Organic Component Contains Ether Linkage (e.g., Peg Ether, Etc.) Patents (Class 507/136)
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Patent number: 11591508Abstract: Treatment fluids and methods of using a treatment fluid for minimizing fluid loss in a wellbore are disclosed. A method may comprise providing a drill-in fluid. The drill-in fluid may comprise an aqueous liquid, a base oil, a polyol, an emulsifying surfactant, and a solid bridging agent. The method may further comprise circulating the drill-in fluid through a drill-string and past a drill bit. The method may further comprise drilling in a reservoir section of a subterranean formation to extend a wellbore in the reservoir section the drill-in fluid is circulated therein.Type: GrantFiled: November 19, 2018Date of Patent: February 28, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Chesnee Lae Davis, Jeffrey J. Miller, William Walter Shumway
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Patent number: 11560508Abstract: An invert oil-based mud (OBM) may include an oleaginous continuous phase, an aqueous internal phase, and an emulsifier. The emulsifier may include one or more of the group consisting of epoxidized methyl oleate, epoxidized methyl linoleate, and epoxidized methyl ?-linolenate. The invert OBM may contain the emulsifier in an amount of the range of 0.1 to 10 wt. % (weight percent), relative to the total weight of the OBM.Type: GrantFiled: July 17, 2020Date of Patent: January 24, 2023Assignee: SAUDI ARABIAN OIL COMPANYInventors: Jothibasu Ramasamy, Vikrant Wagle
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Patent number: 11535786Abstract: A wellbore fluid may include an oleaginous fluid forming a continuous phase; a non-oleaginous fluid forming a discontinuous phase; at least one emulsifier stabilizing an emulsion of the non-oleaginous continuous phase within the oleaginous continuous phase; and at least one viscosifier dispersed into the oleaginous continuous phase in a concentration of at least 4 ppb; wherein upon subjecting the wellbore fluid to shear rate of at least 10,000 s?1, the emulsion is disrupted and the non-oleaginous fluid contacts the at least one viscosifier, thereby solidifying the wellbore fluid.Type: GrantFiled: November 12, 2019Date of Patent: December 27, 2022Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Steven Young, Aaron Blue, Josh Sheldon
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Patent number: 11021644Abstract: Drilling fluids and methods of making and using drilling fluids are provided. The drilling fluid includes an emulsion comprising an oleaginous phase suspended within an aqueous phase, a clay-based component in the aqueous phase, CaCl2, KCl, or both in the aqueous phase, and a polyglycerol-fatty acid complex. The polyglycerol-fatty acid complex may be free of covalent crosslinks. The polyglycerol-fatty acid complex may include polyglycerol hydrogen bonded to a fatty acid, and the oleaginous phase may include safra oil and the polyglycerol-fatty acid complex. Methods of producing the drilling fluid include reacting polyglycerol and a fatty acid at a temperature of less than 250° C. thereby forming a polyglycerol-fatty acid complex. The method further includes mixing an aqueous phase, a clay-based component, and the polyglycerol-fatty acid complex to produce a drilling fluid.Type: GrantFiled: September 11, 2019Date of Patent: June 1, 2021Assignee: Saudi Arabian Oil CompanyInventors: Jothibasu Ramasamy, Md Amanullah, Abdullah Saleh Al-Yami, Ali Radhwan
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Patent number: 10876028Abstract: A wellbore servicing fluid comprises an aqueous base fluid, one or more alkali metal or alkali earth metal salts, at least one visocisifier, and a filtration control package. The filtration control package may comprise a carboxylic acid and an ethoxylated alcohol compound. Alternatively, the filtration control package may comprise a polyethylene glycol. The carboxylic acid may have from 8 to 20 carbon atoms. The ethoxylated alcohol compound may have a general formula R—(OCH2CH2)x—OH, where R is a hydrocarbon having from 10 to 16 atoms and x is an integer from 6 to 9. The ethoxylated alcohol compound may have a hydrophilic-lipophilic balance of from 8.0 to 16.0. The polyethylene glycol may have a mass average molar mass (Mw) of less than or equal to 1500 daltons.Type: GrantFiled: April 11, 2019Date of Patent: December 29, 2020Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Vikrant Wagle, Hussain AlBahrani, Ali Safran, Nasser AlHareth
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Patent number: 10703957Abstract: In one embodiment, a retarded acid system comprises an aqueous acid and a retarding surfactant. The aqueous acid may comprise from 5 wt. % to 25 wt. % of a strong acid, that is, an acid having a Ka greater than or equal to 0.01. The aqueous acid may further comprise from 75 wt. % to 95 wt. % water. The retarding surfactant may have the general chemical formula R—(OC2H4)X—OH where R is a hydrocarbon having from 11 to 15 carbon atoms and x is an integer from 6 to 10. The retarding surfactant may have a hydrophilic-lipophilic balance from 8 to 16.Type: GrantFiled: July 19, 2018Date of Patent: July 7, 2020Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Vikrant Wagle, Ali Safran
