And Identified Color-former Patents (Class 503/217)
  • Patent number: 11926168
    Abstract: The invention relates to a color developer of formula (I), (Ar1—SO2—NH—)m-Y—(—NH—C(O)—NH—SO2—Ar2)n (I), wherein Ar1 is an unsubstituted or substituted aromatic moiety, Ar2 is an unsubstituted or substituted phenyl moiety, Y is at least an (m+n)-times substituted benzene group or naphthalene group, and Y is substituted in such a way that at least one Ar2—SO2—NH—C(O)—NH group is in ortho-position with respect to at least one Ar1—SO2—NH group. The invention further relates to a heat-sensitive recording material, comprising a carrier substrate and a heat-sensitive color-forming layer, which contains at least one color former and at least one phenol-free color developer, the at least one color developer being the compound of formula (I). The invention further relates to a method for producing said heat-sensitive recording material.
    Type: Grant
    Filed: May 17, 2018
    Date of Patent: March 12, 2024
    Assignee: PAPIERFABRIK AUGUST KOEHLER SE
    Inventors: Michael Horn, Timo Stalling, Maren Steppat
  • Patent number: 9376594
    Abstract: There is provided a polishing composition capable of suppressing formation of a stepped portion caused by etching of a surface of a polishing object including a portion containing a group IV material when the polishing object is polished. The present invention relates to a polishing composition for polishing of a polishing object including a portion that contains a group IV material, and the polishing composition contains an oxidizing agent and an anticorrosive agent. Preferably, the anticorrosive agent includes at least one selected from the group consisting of compounds in which two or more carbonyl groups contained in a molecule are bonded through a carbon atom in the molecule. To be more specific, preferably, the anticorrosive agent includes at least one selected from the group consisting of a 1,3-diketone compound, a 1,4-diketone compound, and a triketone compound.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: June 28, 2016
    Assignee: FUJIMI INCORPORATED
    Inventors: Shuichi Tamada, Satoru Yarita
  • Patent number: 9034790
    Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The modifier compound can be selected from the group consisting of a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide, or any of 1,2-diphenoxy ethane, dimethyl diphenoxy ethane, and dimethyl phthalate.
    Type: Grant
    Filed: March 14, 2013
    Date of Patent: May 19, 2015
    Assignee: Appvion, Inc.
    Inventors: Fadi Selim Chakar, Mark Robert Fisher
  • Patent number: 8916496
    Abstract: The invention describes an improved thermally-responsive record material substantially free of aromatic isocyanate yielding an image of high intensity and useful for bar codes. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless color former comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, and an organic acid which upon being heated reacts with said color former to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The compound can be selected from the group consisting of a fatty acid amide, such as stearmide. Optionally, magnesium state is included.
    Type: Grant
    Filed: October 11, 2013
    Date of Patent: December 23, 2014
    Assignee: Appvion, Inc.
    Inventors: Fadi Selim Chakar, Mark Robert Fisher
  • Patent number: 8916497
    Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.
    Type: Grant
    Filed: April 29, 2014
    Date of Patent: December 23, 2014
    Assignee: Appvion, Inc.
    Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
  • Patent number: 8888906
    Abstract: A heat-sensitive color-developing composition containing a hydroxyquinoline compound having a methyl group and an acid anhydride compound represented by general formula (1): wherein ring A represents a substituted or unsubstituted aromatic hydrocarbon ring, and n represents an integer of 1 to 3, and a heat-sensitive recording material containing the composition in a recording layer.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: November 18, 2014
    Assignee: Yamamoto Chemicals, Inc.
    Inventors: Ryoji Yamaguchi, Toshihiro Masaoka, Keisuke Takuma
  • Publication number: 20140315713
    Abstract: The present invention provides a compound represented by the formula (1). The compound represented by the formula (1) is a developing agent superior in both color-developing sensitivity with low energy and image stability [in the following formula, wherein R1 is a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or an aralkyl group, R2 in the number of m are each independently an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, a hydroxy group, a cyano group, a nitro group, a carboxy group or an amino group, R3 in the number of n are each independently an alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, a halogen atom, a hydroxy group, a cyano group, a nitro group, a carboxy group or an amino group, and m and n are each independently an integer of 0-4.
