Abstract: The invention relates to a wellbore fluid, which is a monovalent brine comprising one or more alkali bromide salt(s) and one or more TCT-reducing additive(s) selected from the group consisting of alkali nitrates. A method of treating a subterranean formation, comprising placing the wellbore fluids of the invention in a wellbore in the subterranean formation is also provided.

Abstract: A modified drilling mud is provided which addresses a problem of H2S and other gaseous contaminants in the environment around a well drilling platform or other well drilling operation by remediating or eliminating the gaseous contaminants in the fluids being extracted from the well. The drilling mud is modified by addition of a liquid treatment composition including water and collectively 35-55 weight percent of one or more hydroxide compounds, wherein a ratio of the liquid treatment composition to the drilling mud in the modified drilling mud is in a range of 10 gallons of the liquid treatment composition per 42,000 gallons of drilling mud to 100 gallons of the liquid treatment composition per 42,000 gallons of drilling mud.

Abstract: A stable water based nanofluid of graphene-based amphiphilic Janus nanosheets, where the nanofluid has a high salt-content while retaining the interfacial activities of the nanosheets. Such a nanofluid of amphiphilic Janus nanosheets may be used for enhanced oil recovery.

Abstract: A fluidized sand composition for use as a filling material for sinkholes and the like weakened ground cavities. The fluidized sand composition is produced by mixing graded sand, water, a fluidizer, a plasticizer, and a surface active agent. The fluidized sand composition is easily injected into the ground cavity of a sinkhole. After filling, the fluidized sand composition will return to the solid natural condition according to the effect of plasticizer previously added. The fluidized sand composition allows for compaction, soil stabilization, permits water migration through the material, and can be easily excavated.

Abstract: Enhanced oil recovery (EOR) including with a lamellar phase having Janus nanoparticles, petroleum surfactant, crude oil, and water and with additional water to give the flooding fluid that may be pumped through a wellbore into a subterranean formation to affect a property of hydrocarbon in the subterranean formation via contact of the flooding fluid with the hydrocarbon.

Abstract: A drilling fluid formulation is provided, which includes an aqueous base fluid, a synthetic modified phyllosilicate as an anti-sagging additive, an inorganic base, and a weighting agent (e.g. barite). The synthetic modified phyllosilicate contains a clay material (e.g. smectite) and a metal selected from ruthenium, rhodium, palladium, osmium, iridium, and platinum. The synthetic modified phyllosilicate is effective in preventing barite sagging as demonstrated by low sag factor when drilling at elevated temperatures. Rheology properties of the drilling fluid including gel strength, yield point, plastic viscosity, and storage modulus are also specified.

Abstract: A grease composition is disclosed which is intended primarily for use in constant velocity joints (CV joints), especially ball joints and/or tripod joints, which are used in the driveline of motor vehicles. The grease composition for use in constant velocity joints comprises at least one base oil, at least one thickener, zinc sulfide, at least one copper sulfide and molybdenum disulfide and/or tungsten disulfide. Further, the present disclosure relates to a constant velocity joint comprising such a grease composition.

Abstract: A grease composition is intended primarily for use in constant velocity joints (CV joints), especially ball joints and/or tripod joints, which are used in the driveline of motor vehicles. The grease composition for use in constant velocity joints comprises at least one base oil, at least one thickener, zinc sulfide, as well as molybdenum disulfide and/or tungsten disulfide. Further, a constant velocity joint comprises the grease composition.

Abstract: A method of stimulating petroleum production includes introducing a fracturing fluid into a petroleum bearing carbonate formation, thereby creating at least one fracture to stimulate the petroleum production. The fracturing fluid is introduced into the petroleum bearing carbonate formation at a pressure above the breakdown pressure of the formation. The fracturing fluid includes a plurality of proppants where from 1 to 50 wt. % of the plurality of proppants includes micro proppants having a particle size ranging from 0.5 to 150 ?m, and from 50 to 99 wt. % of the plurality of proppants includes macro proppants having a particle size greater than 100 mesh.

Abstract: Provided are compositions and methods that use a true crystallization temperature reduction additive in the aqueous internal phase. An example method may comprise providing an oil-based treatment fluid in the form of an invert emulsion comprising an aqueous internal phase and an oil external phase. The aqueous internal phase may include a bromide brine and a true crystallization temperature reduction additive, wherein the bromide brine has a density of about 14.2 lbs/gal or greater. The method may further include placing the oil-based treatment fluid into a wellbore.