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Patent number: 10590323Abstract: A method including providing a drilling fluid that comprises a base fluid, a weighting agent, and a sag stability enhancer, wherein the sag stability enhancer comprises polyethylene glycol (PEG) having a molecular weight of greater than or equal to about 200 g/mol; and placing the drilling fluid in a subterranean formation via a wellbore penetrating the subterranean formation. A method including forming a fluid comprising a base fluid, a weighting agent, and from about 0.5 ppb (1.4 kg/m3) to about 30 ppb (85.5 kg/m3) of a sag stability enhancer, wherein the sag stability enhancer comprises a glycol; and introducing the fluid into at least a portion of a well. A drilling fluid containing a base fluid, a weighting agent, and a sag stability enhancer comprising polyethylene glycol (PEG) having a molecular weight of greater than or equal to about 200 g/mol.Type: GrantFiled: April 27, 2016Date of Patent: March 17, 2020Assignee: HALLIBURTON ENERGY SERVICES, INC.Inventors: Chesnee Lae Davis, Philip Wayne Livanec, William Walter Shumway
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Patent number: 10526520Abstract: Anti-bit balling drilling fluids and methods of making and using drilling fluids are provided. The anti-bit balling drilling fluid contains water, a clay-based component, and a polyethylene glycol having the formula: H—(O—CH2—CH2)n—OH, where n is an integer from 1 to 50.Type: GrantFiled: March 14, 2018Date of Patent: January 7, 2020Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Abdulaziz A. Ba Hamdan, Saleh A. Haidary, Vikrant Wagle, Hussain AlBahrani, Ali Safran, Nasser AlHareth, Abdulla H. Awadh
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Patent number: 10435612Abstract: Among the methods provided is a method comprising: providing an oil-based fluid formed by combining components that comprise a glycol ether additive comprising a glycol ether, wherein the glycol ether additive substantially increases the low-shear viscosity of the oil-based fluid at temperatures between approximately 120 degrees Fahrenheit (48.9 degrees Celsius) and 500 degrees Fahrenheit (260 degrees Celsius); and using the oil-based fluid to drill at least a portion of a well bore penetrating at least a portion of a subterranean formation.Type: GrantFiled: August 7, 2018Date of Patent: October 8, 2019Assignee: Halliburton Energy Services, Inc.Inventors: Philip Wayne Livanec, Jay Paul Deville, Chesnee Lae Davis, Jonathan Paul Walker
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Patent number: 10377939Abstract: Anti-bit balling drilling fluids and methods of making and using drilling fluids are provided. The anti-bit balling drilling fluid contains water, a clay-based component, and at least one of a surfactant having the formula: R—(OC2H4)x—OH, where R is a hydrocarbyl group having from 10 to 20 carbon atoms and x is an integer from 1 and 10, or a polyethylene glycol having the formula: H—(O—CH2—CH2)n—OH, where n is an integer from 1 to 50. Methods of making and using these drilling fluids are also provided.Type: GrantFiled: March 15, 2018Date of Patent: August 13, 2019Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Abdulaziz A. Ba Hamdan, Saleh A. Haidary, Vikrant Wagle, Hussain AlBahrani, Ali Safran, Nasser AlHareth, Abdulla H. Awadh
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Patent number: 10266745Abstract: Anti-bit balling drilling fluids and methods of making and using drilling fluids are provided. The anti-bit balling drilling fluid contains water, a clay-based component, and at least one of a surfactant having the formula: R—(OC2H4)x—OH, where R is a hydrocarbyl group having from 10 to 20 carbon atoms and x is an integer from 1 and 10, or a polyethylene glycol having the formula: H—(O—CH2—CH2)n—OH, where n is an integer from 1 to 50. Methods of making and using these drilling fluids are also provided.Type: GrantFiled: April 12, 2017Date of Patent: April 23, 2019Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Abdulaziz A. Ba Hamdan, Saleh A. Haidary, Vikrant Wagle, Hussain AlBahrani, Ali Safran, Nasser AlHareth, Abdulla H. Awadh
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Patent number: 10227545Abstract: The present invention relates to new ether carboxylic acids as high temperature stable rheology modifier, viscosifier, lubricant or emulsifier additives in oilfield and industrial applications. In particular, the invention relates to an ether carboxylic acid or a derivative thereof obtainable by reacting a branched polyol alkoxylate with a halogen carboxylic acid or a halogen carboxylic acid derivative. Further aspects of the invention relate to a lubricant composition comprising an ether carboxylic acid of the invention and the use of said ether carboxylic acid.Type: GrantFiled: January 7, 2015Date of Patent: March 12, 2019Assignee: Emery Oleochemicals GmbHInventors: Diana Mäker, Heinz Müller
