Abstract: A method for consolidating a subterranean geologic formation is provided. The method includes injecting a first composition, a second composition, and a third composition into the subterranean geologic formation. The first composition includes CaO, the second composition includes MgO, and the third composition includes NH4HF2. The method includes injecting at least one thermochemical fluid into the subterranean geologic formation to raise a temperature of the subterranean geologic formation to at least 120° C. The method includes reacting the third composition respectively with the first composition and the second composition to form CaF2 and MgF2 in the subterranean geologic formation. The method includes precipitating the CaF2 and the MgF2 on sand grains of the subterranean geologic formation to bind the sand grains together into a consolidated matrix in the subterranean geologic formation.

Abstract: A method for drilling through a producing zone in a subterranean formation or for completing a wellbore in a subterranean formation, using a drill-in and completion fluid comprising a blend of a phosphate brine and water.

Abstract: A composition and method for use in drilling or completing a subterranean well comprising a solidsfree, high-density brine composed of alkali metal polytungstate and blends thereof. These high-density brines are also useful as wellbore fluids and other non-oilfield fluids requiring high density properties.

Abstract: A method of drilling a gas or oil well consists of use of a water-based drilling fluids containing high molecular weight crosslinked polyacrylic acid as viscosifying agent. The drilling fluid may further contain a lubricant, weighting agent and/or a wetting agent as well as a synthetic silicate or smectite clay. The aqueous based drilling fluid exhibits a coefficient of friction which is substantially close to the coefficient of friction of oil based drilling muds. The drilling fluid exhibits stability at well temperatures in excess of 150° C.

Abstract: Various salt crystal and agglomeration settling inhibiting agents may aid the ability to keep salt crystals of a desired particle size undissolved and dissolved in an aqueous drilling fluid, including, whey, wine-making residues, “steepwater solubles” or an organic liquid formed from the residue of wet processing of grains, sugar cane, sugar beets, and similar plants for the food and beverage industries for consumption by human or animals, and combinations thereof. A fluid so treated has more uniform properties and a reduced tendency for the salt therein to settle out as compared to an otherwise identical fluid absent an effective proportion or amount of the salt crystal agglomeration and settling inhibiting agent, even for saturated salt fluids. The salt crystal agglomeration and settling inhibiting agents are also believed to be useful in inhibiting or preventing the formation of gas hydrates under gas hydrate forming conditions of low temperature and high pressure.

Abstract: Compositions including relatively low reactivity acids and having a pH of from about 2 to about 5, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as fluids, in a non-limiting embodiment as drilling fluids, to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The fluids initially have low viscosities. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the fluids causing the VES to gel the fluid at the bottom of the hole and within the formation rock. Even when the subterranean formation contains naturally-occurring fractures, the viscosified fluid will reduce fluid loss into the formation. After drilling through the targeted formation, internal breakers in the viscosified fluids will break down the fluids to permit their removal, and production of the well with very little or no near well bore damage.

Abstract: A drilling fluid and method for drilling in a coal containing formation. The method includes: providing a mixed metal-viscosified drilling fluid including at least 1% potassium salt; circulating the drilling fluid through the well; and drilling into a coal seam.

Abstract: A method for for drilling through a producing zone in a subterranean formation or for completing a wellbore in a subterranean formation, using a drill-in and completion fluid comprising a blend of a phosphate brine and water.

Abstract: A drilling fluid and method for drilling in a coal containing formation. The method includes: providing a mixed metal-viscosified drilling fluid including at least 0.05% calcium sulfate; circulating the drilling fluid through the well; and drilling into a coal seam.

Abstract: Methods relate to using phosphate and/or nitrate brines to reduce hydrate formation in flowlines under conditions conducive for hydrate formation in the absence of the phosphate and/or nitrate brine. The phosphate and/or nitrate brines may include compatible anti-corrosion additives.

Abstract: Additives and treatment fluids with improved shale inhibition, and associated methods of use in subterranean operations, are provided. The additives and treatment fluids used generally comprise a shale-inhibiting component and one or more silicates.

