Powder Metallurgy: (class 419) Patents (Class 505/823)
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Publication number: 20030056857Abstract: A biaxially textured alloy article having a magnetism less than pure Ni includes a rolled and annealed compacted and sintered powder-metallurgy preform article, the preform article having been formed from a powder mixture selected from the group of mixtures consisting of: at least 60 at % Ni powder and at least one of Cr powder, W powder, V powder, Mo powder, Cu powder, Al powder, Ce powder, YSZ powder, Y powder, Mg powder, and RE powder; the article having a fine and homogeneous grain structure; and having a dominant cube oriented {100}<100> orientation texture; and further having a Curie temperature less than that of pure Ni.Type: ApplicationFiled: October 28, 2002Publication date: March 27, 2003Inventors: Amit Goval, Robert K. Williams, Donald M. Kroeger
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Patent number: 6038461Abstract: There are disclosed a high temperature superconductive material which can be plastically deformed, processed optionally into predetermined configurations and industrially mass produced and a method of manufacturing a formed body of the high temperature superconductive material. Mixed is a powder raw material which is mainly composed of: 10 to 50 mol % of at least one amide or nitride of alkali metal of Li, Na or K; 10 to 60 mol % of cyanide containing at least one metal selected from aluminum, copper, silver or gold; 5 to 50 mol % of at least one pure metal selected from aluminum, copper, silver or gold; and 10 mol % or less of at least one alkaline earth metal selected from Be, Mg, Ca, Sr or Ba. The powder raw material is pressed, and heated and sintered at the temperature of 673 K to 1553 K. In this manner, obtained is the plastically deformable high temperature superconductive material which can be optionally processed through forging, rolling and the like.Type: GrantFiled: April 24, 1998Date of Patent: March 14, 2000Inventors: Yoshifumi Sakai, Itsuko Sakai
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Patent number: 5814585Abstract: The invention relates to a spray pyrolytic process for the preparation of multi-element metal oxide powders useful as precursors of high temperature superconductor ceramics. Aerosols of aqueous solutions containing corresponding metal salts admixed in the required stoichiometric proportion are sprayed through an independently operated hydrogen/oxygen flame in such a way that a flame temperature of 800.degree.-1100.degree. C. is maintained to form said powders. Any contact of the aerosols and powders generated during the process with carbon or carbon-containing compounds or materials is strictly avoided.Type: GrantFiled: November 26, 1996Date of Patent: September 29, 1998Assignee: Merck Patent Gesellschaft mit Beschrankter HaftungInventors: Rodney Riddle, Matthias Kuntz, Bernd Muller, Dietmar Raulin, Gunther Feldmann-Schlobohm
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Patent number: 5620532Abstract: In a method for manufacturing Nb.sub.3 Al phase by a diffusion reaction of Nb.sub.2 Al phase and Nb phase, a part of the Nb.sub.2 Al phase is remained and dispersed in the Nb.sub.3 Al phase homogeneously as for magnetic flux pinning centers for a high magnetic field. As for a method for dispersing the Nb.sub.2 Al phase homogeneously, a Nb.sub.3 Al group superconducting precursory composition obtained by dispersing Nb particles and Nb.sub.2 Al ultrafine particles by a mechanical alloying method is used, and further, by a conventional method for generating Nb.sub.3 Al phase by a diffusion reaction of Nb and an aluminum alloy, A Nb.sub.3 Al group superconductor can be achieved.Type: GrantFiled: June 6, 1995Date of Patent: April 15, 1997Assignee: Hitachi, Ltd.Inventors: Naofumi Tada, Fumio Iida, Ryukichi Takahashi, Takaaki Suzuki
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Patent number: 5614472Abstract: The invention relates to a spray pyrolyric process for the preparation of multi-element metal oxide powders useful as precursors of high temperature superconductor ceramics. Aerosols of aqueous solutions containing corresponding metal salts admixed in the required stoichiometric proportion are sprayed through an independently operated hydrogen/oxygen flame in such a way that a flame temperature of 800.degree.-1100.degree. C. is maintained to form said powders. Any contact of the aerosols and powders generated during the process with carbon or carbon-containing compounds or materials is strictly avoided.Type: GrantFiled: May 12, 1995Date of Patent: March 25, 1997Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Rodney Riddle, Matthias Kuntz, Bernd M uller, Dietmar Raulin, G unther Feldmann-Schlobohm
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Patent number: 5480728Abstract: A conductive contact for use with metal oxide superconductors is described. The conductive contact comprises a metal contact which is attached by a diffusion bonding means to a superconductive metal oxide substrate. In a preferred embodiment, diffusion bonding means comprises a metal paint which includes metal particles and an organic binder which is heated to pyrolized the organic binder and form metallic diffusion bonds to the metal contact and metal oxide substrate. The invention also comprises a method for forming the conductive contact which includes selecting the superconducting metal oxide substrate, coating the substrate with a metal paint, placing the metal contact in touching contact with the metal paint and heating the combination of materials described above to pyrolized the organic binder and coalesce the metal particles.Type: GrantFiled: January 3, 1994Date of Patent: January 2, 1996Assignee: General Electric CompanyInventor: John E. Tkaczyk
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Patent number: 5468566Abstract: An article and method of manufacture of (Bi, Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor.Type: GrantFiled: September 13, 1994Date of Patent: November 21, 1995Assignee: University of ChicagoInventors: Stephen E. Dorris, Roger B. Poeppel, Barton C. Prorok, Michael T. Lanagan, Victor A. Maroni
