Support Per Se Patents (Class 502/87)
  • Patent number: 6828396
    Abstract: There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: December 7, 2004
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
  • Patent number: 6806221
    Abstract: A method of making a spray-dried composition using a solution or mixture comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from 1 &mgr;m to about 12 &mgr;m.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: October 19, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
  • Patent number: 6787497
    Abstract: The invention concerns a catalyst carrier comprising a fibre paper impregnated with a slurry comprising silica sol, micro fibres and a filler, wherein said micro fibres have an equivalent average particle size, measured with sedigraph method, from about 200 nm to about 30000 nm and said filler has an average equivalent particle size, measured with sedigraph method, from about 300 to about 10000 nm. The invention further concerns a method of its preparation, a slurry useful therefore, a catalyst comprising such a catalyst carrier and use of the catalyst.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: September 7, 2004
    Assignee: Akzo Nobel N.V.
    Inventors: Anna-Carin Dellve, Bozena Tokarz, Mats Nyström
  • Patent number: 6780805
    Abstract: Zeolite/alumina composite, and a method for making, the composite for use as a catalyst substrate or catalyst carrier and comprising zeolite having a silica/alumina ratio of greater than 300 and gamma alumina having a specific surface area of greater than 100 m2/g. The zeolite/alumina composite exhibits a modulus of rupture of at least 750 psi. Additionally, the invention is also directed at a three catalyst (TWC) system for use in the removal of hydrocarbons, carbon monoxide and oxides of nitrogen from waste gas, the TWC system comprising the following components: (1) a zeolite/alumina composite catalyst support exhibiting a modulus of rupture of at least 750 psi and having a zeolite with a silica/zeolite ratio of at least 300 and the alumina comprising a gamma alumina having a specific surface area of greater than 100 m2/g; and, (2) a noble metal catalyst impregnated on the catalyst support, the noble metal selected from the group consisting of platinum, rhodium, iridium and palladium.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: August 24, 2004
    Assignee: Corning Incorporated
    Inventors: Margaret K. Faber, Shy-Hsien Wu, Yuming Xie, Kenneth E. Zaun
  • Patent number: 6723808
    Abstract: Disclosed are polymerization catalyst activator compositions which include a carbonium cation and an aluminum containing anion. These activator compositions are prepared by combining a carbonium or trityl source and with an aluminum containing complex, preferably a perfluorophenylaluminum compound. Also disclosed are polymerization catalyst systems including the activator composition of the invention, and processes for polymerizing olefins utilizing same.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: April 20, 2004
    Assignee: Univation Technologies, LLC
    Inventor: Matthew W. Holtcamp
  • Patent number: 6682650
    Abstract: A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: January 27, 2004
    Assignees: Japan Cooperation Center, Petroleum, National Institute of Advanced Industrial Science and Technology
    Inventors: Kosaku Honna, Yasuhiro Araki, Yasuo Miki, Hiromichi Shimada
  • Publication number: 20040010100
    Abstract: A spray-dried composition comprising an inert porous filler and a reaction product of 1) a mixture or reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound. The filler is substantially spherical and has an average particle size ranging from about 1 &mgr;m to about 12 &mgr;m. Methods of making spray-dried compositions, catalysts and polymerization processes employing such are also described.
