Abstract: A lost circulation material (LCM) that includes whole date palm seeds. The whole date palm seeds LCM includes date palm seeds having lengths greater than 22.6 millimeters (mm), date palm seeds having lengths in the range of 16 mm to 22.6 mm, and date palm seeds having lengths in the range of 1 mm to less than 16 mm. Method of manufacturing the whole date palm seeds LCM include washing and drying whole date palm seeds, such that the drying includes air-drying, hot rolling, and cooling. Methods of reducing lost circulation are also provided.

Abstract: A method for improving the performance of fracturing processes in oil production fields may rely on polymer coated particles carried in the fracturing fluid. The particles may include heavy substrates, such as sand, ceramic sand, or the like coated with polymers selected to absorb water, increasing the area and volume to travel more readily with the flow of fluid without settling out, or allowing the substrate to settle out. Ultimately, the substrate may become lodged in the fissures formed by the pressure or hydraulic fracturing, resulting in propping open of the fissures for improved productivity.

Abstract: A drilling fluid composition including a viscosifier, treated date pit particles which are i) de-oiled and ii) treated with a base or both a base and an acid, and an aqueous base fluid, wherein the treated date pit particles are present in an amount of 0.01-5 wt %, relative to a total weight of the drilling fluid composition. A method of making the drilling fluid composition by de-oiling date pit particles, treating with a base or a base and an acid in a freeze/thaw process, and adding the freeze/thaw mixture to the viscosifier and the aqueous base fluid. A process for drilling a subterranean geological formation with the drilling fluid composition.

Abstract: A lost circulation material (LCM) that includes whole date palm seeds. The whole date palm seeds LCM includes date palm seeds having lengths greater than 22.6 millimeters (mm), date palm seeds having lengths in the range of 16 mm to 22.6 mm, and date palm seeds having lengths in the range of 1 mm to less than 16 mm. Method of manufacturing the whole date palm seeds LCM include washing and drying whole date palm seeds, such that the drying includes air-drying, hot rolling, and cooling. Methods of reducing lost circulation are also provided.

Abstract: A drilling fluid composition including a viscosifier, treated date pit particles which are i) de-oiled and ii) treated with a base or both a base and an acid, and an aqueous base fluid, wherein the treated date pit particles are present in an amount of 0.01-5 wt %, relative to a total weight of the drilling fluid composition. A method of making the drilling fluid composition by de-oiling date pit particles, treating with a base or a base and an acid in a freeze/thaw process, and adding the freeze/thaw mixture to the viscosifier and the aqueous base fluid. A process for drilling a subterranean geological formation with the drilling fluid composition.

Abstract: Provided here are various invert emulsion drilling fluid compositions. The invert emulsion fluid is a water in oil emulsion, which can include an invert emulsifier to stabilize the water in oil emulsion, a 16 to 18 carbon carboxylic acid, a 36 carbon fatty dimer diol, a polymeric filter control agent, and an inorganic mineral including one or more of lime, calcium chloride, and barite. The invert emulsion drilling fluids can be formulated to be substantially free of clay.

Abstract: Spacer compositions and products may include a biopolymer component, a plant fiber component, and a weighting agent component, and in further non-limiting embodiments may include xanthan gum, a blend of plant fibers, and a weighting agent component. These spacer compositions and spacer products may be utilized in well fluid operations, including well cementing operations and well completion operations.

Abstract: Methods for servicing subterranean wells are disclosed. Particularly, the use of a fiber-laden fluid to separate and prevent the commingling of two stationary process fluids after placement in the borehole of a subterranean well, or in a tubular body installed in a subterranean well. The fiber-laden fluids prevent the cement plug from descending through drilling fluid to the bottom of the well. It obviates the need for mechanical devices such as packers, or special adjustment of the process fluids' rheological properties.

Abstract: Cements, such as alkali activated aluminosilicate, may be used as coatings on proppants, such as brown sand and white sand, to improve the strength thereof. The resulting coated proppants show increased strength as well as produced fines of lower than about 10 wt % at 10,000 psi closure stress.

Abstract: Methods of inhibiting corrosion of a metal surface in a well or pipeline are provided. The methods include the steps of: (a) forming a fluid of: (i) an aqueous acid solution; and (ii) inulin; and (b) introducing the fluid into the well or pipeline. The methods have wide application in various kinds of operations involved in the production or transportation of oil and gas, such as acid stimulation or remedial treatment in a pipeline.

Abstract: Methods are disclosed for improved sand control, fines control, load recovery and well productivity, where the compositions comprise reaction products of an amine and a phosphate-containing compound.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.

