And Identified Color-former Patents (Class 503/217)
  • Patent number: 6746985
    Abstract: A full-color heat-sensitive recording material. At least a heat-sensitive recording layer that color-develops to yellow color; a heat-sensitive recording layer that color-develops to cyan color and a heat-sensitive recording layer that color-develops to magenta color are sequentially provided on a support in this order from the support side. All of the above-mentioned heat-sensitive recording layers contain a diazo compound and/or diazonium salt, and a coupler compound that reacts with the diazo compound and/or diazonium salt for color development.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: June 8, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Shunsaku Higashi
  • Patent number: 6743750
    Abstract: A heat-sensitive recording material includes, on a support thereof, a heat-sensitive recording layer containing a diazo compound and a coupler.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: June 1, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisato Nagase, Yoshihiro Jimbo
  • Patent number: 6693061
    Abstract: A light-permeable thermosensitive recording material having a light permeable support and a thermosensitive recording layer formed thereon and including a leuco dye, a color developer for the leuco dye, and a binder resin, wherein the developer is a compound represented by the following formula (1): wherein R1 represents an alkyl group having 4-16 carbon atoms or an aminoalkyl group having 4-16 carbon atoms.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: February 17, 2004
    Assignee: Ricoh Company, Ltd.
    Inventors: Hitoshi Shimbo, Hideo Suzaki, Masafumi Torii, Masaru Shimada
  • Patent number: 6677275
    Abstract: A thermally recording sheet which has high sensitivity in color development, satisfactory background heat resistance, and a satisfactory background color. The sheet contains a dihydroxydiphenylsulfone compound represented by general formula (1) as a color developer and a sulfonamide represented by general formula (2). In the formula, R1 and R2 each represents C1-8 alkyl, alkenyl, or halogeno; and a and b each is an integer of 0 to 3. In the formula, R3 represents C1-66 alkyl or electron-attracting group; and n is an integer of 0 to 2.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: January 13, 2004
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yoshimi Midorikawa, Naomi Sumikawa, Kaoru Hamada, Yoshihide Kimura, Toshio Kaneko
  • Patent number: 6645909
    Abstract: A process for an azo coupling reaction is provided that has a large coupling reaction rate and an excellent coloring density and exerts high coupling activity using a stable coupler, and a recording material containing the coupler is provided. The process for an azo coupling reaction comprises carrying out a coupling reaction of a diazonium salt and a coupler to make the diazonium salt form color, and the coupler has certain specified structures.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: November 11, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akinori Fujita, Tetsunori Matsushita
  • Publication number: 20030166467
    Abstract: A reversible thermal recording material permits recording having a clear contrast at a high sensitivity and erasing such images a number of times, at least 1,000 times, repetitively, and comprises a leuco dye, a reversible developer and a light-heat-converting dye, the light-heat-converting dye having a deterioration ratio of 20% or less when a laser beam having an oscillation wavelength of 830 nm is applied thereto repeatedly 1000 times at a temperature of 25° C. at an energy of 2 J/cm2 or being a phthalocyanine compound having a vanadyl group, and a method of recording an image comprises applying a laser beam to the reversible thermal recording material, wherein the colored leuco dye is achromatized with energy that is 25 to 65% of the energy of the laser beam employed for causing the leuco dye to develop a color.
    Type: Application
    Filed: February 11, 2003
    Publication date: September 4, 2003
    Inventor: Yoichiro Azuma
  • Patent number: 6613716
    Abstract: A coating composition is applied to a print stock substrate for preparing a thermally-active layer, the coating composition comprising: a developer comprising at least one or a combination of 6′-dipentylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 129473-78-5) and 6′-dibutylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 89331-94-2); a sensitizer comprising at least one or a combination of 1,1′-sulfonylbisbenzene (CAS No. 127-63-9) and dimethylterephthalate (CAS No. 120-61-6); and a coreactant (or developer) comprising at least one or a combination of bis(4-hydroxyphenyl)-4-methylpentane (CAS No. 6807-17-6) and 4-hydroxy-4′-isopropoxydiphenylsulfone (CAS No. 95235-30-6). Preferably, the print stock substrate will be coated with clay or the like to provide a smooth coating surface for the thermally-active layer.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: September 2, 2003
    Assignee: Miami Wabash Paper LLC
    Inventors: Eugene V. Hoefs, Regina A. Kleinhenz
  • Publication number: 20030158038
    Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance.
