Faujasite Type (e.g., X Or Y, Etc.) Patents (Class 502/79)
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Patent number: 12152201Abstract: Provided is a method of converting a hydrocarbon using a catalyst/catalyst support including a PST-32 or PST-2 zeolite, which has an effect of increasing the selectivity/yield of a light olefin product and reducing a side reaction to sustain catalytic activity, in various hydrocarbon conversion reactions, in particular, catalytic cracking of diesel.Type: GrantFiled: August 3, 2022Date of Patent: November 26, 2024Assignees: POSTECH RESEARCH AND BUSINESS DEVELOPMENT FOUNDATION, KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Suk Bong Hong, Hwajun Lee, Jiho Shin, Na Young Kang, Yong-Ki Park
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Patent number: 11923548Abstract: The present invention relates to the redox buffer electro-catalyst for bi-functional air electrode of metal-air batteries and fuel cells, wherein an electro-catalyst comprising of redox buffer oxides facilitates bi-functional activity of air electrode towards oxygen reduction and oxygen evolution reactions at the air electrode-electrolyte interface. The bi-functional activity of electro-catalyst comprising of redox buffer oxides is superior, due to improved electron transfer ability in comparison to electro-catalyst without redox buffer oxides.Type: GrantFiled: September 2, 2021Date of Patent: March 5, 2024Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Narayanam Seshubabu, Vakakuzhiyil Gopinathan Anju, Naduhatty Selai Raman, Shailendra Kumar Sharma, Sankara Sri Venkata Ramakumar
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Patent number: 11745164Abstract: A sorbent composition for enhanced baghouse function is described. The composition may include a sorbent such as powder activated carbon as well as an additive that is a heat moderator or a permeability agent. The heat moderator may act as a heat sink or barrier. Heat moderators may include in non-limiting examples phyllosilicates, cyclosilicates, or nesosilicates that may include, montmorillonite, bentonite, halloysite, aluminum silicates, muscovite, illite, kaolin, andalusite, kyanite, sillimanite, metakaolin, mullite, polymers, such as chitosan, and/or clays, either natural or synthetic (e.g., montmorillonite), or polyethylenimine. Permeability may be affected by mixing sorbents of lower D50 with sorbents of higher D50 in various ratios, or addition of a permeability agent such as a phyllosilicate, perlite, silica, diatomaceous earth. Further, a permeability agent such as a fluoropolymer may be coated onto or admixed with the sorbent.Type: GrantFiled: June 22, 2021Date of Patent: September 5, 2023Assignee: ADA Carbon Solutions, LLCInventors: Mowen Li, Robert B. Huston, Joseph M. Wong, Sarah G. McMurray
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Patent number: 11684909Abstract: To provide a highly active structured catalyst for methanol reforming that suppresses the decline in catalytic function and has excellent catalytic function, and a methanol reforming device. A structured catalyst for methanol reforming, including: a support of a porous structure composed of a zeolite-type compound; and a catalytic substance present in the support, in which the support has channels communicating with each other, and the catalytic substance is present at least in the channels of the support.Type: GrantFiled: November 27, 2019Date of Patent: June 27, 2023Assignee: FURUKAWA ELECTRIC CO., LTD.Inventors: Takao Masuda, Yuta Nakasaka, Takuya Yoshikawa, Sadahiro Kato, Masayuki Fukushima, Hiroko Takahashi, Yuichiro Banba, Kaori Sekine
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Patent number: 11660585Abstract: Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.Type: GrantFiled: February 6, 2020Date of Patent: May 30, 2023Assignee: BASF CorporationInventors: Ivor Bull, Ahmad Moini, Mukta Rai
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Patent number: 11648543Abstract: Provide is a functional structural body that can suppress aggregation of metal oxide nanoparticles and prevent functional loss of metal oxide nanoparticles, and thus exhibit a stable function over a long period of time. A functional structural body (1) includes: a skeletal body (10) of a porous structure composed of a zeolite-type compound; and at least one type of metal oxide nanoparticles (20) containing a perovskite-type oxide present in the skeletal body (10), the skeletal body (10) having channels (11) that connect with each other, and the metal oxide nanoparticles (20) being present at least in the channels (11) of the skeletal body (10).Type: GrantFiled: November 27, 2019Date of Patent: May 16, 2023Assignees: NATIONAL UNIVERSITY CORPORATION HOKKAIDO UNIVERSITY, FURUKAWA ELECTRIC CO., LTD.Inventors: Takao Masuda, Yuta Nakasaka, Takuya Yoshikawa, Sadahiro Kato, Masayuki Fukushima, Kojiro Inamori, Hiroko Takahashi, Yuichiro Banba, Kaori Sekine
