Having Constituent Defined In Terms Of Melting Temperature Patents (Class 503/208)
-
Patent number: 5246905Abstract: A thermosensitive recording material which contains an aromatic isocyanate compound, an imino compound having at least one >C.dbd.Type: GrantFiled: December 24, 1991Date of Patent: September 21, 1993Assignee: Mitsubishi Paper Mills LimitedInventors: Mikiya Sekine, Hidetaka Tsukada
-
Patent number: 5219820Abstract: A reversible thermosensitive recording material is composed of a support, and a reversible thermosensitive recording layer formed thereon, having a reversible temperature-dependent transparency, which contains a matrix resin and an organic low-molecular-weight material. The organic low-molecular-weight material is in the form of particles, and substantially covered by the matrix resin, and the content thereof in the reversible thermosensitive recording layer is increased from the surface side thereof toward the support side. This reversible thermosensitive recording material can be prepared by a method of coating a solution or dispersion of the matrix resin and the organic low-molecular-weight material on the support, which are dissolved or dispersed in a mixed solvent composed of at least two solvents, each having a different vapor pressure, and drying the solution or dispersion.Type: GrantFiled: November 21, 1991Date of Patent: June 15, 1993Assignee: Ricoh Company, Ltd.Inventors: Kunichika Morohoshi, Yoshihiko Hotta, Yukio Konagaya, Makoto Kawaguchi, Toru Nogiwa, Akira Suzuki
-
Patent number: 5208208Abstract: There is disclosed a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on said support; said heat-sensitive recording layer containing an aromatic isocyanate compound and an imino compound as color developing agent and a silane-modified acrylic resin constituting at least a part of binder.Type: GrantFiled: July 22, 1991Date of Patent: May 4, 1993Assignee: Mitsubishi Paper Mills LimitedInventors: Makoto Motoda, Hideaki Senoo
-
Patent number: 5179066Abstract: This invention relates to a thermosensitive recording material containing at least one of durene derivative represented by the formula (I): ##STR1## wherein Z represents CH.sub.2 OX or H, X represents an alkyl group, a cycloalkyl group, a substituted or unsubstituted aralkyl group or aryl group, or --COR group where R represents an alkyl group or a substituted or unsubstituted aryl group,in a recording layer which contains a leuco dye and a color-developing agent which reacts with said dye so as to form a color by heating, and the thermosensitive recording material having high color sensitivity can be obtained.Type: GrantFiled: April 8, 1992Date of Patent: January 12, 1993Assignees: Yamada Chemical Co., Ltd., Nagase Chemicals Ltd.Inventors: Manabu Yamada, Toshiro Narizuka, Katsuhiko Tsunemitsu, Hajime Kawai, Takayuki Kurosaki
-
Patent number: 5179068Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer provided on the support, the heat-sensitive recording layer comprises a dye precursor, a developer, a binder and an aromatic compound represented by the following structural formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently hydrogen atoms or lower alkyl groups; R.sup.4, R.sup.5 and R.sup.6 are independently hydrogen atoms, alkyl groups, cycloalkyl groups, alkoxy groups, halogen atoms, aralkyl groups, aryl groups, acyl groups, formyl groups, nitro groups or cyano groups; and X.sup.1 and X.sup.2 are oxygen atoms or sulfur atoms. This heat-sensitive recording material is excellent in heat responsiveness and sensitivity, and cause little thermal head stain.Type: GrantFiled: November 5, 1991Date of Patent: January 12, 1993Assignee: Mitsubishi Paper Mills LimitedInventor: Atsuo Goto
-
Patent number: 5179067Abstract: The present invention relates to a color forming solution including the benzoin derivatives as a sensitizer.Type: GrantFiled: May 23, 1991Date of Patent: January 12, 1993Assignee: Chonju Paper Mfg. Co., Ltd.Inventors: Suk K. Chang, Dong J. Yang, Kyu C. Paik, Don W. Kim, Jae S. Ryu
-
Patent number: 5175138Abstract: A heat-sensitive recording material which comprises a color-forming layer containing a coupling substance which is usually colorless or light-colored and a developer which gives rise to color in the coupling substance upon heating, wherein the color-forming layer contains an organic phosphate, its metal salt or its basic salt of the following general formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R.sub.2 and R.sub.3 each represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms, M represents a hydrogen atom or a metal atom having a valence of 1 to 4, L represents 0 or 1, m, represents a number of 0 to 1, n represents 1 or 2, and m+n represents the valence of the metal M.Type: GrantFiled: June 17, 1991Date of Patent: December 29, 1992Assignee: Asahi Denka Kogyo Kabushiki KaishaInventors: Mitsuo Akutsu, Keiji Tabata
