Having Constituent Defined In Terms Of Melting Temperature Patents (Class 503/208)
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Patent number: 11326943Abstract: A data collection device includes a housing and a data collection unit located in the housing. A power unit is located in the housing and is operably connected to the data unit to provide power for operation of the data unit. An irradiation sensor is located at the data collection device to detect exposure of the data collection device to irradiation. An irradiation sensor includes a thermal energy absorbing material and a thermal energy sensitive material in thermal communication with the thermal energy absorbing material. The thermal energy sensitive material is characterized by a change in color when exposed to a selected degree of thermal energy due to irradiation.Type: GrantFiled: February 15, 2017Date of Patent: May 10, 2022Assignee: CARRIER CORPORATIONInventors: Richard Desmarais, Eric Day
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Patent number: 10906341Abstract: The present invention relates to a thermosensitive recording material and, specifically, to a thermosensitive recording material comprising: a colorless or light-colored leuco dye; a compound of chemical formula (1) containing a non-phenolic sulfonyl urea group as a developer; at least one of general formulas II-1, II-2, and II-3 as a sensitizer; a binder; and other fillers. The thermosensitive recording material of the present invention improves the background blurring of a color-developed image by using a non-phenolic developer and exhibits excellent effects in view of color development sensitivity, water resistance, oil resistance, plasticizer resistance, and the like.Type: GrantFiled: December 9, 2016Date of Patent: February 2, 2021Assignees: HANSOL PAPER CO., LTD.Inventors: Kyu-Cheol Paik, Jung-Ok An
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Patent number: 10581000Abstract: A condensed cyclic compound represented by Formula 1: wherein in Formula 1, groups X1 to X3 and X11 to X18 are the same as described in the specification.Type: GrantFiled: September 21, 2015Date of Patent: March 3, 2020Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD.Inventors: Soonok Jeon, Sangmo Kim, Joonghyuk Kim, Youngseok Park, Youngmok Son, Yeonsook Chung, Yongsik Jung
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Patent number: 9273232Abstract: Disclosed is a tape that includes a substrate having an adhesive layer applied thereto, and an edge coating applied to a masking edge of the tape. The substrate and the adhesive, together, define a first and a second masking edge of the tape. The edge coating includes a flocculating agent that is a polyvalent metal salt or an ionic polymer. The edge coating improves the ability of the tape to provide a sharp mask line after a paint, a varnish, a paint stripper, or other coating composition is applied to a surface where the tape is adhered.Type: GrantFiled: November 8, 2011Date of Patent: March 1, 2016Assignee: INTERTAPE POLYMER CORP.Inventors: John K. Tynan, Jr., Mark A. Lewandowski, Deborah Anne Chrzanowski, Paul E. Rhude
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Patent number: 9254936Abstract: Methods for applying a liner-free, or liner-less label, to a substrate, particularly glass or plastic (e.g., polyethylene terephthalate) substrates, are described herein. The method includes applying an adhesive composition, such as a polymeric coating, to a label face sheet, activating the adhesive composition with an activating fluid, and contacting the label to the substrate. The activating fluid is preferably a mixture of water and one or more organic solvents, such as low molecular weight alcohols.Type: GrantFiled: June 20, 2014Date of Patent: February 9, 2016Assignee: NuLabel Technologies, Inc.Inventors: Daniel Cho, Heidi Munnelly, Benjamin Lux
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Patent number: 8975211Abstract: A security document precursor including, in order, at least: a) a transparent biaxially stretched polyethylene terephthalate foil; b) a colorless color forming layer containing at least an infrared absorber, a color forming component and a polymeric binder; and c) a polymeric support; wherein the colorless color forming layer contains at least one component forming a compound having a melting temperature of less than 20° C. upon laser marking the colorless color forming layer with an infrared laser. Methods for securing a security document using the security document precursor are also disclosed.Type: GrantFiled: December 2, 2011Date of Patent: March 10, 2015Assignee: Agfa-Gevaert N.V.Inventors: Bart Waumans, Ingrid Geuens, Paul Callant, Hubertus Van Aert
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Patent number: 8889590Abstract: An irreversible thermochromic ink composition can include thermochromic pigment capsules dispersed in a carrier. The irreversible thermochromic pigment capsules can include an inner core having a color changing dye, a color activator for activating the color changing dye, and a wax, an outer core surrounding the inner core and comprising a color destroying agent, and a shell surrounding the outer core. Alternatively, the irreversible thermochromic pigment capsules can include an inner core having a color destroying agent and a wax, an outer core surrounding the inner core and comprising a color changing dye and a color activator for activating the color changing dye, and a shell surrounding the outer core. Written marks made with the irreversible thermochromic inks can be rendered a different color or substantially colorless by application of a sufficient amount of heat to melt or substantially liquefy the wax in the irreversible thermochromic pigment capsules.Type: GrantFiled: December 31, 2013Date of Patent: November 18, 2014Assignee: Sanford, L.P.Inventor: Wing Sum Vincent Kwan