Abstract: The present invention relates to a powdery composition comprising a chloride selected from sodium chloride, magnesium chloride, calcium chloride, potassium chloride and mixtures thereof; metal particles of zinc and/or of aluminium and/or a metal salt; and optionally another corrosion inhibitor, and its method of preparation. It also relates to the use of metal particles in such compositions to protect steel or iron structures against the corrosion induced by chloride ions.

Abstract: A drilling fluid and method for drilling in a coal containing formation. The method includes: providing a mixed metal-viscosified drilling fluid including at least 1% potassium salt; circulating the drilling fluid through the well; and drilling into a coal seam.

Abstract: Spray dried emulsifier compositions are described, which have desirable emulsifying and wetting characteristics. Among other advantages, the solid particulate emulsifier compositions greatly reduce transportation costs and simplify the logistics and environmental concerns associated with shipping large volumes of solvent-containing liquids. The emulsifier comprises (1) a carboxylic acid terminated fatty amine condensate or (2) a modified tall oil or (3) a blend of (1) and (2) that is converted to its alkali or alkaline earth metal salt and spray dried.

Abstract: Drilling fluids comprising polymers containing hydroxylated structural units are useful as accretion inhibiting agents, and/or as fluid rheology controlling agents, and/or as filtrate reducing agents, and/or as lubricating agents.

Abstract: A drill-in and completion fluid for drilling through a producing zone in a subterranean formation or for completing a wellbore in a subterranean formation. The fluid comprises a blend of a phosphate brine and water.

Abstract: An underground formation is consolidated by (a) incorporating into a treatment fluid (i) at least one chemical substance which is capable of undergoing a chemical change that alters the physico-chemical environment of the treatment fluid and which is a bicarbonate or a compound that generates a phosphate, phosphoric acid, sulphate, sulphuric acid, hydrogen sulphide, S2?, carbon dioxide, bicarbonate, base or acid; and, optionally, (ii) at least one additional chemical substance selected from salts and complexes of metals having a valency of 2 or higher; introducing the treatment fluid into the formation; and allowing the chemical substance (i), alone or in combination with the optional chemical substance (ii), to undergo a chemical change that alters the physico-chemical environment of the treatment fluid such that a consolidating mineral is deposited in the underground formation.

Abstract: Drilling, drill-in and completion fluids containing nanoparticles for use in hydrocarbon drilling and recovery processes and methods related thereto are provided. The fluids also include a dual acting shield agent that shields the nanoparticles and also acts as a viscosifier. The fluids can be used in various types of hydrocarbon drilling and recovery processes, such as drilling, drill in, completion, and the like.

Abstract: The present invention relates to glycerol based drilling fluids. In particular, the invention relates to drilling fluids comprising a 95-20 volume % glycerol/water solution capable of stabilizing water-sensitive formations during drilling and the use of such solutions for drilling a well having water-sensitive formations.

Abstract: This invention relates to improved lubrication in drilling and completion fluids used in subterrane drilling for oil and gas. The addition of zinc dialkyl dithiophosphate (ZDDP) acts as a lubricant, an enhancer to other lubricants and rate of penetration enhancer.

Abstract: A synthetic glass family in the quaternary phase field of CaO—SiO2-Al2O3-MgO (CSAM) with hydraulic and pozzolanic properties for use in differing applications in the gas and oil well cementing area. A method of making a mud-to-cement (MTC) slurry and a method for treating oil and gas wells with the MTC slurry containing a homogenous amorphous synthetic glass made from a mixture of inorganic materials selected from the group consisting of CSAM, wherein the cementing glasses with the mixture of inorganic materials are in a 100% amorphous phase with a degree of crystallization of zero.

Abstract: Compositions including relatively low reactivity acids, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as drilling fluids to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The drilling fluids have low viscosities in the drilling pipe. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the drilling fluids causing the VES to gel the fluid at the bottom of the hole and the downhole annulus between the drilling pipe and the formation rock. The viscosified drilling fluid will reduce fluid loss and will carry no dissolved drilling debris to the surface. After drilling through the targeted formation, the internal breakers in the viscosified drilling fluids will break down the fluids to permit their removal, and the well is ready to produce with very little or no near well bore damage.

