And Identified Color-former Patents (Class 503/217)
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Patent number: 11926168Abstract: The invention relates to a color developer of formula (I), (Ar1—SO2—NH—)m-Y—(—NH—C(O)—NH—SO2—Ar2)n (I), wherein Ar1 is an unsubstituted or substituted aromatic moiety, Ar2 is an unsubstituted or substituted phenyl moiety, Y is at least an (m+n)-times substituted benzene group or naphthalene group, and Y is substituted in such a way that at least one Ar2—SO2—NH—C(O)—NH group is in ortho-position with respect to at least one Ar1—SO2—NH group. The invention further relates to a heat-sensitive recording material, comprising a carrier substrate and a heat-sensitive color-forming layer, which contains at least one color former and at least one phenol-free color developer, the at least one color developer being the compound of formula (I). The invention further relates to a method for producing said heat-sensitive recording material.Type: GrantFiled: May 17, 2018Date of Patent: March 12, 2024Assignee: PAPIERFABRIK AUGUST KOEHLER SEInventors: Michael Horn, Timo Stalling, Maren Steppat
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Patent number: 9376594Abstract: There is provided a polishing composition capable of suppressing formation of a stepped portion caused by etching of a surface of a polishing object including a portion containing a group IV material when the polishing object is polished. The present invention relates to a polishing composition for polishing of a polishing object including a portion that contains a group IV material, and the polishing composition contains an oxidizing agent and an anticorrosive agent. Preferably, the anticorrosive agent includes at least one selected from the group consisting of compounds in which two or more carbonyl groups contained in a molecule are bonded through a carbon atom in the molecule. To be more specific, preferably, the anticorrosive agent includes at least one selected from the group consisting of a 1,3-diketone compound, a 1,4-diketone compound, and a triketone compound.Type: GrantFiled: March 11, 2013Date of Patent: June 28, 2016Assignee: FUJIMI INCORPORATEDInventors: Shuichi Tamada, Satoru Yarita
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Patent number: 9034790Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The modifier compound can be selected from the group consisting of a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide, or any of 1,2-diphenoxy ethane, dimethyl diphenoxy ethane, and dimethyl phthalate.Type: GrantFiled: March 14, 2013Date of Patent: May 19, 2015Assignee: Appvion, Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Patent number: 8916496Abstract: The invention describes an improved thermally-responsive record material substantially free of aromatic isocyanate yielding an image of high intensity and useful for bar codes. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless color former comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, and an organic acid which upon being heated reacts with said color former to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The compound can be selected from the group consisting of a fatty acid amide, such as stearmide. Optionally, magnesium state is included.Type: GrantFiled: October 11, 2013Date of Patent: December 23, 2014Assignee: Appvion, Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Patent number: 8916497Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.Type: GrantFiled: April 29, 2014Date of Patent: December 23, 2014Assignee: Appvion, Inc.Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
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Patent number: 8888906Abstract: A heat-sensitive color-developing composition containing a hydroxyquinoline compound having a methyl group and an acid anhydride compound represented by general formula (1): wherein ring A represents a substituted or unsubstituted aromatic hydrocarbon ring, and n represents an integer of 1 to 3, and a heat-sensitive recording material containing the composition in a recording layer.Type: GrantFiled: September 13, 2011Date of Patent: November 18, 2014Assignee: Yamamoto Chemicals, Inc.Inventors: Ryoji Yamaguchi, Toshihiro Masaoka, Keisuke Takuma
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Publication number: 20140315713Abstract: The present invention provides a compound represented by the formula (1). The compound represented by the formula (1) is a developing agent superior in both color-developing sensitivity with low energy and image stability [in the following formula, wherein R1 is a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or an aralkyl group, R2 in the number of m are each independently an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, a hydroxy group, a cyano group, a nitro group, a carboxy group or an amino group, R3 in the number of n are each independently an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, a hydroxy group, a cyano group, a nitro group, a carboxy group or an amino group, and m and n are each independently an integer of 0-4.Type: ApplicationFiled: October 31, 2012Publication date: October 23, 2014Applicants: NIPPON PAPER INDUSTRIES CO., LTD., MITSUBISHI CHEMICAL CORPORATIONInventors: Akihito Ogino, Yoshimi Midorikawa, Yukiko Sato, Keiichiro Inada, Mai Higuchi, Mamoru Suga