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Patent number: 8664156Abstract: An irreversible thermochromic ink composition can include thermochromic pigment capsules dispersed in a carrier. The irreversible thermochromic pigment capsules can include an inner core having a color changing dye, a color activator for activating the color changing dye, and a wax, an outer core surrounding the inner core and comprising a color destroying agent, and a shell surrounding the outer core. Alternatively, the irreversible thermochromic pigment capsules can include an inner core having a color destroying agent and a wax, an outer core surrounding the inner core and comprising a color changing dye and a color activator for activating the color changing dye, and a shell surrounding the outer core. Written marks made with the irreversible thermochromic inks can be rendered a different color or substantially colorless by application of a sufficient amount of heat to melt or substantially liquefy the wax in the irreversible thermochromic pigment capsules.Type: GrantFiled: December 31, 2011Date of Patent: March 4, 2014Assignee: Sanford, L.P.Inventor: Wing Sum V. Kwan
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Patent number: 8603943Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.Type: GrantFiled: November 19, 2009Date of Patent: December 10, 2013Assignee: Mitsubishi HiTec Paper Europe GmbHInventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
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Publication number: 20120252666Abstract: The present invention provides a heat-sensitive recording material, characterized in that a carrier material carries at least one coating layer in which at least two colour-forming reactants A and B are contained, wherein the layer contains a water-insoluble or sparingly water-soluble iron compound as colour-forming reactant A and a water-insoluble or sparingly water-soluble phenol compound having 2 or more adjacent OH groups as reactant B separated from each other, wherein at least one of the compounds melts at less than 100° C. and this melt reacts with the other colour-forming reactant by colour development in less than 1 second's contact time and at least one of the two colour-forming reactants is present as particles having a size of less than 20 ?m.Type: ApplicationFiled: November 22, 2010Publication date: October 4, 2012Inventors: Andreas Kornherr, Thomas Schalkhammer, Roland Palkovits
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Publication number: 20110251060Abstract: A thermographic substrate assembly comprised of a colorant and a flexible substrate. This assembly also contains a thermosensitive layer, and the thermosensitive layer contains a binder, a multiplicity of hollow sphere organic pigments, and a thermal solvent.Type: ApplicationFiled: April 5, 2011Publication date: October 13, 2011Applicant: International Imaging Materials, Inc.Inventors: Daniel Jude Harrison, Barry Marginean, Kathleen Lindstrom, Natalie Soldwisch, John Przybylo
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Publication number: 20110224074Abstract: To provide a thermosensitive recording medium, containing: a support; a thermosensitive recording layer; and a surface layer, where the thermosensitive recording layer and the surface layer are provided over the support, wherein the thermosensitive recording layer contains a binding agent, a coloring agent, and a color developer, and wherein the surface layer contains polyester (meth)acrylate having at least three (meth)acryloyl groups, and an ?-hydroxyketone-based polymerization initiator having a melting point of 80° C. or higher.Type: ApplicationFiled: March 7, 2011Publication date: September 15, 2011Applicant: RICOH COMPANY, LTD.Inventors: Shinji OKADA, Kenji Shimizu
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Patent number: 7557065Abstract: The invention provides a heat-sensitive recording material, which is highly sensitive, is almost free of staining on the background, and gives a recorded image excellent in stability during storage, by using a finely divided sensitizer dispersion excellent in shelf stability produced in a short time with high volumetric efficiency. The invention relates to a method of producing a sensitizer dispersion, which comprises emulsifying and finely dividing a heat-sensitive recording sensitizer by melting under heating in an aqueous emulsifying dispersant, and then crystallizing the finely divided emulsified dispersion under rapid cooling, wherein the sensitizer is at least one member selected from the group consisting of 1,2-bis(phenoxy)ethane, 1,2-bis(3-methylphenoxy)ethane, 1,2-bis(4-methylphenoxy)ethane, p-benzylbiphenyl, di-p-methylbenzyl oxalate, and ?-naphthyl benzyl ether.Type: GrantFiled: April 8, 2004Date of Patent: July 7, 2009Assignee: Sanko Co., Ltd.Inventors: Shigeru Oda, Eiji Kawabata, Takaaki Mori, Tjang Kie Tan, Hiroshi Sumitomo, Yoshito Nakagawa