-
Patent number: 5173477Abstract: Novel heat-sensitive recording media include a support substrate, e.g., paper or a synthetic polymer film, having a thermosensitive recording layer deposited thereon, such thermosensitive recording layer comprising a colorant precursor, a heat-sensitive developer therefor and at least one polyphenylmethane of the formula (A1): ##STR1## in which R.sub.1 and R.sub.2, which may be identical or different, are each a halogen atom, NO.sub.2, CN, OCH.sub.3, H or an alkyl radical having up to 5 carbon atoms; n is 3, 4 or 5; p is 1, 2 or 3; g is 0 or 1 and the maximum value of p+g is 2; and the melting point of which polyphenylmethane being at least 50.degree. C.Type: GrantFiled: December 19, 1991Date of Patent: December 22, 1992Assignee: Societe AtochemInventors: Raymond Commandeur, Jean-Pierre Sarron
-
Patent number: 5164356Abstract: Thermally-responsive record materials are described containing a "complex" material formed from interactions at high pH between zinc stearate and ammonia and/or zinc stearate, ammonia and zinc oxide. The use of these materials in thermally-responsive sheets improves thermal image response and/or improves resistance to thermal image decline upon exposure to elevated temperature.Type: GrantFiled: November 12, 1991Date of Patent: November 17, 1992Assignee: Appleton Papers Inc.Inventor: Dean G. Dalebroux
-
Patent number: 5158926Abstract: A reversible thermosensitive recording material is composed of a support and a reversible thermosensitive recording layer formed on the support. The reversible thermosensitive recording layer includes a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and has a temperature-dependent transparency. The matrix resin includes a resin component having a glass transition temperature of 90.degree. C. or more.Type: GrantFiled: August 30, 1991Date of Patent: October 27, 1992Assignee: Ricoh Company, Ltd.Inventors: Yoshihiko Hotta, Makoto Kawaguchi, Kunichika Morohoshi, Yukio Konagaya, Toru Nogiwa, Akira Suzuki, Fumihito Masubuchi
-
Patent number: 5158925Abstract: A thermosensitive recording material comprising a substrate and a thermosensitive coloring layer, formed thereon, which comprises a leuco dye; at least one color developer selected from the group consisting of 1,5-bis(4-hydroxyphenylthio)-3-oxapentane and 1,7-bis(4-hydroxyphenylthio)-3,5-dioxapentane; and an isocyanuric acid derivative of the formula (I): ##STR1## wherein R.sup.1, R.sup.3, R.sup.4 and R.sup.5 independently represent hydrogen or an alkyl group having 1 to 4 carbon atoms, provided that at least either R.sup.1 or R.sup.3 represents an alkyl group having 1 to 4 carbon atoms; and R.sup.2 represents --C.sub.n H.sub.2n OH in which n is an integer of 0 to 4.Type: GrantFiled: October 9, 1990Date of Patent: October 27, 1992Assignee: Ricoh Company, Ltd.Inventor: Tomohisa Kakuda
-
Patent number: 5157012Abstract: Pressure-sensitive and heat-sensitive record materials are described comprising a substrate, an acidic developer and chromogenic di-[bis-(indolyl) ethylenyl]tetrahalophthalides of the formula ##STR1## wherein each X.sup.1, S.sup.2, X.sup.3, and X.sup.4 is independently selected from chlorine or bromine;wherein each of R.sup.1 and R.sup.7 is independently selected from cycloalkyl, aralkyl, alkoxyalkyl, or aroxyalkyl;wherein each of R.sup.2 and R.sup.8 is independently selected from alkyl (C.sub.1 -C.sub.8) or aryl (substituted or unsubstituted);wherein each of R.sup.3, R.sup.4, R.sup.5, R.sup.6,R.sup.9, R.sup.10, R.sup.11, and R.sup.12 is independently selected from hydrogen alkyl (C.sub.1 -C.sub.8), cycloalkyl, aryl (substituted or unsubstituted), halogen, alkoxy (C.sub.1 -C.sub.8), aroxy, cycloalkoxy, dialkylamino including symmetrical and unsymmetrical alkyl (C.sub.1 -C.sub.Type: GrantFiled: July 24, 1990Date of Patent: October 20, 1992Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, Dean G. Dalebroux, Kenneth D. Glanz
-
Patent number: 5143890Abstract: The present invention provides a heat sensitive recording material, including a substrate and a heat sensitive recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material also including 1-(4-methoxyphenoxy)-2-(2-methylphenoxy)ethane in the heat sensitive recording layer.Type: GrantFiled: November 21, 1990Date of Patent: September 1, 1992Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho CorporationInventors: Tetsuo Tsuchida, Yukihiro Abe, Tomoyuki Okimoto, Toranosuke Saito
