And Identified Color-former Patents (Class 503/217)
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Patent number: 6746985Abstract: A full-color heat-sensitive recording material. At least a heat-sensitive recording layer that color-develops to yellow color; a heat-sensitive recording layer that color-develops to cyan color and a heat-sensitive recording layer that color-develops to magenta color are sequentially provided on a support in this order from the support side. All of the above-mentioned heat-sensitive recording layers contain a diazo compound and/or diazonium salt, and a coupler compound that reacts with the diazo compound and/or diazonium salt for color development.Type: GrantFiled: April 26, 2002Date of Patent: June 8, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Shunsaku Higashi
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Patent number: 6743750Abstract: A heat-sensitive recording material includes, on a support thereof, a heat-sensitive recording layer containing a diazo compound and a coupler.Type: GrantFiled: November 13, 2001Date of Patent: June 1, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisato Nagase, Yoshihiro Jimbo
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Patent number: 6693061Abstract: A light-permeable thermosensitive recording material having a light permeable support and a thermosensitive recording layer formed thereon and including a leuco dye, a color developer for the leuco dye, and a binder resin, wherein the developer is a compound represented by the following formula (1): wherein R1 represents an alkyl group having 4-16 carbon atoms or an aminoalkyl group having 4-16 carbon atoms.Type: GrantFiled: November 21, 2001Date of Patent: February 17, 2004Assignee: Ricoh Company, Ltd.Inventors: Hitoshi Shimbo, Hideo Suzaki, Masafumi Torii, Masaru Shimada
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Patent number: 6677275Abstract: A thermally recording sheet which has high sensitivity in color development, satisfactory background heat resistance, and a satisfactory background color. The sheet contains a dihydroxydiphenylsulfone compound represented by general formula (1) as a color developer and a sulfonamide represented by general formula (2). In the formula, R1 and R2 each represents C1-8 alkyl, alkenyl, or halogeno; and a and b each is an integer of 0 to 3. In the formula, R3 represents C1-66 alkyl or electron-attracting group; and n is an integer of 0 to 2.Type: GrantFiled: October 31, 2000Date of Patent: January 13, 2004Assignee: Nippon Paper Industries Co., Ltd.Inventors: Yoshimi Midorikawa, Naomi Sumikawa, Kaoru Hamada, Yoshihide Kimura, Toshio Kaneko
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Patent number: 6645909Abstract: A process for an azo coupling reaction is provided that has a large coupling reaction rate and an excellent coloring density and exerts high coupling activity using a stable coupler, and a recording material containing the coupler is provided. The process for an azo coupling reaction comprises carrying out a coupling reaction of a diazonium salt and a coupler to make the diazonium salt form color, and the coupler has certain specified structures.Type: GrantFiled: October 26, 2001Date of Patent: November 11, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Akinori Fujita, Tetsunori Matsushita
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Publication number: 20030166467Abstract: A reversible thermal recording material permits recording having a clear contrast at a high sensitivity and erasing such images a number of times, at least 1,000 times, repetitively, and comprises a leuco dye, a reversible developer and a light-heat-converting dye, the light-heat-converting dye having a deterioration ratio of 20% or less when a laser beam having an oscillation wavelength of 830 nm is applied thereto repeatedly 1000 times at a temperature of 25° C. at an energy of 2 J/cm2 or being a phthalocyanine compound having a vanadyl group, and a method of recording an image comprises applying a laser beam to the reversible thermal recording material, wherein the colored leuco dye is achromatized with energy that is 25 to 65% of the energy of the laser beam employed for causing the leuco dye to develop a color.Type: ApplicationFiled: February 11, 2003Publication date: September 4, 2003Inventor: Yoichiro Azuma
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Patent number: 6613716Abstract: A coating composition is applied to a print stock substrate for preparing a thermally-active layer, the coating composition comprising: a developer comprising at least one or a combination of 6′-dipentylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 129473-78-5) and 6′-dibutylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 89331-94-2); a sensitizer comprising at least one or a combination of 1,1′-sulfonylbisbenzene (CAS No. 127-63-9) and dimethylterephthalate (CAS No. 120-61-6); and a coreactant (or developer) comprising at least one or a combination of bis(4-hydroxyphenyl)-4-methylpentane (CAS No. 6807-17-6) and 4-hydroxy-4′-isopropoxydiphenylsulfone (CAS No. 95235-30-6). Preferably, the print stock substrate will be coated with clay or the like to provide a smooth coating surface for the thermally-active layer.Type: GrantFiled: March 28, 2001Date of Patent: September 2, 2003Assignee: Miami Wabash Paper LLCInventors: Eugene V. Hoefs, Regina A. Kleinhenz