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Patent number: 8859460Abstract: A heat-sensitive recording material includes at least a paper substrate, a heat-sensitive recording layer arranged on the front side of the substrate and which has at least one dye precursor and at least one color acceptor, wherein dye precursor and color acceptor react with one another under the action of heat to form color, and an authenticating security feature. The authenticating security feature is a mark which is applied to the back side of the paper substrate and which is made of a tincture having at least one organic solvent. A barrier coating is arranged between the substrate and heat-sensitive recording layer and is suitable to protect the heat-sensitive recording layer against penetration of the tincture into the heat-sensitive recording layer from the back side.Type: GrantFiled: November 30, 2010Date of Patent: October 14, 2014Assignee: Mitsubishi HiTec Paper Europe GmbHInventors: Ulf Behrens, Gerhard Stork, Svenja Eisernitz, Matthias Marx
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Publication number: 20140263665Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The modifier compound can be selected from the group consisting of a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide, or any of 1,2-diphenoxy ethane, dimethyl diphenoxy ethane, and dimethyl phthalate.Type: ApplicationFiled: March 14, 2013Publication date: September 18, 2014Applicant: Appleton Papers Inc.Inventors: Fadi Selim Chakar, Mark Robert Fisher
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Publication number: 20140231529Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.Type: ApplicationFiled: April 29, 2014Publication date: August 21, 2014Applicant: Appvion, Inc.Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
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Publication number: 20140235437Abstract: A color acceptor for chemical reaction with a dye precursor to form a visually recognizable color. The color acceptor is constructed of lactic acid monomers. Also disclosed is a heat-sensitive recording material with a substrate and a heat-sensitive recording layer, wherein the heat-sensitive recording layer contains at least one dye precursor and at least one color acceptor which react with one another in a color-forming manner when heat is applied, and wherein the color acceptor is constructed of lactic acid monomers.Type: ApplicationFiled: November 8, 2012Publication date: August 21, 2014Inventor: Matthias Neukirch
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Patent number: 8722574Abstract: There are described thermal imaging members and thermal imaging methods utilizing unsymmetrical rhodamine compounds. The rhodamine color-forming compounds exhibit a first color when in a crystalline form and a second color, different from the first color, when in an amorphous form.Type: GrantFiled: April 27, 2012Date of Patent: May 13, 2014Assignee: Zink Imaging, Inc.Inventors: Michael P Filosa, Stephen J. Telfer, John L Marshall, Richard M Allen, John M Hardin
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Publication number: 20140057783Abstract: A method for producing a heat-sensitive recording material comprises: preparing a first coating composition, which includes as color acceptor 4,4?-dihydroxydiphenyl sulfone, at least one sensitizer selected from the list of methylolstearamide, stearic acid amide, and dimethyl terephtalate; preparing a second coating composition, which includes: from 65 to 95% by weight of one or more (meth)acrylate from 0 to 20% by weight of photoinitiators and from 0.5 to 20% by weight of wax; applying the prepared first coating composition to form the heat-sensitive recording layer on the front side of the substrate; drying the first coating composition; applying the second coating composition to form the protective layer covering the heat-sensitive recording layer; crosslinking the protective layer covering the heat-sensitive recording layer; applying the second coating composition to form the coating on the back side of the substrate; crosslinking the coating.Type: ApplicationFiled: February 8, 2012Publication date: February 27, 2014Inventors: Gerhard Stork, Matthias Marx, Falk Jahns
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Patent number: 8603943Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.Type: GrantFiled: November 19, 2009Date of Patent: December 10, 2013Assignee: Mitsubishi HiTec Paper Europe GmbHInventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