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Patent number: 7335624Abstract: A reversible thermochromic display article which comprises a substrate and, formed thereon, a heat coloration image containing a heat coloration type reversible thermochromic composition which is colored by heating and is decolored by cooling and a heat decoloration image containing a heat decoloration type reversible thermochromic composition which is decolored by heating and is colored by cooling, or having a multilayer structure comprising a heat coloration layer containing the heat coloration type reversible thermochromic composition and a heat decoloration layer containing the heat decoloration type reversible thermochromic composition, wherein the heat coloration type reversible thermochromic composition is a microcapsule composition which contains, enclosed therein, (a) an electron-donating chromatic organic compound, (b)? an electron-accepting compound selected from gallic acid esters, and (c) a reaction medium having a melting point lower than 50° C.Type: GrantFiled: January 27, 2005Date of Patent: February 26, 2008Assignee: The Pilot Ink Co., Ltd.Inventors: Kuniyuki Senga, Katsuyuki Fujita, Shigehiro Koide
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Patent number: 7087276Abstract: A thermal transfer recording medium include a support; and a heat-sensitive transfer layer on the support, and wherein the heat-sensitive transfer layer includes: a resin made from monomer which includes a glycidyl ester of an unsaturated carboxylic acid; and sulfonamide. The present invention also provides a thermal transfer recording method including transferring an image from the thermal transfer recording medium to an image receiving member.Type: GrantFiled: March 17, 2005Date of Patent: August 8, 2006Assignee: Ricoh Company, Ltd.Inventors: Takayuki Sasaki, Shigeru Miyajima, Yoshiaki Yamada
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Patent number: 7081435Abstract: The present invention is the thermally sensitive recording medium comprising a thermally sensitive color developing layer containing colorless or pale colored basic leuco dye and a color developing agent as a main components on a substrate, wherein said thermally sensitive recording layer contains acrylic emulsion and colloidal silica, further contains at least one kind of diphenylsulfone bridgeable compound represented by general formula A as the color developing agent, wherein, X and Y can be different or same and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1–12 which can possess an ether bond, or indicate, wherein, R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1–4, and R1–R6 independently indicate a halogen-atom, an alkyl group of carbon number 1–6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0–4 and when are bigger than 2, R1–R6 can be different, anType: GrantFiled: January 15, 2003Date of Patent: July 25, 2006Assignee: Nippon Paper Industries Co., Ltd.Inventors: Takanori Otsuhata, Tadakazu Fukuchi
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Patent number: 7060654Abstract: A coating includes an antenna uniformly distributed in both a matrix and a leuco-dye phase of the coating. A method for preparing an imaging material includes providing a powder having an activator and an antenna, dissolving the activator/antenna powder to form an activator/matrix pre-polymer solution, providing a leuco-dye alloy, and dispersing the leuco-dye alloy into the activator/matrix pre-polymer solution to form a radiation-curable paste. An image-recording medium includes a matrix having an antenna and an activator, and an alloy dispersed in the matrix as an independent phase. The alloy includes an antenna, a leuco-dye, and an accelerator.Type: GrantFiled: October 28, 2003Date of Patent: June 13, 2006Assignee: Hewlett-Packard Development CompanyInventors: Vladek P Kasperchik, Makarand P. Gore, Marshall Field, Jayprakash Bhatt
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Patent number: 7045487Abstract: A black and white monosheet substantially light-insensitive thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, a binder and at least one toning agent, wherein the at least one toning agent is selected from compounds represented by formula (I): wherein R1 is an alkyl group optionally substituted with a hydroxy, carboxy, carboxy ester, acyl or carbonato group; X is S, O or N—R6; R6 is an optionally substituted alkyl group; R2, R3, R4 and R5 independently represent a hydrogen atom, a halogen atom or an alkyl, an alkoxy, a thio-alkoxy, a nitro, a cyano, a carboxy, a carboxy ester, an acyl, an aldehyde, an acylamido, a sulphonamido, an acylamino, a carbonato, a hydroxy or an aryl group or at least one of R2 and R3, R3 and R4 and R4 and R5 independently represent the atoms necessary to form a carbocyclic or hType: GrantFiled: December 18, 2003Date of Patent: May 16, 2006Assignee: AGFA GevaertInventors: Ingrid Geuens, Johan Loccufier, Vera Drieghe