-
Patent number: 5135776Abstract: A heat-sensitive recording material is obtained by coating an aqueous dispersion which is prepared by mixing an aqueous dispersion of an electron donating colorless dye with an aqueous dispersion of an electron accepting compound on a base sheet. The aqueous dispersion of an electron donating dye is prepared by a method which comprises the steps of uniformly dispersing at least one electron donating colorless dye and at least one heat-fusible substance selected from the group consisting of 2-benzyloxynaphthalene, parabenzyl biphenyl, 1,4-bis(2-vinyloxyethoxy)benzene, bis [2-(4-methoxyphenoxy)ethyl] ether, 1,2-bis (3-methylphenoxy)ethane, 1,2-diphenoxyethane, benzyl 4-methylthiophenyl ether, 1-(2-methylphenoxy)-2-(4-methoxyphenoxy)ethane and oxalic acid dibenzyl ester with a dispersing binder and/or a surface active agent in water; and pulverizing thus obtained dispersion with use of a horizontal sand mill.Type: GrantFiled: June 27, 1990Date of Patent: August 4, 1992Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventors: Shuki Okauchi, Kazuo Kojima
-
Patent number: 5128309Abstract: A recording material containing an electron donating colorless dye capable of undergoing a coloration reaction, wherein a metal salt of a salicylic acid derivative represented by the following formula (I) and a fatty acid derivative having a benzotriazole group as a substituent group or an alcohol derivative having a benzotriazole group as a substituent group are provided on a same support: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent each hydrogen atom, an alkyl group or an aryl group.Type: GrantFiled: July 25, 1990Date of Patent: July 7, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Iwakura, Koreshige Ito, Shojiro Sano
-
Patent number: 5116803Abstract: The present invention provides the following 3 types of reversible thermosensitive recording materials:1. A reversible thermosensitive recording material having a thermosensitive layer whose transparency reversibly changes depending on its temperature, said layer comprising a resin matrix and an organic low molecular substance dispersed in said resin matrix;2. A reversible thermosensitive recording material having a thermosensitive layer that is consisted essentially of a resin matrix and an organic low molecular substance dispersed in this resin matrix and is arranged to change its transparency reversibly depending upon temperatures, wherein said thermosensitive layer further contains at least one additive; and3.Type: GrantFiled: October 10, 1990Date of Patent: May 26, 1992Assignee: Ricoh Company, Ltd.Inventors: Yoshihiko Hotta, Keishi Kubo
-
Patent number: 5116802Abstract: The invention provides a heat-sensitive recording material comprising (a) a base sheet and (b) a heat-sensitive recording layer formed on the base sheet and comprising a colorless or pale-colored basic dye, a color developing material which develops a color on contact with the dye, and a heat-fusible material, the recording material being characterized in that the basic dye comprises 3-di(n-butyl)amino-6-methyl-7-phenylaminofluoran, and that the heat-fusible material comprises di(p-methylbenzyl) oxalate.Type: GrantFiled: January 23, 1991Date of Patent: May 26, 1992Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventors: Naoto Arai, Kazuo Watanabe
-
Patent number: 5116804Abstract: A thermosensitive recording material with a highly improved dynamic coloring sensitivity, comprising a support, and a coloring layer formed thereon, which comprises (a) a leuco dye, (b) at least one of 1,7-bis(4-hydroxphenylthio)-3,5-dioxahepetane and 1,5-bis(4-hydroxyphenylthio)-3-oxapentane as a color developer, and (c) a dibenzyl oxalate derivative having formula (I) as a sensitizer: ##STR1## wherein R.sup.1 and R.sup.2 each independently represent hydrogen, an alkyl group having 1 to 4 carbon atoms, a halogen or a hydroxyl group.Type: GrantFiled: May 30, 1990Date of Patent: May 26, 1992Assignee: Ricoh Company, Ltd.Inventors: Tomohisa Kakuda, Norio Kurisu
-