Abstract: A grease composition is intended primarily for use in constant velocity joins (CV joints), especially ball joints and/or tripod joints, which are used in the drivelines of motor vehicles. The grease composition for use in constant velocity joints comprises at least one base oil, and least one thickener, at least one copper sulfide in an amount of approximately 0.01 wt-% up to approximately 1.5 wt-% of the grease composition, molybdenum disulfide and/or at least one phosphorus-free organic molybdenum complex in an amount of approximately 0.1 wt-% up to approximately 5.0 wt-% of the grease composition. Further, a constant velocity joint comprises the grease composition.

Abstract: A method of stimulating petroleum production includes introducing a fracturing fluid into a petroleum formation, thereby creating at least one fracture to stimulate the petroleum production. The fracturing fluid is introduced into the petroleum formation at a pressure above the breakdown pressure of the formation. The fracturing fluid includes a plurality of proppants where from 1 to 50 wt. % of the plurality of proppants includes micro proppants having a particle size ranging from 0.5 to 150 ?m, and from 50 to 99 wt. % of the plurality of proppants includes macro proppants having a particle size greater than 100 mesh.

Abstract: A method comprises flowing a mud into a wellbore, wherein the mud has a mud composition and has a weight in a defined range. The method includes introducing a fluid pill into the mud flowing into the wellbore, wherein the fluid pill has an injection fluid with an injection composition that is different from the mud composition. A particulate has been added to the injection fluid to increase the weight of the fluid pill. After flowing the mud into the wellbore such that the fluid pill is positioned in a zone of the wellbore: filtering out the particulate from the injection fluid; injecting, after the filtering, the injection fluid into the zone; measuring a downhole parameter that changes in response to injecting the injection fluid into the zone; and determining a property of the formation of the zone based on the measured downhole parameter.

Abstract: A method of drilling a wellbore may include drilling the wellbore using a wellbore fluid that has rheological property values for 6 rpm, 10 minute gel, Yield Point, and/or 10 minute-to-10 second gel ratio that are +/20% of the mean values across a temperature range from 40° F. to 300° F.; and conditioning the wellbore with less than 2 hole volumes. The wellbore fluid may include an oleaginous external phase; a non-oleaginous internal phase; an amidoamine emulsifier stabilizing the non-oleaginous internal phase within the oleaginous external phase; at least two oil wetting agents; a rheology modifier; and a weighting agent having a d50 ranging from 5 to 10 ?m.

Abstract: A hybrid nanosurfactant composition may include a core phase including a sulfonate surfactant and a first aqueous fluid, a zwitterionic surfactant encapsulating the core phase, a plurality of magnetic particles disposed in the core phase, and a second aqueous fluid in which the encapsulated core phase is suspended. The plurality of magnetic particles may be disposed in the first aqueous fluid.

Abstract: A method includes selecting a model for a simulation of hydrocarbon recovery from a reservoir having a plurality of fractures during injection of an injected gas into the plurality of fractures. Selecting the model includes determining a flux ratio of a convection rate to a diffusion rate for the reservoir, determining whether the flux ratio is less than a threshold, and in response to the flux ratio being less than the threshold, selecting the model that includes diffusion. Selecting the model includes performing the simulation of the hydrocarbon recovery from the reservoir based on the model.

Abstract: Compositions and methods for treating kerogen in a subterranean formation by generating bromine and other halogens in situ in a subterranean formation. In some implementations, the generation of the bromine or halogen is delayed. This can occur, for example, by the decomposition of precursors, a chemical reaction, the encapsulation of precursors or reactants, or a combination of these approaches.

Abstract: Method for enhancing oil recovery in a hydrocarbon-containing carbonate reservoir including: injecting a slug of an oil recovery solution into the carbonate reservoir such that the wettability of a rock surface of the hydrocarbon-containing reservoir is altered toward more water-wet; and injecting a slug of a displacing fluid into the hydrocarbon-containing carbonate reservoir formation after injecting the slug of the oil recovery solution. The oil recovery solution comprising: a manganese-bearing aqueous solution having manganese ions and one or more major ions. The aqueous saline solution having a concentration of manganese ions between 100 and 1,000 ppm TDS and a concentration of major ions that is equivalent to the concentration of major ions in seawater as it is found in nature. The one or more major ions can include: sodium ion, magnesium ion, calcium ion, chlorine ion, sulfate ion, bicarbonate ion, and combinations of the same.

Abstract: A method of treating a well or a subterranean formation with an aqueous treatment fluid containing one or more oil-soluble, water-insoluble well treatment agents. The fluid includes an aqueous dispersion containing the well treatment agent in an amount from 25 to 60 weight percent. The volume average particle diameter of the oil-soluble well treatment agent in the fluid may be less than or equal to 2.5 microns. The fluid may further contain a water-soluble well treatment agent.