    Type: Application
    Filed: January 9, 2003
    Publication date: August 21, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
  • Publication number: 20030104939
    Abstract: A full-color heat-sensitive recording material. At least a heat-sensitive recording layer that color-develops to yellow color; a heat-sensitive recording layer that color-develops to cyan color and a heat-sensitive recording layer that color-develops to magenta color are sequentially provided on a support in this order from the support side. All of the above-mentioned heat-sensitive recording layers contain a diazo compound and/or diazonium salt, and a coupler compound that reacts with the diazo compound and/or diazonium salt for color development.
    Type: Application
    Filed: April 26, 2002
    Publication date: June 5, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Shunsaku Higashi
  • Patent number: 6551961
    Abstract: A thermal recording material which has high sensitivity in color development and a high whiteness of the background and is excellent in image retention and heat resistance. The thermal recording material contains a dihydroxydiphenylsulfon compound represented by general formula (1) as an organic color developer and 3-di-n-pentylamino-6-methyl-7-anilinofluoran as a colorless basic dye. (In the formula, R1 and R2 each represents C1-8 alkyl, alkenyl, or halogeno; and p and q each is an integer of 0 to 3.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: April 22, 2003
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Naomi Sumikawa, Kaoru Hamada, Yoshihide Kimura
  • Publication number: 20030045426
    Abstract: The present invention discloses a heat-sensitive recording material comprising a thermal recording layer disposed on a substrate which layer contains at least a diazonium salt compound and a coupler which has a coupling reaction with the diazonium salt compound to develop a color, wherein the thermal recording layer microcapsules, which encapsulate the diazonium salt compound, an aromatic carboxylate represented by the following general formula (I) and an aromatic carboxylate represented by the following general formula (II).
    Type: Application
    Filed: June 13, 2002
    Publication date: March 6, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Koreshige Ito
  • Publication number: 20030036478
    Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye, a developer and a binder, wherein the heat-sensitive recording material uses as the developer at least two hydroxy-diphenylsulfone compounds such as 4-hydroxy-4′-isopropoxy-diphenylsulfone, 2,4′-dihydroxy-diphenylsulfone and the like, and uses as the leuco dye a black-color-forming leuco dye such as 3-di(n-butyl)amino-6-methyl-7-anilinofluoran or the like and 0.5 to 3.5 wt. %, relative to the black-color-forming leuco dye, of a red-color-forming leuco dye such as 3-diethylamino-7-chlorofluoran or the like.
    Type: Application
    Filed: August 20, 2002
    Publication date: February 20, 2003
    Inventors: Shigetoshi Seki, Toshiro Hata
  • Publication number: 20020183203
    Abstract: A coating composition is applied to a print stock substrate for preparing a thermally-active layer, the coating composition comprising: a developer comprising at least one or a combination of 6′-dipentylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 129473-78-5) and 6′-dibutylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 89331-94-2); a sensitizer comprising at least one or a combination of 1,1′-sulfonylbisbenzene (CAS No. 127-63-9) and dimethylterephthalate (CAS No. 120-61-6); and a coreactant (or developer) comprising at least one or a combination of bis(4-hydroxyphenyl)-4-methylpentane (CAS No. 6807-17-6) and 4-hydroxy-4′-isopropoxydiphenylsulfone (CAS No. 95235-30-6). Preferably, the print stock substrate will be coated with clay or the like to provide a smooth coating surface for the thermally-active layer.