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Patent number: 11603500Abstract: A process to catalytically transform natural gas liquid (NGL) into higher molecular weight hydrocarbons includes providing an NGL stream, catalytically dehydrogenating at least a portion of the NGL stream components to their corresponding alkene derivatives, catalytically oligomerizing at least a portion of the alkenes to higher molecular weight hydrocarbons and recovering the higher molecular weight hydrocarbons. The NGL stream can be extracted from a gas stream such as a gas stream coming from shale formations. The higher molecular weight hydrocarbons can be hydrocarbons that are liquid at ambient temperature and ambient pressure.Type: GrantFiled: September 6, 2018Date of Patent: March 14, 2023Assignee: PURDUE RESEARCH FOUNDATIONInventors: Rakesh Agrawal, Jeffrey J. Siirola, Taufik Ridha, Yiru Li, Fabio H. Ribeiro, Jeffrey T. Miller
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Patent number: 11518684Abstract: A NaY molecular sieve with an aluminum-rich surface is prepared using a process that includes the steps of: a. mixing a directing agent and a first silicon source to obtain a first mixture, wherein the directing agent has a molar composition of Na2O:Al2O3:SiO2:H2O=(6-25):1:(6-25):(200-400); b. mixing the first mixture obtained in the step a with a second silicon source, an aluminum source and water to obtain a second mixture; c. carrying out hydrothermal crystallization on the second mixture obtained in the step b, and collecting a solid product. Calculated as SiO2, the weight ratio of the first silicon source to the second silicon source is 1:(0.01-12). The NaY molecular sieve has larger aluminum distribution gradient from the surface to the center of the particle than the conventional molecular sieve.Type: GrantFiled: May 27, 2019Date of Patent: December 6, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Qiang Fu, Yongxiang Li, Chengxi Zhang, Hexin Hu, Xuhong Mu, Xingtian Shu
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Patent number: 11491468Abstract: Supported catalyst for use in a process for the synthesis of methanol, characterized in that the supported catalyst comprises indium oxide in the form of In2O3 and at least one noble metal being palladium, Pd, wherein both indium oxide and at least one noble metal are deposited on a support remarkable in that the supported catalyst is a calcined supported catalyst comprising from 0.01 to 10.0 wt. % of palladium and zirconium dioxide (ZrO2) in an amount of at least 50 wt. % on the total weight of said supported catalyst.Type: GrantFiled: September 5, 2019Date of Patent: November 8, 2022Assignees: TOTAL SE, ETH ZURICHInventors: Joseph Stewart, Daniel Curulla-Ferre, Javier Perez-Ramirez, Cecilia Mondelli, Matthias Frei
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Patent number: 11400443Abstract: The present invention relates to a method for producing automobile exhaust gas catalytic converters, to the catalytic converters as such and to the use thereof. In particular, the method comprises a step which results in a smaller particle size of the catalytically active material used.Type: GrantFiled: January 16, 2019Date of Patent: August 2, 2022Assignee: UMICORE AG & CO. KGInventors: Benjamin Barth, Martin Foerster, Morten Schonert
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Patent number: 11033879Abstract: FAU type binderless zeolitic adsorbents and methods for making the FAU type binderless adsorbents are described. The binderless zeolitic adsorbent comprises a first FAU type zeolite having a silica to alumina molar ratio below 3.0; a binder-converted FAU type zeolite having a silica to alumina molar ratio of from about 2.5 to about 6.0, wherein the binder-converted FAU type zeolite may be 5-50% of the binderless zeolitic adsorbent; and cationic exchangeable sites within the binderless zeolitic adsorbent. The FAU type binderless adsorbents may be used for xylene separation and purification in selective adsorptive separation processes using binderless zeolitic adsorbents.Type: GrantFiled: June 4, 2018Date of Patent: June 15, 2021Assignee: UOP LLCInventors: Linda S. Cheng, David A. Lesch