Abstract: A composition and method for breaking down and denaturing friction-reducing compound introduced into the ground during the drilling of gas and oil wells and for destroying other contaminants and biohazards naturally present within and artificially introduced into hydrocarbon wells, which are formed as a result of the drilling and pumping processes. The composition includes several species of oxidizing agent compounds that are effective in breaking down hydrogen sulfide produced by bacteria as well as the friction-reducing polymer used during drilling and several other organic compounds.

Abstract: An inhibitive water-based polymer mud system and method for using the system in drilling and in stabilizing wellbores is disclosed for use in water sensitive formations as an alternative to oil-based muds. The system comprises a substantially non-ionic low molecular weight polyacrylamide in combination with a substantially non-ionic high molecular weight polyacrylamide, preferably long chain alcohol or an amine or silicate shale inhibitor, and poly anionic cellulose.

Abstract: Various salt crystal and agglomeration settling inhibiting agents may aid the ability to keep salt crystals of a desired particle size undissolved and dissolved in an aqueous drilling fluid, including, whey, wine-making residues, “steepwater solubles” or an organic liquid formed from the residue of wet processing of grains, sugar cane, sugar beets, and similar plants for the food and beverage industries for consumption by human or animals, and combinations thereof. A fluid so treated has more uniform properties and a reduced tendency for the salt therein to settle out as compared to an otherwise identical fluid absent an effective proportion or amount of the salt crystal agglomeration and settling inhibiting agent, even for saturated salt fluids. The salt crystal agglomeration and settling inhibiting agents are also believed to be useful in inhibiting or preventing the formation of gas hydrates under gas hydrate forming conditions of low temperature and high pressure.

Abstract: This invention relates to improved lubrication in drilling and completion fluids used in subterrain drilling for oil and gas. The addition of zinc dialkyl dithiophosphate (ZDDP) acts as a lubricant, an enhancer to other lubricants and rate of penetration enhancer.

Abstract: A drilling fluid and method for drilling in a coal containing formation. The method includes: providing a mixed metal-viscosified drilling fluid including at least 1% potassium salt; circulating the drilling fluid through the well; and drilling into a coal seam.

Abstract: A water-based drilling fluid containing Mn3O4 has been found to be effective in providing petroleum reservoirs with the ability to flow naturally and achieve a return permeability of 90% or greater without the need for acidizing treatments.

Abstract: A completion and workover fluid composition comprising, water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient selected from the group consisting of inorganic salts, shale inhibitors, corrosion inhibitor, biocide, defoamers and finely divided solids particles (e.g., bentonite, attapulgite, sepiolite, calcium carbonate, etc.), depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent is an ethoxylated raw cotton linters or a modified ethoxylated raw cotton linters. The ethoxylated raw cotton linters provides comparable or better rheology and viscosity properties compared to high molecular weight commercial HECs made from purified cotton linters. These ethoxylated raw cotton linters derivatives are suitable for applications in oil-well servicing fluids, particularly to enhance functional properties of completion and workover fluids used during oil-well drilling operations.

Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid of potassium formate together with a cationic formation control additive.

Abstract: An under-balanced drilling fluid additive is disclosed which reduces reactive shale and/or clay swelling during under-balanced drilling operations, where the additive includes an effective amount of a choline salt. A method for under-balanced drilling is also disclosed including the step of circulating a drilling fluid including an effective amount of a choline salt to reduce reactive shale and/or clay swelling during under-balanced drilling operations.

Abstract: The invention provides a method of enhancing the recovery of shale-containing cuttings during the drilling of a borehole in a shale-containing subterranean formation which comprises adding to the drilling fluid circulating in the borehole a finely ground, very sparingly soluble, anhydrous, alkali metal silicate glassy material to provide the drilling fluid with a concentration of soluble silica in the range from about 0.1% to about 1.0% by weight of the aqueous phase of the drilling fluid. Preferably the drilling fluid has a pH in the range from about 8.0 to about 11.0, most preferably about 8.5 to less than 11.0. The preferred alkali metal is potassium.