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Publication number: 20030158038Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance.Type: ApplicationFiled: January 9, 2003Publication date: August 21, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
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Publication number: 20030104939Abstract: A full-color heat-sensitive recording material. At least a heat-sensitive recording layer that color-develops to yellow color; a heat-sensitive recording layer that color-develops to cyan color and a heat-sensitive recording layer that color-develops to magenta color are sequentially provided on a support in this order from the support side. All of the above-mentioned heat-sensitive recording layers contain a diazo compound and/or diazonium salt, and a coupler compound that reacts with the diazo compound and/or diazonium salt for color development.Type: ApplicationFiled: April 26, 2002Publication date: June 5, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Shunsaku Higashi
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Patent number: 6551961Abstract: A thermal recording material which has high sensitivity in color development and a high whiteness of the background and is excellent in image retention and heat resistance. The thermal recording material contains a dihydroxydiphenylsulfon compound represented by general formula (1) as an organic color developer and 3-di-n-pentylamino-6-methyl-7-anilinofluoran as a colorless basic dye. (In the formula, R1 and R2 each represents C1-8 alkyl, alkenyl, or halogeno; and p and q each is an integer of 0 to 3.Type: GrantFiled: October 31, 2000Date of Patent: April 22, 2003Assignee: Nippon Paper Industries Co LtdInventors: Yoshimi Midorikawa, Naomi Sumikawa, Kaoru Hamada, Yoshihide Kimura
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Publication number: 20030045426Abstract: The present invention discloses a heat-sensitive recording material comprising a thermal recording layer disposed on a substrate which layer contains at least a diazonium salt compound and a coupler which has a coupling reaction with the diazonium salt compound to develop a color, wherein the thermal recording layer microcapsules, which encapsulate the diazonium salt compound, an aromatic carboxylate represented by the following general formula (I) and an aromatic carboxylate represented by the following general formula (II).Type: ApplicationFiled: June 13, 2002Publication date: March 6, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Koreshige Ito
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Publication number: 20030036478Abstract: Disclosed is a heat-sensitive recording material comprising a support and a heat-sensitive recording layer formed on the support and containing a leuco dye, a developer and a binder, wherein the heat-sensitive recording material uses as the developer at least two hydroxy-diphenylsulfone compounds such as 4-hydroxy-4′-isopropoxy-diphenylsulfone, 2,4′-dihydroxy-diphenylsulfone and the like, and uses as the leuco dye a black-color-forming leuco dye such as 3-di(n-butyl)amino-6-methyl-7-anilinofluoran or the like and 0.5 to 3.5 wt. %, relative to the black-color-forming leuco dye, of a red-color-forming leuco dye such as 3-diethylamino-7-chlorofluoran or the like.Type: ApplicationFiled: August 20, 2002Publication date: February 20, 2003Inventors: Shigetoshi Seki, Toshiro Hata
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Publication number: 20020183203Abstract: A coating composition is applied to a print stock substrate for preparing a thermally-active layer, the coating composition comprising: a developer comprising at least one or a combination of 6′-dipentylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 129473-78-5) and 6′-dibutylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 89331-94-2); a sensitizer comprising at least one or a combination of 1,1′-sulfonylbisbenzene (CAS No. 127-63-9) and dimethylterephthalate (CAS No. 120-61-6); and a coreactant (or developer) comprising at least one or a combination of bis(4-hydroxyphenyl)-4-methylpentane (CAS No. 6807-17-6) and 4-hydroxy-4′-isopropoxydiphenylsulfone (CAS No. 95235-30-6). Preferably, the print stock substrate will be coated with clay or the like to provide a smooth coating surface for the thermally-active layer.Type: ApplicationFiled: March 28, 2001Publication date: December 5, 2002Inventors: Eugene V. Hoefs, Regina A. Kleinhenz
