Organic Component Contains Ether Linkage (e.g., Peg Ether, Etc.) Patents (Class 507/136)
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Publication number: 20090095534Abstract: Of the many compositions and methods provided herein, one method includes a method comprising: contacting tar resident in a well bore with a treatment fluid comprising a styrene-acrylate polymer; and allowing the styrene-acrylate polymer to interact with the tar to at least partially reduce the tendency of the tar to adhere to a surface. Another method provided herein includes a method for treating tar sand comprising: contacting the tar sand with a treatment fluid comprising an aqueous fluid and a styrene-acrylate polymer, the tar sand comprising tar and sand; and allowing the styrene-acrylate polymers to interact with the tar to at least partially separate the tar from the sand.Type: ApplicationFiled: October 16, 2007Publication date: April 16, 2009Inventor: Gregory P. Perez
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Patent number: 7507694Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles; and treating the subterranean formation.Type: GrantFiled: March 12, 2004Date of Patent: March 24, 2009Assignee: Halliburton Energy Services, Inc.Inventors: William W. Shumway, Kenneth W. Pober, Jeff Kirsner
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Patent number: 7501499Abstract: The present invention provides a hemoglobin molecule (Hb) having six ± one PEG chains, wherein two of said PEG chains are bound to Cys-93 (?) of Hb, and the remaining PEG chains are bound to thiol groups introduced on ?-NH2 of Hb. The present invention also provides a process for preparing a modified hemoglobin molecule (Hb), comprising the steps of: (a) reacting Hb with 8-15 fold excess of iminothiolane to form thiolated Hb; and (b) reacting the thiolated Hb with 16-30 fold excess of PEG functionalized with a maleimide moiety, to form the modified Hb.Type: GrantFiled: December 18, 2003Date of Patent: March 10, 2009Assignee: Albert Einstein College of Medicine of Yeshiva UniversityInventors: Seetharama A. Acharya, Belur N. Manjula
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Patent number: 7497278Abstract: Many methods are presented including one that comprises: providing a well drill-in and servicing fluid comprising an aqueous fluid, a viscosifier, a fluid loss control additive, a bridging agent, and an orthoester composition; using the well drill-in and servicing fluid to drill a well bore in a subterranean formation; allowing the well drill-in and servicing fluid to establish a filter cake in at least a portion of the well bore; contacting at least a portion of the filter cake with a breaker fluid comprising an orthoester composition; and allowing at least a portion of the filter cake to degrade.Type: GrantFiled: August 24, 2006Date of Patent: March 3, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Kirk Schriener, Trinidad Munoz, Jr.
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Patent number: 7485602Abstract: Environmentally acceptable or regulatory compliant oil-based drilling fluids and methods of using same in drilling a wellbore in a subterranean formation are disclosed. The fluids are able to meet environmental regulations while maintaining acceptable oil mud rheology and overall oil mud performance. The fluids are comprised of an invert emulsion. The base or continuous phase of the emulsion is comprised of esters blended with isomerized olefins, and/or other hydrocarbons, such as paraffins, mineral oils or glyceride triesters or combinations thereof. Alternatively, the emulsion has as a base comprising isomerized olefins blended with other hydrocarbons such as linear alpha olefins, paraffins or naphthenes.Type: GrantFiled: January 21, 2004Date of Patent: February 3, 2009Assignee: Halliburton Energy Services, Inc.Inventors: Jeff Kirsner, Kenneth W. Pober, Robert W. Pike
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Patent number: 7456135Abstract: Methods for drilling, running casing in, and/or cementing a borehole in a subterranean formation without significant loss of drilling fluid are disclosed, as well as compositions for use in such methods. The methods employ drilling fluids comprising fragile gels or having fragile gel behavior and providing superior oil mud rheology and overall performance. The fluids are especially advantageous for use in offshore wells because the fluids exhibit minimal differences between downhole equivalent circulating densities and surface densities notwithstanding differences in drilling or penetration rates. When an ester and isomerized olefin blend is used for the base of the fluids, the fluids make environmentally acceptable and regulatory compliant invert emulsion drilling fluids.Type: GrantFiled: November 12, 2002Date of Patent: November 25, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Jeff Kirsner, Don Siems, Kimberly Burrows-Lawson, David Carbajal, Ian Robb, Dale E. Jamison