Abstract: A hydraulic fracturing composition includes: a superabsorbent polymer in an expanded state and configured to break in response to a breaking condition; a plurality of proppant particles disposed in the superabsorbent polymer prior to release of the plurality of proppant particles from the superabsorbent polymer in response to breaking the superabsorbent polymer; and a fluid to expand the superabsorbent polymer into the expanded state. The hydraulic fracturing composition can be made by contacting a superabsorbent polymer with a fluid to expand the superabsorbent polymer into an expanded state; and disposing a plurality of proppant particles in the superabsorbent polymer to make the hydraulic fracturing composition.

Abstract: A proppant includes a particle and a hybrid coating disposed about the particle. The particle is present in an amount of from about 90 to about 99.5 percent by weight based on the total weight of the proppant and the hybrid coating is present in an amount of from about 0.5 to about 10 percent by weight based on the total weight of the proppant. The hybrid coating comprises the reaction product of an isocyanate component and an alkali metal silicate solution including water and an alkali metal silicate. A method of forming the proppant includes the steps of providing the particle, the isocyanate composition, and the alkali metal silicate solution. The method also includes the steps of combining the isocyanate composition and the alkali metal silicate solution to react and form the hybrid coating and coating the particle with the hybrid coating to form the proppant.

Abstract: A lost circulation material and method for well treatment employing the material that is effective at sealing or plugging fractured zones and has utility over a wide range of temperatures, including high temperatures. The lost circulation material includes particulate material to quickly de-fluidize the fluid formulation, fibrous material to suspend particles in the slurrified form of the composition and increase the shear strength of the resultant seal, and non-Portland cement material for increasing the compressive strength.

Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a wellbore servicing fluid comprising a lost-circulation composite material into a wellbore, wherein the lost-circulation composite material comprises a swellable component and a reinforcing component. A wellbore servicing fluid comprising a reinforcing component disposed within a swellable component wherein the swellable component comprises a crosslinked polymer.

Abstract: A well treatment composite comprising a well treatment agent adsorbed onto a water-insoluble adsorbent may be prepared by precipitating the well treatment agent, in the presence of a metal salt, from a liquid while the well treatment agent is being adsorbed onto the water-insoluble adsorbent. After a treatment fluid containing the composite is introduced into a well or a subterranean formation, the well treatment agent is slowly released from the composite. The composite permits a continuous supply of the well treatment agent into a targeted area and is particularly effective in high pH treatment fluids.

Abstract: A method of servicing a wellbore penetrating a formation comprising placing a wellbore servicing fluid comprising a modified proppant pack into the wellbore or formation wherein the modified proppant pack comprises a proppant and a self-assembly directing material. A modified proppant pack comprising a proppant and a self-assembly directing material comprising a water-soluble moiety, an oil-soluble moiety and a crosslinkable moiety.

Abstract: A method of treating a portion of a subterranean formation through the use of an aqueous fracturing fluid comprising dissolved therein from 0.3 to 3.0% by weight of a viscosifying agent, wherein the viscosifying agent consists of fast dissolving and easy dispersible glyoxalated, ground guar splits containing from 0.01 to 0.05% by weight of glyoxal.

Abstract: A cement retarder composition, method, kit and system are herein disclosed. Seeds are added to cement to delay the setting of cement. Cement retarders are added to cement to delay the setting of the cement until it is pumped to the desired position.

Abstract: The present invention relates to compositions comprising a plant material, and methods for using the same in extracting or removing a hydrocarbon-containing substance from a substrate or remediating a substrate.

Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treating composition and treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.

Abstract: Disclosed are spacer fluids comprising cement kiln dust (“CKD”) and methods of use in subterranean formations.

Abstract: Method for substantially sealing at least a portion of a wall of a wellbore. Method includes selecting a fracture sealing width defined by the portion of the wellbore wall and the formation, and formulating a fracture sealing composition based on the fracture sealing width. Sealing fluid includes drilling fluid, cementing slurry, completion fluid, and a concentration of particulates forming the fracture sealing composition. The method also includes determining a spurt loss volume of the sealing fluid based at least on the fracture sealing width, determining a fracture volume capacity based at least on the fracture sealing width, and comparing the spurt loss volume of the sealing fluid to the fracture volume capacity. If the sealing fluid has a spurt loss volume less than or equal to the fracture volume capacity, the sealing fluid is pumped into the wellbore, wherein the sealing fluid forms a sealing relationship with the fracture.

Abstract: A plurality of particles comprising an elastomer-modified crosslinked aromatic epoxy vinyl ester polymer, wherein a particle from the plurality of particles maintains at least 50 percent of its height under a pressure of 1.7×107 Pascals at a temperature of at least 150° C. is disclosed. Mixtures of the plurality of particles and other particles, fluids containing the plurality of particles, methods of making the plurality of particles, and methods of fracturing a subterranean geological formation are also disclosed.