Abstract: A nanometer plugging water-based drilling fluid and preparation method and use thereof are within this disclosure. The nanometer plugging water-based drilling fluid comprise a nanometer plugging agent. The nanometer plugging agent may be surface modified SiO2 powder with the surfactant. The surfactant may be sodium dodecyl benzene sulfonate and/or sodium dodecyl sulfate. The nanometer plugging water-based drilling fluid may perform effective anti-collapse of stratum and maintain the stability of stratum.

Abstract: Provided herein are carbon-based oxide (CBO) materials and reduced carbon-based oxide (rCBO) materials, fabrication processes, and devices with improved performance and a high throughput. In some embodiments, the present disclosure provides materials and methods for synthesizing CBO and rCBO materials. Such methods avoid the shortcomings of current synthesizing methods to facilitate facile, high-throughput production of CBO and rCBO materials.

Abstract: Systems and methods for treating subterranean formations using particulates treated with hydrophobizing agents in aqueous base fluid are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising an aqueous base fluid and at least one particulate treated with one or more hydrophobizing agents; introducing the into a wellbore penetrating at least a portion of a subterranean formation; and using the treatment fluid to drill a portion of the wellbore.

Abstract: A hydraulic fracturing fluid comprising a water-in-oil emulsion comprising (i) an aqueous solution, (ii) an oil, (iii) a first surfactant, and, optionally, (iv) at least one secondary surfactant selected from an emulsifying surfactant and/or a phosphate ester of ethoxylated alcohol or alkylphenol, and methods of making and using the same.

Abstract: A composition of a treatment fluid having an aqueous base fluid and a true crystallization temperature reduction additive. A method includes providing a treatment fluid having an aqueous base fluid, adding a true crystallization temperature reduction additive and placing the treatment fluid in a subterranean wellbore.

Abstract: The present invention is an improved method of production of graphenic materials used to store energy and the energy storage systems using such produced graphenic materials. Provided herein is a method of producing graphene oxide that includes oxidizing graphite powder in a mixture of H3PO4 and H2SO4 in the presence of KMnO4, wherein the ratio of graphite powder to KMnO4 is about 1:9 by weight and the ratio of H3PO4 to H2SO4 is about 1:9 by volume, to produce graphene oxide; dispersing the graphene oxide in water at an acidic pH (e.g., about 0) to form a solution; adjusting the solution to about a neutral pH; and isolating the graphene oxide. An energy storage device is provided herein that includes the graphene oxide made by the disclosed methods or that includes the population (plurality) of reduced graphene oxide particles having the properties disclosed herein, such as batteries and supercapacitors.

Abstract: This can be a method of making a high strength composite reinforcing fiber using flat GO flakes coated on a conventional reinforcing fiber. This maintains some the flexibility of the fiber and aligns the flat graphene flakes along the surface of the fiber; this dramatically increases the strength of the fiber. It also allows bonding between overlapping flakes, in contrast to flakes being uniformly dispersed in a host material that is being reinforced and dramatically increases the strength of the host material.

Abstract: Provided are compositions, methods, and systems that relate to use of crystallization temperature reduction additives in treatment fluids. A treatment fluid for use in subterranean operations, the treatment fluid comprising: a bromide brine having a first true crystallization temperature; a true crystallization temperature reduction additive, the first true crystallization temperature is the true crystallization temperature of the bromide brine without inclusion of the true crystallization temperature reduction additive; the treatment fluid has a second true crystallization temperature that is lower than the first true crystallization temperature.

Abstract: Drilling fluids having improved rheology under downhole temperature and pressure. The improved rheology (IR) drilling fluids are particularly suited for use in deepwater drilling operations. The IR drilling fluids are invert emulsion fluids with viscosifier to rheology modifier weight ratios between about 6 and about 14. The IR drilling fluids exhibit low shear yield point variance and/or yield point variance of below 60 percent based on high-temperature, high-pressure viscometer measurements.

Abstract: Application of polyaminated fatty acid-based oil compositions to additive particles to control dusting. A method reducing an amount of dust produced during transfer of additive particles in well operations may comprise providing treated additive particles comprising additive particles and a polyaminated fatty acid-based oil composition disposed on a surface of at least portion of the particles, wherein the polyaminated fatty acid-based oil composition comprises a polyaminated fatty acid and an organic solvent. The method may further comprise mixing components comprising the treated additive particles and a base fluid to provide a treatment fluid. The method may further comprise introducing the treatment fluid into a subterranean formation.

