Benzene Ring Attached Directly Or Indirectly To Urea Or Thiourea Nitrogen By Nonionic Bonding Patents (Class 504/330)
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Patent number: 11459410Abstract: The present invention provides a high-purity arylsulfonic acid amine salt vinyl monomer which is an extremely industrially useful arylsulfonic acid monomer with excellent storage stability and amphiphilic solubility in both water and organic solvents, a simple and practical method for producing the same, a polyarylsulfonic acid amine salt which is a polymer thereof, and a method for producing the same. In the arylsulfonic acid amine salt vinyl monomer, a tertiary amine having 2 or 3 different substituents that each have 1 to 7 carbon atoms and also containing at least one or more of tertiary carbon or quaternary carbon or cyclic skeleton in the structure is applied to an amine moiety thereof, and in addition, a polyarylsulfonic acid amine salt having high purity in terms of sulfonation rate and polymerization conversion rate and a polymer thereof are used.Type: GrantFiled: August 6, 2018Date of Patent: October 4, 2022Assignee: TOSOH FINECHEM CORPORATIONInventors: Yusuke Shigeta, Shinji Ozoe, Akihiro Fuji
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Publication number: 20150099635Abstract: An agricultural oil-based suspension formulation comprising an active ingredient suspended in finely divided form in an oil and at least one unsaturated rubber-type copolymer or a mixture thereof, wherein the rubber-type copolymer comprises at least styrene as a residue.Type: ApplicationFiled: June 8, 2012Publication date: April 9, 2015Inventors: Andrew David Holliday, Dilek Saylik, Rowan Brown, Karen Vab Der Sande, Andrew F. Kirby, Robert E. Bohun
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Publication number: 20140206542Abstract: An agricultural oil-based suspension formulation comprising an active ingredient suspended in finely divided form in an oil; and at least one surfactant selected from a polyalkylene glycol-fatty acid condensate or a polyalkylene glycolether fatty acid condensate formed from a reaction between a compound having Structure (1) and a compound having Structure (2): wherein R1=H or a C1-C30 alkyl radical; A and B are ethylene or propylene groups in succession or random; n=0 or >1; and m=0 or >1, and wherein n+m>34; R2=C8-C30 alkyl or alkylene radical (branched or linear); and x=>1.Type: ApplicationFiled: June 8, 2012Publication date: July 24, 2014Applicant: Huntsman Corporation Australia Pty LimitedInventors: Keith Moody, Dilek Saylik, Rowan Brown
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Publication number: 20130172190Abstract: Agrochemical concentrates having a continuous water-containing single phase, where said continuous phase also comprises an oil-based adjuvant and a hydrotrope capable of solubilising said adjuvant in said continuous phase, a process for making these concentrates and a method of using these concentrates.Type: ApplicationFiled: July 2, 2012Publication date: July 4, 2013Applicant: Syngenta Crop Protection LLCInventors: Gordon Alastair Bell, Guy Ramsay
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Publication number: 20130130909Abstract: Provided herein are exemplary methods for controlling a density of algae growing in an aquatic environment. Some exemplary methods include applying an effective amount of 3-(3,4-dichlorophenyl)-1,1-dimethylurea (DCMU) to the density of algae growing in the aquatic environment, wherein the algae includes genus Nannochloropsis. The algae may also include algae of genus Tetraselmis and/or genus Chlorella. Applying the effective amount may result in an approximate concentration of between 100 nanomolar to 1500 nanomolar DCMU in the aquatic environment. Further, the aquatic environment may include seawater, freshwater, or mixtures thereof.Type: ApplicationFiled: June 7, 2012Publication date: May 23, 2013Inventors: Bertrand Vick, Shaun Bailey
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Patent number: 8383548Abstract: The present invention is directed to a composition comprising i) a microencapsulated pesticide, ii) a dispersant selected from the group consisting of a lignin, b) a lignosulfonate salt and c) a lignosulfonate salt combined with the sodium salt of substituted naphthalene sulfonate formaldehyde polymer, iii) a salt selected from the group consisting of magnesium sulfate, sodium chloride, sodium nitrate and calcium chloride, and iv) a non-encapsulated pesticide. The present invention is also directed to methods of making and using the compositions of the present invention.Type: GrantFiled: February 21, 2007Date of Patent: February 26, 2013Assignee: FMC CorporationInventors: Robin W. Dexter, Hong Liu