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Patent number: 7021846Abstract: A method of printing an image on a composite medium is described. A composite medium comprises a thermally sensitive image receiving layer and a protective layer. The image receiving layer is activated through the protective layer whereby to generate an image in the image receiving layer which is protected by the already present protective layer. A tape and cassette comprising the composite medium are also described, as it is a printing device for use with the composite medium, and a method of producing a printed label from the composite medium.Type: GrantFiled: March 19, 2002Date of Patent: April 4, 2006Assignee: EsselteInventors: Michel Woodman, Clive Lawrence Ayling, Robert Charles Lewis Day
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Patent number: 6894001Abstract: A functional material is proposed in which by developing colors, the degree of volatilization of a volatile agent can be visually checked, and the color is stabilized. A volatile agent having desensitizing property, a coloring agent, a developer and an embedding material are mixed while heating and melting, and retained on a carrier.Type: GrantFiled: August 27, 2002Date of Patent: May 17, 2005Assignee: Rengo Co., Ltd.Inventors: Hidenao Saito, Koichi Taniguchi, Dazhong Wang
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Patent number: 6835691Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen. The alkyl group in these substituents also is eight carbons or less, and more preferably from one through four carbons.Type: GrantFiled: March 18, 2003Date of Patent: December 28, 2004Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher
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Patent number: 6818592Abstract: A heat-sensitive recording material includes a support having disposed thereon a heat-sensitive color-forming layer that includes an electron-donating leuco-dye, an electron-receiving compound and an UV absorbent, wherein the layer contains 4-hydroxybenzenesulfonanilide as the electron-receiving compound. Because the layer includes 4-hydroxybenzenesulfonanilide, the heat-sensitive recording material has high sensitivity and improved image preservability, chemical resistance and sticking resistance.Type: GrantFiled: August 21, 2002Date of Patent: November 16, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Watanabe, Masayuki Iwasaki, Hirofumi Mitsuo
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Patent number: 6794334Abstract: The thermo reversible recording medium comprises a substrate and a thermo sensible layer. This thermo sensible layer is made of resin and organic lower molecular weight substance and can become transparent-state or opaque-state depending on temperature. The organic lower molecular weight substance is a linear hydrocarbon-containing compound having no carboxyl group (A) and a linear hydrocarbon-containing compound having no carboxyl group (B) having a melting point lower than the melting point of the linear hydrocarbon-containing compound having no carboxyl group (A) by 20° C. or more.Type: GrantFiled: June 8, 2001Date of Patent: September 21, 2004Assignees: Ricoh Company, Ltd., Miyashi Yushi Kabushiki KaishaInventors: Yoshihiko Hotta, Kunichika Moroboshi, Fumio Kawamura, Katsushi Sugiyama, Katsuaki Kokubo, Koji Kawai, Kazuo Hosoda, Masafumi Moriya
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Patent number: 6790809Abstract: A heat-responsive-discoloring coloring composition, which is colored at a temperature lower than its discoloration initiation temperature (T) of 60° C. to 200° C.; which is substantially discolored at a temperature equal to or higher than the discoloration initiation temperature (T); and which does not recover its color once discolored, even when its temperature is lowered to a temperature lower than the discoloration initiation temperature (T) again, the heat-responsive-discoloring coloring composition comprising a polymer having a glass transition temperature (Tg) of 60° C. to 200° C.Type: GrantFiled: August 16, 2002Date of Patent: September 14, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Keiichi Suzuki
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Patent number: 6787502Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance. The present invention for attaining the above-described object is a heat sensitive recording material comprising a substrate supporting thereon a heat sensitive recording layer containing a diazonium salt compound, a coupler which reacts with the diazonium salt compound when heated to develop color, and a base, wherein the heat sensitive recording layer includes as the base at least one of the guanidine compounds represented by the general formula (1): wherein, in the general formula (1), R1 and R2 represent an alkyl group or aryl group and may be the same or different, R3 and R4 represent a hydrogen atom, alkyl group or halogen atom and may be the same or different, and X represents a divalent connecting group.Type: GrantFiled: July 19, 2001Date of Patent: September 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
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Patent number: 6759367Abstract: A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt, a 3,4-dihydroxybenzene compound in thermal working relationship therewith and a binder, wherein the 3,4-dihydroxybenzene compound is an aryloxo-3,4-dihydroxybenzene compound in which the aryl-group is substituted with at least one substituent having a &sgr;m-value greater than 0; or a heteroaryloxo-3,4-dihydroxybenzene compound in which the heteroaryl group has a unified aromaticity index IA greater than 53 and is optionally substituted with at least one group selected from the group consisting of aryl, hydroxy, carboxy, sulfo, sulfoalkyl, sulfoaryl, sulfonylalkyl, sulfonylaryl, annulated aryl, annulated heteroaryl, carboxyalkyl, carboxyaryl, oxoalkyl, oxoaryl, halogen, nitro, cyano and mercapto-alkyl groups; and a thermographic recording process therefor.Type: GrantFiled: March 27, 2002Date of Patent: July 6, 2004Assignee: AGFA-GevaertInventors: Johan Loccufier, Geert Defieuw, Ivan Hoogmartens