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Patent number: 10072201Abstract: Among the methods provided is a method comprising: providing an invert emulsion fluid formed by combining components that comprise: an oil-based continuous phase; an aqueous discontinuous phase; and a glycol ether additive that comprises a glycol ether and using the invert emulsion fluid to drill at least a portion of a well bore penetrating at least a portion of a subterranean formation.Type: GrantFiled: May 17, 2014Date of Patent: September 11, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Philip Wayne Livanec, Jay Paul Deville, Chesnee Lae Davis, Jonathan Paul Walker
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Patent number: 9675828Abstract: Provided are novel compositions for producing foam comprising a water-soluble polymer that is capable of self-hydrating. The present invention is also directed to methods for producing foam from compositions comprising a water-soluble polymer that is capable of self-hydrating.Type: GrantFiled: March 14, 2013Date of Patent: June 13, 2017Assignee: AF3—American Firefighting Foam, LLCInventor: Matthew James Sery
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Patent number: 9574128Abstract: This invention relates to compositions and methods for treating subterranean formations, in particular, oilfield stimulation compositions and methods using water-in-water polymer emulsions to uniformly dissolve a rheologically active polymer, such as a thickener or friction reducer, in the treatment fluid. The emulsions have a low viscosity and are easily pumped for mixing into a treatment fluid, where upon dilution with an aqueous medium, the polymer is easily hydrated without forming fish-eyes. The partitioning agent in the water-in-water emulsion does not generally affect the rheology of the treatment fluid. The invention also relates to further processing of the emulsion by wet grinding, high shear mixing and/or heating to enhance the hydration rate in the preparation of the well treatment fluid.Type: GrantFiled: July 2, 2008Date of Patent: February 21, 2017Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Yiyan Chen, Lijun Lin, Philip F. Sullivan
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Patent number: 9528040Abstract: An additive composition for boosting performance of water-based drilling fluids. Modified water-based drilling fluids including the additive composition. Methods of making the additive compositions. Methods of using the modified drilling fluids to drill or perform other operations in reactive shale formations. The additive compositions include one or more multi-hydroxyl alcohols, a lubricant mix, a shale inhibitor, a strong base to adjust pH, and optionally water up to about 20 percent by volume, based on total volume of the additive composition.Type: GrantFiled: July 3, 2014Date of Patent: December 27, 2016Assignee: ViChem Speciality Products LLCInventors: James P. Gaertner, Corey G. Peterson
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Patent number: 9518206Abstract: An invert emulsion treatment fluid comprises: (A) an external phase, wherein the external phase comprises a hydrocarbon liquid; (B) an internal phase, wherein the internal phase comprises a hygroscopic liquid; (C) a suspending agent, wherein the suspending agent is a polymer, and wherein the polymer comprises urea linkages; and (D) a particulate, wherein the particulate has a density less than 3.5 g/cm3, wherein a test fluid consisting essentially of the external phase, the internal phase, the suspending agent, and the particulate, and in the same proportions as the treatment fluid, and after static aging for 2 months at a temperature of 200° F. (93.3° C.), has a 10 minute gel strength of at least 30 lb/100 ft2 (1,436 Pa) at a temperature of 120° F. (48.9° C.). A method of using the invert emulsion treatment fluid comprises: introducing the treatment fluid into a portion of a subterranean formation.Type: GrantFiled: August 2, 2014Date of Patent: December 13, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Shadaab S. Maghrabi, Vikrant B. Wagle, Dhanashree G. Kulkarni
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Patent number: 9200996Abstract: Disclosed is a method for estimating porous-media longitudinal dispersion and adsorption coefficients. According to various embodiments of the invention, a method for estimating porous-media longitudinal dispersion coefficients is provided, which includes introducing a pure phase component though a porous medium, and introducing a component having a same phase as the pure phase component through the porous medium. The component includes a viscosifying agent having a non-linear viscosity-concentration dependence. The method further includes measuring, using a permeability analyzer, a pressure drop across the porous medium after each introduction at a plurality of intervals over a period of time. Further, the method includes determining, using the measured pressure drops, a pressure transition, and analyzing the pressure transition across the porous medium to determine a dispersion coefficient for the porous medium.Type: GrantFiled: April 11, 2013Date of Patent: December 1, 2015Assignee: Saudi Arabian Oil CompanyInventor: Abdulkareem Mohamad AlSofi