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Publication number: 20120129698Abstract: A suspension and a method of preparation are provided herein. The suspension comprises a continuous aqueous phase (a), a substance (b) that is capable of transport through the aqueous phase thereby resulting in Ostwald ripening of the substance, and a dispersing agent (c). The dispersing agent comprises the reaction product of at least one monomer (i) and at least one additional monomer (ii). The at least one monomer (ii) is represented by the general formula (1) wherein R is hydrogen, an alkyl group or an aryl group, R1 is an alkyl group having at least 2 carbon atoms, k is 2 to 4, and n is at least about 10. The at least one additional monomer (ii) has unsaturated functionality and contains at least one carbonyl group. The dispersing agent is present in the suspension in an amount sufficient to limit Ostwald ripening of the substance (b) in the suspension.Type: ApplicationFiled: June 11, 2010Publication date: May 24, 2012Inventors: Laura L. Brasher, Michael D. Capracotta
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Publication number: 20090042730Abstract: The invention relates to novel aryl ketones of the formula (I) in which A1, A2, Q, R1, R2, X, Y and Z are as defined in the description, their use as herbicides and processes and intermediates for their preparation.Type: ApplicationFiled: September 4, 2008Publication date: February 12, 2009Inventors: Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Klaus-Helmut Muller, Otto Schallner, Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen
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Patent number: 7179859Abstract: A method of dispersing an insoluble material in an aqueous solution comprising the following steps: (i) providing a formulation comprising at least one insoluble material and at least one dispersant comprising a water soluble agriculturally acceptable derivative of an alternating copolymer or an agriculturally acceptable salt thereof wherein said alternating copolymer comprises at least one residue of a first comonomer and at least one residue of a second comonomer, wherein said first comonomer comprises ?,?-unsaturated oxyacids or anhydrides and said second comonomer comprises olefinic compounds containing one or more polymerizable double bonds; and (ii) dispersing said formulation in an aqueous medium.Type: GrantFiled: December 9, 2004Date of Patent: February 20, 2007Assignee: Huntsman Surfactants Technology CorporationInventors: Andrew Francis Kirby, Rodney Walter Parr, Phillip Robert Tudor, David Hayshiv Parris
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Patent number: 7049271Abstract: The present invention relates to novel phenyl-substituted 2-enamino-ketonitriles of the formula (I): in which Ar, X, Z, Y and K are each as defined in the description, to a plurality of processes for their preparation and to their use as herbicides and pesticides.Type: GrantFiled: April 25, 2001Date of Patent: May 23, 2006Assignee: Bayer AktiengesellschaftInventors: Reiner Fischer, Jutta Böhmer, Ralf Wischnat, Mark Wilhelm Drewes, Peter Dahmen, Rolf Pontzen, Peter Lösel, Christoph Erdelen, Dieter Feucht
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Patent number: 6835694Abstract: A method for controlling the growth of weeds at a locus which comprises applying to the locus an effective amount of: (a) a urea herbicide of general formula (1); and (b) 2-(2′-nitro-4′-methylsulfonylbenzoyl)-1,3-cyclohexanedione or an agriculturally acceptable salt or metal complex thereof.Type: GrantFiled: October 2, 2003Date of Patent: December 28, 2004Assignee: Bayer CropScience S.A.Inventors: Ken Pallett, Ashley Slater
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Publication number: 20040058820Abstract: Novel compounds of the structural formula (I) are antagonists and/or inverse agonists of the Cannabinoid-1 (CB1) receptor and are useful in the treatment, prevention and suppression of diseases mediated by the CB1 receptor. The compounds of the present invention are useful as centrally acting drugs in the treatment of psychosis, memory deficits, cognitive disorders, migraine, neuropathy, neuro-inflammatory disorders including multiple sclerosis and Guillain-Barre syndrome and the inflammatory sequelae of viral encephalitis, cerebral vascular accidents, and head trauma, anxiety disorders, stress, epilepsy, Parkinson's disease, movement disorders, and schizophrenia. The compounds are also useful for the treatment of substance abuse disorders, the treatment of obesity or eating disorders, as well as the treatment of asthma, constipation, chronic intestinal pseudo-obstruction, and cirrhosis of the liver.Type: ApplicationFiled: March 12, 2003Publication date: March 25, 2004Inventors: William K. Hagmann, Linus S. Lin, Shrenik K. Shah, Ravindra N. Guthikonda, Hongbo Qi, Linda L. Chang, Ping Liu, Helen M. Armstrong, James P. Jewell, Thomas J. Lanza