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Patent number: 7435706Abstract: A method of reducing the viscosity of oil-based drilling fluids and well service fluids at low temperatures and a thinner compound for use in such drilling fluids and well service fluids is disclosed. The method comprises adding to said drilling fluids or well service fluids a thinner having the formula: R—(C2H4O)n(C3H6O)m(C4H8O)k-H where R is a saturated or unsaturated, linear or branched alkyl radical having about 8 to about 24 carbon atoms, n is a number ranging from about 1 to about 10, m is a number ranging form about 0 to about 10, and k is a number ranging from about 0 to about 10.Type: GrantFiled: December 29, 2000Date of Patent: October 14, 2008Assignee: Halliburton Energy Services, Inc.Inventors: Heinz Mueller, Jeff Kirsner, Kimberly Burrows
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Patent number: 7399731Abstract: A non-aqueous wellbore fluid comprises a non-aqueous continuous phase with one or more organic salts having the formula ((R1-Q)pX)mZn, one or more oligomeric organic salts based on linked ((R1-Q)pX)mZn subunits, or a combination thereof dissolved therein. X is a negatively charged functional group. R1 is an organic group comprising a principal straight chain and one or more side chains which branch from and are shorter than said principal straight chain. Q is a covalent bond or a polar linkage group which connects a terminal atom of the principal straight chain of the organic group R1 to the functional group X. p is a positive integer which is the number of organic groups R1 which are connected to the functional group X. Z is a cation. m and n are positive integers which ensure that the organic salts are charge neutral. The one or more organic salts increase the electrical conductivity of the wellbore fluid.Type: GrantFiled: December 9, 2002Date of Patent: July 15, 2008Assignee: M-I L.L.C.Inventors: Timothy Gareth John Jones, Gary John Tustin
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Patent number: 7387987Abstract: A method for increasing the rate of shear rehealing of fluids made with cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a polymeric rheology enhancer selected from polypropylene glycols and block copolymers of polypropylene glycol and polyethylene glycol. For applications in which rapid shear rehealing is required, the rheology enhancer allows fluids to be made and used at lower viscoelastic surfactant concentrations. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.Type: GrantFiled: April 13, 2006Date of Patent: June 17, 2008Assignee: Schlumberger Technology CorporationInventors: Yiyan Chen, Jesse C. Lee, Mathew Samuel
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Patent number: 7384892Abstract: A water-based drilling fluid composition includes water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient of polymeric additive, inorganic salts, dispersants, shale stabilizers, weighting agents, or finely divided clay particles, depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent comprises carboxymethylated raw cotton linters (CM-RCL) made from the baled raw cotton linters or comminuted raw cotton linters with increased bulk density.Type: GrantFiled: July 22, 2004Date of Patent: June 10, 2008Assignee: Hercules IncorporatedInventors: Mohand Melbouci, Arjun C. Sau
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Patent number: 7381689Abstract: A method and an amide composition used therein for inhibiting, retarding, mitigating, reducing, controlling and/or delaying formation of hydrocarbon hydrates or agglomerates of hydrates. The method may be applied to prevent or reduce or mitigate plugging of conduits, pipes, transfer lines, valves, and other places or equipment where hydrocarbon hydrate solids may form under the conditions. At least one amide compound is added into the process stream, where the compound may be mixed with another compound selected from amino alcohols, esters, quaternary ammonium, phosphonium or sulphonium salts, betaines, amine oxides, other amides, simple amine salts, and combinations thereof.Type: GrantFiled: August 13, 2004Date of Patent: June 3, 2008Assignee: Champion Technologies, Inc.Inventors: Vaithilingam Panchalingam, Michael Gregory Rudel, Scot Harris Bodnar