Patent number: 5112798Abstract: The present invention relates to a heat-sensitive recording sheet which comprises a support, an undercoat layer provided on said support and a heat-sensitive color forming layer provided on said undercoat layer, said heat-sensitive color fomring layer containing a colorless or palely colored dye precursor, a developer which reacts with said dye precursor upon application of heat to cause said dye precursor to form color, N-methylolbehenic acid amide, and at least one sensitivity enhancing agent. This heat-sensitive recording sheet is excellent in heat responsiveness, high in sensitivity and superior in mechanical matching properties.Type: GrantFiled: August 24, 1990Date of Patent: May 12, 1992Assignee: Mitsubishi Paper Mills LimitedInventor: Masahiro Miyauchi
-
Patent number: 5110786Abstract: A heat-sensitive recording material comprises a recording layer formed on a base sheet where the recording layer comprises a colorless or pale colored basic chromogenic material, a color developing material which develops a color by contacting with said chromogenic material, and a stabilizer.Type: GrantFiled: April 12, 1990Date of Patent: May 5, 1992Assignee: Kanzaki Paper Manufacturing Co., Ltd.Inventors: Naoto Arai, Nobuo Kanda, Masaharu Nojima
-
Patent number: 5106814Abstract: The present invention provides a heat-sensitive recording material excellent in image stability and heat-responsiveness which contains an aromatic isocyanate compound, an imino compound and at least one compound represented by the following formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group.Type: GrantFiled: December 28, 1990Date of Patent: April 21, 1992Assignee: Mitsubishi Paper Mills LimitedInventors: Shigetoshi Hiraishi, Akinori Okada, Mikiya Sekine
-
Patent number: 5102857Abstract: A heat-sensitive recording material which comprises a support and a heat-sensitive recording layer provided on the support, the heat-sensitive recording layer comprising a colorless or pale-colored dye precursor, a developer which reacts with the dye precursor to form color upon heating, and two compounds represented by the following formulas (I) and (II): ##STR1## The heat-sensitive recording material causes little fogging and generates little thermal head scum while having almost the same sensitivity and image stability as conventional heat-sensitive recording materials.Type: GrantFiled: January 4, 1991Date of Patent: April 7, 1992Assignee: Mitsubishi Paper Mills LimitedInventor: Akinori Okada
-
Patent number: 5098882Abstract: A heat-sensitive recording medium comprising, on a support, a heat-sensitive color-developing layer containing a colorless or light-colored leuco dye (or an electron-donating dye precursor) and a color-developing agent (or an electron-accepting substance) reacting with the leuco dye to develop color as main constituents, said leuco dye being a compound represented by the formula (I): ##STR1## wherein X represents CH.sub.3 --(CH.sub.2).sub.3 --CH.sub.2 or CH.sub.3 --CH.sub.2 --CH.sub.2 and Y represents CH.sub.3 --(CH.sub.2).sub.3 --Ch.sub.2 or CH.sub.3, and said heat-sensitive color-developing layer containing at least one of the compounds represented by the general formula (II) and (III): ##STR2## where R.sub.1, R.sub.1 ' are respectively any one of H, Cl, and CH.sub.3, and may be the same with or different from each other: ##STR3## where R.sub.2, R.sub.2 ' are respectively any one of H and CH.sub.3, and may be the same with or different from each other.Type: GrantFiled: August 20, 1990Date of Patent: March 24, 1992Assignee: Daio Paper CorporationInventors: Hiroshige Teraji, Yasunori Shimada, Motokazu Aono, Hisashi Yamamoto
-
Patent number: 5087601Abstract: A reversible thermosensitive recording material is disclosed, which comprises (i) a reversible thermosensitive recording layer which comprises as the main components a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and (ii) a light reflection layer made of a metal thin film, which is preferably surface-treated to have a specular gloss of 70 to 250% in accordance with JIS Z8741 or a surface roughness of 0.5 to 10 .mu.m in terms of the ten-point average roughness defined in JIS B0601. This reversible thermosensitive recording material may further comprises a crystal-growth controlling agent in the reversible thermosensitive recording layer.Type: GrantFiled: October 4, 1989Date of Patent: February 11, 1992Assignee: Ricoh Company, Ltd.Inventors: Yoshihiko Hotta, Keishi Kubo, Makoto Kawaguchi, Toru Nogiwa
-
