Powder: (class 75) Patents (Class 505/807)
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Patent number: 6809042Abstract: The present invention provides an oxide superconductor thick film which is formed on a substrate or a board and has a high Jc and Ic and a method for manufacturing the same. Predetermined amounts of materials containing elements of Bi, Pb, Sr, Ca and Cu are weighed, mixed and subjected to steps of calcining, milling, and drying, and thereafter an organic binder and an organic vehicle are added thereto to prepare a (Bi, Pb)2+aSr2Ca2Cu3Oz, superconductive paste, which is applied to the surface of a substrate or a board in a thickness of 260 &mgr;m or more and dried. Thereafter, the paste is first subjected to burning at temperatures of 835° C. to 840° C. for 100 hours, then pressurization, and further burning at temperatures of 835° C. to 840° C. for 100 hours, thereby preparing an oxide superconductor thick film having a film thickness of 130 &mgr;m or more having a high Jc and Ic.Type: GrantFiled: August 26, 2002Date of Patent: October 26, 2004Assignees: Dowa Mining Co., Ltd., Central Research Institute of Electric Power IndustryInventors: Masahiro Kojima, Masakazu Kawahara, Michiharu Ichikawa, Hiroyuki Kado, Masatoyo Shibuya
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Patent number: 5814585Abstract: The invention relates to a spray pyrolytic process for the preparation of multi-element metal oxide powders useful as precursors of high temperature superconductor ceramics. Aerosols of aqueous solutions containing corresponding metal salts admixed in the required stoichiometric proportion are sprayed through an independently operated hydrogen/oxygen flame in such a way that a flame temperature of 800.degree.-1100.degree. C. is maintained to form said powders. Any contact of the aerosols and powders generated during the process with carbon or carbon-containing compounds or materials is strictly avoided.Type: GrantFiled: November 26, 1996Date of Patent: September 29, 1998Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Rodney Riddle, Matthias Kuntz, Bernd Muller, Dietmar Raulin, Gunther Feldmann-Schlobohm
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Patent number: 5620532Abstract: In a method for manufacturing Nb.sub.3 Al phase by a diffusion reaction of Nb.sub.2 Al phase and Nb phase, a part of the Nb.sub.2 Al phase is remained and dispersed in the Nb.sub.3 Al phase homogeneously as for magnetic flux pinning centers for a high magnetic field. As for a method for dispersing the Nb.sub.2 Al phase homogeneously, a Nb.sub.3 Al group superconducting precursory composition obtained by dispersing Nb particles and Nb.sub.2 Al ultrafine particles by a mechanical alloying method is used, and further, by a conventional method for generating Nb.sub.3 Al phase by a diffusion reaction of Nb and an aluminum alloy, A Nb.sub.3 Al group superconductor can be achieved.Type: GrantFiled: June 6, 1995Date of Patent: April 15, 1997Assignee: Hitachi, Ltd.Inventors: Naofumi Tada, Fumio Iida, Ryukichi Takahashi, Takaaki Suzuki
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Patent number: 5614472Abstract: The invention relates to a spray pyrolyric process for the preparation of multi-element metal oxide powders useful as precursors of high temperature superconductor ceramics. Aerosols of aqueous solutions containing corresponding metal salts admixed in the required stoichiometric proportion are sprayed through an independently operated hydrogen/oxygen flame in such a way that a flame temperature of 800.degree.-1100.degree. C. is maintained to form said powders. Any contact of the aerosols and powders generated during the process with carbon or carbon-containing compounds or materials is strictly avoided.Type: GrantFiled: May 12, 1995Date of Patent: March 25, 1997Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Rodney Riddle, Matthias Kuntz, Bernd M uller, Dietmar Raulin, G unther Feldmann-Schlobohm
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Patent number: 5102863Abstract: A process for fabricating superconducting composite wire by the steps of placing a superconductive precursor admixture capable of undergoing a self propagating combustion in stoichiometric amounts sufficient to form a superconductive product within a metal tube, sealing one end of said tube, igniting said superconductive precursor admixture whereby said superconductive precursor admixture endburns along the length of the admixture, and cross-section reducing said tube at a rate substantially equal to the rate of burning of said superconductive precursor admixture and at a point substantially planar with the burnfront of the superconductive precursor mixture, whereby a clad superconductive product is formed in situ, the product characterized as superconductive without a subsequent sintering stage, is disclosed.Type: GrantFiled: March 19, 1991Date of Patent: April 7, 1992Assignee: The United States of America as represented by the United States Department of EnergyInventors: Richard B. Cass, Kevin C. Ott, Dean E. Peterson
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Patent number: 5100869Abstract: A metal oxide-type superconductive material is produced by a process which comprises a first step of subjecting a powder raw material containing given proportions of metal elements to be contained in said metal oxide-type superconductive material, to mechanical grinding and alloying simultaneously to obtain an alloy powder and a second step of heat-treating the alloy powder in an oxygen-containing gas atmosphere to obtain a metal oxide.The superconductive material obtained has a high density, a low porosity, a high strength and a high critical current density.Type: GrantFiled: March 10, 1989Date of Patent: March 31, 1992Assignees: Tsuyoshi Masumoto, Hoya CorporationInventors: Tsuyoshi Masumoto, Akihisa Inoue, Kunio Matsuzaki, Keiji Moroishi
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Patent number: 4983572Abstract: A superconductive body of an oxidic superconductive material having good mechanical properties is characterized in that the oxidic material forms a matrix through which finely divided particles are mixed at least the surface of which consists of a metal or a metal alloy. Particles in the form of fibres are preferably used and the surface of the particles consists of silver or gold.Type: GrantFiled: August 25, 1988Date of Patent: January 8, 1991Assignee: U.S. Philips CorporationInventor: Gijsbertus De With
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Patent number: 4983574Abstract: Conductor in strip, sheet or wire form with an electrical conductivity of at least 0.85.times.10.sup.6 .OMEGA..sup.-1 cm.sup.-1 at 77.degree. K. composed of a composite material of a metal matrix (1) and particles (2) composed of a high-temperature superconductor of the type RE Ba.sub.2 Cu.sub.3 O.sub.6.5-7.5 embedded therein and arranged rectilinearly in the longitudinal direction, RE generally denoting a rare earth metal. Preferably RE=yttrium and specifically the substance YBa.sub.2 Cu.sub.3 O.sub.7 and the particle diameter=0.1-100 .mu.m, more narrowly 0.2-20 .mu.m. Optionally an additional metal sheath which envelops the body forming the matrix (1).Type: GrantFiled: July 20, 1988Date of Patent: January 8, 1991Assignee: BBC Brown Boveri AGInventor: Gundolf Meyer
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Patent number: 4804649Abstract: Metal oxide superconductors of the yttrium-barium-copper type (YBa.sub.2 Cu.sub.3 O.sub.4 type) can be formed by precipitation from an aqueous solution of the salts of the metals using an oxalate precipitation reagent under basic pH conditions (e.g., at least 11) to form a fireable precursor only partly in the form of the oxalate salts of these metals.Type: GrantFiled: October 16, 1987Date of Patent: February 14, 1989Assignee: Akzo America Inc.Inventor: Fawzy G. Sherif