    Type: Application
    Filed: March 28, 2001
    Publication date: December 5, 2002
    Inventors: Eugene V. Hoefs, Regina A. Kleinhenz
  • Publication number: 20020183204
    Abstract: The present invention provides a diazonium salt represented by the following general formula (1) wherein R1 represents a branched alkyl group; R2 and R3separately represent an alkyl group and may bond to each other to form a ring; R4, R5, and R6 separately represent a hydrogen atom, an alkyl group, or an aryl group and R4 and R5 may bond to each other to form a ring; and X— represents an anion and a heat-sensitive recording material comprising a heat-sensitive recording layer including the diazonium salt and a coupler.
    Type: Application
    Filed: April 26, 2002
    Publication date: December 5, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Kimiatsu Nomura, Tatsuo Kawabuchi, Hisato Nagase, Satoshi Higuchi, Kimi Ikeda, Yoshihiro Jinbo
  • Publication number: 20020107145
    Abstract: A reversible thermosensitive recording material including: a substrate; a recording layer located overlying the substrate and including a crosslinked resin, an electron donating coloring agent and an electron accepting coloring developer; and a protective layer located overlying the recording layer and including a filler and a crosslinked resin, wherein the recording layer achieves a colored state or a non-colored state when appropriately heating and cooling the recording layer, and wherein the reversible thermosensitive recording material has a surface having at least one of a ten-point mean roughness (Rz) not less than 1.5 &mgr;m or a ratio Sm/Rz not greater than 120, wherein Sm represents an average peak-to-peak length of the surface of the recording material.
    Type: Application
    Filed: November 30, 2001
    Publication date: August 8, 2002
    Inventors: Kazumi Suzuki, Toshihiko Hotta, Tetsuya Amano, Satoru Sanpei
  • Publication number: 20020077252
    Abstract: A process for an azo coupling reaction is provided that has a large coupling reaction rate and an excellent coloring density and exerts high coupling activity using a stable coupler, and a recording material containing the coupler is provided. The process for an azo coupling reaction comprises carrying out a coupling reaction of a diazonium salt and a coupler to make the diazonium salt form color, and the coupler has certain specified structures.
    Type: Application
    Filed: October 26, 2001
    Publication date: June 20, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Akinori Fujita, Tetsunori Matsushita
  • Patent number: 6407034
    Abstract: A thermally printable thermoplastic media includes a thermoplastic material having a thermally activated composition incorporated therein. The thermally activated composition includes a leuco-dye, a color developer, and a reaction promoter. The printable media preferably has a thickness of from about 0.5 to about 1.5 mils to provide a roll with a longer length than a conventional paper roll, thereby increasing the amount of printable media which can be contained on a roll. The thermally printable thermoplastic media is manufactured by combining a thermoplastic material and a thermally activated composition, melting the combined thermoplastic material and thermally activated composition and forming a film from the combined thermoplastic material and thermally activated composition, typically by extrusion. To prevent pre-imaging or initiation of a thermo-chromogenic reaction from the heat involved in extrusion, the extrusion is preferably carried out in an oxygen-free environment.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: June 18, 2002
    Inventor: William D. Ewing
  • Publication number: 20020065194
    Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance.
