Reactive Formation Of Superconducting Intermetallic Compound Patents (Class 505/919)
  • Patent number: 7505800
    Abstract: A superconductive element containing Nb3Sn, in particular a multifilament wire, comprising at least one superconductive filament (8) which is obtained by a solid state diffusion reaction from a preliminary filament structure (1), said preliminary filament structure (1) containing an elongated hollow pipe (2) having an inner surface (3) and an outer surface (4), wherein said hollow pipe (2) consists of Nb or an Nb alloy, in particular NbTa, wherein the outer surface (4) is in close contact with a surrounding bronze matrix (5) containing Cu and Sn, and wherein the inner surface (3) is in close contact with an inner bronze matrix (5) also containing Cu and Sn, is characterized in that the inner bronze matrix (5) of the preliminary filament structure (1) encloses in its central region an elongated core (6) consisting of a metallic material, said metallic material having at room temperature (=RT) a thermal expansion coefficient ?core<17*10?6K?1, preferably ?core?8*10?6 K?1, said metallic material having at RT a
    Type: Grant
    Filed: April 11, 2006
    Date of Patent: March 17, 2009
    Assignee: Bruker BioSpin AG
    Inventors: René Flükiger, Vital Abächerli, Davide Uglietti, Daniel Eckert
  • Publication number: 20040206544
    Abstract: To improve the performance of superconducting cables, a composition method for obtaining a bar-like semifinished product by exclusively cold plastic deformation operations has been devised, and which includes the steps of: forming round-section, mono- or multifilament, superconducting copper bars of relatively long length; assembling the bars about a cylindrical copper core of substantially the same length, using assembly templates which open book-fashion and are fitted to and slide along an assembly bench, the templates having through holes arranged in a circle to support the bars, and a central through seat for supporting the core; tying the bars onto an outer lateral surface of the core; sliding onto one end of the assembly so formed a number of metal supporting rings resting on the assembly bench, while sliding the templates off the opposite end of the assembly; sliding a copper tube onto the assembly so formed, while at the same time cutting the ties in axial sequence and sliding off the supporting rings
    Type: Application
    Filed: October 17, 2003
    Publication date: October 21, 2004
    Inventor: Sergio Rossi
  • Patent number: 6561412
    Abstract: Methods for implementing production of an oxide superconductor joined member, excellent in electric current transmission performance, without a need of going through particularly complex steps, are provided. When joining together oxide superconductors by use of a solder composed of an oxide superconducting material, a finally solidified portion of the solder is positioned in a region where a transmission path of electric current flowing between oxide superconductor base materials as joined together is not obstructed by, for example, disposing the solder on a face of the oxide superconductor base materials, other than butting surfaces of the oxide superconductor base materials, so as to straddle both the base materials like bridge-building. Current flow is also not obstructed by, for example, shaping junction faces of the oxide superconductor base materials such that at least portions of the butting surfaces thereof are in the shape of sloped open faces, parting from each other.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: May 13, 2003
    Assignee: Superconductivity Research Laboratory
    Inventors: Jyunya Maeda, Susumu Seiki, Teruo Izumi, Yuh Shiohara
  • Patent number: 6436554
    Abstract: A method of producing an Nb—Sn compound superconducting wire precursor includes forming composite filament materials, each filament including a niobium material of an Nb-based metal and a titanium material of pure Ti enveloped in the niobium material; forming a composite rod in which composite filament materials are arranged in a matrix of a Cu-based metal but not in contact with one another, the matrix containing Sn diffused by heat treatment to combine with the niobium material to form a compound; and drawing the composite rod.