Patent number: 5081098Abstract: A heat-sensitive recording material that utilizes the color forming reaction between at least one basic dye and a developer that is capable of forming a color upon contact with said basic dye is characterized in that the heat-sensitive recording layer of said material contains both dihydroxydiphenyl ether represented by the formula (I): ##STR1## and a compound represented by the general formula (II): ##STR2## (where R is H or C.sub.n H.sub.2n+1, with n being an integer of 1-5). This heat-sensitive recording material has a sufficiently high sensitivity for color formation to kake it suitable for use in a broad range of practical applications and it also exhibits enhanced keeping quality and whiteness.Type: GrantFiled: May 17, 1990Date of Patent: January 14, 1992Assignee: Oji Paper Co., Ltd.Inventor: Satoshi Fukui
-
Patent number: 5081099Abstract: A heat-sensitive recording material wherein a color-forming layer comprising a coupling substance which is usually colorless or light-colored and a developer which gives rise to color in the coupling substance upon heating further contains, as a sensitizer, a tetrahydronaphthalene compound of the following general formula (I): ##STR1## wherein X represents an alkylene group, --O--CO--O--, --O--CO-- or --O--R'.sub.n Y--, n represents 1 or 2, Y represents --O-- or --S--, R' represents an alkylene group, and R represents a phenyl, alkylphenyl or tetrahydronaphthyl group.Type: GrantFiled: July 19, 1990Date of Patent: January 14, 1992Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Mitsuo Akutsu, Syuji Iwakura, Keiji Oya
-
Patent number: 5071821Abstract: Thermally sensitive record material (thermal paper) using 2,2-bis(4-hydroxyphenyl)-4-methylpentane as co-reactant with conventional electron donating chromogenic compounds and a combination of a long chain fatty acid amide was melting between 80.degree. and 140.degree. C. and a sensitizer melting between 60.degree. and 120.degree. C. and selected from diaryl ethers, acetoacetic anilides, phenyl hydroxynaphthoates, aryl or aralkyl substituted biphenyls and diaryl carbonates have high thermal sensitivity and good background whiteness.Type: GrantFiled: January 19, 1990Date of Patent: December 10, 1991Assignee: The Wiggins Teape Group LimitedInventors: Vivienne J. Smith, Debra J. Clark, Keith B. Damarell
-
Patent number: 5063197Abstract: A heat-sensitive recording material comprising a support and a heat-sensitive recording layer provided on the support, said heat-sensitive recording layer comprising an electron-donating, colorless or pale-colored dye precursor, an electron-accepting developer which reacts with the dye precursor to form images upon heating, a binder, and a specific aromatic compound. The heat-sensitive recording material has an excellent heat responsiveness, and hence recorded images having a sufficient optical density can be printed even with low energy.Type: GrantFiled: September 4, 1990Date of Patent: November 5, 1991Assignee: Mitsubishi Paper Mills LimitedInventors: Atsuo Goto, Fumio Okumura, Kazuhiko Ito
-
Patent number: 5043312Abstract: A heat-sensitive recording material comprising a support and a heat-sensitive recording layer provided on the support, said heat-sensitive recording layer comprising an aromatic or heterocyclic isocyanate compound, an imino compound, a binder, a specific alcoholic compound, and preferably, a specific biphenyl derivative. The heat-sensitive recording material have an excellent image preservability and heat responsiveness.Type: GrantFiled: November 2, 1990Date of Patent: August 27, 1991Assignee: Mitsubishi Paper Mills LimitedInventors: Shigetoshi Hiraishi, Akinori Okada, Mikiya Sekine
-
Patent number: 5036039Abstract: Disclosed is a heat-sensitive recording material comprising an aromatic isocyanate compound, an imino compound which reacts with said aromatic isocyanate compound upon application of heat to form color, and a support, wherein a coating color comprising a dispersion obtained by pulverizing a mixture of said aromatic isocyanate compound and an alcoholic compound has been coated on the support. This heat-sensitive recording material is excellent in image stability and sensitivity.Type: GrantFiled: August 10, 1990Date of Patent: July 30, 1991Assignee: Mitsubishi Paper Mills LimitedInventors: Mikiya Sekine, Shigetoshi Hiraishi
-
Patent number: 5034301Abstract: A transfer recording medium comprises a support and a recording layer formed thereon comprising at least a colorant and a functional component sensitive to provision of light energy and heat energy. The recording layer is composed to have a specifically high sensitivity selective to provision of both light energy and heat energy defined as follows. The adhesion force f.sub.1 between the support and the recording layer and the adhesion force f.sub.2 between the recording layer and a transfer-receiving medium such as plain paper satisfy the relations of f.sub.1 >f.sub.2 at a lower temperature and f.sub.1 <f.sub.2 at a higher heated temperature. A minimum exposure quantity is defined as a minimum quantity of light, with a wavelength to which the functional component in the recording layer is sensitive at 100.degree. C., providing f.sub.1 >f.sub.2 at the higher heated temperature when the recording layer is exposed to the light and then heated. Then, the recording layer provides f.sub.1 <f.sub.Type: GrantFiled: July 21, 1989Date of Patent: July 23, 1991Assignee: Canon Kabushiki KaishaInventors: Masashi Miyagawa, Masanori Takenouchi, Norio Ohkuma