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Patent number: 8551911Abstract: An object of the present invention is to provide a recording material or a recording sheet that is excellent in background and image stabilities and further excellent in color-developing sensitivity. The recording material of the present invention contains a color-forming compound, an additive, and at least one compound represented by formula (I) [wherein R1 and R4 each independently represent a C1-C6 alkyl group or the like; p represents 0 or any integer of 1 to 4; q represents 0 or any integer of 1 to 5; when p and q represents 2 or more, each of R1 and each of R4 are the same or different; R2 and R3 each independently represent a hydrogen atom or the like; R5 represents a hydrogen atom or the like; and the bond represented by the wavy line represents E, Z, or a mixture thereof].Type: GrantFiled: September 27, 2010Date of Patent: October 8, 2013Assignee: Nippon Soda Co., Ltd.Inventors: Hiroshi Sakai, Toshio Aihara, Satoshi Kodama, Shuntaro Kinoshita, Kazumi Jyujyo, Tadahiro Kondo
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Patent number: 8198212Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.Type: GrantFiled: September 4, 2008Date of Patent: June 12, 2012Assignee: Mitsubishi HiTec Paper Flensburg GmbHInventors: Gerhard Stork, Annette Schreiber
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Publication number: 20110237432Abstract: A heat-sensitive recording material includes a paper web with recycled fibers and a heat-sensitive recording layer includes color formers and color acceptors. The amount of recycled fiber contained in the paper web is at least 70 percent by weight, and the heat-sensitive recording layer has, as color acceptor, at least 33? percent by weight of N-(p-toluenesulphonyl)-N?-3-(p-toluenesulphonyloxyphenyl)urea in relation to the total content of color acceptors in the heat-sensitive recording layer.Type: ApplicationFiled: July 9, 2009Publication date: September 29, 2011Applicant: Mitsubishi HiTec Paper Flensburg GmbHInventors: Gerhard Stork, Annette Schreiber, Svenja Eisernitz, Falk Jahns
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Publication number: 20110028317Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.Type: ApplicationFiled: November 19, 2009Publication date: February 3, 2011Applicant: Mitsubishi HiTec Paper Flensburg GmbHInventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
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Patent number: 7829497Abstract: There are described thermal imaging members and thermal imaging methods utilizing unsymmetrical rhodamine compounds. The rhodamine color-forming compounds exhibit a first color when in a crystalline form and a second color, different from the first color, when in an amorphous form.Type: GrantFiled: May 12, 2006Date of Patent: November 9, 2010Assignee: Zink Imaging, Inc.Inventors: Michael P. Filosa, Stephen J. Telfer, John L. Marshall, Richard M. Allen, John M. Hardin
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Publication number: 20100130356Abstract: A thermally-responsive record material useful for bar coding is taught comprising a support having provided thereon in substantially contiguous relationship a heat sensitive coating comprising at least one chromogenic material, said chromogenic material being selected from a fluoran, and at least one developer of the formula (II) wherein the chromogenic material and developer are of an average particle size equal to or less than 0.7 ?m meters, wherein the composition is substantially free of sensitizer or modifier. The record material of the invention remarkably images at high speed, with stable or intense imaging and little or no background discoloration.Type: ApplicationFiled: November 16, 2009Publication date: May 27, 2010Applicant: Appleton Papers Inc.Inventors: Mark Robert Fisher, Joseph Peter Gusse
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Publication number: 20090318289Abstract: The presently disclosed embodiments are directed to image forming mediums useful for reimageable and transient documents. More particularly, the embodiments pertain to an image forming medium comprising photochromic materials comprising unsymmetrical dithienylethene (DTE) photochromes which provide longer image lifetimes and “erase-on-demand” capability.Type: ApplicationFiled: June 24, 2008Publication date: December 24, 2009Applicant: Xerox CorporationInventors: Tyler Norsten, Gabriel Iftime, Peter Kazmaier, Fazila Seker
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Patent number: 7569515Abstract: An erasable image forming material includes a color former containing crystal violet lactone, a developer, a first binder resin of styrene-butadiene copolymer and a second binder resin of a styrene-based resin containing ?-methylstyrene, the first and second binder resins being in a compatible state.Type: GrantFiled: February 15, 2008Date of Patent: August 4, 2009Assignee: Kabushiki Kaisha ToshibaInventors: Satoshi Takayama, Kenji Sano, Takeshi Gotanda, Yumiko Sekiguchi