    Type: Application
    Filed: July 19, 2001
    Publication date: May 30, 2002
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
  • Patent number: 6348432
    Abstract: Disclosed are heat sensitive coatings and record materials that are environmentally resistant and therefore do not require a protective coating. One embodiment includes an environmentally resistant heat sensitive coating that includes an acrylate polymer of the formula: wherein R1 is a hydrogen or a methyl group, R2 is a hydrogen or a methyl group, and R3 is nitrile or chlorine or wherein, when c is 0, R4 is methyl, phenyl, or substituted phenyl, and when c is greater than 0, R4 is methyl, phenyl, substituted phenyl, halogen, nitrile or hydroxyl; m is greater than 1; n is greater than 1; b is greater than or equal to 0; and c is an integer from 0 to 38.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: February 19, 2002
    Assignee: Nashua Corporation
    Inventor: Mohamed Elmasry
  • Patent number: 6284706
    Abstract: The thermally sensitive recording medium having sufficient color developing density and develops sepia color or light brown color. The color difference a* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 is within the region of 0˜40 and b* value is within the region of 0˜55.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: September 4, 2001
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6284707
    Abstract: The thermally sensitive recording medium having sufficient color developing density and develops navy blue or grayish blue color. The color difference L* value a* value and b* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 are within the regions of, A. L* value is 30˜50, a* value is −15˜0 and b* value is −30˜10, B. L* value is 30˜50, a* value is 0˜10 and b* value is −30˜0 or C. L* value is 30˜50, a* value is 10˜20 and b* value is −30˜15.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: September 4, 2001
    Assignee: Nopon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6258747
    Abstract: A thermally sensitive recording medium having sufficient color developing density and which develops russet or wine red color. The recording medium incorporates a dye precursor which includes at least one red color developing leuco dye having a maximum absorption wavelength of 480 to 570 nm and at least one black color developing leuco dye with maximum absorption wavelengths at 420 to 480 nm and 550 to 640 nm. The color difference a* value of developed image of said thermally sensitive recording medium, measured according to JIS-Z-8729 is within the region of 0 to 50 and b* value is within the region of −15 to 10.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: July 10, 2001
    Assignee: Nippon Paper Industries Co Ltd
    Inventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
  • Patent number: 6214766
    Abstract: Authenticatable paper and paperboard products are prepared by printing images such as microdots on one or both surfaces of the paper using a starch containing authenticating solution. The images are not detectable by the human eye, but can be revealed with the application of a standard iodine solution.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: April 10, 2001
    Assignee: Westvaco Corporation
    Inventor: Frederick L. Kurrle
  • Patent number: 6202926
    Abstract: A magnetic recording medium, and methods of making and reading the same, including on at least a portion of a substrate an irreversible recording layer which contains an irreversible recording material undergoing an irreversible change of saturation magnetization upon heating. The invention involves the steps of previously heating the irreversible recording layer to form an initial heated region in which a plurality of heated bars whose saturation magnetization has been irreversibly changed are arrayed in a bar code pattern, and converting unheated bars disposed between the heated bars into a heated state for changing the array pattern of heated bars, thereby recording the information.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: March 20, 2001
    Assignees: Tokyo Magnetic Printing Co., Ltd., TDK Corporation
    Inventors: Masahiro Ito, Shohei Mimura, Masao Shigeta, Tsutomu Chou
  • Patent number: 6197725
    Abstract: There is provided a coupler giving a magenta pigment excellent in hue using a diazonium salt compound which can be fixed at a wavelength around 420 nm.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: March 6, 2001
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuhiro Ohkawa, Hisao Yamada
  • Patent number: 6124377
    Abstract: A marking system that advantageously minimizes messiness during use is disclosed. The marking system comprises a marking composition comprising at least one color precursor in the form of a leuco dye. A marking instrument can be utilized to store the marking composition and/or apply the marking composition to a desired substrate. The substrate is provided with a coating comprising at least one color-triggering developer. Upon application of the leuco dye to the substrate, a chromophore, and hence, color, is formed. If, however, color is inadvertently triggered on an unintended surface, thereby resulting in an unwanted stain, the stain can be readily removed.
    Type: Grant
    Filed: July 1, 1998
    Date of Patent: September 26, 2000
    Assignee: Binney & Smith Inc.
    Inventors: Richard J. Kaiser, Arthur N. Urbanski
  • Patent number: 6093678
    Abstract: A thermal sensitive recording medium which has a feature to change the color of recorded pattern slowly and spontaneously after development, and the recorded pattern which has several days passed can be easily distinguished from that of just after development. Said thermal sensitive recording medium contains 4-hydroxybenzoic acid ester represented by general formula (I) as a color developer and uses triphenylmethane-based leuco dye and reddish color developing leuco dye whose maximum absorption wave length is 450.about.560 nm as a dye precursor. ##STR1## In this formula, R represents unsubstituted or substituted lower alkyl group of carbon number 1-7 or benzyl group.
    Type: Grant
    Filed: August 18, 1998
    Date of Patent: July 25, 2000
    Assignee: Nippon Paper Industries Co. Ltd.