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Patent number: 7378378Abstract: A method for increasing the rate of shear rehealing of fluids made with cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a rheology enhancer package containing, for example a polyethylene glycol-polypropylene glycol block copolymer and a polynaphthalene sulfonate. The rheology enhancer package allows viscoelastic surfactant fluids to be used at lower viscoelastic surfactant concentrations in certain applications, for example certain oilfield treatments, for example fracturing and gravel packing. Preferred surfactants are betaines and quaternary amines.Type: GrantFiled: April 13, 2006Date of Patent: May 27, 2008Assignee: Schlumberger Technology CorporationInventors: Yiyan Chen, Jesse C. Lee, Fang Li, Manilal Dahanayake, Robert Tillotson, Allwyn Colaco
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Patent number: 7354886Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.Type: GrantFiled: October 13, 2004Date of Patent: April 8, 2008Assignee: Baker Hughes IncorporatedInventors: Ronald G. Bland, Lirio Quintero
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Patent number: 7348297Abstract: Compounds of the formula H(CH2)zCOO—[C2H4O]xCyH2y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H40]3C6H7.Type: GrantFiled: October 5, 2004Date of Patent: March 25, 2008Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
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Patent number: 7343986Abstract: This invention relates to drilling fluids, to drilling lubricants for such drilling fluids and to methods of drilling wells, particularly oil and/or gas wells using such drilling fluids. In particular, the invention relates to the inclusion of lubricants which afford lubrication in drilling fluids in which the lubricant compatibility and/or performance may be adversely affected by other components of the drilling fluid, particularly divalent cations such as calcium, formate salts or highly alkaline components such as alkali silicate.Type: GrantFiled: May 24, 2004Date of Patent: March 18, 2008Assignee: Croda International PLCInventor: Jeanette Dixon
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Publication number: 20070298976Abstract: A wellbore fluid that includes an oleaginous continuous phase; a non-oleaginous phase; and a polymeric additive formed by mixing at least one lipophilic monomer and at least one crosslinking agent, wherein the at least one lipophilic monomer is at least one of an epoxide-functionalized derivative of at least one selected from soybean oil, linseed oil, rapeseed oil, cashew nut shell oil; perilla oil, tung oil, oiticia oil, safflower oil, poppy oil, hemp oil, cottonseed oil, sunflower oil, high-oleic triglycerides, triglycerides of euphorbia plants, peanut oil, olive oil, olive kernel oil, almond oil, kapok oil, hazelnut oil, apricot kernel oil, beechnut oil, lupine oil, maize oil, sesame oil, grapeseed oil, lallemantia oil, castor oil, herring oil, sardine oil, menhaden oil, whale oil, tall oil, and synthetic aliphatic or aromatic ethers, and the at least one crosslinking agent includes at least one selected from amines, alcohols, phenols, thiols, carbanions, carboxylates, and mixtures thereof is disclosed.Type: ApplicationFiled: June 8, 2007Publication date: December 27, 2007Inventor: David Antony Ballard
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Patent number: 7304019Abstract: Suspensions are provided of water-soluble materials in non-aqueous carrier fluids using suspension agents that include organophilic clays. Methods of forming such suspensions are provided. Methods are also provided for using such suspensions to prepare aqueous solutions, in particular thickened aqueous solutions, in particular for use in oilfield treatments.Type: GrantFiled: May 31, 2006Date of Patent: December 4, 2007Assignee: Schlumberger Technology CorporationInventors: Lijun Lin, Alejandro Pena, Golchehreh Salamat, Michael D. Parris, Geoff Robinson
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Patent number: 7279447Abstract: Compositions containing surfactant compounds according to formula (I) ROCH2CH(OH)CR1R2ZCR1R2CH(OH)CH2OR,??(I) wherein Z is S, SO, or SO2, can have a range of equilibrium and/or dynamic surface tensions and a range of foaming performance attributes, depending upon the particular values of Z, R, R1, and R2. The compounds of formula (I) may be prepared by a process that includes reaction of a sulfide source such as a metal sulfide or bisulfide with an alkyl glycidyl ether. The compounds may be useful in any of a broad range of applications requiring the use of a surfactant.Type: GrantFiled: January 25, 2007Date of Patent: October 9, 2007Assignee: Air Products and Chemicals, Inc.Inventors: Gauri Sankar Lal, Williams Rene Edouard Raymond, Khalil Yacoub