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Patent number: 7566682Abstract: In a thermal recording medium including a basic chromogenic dye, a developer and a sensitizer, a composition for a thermal recording medium which composition contains 50 ppm to 5.0 mass % of 1-(3-methylphenoxy)-2-(4-methylphenoxy)ethane and/or 1,2-bis(4-methylphenoxy)ethane in 1,2-bis(3-methylphenoxy)ethane is used as said sensitizer, whereby the 1,2-bis(3-methylphenoxy)ethane compound is remarkably improved in milling property in the preparation of the above sensitizer, and a thermal recording medium is provided without impairing the colorability, etc., such as thermal colorability.Type: GrantFiled: February 16, 2004Date of Patent: July 28, 2009Assignee: Sanko Co., LtdInventor: Shigeru Oda
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Publication number: 20090176647Abstract: The present invention provides a heat-sensitive recording material having a support, a heat-sensitive color-developing layer containing a leuco dye and a developer, and a protective layer, the heat-sensitive color-developing layer and the protective layer being formed on the support, wherein carboxylic-acid-modified polyvinyl alcohol with a weight average degree of polymerization of 100 to 400 and a modification degree of 0.2 mol % to 1.0 mol % is used as a dispersing agent for dispersing the leuco dye.Type: ApplicationFiled: March 12, 2008Publication date: July 9, 2009Inventors: Kunihiko HADA, Yoshikazu Kaneko, Michiyo Fukushima, Kazuyuki Uetake
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Patent number: 7557065Abstract: The invention provides a heat-sensitive recording material, which is highly sensitive, is almost free of staining on the background, and gives a recorded image excellent in stability during storage, by using a finely divided sensitizer dispersion excellent in shelf stability produced in a short time with high volumetric efficiency. The invention relates to a method of producing a sensitizer dispersion, which comprises emulsifying and finely dividing a heat-sensitive recording sensitizer by melting under heating in an aqueous emulsifying dispersant, and then crystallizing the finely divided emulsified dispersion under rapid cooling, wherein the sensitizer is at least one member selected from the group consisting of 1,2-bis(phenoxy)ethane, 1,2-bis(3-methylphenoxy)ethane, 1,2-bis(4-methylphenoxy)ethane, p-benzylbiphenyl, di-p-methylbenzyl oxalate, and ?-naphthyl benzyl ether.Type: GrantFiled: April 8, 2004Date of Patent: July 7, 2009Assignee: Sanko Co., Ltd.Inventors: Shigeru Oda, Eiji Kawabata, Takaaki Mori, Tjang Kie Tan, Hiroshi Sumitomo, Yoshito Nakagawa
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Publication number: 20090088321Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.Type: ApplicationFiled: September 4, 2008Publication date: April 2, 2009Inventors: Gerhard Stork, Annette Schreiber
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Publication number: 20090082202Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): ?and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.Type: ApplicationFiled: September 4, 2008Publication date: March 26, 2009Inventors: Gerhard Stork, Annette Schreiber
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Publication number: 20080269050Abstract: By printing a bar code (comprising dark and light regions) or parts of such a bar code with an ink containing a dye, which changes colour in the presence of an acid or a base to remove the contrast between the regions of the bar code, and a neutral compound which releases an acid or a base on exposure to energising radiation, a bar code can be produced that becomes unreadable after a pre-determined interval. This can be used as a time/temperature indicator to ensure that products, which might be perishable, associated with such a bar code are not used by the public.Type: ApplicationFiled: September 14, 2006Publication date: October 30, 2008Applicant: SUN CHEMICAL CORPORATIONInventors: Farid Azizian, Michael William Leonard
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Publication number: 20080233290Abstract: A method of preparing a thermally printable sheet which comprises providing a substrate comprising a base sheet having at least one surface coated with a layer containing a pigment in solid porous particulate form, and, using a printer, printing onto the coated surface of said substrate, a thermal ink which comprises a colour former, a colour developer and a sensitizer, characterised in that the sensitizer comprises dimethyl terephthalate, and that the ink also comprises at least one pigment. A novel thermally printable sheet suitable for use in such method is also provided.Type: ApplicationFiled: September 29, 2004Publication date: September 25, 2008Inventors: Andrew Ward-Askey, John Brian Cooper, Michael Eric Hobson
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Patent number: 7425523Abstract: A thermal transfer recording material contains at least one colorant represented by the following general formula (II), wherein R21 and R22 each represent a substituted or unsubstituted aliphatic group; R23 represents a substituent; n represents an integer of 0 to 4; when n is 2 or more, R23 is the same or different each other; R25 and R26 represent alkyl groups respectively; and at least one of R25 and R26 represents a secondary alkyl group.Type: GrantFiled: July 1, 2005Date of Patent: September 16, 2008Assignee: Dai Nippon Printing Co., Ltd.Inventors: Dai Ikemizu, Emiko Kataoka, Takatugu Suzuki, Kazuya Yoshida, Hiroyuki Yamashita