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Patent number: 5314714Abstract: Process for increasing the density and improving the homogeneity of Chevrel phase powders and Chevrel phase wire obtained using said process. Chevrel phase powers are compounds of lead, mobydenum, and sulfur. Metallic additives in the range of 0.5% to 20% by weight are introduced in the Chevrel phase powders by a physical or chemical process. The melting temperature of the metallic additives is lower than the synthesis temperature of the Chevrel phase powders so as to increase the homogeneity. The wires obtained using this process are capable of generating high magnetic fields.Type: GrantFiled: September 3, 1990Date of Patent: May 24, 1994Assignee: PromogapInventors: Bernd Seeber, Oystein Fischer, Michel Decroux
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Patent number: 5102863Abstract: A process for fabricating superconducting composite wire by the steps of placing a superconductive precursor admixture capable of undergoing a self propagating combustion in stoichiometric amounts sufficient to form a superconductive product within a metal tube, sealing one end of said tube, igniting said superconductive precursor admixture whereby said superconductive precursor admixture endburns along the length of the admixture, and cross-section reducing said tube at a rate substantially equal to the rate of burning of said superconductive precursor admixture and at a point substantially planar with the burnfront of the superconductive precursor mixture, whereby a clad superconductive product is formed in situ, the product characterized as superconductive without a subsequent sintering stage, is disclosed.Type: GrantFiled: March 19, 1991Date of Patent: April 7, 1992Assignee: The United States of America as represented by the United States Department of EnergyInventors: Richard B. Cass, Kevin C. Ott, Dean E. Peterson
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Patent number: 4985401Abstract: A superconductor is produced by electric discharge explosion flame spraying of a composite body of constituents of an immiscible alloy. The electrically discharged composite body is deposited on a substrate and the resultant alloy is oxidized to yield an oxide of the alloy having superconductive property. This process can be applied to the Ln-Ba-Cu system (Ln is at least one of the rare earth elements including Y), typically the Y.sub.1 Ba.sub.2 Cu.sub.3 - or Y.sub.2 Ba.sub.4 Cu.sub.8 system, or other immiscible alloy systems such as the Bi-(Ca, Sr)-Cu system to form an oxide thereof.Type: GrantFiled: February 24, 1989Date of Patent: January 15, 1991Assignee: Aisin Seiki Kabushiki KaishaInventors: Akira Sawaoka, Ryuichi Matsuda, Tadashi Kondo
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Patent number: 4983572Abstract: A superconductive body of an oxidic superconductive material having good mechanical properties is characterized in that the oxidic material forms a matrix through which finely divided particles are mixed at least the surface of which consists of a metal or a metal alloy. Particles in the form of fibres are preferably used and the surface of the particles consists of silver or gold.Type: GrantFiled: August 25, 1988Date of Patent: January 8, 1991Assignee: U.S. Philips CorporationInventor: Gijsbertus De With
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Patent number: 4983574Abstract: Conductor in strip, sheet or wire form with an electrical conductivity of at least 0.85.times.10.sup.6 .OMEGA..sup.-1 cm.sup.-1 at 77.degree. K. composed of a composite material of a metal matrix (1) and particles (2) composed of a high-temperature superconductor of the type RE Ba.sub.2 Cu.sub.3 O.sub.6.5-7.5 embedded therein and arranged rectilinearly in the longitudinal direction, RE generally denoting a rare earth metal. Preferably RE=yttrium and specifically the substance YBa.sub.2 Cu.sub.3 O.sub.7 and the particle diameter=0.1-100 .mu.m, more narrowly 0.2-20 .mu.m. Optionally an additional metal sheath which envelops the body forming the matrix (1).Type: GrantFiled: July 20, 1988Date of Patent: January 8, 1991Assignee: BBC Brown Boveri AGInventor: Gundolf Meyer
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Patent number: 4975414Abstract: The method of producing a superconducting product includes: providing a pressed-powder preform consisting essentially of REBa.sub.2 Cu.sub.3 O.sub.x where 6.0<x<7.0; preheating the preform to elevated temperature for a time period between 0 and 10 minutes, within a medium consisting of a mixture of refractory ceramic particles, carbonaceous particles and ultra fine graphitic particles; providing a preheated grain bed and embedding the heated preform in that bed, the bed having the same composition as the medium; and consolidating the preform to at least about 95% of theoretical density by application of pressure to the grain bed, thereby to form the product.Type: GrantFiled: November 13, 1989Date of Patent: December 4, 1990Assignee: Ceracon, Inc.Inventors: Henry S. Meeks, Sundeep V. Rele
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Patent number: 4933139Abstract: A process for the production of at least a one kilogram block of Chevrel-phase Pb.sub.x Mo.sub.y S.sub.z, wherein x=0.9 to 1.2, y=6.0 to 6.4, and z=7 to 8, includes mixing thoroughly stoichiometric quantities of starting materials in powdered form. The starting materials are selected from elemental Pb, Mo and S, sulfides of elemental Pb and Mo, and mixtures thereof. The starting mixture is introduced into a metallic container and evacuated to a pressure to 10.sup.4 Pa or less. The evacuated container is subjected to hot isostatic pressing at a constant pressure selected from a pressure ranging from 100 to 300 MPa, at a heating rate ranging from 10.degree. to 100.degree. C./hr., at a final pressing temperature ranging from 800.degree. to 1200.degree. C., and for a pressing period ranging from 10 to 100 hours, whereby the starting materials react to form the block of Chevrel-phase Pb.sub.x Mo.sub.y S.sub.z. The block is cooled at a cooling rate ranging from 50.degree. to 500.degree. C./hr.Type: GrantFiled: September 1, 1987Date of Patent: June 12, 1990Assignee: Kernforschungszentrum Karlsruhe GmbHInventors: Rene Flukiger, Wilfried Goldacker