composition to facilitate removing oil and impurities from the spent solvent material.

Abstract: The invention provides an inorganic electrolyte setting agent capable of blocking hazardous heavy metals almost permanently and further usable as resources, based on the geological balance of elements, and a treating method for utilization as resources using the same. There is provided an inorganic electrolyte setting agent capable of rendering heavy metal ions nonhazardous, including an aqueous solution as a main agent mixed with A below and also at least one of B and C below: (A) sulfuric acid, (B) at least one of aluminum sulfate and polyaluminum sulfate, (C) at least one of polyferric sulfate and ferric chloride; and an aqueous solution as a concomitant agent mixed with D below: (D) at least one of potassium silicate and sodium silicate.

Abstract: The present invention provides a method of recycling a spent flue gas denitration catalyst and a method of determining a washing time of the spent flue gas denitration catalyst. The method of recycling the spent flue gas denitration catalyst includes physically removing solids deposited in the spent flue gas denitration catalyst, removing poisoning substances deposited in the spent flue gas denitration catalyst by washing the spent flue gas denitration catalyst with a washing liquid for a washing time determined by measuring the hydrogen ion concentration of the washing liquid and drying the resulting spent flue gas denitration catalyst.

Abstract: A process for regenerating a catalyst used in the preparation of acrolein from glycerol, which comprises tungsten compounds and has acidic properties and at least one promoter.

Abstract: A hydrocarbon trap comprises an Ag-zeolite which is heated by a unique steaming regimen.

Abstract: A lithium exchanged zeolite X adsorbent blend with improved performance characteristics produced by preparing a zeolite X, preparing a binder which includes highly dispersed attapulgite fibers wherein the tapped bulk density of the highly dispersed attapulgite fibers measured according to DIN/ISO 787 is more than about 550 g/ml, mixing the zeolite X with the binder to form a mixture, forming the mixture into a shaped material, ion exchanging the zeolite X at least 75% with lithium ions, and calcining the shaped material.

Abstract: A composition for controlling NOx emissions during FCC processes comprises (i) an acidic oxide support, (ii) cerium oxide, (iii) a lanthanide oxide other than ceria such as praseodymium oxide, and (iv), optionally, an oxide of a metal from Groups Ib and IIb such as copper, silver and zinc.

Abstract: The present invention is directed to a process for the preparation of crystalline anionic clay-containing bodies from sources comprising a trivalent metal source and a divalent metal source comprising the steps of: a) preparing a precursor mixture containing a liquid, a divalent metal source and/or a trivalent metal source, at least one of them being insoluble in the liquid; b) shaping the precursor mixture to obtain shaped bodies; c) optionally thermally treating the shaped bodies; and d) aging the shaped bodies to obtain crystalline anionic clay-containing bodies; with the proviso that if no divalent or trivalent metal source is present in the precursor mixture of step a), such source is added to the shaped bodies after shaping step b) and before aging step d); and with the further proviso that the combined use of an aluminium source as the trivalent metal source and a magnesium source as the divalent metal source is excluded.

Abstract: Formation of dioxins in flue gases is inhibited by contacting the flue gas with at least one of sodium phosphite, calcium phosphate, sodium hypophosphite, and calcium as reducing agents preferably at a temperature in the range of from 150° C. to 850° C. Hydrogen chlorides are also rendered harmless by the contact with the reducing agent. Also, metal ions contained in the fly ash of the flue gas are reduced to metals to reduce the occurrence of dissolution of the metals in subsequent treatment of the fly ash.

Abstract: Provided is a process for producing a tetrahydrofuran polymer using a heteropoly-acid catalyst wherein the content of Al in the heteropoly-acid is 4 ppm or less.

Abstract: An efficient method for producing a hydrogen-containing gas for a fuel cell by using a gas produced by reforming reaction of an organic compound is disclosed. The method comprises the following steps: adding an oxygen-containing gas to a hydrogen-containing gas containing carbon monoxide to form a mixed gas, and bringing the mixed gas into contact with a catalyst comprising a ruthenium metal as a main component and having a carbon monoxide adsorption of not less than 1 mmol/g-ruthenium and a carbon monoxide adsorption index of not less than 0.5, to thereby oxidize and remove carbon monoxide.

Abstract: The present invention discloses an adsorbent comprising a densified carbon black. The densified carbon black comprising the adsorbent preferably has an increase in density of from about 100% to about 500% above the undensified form of the adsorbent. The densified carbon black adsorbent has an increase in adsorption capacity per unit volume over the undensified form of the adsorbent in excess of 100%. The densified carbon blacks are particularly useful as adsorbents for gases.