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Patent number: 6759368Abstract: A thermally imageable element can be imaged using heat alone without the need for photosensitivity or post-imaging processing. The element contains image-forming chemistry that comprises i) image precursor chemistry and ii) a catalyst or a catalyst precursor that upon imagewise heating is capable of promoting thermally induced image formation with the image precursor chemistry. The image-forming chemistry i) and ii) components are in reactive association and uniformly dispersed or dissolved within a binder in one or more layers of the element. Thus, the element is capable of being thermally addressed to provide a visible image as a result of thermally induced catalytic transformation of the image-forming chemistry.Type: GrantFiled: June 30, 2003Date of Patent: July 6, 2004Assignee: Eastman Kodak CompanyInventors: Mark Lelental, Henry J. Gysling, David F. Jennings
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Patent number: 6750174Abstract: The present invention provides a heat sensitive recording material which has high sensitivity and high degree of color formation, excellent storage stability in image portions and non-image portions (i.e., background portions), high whiteness in background portions, and can stably maintain a high contrast image for a long period of time. The heat sensitive recording material has, on a support, a heat sensitive color-forming layer having an electron donating colorless dye and an electron accepting compound. At least one type of the electron accepting compound is 2,4-bis(phenylsulfonyl) phenol, and the heat sensitive color-forming layer further has 2-naphthylbenzyl ether and an amide compound as thermally fusible substances.Type: GrantFiled: December 6, 2001Date of Patent: June 15, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Tsutomu Watanabe, Hirofumi Mitsuo
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Patent number: 6720286Abstract: A heat-sensitive recording material comprising a substrate and a heat-sensitive coloring layer containing a colorless electron-donating dye, an electron-accepting compound including at least 4,4′-dihydroxydiphenylsulfone, and a sensitizer comprising 2-benzyloxynaphthalene and aliphatic monoamide in the mass ratio in a range of 30/70 to 70/30.Type: GrantFiled: September 12, 2001Date of Patent: April 13, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirofumi Mitsuo, Masayuki Iwasaki
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Patent number: 6660688Abstract: A thermosensitive recording medium including; a support; and a thermosensitive recording layer formed overlying the support and including a leuco dye, a color developer and a sensitizer, wherein the color developer includes a compound selected from the group consisting of compounds having one of the following formulae (1), (2) and (3): methylenebis(2-naphthol); and condensation products of a polyhydric alcohol component including a polyhydric alcohol having three or more hydroxyl groups with a carboxylic acid component including a 4-hydroxybenzoic acid compound having the following formula (4): wherein m is 0 or an integer of from 1 to 2, and wherein the sensitizer includes 4-acetylbiphenyl.Type: GrantFiled: May 30, 2001Date of Patent: December 9, 2003Assignee: Ricoh Company Ltd.Inventors: Hiroshi Yamada, Tomohisa Kakuda, Takeshi Kajikawa
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Patent number: 6642175Abstract: A heat-sensitive recording material formed of a support having disposed thereon a heat-sensitive color-forming layer that includes an electron-donating leuco-dye and an electron-receiving compound, with the heat-sensitive color-forming layer including, N-(4-hydroxyphenyl)-p-toluenesulfonamide as the electron-donating leuco-dye. The heat-sensitive color-forming layer may include 2-benzyloxynaphthalene or a combination of 2-benzyloxynaphthalene and methylolstearic acid amide as a sensitizer, calcite-type precipitated calcium carbonate light and/or aluminium hydroxide as an inorganic pigment, polyvinyl alcohol having a degree of saponification of 85 to 99 mol % and a degree of polymerization of from 200 to 2000 as an adhesive, and 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane and/or 1,1,3-tris(2-methyl-4-hydroxy-5-cyclohexylphenyl)butane as an image stabilizer.Type: GrantFiled: October 3, 2001Date of Patent: November 4, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirofumi Mitsuo, Tsutomu Watanabe, Masayuki Iwasaki
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Patent number: 6607871Abstract: An image recording medium comprising a light and heat change material capable of recording an image with laser beam is described, characterized in that therein are incorporated a heat generator having no absorption at a wavelength of 500 nm or more which undergoes exothermic decomposition to amplify heat generation when acted upon by heat and a compound which undergoes thermochemical reaction to show an absorption change at a wavelength of from 360 nm to 900 nm.Type: GrantFiled: September 21, 2000Date of Patent: August 19, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Tatsuhiko Obayashi, Atsuhiro Ookawa