Abstract: A method of treating a subterranean formation comprising: forming a treatment fluid by adding a desired volume of a liquid concentrate suspension to at least a base fluid, wherein the treatment fluid comprises the liquid concentrate suspension and the base fluid, and wherein the liquid concentrate suspension comprises: (A) water; (B) an additive; and (C) a magnesium silicate clay, wherein the clay increases the viscosity of the water, wherein the liquid concentrate suspension is stable for a time period of at least 2 weeks; and introducing the treatment fluid into the subterranean formation.

Abstract: Drilling fluids were developed including a base fluid, a weighting agent and/or a bridging agent, and a thickening agent, where the weighting agent and/or the bridging agent includes a particulate strontium carbonate having a desired distribution, for weighting agents, the distribution includes particles between 2? and 5000? and for bridging agents, the distribution is constructed from particles having specific sizes. Methods making and using the drilling fluids were also discovered.

Abstract: An acid soluble defluidizing pill for reducing fluid loss in a wellbore is provided that includes an oleaginous or non-oleaginous base fluid; at least one synthetic fiber; and at least one inorganic crystalline fiber; in which one or more of the synthetic fiber and the inorganic crystalline fiber are at least substantially acid soluble.

Abstract: The present invention relates to a preparation method of graphene oxide based on mixed acid system. The method consists of the following steps. a. Preparation of graphite powder; b. Preparation of suspension liquid of first acid system; c. Preparation of second acid system; d. Preparation of graphene oxide. The invention also relates to a preparation method of graphene using graphene oxide obtained by method mentioned above. The method consists of the following steps. e. Preparation of graphene oxide-dispersant solution; f. Reduction of graphene oxide; g. Process of supersonic stripping; h. Obtaining graphene by separation and drying. The preparation methods of graphene oxide and graphene in our invention could reduce the dosage of strong acid as well as heat release of chemical reaction, and cause less corrosion to our equipments, which makes the reaction more effective and properties of graphene products better, facilitating the achievement of large scale industrial production.

Abstract: An audio device with an insertion part being adapted to be inserted into an ear canal of a user. The insertion part comprises pressure means and a resilient surface. The resilient surface comprises an adhesive, which is adapted to adhere to a skin portion of a bony portion of an ear canal of a user. The pressure means are adapted to provide a force to press the adhesive against the skin portion. The pressure means include a phase-changing material, which is adapted to cause a reduction in the force, when heat is supplied to the phase-changing material.

Abstract: A method of fabricating a graphene oxide material in which oxidation is confined within the graphene layer and that possesses a desired band gap is provided. The method allows specific band gap values to be developed. Additionally, the use of masks is consistent with the method, so intricate configurations can be achieved. The resulting graphene oxide material is thus completely customizable and can be adapted to a plethora of useful engineering applications.

Abstract: There is described a drilling fluid for wellbore strengthening having nanoparticles and granular particles. In one aspect described herein, the drilling fluid is an invert emulsion based fluid. In a further aspect, the nanoparticles are iron hydroxide or calcium carbonate, and in a further aspect from about 1 to 30 nm in size. In one aspect described herein, the granular particles are graphite or calcium carbonate and in a further aspect, up to 250 ?m in size. The nanoparticles and granular particles plug fractures in the wellbore to strengthen the wellbore.

Abstract: A method for controlling the loss of drilling fluid from an oil well borehole into formations penetrated by a drill bit is disclosed by which resilient graphitic carbon particles having a resiliency greater than about 130% rebound after compression to 10,000 psi; a degree of graphitization greater than 85%, as measured by d002 using XRD; an average pore size larger than 0.035 micron; and an aspect ratio smaller than 0.63 are added to the drilling fluid.

Abstract: A treatment fluid comprises: a metal oxide, wherein the metal oxide is capable of forming a chelate complex or coordination complex with a ligand, wherein the chelate complex or coordination complex has a setting time of less than 90 minutes at a temperature of 71° F. and a pressure of 1 atmosphere. A method of treating a portion of a subterranean formation comprises: introducing the treatment fluid into the subterranean formation; allowing or causing a chelate complex or coordination complex to form between the metal oxide and a ligand; and allowing or causing the chelate complex or coordination complex to set.

Abstract: A system and method of treating a fluid to be used for hydraulic fracturing adds an effective amount of chlorine dioxide to the fluid to act as a biocide that kills harmful bacteria. A system for adding chlorine dioxide to the fluid can continuously add chlorine dioxide to an incoming flow of the fluid to produce a continuous flow of treated fluid.