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Patent number: 10981143Abstract: The present invention generally relates to binderless zeolitic adsorbents and methods for making the binderless adsorbents. More particularly, the invention relates to FAU type binderless zeolitic adsorbents and methods for making the FAU type binderless adsorbents. The FAU type binderless adsorbents may be used for xylene separation and purification in selective adsorptive separation processes using binderless zeolitic adsorbents.Type: GrantFiled: June 4, 2018Date of Patent: April 20, 2021Assignee: UOP LLCInventors: Linda S. Cheng, David A. Lesch
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Patent number: 10744492Abstract: A process is provided for removing contaminants from olefin containing C4 streams. The streams are contacted with an X based zeolite adsorbent comprising greater than 88% X zeolite at a SiO2/Al2O3 ratio of less than 2.5 and an alkali metal salt present in excess of an amount required to achieve full exchange of cation sites on the X based zeolite. The resulting alkali oxide on a volatile free basis is less than 1% (by mass) of the X based adsorbent. The contaminants that are removed include sulfur, oxygenate, and nitrogen based contaminants.Type: GrantFiled: November 3, 2017Date of Patent: August 18, 2020Assignee: UOP LLCInventors: Stephen R. Caskey, Munish Kumar Sharma, Jayant K. Gorawara, Pijus Kanti Roy, Frank S. Modica
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Patent number: 10745329Abstract: The present invention relates to zeolite adsorbents based on agglomerated zeolite X crystals comprising barium, potassium and sodium. These adsorbents find applications in the separation of aromatic C8 isomer fractions and especially xylene.Type: GrantFiled: July 8, 2016Date of Patent: August 18, 2020Assignees: ARKEMA FRANCE, IFP ENERGIES NOUVELLESInventors: Ludivine Bouvier, Catherine Laroche, Julien Grandjean
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Patent number: 10583424Abstract: Disclosed are zeolite catalysts having the CHA crystal structure with a low silica to alumina ratio, as well as articles and systems incorporating the catalysts and methods for their preparation and use. The catalysts can be used to reduce NOx from exhaust gas streams, particularly those emanating from gasoline or diesel engines.Type: GrantFiled: November 4, 2009Date of Patent: March 10, 2020Assignee: BASF CorporationInventors: Ivor Bull, Ahmad Moini, Mukta Rai
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Patent number: 10502700Abstract: Provided is a method for detecting respirable participles in a bulk material comprising particles. The method comprises: analyzing morphology of the particles; analyzing chemical composition of the particles; creating a profile of the particles, wherein each particle in the profile is characterized by its shape, size and chemical composition; selecting particles from the profile which match the size and chemical composition of a respirable particle; and calculating a percentage of the respirable particles in the bulk material.Type: GrantFiled: July 6, 2017Date of Patent: December 10, 2019Assignee: United States Gypsum CompanyInventors: James W. Barber, Feng Peng
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Patent number: 10427945Abstract: The present invention relates to an ion sieve material, comprising, based on the weight of the ion sieve material, 15-55% by weight (wt %) of SiO2, 5-50 wt % of an auxiliary material, and 15-48 wt % of at least one functional metal oxide, wherein the metal in the functional metal oxide is a monovalent and/or divalent metal. A method for preparing the ion sieve material and a method of using the same are further provided.Type: GrantFiled: November 1, 2017Date of Patent: October 1, 2019Assignee: Shenzhen Donglihua Technology Co., Ltd.Inventors: Wei Hu, Fanghua Chen, Zhenyu Chen, Weihua Wan, Peng Zhou, Yunfei Zhang
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Patent number: 10195593Abstract: The invention relates generally to a sodium faujasite catalyst, and in particular the use of the sodium faujasite catalyst in producing acrylic acid. In particular, the invention relates to the use of the sodium faujasite catalyst in catalytic dehydration of lactic acid and 3-hydroxypropionic acid (3-HP) to produce acrylic acid.Type: GrantFiled: March 26, 2015Date of Patent: February 5, 2019Assignee: Agency for Science, Technology and ResearchInventors: Chuan Wang, Zhen Guo, Armando Borgna