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Publication number: 20070213233Abstract: A method of treating a well that includes selectively emplacing a fluid loss pill into the well, wherein the fluid loss pill includes at least one of diethylene glycol, triethylene glycol, and tetraethylene glycol, and wherein the at least one of diethylene glycol, triethylene glycol, and tetraethylene glycol reacts with a calcium brine present in the well to form a plug is disclosed.Type: ApplicationFiled: March 8, 2007Publication date: September 13, 2007Applicant: M-I LLCInventors: Michael A. Freeman, Bethicia B. Prasek, Robert L. Horton
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Patent number: 7199084Abstract: Suspensions are provided of water-soluble materials in non-aqueous carrier fluids using suspension agents that include thixotropic agents and, optionally, organophilic clays. Methods of forming such suspensions are provided. Methods are also provided for using such suspensions to prepare aqueous solutions, in particular thickened aqueous solutions, in particular for use in oilfield treatments.Type: GrantFiled: March 21, 2002Date of Patent: April 3, 2007Assignee: Schlumberger Technology CorporationInventors: Michael Parris, Geoff Robinson
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Patent number: 7137401Abstract: Non-polymeric drag reducing agents in the form of maleated fatty acids and the esters thereof and the organic, inorganic or amine salts thereof are described herein. These additives are useful to reduce drag in hydrocarbon fluids and multi-phase fluids of hydrocarbon(s) and water. No injection probes or other special equipment is expected to be required to introduce the drag reducing agent into the liquid stream, nor is grinding (cryogenic or otherwise) of the additive necessary to form a suitable drag reducing agent. The drag reducing additives of the invention are not subject to shear degradation and do not cause undesirable changes in the emulsion or fluid quality of the fluid being treated, or undesirable foaming.Type: GrantFiled: August 30, 2001Date of Patent: November 21, 2006Assignee: Baker Hughes IncorporatedInventors: Vladimir Jovancicevic, Young Soo Ahn
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Patent number: 7122507Abstract: Drilling, completing or workover of a well, particularly an oil and/or gas well, is carried out using a fluid which includes a continuous phase including an ester of the formula (I): (R2)p-Ph-(CH2)m—COO-(AO)n-R1 where R1, AO, n, m, Ph, R2 and p have defined meanings and particularly where the esters are alkyl or alkenyl benzoate esters. These esters are beneficial by having a range of viscosities, especially extending to low viscosities, and attractive toxicological and environmental profiles for use in drilling, completion and/or workover of wells.Type: GrantFiled: November 14, 2002Date of Patent: October 17, 2006Assignee: Imperial Chemical Industries PLCInventors: Neil Grainger, Terence Cox, Edward George Scovell
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Patent number: 7112557Abstract: An electrically conductive oil mud meeting the fluid requirements for resistive logging tools and a method for preparing such mud is disclosed. The fluid has been optimized to deliver performance in a manner as similar to that of a traditional invert emulsion drilling fluid as is practical while still maintaining the required electrical conductivity for resistivity-based logging tools. This electrically conductive oil-based mud comprises a polar synthetic ester base and complimentary ester surfactants, one being more oil soluble, the other being more water soluble. The surfactants interact synergistically to provide dense packing of micelles at the palisade layer. This fluid is oil-wetting to solids, and in general behaves like a traditional oil mud.Type: GrantFiled: October 9, 2003Date of Patent: September 26, 2006Assignee: Halliburton Energy Services, Inc.Inventor: Carl Joseph Thaemlitz
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Patent number: 7067461Abstract: A drilling fluid additive is provided wherein the additive is manufactured by a method comprised of admixing graphite with at least one carrier such as a polypropylene glycol or oil to create a suspended mixture, and allowing the surface of the graphite to be pre-wet with the carrier prior to adding the mixture to a drilling fluid.Type: GrantFiled: September 23, 2003Date of Patent: June 27, 2006Assignee: Alpine Mud Products Corp.Inventor: Jerry Rayborn
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Patent number: 7060660Abstract: A drilling fluid additive system is provided wherein the system comprises: a drilling fluid additive comprising talc, graphite and at least one carrier such as a glycol; and hydrophilic clay, a pH controller, a fluid loss controller, and at least one dispersant.Type: GrantFiled: September 23, 2003Date of Patent: June 13, 2006Assignee: Alpine Mud Products CorpInventor: Jerry Rayborn