    Inventors: Kaoru Hamada, Tadakazu Fukuchi, Tomoaki Nagai, Reiko Sato, Yutaka Wakita
  • Patent number: 6090748
    Abstract: A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording material has an image density retention not less than about 60% when the recording material having an image is allowed to settle in a dry place at 50.degree. C. for 24 hours, a residual image density not greater than about 0.03 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image, and a residual image density after light irradiation not greater than about 0.04 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image after light of 5,000 lux is irradiated to the recording material for 100 hours.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: July 18, 2000
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiromi Furuya, Tadafumi Tatewaki, Masafumi Torii, Fumio Kawamura, Hiroaki Matsui, Masaru Shimada, Kyoji Tsutsui
  • Patent number: 5977020
    Abstract: A thermosensitive reversible recording material capable of forming and holding clear colored images with a high contrast and capable of being repeatedly color-developed and color-erased many times, has a thermosensitive recording layer formed on substrate sheet and including (A) at least one reversibly color-developing and -erasing compound selected from those of the formulae (I), (II) and (III), and (B) at least one dye precursor compound of the formula (IV). ##STR1## R.sup.1 =naphyl or lower alkoxy-substituted phenyl group Y.sup.1, Y.sup.2 =--NHCO--, --SCONH--, --CONHCO--, etc., n, m, p=10 to 29, R.sup.2, R.sup.3, R.sup.4, R.sup.5 =C.sub.1 -C.sub.9 alkyl, C.sub.3 -C.sub.6 cycloalkyl or substituted or non-substituted phenyl group, R.sup.6, R.sup.7 =C.sub.1 -C.sub.6 alkyl or phenyl group.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: November 2, 1999
    Assignee: Oji Paper Co., Ltd.
    Inventors: Makoto Nishioka, Kazuo Yamane
  • Patent number: 5955225
    Abstract: A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.3 represent, independently from each other, a substituted or non-substituted hydrocarbon group, R.sup.2 represents a substituted or non-substituted aliphatic hydrocarbon group having at least two carbon atoms, with the proviso that the total number of carbon atoms of R.sup.1, R.sup.2 and R.sup.3 is at least 8, X and Y represent, independently from each other, a divalent group having a nitrogen atom or an oxygen atom and r is an integer of between 1 and 3.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: September 21, 1999
    Assignee: Ricoh Company Ltd.
    Inventors: Hiromi Furuya, Masafumi Torii, Masaru Shimada, Fumio Kawamura, Kyoji Tsutsui, Katsushi Sugiyama, Katsuaki Kokubo, Katsuhisa Kamio, Kazuo Hosoda, Masafumi Moriya
  • Patent number: 5955398
    Abstract: An improved thermally-responsive record material useful for bar coding is disclosed comprising a support having provided thereon in substantially contiguous relationship: a substantially colorless dye precursor comprising 2-anilino-3-methyl-6-dibutylaminofluoran; a sensitizer selected from the group consisting of 1,2-diphenoxyethane and 1,2-(4-methylphenoxy)ethane; an acidic developer material comprising bis-(3-allyl-4-hydroxyphenyl)sulfone which upon being heated reacts with said dye precursor to develop color; and a binder material. The improved thermally-responsive record material and bar code of the invention has a high print contrast signal; high dimensional stability in terms of low bar width growth degradation; a high percentage of successful decodes; and high contrast of the bar code with the background. The invention overcomes difficulties in past efforts to bring together a confluence of these characteristics in one coating formulation.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: September 21, 1999
    Assignee: Appleton Papers Inc.