Abstract: An antioxidant composition which utilizes a desiccant carrier impregnated with a suitable fat soluble antioxidant is conveniently contained within a vapor permeable housing to prevent homogeneous mixing thereof with a stored product when the composition is provided in granulated form. The desiccant carrier is selected from a group of suitable hydrophilic materials which demonstrates the capacity for reducing levels of atmospheric moisture by absorption thereof, including for example, silica gel. The housing may conveniently be a sealed packet formed from a porous fiber material, such as, for example, that commonly used for fashioning tea bags and the like. Alternatively, the housing may include an enclosed perforated structure, the perforations of which are smaller than the granules of the contained composition. Where the composition is provided in the form of a unitary body, a housing need not be used.

Abstract: A method for detection of the performance reduction of an exhaust gas purification catalyst used for reducing the concentration(s) of combustible components or (and) nitrogen oxides all present in an exhaust gas, which method detects a reduction in the heat amount E.sub.g generated from the exhaust gas by the reaction of the exhaust gas catalyzed by the catalyst, or a reduction in the cumulative heat amount generated from the exhaust gas by said reaction in a predetermined temperature range taken by the catalyst during its temperature increase. This method can detect the performance reduction of the catalyst accurately without conducting constant-speed vehicle running for a long time.

Abstract: Inorganic and organic impurities are removed from a metallocene catalyst compound comprising the steps of (a) separating inorganic impurities from said compound by forming a solution of said compound in an organic solvent medium which is substantially a non-solvent for said inorganic impurities, (b) treating the solution of said compound with a particulate absorbing material so as to absorb and remove organic impurities from said solution, and (c) separating the solid material, including said particulate absorbing material, from said solution. Optionally, water can be removed by adding a drying agent.

Abstract: A method of removing chloride from phosphorus/vanadium/oxygen mixed oxide oxidation catalysts comprising treating a chloride containing catalyst comprising phosphorus, vanadium and oxygen with a stream of gas comprising oxygen, steam and an inert gas at flow rate and temperature and for a period of time to substantially reduce the amount of chloride in the catalyst.

Abstract: Mixed-metal oxide absorbents having superior CO.sub.2 and water removal capacity and superior regenerability are prepared from novel mixed-metal carbonate precursors or from mixed-metal oxides derived from those precursors. The precursors are prepared from a salt of silver and the salt of a second metal. The second metal may be selected from the group consisting of magnesium, iron, cobalt, nickel, zinc, and other metals for which the metal carbonate to metal oxide reaction occurs at a temperature of not greater than about 400.degree. C. The precursors have an unique x-ray diffraction pattern characteristic of the silver carbonate pattern rather than of the physical mixture of the silver carbonate and the carbonate of the second metal.

Abstract: The present invention provides a Lewis acid-catalyzed isoparaffin/olefin alkylation process in which acid consumption and energy costs are decreased by employing an acid sorption stage to separate the Lewis acid catalyst from the alkylate product stream, or from a selected fraction of the alkylate product stream, and desorbing the Lewis acid from the sorption stage with an isoparaffin-containing alkylation process feedstream.

Abstract: A method for the decomposition of halogenated and non-halogenated organic contaminant compounds contained in a contaminated medium comprises adding an alkali or alkaline earth metal carbonate, bicarbonate or hydroxide to the contaminated medium in an aqueous solution or in a solvent having a boiling point of at least 200.degree. C., or in the form of a solid dispersion or suspension. The medium includes a hydrogen donor compound. The hydrogen donor compound may be originally contained in the medium or may be added to the medium. The medium further includes a catalytic source of carbon, for example, a carabohydrate, which will cause formation of a free radical hydrogen ion from the hydrogen donor compound. The medium is heated to dehydrate the medium and then is further heated at a temperature between about 200.degree. and 400.degree. C. to cause formation of the free radical hydrogen ion and effect reductive decomposition of the halogenated and non-halogenated organic contaminant compounds.

Abstract: A method for the decomposition of halogenated organic compounds contained in a contaminated medium comprises adding an alkali metal carbonate or bicarbonate to the contaminated medium in an aqueous solution or in a solvent having a boiling point of at least 200.degree. C., or in the form of a solid dispersion or suspension. The medium is heated to dehydrate the medium and then is further heated at a temperature between about 250.degree. and 400.degree. C. to effect decomposition of the halogenated organic compounds. An acid is then added to the medium in an amount sufficient to neutralize the same.