Abstract: A composition and method for use in drilling or completing a subterranean well comprising a solids free, high-density brine composed of alkali metal polytungstate and blends thereof. These high-density brines are also useful as wellbore fluids and other non-oilfield fluids requiring high density properties.

Abstract: A water-based drilling fluid composition includes water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient of polymeric additive, inorganic salts, dispersants, shale stabilizers, weighting agents, or finely divided clay particles, depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent comprises carboxymethylated raw cotton linters (CM-RCL) made from the baled raw cotton linters or comminuted raw cotton linters with increased bulk density.

Abstract: An underground formation is consolidated by (a) incorporating into a treatment fluid (i) at least one chemical substance which is capable of undergoing a chemical change that alters the physico-chemical environment of the treatment fluid and which is a bicarbonate or a compound that generates a phosphate, phosphoric acid, sulphate, sulphuric acid, hydrogen sulphide, S2?, carbon dioxide, bicarbonate, base or acid; and, optionally, (ii) at least one additional chemical substance selected from salts and complexes of metals having a valency of 2 or higher; introducing the treatment fluid into the formation; and allowing the chemical substance (i), alone or in combination with the optional chemical substance (ii), to undergo a chemical change that alters the physico-chemical environment of the treatment fluid such that a consolidating mineral is deposited in the underground formation.

Abstract: A fluid breaking composition including an effective amount of an alkali chlorite and/or hyperchlorite is disclosed, where the composition reduces a viscosity of a polymer viscosified fluid to a desired low value at down hole conditions within a time period coincident with a formation stimulation time, generally between about 30 minutes and 195 minutes. Methods for making and using the breaking composition are also disclosed.

Abstract: Compositions and methods are given for delayed breaking of viscoelastic surfactant gels inside formation pores, particularly for use in hydraulic fracturing. Breaking inside formation pores is accomplished without mechanical intervention or use of a second fluid. Bromate oxidizing agents are used along with selected breaking activators for the bromate breaking compounds. Useful bromate breaking activators include acid-generating breaking activators, oxidizing sulfur containing breaking activators, and reducing agent breaking activators.

Abstract: Self-generating foamed fluids for circulation through a well during drilling operations and methods for circulating such self-generating foamed drilling fluids are provided for. The drilling fluid comprises an aqueous solvent, a polymer, a surfactant, a first foam generating agent, and a second foam generating agent. The first and second foam generating agents react to generate a gas within the drilling fluid and thereby to foam the drilling fluid. Preferably, the foam generating agents are selected such that they react to generate carbon dioxide. Preferably a base fluid comprising excess amounts of only one of the foam generating agents is pumped into the drill string using a hydraulic pump. The other foam generating agent then is injected in a controlled manner downstream of the circulation pump such that the drilling fluid is foamed after being pumped for circulation through the well. The novel drilling fluids preferably have a density of from about 5.8 lb/gal to about 0.

Abstract: Methods of reducing the fluid loss from a wellbore servicing fluid include combining a terpolymer with the wellbore servicing fluid to reduce the fluid loss from the fluid, followed by displacing the fluid into a wellbore. In an embodiment, the following monomers are used to make the terpolymer: from about 75 wt. % to about 95 wt. % of 2-acrylamido-2-methylpropanesulfonic acid or an alkali salt thereof; from about 3 wt. % to about 15 wt. % of acrylamide; and from about 3 wt. % to about 15 wt. % of N-vinyl-2-pyrrolidone, all weight percentages being based on a total weight of the monomers. The wellbore servicing fluid may comprise water or an aqueous salt solution such as a formate solution. The wellbore servicing fluid may also comprise clay such as montmorillonite and attapulgite clay.

Abstract: The invention discloses methods of formulating an alkali metal silicate-containing drilling fluid and drilling a well therewith. Thus an alkali metal silicate is added to an aqueous base drilling fluid, when the drilling fluid is being circulated while drilling, at a rate sufficient to react with the drilled cuttings and freshly exposed surface of the borehole while leaving very little excess soluble silicate in the drilling fluid circulated to the surface. The rate of addition of the silicate is based on the circulation rate of the drilling fluid in the wellbore and the volume of the hole being drilled.