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Patent number: 7056867Abstract: A drilling fluid additive system is provided wherein the system is manufactured by a method comprised of admixing graphite with at least one carrier such as a polypropylene glycol or oil to create a suspended mixture, and allowing the surface of the graphite to be pre-wet with the carrier prior to adding the mixture to a drilling fluid; and then further admixing hydrophilic clay, a pH controller, a fluid loss controller, and at least one dispersant to said drilling fluid additive system.Type: GrantFiled: September 23, 2003Date of Patent: June 6, 2006Assignee: Alpine Mud Products CorpInventor: Jerry Rayborn
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Patent number: 7028771Abstract: Low concentrations, 1–10% of potassium salt, especially potassium formate, are used in a drilling fluid in oil production. Preferably they are used with guar derivatives, most preferably carboxymethyl hydroxypropyl guar. The concentration of potassium formate is maintained at the desired level by adjusting the potassium formate to maintain a desired Zeta potential in the circulating drilling fluid. The potassium formate/guar derivative composition may be used in the substantial absence of hydrophilic clay additive.Type: GrantFiled: May 30, 2002Date of Patent: April 18, 2006Assignee: Clearwater International, L.L.C.Inventors: Kevin W. Smith, Rusty R. Mackey, John H. Hallman
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Patent number: 7001871Abstract: A drilling fluid additive is provided wherein the additive is manufactured by a method comprised of admixing at least one carrier such as a polypropylene glycol to talc and subsequently admixing graphite to the talc and carrier mixture; and then admixing an uintaite to the talc, carrier and graphite mixture.Type: GrantFiled: September 23, 2003Date of Patent: February 21, 2006Assignee: Alpine Mud Products CorpInventor: Jerry Rayborn
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Patent number: 6989352Abstract: A lubricant for use in silicic acid muds and other drilling fluids comprising silicate or silica species is disclosed. The lubricant significantly improves the lubricity of the fluid. A method of drilling a wellbore in a subterranean formation employing the lubricant is also disclosed. A preferred lubricant of the invention comprises about 80 volume percent 2-octyldodecanol and about 20 volume percent alkylglucoside. The alkylglucoside is preferably comprised of 2-ethylhexylglucoside or a mixture of alkylglucosides having more than about 10 carbon atoms in the alkyl chain.Type: GrantFiled: June 12, 2002Date of Patent: January 24, 2006Assignee: Halliburton Energy Services, Inc.Inventors: James V. Fisk, Jr., Jim D. Kerchevile, Kenneth W. Pober
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Patent number: 6914036Abstract: Methods and compositions effective for preventing or resolving emulsions of oil in aqueous solutions, preferably for preventing or resolving oil-in-water emulsions formed in aqueous brines used as completion fluids or workover fluids.Type: GrantFiled: March 15, 2001Date of Patent: July 5, 2005Assignee: Baker Hughes IncorporatedInventor: William A. Spalding
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Patent number: 6887832Abstract: A method for drilling, running casing in, and/or cementing a borehole in a subterranean formation without significant loss of drilling fluid is disclosed, as well as compositions for use in such method. The method employs a drilling fluid comprising a fragile gel or having fragile gel behavior and providing superior oil mud rheology and overall performance. The fluid is especially advantageous for use in deep water wells because the fluid exhibits minimal difference between downhole equivalent circulating density and surface density notwithstanding differences in drilling or penetration rates. When an ester and isomerized olefin blend is used for the base of the fluid, the fluid makes an environmentally acceptable and regulatory compliant invert emulsion drilling fluid. The fluid preferably contains no organophilic clays.Type: GrantFiled: June 19, 2002Date of Patent: May 3, 2005Assignee: Halliburton Energy Service,s Inc.Inventors: Jeff Kirsner, Don Siems, Kimberly Burrows-Lawson, David Carbajal