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Publication number: 20150065398Abstract: The invention provides, inter alia, compositions and methods of using a lubricating agent containing nanoparticles in various drilling applications. Furthermore, the lubricating agent may act as a corrosion inhibitor and a friction reducer.Type: ApplicationFiled: September 2, 2014Publication date: March 5, 2015Inventors: Cherie Gartland, Guy McClung, Randy Block
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Patent number: 8969263Abstract: A treatment fluid comprises: water; a carboxylate; and a corrosion inhibitor, wherein the corrosion inhibitor is a polymer, wherein the polymer comprises silicone, an ether monomer residue, and an amine functional group; wherein a test fluid consisting essentially of the water, the carboxylate, and the corrosion inhibitor, and in the same proportions as in the treatment fluid, is capable of providing a corrosion weight loss to a metal plate of less than 0.05 pounds per square feet (lb/ft2) under testing conditions of 200° F. (93.3° C.), a pressure of 500 psi (3.4 MPa), and a time of 24 hours whereas a substantially identical test fluid without the corrosion inhibitor provides a corrosion weight loss of greater than 0.05 lb/ft2 under the testing conditions. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.Type: GrantFiled: September 21, 2012Date of Patent: March 3, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Garima Misra, Arunesh Kumar
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Publication number: 20150045260Abstract: Aqueous and substantially anhydrous fluids having particularly low thermal conductivities and variable densities are disclosed. The fluids include: one or more organic and/or inorganic salts and at least one aprotic polar organic solvent, a mixture of aprotic and protic polar organic solvents, and/or a polar organic solvent having both protic and aprotic polar functional group linkages. The fluids optionally include one or more viscosifying agents and are free of cross-linking agents. Methods for formulating and using the fluids are also disclosed.Type: ApplicationFiled: October 23, 2014Publication date: February 12, 2015Inventors: Jeffrey McKennis, Marshall Chiasson, Mohammad Hossaini, Nam-Sook Bae
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Patent number: 8946133Abstract: A composition made of fibers and a material able to exhibit reverse solubility has utility for treating subterranean wells. The composition may used to cure lost circulation. The composition may be added to drilling fluids, spacer fluids or cement slurries. As the fluid temperature increases in a well, the reverse solubility material may precipitate and migrate to the fibers, causing the fibers to stick to each other and form a network, thereby forming a barrier that reduces further egress of treatment fluid from the wellbore.Type: GrantFiled: July 28, 2009Date of Patent: February 3, 2015Assignee: Schlumberger Technology CorporationInventors: Jesse Lee, Nikhil Shindgikar
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Publication number: 20150014062Abstract: The object of the present invention is a composition comprising amine compound and carboxylic acid compounds, wherein at least the amine compounds are alkoxylated, use thereof as a drilling fluid, and a method for using the drilling fluidType: ApplicationFiled: February 20, 2013Publication date: January 15, 2015Inventors: Heinz Napierala, Ludger Bosing
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Publication number: 20140349894Abstract: Nanomaterial compositions are useful for applications in drilling and completion fluids as enhancers of electrical and thermal conductivity, emulsion stabilizers, wellbore strength improvers, drag reduction agents, wettability changers, corrosion coating compositions and the like These nanomaterials may be dispersed in the liquid phase in low volumetric fraction, particularly as compared to corresponding agents of larger size. Nanofluids (fluids containing nano-sized particles) may be used to drill at least part of the wellbore. Nanofluids for drilling and completion applications may be designed including nanoparticles such as carbon nanotubes. These fluids containing nanomaterials, such as carbon nanotubes, meet the required rheological and filtration properties for application in challenging HPHT drilling and completions operations.Type: ApplicationFiled: August 8, 2014Publication date: November 27, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: LIRIO QUINTERO, ANTONIA ENRIQUE CARDENAS, DAVID E. CLARK