    Type: Application
    Filed: July 15, 2002
    Publication date: January 15, 2004
    Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
  • Patent number: 6664352
    Abstract: The invention provides a process for the preparation of a supported polymerization catalyst, said process comprising impregnating a porous particulate support in a mechanically fluidized state with a catalyst material.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: December 16, 2003
    Assignee: Borealis Technology Oy
    Inventors: Siw Fredriksen, Tore Dreng, Vidar Almquist
  • Patent number: 6653416
    Abstract: This invention provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer. This invention also provides catalyst compositions that are useful for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises a post-contacted organometal compound, a post-contacted organoaluminum compound, and a post-contacted fluorided solid oxide compound.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: November 25, 2003
    Assignee: Phillips Petroleum Company
    Inventors: Max P. McDaniel, Kathy S. Collins, James L. Smith, Elizabeth A. Benham, Marvin M. Johnson, Anthony P. Eaton, Michael D. Jensen, Joel L. Martin, Gil R. Hawley
  • Patent number: 6645900
    Abstract: The invention relates to a catalyst support and to a method for the production of the catalyst support comprising the following steps: a) production of a silicic acid hydrogel having a solids content of from 10 to 25% by weight (calculated as SiO2) whose particles are substantially spherical, b) extraction of the hydrogel particles with an alcohol until at least 60% of the water present in the hydrogel has been removed, c) drying of the resultant hydrogel until the residual alcohol content is less than 10% by weight (xerogel formation) at temperatures of ≧160° C. at atmospheric pressure using an inert entraining gas, d) setting of the desired particle size of the resultant xerogel, in which the hydrogel particles have a particle size of ≧8 mm before the extraction, and to a catalyst and to a method for the production of the catalyst by loading the catalyst support with a chromium compound. The invention also relates to a method for the production of polyolefins using the catalyst.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: November 11, 2003
    Assignee: Basell Polyolefine GmbH
    Inventors: Paulus de Lange, Guido Funk, Andreas Deckers, Peter Kölle
  • Patent number: 6642340
    Abstract: A process for preparing an ethylene/&agr;-olefin copolymer, which includes the steps of (A) copolymerizing ethylene and an &agr;-olefin of 3 to 20 carbon atoms by continuous vapor phase polymerization; (B) copolymerization is conducted in the presence of a prepolymerized catalyst obtained by prepolymerizing an olefin in the presence of (a) a transition metal compound, (b) an organoaluminum oxy-compound, (c) a fine particle carrier, and optionally (d) an organoaluminum compound; and (C) copolymerization is conducted under such condition that the partial pressure of sum total of ethylene and &agr;-olefin is 10 to 28 kg/cm2. The resulting ethylene/&agr;-olefin copolymer has the following properties: (i) the density is in the range of 0.880 to 0.960 g/cm3, (ii) the melt flow rate of 190° C. under a load of 2.16 kg is in the range of 0.1 to 100 g/10 min, (iii) the melt tension (MT (g)) at 190° C. and the melt flow rate (MFR (g/10 min)) satisfy the relation MT≦2.2×MFR−084.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: November 4, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Mamoru Takahashi, Takasi Nakagawa, Masaaki Ohgizawa
  • Patent number: 6635728
    Abstract: A process for making an ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The process is performed with a supported quinolinoxy-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen. The process significantly increases the catalyst activity and the UHMWPE produced has improved tensile and impact properties.
    Type: Grant
    Filed: January 10, 2002
    Date of Patent: October 21, 2003
    Assignee: Equistar Chemicals, LP
    Inventor: Jia-Chu Liu
  • Publication number: 20030153466
    Abstract: An agricultural and horticultural plant growth zeolite-based composition containing a particular zeolitic (i.e., zeolite-containing) material, termed “Jordanite,” is disclosed. This composition exhibits a collection of outstanding advantageous properties in agricultural and horticultural applications. Jordanite, which is found in a particular area of Jordan, comprises primarily phillipsite as the zeolite, optionally in conjunction with palagonite. Jordanite provides surprisingly better results as compared to when other zeolite-based soil amendment compositions, even when it is used as the mined material that has been only subject to a grinding or crushing operation to a desired mesh size. As mined, Jordanite contains very low levels of undesired Na+ ions. It can, therefore, be used without being subjected to a washing operation to remove these ions. Jordanite also possesses a very high CEC.
    Type: Application
    Filed: December 21, 2001
    Publication date: August 14, 2003
    Applicant: ASI SPECIALITIES, LTD.