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Patent number: 6828279Abstract: An invert emulsion drilling fluid includes an oleaginous continuous phase; a non-oleaginous discontinuous phase; a biodegradable surfactant including a di-fatty acid ester of triglycerol; and a weighting agent. It is preferred that the fatty acid have the formula RCO2H in which R is an alkyl or alkenyl having 10 to 20 carbon atoms. The oleaginous fluid is selected from diesel oil, mineral oil, synthetic oil, ester oils, glycerides of fatty acids, aliphatic esters, aliphatic ethers, aliphatic acetals, or other such hydrocarbons and combinations of these and similar compounds. The non-oleaginous phase is selected from fresh water, sea water, brine, aqueous solutions containing water soluble organic salts, water soluble alcohols or water soluble glycols or combinations of these and similar compounds.Type: GrantFiled: August 10, 2001Date of Patent: December 7, 2004Assignee: M-I LLCInventors: Arvind D. Patel, Burnhan Hoxha, Reginald Bell
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Patent number: 6821931Abstract: A drilling fluid additive is provided wherein the additive is manufactured by a method comprised of admixing colloidal solids such as talc with at least one carrier such as an oil or glycol to create a suspended mixture to thereby allow the colloidal solids to be pre-wet with the carrier; and then admixing copolymer beads to the suspended mixture.Type: GrantFiled: March 5, 2002Date of Patent: November 23, 2004Assignee: Alpine Mud Products CorporationInventor: Jerry Rayborn
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Patent number: 6818597Abstract: Liquid water soluble polymer suspensions in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed water soluble polymer. The suspensions enable a user to rapidly add the suspension to water, being mixed at low speeds, without the formation of lumps or fisheyes and without generating fugitive dust in the process. The suspensions are environmentally safe and biodegradable. Unlike many other liquid polymer suspensions, the suspensions exhibit minimal oil or grease upon dilution. They contain no surfactants that can add to the oil and grease determination. The suspensions and the fluids produced by diluting the fluids to a working concentration of the water soluble polymer exhibit low toxicity to marine organisms and to humans. The suspensions can be manufactured from ingredients suitable for use in personal care applications such as cosmetics, shampoos and the like.Type: GrantFiled: January 26, 2001Date of Patent: November 16, 2004Assignee: Benchmark Research & Technology, Inc.Inventor: William Franklin Harris
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Patent number: 6806234Abstract: Compounds of the formula H(CH2)zCOO—[C2H4O]xCyH2y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H4O]3C6H7.Type: GrantFiled: August 19, 2002Date of Patent: October 19, 2004Assignee: Clearwater International, LLCInventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
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Patent number: 6800593Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.Type: GrantFiled: June 19, 2002Date of Patent: October 5, 2004Assignee: Texas United Chemical Company, LLC.Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
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Patent number: 6793025Abstract: A method of electrically logging subterranean wells using a conductive double emulsion fluid includes a miscible combination of an oleaginous fluid, an emulsifier capable of forming a microemulsion, an emulsifier capable of forming an invert emulsion, and an electrolytic salt. A microemulsion is the continuous phase of an invert emulsion. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The fluid may additionally contain a polar organic solvent and a carbon dioxide buffer. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like.Type: GrantFiled: June 17, 2002Date of Patent: September 21, 2004Assignee: M-I L. L. C.Inventors: Arvind D. Patel, Reginald J. Bell, Steve Young, Ahmadi Tehrani
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Patent number: 6787505Abstract: A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity of not less than 10 &mgr;S m−1 at 1 kHz comprises a polar organic liquid (POL) which exhibits a dielectric constant of at least about 5.0 and a Hildebrand Solubility Parameter of at least about 17 (J cm−3)1/2. Oils or other organic liquids (OL) known to be suitable as the continuous liquid phase of wellbore fluids, may be used in admixture with POL component. Certain inorganic salts, organic bases, quaternary ammonium salts or hydroxides (the dissolved component, DC), display sufficient solubility (and current carrying abilities) in POL, OL or in mixtures of liquid (POL) and liquid (OL) to further improve the electrical conductivity of the mixture. The wellbore fluid can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.Type: GrantFiled: June 8, 2000Date of Patent: September 7, 2004Assignee: M-I LLCInventors: Geoffrey Maitland, Christopher Sawdon, Mostafa Tehrani