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Patent number: 6660692Abstract: This invention provides a method for controlling the growth of weeds (i.e. undesired vegetation) at a locus which comprises applying to the locus a herbicidally effective amount of: (a) picolinfen, a phenoxypicolinamide derivative of formula (I); and (b) a partner herbicide, selected from isoxazole, dione, urea and hydroxybenzonitrile herbicide.Type: GrantFiled: December 13, 2001Date of Patent: December 9, 2003Assignee: Aventis CropScience S.A.Inventor: Richard Henry Hewett
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Patent number: 6339043Abstract: A method of dispersing an insoluble material in an aqueous solution comprising the following steps: (i) providing a formulation comprising at least one insoluble material and at least one dispersant comprising a water soluble agriculturally acceptable derivative of an alternating copolymer or an agriculturally acceptable salt thereof wherein said alternating copolymer comprises at least one first comonomer residue according to formula I and at least one second comonomer residue according to formula II; and (ii) dispersing said formulation in an aqueous medium. An agricultural formulation comprising at least one insoluble material and at least one dispersant comprising a water soluble agriculturally acceptable derivative of an alternating copolymer or an agriculturally acceptable salt thereof wherein said alternating copolymer comprises at least one first comonomer residue according to formula I and at least one second comonomer residue according to formula II.Type: GrantFiled: July 25, 2000Date of Patent: January 15, 2002Assignee: Huntsman Surfactants Technology CorporationInventors: Andrew Francis Kirby, Rodney Walter Parr, Phillip Robert Tudor, David Hayshiv Parris
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Patent number: 6242385Abstract: A method for increasing the seed/fruit/nut yield of a flowering plant is disclosed wherein the method comprises treating said plant with a phenylurea of the structure wherein R10, R11, R12, R13, and R14 are independently selected from the group consisting of hydrogen, halogen, alkyl, alkenyl, alkoxy, aryl, aryloxy, nitro, cyano, alkylthio, alkylsulfinyl, alkylsulfonyl, and alkylenedioxy.Type: GrantFiled: February 28, 2000Date of Patent: June 5, 2001Assignee: Uniroyal Chemical Company, Inc.Inventors: Robert Timothy Weiland, Richard John Strunk
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Patent number: 5981433Abstract: Dispersing agents for solid plant-protection agrochemicals, for example pesticidal dispersible granules, comprise (a) at least one alkali or alkaline earth metal or ammonium lignosulfonate, intimately admixed with (b) at least one optionally sulfated, ethoxylated or ethoxylated-propoxylated di- or tri(1-phenylethyl)phenol.Type: GrantFiled: December 22, 1995Date of Patent: November 9, 1999Assignee: Rhone-Poulenc ChimierInventors: Valerio Bramati, Isabelle Gubelmann-Bonneau, Antonio Marchetto, Norman R. Pallas
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Patent number: 5672564Abstract: An aqueous, multiphase, stable finished formulation for crop protection active compounds is described, containing in addition to watera) 10 to 700 g/l of one or more crop protection active compounds,b) 5 to 150 g/l of one or more dispersants,c) 50 to 500 g/l of one or more wetting agents,d) 0.5 to 5 g/l of one or more thickeners ande) if appropriate an organic solventand processes for preparation thereof are described.Type: GrantFiled: January 3, 1996Date of Patent: September 30, 1997Assignee: BASF AktiengesellschaftInventors: August Wigger, Hans-Michael Fricke, Uwe Kardorff, Adolf Parg, Reiner Kober
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Patent number: 5665678Abstract: Agriculturally acceptable pesticidally active ingredients, such as herbicides, fungicides, and insecticides of low melting point, typically in the range from about 30.degree. C. to about 130.degree. C. and preferably in the range from about 30.degree. C. to about 90.degree. C. and low water solubility, typically in the range from about 0.01 ppm to about 1000 ppm and preferably in the range from about 0.01 ppm to about 300 ppm are frequently formulated as water-dispersed agrichemically acceptable formulations such as wettable powders (WP), water-dispersible granules (WG), and suspension concentrates (SC) and the like.Type: GrantFiled: May 31, 1995Date of Patent: September 9, 1997Assignee: Monsanto CompanyInventor: James Franklin Essinger, Jr.