    Inventors: A. John Allen, Sebastian Braum
  • Patent number: 6602816
    Abstract: Activated regular-shaped clay particles forming macropores therein, preserving fine structure of the dioctahedral smectite clay minerals, and having particle diameters controlled to lie within a range in which they exhibit excellent filtering property. The invention further provides method of producing activated regular-shaped clay particles comprising the steps of adjusting the particle size of the dioctahedral smectite clay minerals to possess a volume-based median diameter (D50) of from 1 to 10 &mgr;m as found by a laser diffraction method, mixing an acid-soluble or acid-decomposing inorganic compound to the milled product thereof, granulating the mixture into regular particles having a volume-based median diameter (D50) of from 10 to 60 &mgr;m as found by a laser diffraction method, and treating the regular-shaped particles with an acid while maintaining the particle shapes.
    Type: Grant
    Filed: March 13, 2001
    Date of Patent: August 5, 2003
    Assignee: Mizusawa Industrial Chemicals Ltd
    Inventors: Masashi Hatano, Hitoshi Yamamoto, Daisuke Kuse
  • Publication number: 20030130110
    Abstract: There are provided:
    Type: Application
    Filed: January 21, 2003
    Publication date: July 10, 2003
    Inventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
  • Publication number: 20030130448
    Abstract: A process for making an ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The process is performed with a supported quinolinoxy-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen. The process significantly increases the catalyst activity and the UHMWPE produced has improved tensile and impact properties.
    Type: Application
    Filed: January 10, 2002
    Publication date: July 10, 2003
    Inventor: Jia-Chu Liu
  • Patent number: 6544921
    Abstract: There are provided: (I) a solid catalyst component (A-1) for olefin polymerization, which is obtained by a process comprising the step of contacting: (a-1) a carrier of carboxyl group-carrying polymer particles having an average particle diameter of from 1 to 300 &mgr;m, and (b) a transition metal compound of the number 4 group of metals in the periodic table of elements; (II) a catalyst for olefin polymerization, which is obtained by a process comprising the step of contacting: (A-1) the above solid catalyst component, and (B) at least one compound selected from the group consisting of an organoaluminum compound and an organoaluminumoxy compound; (III) a process for producing an olefin polymer, which comprises the step of polymerizing an olefin in the presence of the above catalyst; and (IV) a process for producing the above solid catalyst component (A-1), which comprises the step of contacting: (a-1) the above carrier, and (b) the above transition metal compound.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: April 8, 2003
    Assignee: Sumitomo Chemical Comapny, Limited
    Inventors: Tatsuya Miyatake, Masaaki Nabika, Seiki Kiuchi
  • Patent number: 6531552
    Abstract: An olefin polymerization catalyst comprising the following components (A) and (B): Component (A): an ion-exchange layered silicate having an acid site of at most −8.2 pKa, the amount of the acid site is equivalent to at least 0.05 mmol/g of 2,6-dimethylpyridine consumed for neutralization; and Component (B): a compound of a transition metal belonging to Group 3 to Group 12 of the Periodic Table.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: March 11, 2003
    Assignee: Japan Polychem Corporation
    Inventors: Hiroshi Nakano, Takao Tayano, Hideshi Uchino, Tadashi Takahashi
  • Patent number: 6495484
    Abstract: Disclosed are polymerization catalyst activator compositions which include a carbonium cation and an aluminum containing anion. These activator compositions are prepared by combining a carbonium or trityl source and with an aluminum containing complex, preferably a perfluorophenylaluminum compound. Also disclosed are polymerization catalyst systems including the activator composition of the invention, and processes for polymerizing olefins utilizing same.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: December 17, 2002
    Assignee: Univation Technologies, LLC
    Inventor: Matthew W. Holtcamp
  • Patent number: 6476085
    Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: November 5, 2002
    Assignee: Conoco Inc.