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Patent number: 6583086Abstract: A thermally sensitive recording medium that contains a compound represented by general formula (1) as a color developer, and a compound represented by general formula (2) or general formula (3) as a sensitizer. The said thermally sensitive recording medium has sufficient color developing sensitivity with lower impressive energy, and has good image preservability of recorded part, good resistance to humid and heat resistance of background white paper part. In the formulae, R1 represents a hydrogen atom, a methyl group or a chlorine atom, R2 and R3 represents a methyl group, an alkoxy group or an allyloxy group, m and n represents an integer of 1-5, R4 represents an alkyl group, an alkoxy group of carbon number 1-6 or an electron withdrawing group and o represents an integer of 0-2.Type: GrantFiled: June 9, 2000Date of Patent: June 24, 2003Assignee: Nippon Paper Industries Co. Ltd.Inventors: Seiki Yoneshige, Tomoyuki Nakano, Reiji Ohashi
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Patent number: 6566301Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula wherein P is selected from wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen.Type: GrantFiled: December 19, 2000Date of Patent: May 20, 2003Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, John Charles DeBraal, Mark Robert Fisher, Stacey Ann Justa MacNeil, Debra Arlene Berggren
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Patent number: 6559097Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, alkoxyalkoxy, and aralkoxyalkoxy; with the proviso that when R1, R2 and R3 are hydrogen, that R4 is not benzyloxyethoxy or alkyl-substituted benzyloxyethoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen.Type: GrantFiled: September 10, 2001Date of Patent: May 6, 2003Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher, John Charles DeBraal
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Patent number: 6543808Abstract: An improved construction for pull-tab game pieces involves the use or two or more substrates, one of which is at least partially transparent. A thermosensitive imaging layer within which game results are direct thermally printed is located between the transparent substrate and an opaque cover layer through which the game results are printed. An opaque substrate precut to form one or more tabs covers the opposite side of the transparent substrate. The game results are revealed by retracting the tabs to view the game results through the transparent substrate.Type: GrantFiled: July 5, 2001Date of Patent: April 8, 2003Assignee: Translucent Technologies, LLCInventors: Chauncey T. Mitchell, Jr., Daniel R. Fulwiler
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Publication number: 20030050190Abstract: An image forming material for forming an image on an image recording material with an image binding force being established between the image and the image recording material, the image forming material containing an image forming substance, and a binding force reducing substance which reduces the image binding force when the image is heated. A method of removing an image formed on an image recording material with a binding force being established between the image and the recording material by contacting a stripping member with the image with heating under pressure. A binding force reducing substance may be contained in the surface of the stripping member or in the image recording material.Type: ApplicationFiled: July 31, 2002Publication date: March 13, 2003Inventors: Hidehiro Mochizuki, Tadashi Saitou
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Patent number: 6494950Abstract: Disclosed is a thermochromic microencapsulated pigment which comprises as four essential components (a) an electron-donating chromatic organic compound, (b) an electron-accepting compound, (c) a reaction medium determining the temperatures at which the color reactions of component (a) with component (b) take place, and (d) a color change temperature regulator, the color change temperature regulator (d) comprising one or more compounds selected from the group consisting of esters, alcohols, ketones, acid amides, hydrocarbons, and fatty acids and having a melting point Y (° C.) satisfying the relationship (X+30)° C.≦Y≦200° C., wherein X (° C.) is the melting point of component (c), and the four essential components being microencapsulated.Type: GrantFiled: September 18, 2000Date of Patent: December 17, 2002Assignee: The Pilot Ink Co., Ltd.Inventors: Katsuyuki Fujita, Kuniyuki Senga
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Publication number: 20020111271Abstract: The present invention provides a heat sensitive recording material which has high sensitivity and high degree of color formation, excellent storage stability in image portions and non-image portions (i.e., background portions), high whiteness in background portions, and can stably maintain a high contrast image for a long period of time. The heat sensitive recording material has, on a support, a heat sensitive color-forming layer having an electron donating colorless dye and an electron accepting compound. At least one type of the electron accepting compound is 2,4-bis(phenylsulfonyl) phenol, and the heat sensitive color-forming layer further has 2-naphthylbenzyl ether and an amide compound as thermally fusible substances.Type: ApplicationFiled: December 6, 2001Publication date: August 15, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Tsutomu Watanabe, Hirofumi Mitsuo