    Type: Application
    Filed: October 31, 2012
    Publication date: October 23, 2014
    Applicants: NIPPON PAPER INDUSTRIES CO., LTD., MITSUBISHI CHEMICAL CORPORATION
    Inventors: Akihito Ogino, Yoshimi Midorikawa, Yukiko Sato, Keiichiro Inada, Mai Higuchi, Mamoru Suga
  • Patent number: 8859460
    Abstract: A heat-sensitive recording material includes at least a paper substrate, a heat-sensitive recording layer arranged on the front side of the substrate and which has at least one dye precursor and at least one color acceptor, wherein dye precursor and color acceptor react with one another under the action of heat to form color, and an authenticating security feature. The authenticating security feature is a mark which is applied to the back side of the paper substrate and which is made of a tincture having at least one organic solvent. A barrier coating is arranged between the substrate and heat-sensitive recording layer and is suitable to protect the heat-sensitive recording layer against penetration of the tincture into the heat-sensitive recording layer from the back side.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: October 14, 2014
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Ulf Behrens, Gerhard Stork, Svenja Eisernitz, Matthias Marx
  • Publication number: 20140263665
    Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone, which upon being heated react with said dye precursor to develop color, and including a binder material. Optionally, a modifier compound is included in the heat-sensitive composition. The modifier compound can be selected from the group consisting of a fatty acid amide, preferably a saturated fatty acid amide such as an alkyl amide, a bis methylene alkyl amide, or a bis ethylene alkyl amide, or any of 1,2-diphenoxy ethane, dimethyl diphenoxy ethane, and dimethyl phthalate.
    Type: Application
    Filed: March 14, 2013
    Publication date: September 18, 2014
    Applicant: Appleton Papers Inc.
    Inventors: Fadi Selim Chakar, Mark Robert Fisher
  • Publication number: 20140231529
    Abstract: The invention describes a thermally-responsive record material substantially free of aromatic isocyanate. The record material comprises a support having provided thereon a heat-sensitive composition comprising a substantially colorless dye precursor comprising a fluoran; and a developer material selected from the group consisting of 4,4?-diaminodiphenylsulfone and 3,3?-diaminodiphenylsulfone in combination with N-[(butylamino)carbonyl]-4-methylbenzene sulfonamide, which upon being heated react with said dye precursor to develop color, and including a binder material.
    Type: Application
    Filed: April 29, 2014
    Publication date: August 21, 2014
    Applicant: Appvion, Inc.
    Inventors: Mark Robert Fisher, Fadi Selim Chakar, Yves Defrenne
  • Publication number: 20140235437
    Abstract: A color acceptor for chemical reaction with a dye precursor to form a visually recognizable color. The color acceptor is constructed of lactic acid monomers. Also disclosed is a heat-sensitive recording material with a substrate and a heat-sensitive recording layer, wherein the heat-sensitive recording layer contains at least one dye precursor and at least one color acceptor which react with one another in a color-forming manner when heat is applied, and wherein the color acceptor is constructed of lactic acid monomers.
    Type: Application
    Filed: November 8, 2012
    Publication date: August 21, 2014
    Inventor: Matthias Neukirch
  • Patent number: 8722574
    Abstract: There are described thermal imaging members and thermal imaging methods utilizing unsymmetrical rhodamine compounds. The rhodamine color-forming compounds exhibit a first color when in a crystalline form and a second color, different from the first color, when in an amorphous form.
    Type: Grant
    Filed: April 27, 2012
    Date of Patent: May 13, 2014
    Assignee: Zink Imaging, Inc.