    Inventors: Leo E. Manzer, Stephan Schwarz
  • Patent number: 6475945
    Abstract: The present invention relates to functionalized catalyst supports that are useful in the formation of supported polymerization catalysts, supported catalysts derived from such functionalized catalyst supports, methods for preparing such functionalized catalyst supports and supported catalysts, and polymerization processes utilizing such supported catalysts. The functionalized catalyst support comprises a particulated support material having chemically bonded thereto a plurality of aluminum-containing groups derived from a non-ionic Lewis acid, said aluminum-containing groups: containing at least one fluoro-substituted hydrocarbyl ligand containing from 1 to 20 carbons, said hydrocarbyl ligand being bonded to aluminum, and being bonded to said support material, optionally through a bridging moiety, said composition being capable of activating a Group 3-10 metal complex for the addition polymerization of one or more addition polymerizable monomers.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: November 5, 2002
    Assignee: The Dow Chemical Company
    Inventors: Edmund M. Carnahan, Grant B. Jacobsen
  • Publication number: 20020140138
    Abstract: Zeolite based material and a method for making the zeolite, comprising a zeolite having a silica/alumina ratio of at least 300 and a surface area of 250 m2/g and no greater than about 20 parts, by weight, of a silica binder. The combination of properties this zeolite based material exhibits includes the following: (1) a modulus of rupture of at least 1500 psi; (2) a surface area of at least 100 m2/g; (3) a coefficient of thermal expansion of less than about +/−10 ppm/° C.; and, (4) a thermal shock resistance of at least 850° C. The zeolite-based material can include a third component, specifically a gamma alumina having a specific surface area of greater than 100 m2/g.
    Type: Application
    Filed: December 12, 2000
    Publication date: October 3, 2002
    Inventors: Shy-Hsien Wu, Kenneth E. Zaun
  • Patent number: 6413898
    Abstract: Zeolite/alumina composite, and a method for making, the composite for use as a catalyst substrate or catalyst carrier and comprising zeolite having a silica/alumina ratio of greater than 300 and gamma alumina having a specific surface area of greater than 100 m2/g. The zeolite/alumina composite exhibits a modulus of rupture of at least 750 psi. Additionally, the invention is also directed at a three catalyst (TWC) system for use in the removal of hydrocarbons, carbon monoxide and oxides of nitrogen from waste gas, the TWC system comprising the following components: (1) a zeolite/alumina composite catalyst support exhibiting a modulus of rupture of at least 750 psi and having a zeolite with a silica/zeolite ratio of at least 300 and the alumina comprising a gamma alumina having a specific surface area of greater than 100 m2/g; and, (2) a noble metal catalyst impregnated on the catalyst support, the noble metal selected from the group consisting of platinum, rhodium, iridium and palladium.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: July 2, 2002
    Assignee: Corning Incorporated
    Inventors: Margaret K. Faber, Shy-Hsien Wu, Yuming Xie, Kenneth E. Zaun
  • Patent number: 6395666
    Abstract: This invention provides catalyst composition for polymerizing at least one monomer to produce a polymer, wherein said catalyst composition comprises as organometal compound, as organoaluminum compound, and a fluorided solid oxide compound.
    Type: Grant
    Filed: September 29, 1999
    Date of Patent: May 28, 2002
    Assignee: Phillips Petroleum Company
    Inventors: Max P. McDaniel, Kathy S. Collins, James L. Smith, Elizabeth A. Benham, Marvin M. Johnson, Anthony P. Eaton, Michael D. Jensen, Joel L. Martin, Gil R. Hawley
  • Publication number: 20020061812
    Abstract: The slurry for carrying zeolite of the present invention is slurry for attaching zeolite to a carrier and comprises zeolite and an organic emulsion binder dispersed in water. This slurry for carrying zeolite has viscosity not excessively high in spite of a large content of zeolite and binder and has a pH at which the zeolite and binder are stable. The slurry therefore can be stored for a long time in a stable manner.
    Type: Application
    Filed: September 24, 2001
    Publication date: May 23, 2002
    Applicant: Nichias Co., Ltd.
    Inventors: Teruzi Yamazaki, Jun Shimada
  • Patent number: 6387837
    Abstract: This invention relates to a process for the free-radical polymerization of monomers in gas phase or suspension processes using a supported, polymerization-initiating system comprising a) one or more polymerization-initiating components which initiate and start free-radical polymerization, b) a support, onto which said polymerization-initiating component is applied, and c) optionally, one or more modifiers which have an influence upon reaction kinetics and/or product properties.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: May 14, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Dauben, Martin Hoch, Christiane Oppenheimer-Stix, Peter Schertl
  • Publication number: 20020052289
    Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.