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Patent number: 6432875Abstract: A thermal recording material includes a condensation reaction product of a carboxylic acid component (A) with a polyhydric alcohol component (B) in a thermal recording layer as an essential component, wherein the carboxylic acid component (A) includes (poly) 4-hydroxybenzoic acid represented by the following general formula (I) as an essential component and another monocarboxylic acid and/or dicarboxylic acid as an arbitrary component, and wherein the polyhydric alcohol component (B) includes a polyhydric alcohol which is a trihydric or more alcohol as an essential component and a dihydric low molecular-weight alcohol as an arbitrary component. wherein in the general formula(I), a letter p denotes an integer ranging from 0 to 2.Type: GrantFiled: December 1, 1999Date of Patent: August 13, 2002Assignee: Asahi Denka Kogyo K.K.Inventors: Mitsuo Akutsu, Nobuhide Tominaga, Keiji Ohya, Koichi Shigeno, Takahiro Mori
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Patent number: 6416923Abstract: A thermal transfer material includes a support. A release layer is overlaid on the support. A coloring transfer layer is overlaid on the release layer, has thermoplasticity, and is colorable by being exposed and then pressurized. In a printer for use with the thermal transfer material, an image is formed by exposing the coloring transfer layer. The coloring transfer layer is placed on image receiving material after the image is formed. The thermal transfer material is heated and pressurized while the coloring transfer layer is placed on, so as to color the image and transfer the coloring transfer layer to the image receiving material.Type: GrantFiled: October 5, 2001Date of Patent: July 9, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Takao Miyazaki
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Patent number: 6335140Abstract: A thermal transfer material includes a support. A release layer is overlaid on the support. A coloring transfer layer is overlaid on the release layer, has thermoplasticity, and is colorable by being exposed and then pressurized. In a printer for use with the thermal transfer material, an image is formed by exposing the coloring transfer layer. The coloring transfer layer is placed on image receiving material after the image is formed. The thermal transfer material is heated and pressurized while the coloring transfer layer is placed on, so as to color the image and transfer the coloring transfer layer to the image receiving material.Type: GrantFiled: June 7, 2000Date of Patent: January 1, 2002Assignee: Fuji Photo Film Co., Ltd.Inventor: Takao Miyazaki
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Patent number: 6331374Abstract: The present invention relates to an imaging system, which comprises a support having a front and rear surface, at least one layer of microcapsules or at least one layer of microcapsules and developer in the same layer or at least one layer of microcapsules and developer in separate layers, on said front surface of the support, wherein the microcapsules or developer or microcapsules and developer are dispersed in a carrier of the invention, said carrier is capable of transferring and adhering developed image and non-image areas from said front surface of said support upon the application of heat energy to the rear surface of the support, said carrier strips from said front surface of the support by liquefying and releasing from said support when heated, said liquefied carrier providing adherence to a receptor element by flowing onto said receptor element and solidifying thereon, said adherence does not require an external adhesive layer, with the proviso that the carrier is not capable of reacting to form an iType: GrantFiled: March 31, 2000Date of Patent: December 18, 2001Assignee: Foto-Wear, Inc.Inventors: Donald S. Hare, Scott A. Williams
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Patent number: 6294502Abstract: The invention discloses a novel thermally-responsive record material comprising a support having coated thereon a thermally sensitive color forming composition comprising a chromogenic material, an acidic developer material and a certain carbamate component that does not include dodecyl-N-phenylcarbamate. The novel record material displays enhanced image intensity or improved thermal response.Type: GrantFiled: May 14, 1999Date of Patent: September 25, 2001Assignee: Bayer AktiengesellschaftInventors: Mark Robert Fisher, John Charles DeBraal, Guido Steffan, Peter P. Wenzl