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Publication number: 20020183204Abstract: The present invention provides a diazonium salt represented by the following general formula (1) wherein R1 represents a branched alkyl group; R2 and R3separately represent an alkyl group and may bond to each other to form a ring; R4, R5, and R6 separately represent a hydrogen atom, an alkyl group, or an aryl group and R4 and R5 may bond to each other to form a ring; and X— represents an anion and a heat-sensitive recording material comprising a heat-sensitive recording layer including the diazonium salt and a coupler.Type: ApplicationFiled: April 26, 2002Publication date: December 5, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Kimiatsu Nomura, Tatsuo Kawabuchi, Hisato Nagase, Satoshi Higuchi, Kimi Ikeda, Yoshihiro Jinbo
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Publication number: 20020107145Abstract: A reversible thermosensitive recording material including: a substrate; a recording layer located overlying the substrate and including a crosslinked resin, an electron donating coloring agent and an electron accepting coloring developer; and a protective layer located overlying the recording layer and including a filler and a crosslinked resin, wherein the recording layer achieves a colored state or a non-colored state when appropriately heating and cooling the recording layer, and wherein the reversible thermosensitive recording material has a surface having at least one of a ten-point mean roughness (Rz) not less than 1.5 &mgr;m or a ratio Sm/Rz not greater than 120, wherein Sm represents an average peak-to-peak length of the surface of the recording material.Type: ApplicationFiled: November 30, 2001Publication date: August 8, 2002Inventors: Kazumi Suzuki, Toshihiko Hotta, Tetsuya Amano, Satoru Sanpei
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Publication number: 20020077252Abstract: A process for an azo coupling reaction is provided that has a large coupling reaction rate and an excellent coloring density and exerts high coupling activity using a stable coupler, and a recording material containing the coupler is provided. The process for an azo coupling reaction comprises carrying out a coupling reaction of a diazonium salt and a coupler to make the diazonium salt form color, and the coupler has certain specified structures.Type: ApplicationFiled: October 26, 2001Publication date: June 20, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Akinori Fujita, Tetsunori Matsushita
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Patent number: 6407034Abstract: A thermally printable thermoplastic media includes a thermoplastic material having a thermally activated composition incorporated therein. The thermally activated composition includes a leuco-dye, a color developer, and a reaction promoter. The printable media preferably has a thickness of from about 0.5 to about 1.5 mils to provide a roll with a longer length than a conventional paper roll, thereby increasing the amount of printable media which can be contained on a roll. The thermally printable thermoplastic media is manufactured by combining a thermoplastic material and a thermally activated composition, melting the combined thermoplastic material and thermally activated composition and forming a film from the combined thermoplastic material and thermally activated composition, typically by extrusion. To prevent pre-imaging or initiation of a thermo-chromogenic reaction from the heat involved in extrusion, the extrusion is preferably carried out in an oxygen-free environment.Type: GrantFiled: September 13, 1999Date of Patent: June 18, 2002Inventor: William D. Ewing
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Publication number: 20020065194Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance.Type: ApplicationFiled: July 19, 2001Publication date: May 30, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
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Patent number: 6348432Abstract: Disclosed are heat sensitive coatings and record materials that are environmentally resistant and therefore do not require a protective coating. One embodiment includes an environmentally resistant heat sensitive coating that includes an acrylate polymer of the formula: wherein R1 is a hydrogen or a methyl group, R2 is a hydrogen or a methyl group, and R3 is nitrile or chlorine or wherein, when c is 0, R4 is methyl, phenyl, or substituted phenyl, and when c is greater than 0, R4 is methyl, phenyl, substituted phenyl, halogen, nitrile or hydroxyl; m is greater than 1; n is greater than 1; b is greater than or equal to 0; and c is an integer from 0 to 38.Type: GrantFiled: March 10, 2000Date of Patent: February 19, 2002Assignee: Nashua CorporationInventor: Mohamed Elmasry
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Patent number: 6284706Abstract: The thermally sensitive recording medium having sufficient color developing density and develops sepia color or light brown color. The color difference a* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 is within the region of 0˜40 and b* value is within the region of 0˜55.Type: GrantFiled: May 19, 1999Date of Patent: September 4, 2001Assignee: Nippon Paper Industries Co LtdInventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