Abstract: Cement compositions comprising carboxylated inulin and methods of using the same to cement a workspace. In one embodiment, a method of cementing includes providing a cement composition comprising a carboxylated inulin, for example, in a subterranean formation. The method further includes allowing the cement composition to set. In some embodiments, the cement composition has a thickening time of from about 2 hours to about 11 hours. In other embodiments, the cement composition has a viscosity that is about constant for a period of time after the cement composition is placed.

Abstract: A proppant comprises a particle and a polycarbodiimide coating disposed on the particle. The polycarbodiimide coating comprises the reaction product of an isocyanate reacted in the presence of a phospholene oxide catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the isocyanate, providing the phospholene oxide catalyst, reacting the isocyanate in the presence of the phospholene oxide catalyst to form the polycarbodiimide coating, and coating the particle with the polycarbodiimide coating.

Abstract: A method and apparatus for treating a subterranean formation traversed by a wellbore including forming an emulsion comprising oil, acid, and particulate, wherein the forming the emulsion is prepared on the fly, and introducing the emulsion into a wellbore.

Abstract: A composition for wellbore consolidation comprises fibers having a core formed from a material that is electrically and/or magnetically susceptible, and a polymeric coating. When the composition is placed in a wellbore in a zone to be consolidated and an electric current or magnetic field is applied, the fibers bond together by melting or setting of the polymeric coating.

Abstract: Methods that comprise selecting proppant for use in a fracturing fluid based on one or more factors, wherein the one or more factors comprise an interaction between the proppant and the fracturing fluid. Methods that comprise designing a treatment fluid that comprises a gelled base fluid and a particulate based on one or more factors, wherein the one or more factors comprise an interaction between the particulate and the gelled base fluid.

Abstract: Fiber aggregate comprising organic polymeric fibers, wherein the organic polymeric fibers have an average length in a range from 2 to 20 millimeters, an average diameter up to 100 micrometer, and comprise at least 75 percent by solid volume of the fiber aggregate, wherein the fiber aggregate has an unrestrained bulk density of at least 0.05 g/cm3, and wherein at least 85% by volume of the fiber aggregate disassociates to provide dispersed fibers. The fiber aggregates are useful, for example, for flowback control in wellbores and reservoirs.

Abstract: Embodiments disclose method and compositions that comprise cement kiln dust and rice husk ash. An embodiment comprises a method of cementing comprising: placing a settable composition into a subterranean formation, the settable composition comprising cement kiln dust, rice husk ash, and water; and allowing the settable composition to set.

Abstract: A well treatment composite comprising a well treatment agent adsorbed onto a water-insoluble adsorbent may be prepared by precipitating the well treatment agent, in the presence of a metal salt, from a liquid while the well treatment agent is being adsorbed onto the water-insoluble adsorbent. After a treatment fluid containing the composite is introduced into a well or a subterranean formation, the well treatment agent is slowly released from the composite. The composite permits a continuous supply of the well treatment agent into a targeted area and is particularly effective in high pH treatment fluids.

Abstract: Methods of inhibiting corrosion of a metal surface in a well or pipeline are provided. The methods include the steps of: (a) forming a fluid of: (i) an aqueous acid solution; and (ii) inulin; and (b) introducing the fluid into the well or pipeline. The methods have wide application in various kinds of operations involved in the production or transportation of oil and gas, such as acid stimulation or remedial treatment in a pipeline.

Abstract: Pre-coated particulate for use in a subterranean operation comprising a particulate; and a film coated onto a surface of the particulate. The film is formed by allowing an anionic polymer and a cationic surfactant to contact the surface of the particulate, and allowing the anionic polymer and the cationic surfactant to interact with each other. In some cases, the anionic polymer is selected from the group consisting of a polyacrylamide; an alkylpolyacrylamide; a copolymer of polyacrylamide, with ethylene, propylene, and styrene; a copolymer of alkylpolyacrylamide with ethylene, propylene, and styrene; a polymaleic anhydride; and any derivatives thereof.

Abstract: A wellbore fluid that includes an oleaginous continuous phase; a non-oleaginous phase; and a polymeric additive formed by mixing at least one lipophilic monomer and at least one crosslinking agent, wherein the at least one lipophilic monomer is at least one of an epoxide-functionalized derivative of at least one selected from soybean oil, linseed oil, rapeseed oil, cashew nut shell oil; perilla oil, tung oil, oiticia oil, safflower oil, poppy oil, hemp oil, cottonseed oil, sunflower oil, high-oleic triglycerides, triglycerides of euphorbia plants, peanut oil, olive oil, olive kernel oil, almond oil, kapok oil, hazelnut oil, apricot kernel oil, beechnut oil, lupine oil, maize oil, sesame oil, grapeseed oil, lallemantia oil, castor oil, herring oil, sardine oil, menhaden oil, whale oil, tall oil, and synthetic aliphatic or aromatic ethers, and the at least one crosslinking agent includes at least one selected from amines, alcohols, phenols, thiols, carbanions, carboxylates, and mixtures thereof is disclosed.