    Inventors: Mark Robert Fisher, John Charles DeBraal, Joseph Peter Gusse
  • Patent number: 5858583
    Abstract: Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention comprise (a) at least one hexaarylbiimidazole (HABI) compound, (b) at least one leuco dye, (c) at least one acid-generating compound, (d) a polymeric binder, (e) optionally at least one UV stabilizer and/or at least one inhibitor of color formation, and, in certain embodiments, (f) at least one near IR-absorbing dye. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: January 12, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Rolf Dessauer, Jonathan V. Caspar
  • Patent number: 5858913
    Abstract: Receiving element for use according to transfer printing, comprising on a support a receiving layer comprising a silver source, capable of being reduced by means of heat in the presence of a reducing agent, a binder and a stabilizer selected from the group of benzotriazoles, heterocyclic mercaptanes, sulphinic acids, 1,3,4-triazo-indolizines, 1,3-dinitroaryl compounds, 1,2,3-triazoles, phthalic acids and phthalic acid derivatives.The receiving element provides images with higher stability at elevated temperatures and upon exposure to light.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: January 12, 1999
    Assignee: Agfa-Gevaert
    Inventors: Jean-Marie Dewanckele, Geert Defieuw, Marcel Monbaliu, Wilhelmus Janssens
  • Patent number: 5858914
    Abstract: A footwear has a thermochromic coloring color-memory layer having a large hysteresis on a color-density-to-temperature curve so as to show interchangeability between a first color phase and a second color phase different from the first color phase, and a coloring tool for forming a desired image on the footwear.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: January 12, 1999
    Assignee: The Pilot Ink Co., Ltd.
    Inventors: Yutaka Shibahashi, Katsuyuki Fujita, Akio Nakashima
  • Patent number: 5849651
    Abstract: A reversible thermal recording medium comprises a composition containing a color former, a developer, a reversible material capable of reversibly changing the state of the composition by supplying heat energies with two different values, and, as required, a phase separation controller which permits changing the phase separation speed of the developer at temperatures in the vicinity of the melting point of the phase separation controller, at least 80% by weight of the reversible material being a sterol compound in which the carbon-to-carbon bond between 2- and 3-positions of the stroid skeleton is a single bond, the carbon-to-carbon bond between 3- and 4-positions of the steroid skeleton is a single bond, a hydroxyl group is attached to the carbon atom in at least the 3-position of the steroid skeleton, and a specified chemical structure is bonded at 16- and 17-positions of the stroid skeleton, and the phase separation controller being provided by a low molecular organic material, the maximum carbon chain leng
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: December 15, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Satoshi Takayama, Sawako Fujioka, Tetsuo Okuyama, Hideyuki Nishizawa, Hirohisa Miyamoto, Masami Sugiuchi
  • Patent number: 5814579
    Abstract: The invention described in the specification relates to latent image printing and developing systems and to substrates containing latent images. High quality latent images are prepared by a printing method which deposits a layer containing organic-based dye particles and organic-based developer particles, each having a particle size of from about 2 to about 6 microns, on a substrate. The image is then developed by contacting the substantially invisible image of dye and developer particles with an oxygenated solvent from an imaging device. Multicolor, vivid images are obtained as a result of the image printing and developing system of the invention.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: September 29, 1998
    Assignee: The Standard Register Company
    Inventors: Mark D. Dotson, William J. Castle, Bryan A. Netsch
  • Patent number: 5780387
    Abstract: A reversible thermosensitive recording medium includes a support material; a thermosensitive recording layer whose transparency is reversibly changeable depending upon the temperature thereof, which is provided on the support material and includes a low-molecular-weight organic compound and a resin matrix in which the organic low-molecular-weight compound is dispersed; and an overcoat layer provided on the thermosensitive recording layer, the overcoat layer having a pencil hardness of 1H or more and including at the surface thereof at least three protrusions with a height of 0.05 .mu.m or more per area of 125 .mu.m.times.125 .mu.m of the surface of the overcoat layer.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: July 14, 1998
    Assignee: Ricoh Company, Ltd.