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Patent number: 6284707Abstract: The thermally sensitive recording medium having sufficient color developing density and develops navy blue or grayish blue color. The color difference L* value a* value and b* value of developed image of said thermally sensitive recording medium regulated by JIS-Z-8729 are within the regions of, A. L* value is 30˜50, a* value is −15˜0 and b* value is −30˜10, B. L* value is 30˜50, a* value is 0˜10 and b* value is −30˜0 or C. L* value is 30˜50, a* value is 10˜20 and b* value is −30˜15.Type: GrantFiled: June 30, 1999Date of Patent: September 4, 2001Assignee: Nopon Paper Industries Co LtdInventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
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Patent number: 6258747Abstract: A thermally sensitive recording medium having sufficient color developing density and which develops russet or wine red color. The recording medium incorporates a dye precursor which includes at least one red color developing leuco dye having a maximum absorption wavelength of 480 to 570 nm and at least one black color developing leuco dye with maximum absorption wavelengths at 420 to 480 nm and 550 to 640 nm. The color difference a* value of developed image of said thermally sensitive recording medium, measured according to JIS-Z-8729 is within the region of 0 to 50 and b* value is within the region of −15 to 10.Type: GrantFiled: June 16, 1999Date of Patent: July 10, 2001Assignee: Nippon Paper Industries Co LtdInventors: Yoshimi Midorikawa, Kaoru Hamada, Yoshihide Kimura, Tomoaki Nagai
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Patent number: 6214766Abstract: Authenticatable paper and paperboard products are prepared by printing images such as microdots on one or both surfaces of the paper using a starch containing authenticating solution. The images are not detectable by the human eye, but can be revealed with the application of a standard iodine solution.Type: GrantFiled: February 3, 1999Date of Patent: April 10, 2001Assignee: Westvaco CorporationInventor: Frederick L. Kurrle
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Patent number: 6202926Abstract: A magnetic recording medium, and methods of making and reading the same, including on at least a portion of a substrate an irreversible recording layer which contains an irreversible recording material undergoing an irreversible change of saturation magnetization upon heating. The invention involves the steps of previously heating the irreversible recording layer to form an initial heated region in which a plurality of heated bars whose saturation magnetization has been irreversibly changed are arrayed in a bar code pattern, and converting unheated bars disposed between the heated bars into a heated state for changing the array pattern of heated bars, thereby recording the information.Type: GrantFiled: February 4, 1999Date of Patent: March 20, 2001Assignees: Tokyo Magnetic Printing Co., Ltd., TDK CorporationInventors: Masahiro Ito, Shohei Mimura, Masao Shigeta, Tsutomu Chou
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Patent number: 6197725Abstract: There is provided a coupler giving a magenta pigment excellent in hue using a diazonium salt compound which can be fixed at a wavelength around 420 nm.Type: GrantFiled: December 1, 1998Date of Patent: March 6, 2001Assignee: Fuji Photo Film Co., Ltd.Inventors: Atsuhiro Ohkawa, Hisao Yamada
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Patent number: 6124377Abstract: A marking system that advantageously minimizes messiness during use is disclosed. The marking system comprises a marking composition comprising at least one color precursor in the form of a leuco dye. A marking instrument can be utilized to store the marking composition and/or apply the marking composition to a desired substrate. The substrate is provided with a coating comprising at least one color-triggering developer. Upon application of the leuco dye to the substrate, a chromophore, and hence, color, is formed. If, however, color is inadvertently triggered on an unintended surface, thereby resulting in an unwanted stain, the stain can be readily removed.Type: GrantFiled: July 1, 1998Date of Patent: September 26, 2000Assignee: Binney & Smith Inc.Inventors: Richard J. Kaiser, Arthur N. Urbanski
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Patent number: 6093678Abstract: A thermal sensitive recording medium which has a feature to change the color of recorded pattern slowly and spontaneously after development, and the recorded pattern which has several days passed can be easily distinguished from that of just after development. Said thermal sensitive recording medium contains 4-hydroxybenzoic acid ester represented by general formula (I) as a color developer and uses triphenylmethane-based leuco dye and reddish color developing leuco dye whose maximum absorption wave length is 450.about.560 nm as a dye precursor. ##STR1## In this formula, R represents unsubstituted or substituted lower alkyl group of carbon number 1-7 or benzyl group.Type: GrantFiled: August 18, 1998Date of Patent: July 25, 2000Assignee: Nippon Paper Industries Co. Ltd.Inventors: Kaoru Hamada, Tadakazu Fukuchi, Tomoaki Nagai, Reiko Sato, Yutaka Wakita