    Inventors: Michael P Filosa, Stephen J. Telfer, John L Marshall, Richard M Allen, John M Hardin
  • Publication number: 20140057783
    Abstract: A method for producing a heat-sensitive recording material comprises: preparing a first coating composition, which includes as color acceptor 4,4?-dihydroxydiphenyl sulfone, at least one sensitizer selected from the list of methylolstearamide, stearic acid amide, and dimethyl terephtalate; preparing a second coating composition, which includes: from 65 to 95% by weight of one or more (meth)acrylate from 0 to 20% by weight of photoinitiators and from 0.5 to 20% by weight of wax; applying the prepared first coating composition to form the heat-sensitive recording layer on the front side of the substrate; drying the first coating composition; applying the second coating composition to form the protective layer covering the heat-sensitive recording layer; crosslinking the protective layer covering the heat-sensitive recording layer; applying the second coating composition to form the coating on the back side of the substrate; crosslinking the coating.
    Type: Application
    Filed: February 8, 2012
    Publication date: February 27, 2014
    Inventors: Gerhard Stork, Matthias Marx, Falk Jahns
  • Patent number: 8603943
    Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: December 10, 2013
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
  • Patent number: 8551911
    Abstract: An object of the present invention is to provide a recording material or a recording sheet that is excellent in background and image stabilities and further excellent in color-developing sensitivity. The recording material of the present invention contains a color-forming compound, an additive, and at least one compound represented by formula (I) [wherein R1 and R4 each independently represent a C1-C6 alkyl group or the like; p represents 0 or any integer of 1 to 4; q represents 0 or any integer of 1 to 5; when p and q represents 2 or more, each of R1 and each of R4 are the same or different; R2 and R3 each independently represent a hydrogen atom or the like; R5 represents a hydrogen atom or the like; and the bond represented by the wavy line represents E, Z, or a mixture thereof].
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: October 8, 2013
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Hiroshi Sakai, Toshio Aihara, Satoshi Kodama, Shuntaro Kinoshita, Kazumi Jyujyo, Tadahiro Kondo
  • Patent number: 8198212
    Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.
    Type: Grant
    Filed: September 4, 2008
    Date of Patent: June 12, 2012
    Assignee: Mitsubishi HiTec Paper Flensburg GmbH
    Inventors: Gerhard Stork, Annette Schreiber
  • Publication number: 20110237432
    Abstract: A heat-sensitive recording material includes a paper web with recycled fibers and a heat-sensitive recording layer includes color formers and color acceptors. The amount of recycled fiber contained in the paper web is at least 70 percent by weight, and the heat-sensitive recording layer has, as color acceptor, at least 33? percent by weight of N-(p-toluenesulphonyl)-N?-3-(p-toluenesulphonyloxyphenyl)urea in relation to the total content of color acceptors in the heat-sensitive recording layer.
    Type: Application
    Filed: July 9, 2009
    Publication date: September 29, 2011
    Applicant: Mitsubishi HiTec Paper Flensburg GmbH
    Inventors: Gerhard Stork, Annette Schreiber, Svenja Eisernitz, Falk Jahns
  • Publication number: 20110028317
    Abstract: A proposed heat-sensitive recording material comprises a substrate, a heat-sensitive recording layer containing color formers and color acceptors, and a protective layer covering this heat-sensitive recording layer. The heat-sensitive recording layer has, as color acceptor, at least 66? percent by weight of 4,4?-dihydroxydiphenyl sulfone based on the total percentage of color acceptors in the heat-sensitive recording layer, and the protective layer has, as binder, at least 60 percent by weight of diacetone-modified polyvinyl alcohol based on the total percentage of binder in the protective layer.
    Type: Application
    Filed: November 19, 2009
    Publication date: February 3, 2011
    Applicant: Mitsubishi HiTec Paper Flensburg GmbH
    Inventors: Gerhard Stork, Annette Schreiber, Diana Valentina Becerra Siabato
  • Patent number: 7829497
    Abstract: There are described thermal imaging members and thermal imaging methods utilizing unsymmetrical rhodamine compounds. The rhodamine color-forming compounds exhibit a first color when in a crystalline form and a second color, different from the first color, when in an amorphous form.
    Type: Grant
    Filed: May 12, 2006
    Date of Patent: November 9, 2010
    Assignee: Zink Imaging, Inc.