    Type: Application
    Filed: November 16, 2001
    Publication date: May 2, 2002
    Inventors: Leo E. Manzer, Stephan Schwarz
  • Patent number: 6372685
    Abstract: Silica powders and mixed silica-oxide powders and methods of preparing such powders for use as catalyst supports for polymerization processes.
    Type: Grant
    Filed: April 25, 2000
    Date of Patent: April 16, 2002
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Theresa A. Pecoraro, Ignatius Y. Chan, Darryl K. Whaley, Pamela R. Auburn
  • Patent number: 6362122
    Abstract: A process for regenerating spent zeolite composites. The process involves contacting the composite, either as a shaped article or a fine powder, with a caustic solution, e.g., sodium hydroxide at treating condition. Once the contacting is completed, the composite is isolated, washed with water, dried and calcined to give a regenerated composite.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: March 26, 2002
    Assignee: UOP LLC
    Inventor: Thomas R. Cannan
  • Patent number: 6333289
    Abstract: The present invention relates to a process for activating catalysts for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization and at least one passivation using ammonia.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: December 25, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Jean-François Joly, Julia Magne-Drisch, Fabio Alario, Elisabeth Merlen, Eric Benazzi, Sylvie Lacombe
  • Patent number: 6319872
    Abstract: This invention provides a process for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons, and uses a catalyst including (a) at least one catalytic metal for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium) and (b) a non-layered mesoporous support which exhibits an X-ray diffraction after calcination that has at least one peak at a d-spacing of greater than 18 Ångstrom units.
    Type: Grant
    Filed: August 18, 1999
    Date of Patent: November 20, 2001
    Assignee: Conoco INC
    Inventors: Leo E. Manzer, Stephan Schwarz
  • Publication number: 20010009884
    Abstract: The invention relates to a method for producing an adsorbent and/or catalyst and binder system comprising I) mixing components comprising (a) a binder comprising a colloidal metal oxide or colloidal metalloid oxide, (b) an oxide adsorbent and/or catalyst particle, and (c) an acid, (ii) removing a sufficient amount of water from the mixture to cross-link components a and b to form an adsorbent and/or catalyst and binder system. The invention also relates to particles made by the process, binders, and methods for remediating contaminants in a stream.
    Type: Application
    Filed: December 7, 2000
    Publication date: July 26, 2001
    Inventors: Mark L. Moskovitz, Bryan E. Kepner, Eric A. Mintz
  • Patent number: 6242167
    Abstract: An electron accepting developer useful for producing visible images by reaction with an electron donor in carbonless paper and photo-imaging systems, the developer comprising an acid-treated, water insoluble alkali metal-modified, inorganic oxide or an acid-treated molecular sieve.
    Type: Grant
    Filed: April 12, 1999
    Date of Patent: June 5, 2001
    Assignee: Rentech, Inc.