Abstract: The present invention relates to oil well drilling comprising a weighting agent consisting of microfine, particulate ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, where 90% by volume of the particles have a size of less than 12.5 ?m and a D50 between 3 ?m and 6 ?m by volume measured by laser diffraction using Malvern laser diffraction particle size analyzer, where the particles have an average circularity of at least 0.85 determined by image analysis. The invention further relates to high density oil well cement slurry comprising water, Portland cement, a to weighting material and optionally silica flour, microsilica, fiber, rubbery particles a fluid loss addition and a retarder, where the weighting material is particulate microfine ilmenite having a FeTiO3 content of at least 85% by weight, a specific surface area (BET) between 1 and 5 m2/g, and where 90% by volume of the particles have a size of less than 12.

Abstract: The instant invention pertains to a composition which may be useful for enhancing oil recovery. The composition typically comprises the reaction mixture of at least (a) two or more compounds capable of generating at least about 20 kcal to about 150 kcal per mole when contacted; (b) one or more suitable surfactants or one or more suitable polymers or a mixture thereof; and (c) oil. The invention also pertains to a method for enhancing oil recovery wherein a suitable system is injected through a wellbore into a reservoir to enhance mobility of oil.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.

Abstract: A cordierite material having an increased ?-cordierite phase and a reduced ?-cordierite phase is described. Methods of making the cordierite material are further described, and a proppant containing the cordierite is further described, as well as use of the proppant.

Abstract: Methods of treatment subterranean formations including providing a treatment fluid comprising a base fluid and a lubricating agent, wherein the lubricating agent is selected from the group consisting of bismuth dialkyl dithiophosphate; tungsten disulfide; a mixture of micronized graphite and micronized metal disulfide; and any combination thereof; and introducing the treatment fluid into a wellbore in the subterranean formation.

Abstract: In some embodiments, the present invention pertains to methods of detecting a contamination of an environment by a fracture fluid that comprises magnetic particles. In some embodiments, such methods include: (1) collecting a sample from the environment; and (2) measuring a magnetic susceptibility of the sample in order to detect the presence or absence of the magnetic particles. Further embodiments of the present invention pertain to methods of tracing fracture fluids in a mineral formation. In some embodiments, such methods include: (1) associating the fracture fluids with magnetic particles; (2) introducing the fracture fluids into the mineral formation; and (3) measuring a magnetic susceptibility of the fracture fluids. Additional embodiments of the present invention pertain to fracture fluids containing the aforementioned magnetic particles, the actual magnetic particles, and methods of making said magnetic particles.

Abstract: Nanomaterial compositions are useful for applications in drilling and completion fluids as enhancers of electrical and thermal conductivity, emulsion stabilizers, wellbore strength improvers, drag reduction agents, wettability changers, corrosion coating compositions and the like These nanomaterials may be dispersed in the liquid phase in low volumetric fraction, particularly as compared to corresponding agents of larger size. Nanofluids (fluids containing nano-sized particles) may be used to drill at least part of the wellbore. Nanofluids for drilling and completion applications may be designed including nanoparticles such as carbon nanotubes. These fluids containing nanomaterials, such as carbon nanotubes, meet the required rheological and filtration properties for application in challenging HPHT drilling and completions operations.

Abstract: A drilling fluid for discharging in a borehole to facilitate drilling operations, and hydraulic fracturing in particular, comprising amorphous silicas having a particle size ranging from about one to about ten nanometers and water, wherein the pH of the fluid is substantially neutral.

Abstract: Defoamer compositions are disclosed and methods for making and using same, where the defoamer has universal applicability at low concentrations. The defoamer compositions include between 40 vol. % and about 80 vol. % distilled water (other waters may be used instead), 10 vol. % and about 30 vol. % of silicon anti-foam agent and between about 10 vol. % and about 30 vol. % of active silicon anti-foam agent. The defoamer compositions are used in amount of less than or equal to 200 ppm in all foamed downhole fluid systems.

Abstract: A method for controlling the loss of drilling fluid from an oil well borehole into formations penetrated by a drill bit is disclosed by which resilient graphitic carbon particles having a resiliency greater than about 130% rebound after compression to 10,000 psi; a degree of graphitization greater than 85%, as measured by d002 using XRD; an average pore size larger than 0.035 micron; and an aspect ratio smaller than 0.63 are added to the drilling fluid.

Abstract: Drilling, drill-in and completion fluids containing nanoparticles for use in hydrocarbon drilling and recovery processes and methods related thereto are provided. The fluids also include a dual acting shield agent that shields the nanoparticles and also acts as a viscosifier. The fluids can be used in various types of hydrocarbon drilling and recovery processes, such as drilling, drill in, completion, and the like.