-
Patent number: 5032567Abstract: A hydantoin compound of the formula: ##STR1## (wherein R stands for an alkyl group of 8 to 20 carbon atoms) increases the sensitivity of a color developing reaction of a heat-sensitive recording material and enhances the high-speed recording property of the recording material without sacrifice of the whiteness thereof. The heat-sensitive recording material containing the hydantoin compound is novel to the art.Type: GrantFiled: January 19, 1990Date of Patent: July 16, 1991Assignee: Showa Denko K.K.Inventors: Akihiro Ohtsubo, Kouhei Morikawa, Yohko Kataoka, Sumio Soya
-
Patent number: 5019548Abstract: A heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material being characterized in that, as the color acceptor is used at least one compound selected from the group consisting of 4-hydroxy-4'-isopropyloxydiphenylsulfone, 4,4'-(1,3-dimethylbutylidene) bisphenol, 4,4'-(1-phenylethylidene)bisphenol, 4,4'-(p-phenylenediisopropylidene)bisphenol and 4,4'-(m-phenylenediisopropylidene) bisphenol, and to the recording layer is added at least one of a heat-fusible substance represented by the formula [I] ##STR1## wherein X is hydrogen atom, halogen atom, C.sub.1.about.4 alkyl or C.sub.1.about.4 alkoxy.Type: GrantFiled: August 24, 1989Date of Patent: May 28, 1991Assignees: Kanzaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kenkyusho CorporationInventors: Toshitake Suzuki, Fumio Seyama, Shuki Okauchi, Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi
-
Patent number: 5017545Abstract: A heat sensitive recording material comprising a substrate and a heat sensitive recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor reactive with the dye to form a color when contacted therewith, the recording material being characterized in that the material has a heat sensitive recording layer having incorporated therein (1) a heat-fusible substance exhibiting a weight reduction of at least 5% at 200.degree. C. based on the weight at 25.degree. C. under the condition of 20.degree. C./min in the rate of rise of temperature, (2) a wax, (3) a lubricant, and (4) an oil-absorbing pigment at least 85 ml/100 g in oil absorption.Type: GrantFiled: June 1, 1989Date of Patent: May 21, 1991Assignee: Kanzaki Paper Manufacturing Company, LimitedInventors: Nobuo Kanda, Ritsuo Mandoh, Masaharu Nojima, Naoto Arai
-
Patent number: 5008236Abstract: A heat-sensitive recording material with an excellent recording sensitivity and capable of recording thereon high quality images at a high recording speed, comprising a heat-sensitive color-forming layer formed on a substrate sheet and comprising a colorless dye precursor, a color-developing agent, a binder and a sensitizing agent consisting essentially of 1,2-diphenoxybenzene.Type: GrantFiled: December 28, 1989Date of Patent: April 16, 1991Assignee: Oji Paper Co., Ltd.Inventors: Yoshiyuki Takahashi, Kunitaka Toyofuku, Akiko Iwasaki
-
Patent number: 5001104Abstract: A heat-sensitive recording material in which a heat-sensitive recording layer containing a colorless to light-colored basic Leuco dyestuff and a color developer is tightly contacted with a thermal head to effect color development, characterized in that ammonium zirconyl carbonate is contained in said heat-sensitive color-developing layer or in an undercoating layer so as to offer a heat-sensitive recording material which is superior in its high speed printing properties and free from printing hindrances caused by smudge deposition or sticking.Type: GrantFiled: August 14, 1989Date of Patent: March 19, 1991Assignee: Oji Paper Co., Ltd.Inventors: Yasuyoshi Morita, Masaaki Matsuoka, Satoshi Fukui, Kyoko Koyabu, Tatsuya Murata
-
Patent number: 4999332Abstract: A heat-sensitive recording material comprising a dye precursor which is colorless or light-colored in the usual state and a color developing agent capable of reacting with said dye precursor upon heating to develop a color which is a combination of compounds of the following chemical formulas (I) and (II).Type: GrantFiled: September 8, 1988Date of Patent: March 12, 1991Assignee: Mitsubishi Paper Mills, LimitedInventors: Fumio Okumura, Akinori Okada, Kazuyoshi Kondo