    Inventors: Dale R. Shackle, Benjamin Chaloner-Gill
  • Patent number: 6174834
    Abstract: Oxychlorination catalyst is produced by mixing together wet support material, copper chloride or precursor thereof, to form a paste, wherein the wet support material is wet clay, wet silica, wet silica gel, wet alumina, wet diatomaceous earth, or a mixture of two or more thereof; removing water from the paste to produce a substantially dry mixture; and calcining the substantially dry mixture at elevated temperatures to produce a calcined mixture wherein alkali metal chloride or precursor thereof is mixed with the wet support material or an aqueous solution of alkali metal chloride or precursor thereof is applied to the paste, the substantially dry mixture, or the calcined mixture and the water of the aqueous solution is substantially removed. Preferably wet attapulgus clay, cupric chloride, and potassium chloride are mixed to form the paste.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: January 16, 2001
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Henry W. Schussler, III
  • Patent number: 6174430
    Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises: a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na2O level of less than or equal to about 0.2 weight percent; b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; and c) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m2/g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: January 16, 2001
    Assignee: Shell Oil Company
    Inventors: Bruce Herman Charles Winquist, David Allen Cooper
  • Patent number: 6093672
    Abstract: A noble metal hydrocracking catalyst which has high selectivity for naphtha range products is provided. The hydrocracking catalyst comprises:a) from about 70 to about 90 weight percent of a Y zeolite, based on the catalyst having a silica to alumina mole ratio of from about 4.8 to less than 6.0, a unit cell constant within the range of about 24.50 to about 24.57, a Na.sub.2 O level of less than or equal to about 0.2 weight percent;b) from about 10 to about 30 weight percent, based on the catalyst of an alumina having a mercury intrusion pore volume within the range from about 0.55 to about 0.85 cc/g; andc) from about 0.5 to 1 weight percent, based on the catalyst of a noble metal; wherein said hydrocracking catalyst have a dispersivity of the noble metal of equal or greater than about 50% by hydrogen chemisorption measurement, a surface area of greater than or equal to 700 m.sup.2 /g by BET surface area measurement, a compacted bulk density within the range of from about 0.40 to 0.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: July 25, 2000
    Assignee: Shell Oil Company
    Inventors: Bruce Herman Charles Winquist, David Allen Cooper
  • Patent number: 5972831
    Abstract: The present invention concerns a novel photocatalytic composition, a photocatalytic element and a novel method for the photocatalytic treatment of effluents, comprising a gaseous or aqueous solution of the organic compounds to be destroyed.This novel photocatalytic composition consists of an inorganic gel comprising a photocatalyst and an aluminosilicate inorganic polymer binder of the Imogolite type.This composition destroys organic compounds efficaciously.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: October 26, 1999
    Assignee: Eastman Kodak Company
    Inventors: Olivier J. Poncelet, Danielle M. Wettling
  • Patent number: 5807800
    Abstract: Stereospecific catalysts and processes for the stereotactic polymerization of ethylenically unsaturated monomers, specifically C.sub.3 -C.sub.4 alpha olefins involving a molecular sieve supported metallocene catalyst comprising a stereospecific metallocene catalyst component and a co-catalyst component. The metallocene catalyst component incorporates a metallocene ligand structure having two sterically dissimilar cyclopentadienyl ring structures coordinated with the central transition metal atom. Both the metallocene catalyst component and the co-catalyst component are supported on a molecular sieve having an average effective pore size which is less than the kinetic diameter of at least one of said ring structures. This supported catalyst is contacted in a polymerization reaction zone with an ethylenically unsaturated monomer which contains 3 or more carbon atoms or which is a substituted vinyl compound under polymerization conditions to produce stereospecific polymerization of the monomer.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: September 15, 1998
    Assignee: Fina Technology, Inc.
    Inventors: Edwar S. Shamshoum, Margarito Lopez
  • Patent number: 5756415
    Abstract: A method of preparing an enzyme immobilizing carrier includes the steps of providing a material consisting of kaolin mineral. The material is subject to acid treatment with a strong acid having a pH of 4 or less, and hydrothermal treatment at a temperature of from about 100.degree. C. to about 250.degree. C. The material is dried, thereby producing a porous powder. The porous powder is baked at a temperature of from about 350.degree. C. to about 1000.degree. C., for thereby producing the carrier.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 26, 1998
    Assignee: Toyo Denka Kogyo Co., Ltd.
    Inventors: Joji Takahashi, Eiji Kanazawa, Yoshitaka Yamashita, Tomio Kashiwai, Hideo Takenaka
  • Patent number: 5750026
    Abstract: A device for purifying a workstream of contaminants and method of making. One device is made of an inorganic monolithic porous particulate filter and a continuous uninterrupted coating of activated carbon impregnated into the pores of the filter. Preferably the filter has inlet and outlet faces, and a multiplicity of cells separated by porous walls and extending longitudinally and mutually parallel therethrough from inlet to outlet end, a portion of the total number of cells being plugged at the inlet end face, and the remaining portion of the total number of cells being plugged at the outlet end face of the device. Another device can be made entirely of activated carbon having the multicellular structure. A workstream containing contaminants is passed through the device to cause retention of the contaminants. The device can have electrically conducting mechanism for conducting electric current therethrough for removal of the contaminants and regeneration of the device.