    Inventors: Michael P. Filosa, Stephen J. Telfer, John L. Marshall, Richard M. Allen, John M. Hardin
  • Publication number: 20100130356
    Abstract: A thermally-responsive record material useful for bar coding is taught comprising a support having provided thereon in substantially contiguous relationship a heat sensitive coating comprising at least one chromogenic material, said chromogenic material being selected from a fluoran, and at least one developer of the formula (II) wherein the chromogenic material and developer are of an average particle size equal to or less than 0.7 ?m meters, wherein the composition is substantially free of sensitizer or modifier. The record material of the invention remarkably images at high speed, with stable or intense imaging and little or no background discoloration.
    Type: Application
    Filed: November 16, 2009
    Publication date: May 27, 2010
    Applicant: Appleton Papers Inc.
    Inventors: Mark Robert Fisher, Joseph Peter Gusse
  • Publication number: 20090318289
    Abstract: The presently disclosed embodiments are directed to image forming mediums useful for reimageable and transient documents. More particularly, the embodiments pertain to an image forming medium comprising photochromic materials comprising unsymmetrical dithienylethene (DTE) photochromes which provide longer image lifetimes and “erase-on-demand” capability.
    Type: Application
    Filed: June 24, 2008
    Publication date: December 24, 2009
    Applicant: Xerox Corporation
    Inventors: Tyler Norsten, Gabriel Iftime, Peter Kazmaier, Fazila Seker
  • Patent number: 7569515
    Abstract: An erasable image forming material includes a color former containing crystal violet lactone, a developer, a first binder resin of styrene-butadiene copolymer and a second binder resin of a styrene-based resin containing ?-methylstyrene, the first and second binder resins being in a compatible state.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: August 4, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Satoshi Takayama, Kenji Sano, Takeshi Gotanda, Yumiko Sekiguchi
  • Patent number: 7566682
    Abstract: In a thermal recording medium including a basic chromogenic dye, a developer and a sensitizer, a composition for a thermal recording medium which composition contains 50 ppm to 5.0 mass % of 1-(3-methylphenoxy)-2-(4-methylphenoxy)ethane and/or 1,2-bis(4-methylphenoxy)ethane in 1,2-bis(3-methylphenoxy)ethane is used as said sensitizer, whereby the 1,2-bis(3-methylphenoxy)ethane compound is remarkably improved in milling property in the preparation of the above sensitizer, and a thermal recording medium is provided without impairing the colorability, etc., such as thermal colorability.
    Type: Grant
    Filed: February 16, 2004
    Date of Patent: July 28, 2009
    Assignee: Sanko Co., Ltd
    Inventor: Shigeru Oda
  • Publication number: 20090176647
    Abstract: The present invention provides a heat-sensitive recording material having a support, a heat-sensitive color-developing layer containing a leuco dye and a developer, and a protective layer, the heat-sensitive color-developing layer and the protective layer being formed on the support, wherein carboxylic-acid-modified polyvinyl alcohol with a weight average degree of polymerization of 100 to 400 and a modification degree of 0.2 mol % to 1.0 mol % is used as a dispersing agent for dispersing the leuco dye.
    Type: Application
    Filed: March 12, 2008
    Publication date: July 9, 2009
    Inventors: Kunihiko HADA, Yoshikazu Kaneko, Michiyo Fukushima, Kazuyuki Uetake
  • Patent number: 7557065
    Abstract: The invention provides a heat-sensitive recording material, which is highly sensitive, is almost free of staining on the background, and gives a recorded image excellent in stability during storage, by using a finely divided sensitizer dispersion excellent in shelf stability produced in a short time with high volumetric efficiency. The invention relates to a method of producing a sensitizer dispersion, which comprises emulsifying and finely dividing a heat-sensitive recording sensitizer by melting under heating in an aqueous emulsifying dispersant, and then crystallizing the finely divided emulsified dispersion under rapid cooling, wherein the sensitizer is at least one member selected from the group consisting of 1,2-bis(phenoxy)ethane, 1,2-bis(3-methylphenoxy)ethane, 1,2-bis(4-methylphenoxy)ethane, p-benzylbiphenyl, di-p-methylbenzyl oxalate, and ?-naphthyl benzyl ether.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: July 7, 2009
    Assignee: Sanko Co., Ltd.