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Patent number: 9962687Abstract: A method for regenerating a spent sulfuric acid catalyst and recovering hydrocarbons from a spent sulfuric acid catalyst from alkylation of olefins and alkanes by using a hydrophobic supported liquid membrane is provided.Type: GrantFiled: June 27, 2017Date of Patent: May 8, 2018Inventors: Chao-Shan Chou, Tse-Chuan Chou
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Patent number: 9901900Abstract: A gas-adsorbing material may increase gas barrier properties for a target gas by reducing a gas-adsorption rate while maintaining gas-adsorption performance. A vacuum insulation material may use the gas-adsorbing material. The gas-adsorbing material may include a gas-adsorbing composition including a copper ion exchanged ZSM-5-type zeolite having a silica to alumina ratio ranging from about 10 to 50 in a framework of zeolite. A ratio of dealuminization of the ZSM-5-type zeolite is at least about 15%, and the gas-adsorbing material is capable of adsorbing at least nitrogen. Furthermore, the gas-adsorbing material may include a calcinated body of a compressed article comprising a gas-adsorbing composition including a copper ion exchanged ZSM-5-type zeolite having a silica to alumina ratio ranging from about 10 to 50 in a framework of zeolite (where a ratio of dealuminization of the ZSM-5-type zeolite is at least about 15%) and a moisture-absorbing material.Type: GrantFiled: November 12, 2015Date of Patent: February 27, 2018Assignee: Samsung Electronics Co., Ltd.Inventors: Nagahisa Sato, Ryosuke Kamitani, Kenichi Nagayama
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Patent number: 9289756Abstract: Described is a copper containing ZSM-34, OFF and/or ERI zeolitic material having a silica to alumina mole ratio ranging from about 4 to about 50 and a copper content, reported as CuO, ranging from about 1 to about 10 wt.-%, based on the total weight of the calcined zeolitic material, and having an alkali metal content, reported as the metal oxide, of less than about 0.7 wt.-%.Type: GrantFiled: July 15, 2011Date of Patent: March 22, 2016Assignee: BASF SEInventors: Ivor Bull, Ulrich Mueller
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Patent number: 9221015Abstract: Described is a copper containing ZSM-34, OFF and/or ERI zeolitic material having a silica to alumina mole ratio ranging from about 4 to about 50 and a copper content, reported as CuO, ranging from about 1 to about 10 wt.-%, based on the total weight of the calcined zeolitic material, and having an alkali metal content, reported as metal oxide, ranging from about 1.5 to about 12 wt.-%.Type: GrantFiled: July 15, 2011Date of Patent: December 29, 2015Assignee: BASF SEInventors: Ivor Bull, Ulrich Müller
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Patent number: 9034780Abstract: This disclosure relates to a catalyst system adapted for transalkylation a C9+ aromatic feedstock with a C6-C7 aromatic feedstock, comprising: (a) a first catalyst comprising a first molecular sieve having a Constraint Index in the range of 3-12 and 0.01 to 5 wt. % of at least one source of a first metal element of Groups 6-10; and (b) a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 and 0 to 5 wt. % of at least one source of a second metal element of Groups 6-10, wherein the weight ratio of the first catalyst over the second catalyst is in the range of 5:95 to 75:25 and wherein the first catalyst is located in front of the second catalyst when they are brought into contacting with the C9+ aromatic feedstock and the C6-C7 aromatic feedstock in the present of hydrogen.Type: GrantFiled: December 17, 2009Date of Patent: May 19, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventor: Doron Levin
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Publication number: 20150126357Abstract: The present invention is related to a nano-structured composite material and process of making for air detoxing and deodoring in enclosed spaces to prevent harmful chemicals in the air from damaging human health. The nano-structured composite material consists of nano-porous carbon, zeolites with sub nano-size pores and at least 1 other component chosen from nano-porous rare earth oxides and nano-sized catalysts, and is made into highly efficient configurations with high geometric surface and low resistance air flow channels. The synergetic action of those nano-structured components can effectively remove toxic chemicals including, but not limited to formaldehyde, benzene, toluene, xylene, propene, butadiene, acetone, carbon monoxide, nitric oxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, ammonia, alcohols, chlorine, mercaptans, as well as bad odors, such cigarette smoke and bathroom/toilet smells.Type: ApplicationFiled: October 27, 2014Publication date: May 7, 2015Inventors: Xiwang Qi, Mei Jiang