    Type: Grant
    Filed: January 15, 1997
    Date of Patent: May 12, 1998
    Assignee: Corning Incorporated
    Inventors: Kishor P. Gadkaree, Timothy V. Johnson
  • Patent number: 5736479
    Abstract: The invention concerns new oxidation catalysts, methods of producing them and their use. These catalysts consist of titanium silicalites crystallized in situ onto activated charcoal or metal oxides. The titanium silicalite content lies preferably in the range of 30 to 60% by wt. The atomic ratio of Si to Ti in the carrier-borne phase is 10 to 100. Such catalysts are particularly suitable for oxidation reactions with H.sub.2 O.sub.2 under mild conditions, such as temperatures of 20.degree. to 120.degree. C. and pressures equal to or higher than atmospheric.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: April 7, 1998
    Assignee: Leuna-Katalysatoren GmbH
    Inventors: Rainer Schodel, Peter Birke, Reinhard Geyer, Peter Kraak, Willibald Muller, Hans-Dieter Neubauer, Rolf Pester, Fritz Vogt, Klaus-Peter Wendlandt
  • Patent number: 5721037
    Abstract: A honeycomb structural body is obtained by mixing 60.about.80 wt % of aggregate, which does not show a transformation of crystal structures substantially up to 500.degree. C., and 20.about.40 wt % of clay to obtain a mixture, adding phosphate as a hardening agent to the mixture in such a manner that more than 2.0 wt % of phosphoric acid exists therein with respect to 100 wt % of the mixture, adding a forming agent and a water to the mixture to obtain a formable batch, extruding the batch into a honeycomb structure to obtain a honeycomb structural formed body, drying the honeycomb structural formed body, and subjecting the honeycomb structural formed body to a heat treatment in 300.degree..about.500.degree. C. The thus obtained honeycomb structural body has excellent catalyst carrying property and fireproof property, which are used as a catalyst carrier for ozone dissolving, deodorizing and so on in an inexpensive manner.
    Type: Grant
    Filed: July 28, 1995
    Date of Patent: February 24, 1998
    Assignee: NGK Insulators, Ltd.
    Inventors: Kazuhiko Kumazawa, Tatsuya Ishiguro
  • Patent number: 5716899
    Abstract: A body made up of substantially continuous high strength multicellular support having porous cell walls, and pores in the cell walls having an average pore diameter of which have active material embedded therein, and an outer surface. The body is made of material which can be ceramics, glass, glass-ceramic, cermet, metal, oxides, and combinations of these. The active material can be molecular sieve, activated carbon, and combinations these. A method for producing a pore-impregnated body which involves providing the substrate having a wall porosity greater than about 45% by volume, and an average pore diameter of about 15 to 30 micrometers, providing a slurry of active material dispersed in a medium, contacting the support with the slurry at subatmospheric pressure to substantially fill the open pores of the substrate with the active material, removing excess slurry from the outer surface and the non-pore surfaces of the cell walls, followed by drying.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: February 10, 1998
    Assignee: Corning Incorporated
    Inventors: Donald L. Guile, Jimmie L. Williams
  • Patent number: 5698165
    Abstract: An ozone filter comprising a paper carrier made of inorganic fiber and having a high porosity is disclosed. Supported by the carrier is a zeolite powder having an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of not smaller than 15 and fine powder-like activated manganese dioxide having ozone decomposing capability. A process for producing the ozone filter is also disclosed. The ozone filter does not give off a foul smell even when used for a long period of time.
    Type: Grant
    Filed: August 24, 1995
    Date of Patent: December 16, 1997
    Assignee: Nichias Corporation
    Inventors: Isao Terada, Shinichiro Arai
  • Patent number: 5632931
    Abstract: Bloated minerals previously used as aggregates for light-weight concrete are here fragmented, wetted, and intermixed with particulate chemical reactants or catalysts, to serve as inert carriers therefor in industrial processes. One use is in the deep-bed flow-through process of reacting and removing hydrogen sulfide as contained in natural gas.