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Patent number: 6090748Abstract: A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording material has an image density retention not less than about 60% when the recording material having an image is allowed to settle in a dry place at 50.degree. C. for 24 hours, a residual image density not greater than about 0.03 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image, and a residual image density after light irradiation not greater than about 0.04 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image after light of 5,000 lux is irradiated to the recording material for 100 hours.Type: GrantFiled: June 25, 1998Date of Patent: July 18, 2000Assignee: Ricoh Company, Ltd.Inventors: Hiromi Furuya, Tadafumi Tatewaki, Masafumi Torii, Fumio Kawamura, Hiroaki Matsui, Masaru Shimada, Kyoji Tsutsui
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Patent number: 5977020Abstract: A thermosensitive reversible recording material capable of forming and holding clear colored images with a high contrast and capable of being repeatedly color-developed and color-erased many times, has a thermosensitive recording layer formed on substrate sheet and including (A) at least one reversibly color-developing and -erasing compound selected from those of the formulae (I), (II) and (III), and (B) at least one dye precursor compound of the formula (IV). ##STR1## R.sup.1 =naphyl or lower alkoxy-substituted phenyl group Y.sup.1, Y.sup.2 =--NHCO--, --SCONH--, --CONHCO--, etc., n, m, p=10 to 29, R.sup.2, R.sup.3, R.sup.4, R.sup.5 =C.sub.1 -C.sub.9 alkyl, C.sub.3 -C.sub.6 cycloalkyl or substituted or non-substituted phenyl group, R.sup.6, R.sup.7 =C.sub.1 -C.sub.6 alkyl or phenyl group.Type: GrantFiled: July 13, 1998Date of Patent: November 2, 1999Assignee: Oji Paper Co., Ltd.Inventors: Makoto Nishioka, Kazuo Yamane
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Patent number: 5955225Abstract: A reversible thermosensitive composition including a coloring agent and a developer and capable of assuming a colored state and a discolored state depending upon the thermal hysteresis thereof. The developer is a phenol compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.3 represent, independently from each other, a substituted or non-substituted hydrocarbon group, R.sup.2 represents a substituted or non-substituted aliphatic hydrocarbon group having at least two carbon atoms, with the proviso that the total number of carbon atoms of R.sup.1, R.sup.2 and R.sup.3 is at least 8, X and Y represent, independently from each other, a divalent group having a nitrogen atom or an oxygen atom and r is an integer of between 1 and 3.Type: GrantFiled: June 6, 1997Date of Patent: September 21, 1999Assignee: Ricoh Company Ltd.Inventors: Hiromi Furuya, Masafumi Torii, Masaru Shimada, Fumio Kawamura, Kyoji Tsutsui, Katsushi Sugiyama, Katsuaki Kokubo, Katsuhisa Kamio, Kazuo Hosoda, Masafumi Moriya
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Patent number: 5955398Abstract: An improved thermally-responsive record material useful for bar coding is disclosed comprising a support having provided thereon in substantially contiguous relationship: a substantially colorless dye precursor comprising 2-anilino-3-methyl-6-dibutylaminofluoran; a sensitizer selected from the group consisting of 1,2-diphenoxyethane and 1,2-(4-methylphenoxy)ethane; an acidic developer material comprising bis-(3-allyl-4-hydroxyphenyl)sulfone which upon being heated reacts with said dye precursor to develop color; and a binder material. The improved thermally-responsive record material and bar code of the invention has a high print contrast signal; high dimensional stability in terms of low bar width growth degradation; a high percentage of successful decodes; and high contrast of the bar code with the background. The invention overcomes difficulties in past efforts to bring together a confluence of these characteristics in one coating formulation.Type: GrantFiled: April 25, 1997Date of Patent: September 21, 1999Assignee: Appleton Papers Inc.Inventors: Mark Robert Fisher, John Charles DeBraal, Joseph Peter Gusse
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Patent number: 5858583Abstract: Novel thermally imageable monochrome product compositions, elements, and processes are disclosed herein. These compositions and elements characteristically have high contrast and fast imaging speeds. The thermally imageable compositions of this invention comprise (a) at least one hexaarylbiimidazole (HABI) compound, (b) at least one leuco dye, (c) at least one acid-generating compound, (d) a polymeric binder, (e) optionally at least one UV stabilizer and/or at least one inhibitor of color formation, and, in certain embodiments, (f) at least one near IR-absorbing dye. These compositions have the propensity for affording, upon thermal imaging, highly colored images having high optical density values. At the same time, background color is low in preferred compositions even after extensive exposure to ambient light. These compositions can be imagewise heated to effect color formation (i.e.Type: GrantFiled: July 3, 1997Date of Patent: January 12, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Rolf Dessauer, Jonathan V. Caspar