    Inventors: Shigeru Oda, Eiji Kawabata, Takaaki Mori, Tjang Kie Tan, Hiroshi Sumitomo, Yoshito Nakagawa
  • Publication number: 20090088321
    Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.
    Type: Application
    Filed: September 4, 2008
    Publication date: April 2, 2009
    Inventors: Gerhard Stork, Annette Schreiber
  • Publication number: 20090082202
    Abstract: A heat-sensitive recording material is proposed, which comprises a substrate and a heat-sensitive recording layer that contains color formers and color acceptors, where the color formers are selected from the list comprising: 3-diethylamino-6-methyl-7-anilinofluoran, 3-dibutylamino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-propyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-isoamyl)amino-6-methyl-7-anilinofluoran, 3-(N-methyl-N-cyclohexyl)amino-6-methyl-7-anilinofluoran, 3-(N-ethyl-N-tolyl)amino-6-methyl-7-anilinofluoran, and 3-(N-ethyl-N-tetrahydrofuryl)amino-6-methyl-7-anilinofluoran, the heat-sensitive recording layer contains two color acceptors, which are: N-(p-toluenesulfonyl)-N?-3-(p-toluenesulfonyloxyphenyl)urea with the following formula (1): ?and a urea-urethane compound with the following formula (2): where the ratio of the two color acceptors, i.e.
    Type: Application
    Filed: September 4, 2008
    Publication date: March 26, 2009
    Inventors: Gerhard Stork, Annette Schreiber
  • Publication number: 20080269050
    Abstract: By printing a bar code (comprising dark and light regions) or parts of such a bar code with an ink containing a dye, which changes colour in the presence of an acid or a base to remove the contrast between the regions of the bar code, and a neutral compound which releases an acid or a base on exposure to energising radiation, a bar code can be produced that becomes unreadable after a pre-determined interval. This can be used as a time/temperature indicator to ensure that products, which might be perishable, associated with such a bar code are not used by the public.
    Type: Application
    Filed: September 14, 2006
    Publication date: October 30, 2008
    Applicant: SUN CHEMICAL CORPORATION
    Inventors: Farid Azizian, Michael William Leonard
  • Publication number: 20080233290
    Abstract: A method of preparing a thermally printable sheet which comprises providing a substrate comprising a base sheet having at least one surface coated with a layer containing a pigment in solid porous particulate form, and, using a printer, printing onto the coated surface of said substrate, a thermal ink which comprises a colour former, a colour developer and a sensitizer, characterised in that the sensitizer comprises dimethyl terephthalate, and that the ink also comprises at least one pigment. A novel thermally printable sheet suitable for use in such method is also provided.
    Type: Application
    Filed: September 29, 2004
    Publication date: September 25, 2008
    Inventors: Andrew Ward-Askey, John Brian Cooper, Michael Eric Hobson
  • Patent number: 7425523
    Abstract: A thermal transfer recording material contains at least one colorant represented by the following general formula (II), wherein R21 and R22 each represent a substituted or unsubstituted aliphatic group; R23 represents a substituent; n represents an integer of 0 to 4; when n is 2 or more, R23 is the same or different each other; R25 and R26 represent alkyl groups respectively; and at least one of R25 and R26 represents a secondary alkyl group.
    Type: Grant
    Filed: July 1, 2005
    Date of Patent: September 16, 2008
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Dai Ikemizu, Emiko Kataoka, Takatugu Suzuki, Kazuya Yoshida, Hiroyuki Yamashita
  • Publication number: 20080220969
    Abstract: The present invention provides a heat-sensitive recording material with enhanced color developing sensitivity maintaining heat resistance and image storage stability characteristics such as plasticizer resistance and water resistance. The present invention provides a heat-sensitive recording material including at least a substrate and a heat-sensitive color developing layer containing a leuco dye and developers on the front surface of the substrate, wherein as the developers 4-hydroxy-4?-allyloxydiphenyl sulfone is used in combination with a first diphenyl compound represented by formula (1) and/or a second diphenyl compound represented by formula (2).