    Type: Grant
    Filed: May 4, 2001
    Date of Patent: August 20, 2002
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventor: Yoshio Kubo
  • Patent number: 6376099
    Abstract: A Cu-containing Nb3Al multifilamentary superconductive wire having a multifilamentary (superfine multi-core structure that a large number of micro-complex cores each obtained by complexing a Cu—Al alloy containing Cu in an amount of more than 0.2 at. % and at most 10 at. % in Nb are embedded in Nb, Ta, an Nb alloy or a Ta alloy as a matrix, wherein in the micro-complex cores, an A15 phase compound structure is formed by rapid heating at a temperature of 1,700° C. or more for 2 seconds or less and quenching to approximately room temperature, and further additionally heat-treated at a temperature of 650 to 900° C. This superconductive wire has high Jc in a low magnetic field, can be applied to all magnetic fields of 29 T or less, and is excellent in Jc characteristics in a high magnetic field in comparison with an Nb3Al wire.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: April 23, 2002
    Assignee: Agency of Industrial Science and Technology National Research Institute for Metals
    Inventors: Kiyoshi Inoue, Yasuo Iijima, Akihiro Kikuchi
  • Patent number: 6372054
    Abstract: A process for producing an ultrafine multifilamentary superconducting Nb3(Al,Ge) wire capable of generating a high critical current density comprising: preparing a composite core material comprising an A1—(2-30)at. % Ge alloy (where at. % represents % by atomic) 1 &mgr;m or less in thickness uniformly incorporated into a Nb matrix at a volume ratio in a range of 1:2.5 to 1:3.5 and forming a composite therewith; fabricating a composite wire having an ultrafine multifilamentary structure by embedding several tens to several millions of the resulting composite core materials in a cylindrical matrix material containing Nb; forming a A15-phase filament having a lower order in crystallinity inside the composite wire by a rapid heating and quenching treatment comprising rapidly heating to a temperature of 1,700° C.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: April 16, 2002
    Assignee: Japan as represented by Director General of National Research Institute for Metals
    Inventors: Akihiro Kikuchi, Yasuo Iijima, Kiyoshi Inoue
  • Publication number: 20020006527
    Abstract: An Nb—Sn compound superconducting wire precursor comprising a matrix of a Cu-base metal, a plurality of composite filaments each composed of a niobium layer of an Nb-base metal and a titanium layer of pure Ti formed so as to be enveloped in the inside of the niobium layer, and Sn diffused in the matrix by heat treatment so as to be combined with the niobium layer to form a compound, the plurality of composite filaments being embedded in the matrix so as not to be in contact with one another.
    Type: Application
    Filed: May 4, 2001
    Publication date: January 17, 2002
    Inventor: Yoshio Kubo
  • Patent number: 6251529
    Abstract: An Nb—Sn compound superconducting wire precursor comprising a matrix of a Cu-base metal, a plurality of composite filaments each composed of a niobium layer of an Nb-base metal and a titanium layer of pure Ti formed so as to be enveloped in the inside of the niobium layer, and Sn diffused in the matrix by heat treatment so as to be combined with the niobium layer to form a compound, the plurality of composite filaments being embedded in the matrix so as not to be in contact with one another.
    Type: Grant
    Filed: August 28, 1998
    Date of Patent: June 26, 2001
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventor: Yoshio Kubo
  • Patent number: 6199266
    Abstract: A superconductor cable with high interstrand resistance is produced from superconductor wire strands which has been electroplated with nickel. The wire strands have filaments of a superconductor alloy in a normally conducting metal matrix and are electroplated before they are formed into an elongated bundle of generally circular cross section. This bundle is then deformed and compacted into a superconductor cable of generally polygonal cross section which is usually trapezoidal. The superconductor wire is preferably comprised of a multiplicity of filaments of niobium/titanium superconductor alloy disposed within a matrix of copper.