    Type: Grant
    Filed: August 24, 1995
    Date of Patent: May 27, 1997
    Assignee: Gas Sweetener Associates, Inc.
    Inventors: Irwin Fox, deceased, Alvin Samuels
  • Patent number: 5409671
    Abstract: A catalytic convertor for treating exhaust gas includes a first catalyst layer formed on a base material and a second catalyst layer formed on the first catalyst layer. The first catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one precious metal borne on the silicate, and the second catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one metal borne on the silicate which is selected from the group consisting of Zr, Co, Cu, Cr, Mn, Y, Fe, Ni, V, Ti, Zn, Ga, Ba, Mg, La, Ce, Pr, Nd, Sm and Tb and differs from the transition metal provided on the silicate by ion exchange.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: April 25, 1995
    Assignee: Mazda Motor Corporation
    Inventors: Takashi Takemoto, Yasuto Watanabe, Masahiko Shigetsu, Kazunari Komatsu, Makoto Kyogoku
  • Patent number: 5407880
    Abstract: A catalyst for the adsorption of hydrocarbons is used in an apparatus for the purification of exhaust gas from an internal engine and comprises a honeycomb monolith carrier, a first layer of at least one zeolite having a different crystalline structure, a second layer containing at least one of Pt and Pd as a catalytic component, and a third layer containing Rh as a catalytic component.
    Type: Grant
    Filed: November 5, 1993
    Date of Patent: April 18, 1995
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Takuya Ikeda, Chiemi Hayashi, Tetsuo Ito, Koji Masuda, Maki Kamikubo
  • Patent number: 5215724
    Abstract: A filter for removing impurities from waste gases, and especially from the waste gases of an internal combustion engine, includes a filter body consisting of a plurality of compression moulded, high temperature resistant, sintered filter plates consisting of metal powder, metal chips, metallic fibres or a mixture of these materials, which are arranged on top of or behind one another and kept at a distance from one another by spacers, to form between them a plurality of flow channels. The flow channels are open at one end and closed at the other end in order to form inlet and outlet channels. The walls of the filter plate situated between the inlet and outlet channels constitute filter surfaces. The filter plates are formed by filter discs lying on top of one another, arranged in a filter housing and having a free or open central interior space, so that the waste gases flow radially through the filter discs from the outside towards the interior space or from the interior space towards the outside.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: June 1, 1993
    Assignee: Schwabische Huttenwerke GmbH
    Inventor: Hans A. Haerle
  • Patent number: 5180701
    Abstract: The present invention relates to a process for preparing a shapable dough which comprises mixing and kneading a silica source, a dealuminated aluminosilicate zeolite source, water and a trialkanolamine containing at least two carbon atoms per alkanolamine moiety, to a shapable dough thus obtained, and to the preparation of extrudates containing dealuminated aluminosilicate zeolites by extruding a shapable dough comprising a silica source, a dealuminated aluminosilicate zeolite source, water and a trialkanolamine and having a total solids content between about 25% by weight and about 75% by weight and a trialkanolamine content between about 0.5% by weight and about 40% by weight, basis on the total solid content of the mixture.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: January 19, 1993
    Assignee: Shell Oil Company
    Inventors: Patrick Moureaux, Jean P. Darnanville
  • Patent number: 5149435
    Abstract: A molecular sieve material is combined with a porous carrier material. The pores of the molecular sieve material are impermeable to molecules or organisms having a size equal to or greater than that of the water molecule either because the molecular sieve material is selected so as to have pores which are smaller than such molecule or because the pores of the molecular sieve material are closed by a film. The pores of the molecular sieve material thus remain unoccupied and are able to exert an attractive force on molecules or organisms which are to be captured. The pores of the carrier material are designed to accept molecules or organisms having a size equal to or greater than that of the water molecule so that, when such molecules or organisms are attracted by the molecular sieve material, they can be trapped in the carrier material.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: September 22, 1992
    Assignee: H J L Projects & Developments Ltd.
    Inventor: Hans-Jurgen Laube