-
Patent number: 4996183Abstract: A thermosensitive recording material having a thermosensitive color forming layer containing a specific dispersing agent and binder mixture showing a softening point of at least 70.degree. C. can minimize occurrence of head stain at a thermal head in thermosensitive recording. The combination of sulfonic acid-containing polyvinyl alcohol and polyacrylamide or acrylamide-acrylonitrile copolymer is preferable.Type: GrantFiled: March 28, 1989Date of Patent: February 26, 1991Assignee: Mitsubishi Paper Mills, LimitedInventors: Masaaki Otani, Shigetoshi Hiraishi, Kenji Hyodo
-
Patent number: 4994431Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive color forming layer containing a colorless or slightly colored electron donating dye precursor and an electron accepting compound capable of forming color by the reaction with the electron donating dye precursor, wherein the heat-sensitive color forming layer contains a 1-alkoxyphenoxy-2-aryloxypropane. The recording material exhibits high sensitivity and satisfactory preservation stability.Type: GrantFiled: September 1, 1989Date of Patent: February 19, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Iwakura, Naoto Yanagihara, Masato Satomura, Takayuki Hayashi
-
Patent number: 4988662Abstract: A thermosensitive recording sheet comprising a substrate sheet and coated on the substrate, a film comprising a color-forming lactone compound, an acidic substance and a sensitizer, said sensitizer being a substituted or unsubstituted phenacyl ether compound or a substituted or unsubstituted phenacyl sulfide compound.Type: GrantFiled: April 27, 1989Date of Patent: January 29, 1991Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Kikuo Tsuchiya, Masaji Inagaki, Shingo Araki
-
Patent number: 4985390Abstract: A thermosensitive recording medium comprises a substrate and a thermosensitive, coloring layer, provided on the substrate, comprising a binder, a colorless or light-colored electron-donating dye, an electron-accepting compound to react with the electron-donating dye and form a coloring matter and then an ester compound obtained from a fatty acid having 20 to 28 carbon atoms and a straight or cyclic alcohol, the ester having a melting point of 50 to 100 degree C. and one or more non-phenolic hydroxy group. It is improved in prevention from fogging and sensitivity.Type: GrantFiled: April 11, 1989Date of Patent: January 15, 1991Assignee: Kao CorporationInventors: Norihiko Nakashima, Yoshiji Kanoh, Atsushi Suzuki, Sadashi Ueda
-
Patent number: 4985391Abstract: A heat-sensitive recording material is disclosed. The material comprises a support having provided thereon a heat-sensitive color forming layer containing an electron donating dye precursor and an electron accepting compound, said heat-sensitive color forming layer containing at least one compound selected from an aromatic polyether and an aromatic polyester, and an aromatic ether.Type: GrantFiled: June 6, 1989Date of Patent: January 15, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Kenji Ikeda, Ken Iwakura, Masanobu Takashima
-
Patent number: 4983568Abstract: There is disclosed a thermosensitive recording material comprising an ordinarily colorless or slightly colored dye precursor, an electron receptive compound (developer) coloring said dye precursor by reacting when heated, and a compound of following general formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each represents hydrogen atom, alkyl, alkenyl or aryl group, and R.sub.1 and R.sub.2 may be different from each other; may also be linked together to form cycloalkyl, cycloether, and the like; and R.sub.3 and R.sub.4 each represents hydrogen atom, alkyl, alkenyl, alkoxy or aryl group and halogen atom, and R.sub.3 and R.sub.4 may be different from each other.Type: GrantFiled: September 28, 1989Date of Patent: January 8, 1991Assignee: Mitsubishi Paper Mills LimitedInventor: Mitsuhiro Ikeda
-
Patent number: 4981835Abstract: A recording material comprising an electron donating colorless dye and an electron accepting compound is disclosed, the recording material further comprising, as a heat-fusible substance, a benzyl ether derivative represented by formula (I): ##STR1## wherein R represents a halogen atom or a substituted or unsubstituted alkoxy group; and when R is a substituted or unsubstituted alkoxy group, X, Y and Z, which may be same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkoxy group or a halogen atom; and when R is a halogen atom, X represents a substituted or unsubstituted alkoxy group, and Y and Z each represents a hydrogen atom.The recording material exhibits improved color developability and color forming sensitivity.Type: GrantFiled: July 27, 1989Date of Patent: January 1, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Ken Iwakura, Naoto Yanagihara, Takayuki Hayashi