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Patent number: 5635447Abstract: A herbicide composition which comprises a herbicide and a small but herbicide absorption enhancing effective amount of a water soluble, non-aromatic polyorganic acid or a salt or copolymer thereof such as polyaspartic acid.Type: GrantFiled: March 22, 1996Date of Patent: June 3, 1997Assignee: Donlar CorporationInventor: J. Larry Sanders
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Patent number: 5599768Abstract: A formulation consisting of an active ingredient (herbicide or pesticide) suspended in an organic medium containing, in addition to usual additives, a polymer and protic solvent and a process for the preparation of such formulation.Type: GrantFiled: November 9, 1994Date of Patent: February 4, 1997Assignee: E. I. du Pont de Nemours and CompanyInventor: Clarence G. Hermansky
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Patent number: 5587353Abstract: Kits comprising an agricultural chemical composition which can be safely applied to crops without causing any chemical damage; comprising a mixture, which exerts excellent potentiating effects on various agricultural chemicals, of compounds represented by the following general formula (I) and having (n1+n2+n3) and (n4+n5+n6) each being a number of 0 to 100 on the average, and an agricultural chemical, wherein the weight ratio of the mixture to the agricultural chemical ranges from 0.1 to 50: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a straight-chain or branched alkyl, alkenyl or hydroxyalkyl group having from 1 to 30 carbon atoms.Type: GrantFiled: June 5, 1995Date of Patent: December 24, 1996Assignee: KAO CorporationInventors: Yuichi Hioki, Kazuhiko Kurita, Keiko Kawabata, Toshikazu Azuma
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Patent number: 5538937Abstract: A method for enhancing an efficacy of an agricultural chemical which comprises incorporating a quaternary ammonium enhancer into a diluted solution of the agricultural chemical.Type: GrantFiled: June 6, 1995Date of Patent: July 23, 1996Inventors: Keiko Hasebe, Yuichi Hioki, Osamu Tachizawa, Takeshi Tomifuji, Tohru Katoh, Uichiro Nishimoto, Yoshifumi Nishimoto, Kohshiro Sotoya
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Patent number: 5474971Abstract: Rapidly disintegrating water-soluble or water-dispersible granular compositions are made by extruding a premix through a die or screen at elevated temperature. The extruded composition is chopped or milled to form a granular product. The compositions contain one or more water-soluble ingredients which soften or melt at elevated temperatures. No water is added in the process thereby eliminating the need for drying.Type: GrantFiled: August 26, 1993Date of Patent: December 12, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Lionel S. Sandell
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Patent number: 5462912Abstract: An agricultural chemical composition which can be safely applied to crops without causing any chemical damage; comprising a mixture, which exerts excellent potentiating effects on various agricultural chemicals, of compounds represented by the following general formula (I) and having (n1+n2+n3) and (n4+n5+n6) each being a number of 0 to 100 on the average, and an agricultural chemical, wherein the weight ratio of the mixture to the agricultural chemical ranges from 0.1 to 50: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent a straight-chain or branched alkyl, alkenyl or hydroxyalkyl group having from 1 to 30 carbon atoms.Type: GrantFiled: September 14, 1994Date of Patent: October 31, 1995Assignee: Kao CorporationInventors: Yuichi Hioki, Kazuhiko Kurita, Keiko Kawabata, Toshikazu Azuma
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Patent number: 5376621Abstract: Herbicides comprising from 1 to 50% by weight of linuron, from 0.1 to 25% by weight of a mixture composed of substituted phenols and polyvinylpyrrolidone in a ratio of from 1:100 to 100:1, from 0.5 to 20% by weight of a ligninsulfonate, from 0.1 to 10% by weight of a salt of a polymerized alkylnaphthalenesulfonic acid, and from 20 to 80% by weight of water.Type: GrantFiled: October 8, 1993Date of Patent: December 27, 1994Assignee: Hoechst AktiengesellschaftInventors: Gerhard Frisch, Thomas Maier