    Type: Grant
    Filed: April 11, 1994
    Date of Patent: March 13, 2001
    Assignee: New England Electric Wire Corporation
    Inventor: Robert F. Meserve
  • Patent number: 5547921
    Abstract: A superconducting film including 0.1-5% by weight of magnesium oxide wherein the superconducting film has a thickness in a range from 300 to 1000 .mu.m. A superconducting device for magnetic shielding comprises: a substrate; and a superconducting layer supported by the substrate, the superconducting layer including grains of a Bi-type superconducting oxide so that the superconducting layer has a critical temperature higher than -196.degree. C., the superconducting layer having a thickness in a range from 300 to 1,000 .mu.m, the superconducting layer including 0.1-5% by weight of magnesium oxide, where the superconducting device has a laminated structure including the substrate and the superconducting layer. A process for producing a superconducting film comprises the steps of: firing a mixture of calcined powders of a superconducting oxide and 0.1-5% by weight of magnesium oxide powders at a temperature at which the superconducting oxide is partially melted.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: August 20, 1996
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Tani, Tooru Hayase, Hideki Shimizu, Kazuyuki Matsuda
  • Patent number: 5504984
    Abstract: A method of manufacturing an Nb.sub.3 Al superconducting wire includes a step of forming a wire by a jelly-roll process, a first thermal step of heating the obtained wire at a temperature of 500.degree. to 700.degree. C. for at least 10 hours for diffusing Al in Nb while suppressing formation of Nb.sub.3 Al, and a second thermal step of heating the wire, after the first thermal step, at a temperature of 800.degree. to 1050.degree. C. for about 0.01 to 10 hours, thereby forming Nb.sub.3 Al. In the jelly-roll process, a sheet of Nb and a sheet of Al are lap-wound on a copper core. The material obtained by such lap winding is inserted in a copper pipe, and then subjected to drawing. The drawn wire is cut to obtain a plurality of segments. The plurality of segments are bundled and charged in a copper pipe, and then subjected to drawing. The resulting drawn wire is subjected to the first and second thermal steps.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: April 9, 1996
    Assignees: Sumitomo Electric Industries, Ltd., Japan Atomic Energy Research Institute
    Inventors: Yuichi Yamada, Toshinari Ando, Yoshikazu Takahashi, Masataka Nishi, Hiroshi Tsuji, Hideo Nakajima
  • Patent number: 5445681
    Abstract: A method for producing a superconductor by partial inter diffusion of layers of metal under a diffusion heat treatment to provide a ductile beta phase alloy, along with undiffused metal layers to permit ease of extrusion and drawing to fine layer thickness. At some point in the reduction the layers are further diffused to give an alloy superconducting product which is optimal for the high field (5-9 T) of interest in contact with a non-superconducting layer. This optimal diffusion is preferably accomplished after a sufficient reduction such that the individual metal layers are 2.5-15 microns thick.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: August 29, 1995
    Assignee: Composite Materials Technology, Inc.
    Inventors: James Wong, Mark K. Rudziak, Terence Wong
  • Patent number: 5174831
    Abstract: A high field superconductor is formed of an A-15 superconductor in the form of a layer thinner than 1000.ANG.. This layer is carried by a support layer formed of a normal metal, the support layer having a thickness less than 1000.ANG..
    Type: Grant
    Filed: September 21, 1990
    Date of Patent: December 29, 1992
    Assignee: Composite Materials Technology, Inc.
    Inventors: James Wong, Mark K. Rudziak
  • Patent number: 4837609
    Abstract: A semiconductor device which includes either a single semiconductor chip bearing an integrated circuit (IC) or two or more electrically interconnected semiconductor chips, is disclosed. This device includes interconnects between device components (on the same chip and/or on different chips), at least one of which includes a region of superconducting material, e.g., a region of copper oxide superconductor having a T.sub.c greater than about 77K. Significantly, to avoid undesirable interactions, at high processing temperatures, between the superconducting material and underlying, silicon-containing material (which, among other things, results in the superconducting material reverting to its non-superconducting state), the interconnect also includes a combination of material regions which prevents such interactions.
    Type: Grant
    Filed: September 9, 1987
    Date of Patent: June 6, 1989
    Assignee: American Telephone and Telegraph Company, AT&T Bell Laboratories
    Inventors: Michael Gurvitch, Roland A. Levy