Abstract: An FCC catalyst regeneration technique in which the catalyst is regenerated in a dense bed regenerator. Regenerator effluent gases are collected from different parts of the regenerator vessel in a common collection zone and passed through the catalyst separation cyclones from the common collection zone. Removal of nitrogen oxides from the regeneration effluent gases is enhanced by passing spent cracking catalyst through the effluent gases from a secondary spent catalyst inlet in the upper part of the regeneration vessel. Coke on the spent catalyst effects a reduction of nitrogen oxide (NOx) species in the effluent gases to nitrogen.

Abstract: An improved process and apparatus are disclosed for fluidized catalytic cracking of hydrocarbons using a swirl type catalyst regenerator. Multiple, symmetrically spaced spent catalyst inlets are provided for addition of coked catalyst to the regenerator. Preferable a single catalyst outlet, for withdrawal of regenerated catalyst, is provided in the center of the regenerator. Use of multiple symmetrical inlets and a central catalyst outlet greatly reduce stagnant regions in the bed.

Abstract: In the purification of light hydrocarbons to remove carbonyl sulfide impurity by selective adsorption thereof on molecular sieve adsorbents, significant losses of the hydrocarbon are incurred by its coadsorption on the adsorbent with the COS impurity. Conventional desorption procedures produce a desorbate which is a non-commercial mixture of COS and hydrocarbon. The purge desorption method of the present invention utilizing a mixture of CO.sub.2 and a non-sorbable purge gas permits recovery of the coadsorbed hydrocarbon in a pure and commercially useful form.

Abstract: A process for hydrogenating a hydrocarbonaceous charge stock containing nitrogen, sulfur or halogen-based impurities which process comprises the steps of: (a) contacting the hydrocarbonaceous charge stock in the presence of hydrogen with a hydrogenation catalyst in a hydrogenation reaction zone to simultaneously increase the hydrogen content of the hydrocarbonaceous charge stock and to generate at least one water-soluble inorganic compound produced from the reaction of said nitrogen, sulfur or halogen-based impurities in said hydrocarbonaceous charge stock and the hydrogen; (b) contacting the reaction zone effluent containing hydrogenated hydrocarbonaceous compounds and at least one said water-soluble inorganic compound with a fresh aqueous scrubbing solution; (c) introducing a resulting admixture of the reaction zone effluent and the aqueous scrubbing solution into a separation zone to provide a hydrogenated hydrocarbonaceous stream and a spent aqueous scrubbing solution stream containing at least a portion

Abstract: Spent solid phosphoric acid catalyst is neutralized prior to removal from a reactor vessel to avoid generation of toxic dust or acidic washings during catalyst removal.

Abstract: A method for regenerating a denitration catalyst for exhaust gases discharged from coal-burning apparatus, in which a used catalyst whose denitration performance has lowered is contacted with fluidized abrasive particles. As a result, catalyst poisons deposited on the catalyst surface are removed by abrasive contact.

Abstract: Solid sorbents (acceptors) for noxious components, e.g. SO.sub.x, NO.sub.x and HX, from gases below about 250.degree., specifically acceptors that contain hydrated divalent metal oxide coated onto an exfoliated or expanded mineral support, are improved by heating them before use at a temperature of 450.degree.-650.degree. for a conditioning period of at least a few minutes. So conditioned pulverulent MgO coated onto water-laden exfoliated vermiculite (alternatively expanded perlite) is preferred because of capacity and the ability of the magnesia-based acceptors to be regenerated at a moderately elevated temperature that precludes substantial deterioration of acceptor or equipment. To insure immediate activity the conditioned acceptor is moistened for use. Advantageously the gas and/or the acceptor is humidified during their contact.

Abstract: A process for hydrotreating a hydrocarbonaceous charge stock having hydrogenatable hydrocarbonaceous compounds which process comprises the steps of: (a) contacting said hydrocarbonaceous charge stock in the presence of hydrogen with a hydrogenation catalyst in a hydrotreating reaction zone; (b) contacting said hydrotreating reaction zone effluent with an aqueous scrubbing solution; (c) introducing a resulting admixture of said reaction zone effluent and said aqueous scrubbing solution into a separation zone to provide a hydrotreated hydrocarbonaceous stream having trace quantities of hydrogenatable hydrocarbonaceous compounds and a spent aqueous stream; and (d) contacting said hydrotreated hydrocarbonaceous stream with an adsorbent to remove at least a portion of said trace quantities of hydrogenatable hydrocarbonaceous compounds from said hydrotreated hydrocarbonaceous stream.