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Publication number: 20140336086Abstract: A drilling fluid comprising 0.1 to 50% by weight of at least one viscosifier selected from epoxidized fatty acid esters, wherein the fatty acid of the fatty acid ester is derived from natural oils or animal fats, and the fatty acid is substantially fully esterified with monohydric or polyhydric alcohols or mixtures thereof.Type: ApplicationFiled: April 23, 2014Publication date: November 13, 2014Applicant: Galata Chemicals LLCInventor: Peter Frenkel
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Publication number: 20140332212Abstract: Compositions of and methods of using a fluid formulation for increasing flow, production, and/or recovery of oil and gas hydrocarbons from a subterranean formation.Type: ApplicationFiled: November 30, 2011Publication date: November 13, 2014Applicant: VERUTEK TECHNOLOGIES, INC.Inventors: Jeffrey T. Ayers, George E. Hoag, Douglas K. Anderson, John B. Collins
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Patent number: 8871695Abstract: Nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both (Winsor III) or single phase microemulsions (Winsor IV) may be formed in situ during hydrocarbon recovery operations after drilling with OBM or SBM using one or more fluid pills. The nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both or single phase microemulsions remove oil and solids from the well and wellbore surfaces. In one non-limiting embodiment, a single phase microemulsion (SPME) or other in situ-formed fluid may be created from a polar phase, a nonpolar phase, at least one viscosifier, and at least one surfactant.Type: GrantFiled: April 22, 2008Date of Patent: October 28, 2014Assignee: Baker Hughes IncorporatedInventors: Lirio Quintero, Chad F. Christian, Alexander McKellar, Cristina Torres, David E. Clark, Thomas A. Jones
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Publication number: 20140213489Abstract: A drilling fluid comprising: a non-ionic surfactant including: a branched alcohol ethoxylate and/or a capped alcohol ethoxylate; and a detergent builder.Type: ApplicationFiled: April 3, 2014Publication date: July 31, 2014Inventor: CARL KEITH SMITH
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Publication number: 20140162910Abstract: A method of servicing a wellbore in a subterranean formation having one or more lost circulation zones comprising placing a wellbore servicing fluid comprising a sealing composition into the wellbore, wherein the sealing composition comprises a latex and an accelerator and wherein the latex, the accelerator or both are encapsulated with an encapsulation material. A wellbore servicing fluid comprising a latex and an accelerator wherein the latex, the accelerator, or both are encapsulated.Type: ApplicationFiled: December 10, 2012Publication date: June 12, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Nicholas Charles BRALEY, Anthony M. BADALAMENTI, Jay Paul DEVILLE
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Patent number: 8703658Abstract: A drilling fluid comprising: a non-ionic surfactant including: a branched alcohol ethoxylate and/or a capped alcohol ethoxylate; and a detergent builder.Type: GrantFiled: June 28, 2011Date of Patent: April 22, 2014Assignee: Canadian Energy Services L.P.Inventor: Carl Keith Smith
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Patent number: 8691733Abstract: Among the methods provided is a method of drilling a subterranean well with an invert emulsion fluid comprising: providing an invert emulsion fluid formed by combining components that comprise: an oil-based continuous phase; an aqueous discontinuous phase; and a polar hydrophobic additive that comprises a polar hydrophobe, wherein the polar hydrophobic additive may substantially increases the yield point, the low-shear yield point, or both of the invert emulsion fluid relative to a fluid without a polar hydrophobic additive while limiting the change in the plastic viscosity to no more than about 35% of the change in the property with the largest increase; and placing the invert emulsion fluid in a subterranean formation.Type: GrantFiled: September 1, 2009Date of Patent: April 8, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Jeffrey J. Miller, Shadaab Syed Maghrabi, Vikrant Bhavanishankar Wagle, William W. Shumway
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Publication number: 20140057810Abstract: According to an embodiment, an invert emulsion drilling fluid comprises: an external phase, wherein the external phase of the drilling fluid comprises a hydrocarbon liquid; an internal phase, wherein the internal phase of the drilling fluid comprises water; and a surfactant, wherein the surfactant: (A) comprises a hydrophobic tail group having a carbon chain length greater than or equal to 16; (B) has a boiling point greater than or equal to 400° F. (204.4° C.); and (C) is in at least a sufficient concentration such that the surfactant spontaneously forms reverse-micelles. According to another embodiment, a method of using the invert emulsion drilling fluid comprises: introducing the drilling fluid into a well.Type: ApplicationFiled: September 23, 2013Publication date: February 27, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventor: James V. FISK, JR.