    Inventor: Shigeyuki Harada
  • Patent number: 5753588
    Abstract: The present invention provides a heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor, the recording material being characterized in that, the basic dye comprises an indolyldiazaphthalide derivative of the formula (1), and the color acceptor comprises a diphenyl sulfone derivative of the formula (2) and/or a benzanilide derivative of the formula (3) ##STR1## wherein R.sub.1 to R.sub.8 are defined in the specification.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: May 19, 1998
    Assignee: New Oji Paper Company Limited
    Inventors: Takeshi Iida, Tatsuya Meguro, Tetsuo Tsuchida
  • Patent number: 5741752
    Abstract: This invention provides a transparent thermal recording medium, in which the transparent thermal recording medium comprises: a thermal recording layer, which is provided on a transparent layer, consisting essentially of an electron-donating chromophoric compound, an electron-accepting compound and binder resin; and a further-provided protective layer having an approximately equal refractive index to the refractive index of the thermal recording layer, wherein the binder resin is a compound having a group selected from a hydroxyl group and a carboxyl group. The transparent thermal recording medium can be effectively used for a block copy film, on which an image is formed, for plate-making, particularly, in photogravure, offset printing and screen process printing, because the transparent thermal recording medium has a contrast of light transmission factors between a color-imaging portion and a non-imaging portion, in which the contrast is not less than 50% at a wavelength ranging from 370 nm to 450 nm.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 21, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Goto, Hideaki Ema, Kiyoshi Sakai
  • Patent number: 5739078
    Abstract: By using the fluoran compound represented by the following general formula (I); ##STR1## wherein R.sup.1 is alkyl containing 1 to 4 carbon atoms, R.sup.3 is alkyl containing 1 to 8 carbon atoms, R.sup.4 is hydrogen or alkyl containing 1 to 8 carbon atoms, or R.sup.3 and R.sup.4 may bond with each other to form a ring together with a N atom, R.sup.2 is alkyl containing 1 to 4 carbon atoms, and n denotes 0, 1 or 2, however, the substituents represented by R.sup.2 may be different with each other when n is 2, as a color former for color forming recording materials, recording materials which have excellent properties in whiteness of the background of the material under light and in photostability of color-formed images on the materials as well as in sufficient color forming capability of the material even after having exposed them to light, can be provided.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: April 14, 1998
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Mitsuhiro Yanagita, Takehiro Sato, Shigemi Suga, Tomoya Hidaka, Toru Kawabe, Mamoru Aizawa, Shinichi Sato, Izuo Aoki
  • Patent number: 5703006
    Abstract: A thermosensitive recording medium is disclosed which includes a support, and a thermosensitive color-developing layer formed on the support and containing a leuco dye having a melting point of at least 200.degree. C. and a color developer having a melting point of at least 180.degree..
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: December 30, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Yasutomo Mori, Motoi Orihara, Kunihiko Hada, Shuji Miyamoto
  • Patent number: 5691271
    Abstract: The present invention provides novel indolylazaphthalides represented by formula (I) described below. The indolylazaphthalides are useful as electron donative colorless dyes for preparing recording materials. Recording materials containing the novel indolylazaphthalides of formula (I) as electron donative colorless dyes provide images having blue to cyan colors at an excellent density, while suppressing light coloration in non-image areas. ##STR1## wherein R.sup.1 represents a divalent linkage group such as an alkylene group, cycloalkylene group, aralkylene group, or a phenylene group, which linkage group is linked to a bimolecular indolylazaphthalide compound to form a bis-type structure.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: November 25, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Yanagihara, Kiyoshi Takeuchi, Toyohisa Oya, Naoki Asanuma, Masanobu Takashima, Syunsaku Higashi
  • Patent number: 5691272
    Abstract: A heat-sensitive recording material which has a support and a heat-sensitive recording layer containing at least one carboxylate represented by the following formula (1) or (2) ##STR1## wherein a ring X is an aromatic residue which may have a substitute; the other substituents are as defined herein. The heat-sensitive recording material exhibits excellent color image stability and can provide an optically character-readable sharp image.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: November 25, 1997
    Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.