    Type: Application
    Filed: March 6, 2008
    Publication date: September 11, 2008
    Applicant: Ricoh Company, Ltd.
    Inventors: Yoshiaki Matsunaga, Yoshikazu Kaneko
  • Patent number: 7381684
    Abstract: A method for using a rewritable thermal label of the non-contact type which comprises recording and erasing information repeatedly in accordance with a non-contact method on a rewitable thermal label which remains attached to an adherend. The label contains (a) an anchor coat layer comprising a crosslinked resin, (b) a heat-sensitive color development layer, (c) a light absorption and a photo-thermal conversion layer and (d) an adhesive layer. The layers (a), (b), (c) and (d) are laminated on a first face of a substrate successively. The anchor coat layer is placed next to the substrate. The layer (c) is an outermost layer. The adhesive layer is placed on a second face of the substrate.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: June 3, 2008
    Assignee: Lintec Corporation
    Inventors: Tatsuya Tsukida, Tetsuyuki Utagawa
  • Publication number: 20080108500
    Abstract: The present invention provides a heat-sensitive recording material comprising a support and a heat-sensitive recording layer, wherein the heat-sensitive recording layer contains a leuco dye and a color developer, the leuco dye is in a form of composite particles comprising the leuco dye and a hydrophobic resin, and the color developer comprises at least 4,4?-cyclohexylidenediphenol and 4,4?-bis(N-p-tolylsulfonylaminocarbonylamino)diphenylmethane.
    Type: Application
    Filed: December 13, 2005
    Publication date: May 8, 2008
    Applicant: OJI PAPER CO., LTD.
    Inventors: Nobuyuki Iwasaki, Hisashi Tani, Masato Kawai, Masaharu Nojima
  • Patent number: 7354885
    Abstract: An erasable image forming material includes a color former containing crystal violet lactone, a developer, a first binder resin of styrene-butadiene copolymer and a second binder resin of a styrene-based resin containing a-methylstyrene, the first and second binder resins being in a compatible state.
    Type: Grant
    Filed: September 18, 2006
    Date of Patent: April 8, 2008
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Satoshi Takayama, Kenji Sano, Takeshi Gotanda, Yumiko Sekiguchi
  • Publication number: 20080070781
    Abstract: An erasable image forming material is provided, which includes a binder resin, and a color former and a developer dispersed in the binder resin. The color former is amorphous.
    Type: Application
    Filed: July 19, 2007
    Publication date: March 20, 2008
    Inventors: Takeshi Gotanda, Satoshi Takayama, Kenji Sano, Yumiko Sekiguchi, Shinya Sakurada
  • Patent number: 7314705
    Abstract: A composition, method, and system for recording an image. The system includes an imaging material in which radiation energy is absorbed by an antenna material. The antenna material may be chosen from the group consisting of phthalocyanines and naphthalocyanines.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: January 1, 2008
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Makarand P. Gore
  • Patent number: 7160840
    Abstract: A thermal recording material having a support and, formed thereon, a thermal coloring layer containing an electron donating colorless dye and an electron accepting compound, wherein the electron accepting compound comprises 4-hydroxybenzenesulfoneanilide and the support comprises a used paper pulp as a primary component; the thermal recording material which further comprises at least one of calcium carbonate of calcite type, amorphous silica and aluminum hydroxide as an inorganic pigment; and the thermal recording material wherein the electron donating colorless dye comprises a specific colorless dye and the recording material is formed through the use of a liquid pigment dispersion having a pH of 7 to 10.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: January 9, 2007
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masayuki Iwasaki, Tsutomu Watanabe, Hirofumi Mitsuo
  • Patent number: 7125824
    Abstract: A linerless label system comprising pressure adhesive coating, release coating and thermal imaging coating is described. The thermal imaging coating contains as one of its components the compounds of the formula (I) wherein R1 and R2 are selected from methyl, ethyl, aryl, aryl substituted with methyl, ethyl, methoxy, ethoxy or halogen, benzyl or benzyl with phenyl substituted with methyl, ethyl, methoxy, ethoxy or halogen, R3,R4,R5 and R6 are selected from hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, phenyl, R7 and R8 are each independently selected from methyl or ethyl, R9 is selected from hydrogen, methoxy or ethoxy, R10 is selected from hydrogen, dimethylamino or diethylamino, R11 is methyl. The imaged linerless label according to the invention has been a bar reflectance of less than 20 at 670 nanometers, a print control contrast signal of at least 80 and a BNL background of at least 75%.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: October 24, 2006
    Assignee: Appleton Papers Inc.
    Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher, Stacey Ann Justa MacNeil
  • Patent number: 7078365
    Abstract: A thermosensitive recording material is provided having improved resistance to heat and chemicals, and having improved sensitivity to image formation while minimizing background coloring, wherein the thermosensitive recording material has a substrate, on which is a thermosensitive recording layer containing a leuco dye, a developer of formula (I) and at least two sensitizers, the two sensitizers being 4-hydroxy-4?-allyloxy diphenylsulfone and 4,4?-diallyloxy diphenylsulfone.
    Type: Grant
    Filed: March 1, 2004
    Date of Patent: July 18, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Takeshi Kajikawa, Toshiaki Ikeda, Mitsuru Naruse
  • Patent number: 7071144
    Abstract: Provided is a thermal recording material that is excellent in thermal response and retainability of an image portion and which generates fewer residues adhering to the thermal head of a thermal printer. The thermal recording material having a thermal recording layer comprising a generally colorless or light-colored electron-donating dye precursor and an electron-accepting developer that reacts under heat to cause said dye precursor to form a color, said thermal recording layer containing a specific diphenylsulfone derivative, a specific amide derivative and a specific fluorane derivative, wherein the weight ratio of the specific diphenylsulfone derivative above and the specific amide derivative above is 2/1 to 1/2.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: July 4, 2006
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventor: Shoji Hizatate
  • Patent number: 7011922
    Abstract: The present invention provides a thermal recording material comprising a support and at least a thermal recording layer disposed on the support, wherein at least one of the thermal recording layer includes, together with an electron donating colorless dye, at least an electron accepting compound represented by the following general formula (1). R1 and R2 each independently represents a hydrogen atom, an alkyl group or an aryl group; and Ar is represented by the following general formula (2). In the general formula (2), R11 to R14 each independently represents a hydrogen atom, an alkyl group with 1 to 4 carbon atoms or an aryl group.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: March 14, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazumori Minami, Hisao Yamada, Hiroshi Sato
  • Patent number: 6984608
    Abstract: The present invention relates to a method of manufacturing heat sensitive recording material for the bar code reader wavelength range of 660–690 nm, the recording material containing a base layer and a coating, and the coating containing at least a color former and a developer. The method of the invention is characterized in that the color former and the developer are selected so that when the reflectance of the color former-developer compound on the recording material is determined, it remains below a target curve determined with a function Hp=1.775*Ap22*10?61, where Hp is the reflectance percent and Ap the wavelength (nm) used in the bar code reader.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: January 10, 2006
    Assignee: Jujo Thermal Oy
    Inventors: Jouka Makitalo, Elina Mattila
  • Patent number: 6919297
    Abstract: A heat-sensitive recording material including at least a heat-sensitive recording layer, a light transmittance adjusting layer and a heat resistant protective layer on a support, wherein oxygen permeability of the light transmittance adjusting layer is 0.8 or less, and the light transmittance adjusting layer includes a polyvinyl alcohol having a saponification rate of 90 mol % or more.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: July 19, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazumori Minami
  • Patent number: 6908505
    Abstract: Thermochromic compositions that include combinations of at least one color former and at least one Lewis acid in a polymer mixture are disclosed. The thermochromic compositions reversibly change appearance from substantially transparent to substantially non-transparent above a lower critical solution temperature.