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Publication number: 20140024560Abstract: A drilling fluid, comprising an aqueous continuous phase, and a surfactant system comprising a mixture of an ester phosphate and a non-ionic ethoxylated alcohol. The drilling fluid may also contain one or more of at least one salt, an alkaline material, a viscosifying agent, a starch or starch derivative, a bridging agent, a weighting material, and a diesel oil or non-aromatic oil.Type: ApplicationFiled: July 19, 2012Publication date: January 23, 2014Applicant: INTEVEP, S.A.Inventors: Jose Miguel Gonzalez Poche, Franklin Quintero Godoy, Rosa Linda Marquez Silva, Sergio Rosales, Jesus Enrique Arellano Varela, Harry Wilson Ogalde Arquero, Domingo Pernia
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Publication number: 20140005079Abstract: A oil field production fluid, namely a drilling mud composition, comprising a mixture of: (a) at least one base oil component; and (b) an additive component comprising a blend of dibasic esters. The functional fluid can optionally comprise additional additive components. The blend of dibasic esters comprises two or more of dialkyl methylglutarate, dialkyl adipate, dialkyl ethylsuccinate, dialkyl succinate, dialkyl glutarate.Type: ApplicationFiled: June 28, 2013Publication date: January 2, 2014Applicant: RHODIA OPERATIONSInventors: Manilal S. DAHANAYAKE, Subramanian KESAVAN, David FLUCK
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Patent number: 8563480Abstract: The present invention relates to bridging agents for use in subterranean formations, to well drill-in and servicing fluids comprising such bridging agents, and to methods of using such bridging agents and well drill-in and servicing fluids in subterranean drilling operations. An example of a well drill-in and servicing fluid of the present invention comprises a viscosified fluid, a fluid loss control additive, and a bridging agent comprising a degradable material.Type: GrantFiled: May 25, 2010Date of Patent: October 22, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Bradley L. Todd, Trinidad Munoz, Jr.
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Publication number: 20130267445Abstract: A method is provided for treating a drilling fluid to reduce foaming therein. The method comprises (a) providing a drilling fluid; and (b) treating the drilling fluid by adding a composition thereto which comprises (a) an alkylene glycol, (b) a polyol having first and second primary hydroxyl groups, (c) an unsaturated vegetable oil, and (d) an alkoxylated alcohol.Type: ApplicationFiled: April 5, 2013Publication date: October 10, 2013Applicant: ILF, Inc.Inventor: Connie M. Hendrickson
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Publication number: 20130264121Abstract: Methods and compositions for use in drilling a wellbore into an earthen formation that includes the use of a graphene-based material, where the graphene-based material may be at least one of graphene, graphene oxide, chemically converted graphene, and derivatized graphite oxide are shown and described. In certain examples, the methods and compositions reduce permeability damage and/or stabilize shales.Type: ApplicationFiled: October 6, 2011Publication date: October 10, 2013Applicants: WILLIAM MARSH RICE UNIVERSITY, M-I L.L.C.Inventors: Steve Young, James Friedheim, Arvind D. Patel, James Tour, Dmitry Kosynkin
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Publication number: 20130261030Abstract: A fluid may contain nanoparticles and a base fluid where the base fluid may be a non-aqueous fluid. The base fluid may be, but is not limited to a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid. The fluid may have at least one property, such as but not limited to a dielectric constant ranging from about 5 to about 10,000, an electrical conductivity ranging from about 1×10?6 S/m to about 1 S/m, and combinations thereof. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion, and combinations thereof. The addition of nanoparticles to the base fluid may modify the electrical properties of the fluid.Type: ApplicationFiled: May 28, 2013Publication date: October 3, 2013Inventors: Othon Monteiro, Daniel R. Ellis
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Patent number: 8541346Abstract: The present invention relates to bridging agents for use in subterranean formations, to well drill-in and servicing fluids comprising such bridging agents, and to methods of using such bridging agents and well drill-in and servicing fluids in subterranean drilling operations. An example of a well drill-in and servicing fluid of the present invention comprises a viscosified fluid, a fluid loss control additive, and a bridging agent comprising a degradable material.Type: GrantFiled: May 25, 2010Date of Patent: September 24, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Bradley L. Todd, Trinidad Munoz, Jr.