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Patent number: 9018120Abstract: The present invention provides a process for the preparation of metal-doped zeolites comprising the steps of i) provision of a dry mixture of a) a zeolite, b) a compound of a catalytically active metal, ii) intimate grinding of the mixture, iii) heating of the mixture in a reactor, iv) cooling to room temperature and obtaining the metal-doped zeolite, wherein the internal pressure in the reactor during the heating is kept in a pressure range from 0 to ?200 millibar. The invention further relates to the use of a metal-doped zeolite prepared by means of the process according to the invention for the conversion of NOx and N2O into harmless products.Type: GrantFiled: July 19, 2007Date of Patent: April 28, 2015Assignee: Süd-Chemie IP GmbH & Co KGInventors: Soovi Hurgobin, Arno Tissler, Ashveer Raghunandan, Attila Jambor, Rainer Rakoczy, Roderik Althoff
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Patent number: 9006125Abstract: In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent.Type: GrantFiled: May 22, 2013Date of Patent: April 14, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Doron Levin, April D. Ross, James H. Beech, Jr.
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Patent number: 8993468Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO).Type: GrantFiled: May 22, 2008Date of Patent: March 31, 2015Assignee: Saudi Basic Industries CorporationInventors: Scott A. Stevenson, Alla K. Khanmamedova, Dustin B. Farmer, Scott F. Mitchell, Jim Vartuli
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Publication number: 20150071841Abstract: In order to improve the lifetime of an SCR catalyst in the waste gas purification by means of the SCR process of waste gas of a biomass combustion plant, the catalyst comprises a sacrificial component selected from a zeolite and/or a clay mineral, in particular halloysite. During operation, catalyst poisons contained in the waste gas, in particular alkali metals, are absorbed by the sacrificial component so that catalytically active centres of the catalyst are not blocked by the catalyst poisons.Type: ApplicationFiled: September 10, 2014Publication date: March 12, 2015Inventor: Maria Theresia Brandmair
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Publication number: 20150064102Abstract: A hydrogen oxidation catalyst is provided, comprising a zeolite that contains at least one catalytically active noble metal or a compound thereof, wherein said zeolite is a hydrophobic zeolite. A use of the catalyst and a method for hydrogen recombination in nuclear power plants, reprocessing plants or fuel element repositories is also specified.Type: ApplicationFiled: April 2, 2013Publication date: March 5, 2015Applicant: Clariant Produkte (Deutschland) GmbHInventors: Patrick Mueller, Arno Tissler, Frank Klose, RoderikPeter Althoff, Olaf Buettner
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Publication number: 20150065338Abstract: The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.Type: ApplicationFiled: November 5, 2014Publication date: March 5, 2015Inventors: Mark G. White, Shetian Liu
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Patent number: 8969233Abstract: The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminum between 2.5 and 20, an initial weight fraction of extra-lattice aluminum atoms greater than 10%, relative to the total weight of aluminum present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g?1 and an initial crystal lattice parameter a0 between 24.38 ? and 24.30 ?, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.Type: GrantFiled: November 23, 2012Date of Patent: March 3, 2015Assignee: IFP Energies NouvellesInventors: Laurent Simon, Emmanuelle Guillon