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Patent number: 5858913Abstract: Receiving element for use according to transfer printing, comprising on a support a receiving layer comprising a silver source, capable of being reduced by means of heat in the presence of a reducing agent, a binder and a stabilizer selected from the group of benzotriazoles, heterocyclic mercaptanes, sulphinic acids, 1,3,4-triazo-indolizines, 1,3-dinitroaryl compounds, 1,2,3-triazoles, phthalic acids and phthalic acid derivatives.The receiving element provides images with higher stability at elevated temperatures and upon exposure to light.Type: GrantFiled: October 13, 1995Date of Patent: January 12, 1999Assignee: Agfa-GevaertInventors: Jean-Marie Dewanckele, Geert Defieuw, Marcel Monbaliu, Wilhelmus Janssens
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Patent number: 5858914Abstract: A footwear has a thermochromic coloring color-memory layer having a large hysteresis on a color-density-to-temperature curve so as to show interchangeability between a first color phase and a second color phase different from the first color phase, and a coloring tool for forming a desired image on the footwear.Type: GrantFiled: June 24, 1996Date of Patent: January 12, 1999Assignee: The Pilot Ink Co., Ltd.Inventors: Yutaka Shibahashi, Katsuyuki Fujita, Akio Nakashima
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Patent number: 5849651Abstract: A reversible thermal recording medium comprises a composition containing a color former, a developer, a reversible material capable of reversibly changing the state of the composition by supplying heat energies with two different values, and, as required, a phase separation controller which permits changing the phase separation speed of the developer at temperatures in the vicinity of the melting point of the phase separation controller, at least 80% by weight of the reversible material being a sterol compound in which the carbon-to-carbon bond between 2- and 3-positions of the stroid skeleton is a single bond, the carbon-to-carbon bond between 3- and 4-positions of the steroid skeleton is a single bond, a hydroxyl group is attached to the carbon atom in at least the 3-position of the steroid skeleton, and a specified chemical structure is bonded at 16- and 17-positions of the stroid skeleton, and the phase separation controller being provided by a low molecular organic material, the maximum carbon chain lengType: GrantFiled: May 31, 1996Date of Patent: December 15, 1998Assignee: Kabushiki Kaisha ToshibaInventors: Satoshi Takayama, Sawako Fujioka, Tetsuo Okuyama, Hideyuki Nishizawa, Hirohisa Miyamoto, Masami Sugiuchi
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Patent number: 5814579Abstract: The invention described in the specification relates to latent image printing and developing systems and to substrates containing latent images. High quality latent images are prepared by a printing method which deposits a layer containing organic-based dye particles and organic-based developer particles, each having a particle size of from about 2 to about 6 microns, on a substrate. The image is then developed by contacting the substantially invisible image of dye and developer particles with an oxygenated solvent from an imaging device. Multicolor, vivid images are obtained as a result of the image printing and developing system of the invention.Type: GrantFiled: August 6, 1996Date of Patent: September 29, 1998Assignee: The Standard Register CompanyInventors: Mark D. Dotson, William J. Castle, Bryan A. Netsch
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Patent number: 5780387Abstract: A reversible thermosensitive recording medium includes a support material; a thermosensitive recording layer whose transparency is reversibly changeable depending upon the temperature thereof, which is provided on the support material and includes a low-molecular-weight organic compound and a resin matrix in which the organic low-molecular-weight compound is dispersed; and an overcoat layer provided on the thermosensitive recording layer, the overcoat layer having a pencil hardness of 1H or more and including at the surface thereof at least three protrusions with a height of 0.05 .mu.m or more per area of 125 .mu.m.times.125 .mu.m of the surface of the overcoat layer.Type: GrantFiled: August 22, 1996Date of Patent: July 14, 1998Assignee: Ricoh Company, Ltd.Inventor: Shigeyuki Harada
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Patent number: 5753588Abstract: The present invention provides a heat sensitive recording material comprising a substrate and a recording layer thereon incorporating a colorless or light-colored basic dye and a color acceptor, the recording material being characterized in that, the basic dye comprises an indolyldiazaphthalide derivative of the formula (1), and the color acceptor comprises a diphenyl sulfone derivative of the formula (2) and/or a benzanilide derivative of the formula (3) ##STR1## wherein R.sub.1 to R.sub.8 are defined in the specification.Type: GrantFiled: July 25, 1996Date of Patent: May 19, 1998Assignee: New Oji Paper Company LimitedInventors: Takeshi Iida, Tatsuya Meguro, Tetsuo Tsuchida