    Inventors: Mansuke Matsumoto, Nobuaki Sasaki, Bunji Sawano, Kiyoharu Hasegawa, Kazuyoshi Kikkawa
  • Patent number: 5679615
    Abstract: A reversible heat-sensitive recording medium which includes at least a support and formed thereon a heat-sensitive recording layer including at least the following components: an electron-donating color-forming compound having a lactone ring, (b) an electron-accepting compound having a phenolic hydroxyl group, (c) at least one organic compound selected from compounds represented by formulae (I) to (V), and (d) a thermoplastic resin having an erasing action. The content of the thermoplastic resin having an erasing action is being from 15 to 70% by weight based on the total amount of components (a) to (d) Formulae (I) to (V) are as follows:R.sub.1 --CO--N(R.sub.2)R.sub.3 (I)R.sub.1 --CO--NH--R.sub.4 --NH--CO--R.sub.2 (II)R.sub.1 --CO--O--R.sub.2 (III)R.sub.1 --NH--CO--NH--R.sub.2 (IV)R.sub.1 --CO--R.sub.2 (V)wherein R.sub.1 represents an alkyl group, an aryl group, an alkenyl group, or a hydroxyalkyl group; R.sub.2 and R.sub.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: October 21, 1997
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Tatsuru Matsumoto, Kenichi Tanaka
  • Patent number: 5668080
    Abstract: A novel thermally-responsive record material is disclosed comprising a support having provided thereon in substantially contiguous relationship an election donating dye precursor and a compound of the formula ##STR1##
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: September 16, 1997
    Assignee: Appleton Papers Inc.
    Inventors: Michael Gerald Cove, Mary Ellen Schulz
  • Patent number: 5643851
    Abstract: A reversible thermosensitive recording label for reversibly forming images and erasing recorded images thereon is composed of a reversible thermosensitive recording member having a temperature-dependent transparency which reversibly changes depending upon the temperature thereof, an adhesive layer provided on the back side of the reversible thermosensitive recording member, and a disposable release sheet applied to the adhesive layer. A reversible thermosensitive recording card is composed of the reversible thermosensitive recording member, the adhesive layer provided on the back side of the reversible thermosensitive recording member, and a label receiving material to which the adhesive layer is applied.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: July 1, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Yukio Konagaya, Takao Igawa, Akihide Ito, Tohru Nogiwa, Tsutomu Kagawa, Nobuo Yamada
  • Patent number: 5641724
    Abstract: This invention generally relates to a reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof which have high light-resisting characteristics, wherein coloring and decolorizing can be repeated suitably.
    Type: Grant
    Filed: September 29, 1995
    Date of Patent: June 24, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Takehito Yamaguchi, Kyoji Tsutsui, Masaru Shimada
  • Patent number: 5627126
    Abstract: A reversible thermosensitive recording medium is composed of a support and a reversible thermosensitive recording layer whose transparency or color reversibly changes by the application of heat thereto formed on the support. The reversible thermosensitive recording layer has a thermal pressure level difference of 40% or less, land a thermal pressure level difference change ratio of 70% or less.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: May 6, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Tetsuya Amano, Yoshihiko Hotta, Makoto Kawaguchi
  • Patent number: RE37034
    Abstract: A reversible thermosensitive recording material is disclosed, which comprises (a) a support, (b) a reversible thermosensitive recording layer formed thereon which comprises as the main components a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and has a temperature-dependent transparency, and (c) an overcoat layer comprising as the main component a resin or an ultraviolet-light-setting resin, formed on the reversible thermosensitive recording layer.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: January 30, 2001
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiko Hotta, Keishi Kubo
  • Patent number: RE35640
    Abstract: A reversible thermosensitive recording material is disclosed, which comprises (i) a reversible thermosensitive recording layer which comprises as the main components a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and (ii) a light reflection layer made of a metal thin film, which is preferably surface-treated to have a specular gloss of 70 to 250% in accordance with JIS Z8741 or a surface roughness of 0.5 to 10 .mu.m in terms of the ten-point average roughness defined in JIS B0601. This reversible thermosensitive recording material may further comprises a crystal-growth controlling agent in the reversible thermosensitive recording layer.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: October 21, 1997
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiko Hotta, Keishi Kubo, Makoto Kawaguchi, Toru Nogiwa