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Publication number: 20080220969Abstract: The present invention provides a heat-sensitive recording material with enhanced color developing sensitivity maintaining heat resistance and image storage stability characteristics such as plasticizer resistance and water resistance. The present invention provides a heat-sensitive recording material including at least a substrate and a heat-sensitive color developing layer containing a leuco dye and developers on the front surface of the substrate, wherein as the developers 4-hydroxy-4?-allyloxydiphenyl sulfone is used in combination with a first diphenyl compound represented by formula (1) and/or a second diphenyl compound represented by formula (2).Type: ApplicationFiled: March 6, 2008Publication date: September 11, 2008Applicant: Ricoh Company, Ltd.Inventors: Yoshiaki Matsunaga, Yoshikazu Kaneko
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Patent number: 7381684Abstract: A method for using a rewritable thermal label of the non-contact type which comprises recording and erasing information repeatedly in accordance with a non-contact method on a rewitable thermal label which remains attached to an adherend. The label contains (a) an anchor coat layer comprising a crosslinked resin, (b) a heat-sensitive color development layer, (c) a light absorption and a photo-thermal conversion layer and (d) an adhesive layer. The layers (a), (b), (c) and (d) are laminated on a first face of a substrate successively. The anchor coat layer is placed next to the substrate. The layer (c) is an outermost layer. The adhesive layer is placed on a second face of the substrate.Type: GrantFiled: March 29, 2005Date of Patent: June 3, 2008Assignee: Lintec CorporationInventors: Tatsuya Tsukida, Tetsuyuki Utagawa
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Publication number: 20080108500Abstract: The present invention provides a heat-sensitive recording material comprising a support and a heat-sensitive recording layer, wherein the heat-sensitive recording layer contains a leuco dye and a color developer, the leuco dye is in a form of composite particles comprising the leuco dye and a hydrophobic resin, and the color developer comprises at least 4,4?-cyclohexylidenediphenol and 4,4?-bis(N-p-tolylsulfonylaminocarbonylamino)diphenylmethane.Type: ApplicationFiled: December 13, 2005Publication date: May 8, 2008Applicant: OJI PAPER CO., LTD.Inventors: Nobuyuki Iwasaki, Hisashi Tani, Masato Kawai, Masaharu Nojima
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Patent number: 7354885Abstract: An erasable image forming material includes a color former containing crystal violet lactone, a developer, a first binder resin of styrene-butadiene copolymer and a second binder resin of a styrene-based resin containing a-methylstyrene, the first and second binder resins being in a compatible state.Type: GrantFiled: September 18, 2006Date of Patent: April 8, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Satoshi Takayama, Kenji Sano, Takeshi Gotanda, Yumiko Sekiguchi
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Publication number: 20080070781Abstract: An erasable image forming material is provided, which includes a binder resin, and a color former and a developer dispersed in the binder resin. The color former is amorphous.Type: ApplicationFiled: July 19, 2007Publication date: March 20, 2008Inventors: Takeshi Gotanda, Satoshi Takayama, Kenji Sano, Yumiko Sekiguchi, Shinya Sakurada
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Patent number: 7314705Abstract: A composition, method, and system for recording an image. The system includes an imaging material in which radiation energy is absorbed by an antenna material. The antenna material may be chosen from the group consisting of phthalocyanines and naphthalocyanines.Type: GrantFiled: June 2, 2006Date of Patent: January 1, 2008Assignee: Hewlett-Packard Development Company, L.P.Inventor: Makarand P. Gore
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Patent number: 7160840Abstract: A thermal recording material having a support and, formed thereon, a thermal coloring layer containing an electron donating colorless dye and an electron accepting compound, wherein the electron accepting compound comprises 4-hydroxybenzenesulfoneanilide and the support comprises a used paper pulp as a primary component; the thermal recording material which further comprises at least one of calcium carbonate of calcite type, amorphous silica and aluminum hydroxide as an inorganic pigment; and the thermal recording material wherein the electron donating colorless dye comprises a specific colorless dye and the recording material is formed through the use of a liquid pigment dispersion having a pH of 7 to 10.Type: GrantFiled: May 31, 2002Date of Patent: January 9, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Masayuki Iwasaki, Tsutomu Watanabe, Hirofumi Mitsuo