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Patent number: 6265128Abstract: The present invention relates to an imaging system, which comprises a support having a front and rear surface, at least one layer of microcapsules or at least one layer of microcapsules and developer in the same layer or at least one layer of microcapsules and developer in separate layers, on said front surface of the support, wherein the microcapsules or developer or microcapsules and developer are dispersed in a carrier of the invention, said carrier is capable of transferring and adhering developed image and non-image areas from said front surface of said support upon the application of heat energy to the rear surface of the support, said carrier strips from said front surface of the support by liquefying and releasing from said support when heated, said liquefied carrier providing adherence to a receptor element by flowing onto said receptor element and solidifying thereon, said adherence does not require an external adhesive layer, with the proviso that the carrier is not capable of reacting to form an iType: GrantFiled: November 14, 1997Date of Patent: July 24, 2001Assignee: Foto-Wear, Inc.Inventors: Donald S. Hare, Scott A. Williams
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Patent number: 6261992Abstract: A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording layer further includes an erasure promoter including one or more secondary amide group having the following formulas (1), (2) or (3): wherein each of R1, R2, R3, R4 and R5 independently represents a hydrocarbon group which is optionally substituted and which may be saturated or unsaturated, and wherein R1 and R2 are optionally combined to form a ring which may include one or more of a nitrogen atom, an oxygen atom and a sulfur atom. Alternatively, the erasure promoter may include two or more secondary amide groups having formula (1), (2) or (3).Type: GrantFiled: September 24, 1999Date of Patent: July 17, 2001Assignee: Ricoh Company, Ltd.Inventors: Hiromi Furuya, Masaru Shimada, Tadafumi Tatewaki, Masafumi Torii, Fumio Kawamura, Hiroaki Matsui
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Patent number: 6174836Abstract: A reversible thermosensitive recording medium includes a reversible thermosensitive recording layer including a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, of which transparency is reversibly changeable depending upon the temperature thereof, and having (1) a transparentizing upper-limit temperature of 125° C. or more, (2) a temperature difference of 20° C. or less between said transparentizing upper-limit temperature and an opaqueness initiation lower-limit temperature, and (3) a transparentizing initiation temperature of less than 95° C., and a method of recording and erasing images, using the recording medium, a method of producing the recording medium, and the application thereof a card, a label, writable or rewritable disk cartridge, disk and tape cassette are proposed.Type: GrantFiled: July 17, 1998Date of Patent: January 16, 2001Assignees: Ricoh Company Ltd., Miyoshi Yushi Kabushiki KaishaInventors: Yoshihiko Hotta, Kunichika Moroboshi, Masafumi Torii, Kunitoshi Sugiyama, Hideyuki Kobori, Katsushi Sugiyama, Katsuaki Kokubo, Koji Kawai, Kazuo Hosoda, Masafumi Moriya
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Patent number: 6096683Abstract: A reversible thermosensitive recording medium having a supporting substrate and a reversible thermosensitive recording layer formed on the supporting substrate, being capable of reversibly varying color density depending upon temperature with improved durability, is provided. The recording medium has the rates of changes in recording sensitivity and in erasure sensitivity, which are caused by the immersion in an artificial perspiration liquid, of 50% or less and 80% or more, respectively, and an average maximum particle size of organic materials of 2.5 microns at most.Type: GrantFiled: October 24, 1997Date of Patent: August 1, 2000Assignee: Ricoh Company, Ltd.Inventors: Tetsuya Amano, Kazumi Suzuki, Atsushi Kutami, Yoshihiko Hotta, Kunichika Moroboshi
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Patent number: 6028030Abstract: A thermal sensitive recording medium which further contains poly urea compound in the thermal color developing layer containing dye precursor and color developer, which displays an excellent image preservative stability. Said poly urea compound contains units of a structure represented by general formula (1), and further contains a repeating unit represented by general formulae (2).about.(7). ##STR1## In these formulae A.sup.1 .about.A.sup.7 are a divalent group, R.sup.1 .about.R.sup.5 are an alkyl group, an alkoxy group or an electron accepting group, o, p, and q are an integer from 0 to 4, r is an integer from 2 to 12 and s and t are an integer from 0 to 8.Type: GrantFiled: March 4, 1998Date of Patent: February 22, 2000Assignee: Nippon Paper Industrie Co., Ltd.Inventors: Tomoyuki Nakano, Koichi Yanai, Junko Seki, Reiji Ohashi, Hidetoshi Yoshioka
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Patent number: 6015771Abstract: The present invention discloses a novel thermally-responsive record material having coated thereon a thermally sensitive color forming composition comprising a chromogenic material, an acidic developer material and a carbamate of the formula ##STR1## wherein R is selected from alkyl, aryl or aralkyl. The alkyl moiety in each of the preceding is selected to be of from one to eight carbons. The novel record material displays enhanced image intensity or improved thermal response.Type: GrantFiled: May 22, 1998Date of Patent: January 18, 2000Assignee: Bayer AktiengesellschaftInventors: Mark Robert Fisher, John Charles DeBraal, Guido Steffan, Peter P. Wenzl