-
Patent number: 4980336Abstract: A heat-sensitive recording material wherein 1,2-bis(3,4-dimethylphenyl)ethane is contained as a sensitizer in a color-forming layer comprising a usually colorless or light-colored coupling substance and a developer which causes coloring of the coupling substance upon heating.Type: GrantFiled: October 27, 1989Date of Patent: December 25, 1990Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Mitsuo Akutsu, Syuji Iwakura, Keiji Tabata, Keiji Oya
-
Patent number: 4966883Abstract: A composition for use in a thermal-sensitive paper coating and a heat-sensitive recording material utilizing the coating, which composition comprises a phenolic developer, e.g., a traditional low speed phenolic having a melting point greater than 120.degree. C., and a pseudo developer. The pseudo developer is combined with the phenolic developer in an amount effective to provide for the formation of homogenous phase when the composition is melted, which phase further solidifies back to a single crystalline phase when cooled.Type: GrantFiled: August 17, 1988Date of Patent: October 30, 1990Assignee: James River Graphics, Inc.Inventors: Nils T. Anderson, Boris J. Katsen
-
Patent number: 4965237Abstract: This invention relates to a thermal printing material comprising a substrate and a thermal printing layer formed thereon containing an aromaticity-possessing isocyanate compound, an imino compound having at least one>C.dbd.NH group which reacts with said aromaticity-possessing isocyanate compound on heating to produce color, and one or more aniline derivatives having at least one amino group, said thermal printing layer being intended to improve the image storage properties, in particular, the storage properties of color-undeveloped portion (ground), and it can be utilized in recorders for measurements, facsimiles, printers, terminals of computers, labels, and automatic ticket vending machines.Type: GrantFiled: December 31, 1987Date of Patent: October 23, 1990Assignees: Mitsubishi Paper Mills, Ltd., Asahi Kasei Kogyo Kabushiki KaishaInventors: Shigetoshi Hiraishi, Kazuo Kabashima
-
Patent number: 4956333Abstract: A heat-sensitive recording material characterized in that a heat-sensitive color-developing layer containing a compound represented by the formula (I), ##STR1## wherein R represents a hydrogen atom or a methyl group, a leuco dye and an acidic substance is formed on a support.Type: GrantFiled: September 18, 1989Date of Patent: September 11, 1990Assignee: Nippon Kayaku Kabushiki KaishaInventors: Kenichi Kawahara, Masaharu Nomura, Hiroaki Tsugawa, Hirofumi Iwamoto
-
Patent number: 4956332Abstract: A heat-sensitive recording material with an excellent recording sensitivity, heat stability and resistance to the whitening phenomenon, comprising a heat-sensitive color developing layer formed on a substrate sheet and containing, in addition to a colorless dye precursor, color developing agent and binder, a heat-fusible sensitizing agent consisting essentially of at least one member selected from 1,4-bis(p-tolyloxy)benzene, 1,4-bis(3', 4'-dimethylphenyloxy)benzene and 1,4-bis(3',5'-dimethylphenyloxy)benzene, in an amount of 10% to 1,000% based on the weight of the color developing agent.Type: GrantFiled: August 28, 1989Date of Patent: September 11, 1990Assignee: Oji Paper Co., Ltd.Inventors: Yoshiyuki Takahashi, Kunitaka Toyofuku, Akiko Iwasaki
-
Patent number: 4950637Abstract: In a heat sensitive recording material comprising a substrate and a heat sensitive recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor which is reactive with the dye to form a color when contacted therewith, the recording material characterized in that at least one of the compounds of the formula (I) is contained in the heat sensitive recording layer ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are same or different and are hydrogen atom, halogen atom, C.sub.1 .about.C.sub.5 alkyl or C.sub.1 .about.C.sub.5 alkoxyl.Type: GrantFiled: April 6, 1989Date of Patent: August 21, 1990Assignee: Kanzaki Paper Manufacturing Co. Ltd.Inventors: Shuki Okauchi, Toshitake Suzuki, Yoshiyuki Nukushina, Masato Kawamura