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Patent number: 8524641Abstract: A composition for providing a stable foam with high tolerance to hydrocarbons includes (a) an aqueous liquid; (b) at least one water soluble or dispersible silicon-containing polyether foamant contained within the aqueous liquid; and (c) a non-aqueous liquid. The aqueous liquid includes water and brine. The non-aqueous liquid includes liquid hydrocarbons.Type: GrantFiled: September 16, 2010Date of Patent: September 3, 2013Assignee: Momentive Performance Materials Inc.Inventors: Kalman Koczo, Oleg Tselinik, Benjamin Falk, George A. Policello
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Publication number: 20130153232Abstract: The present application is directed to an aqueous composition made up of an alkali metal silicate; a hardener containing at least one dibasic ester, at least one nonionic surfactant, at least one terpene or terpene derivative and optionally at least one polyalkylene glycol; and a retarder. The composition is useful for reducing the permeability in a subterranean formation, so as to reduce or prevent water flow and circulation loss of well fluids such as drilling fluids or cement.Type: ApplicationFiled: December 11, 2012Publication date: June 20, 2013Applicant: CALFRAC WELL SERVICES LTD.Inventor: Calfrac Well Services Ltd.
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Publication number: 20130045897Abstract: An amphiphilic nanoparticle comprises a nanoparticle having a hydrophilic region comprising a hydrophilic functional group bonded to a first portion of a surface of the nanoparticle, and a hydrophobic region of a surface of the nanoparticle. A downhole fluid comprises the amphiphilic nanoparticle, and a method of controlling an oil spill using the downhole fluid are also disclosed.Type: ApplicationFiled: August 19, 2011Publication date: February 21, 2013Applicant: BAKER HUGHES INCORPORATEDInventors: Soma Chakraborty, Gaurav Agrawal
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Patent number: 8338340Abstract: A drilling fluid comprising: a non-ionic surfactant including at least one of a branched alcohol ethoxylate and a capped alcohol ethoxylate, a detergent builder and a viscosifier.Type: GrantFiled: July 28, 2011Date of Patent: December 25, 2012Assignee: Tech-Star Fluid Systems Inc.Inventors: Stefan Alexandru Stoian, Carl Keith Smith
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Publication number: 20120322694Abstract: A base fluid may contain nanoparticles where the base fluid may include a non-aqueous fluid, an aqueous fluid, and combinations thereof. The fluid may have a resistivity range of from about 0.02 ohm-m to about 1,000,000 ohm-m. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion; and the aqueous fluid may be an oil-in-water emulsion, or an oil-in-brine emulsion; and combinations thereof. The addition of nanoparticles to the base fluid may improve or increase the electrical conductivity and other electrical properties of the fluid. The fluid may be a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid.Type: ApplicationFiled: July 10, 2012Publication date: December 20, 2012Applicant: BAKER HUGHES INCORPORATEDInventors: Othon Rego Monteiro, Jonathan J. Brege, Lirio Quintero, Soma Chakroborty, Ashley D. Leonard, Chad F. Christian
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Patent number: 8324136Abstract: A drilling fluid lubricant and method for drilling using same comprising a blend of beads having varying densities such that the beads provide lubricity at both the top and bottom portions of a horizontal drill string during horizontal, directional, or expanded extended reach drilling.Type: GrantFiled: January 6, 2011Date of Patent: December 4, 2012Assignee: Grinding & Sizing Company LLCInventors: Gregory A. Ruark, Robert W. Pike