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Patent number: 8969229Abstract: The present invention generally relates to high rate adsorbents and a method for their manufacture involving the steps of component mixing, extrusion, spheronization and calcination. The component mixing can involve both dry mixing in addition to wet mixing of an adsorbent with a binder, if required, and a fluid such as water. The paste so formed from the mixing stage is extruded to produce pellets which are optionally converted to beads by spheronization using in one embodiment, a marumerizer. The product is harvested and calcined to set any binder or binders used and/or burn out any additives or processing aids. This basic manufacturing scheme can be augmented by extra processing steps including ion exchange and activation to alter the composition of the adsorbents, as required.Type: GrantFiled: October 22, 2007Date of Patent: March 3, 2015Assignee: Praxair Technology, Inc.Inventors: Philip Alexander Barrett, Neil Andrew Stephenson, Steven John Pontonio, Jian Zheng
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Patent number: 8957273Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containType: GrantFiled: June 24, 2009Date of Patent: February 17, 2015Assignee: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 8956993Abstract: Oxychlorination catalyst compositions which include a catalytically effective amount of an oxychlorination catalyst and a diluent having certain chemical composition and/or physical properties are disclosed. Processes using such oxychlorination catalyst compositions are also described. Some oxychlorination catalyst compositions and processes disclosed herein can increase the optimal operating temperature, and thereby increase the production capacity of an existing reactor, such as a fluid-bed reactor, compared to other oxychlorination catalyst compositions.Type: GrantFiled: August 10, 2009Date of Patent: February 17, 2015Assignee: Oxy Vinyls LPInventors: Keith S. Kramer, Joseph A. Cowfer
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Patent number: 8957274Abstract: The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-contType: GrantFiled: June 24, 2009Date of Patent: February 17, 2015Assignee: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 8957272Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organicType: GrantFiled: June 24, 2009Date of Patent: February 17, 2015Assignee: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 8957271Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a hType: GrantFiled: June 24, 2009Date of Patent: February 17, 2015Assignee: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Publication number: 20150038751Abstract: The present disclosure discloses bimetal catalysts.Type: ApplicationFiled: March 28, 2013Publication date: February 5, 2015Applicant: Wayne State UniversityInventors: K.Y. Simon Ng, Steve O. Salley, Huali Wang
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Patent number: 8940652Abstract: A phosphorus modification of an FCC catalyst is provided by reducing the sodium content of the as formed catalyst, a first treatment with a phosphate solution, a second ammonium exchange to further reduce the sodium content of the phosphorus solution treated catalyst and a second treatment with a phosphate solution.Type: GrantFiled: November 5, 2012Date of Patent: January 27, 2015Assignee: BASF CorporationInventors: Qi Fu, Chandrashekhar Pandurang Kelkar, Gary Smith, Bilge Yilmaz
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Patent number: 8932974Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: GrantFiled: July 17, 2013Date of Patent: January 13, 2015Assignee: Massachusetts Institute of TechnologyInventor: Javier Garcia-Martinez
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Publication number: 20150010455Abstract: Provided is a microwave catalyst. The microwave catalyst comprises: i) an active catalyst component comprising a metal and/or a metal oxide; ii) a microwave-absorbing component comprising at least one of CuO, ferrite spinel, and active carbon; and iii) a support. The microwave catalyst can be used for denitration by microwave catalysis, and has advantages such as high denitration efficiency, low energy consumption, environmental friendliness, and low costs. Also provided is a process for preparing the microwave catalyst and the use thereof.Type: ApplicationFiled: December 24, 2012Publication date: January 8, 2015Inventors: Jicheng Zhou, Zhe Wang, Hongli Wang, Meng Wang, Guiyue Mao, Zunfang Jiang, Lingfei Gao
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Patent number: 8912109Abstract: An alkylation catalyst having a zeolite catalyst component and a binder component providing mechanical support for the zeolite catalyst component is disclosed. The binder component is an ion-modified binder that can include metal ions selected from the group consisting of Co, Mn, Ti, Zr, V, Nb, K, Cs, Ga, B, P, Rb, Ag, Na, Cu, Mg, Fe, Mo, Ce, and combinations thereof. The metal ions reduce the number of acid sites on the zeolite catalyst component. The metal ions can range from 0.1 to 50 wt % based on the total weight of the ion-modified binder. Optionally, the ion-modified binder is present in amounts ranging from 1 to 80 wt % based on the total weight of the catalyst.Type: GrantFiled: May 22, 2011Date of Patent: December 16, 2014Assignee: Fina Technology, Inc.Inventors: Sivadinarayana Chinta, Joseph E. Pelati