Abstract: A process is described for regeneration of an adsorbent having ammonia adsorbed thereon and comprising a mixture of an alumina and a Y zeolite. The adsorbent may be regenerated to substantially its original capacity for adsorbing ammonia by a two step process which comprises first treating the adsorbent with a saturated solution of an alkali metal carbonate such as sodium carbonate to remove a substantial portion of the ammonia sorbed on the adsorbent mixture and then treating the adsorbent in a second step with a saturated alkali metal bicarbonate solution such as sodium bicarbonate to restore the ammonia adsorption capacity of the adsorbent mixture to substantially its original capacity.

Abstract: Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included.Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves:treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and,separating the solids from the liquid; and thentreating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and,separating the solids and liquids from each other.

Abstract: A method for recovering a denitrating catalyst for ammonia catalytic reduction which is characterized by treating the denitrating catalyst for ammonia catalytic reduction, in which a performance has deteriorated, with at least one selected from the group consisting of SO.sub.4.sup.2- compounds, sulfur compounds and sulfonic acid compounds in order to replenish the catalyst with a sulfur content.

Abstract: In a process for the reactivation of a catalyst, which is used for the removal of NO.sub.x, oxides of nitrogen, from exhaust gases, the catalyst should be capable of easy reactivation. For this purpose, when the catalyst starts to lose its activity, it is exposed in a reducing atmosphere to a carbon monoxide current. In an apparatus for the execution of the process, the catalyst is placed in two separate chambers. The carbon monoxide stream is directed alternately to both chambers.

Abstract: A process for removing nitrogen chemically bound to a zeolite component of a catalytic composition, used in hydroprocessing feedstocks containing nitrogen precursors, including contacting the hydrogen treated used catalyst composition with polar solvents, preferably in the gaseous state, at pressures practically no greater than 100 Torr.

Abstract: A method for recovering a denitrating catalyst which is characterized by washing, with an aqueous oxalic acid solution, the used tungsten-titania or the tungsten-titania-vanadium denitrating catalyst which dust components have adhered to or have accumulated on and in which an SO.sub.2 -oxidizing power has thus risen; impregnating the catalyst with a tungsten compound; and drying and calcining the thus treated catalyst.

Abstract: The instant process relates to a process for treating fluoride-containing catalysts or aluminosilicates which contain insoluble fluoride compounds by the use of soluble aluminum compounds.

Abstract: A method for reactivating catalysts which comprises the steps of:jetting dry steam into a reactor which is charged with the catalysts deteriorated in performance, in order to remove dust adhering to and accumulating on the surfaces of the catalysts;spraying wet steam of 0.4 or less in wetness thereinto to elute and remove water-soluble poisonous materials accumulated inside the catalysts; anddrying the catalysts with the dry steam.

Abstract: Coke or coke and hydrogen production may increase when the Asphalt Residual Treating (ART) Process for removing metallic and carbonaceous contaminants from hydrocarbons is operated with feed stock containing impurities that result in the deposition on the solid particulate contact material of acidic metallic compounds such as heavy metal chlorides. Coke or coke and hydrogen production is reduced by charging ammonia or other fugitive basic nitrogen compounds to the system after burning coke from the circulating inventory of catalytically inert contact material and prior to selectively vaporizing incoming charge of feed stock in the presence of the hot regenerated contact material.

Abstract: A method for the regeneration of end-of-cycle catalysts is provided wherein nitrogen and other deleterious poisons are removed prior to hydrogen treatment by passing over the catalyst bed a stripping mixture consisting of an alkyl amine whose basicity is much greater than that of the indigenous nitrogen compounds found in the catalyst.

Abstract: A novel method is provided for regenerating deactivated crystalline zeolite catalysts at low temperature. The organic residue is contacted with a source of alkali or alkaline earth metal cations, or a source of ammonia, and the organic residue, including nitrogenous compounds, is extracted with an organic solvent. The method is particularly useful with deactivated ZSM-5 type dewaxing catalyst.

Abstract: Regeneration of a phosphorus poisoned automotive exhaust catalyst is accomplished in a preferred embodiment by washing the catalyst or soaking it to the point of incipient wetness with an aqueous solution of an acid such as HCl, HNO.sub.3 or oxalic acid and subsequent heating of the wetted catalyst in air or other oxygen-containing gas.

Abstract: Granular sorbent material comprising a granular high surface area support impregnated with a water soluble, essentially non-volatile primary or secondary amine with equivalent weight less than about 400 and bearing either zero or two carbonyl substituents attached directly to the amino nitrogen atom is disclosed. The resulting material can be used as the filtration media in respirators, powered air purifiers, room air purifiers, ventilation filters, exhaust filters, process gas filters and the like to reduce the formaldehyde content of air.