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Patent number: 7125824Abstract: A linerless label system comprising pressure adhesive coating, release coating and thermal imaging coating is described. The thermal imaging coating contains as one of its components the compounds of the formula (I) wherein R1 and R2 are selected from methyl, ethyl, aryl, aryl substituted with methyl, ethyl, methoxy, ethoxy or halogen, benzyl or benzyl with phenyl substituted with methyl, ethyl, methoxy, ethoxy or halogen, R3,R4,R5 and R6 are selected from hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, phenyl, R7 and R8 are each independently selected from methyl or ethyl, R9 is selected from hydrogen, methoxy or ethoxy, R10 is selected from hydrogen, dimethylamino or diethylamino, R11 is methyl. The imaged linerless label according to the invention has been a bar reflectance of less than 20 at 670 nanometers, a print control contrast signal of at least 80 and a BNL background of at least 75%.Type: GrantFiled: May 19, 2004Date of Patent: October 24, 2006Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher, Stacey Ann Justa MacNeil
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Patent number: 7078365Abstract: A thermosensitive recording material is provided having improved resistance to heat and chemicals, and having improved sensitivity to image formation while minimizing background coloring, wherein the thermosensitive recording material has a substrate, on which is a thermosensitive recording layer containing a leuco dye, a developer of formula (I) and at least two sensitizers, the two sensitizers being 4-hydroxy-4?-allyloxy diphenylsulfone and 4,4?-diallyloxy diphenylsulfone.Type: GrantFiled: March 1, 2004Date of Patent: July 18, 2006Assignee: Ricoh Company, Ltd.Inventors: Takeshi Kajikawa, Toshiaki Ikeda, Mitsuru Naruse
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Patent number: 7071144Abstract: Provided is a thermal recording material that is excellent in thermal response and retainability of an image portion and which generates fewer residues adhering to the thermal head of a thermal printer. The thermal recording material having a thermal recording layer comprising a generally colorless or light-colored electron-donating dye precursor and an electron-accepting developer that reacts under heat to cause said dye precursor to form a color, said thermal recording layer containing a specific diphenylsulfone derivative, a specific amide derivative and a specific fluorane derivative, wherein the weight ratio of the specific diphenylsulfone derivative above and the specific amide derivative above is 2/1 to 1/2.Type: GrantFiled: September 28, 2001Date of Patent: July 4, 2006Assignee: Mitsubishi Paper Mills, Ltd.Inventor: Shoji Hizatate
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Patent number: 7011922Abstract: The present invention provides a thermal recording material comprising a support and at least a thermal recording layer disposed on the support, wherein at least one of the thermal recording layer includes, together with an electron donating colorless dye, at least an electron accepting compound represented by the following general formula (1). R1 and R2 each independently represents a hydrogen atom, an alkyl group or an aryl group; and Ar is represented by the following general formula (2). In the general formula (2), R11 to R14 each independently represents a hydrogen atom, an alkyl group with 1 to 4 carbon atoms or an aryl group.Type: GrantFiled: February 19, 2003Date of Patent: March 14, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazumori Minami, Hisao Yamada, Hiroshi Sato
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Patent number: 6984608Abstract: The present invention relates to a method of manufacturing heat sensitive recording material for the bar code reader wavelength range of 660–690 nm, the recording material containing a base layer and a coating, and the coating containing at least a color former and a developer. The method of the invention is characterized in that the color former and the developer are selected so that when the reflectance of the color former-developer compound on the recording material is determined, it remains below a target curve determined with a function Hp=1.775*Ap22*10?61, where Hp is the reflectance percent and Ap the wavelength (nm) used in the bar code reader.Type: GrantFiled: May 24, 2002Date of Patent: January 10, 2006Assignee: Jujo Thermal OyInventors: Jouka Makitalo, Elina Mattila
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Patent number: 6919297Abstract: A heat-sensitive recording material including at least a heat-sensitive recording layer, a light transmittance adjusting layer and a heat resistant protective layer on a support, wherein oxygen permeability of the light transmittance adjusting layer is 0.8 or less, and the light transmittance adjusting layer includes a polyvinyl alcohol having a saponification rate of 90 mol % or more.Type: GrantFiled: October 16, 2002Date of Patent: July 19, 2005Assignee: Fuji Photo Film Co., Ltd.Inventor: Kazumori Minami