    Type: Grant
    Filed: October 1, 2003
    Date of Patent: June 21, 2005
    Assignee: Spectra Systems Corporation
    Inventors: Nabil M. Lawandy, Timothy J. Driscoll, Charles M. Zepp
  • Patent number: 6878670
    Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye, a developer and a binder, wherein the heat-sensitive recording material uses as the developer at least two hydroxy-diphenylsulfone compounds such as 4-hydroxy-4?-isopropoxy-diphenylsulfone, 2,4?-dihydroxy-diphenylsulfone and the like, and uses as the leuco dye a black-color-forming leuco dye such as 3-di(n-butyl)amino-6-methyl-7-anilinofluoran or the like and 0.5 to 3.5 wt. %, relative to the black-color-forming leuco dye, of a red-color-forming leuco dye such as 3-diethylamino-7-chlorofluoran or the like.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: April 12, 2005
    Assignee: OJI Paper Co., Ltd.
    Inventors: Shigetoshi Seki, Toshiro Hata
  • Patent number: 6835692
    Abstract: The present invention provides a heat-sensitive recording material having a support and a heat-sensitive recording layer, which contains a diazonium salt compound and a coupler compound that reacts with the diazonium salt to develop a color, wherein the recording material contains an oxonol dye.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: December 28, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kimi Ikeda, Shiki Ueki
  • Patent number: 6815679
    Abstract: A reversible thermal recording material permits recording having a clear contrast at a high sensitivity and erasing such images a number of times, at least 1,000 times, repetitively, and comprises a leuco dye, a reversible developer and a light-heat-converting dye, the light-heat-converting dye having a deterioration ratio of 20% or less when a laser beam having an oscillation wavelength of 830 nm is applied thereto repeatedly 1000 times at a temperature of 25° C. at an energy of 2 J/cm2 or being a phthalocyanine compound having a vanadyl group, and a method of recording an image comprises applying a laser beam to the reversible thermal recording material, wherein the colored leuco dye is achromatized with energy that is 25 to 65% of the energy of the laser beam employed for causing the leuco dye to develop a color.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: November 9, 2004
    Assignee: Mitsubishi Paper Mills Limited
    Inventor: Yoichiro Azuma
  • Patent number: 6787502
    Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance. The present invention for attaining the above-described object is a heat sensitive recording material comprising a substrate supporting thereon a heat sensitive recording layer containing a diazonium salt compound, a coupler which reacts with the diazonium salt compound when heated to develop color, and a base, wherein the heat sensitive recording layer includes as the base at least one of the guanidine compounds represented by the general formula (1): wherein, in the general formula (1), R1 and R2 represent an alkyl group or aryl group and may be the same or different, R3 and R4 represent a hydrogen atom, alkyl group or halogen atom and may be the same or different, and X represents a divalent connecting group.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: September 7, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
  • Patent number: 6784136
    Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye and a developer, the developer being N-p-toluenesulfonyl-N′-3-(p-toluenesulfonyloxy)phenylurea, and the heat-sensitive recording layer containing (a) at least one fluoran-based leuco dye with a melting point of 190 to 230° C. and/or (b) at least one pigment selected from the group consisting of aluminum hydroxide, amorphous silica, kaolin and talc.
    Type: Grant
    Filed: November 20, 2001
    Date of Patent: August 31, 2004
    Assignee: Oji Paper Co., Ltd.
    Inventors: Nobuyuki Iwasaki, Koichi Ishida
  • Patent number: 6767862
    Abstract: A thermal recording material having good image storability and good lightfastness. The recording material does not have background fogging, even when exposed to light in a broad wavelength range or exposed to high-temperature surroundings. The recording material has a thermal recording layer provided on a support, and the thermal recording layer contains a compound of general formula (1), a compound of general formula (2), and a compound of general formula (3).
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: July 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazumori Minami, Yoshihiro Jinbo