Abstract: A method of improving the lubricity of an aqueous based drilling fluid composed of an aqueous base fluid, and a weighting agent. The method involves the addition of an effective amount of a phospholipid to substantially reduce the coefficient of friction when compared to the fluid absent the phospholipids. Preferably the phospholipids have the structure: in which R and R? are C6 to C25 hydrocarbon groups; and A is an anion to counter the cationic charge.

Abstract: The present invention relates to substantially hydrated cement particulates. More particularly, the present invention relates to compositions comprising substantially hydrated cement particulates and associated methods of use in drilling and subterranean applications. These substantially hydrated cement particulates may be included in drilling and subterranean treatment fluids, inter alia, as carrier particles for admixtures, lost circulation materials, density-varying additives, proppants, and the like.

Abstract: Low concentrations, 1–10% of potassium salt, especially potassium formate, are used in a drilling fluid in oil production. Preferably they are used with guar derivatives, most preferably carboxymethyl hydroxypropyl guar. The concentration of potassium formate is maintained at the desired level by adjusting the potassium formate to maintain a desired Zeta potential in the circulating drilling fluid. The potassium formate/guar derivative composition may be used in the substantial absence of hydrophilic clay additive.

Abstract: A solution containing a compound having the general formula XF.nH2O2, wherein X is K+, Na+ or NH4+ and n is an integer from 1 to 3 (e.g., a peroxysolvate of potassium fluoride compound such as potassium fluoride hydroperoxide (KF.H2O2)) is injected into a subterranean formation in order to increase its permeability, especially with respect to hydrocarbon flow. These compounds serve to dissolve a wide variety of subterranean formation minerals (e.g., siliceous materials as well as carbonaceous materials). Potassium hydrofluoride (KHF2), can be employed with these compounds to produce particularly efficacious subterranean formation treatment solutions.

Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid fluid of potassium formate together with a cationic formation control additive.

Abstract: An excavation fluid composition useful for enlarging a cavity in the earth includes a synthetic polymer and sodium silicate. The excavation fluid composition is formulated so as to enable the fluid in contact with unstable or sandy soils in the selected areas of the excavation to react and form silicate-based derivatives with lesser solubility, and movement and thus improve soil stability at the excavation wall.

Abstract: A nutrient source for marine organisms comprising: drilling fluids containing organic contaminants; a solidification agent; a cell transport agent; and a cellulosic additive.

Abstract: A drilling fluid or mud is described wherein the drilling fluid contains at least one alkali metal formate or monovalent carboxylic acid salt. The drilling fluid preferably further contains at least one emulsifier or surfactant and at least one hydrocarbon-based fluid. The drilling fluids of the present invention can contain other conventional ingredients. The present invention permits drilling fluids to be essentially solids free due to the use of the alkali metal formate.

Abstract: A drilling fluid or mud having several components, including leonardite (humic acid); potassium acetate; partially hydrolyzed polyacrylamide (PHPA); polyanionic cellulose polymer (PAC); sulfonated asphalt; sulfoalkylated tannin; polystyrene maleic anhydride copolymer; micronized cellulose fiber; calcium carbonate; and calcium carbonate. These components are preferably premixed in a dry formulation as a powder or as pellets, and shipped to the site in bags or bulk barrels. This offers substantial advantages over the prior art in that the drilling mud of the present invention may be formed simply by adding the dry mix to a predetermined amount of water, and is thus much easier to make than the prior art wet mix drilling fluids, which typically require precise ratios of several different powders and liquids to be mixed together. The humic acid serves as hydration buffer to help keep the powder or pellets dry and flowable.

Abstract: A composition for oil and gas drilling fluids containing organic contaminants comprising: a solidification agent; cell transport agent; a cellulosic additive; and wherein said composition comprises enough solidification agent to enable the solidification agent to electrolytically attract the organic contaminates to the surface of the solidification agent when hydrated.