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Publication number: 20120295821Abstract: Drilling fluids comprising a carrier fluid; a weighting agent that comprises sub-micron precipitated barite; a particle having a specific gravity of greater than about 2.6; and, a bridging agent that is not the submicron-precipitated barite or the particle. The weighting agent has a particle size distribution such that at least 10% of particles in the sub-micron precipitated barite have a diameter below about 0.2 microns, at least 50% of the particles in the sub-micron precipitated barite have a diameter below about 0.3 microns and at least 90% of the particles in the sub-micron precipitated barite have a diameter below about 0.5 microns. The particle has a specific gravity of greater than about 2.6 is not sub-micron precipitated barite. The ratio of the sub-micron precipitated barite to the particle is about 10:90 to about 99:1. The bridging agent comprises a degradable material.Type: ApplicationFiled: June 27, 2012Publication date: November 22, 2012Applicant: Halliburton Energy Services, Inc.Inventor: Ying Zhang
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Patent number: 8293686Abstract: A water-based polymer drilling fluid, containing effective quantities of surfactants having HLB numbers equal to or greater than approximately 7, emulsifies oil and bitumen contained in oil sand cuttings, resulting in the oil and bitumen being dispersed into the mud as an emulsion. This eliminates or significantly reduces the ability of the oil, bitumen, and cuttings to clog the well or stick to drill string components when drilling a well through oil-bearing sands, particularly sands containing highly viscous oil or bitumen. The emulsification process separates the sand particles from the oil and bitumen, such that the sand particles can be removed when the mud is run through a conventional shale shaker or other suitable apparatus.Type: GrantFiled: May 30, 2011Date of Patent: October 23, 2012Assignee: Marquis Alliance Energy Group Inc.Inventors: An-Ming Wu, Jay Brockhoff
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Patent number: 8288324Abstract: Wellbore fluids containing poly(trimethylene ether)glycols are provided. The wellbore fluids can provide enhanced functionality, improved cost effectiveness, and reduced environmental impact as compared to conventional wellbore fluids.Type: GrantFiled: March 30, 2011Date of Patent: October 16, 2012Assignee: E I du Pont de Nemours and CompanyInventor: Hari Babu Sunkara
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Publication number: 20120245058Abstract: A base fluid may contain graphene nanoparticles where the base fluid may include an oil-based fluid, a water-based fluid, and combinations thereof. The oil-based fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion, and the water-based fluid may be an oil-in-water emulsion, or an oil-in-brine emulsion; and combinations thereof. The addition of graphene nanoparticles to the base fluid may improve one or more properties of the fluid, which may include the flow assurance properties of the fluid, the fluid loss control properties of the fluid, the rheological properties of the fluid, the stability of the fluid, the lubricity of the fluid, the electrical properties of the fluid, the viscosity of the fluid, the thermal properties of the fluid, and combinations thereof. The fluid may be a drilling fluid, a completion fluid, a production fluid, and/or a servicing fluid.Type: ApplicationFiled: March 20, 2012Publication date: September 27, 2012Applicant: BAKER HUGHES INCORPORATEDInventors: Othon Monteiro, Lirio Quintero
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Publication number: 20120241220Abstract: Modified surfactants may be added to an oil-based drilling fluid where the modified surfactant is selected from the group consisting of an extended surfactant, a dendritic surfactant, a dendritic extended surfactant, and combinations thereof. These oil-based drilling fluids may be used for drilling a well through a subterranean reservoir, while circulating the oil-based drilling fluid through the wellbore. The oil-based drilling fluid may include at least modified surfactant, at least one non-polar continuous phase, and at least one polar non-continuous phase. The modified surfactant may have propoxylated/ethoxylated spacer arms extensions. The modified surfactant may have intramolecular mixtures containing hydrophilic and lipophilic portions. They attain high solubilization in the oil-based drilling fluid and may be, in some instances, insensitive to temperature making them useful for a wide variety of oil types.Type: ApplicationFiled: May 17, 2012Publication date: September 27, 2012Applicant: BAKER HUGHES INCORPORATEDInventors: Lirio Quintero, David E. Clark, Antonio Enrique Cardenas, Jean-Louis Salager, Ana Forgiarini, Ali Hasan Bahsas