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Patent number: 5741752Abstract: This invention provides a transparent thermal recording medium, in which the transparent thermal recording medium comprises: a thermal recording layer, which is provided on a transparent layer, consisting essentially of an electron-donating chromophoric compound, an electron-accepting compound and binder resin; and a further-provided protective layer having an approximately equal refractive index to the refractive index of the thermal recording layer, wherein the binder resin is a compound having a group selected from a hydroxyl group and a carboxyl group. The transparent thermal recording medium can be effectively used for a block copy film, on which an image is formed, for plate-making, particularly, in photogravure, offset printing and screen process printing, because the transparent thermal recording medium has a contrast of light transmission factors between a color-imaging portion and a non-imaging portion, in which the contrast is not less than 50% at a wavelength ranging from 370 nm to 450 nm.Type: GrantFiled: June 7, 1995Date of Patent: April 21, 1998Assignee: Ricoh Company, Ltd.Inventors: Hiroshi Goto, Hideaki Ema, Kiyoshi Sakai
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Patent number: 5739078Abstract: By using the fluoran compound represented by the following general formula (I); ##STR1## wherein R.sup.1 is alkyl containing 1 to 4 carbon atoms, R.sup.3 is alkyl containing 1 to 8 carbon atoms, R.sup.4 is hydrogen or alkyl containing 1 to 8 carbon atoms, or R.sup.3 and R.sup.4 may bond with each other to form a ring together with a N atom, R.sup.2 is alkyl containing 1 to 4 carbon atoms, and n denotes 0, 1 or 2, however, the substituents represented by R.sup.2 may be different with each other when n is 2, as a color former for color forming recording materials, recording materials which have excellent properties in whiteness of the background of the material under light and in photostability of color-formed images on the materials as well as in sufficient color forming capability of the material even after having exposed them to light, can be provided.Type: GrantFiled: August 22, 1996Date of Patent: April 14, 1998Assignee: Nippon Soda Co., Ltd.Inventors: Mitsuhiro Yanagita, Takehiro Sato, Shigemi Suga, Tomoya Hidaka, Toru Kawabe, Mamoru Aizawa, Shinichi Sato, Izuo Aoki
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Patent number: 5703006Abstract: A thermosensitive recording medium is disclosed which includes a support, and a thermosensitive color-developing layer formed on the support and containing a leuco dye having a melting point of at least 200.degree. C. and a color developer having a melting point of at least 180.degree..Type: GrantFiled: January 11, 1996Date of Patent: December 30, 1997Assignee: Ricoh Company, Ltd.Inventors: Yasutomo Mori, Motoi Orihara, Kunihiko Hada, Shuji Miyamoto
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Patent number: 5691271Abstract: The present invention provides novel indolylazaphthalides represented by formula (I) described below. The indolylazaphthalides are useful as electron donative colorless dyes for preparing recording materials. Recording materials containing the novel indolylazaphthalides of formula (I) as electron donative colorless dyes provide images having blue to cyan colors at an excellent density, while suppressing light coloration in non-image areas. ##STR1## wherein R.sup.1 represents a divalent linkage group such as an alkylene group, cycloalkylene group, aralkylene group, or a phenylene group, which linkage group is linked to a bimolecular indolylazaphthalide compound to form a bis-type structure.Type: GrantFiled: May 16, 1996Date of Patent: November 25, 1997Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Yanagihara, Kiyoshi Takeuchi, Toyohisa Oya, Naoki Asanuma, Masanobu Takashima, Syunsaku Higashi
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Patent number: 5691272Abstract: A heat-sensitive recording material which has a support and a heat-sensitive recording layer containing at least one carboxylate represented by the following formula (1) or (2) ##STR1## wherein a ring X is an aromatic residue which may have a substitute; the other substituents are as defined herein. The heat-sensitive recording material exhibits excellent color image stability and can provide an optically character-readable sharp image.Type: GrantFiled: August 14, 1996Date of Patent: November 25, 1997Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals, Inc.Inventors: Mansuke Matsumoto, Nobuaki Sasaki, Bunji Sawano, Kiyoharu Hasegawa, Kazuyoshi Kikkawa