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Patent number: 6908505Abstract: Thermochromic compositions that include combinations of at least one color former and at least one Lewis acid in a polymer mixture are disclosed. The thermochromic compositions reversibly change appearance from substantially transparent to substantially non-transparent above a lower critical solution temperature.Type: GrantFiled: October 1, 2003Date of Patent: June 21, 2005Assignee: Spectra Systems CorporationInventors: Nabil M. Lawandy, Timothy J. Driscoll, Charles M. Zepp
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Patent number: 6878670Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye, a developer and a binder, wherein the heat-sensitive recording material uses as the developer at least two hydroxy-diphenylsulfone compounds such as 4-hydroxy-4?-isopropoxy-diphenylsulfone, 2,4?-dihydroxy-diphenylsulfone and the like, and uses as the leuco dye a black-color-forming leuco dye such as 3-di(n-butyl)amino-6-methyl-7-anilinofluoran or the like and 0.5 to 3.5 wt. %, relative to the black-color-forming leuco dye, of a red-color-forming leuco dye such as 3-diethylamino-7-chlorofluoran or the like.Type: GrantFiled: August 20, 2002Date of Patent: April 12, 2005Assignee: OJI Paper Co., Ltd.Inventors: Shigetoshi Seki, Toshiro Hata
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Patent number: 6835692Abstract: The present invention provides a heat-sensitive recording material having a support and a heat-sensitive recording layer, which contains a diazonium salt compound and a coupler compound that reacts with the diazonium salt to develop a color, wherein the recording material contains an oxonol dye.Type: GrantFiled: October 6, 2003Date of Patent: December 28, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kimi Ikeda, Shiki Ueki
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Patent number: 6815679Abstract: A reversible thermal recording material permits recording having a clear contrast at a high sensitivity and erasing such images a number of times, at least 1,000 times, repetitively, and comprises a leuco dye, a reversible developer and a light-heat-converting dye, the light-heat-converting dye having a deterioration ratio of 20% or less when a laser beam having an oscillation wavelength of 830 nm is applied thereto repeatedly 1000 times at a temperature of 25° C. at an energy of 2 J/cm2 or being a phthalocyanine compound having a vanadyl group, and a method of recording an image comprises applying a laser beam to the reversible thermal recording material, wherein the colored leuco dye is achromatized with energy that is 25 to 65% of the energy of the laser beam employed for causing the leuco dye to develop a color.Type: GrantFiled: February 11, 2003Date of Patent: November 9, 2004Assignee: Mitsubishi Paper Mills LimitedInventor: Yoichiro Azuma
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Patent number: 6787502Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance. The present invention for attaining the above-described object is a heat sensitive recording material comprising a substrate supporting thereon a heat sensitive recording layer containing a diazonium salt compound, a coupler which reacts with the diazonium salt compound when heated to develop color, and a base, wherein the heat sensitive recording layer includes as the base at least one of the guanidine compounds represented by the general formula (1): wherein, in the general formula (1), R1 and R2 represent an alkyl group or aryl group and may be the same or different, R3 and R4 represent a hydrogen atom, alkyl group or halogen atom and may be the same or different, and X represents a divalent connecting group.Type: GrantFiled: July 19, 2001Date of Patent: September 7, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
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Patent number: 6784136Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye and a developer, the developer being N-p-toluenesulfonyl-N′-3-(p-toluenesulfonyloxy)phenylurea, and the heat-sensitive recording layer containing (a) at least one fluoran-based leuco dye with a melting point of 190 to 230° C. and/or (b) at least one pigment selected from the group consisting of aluminum hydroxide, amorphous silica, kaolin and talc.Type: GrantFiled: November 20, 2001Date of Patent: August 31, 2004Assignee: Oji Paper Co., Ltd.Inventors: Nobuyuki Iwasaki, Koichi Ishida
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Patent number: 6767862Abstract: A thermal recording material having good image storability and good lightfastness. The recording material does not have background fogging, even when exposed to light in a broad wavelength range or exposed to high-temperature surroundings. The recording material has a thermal recording layer provided on a support, and the thermal recording layer contains a compound of general formula (1), a compound of general formula (2), and a compound of general formula (3).Type: GrantFiled: March 7, 2002Date of Patent: July 27, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazumori Minami, Yoshihiro Jinbo