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Patent number: 6784140Abstract: A method of treating a well including injecting a thermally stable, substantially water-free well-treating fluid into the well, wherein the well-treating fluid comprises a polymer, a glycol compound, and a salt is disclosed. In another embodiment, a thermally stable, substantially water-free well fluid including a polymer, a diol compound, and a salt is disclosed.Type: GrantFiled: August 15, 2001Date of Patent: August 31, 2004Assignee: M-I L.L.C.Inventors: David P. Kippie, William E. Foxenberg
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Patent number: 6774089Abstract: A drilling fluid additive is provided wherein the additive is manufactured by a method comprised of admixing colloidal solids such as talc with a combination of oil and glycol or cellulose to create a suspended mixture to thereby allow the colloidal solids to be pre-wet, treated or coated with the oil/glycol combination or the cellulose; and then admixing copolymer beads to the suspended mixture.Type: GrantFiled: July 17, 2002Date of Patent: August 10, 2004Assignee: Alpine Mud Products CorporationInventor: Jerry Rayborn
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Patent number: 6770603Abstract: A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity increased by a factor in order of 104 to 107 compared to conventional invert emulsion comprises from about 0.2% to about 10% by volume of carbon black particles and one or more emulsifying surfactant(s) selected from the class including nonionic emulsifiers of Hydrophilic-Lipophilic Balance (HLB) less than about 12, and anionic surfactants wherein the counter-ion (cation) is any of alkali metal, ammonium, or hydrogen ions. This wellbore fluid can be used for drilling or completing a well and can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.Type: GrantFiled: February 5, 2002Date of Patent: August 3, 2004Assignee: M-I L.L.C.Inventors: Christopher Sawdon, Mostafa Tehrani, Paul Craddock, Anthony Lawson
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Patent number: 6770601Abstract: The invention provides a method and fluid for drilling or servicing a well in a subterranean formation containing lost circulation zones or depleted, low pressure reservoirs. The fluid comprises an aqueous liquid having dispersed therein a viscosifier which increases the low shear rate viscosity of the fluid to at least 10,000 centipoise, an aphron-generating surfactant, and aphrons, wherein the fluid contains less than about 20% by volume of aphrons preferably generated by the turbulence and pressure drop as the fluid exits the drill bit in the vicinity of the formation. The method of drilling a wellbore in a subterranean formation comprises continuously re-circulating, while drilling, such a drilling fluid.Type: GrantFiled: February 9, 1999Date of Patent: August 3, 2004Assignee: Masi Technologies, LLCInventor: Tommy F. Brookey
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Patent number: 6740625Abstract: The present invention relates to a method and a fluid for drilling or intervening in a well passing through a porous, permeable formation, wherein a water-based well fluid is circulating in said well. In this method, there is added to the fluid not only the conventional ingredients for such a fluid but also a maximum of 10 wt. % of a composition obtained from a grease or oil and an alcohol, with the chain lengths of the acid and alcohol parts being chosen such that the ester thus obtained has sufficient dispersion in water, compatibility with said ingredients, does not form an emulsion with the reservoir oil, and adsorbs sufficiently on the porous formation.Type: GrantFiled: July 28, 2000Date of Patent: May 25, 2004Assignees: Institut Francais du Petrole, Oleon NVInventors: Annie Audibert, Jean-François Argillier, Daniel Longeron, Carine Dewattines, Michel Janssen
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Patent number: 6737384Abstract: A drilling fluid additive system is provided wherein the system is manufactured by a method comprised of admixing colloidal solids such as talc with a carrier such as oils and glycols or talc with cellulose to create a suspended mixture to thereby allow the colloidal solids to be pre-wet or coated with the carrier; and then admixing copolymer beads to the suspended mixture to allow the beads to be pre-wet or coated with the carrier; and then adding the suspended mixture with a mixture comprised of hydrophilic clay, a pH controller, a fluid loss controller, and a dispersant.Type: GrantFiled: July 17, 2002Date of Patent: May 18, 2004Assignee: Alpine Mud Products CorporationInventor: Jerry Rayborn