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Patent number: 8901026Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radius of less than 0.95 ? at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.Type: GrantFiled: January 28, 2008Date of Patent: December 2, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Richard Franklin Wormsbecher, Ruizhong Hu
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Patent number: 8889587Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.Type: GrantFiled: January 11, 2013Date of Patent: November 18, 2014Assignee: General Electric CompanyInventors: Larry Neil Lewis, Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
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Patent number: 8882993Abstract: This invention relates to stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 ?m. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more.Type: GrantFiled: March 6, 2012Date of Patent: November 11, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Wenyih Frank Lai, Robert E. Kay, Jason Wu, Kun Wang, Robert C. Lemon
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Patent number: 8883668Abstract: The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/Al ratio (advantageously lower than 30) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870° C. for 0.01-200 h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt % of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.Type: GrantFiled: July 28, 2008Date of Patent: November 11, 2014Assignee: Total Research & Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Delphine Minoux, Sander Van Donk
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Patent number: 8883667Abstract: A purification catalyst which prevents contamination within a reflow furnace, including flux components, while suppressing the generation of CO is provided. A purification catalyst for a reflow furnace gas, having one or two of zeolite and silica-alumina as an active ingredient.Type: GrantFiled: October 10, 2007Date of Patent: November 11, 2014Assignee: Nikki-Universal Co., Ltd.Inventors: Yoshiki Nakano, Takanobu Sakurai, Shinichi Ueno
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Patent number: 8877670Abstract: Catalysts are disclosed comprising fibrous substrates having silica-containing fibers with diameters generally from about 1 to about 50 microns, which act effectively as “micro cylinders.” Such catalysts can dramatically improve physical surface area, for example per unit length of a reactor or reaction zone. At least a portion of the silica, originally present in the silica-containing fibers of a fibrous material used to form the fibrous substrate, is converted to a zeolite (e.g., having a SiO2/Al2O3 ratio of at least about 150) that remains deposited on these fibers. The fibrous substrates possess important properties, for example in terms of acidity, which are useful in hydroprocessing (e.g., hydrotreating or hydrocracking) applications.Type: GrantFiled: August 7, 2013Date of Patent: November 4, 2014Assignee: UOP LLCInventors: Antoine Negiz, Hui Wang
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Patent number: 8871667Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.Type: GrantFiled: March 17, 2011Date of Patent: October 28, 2014Assignee: NGK Insulators, Ltd.Inventors: Yoshio Kikuchi, Haruo Otsuka
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Publication number: 20140316177Abstract: A modified catalyst is described which can be used as a dehydration/hydrogenation catalyst in a multistage catalyst system for the catalysed production of saturated hydrocarbons from carbon oxides and hydrogen. The modified catalyst comprises: an acidic substrate comprising an M1-zeolite or M1-silicoalumino phosphate (SAPO) catalyst, where M1 is a metal; and a modifier including a metal M2. M2 comprises an alkali metal or alkaline earth metal. In examples described the modifier includes a Group II metal, for example Ca.Type: ApplicationFiled: April 21, 2011Publication date: October 23, 2014Applicants: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES, BP P.L.C.Inventors: Qingjie Ge, Xiangang Ma, Chuanyan Fang, Hengyong Xu