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Patent number: 5679615Abstract: A reversible heat-sensitive recording medium which includes at least a support and formed thereon a heat-sensitive recording layer including at least the following components: an electron-donating color-forming compound having a lactone ring, (b) an electron-accepting compound having a phenolic hydroxyl group, (c) at least one organic compound selected from compounds represented by formulae (I) to (V), and (d) a thermoplastic resin having an erasing action. The content of the thermoplastic resin having an erasing action is being from 15 to 70% by weight based on the total amount of components (a) to (d) Formulae (I) to (V) are as follows:R.sub.1 --CO--N(R.sub.2)R.sub.3 (I)R.sub.1 --CO--NH--R.sub.4 --NH--CO--R.sub.2 (II)R.sub.1 --CO--O--R.sub.2 (III)R.sub.1 --NH--CO--NH--R.sub.2 (IV)R.sub.1 --CO--R.sub.2 (V)wherein R.sub.1 represents an alkyl group, an aryl group, an alkenyl group, or a hydroxyalkyl group; R.sub.2 and R.sub.Type: GrantFiled: September 13, 1995Date of Patent: October 21, 1997Assignee: Tomoegawa Paper Co., Ltd.Inventors: Tatsuru Matsumoto, Kenichi Tanaka
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Patent number: 5668080Abstract: A novel thermally-responsive record material is disclosed comprising a support having provided thereon in substantially contiguous relationship an election donating dye precursor and a compound of the formula ##STR1##Type: GrantFiled: December 3, 1996Date of Patent: September 16, 1997Assignee: Appleton Papers Inc.Inventors: Michael Gerald Cove, Mary Ellen Schulz
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Patent number: 5643851Abstract: A reversible thermosensitive recording label for reversibly forming images and erasing recorded images thereon is composed of a reversible thermosensitive recording member having a temperature-dependent transparency which reversibly changes depending upon the temperature thereof, an adhesive layer provided on the back side of the reversible thermosensitive recording member, and a disposable release sheet applied to the adhesive layer. A reversible thermosensitive recording card is composed of the reversible thermosensitive recording member, the adhesive layer provided on the back side of the reversible thermosensitive recording member, and a label receiving material to which the adhesive layer is applied.Type: GrantFiled: December 5, 1994Date of Patent: July 1, 1997Assignee: Ricoh Company, Ltd.Inventors: Yukio Konagaya, Takao Igawa, Akihide Ito, Tohru Nogiwa, Tsutomu Kagawa, Nobuo Yamada
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Reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof
Patent number: 5641724Abstract: This invention generally relates to a reversible thermosensitive coloring composition and a thermosensitive recording medium using thereof which have high light-resisting characteristics, wherein coloring and decolorizing can be repeated suitably.Type: GrantFiled: September 29, 1995Date of Patent: June 24, 1997Assignee: Ricoh Company, Ltd.Inventors: Takehito Yamaguchi, Kyoji Tsutsui, Masaru Shimada -
Patent number: 5627126Abstract: A reversible thermosensitive recording medium is composed of a support and a reversible thermosensitive recording layer whose transparency or color reversibly changes by the application of heat thereto formed on the support. The reversible thermosensitive recording layer has a thermal pressure level difference of 40% or less, land a thermal pressure level difference change ratio of 70% or less.Type: GrantFiled: July 6, 1994Date of Patent: May 6, 1997Assignee: Ricoh Company, Ltd.Inventors: Tetsuya Amano, Yoshihiko Hotta, Makoto Kawaguchi
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Patent number: RE37034Abstract: A reversible thermosensitive recording material is disclosed, which comprises (a) a support, (b) a reversible thermosensitive recording layer formed thereon which comprises as the main components a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and has a temperature-dependent transparency, and (c) an overcoat layer comprising as the main component a resin or an ultraviolet-light-setting resin, formed on the reversible thermosensitive recording layer.Type: GrantFiled: April 25, 1994Date of Patent: January 30, 2001Assignee: Ricoh Company, Ltd.Inventors: Yoshihiko Hotta, Keishi Kubo
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Patent number: RE35640Abstract: A reversible thermosensitive recording material is disclosed, which comprises (i) a reversible thermosensitive recording layer which comprises as the main components a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, and (ii) a light reflection layer made of a metal thin film, which is preferably surface-treated to have a specular gloss of 70 to 250% in accordance with JIS Z8741 or a surface roughness of 0.5 to 10 .mu.m in terms of the ten-point average roughness defined in JIS B0601. This reversible thermosensitive recording material may further comprises a crystal-growth controlling agent in the reversible thermosensitive recording layer.Type: GrantFiled: February 14, 1994Date of Patent: October 21, 1997Assignee: Ricoh Company, Ltd.Inventors: Yoshihiko Hotta, Keishi Kubo, Makoto Kawaguchi, Toru Nogiwa