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Patent number: 5374608Abstract: Compositions containing one or more surfactants in combination with sulfuric acid and one or more of certain chalcogen-containing compounds in which the chalcogen compound/H.sub.2 SO.sub.4 molar ratio is below 2. These compositions contain the mono-adduct of sulfuric acid which is herbicidally active for controlling vegetation. Suitable chalcogen-containing compounds have the empirical formula ##STR1## wherein X is a chalcogen, each of R.sub.1 and R.sub.2 is independently selected from hydrogen, NR.sub.3 R.sub.4, and NR.sub.5, at least one of R.sub.1 and R.sub.2 is other than hydrogen, each of R.sub.3 and R.sub.4 is hydrogen or a monovalent organic radical, and R.sub.5 is a divalent organic radical. The surfactant-containing compositions are particularly useful for the treatment of materials containing lipophilic substances.Type: GrantFiled: September 17, 1992Date of Patent: December 20, 1994Assignee: Union Oil Company of CaliforniaInventor: Donald C. Young
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Patent number: 5374607Abstract: Phytopharmaceutical wettable powder comprising at least one phytopharmaceutical active substance which is solid at ambient temperature and at least one pulverulent inert filler, characterized by the fact that the constitutive particles of the filler constitute a support or carrier for the active substance comprised within a liquid composition, said active substance being selected from the group comprising:the esters of the family of the parahydroxybenzonitriles of the group comprising bromoxynil octanoate, bromoxynil heptanoate, bromoxynil butyrate, ioxynil octanoate, ioxynil heptanoate, ioxynil butyrate,the triazines of the group comprising simazine, atrazine and ametryne,the dinitroanilines of the group comprising butraline, pendimethaline, trifluraline, orizaline,the substituted ureas of the group comprising diuron, isoproturon, ethidimuron,the sulphonylureas of the group comprising especially chlorsulfuron.Type: GrantFiled: January 3, 1994Date of Patent: December 20, 1994Assignee: C F P IInventors: Joseph Schapira, Jacques Schild, Jacques Pecheur, Ange C. Guerin, Dominique Ambrosi, Jean-Jacques Fuchs, Bernard Guyenet
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Patent number: 5362707Abstract: The present invention relates to new plant-protection suspo-emulsions. More specifically, the invention relates to a suspo-emulsion of a solid active substance, having a melting point greater than or equal to 45.degree. C. and which is substantially insoluble in water. The suspo-emulsion comprises at least one oil; a first surface-active system comprising at least sucroglycerides; the solid active substance; and either (A) a nonionic or anionic surface-active agent, or (B) a second surface-active system containing sucroglycerides and at least one compound selected from the group consisting of an alkoxylated triglyceride, an alkoxylated fatty acid, a sorbitan ester, and an alkoxylated sorbitan ester, and optionally a phospholipid.Type: GrantFiled: December 10, 1991Date of Patent: November 8, 1994Assignee: Rhone-Poulenc ChimieInventors: Jean-Francois Fiard, Jean-Michel Mercier, Marie-Luce Prevotat
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Patent number: 5198012Abstract: A biocide composition comprises an effective amount of a biocide and an effective amount of a biocide activator selected from the group consisting of an alkyl phosphate, an alkenyl phosphate, a hydroxyalkyl phosphate, a polyoxyalkylene alkyl ether phosphate, a salt thereof, a polyoxyalkylene alkenyl ether phosphate, a salt thereof, a polyoxyalkylene hydroxyalkyl ether phosphate and a salt thereof.Type: GrantFiled: May 21, 1991Date of Patent: March 30, 1993Assignee: Kao CorporationInventor: Tetsuji Iwasaki