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Patent number: 6734145Abstract: A drilling fluid additive system is provided wherein the system is manufactured by a method comprised of admixing colloidal solids such as talc with a carrier such as oils or glycols to create a suspended mixture to thereby allow the colloidal solids to be pre-wet or coated with the carrier; and then admixing copolymer beads to the suspended mixture to allow the beads to be pre-wet or coated with the carrier; and then adding the suspended mixture with a mixture comprised of hydrophilic clay, a pH controller, a fluid loss controller, and a dispersant.Type: GrantFiled: July 17, 2002Date of Patent: May 11, 2004Assignee: Alpine Mud Products CorporationInventor: Jerry Rayborn
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Patent number: 6710019Abstract: The present invention relates to a wellbore fluid comprising a particulate material composed of the reaction product of A) one or more water soluble organic compound having possessing a molecular weight of less than 30,000 and possessing at least two hydroxyl groups and B) any other organic compound(s) capable of forming acetal or hemiacetal cross-links with the hydroxyl groups of compound A. The invention relates also to the specific particulate material itself and to applications of the wellbore fluid of the invention for well processes such as drilling, under-reaming, completing, working over, sealing loss zones, sealing fractures, sealing cavities or other very high permeability conduits in a rock formation, or hydraulic fracturing to stimulate a hydrocarbon-producing zone.Type: GrantFiled: June 1, 2001Date of Patent: March 23, 2004Inventors: Christopher Alan Sawdon, David Antony Ballard
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Patent number: 6660693Abstract: Methods are provided for increasing the production of hydrocarbons from shaly formations that contain adsorbed condensed hydrocarbon gases by treating such formations with dewatering compositions comprising surfactants that cause the surfaces of the formation to be or to remain oil-wet. The methods may be used in stimulation (acidizing or acid fracturing or hydraulic fracturing), remediation or workover, and in enhancing flow from natural fractures or from unstimulated formations.Type: GrantFiled: August 8, 2001Date of Patent: December 9, 2003Assignee: Schlumberger Technology CorporationInventors: Matthew J. Miller, Curtis L. Boney, Kevin W. England, Jerald J. Hinkel
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Low molecular weight water soluble organic compounds as crystallization point suppressants in brines
Patent number: 6635604Abstract: A brine for use during drilling operations, preferably a completion brine, comprising an amount of a low molecular weight water-soluble organic compound effective to reduce the crystallization point of the brine. The low molecular weight water soluble organic compound can be a variety of compounds, with preferred compounds being ethylene glycol, tripropylene glycol bottoms, and combinations thereof. A method of lowering the crystallization point of the brine using a low molecular weight water soluble organic compound also is provided.Type: GrantFiled: September 20, 2000Date of Patent: October 21, 2003Assignee: Baker Hughes IncorporatedInventors: William S. Halliday, Dennis K. Clapper -
Patent number: 6632777Abstract: Composition of water-based drilling fluids characterized in that they comprise an oil in water emulsion.Type: GrantFiled: November 27, 2000Date of Patent: October 14, 2003Assignees: ENI S.p.A., Enitecnologie S.p.AInventors: Stefano Carminati, Alberto Guarneri, Marco Brignoli
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Patent number: 6620769Abstract: This invention provides a water-free oil based fluid polymer suspension composition for use as a rheology modifier and fluid loss reducer in oil or gas well servicing fluids. It has been found that by using white medicinal oil as a carrier, high solids content and environmental friendly anhydrous fluidized polymer suspensions of xanthan gum, cellulose ethers, guar gum and derivatives thereof can be prepared. More specifically, in one aspect, an oil-based fluid polymer suspension (FPS) composition for use in oil or gas well servicing fluids is preferred containing: a) a hydrophilic polymer, b) an organophilic clay, c) a stabilizer, and d) a white medicinal oil having selected properties.Type: GrantFiled: November 21, 2000Date of Patent: September 16, 2003Assignee: Hercules IncorporatedInventors: Herbert L. Juppe, Robert P. Marchant, Mohand Melbouci