Abstract: A method is disclosed for reducing lost circulation in drilling wells, employing composite materials as lost circulation materials. The composites comprise a thermoplastic polymer and cellulosic fibers. Optionally the composites may include other components such as calcium carbonate, clay, oil and other blending agents.

Abstract: Methods and compositions that include a method of cementing comprising providing a cement composition comprising water, a hydraulic cement, and an additive comprising at least one additive selected from the group consisting of a stevia retarder and inulin; placing the cement composition in a subterranean formation; and permitting the cement composition to set in the formation.

Abstract: A proppant comprises a particle and a polyamide imide coating disposed on the particle. A method of forming the proppant comprises the steps of providing the particle, providing the polyamide imide coating, and coating the particle with the polyamide imide coating.

Abstract: A proppant comprises a particle and a polycarbodiimide coating disposed on the particle. The polycarbodiimide coating comprises the reaction product of a polymeric isocyanate and a monomeric isocyanate, in the presence of a catalyst. A method of forming the proppant comprises the steps of providing the particle, providing the polymeric isocyanate, providing the monomeric isocyanate, providing the catalyst, reacting the polymeric isocyanate and the monomeric isocyanate in the presence of the catalyst to form the polycarbodiimide coating, and coating the particle with the polycarbodiimide coating.

Abstract: A lost circulation material and method for well treatment employing the material that is effective at sealing or plugging small fissures and large fractures and has utility over a wide range of temperatures, including high temperatures. The material has an optimized bimodal particle distribution and optionally has a polymer flocculent or water swellable polymer.

Abstract: A process for minimizing breaking of an emulsion type drilling fluid system comprising one or more fibrous lost circulation material, the process comprising: determining the water retention value of one or more candidate fibrous lost circulation materials; and, formulating the emulsion type drilling fluid system to comprise fibrous lost circulation material consisting of one or more of the candidate fibrous lost circulation materials having a water retention value of about 1 or less.

Abstract: A method and apparatus for treating a subterranean formation traversed by a wellbore including forming an emulsion comprising oil, acid, and particulate, wherein the forming the emulsion is prepared on the fly, and introducing the emulsion into a wellbore.

Abstract: The invention provides a well treatment composition comprising: a viscoelastic surfactant or a cementing composition and an environmentally friendly component made of cellulosic matrix with organic acid trapped within. A method is disclosed comprising introducing into a wellbore penetrating a subterranean formation an environmentally friendly component made of cellulosic matrix with organic acid trapped within.

Abstract: Incorporating water-based polymer breakers, such as oxidizers, enzymes and/or acids, into a mixture of an oil and oil-soluble surfactants creates an emulsion that can then perform as a dual-functional breaker for reducing the viscosity of hybrid fluids gelled with both a viscoelastic surfactant (VES) and a polymer. The outer phase of the dual-functional breaker emulsion is oil, e.g. a mineral oil, containing an oil-soluble surfactant that will, over time and with heat, break the VES portion of the gel. As it does so, the polymer breaker in the internal aqueous phase will be released to then break the polymer portion of the gel. The polymer breaker will not start to break the polymer gel before the oil-soluble surfactant starts to break the VES gel. The overall breaking using the emulsion is slower as compared to introducing the polymer breaker and the oil-soluble surfactant in a non-emulsified form.

Abstract: An adaptive cementitious composite composition, comprising: a coarse particulate material such as sand or proppant; a series of other particulate or fibrous materials; and a carrier fluid; the sand and other particulate materials being present as a series of coarse, medium and fine particle sizes in ratios selected to provide an optimized packing volume fraction; wherein the sand or proppant is coated with a resin and at least one of the other particulate or fibrous materials is a material that can be modified when placed at a downhole location.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: Methods and compositions that include a method of cementing comprising providing a cement composition comprising water, a hydraulic cement, and an additive comprising at least one additive selected from the group consisting of a stevia retarder and inulin; placing the cement composition in a subterranean formation; and permitting the cement composition to set in the formation.

Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treating composition and treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.

Abstract: An aqueous viscoelastic surfactant (VES) fluid foamed or energized with carbon dioxide, in which the VES is more compatible with the carbon dioxide, is made by the addition of one or more than one synergistic co-surfactant. The synergist co-surfactant includes quaternary amines and ethoxylated carboxylates having a hydrophobic chain shorter than the hydrophobic chain of the VES. Improved compatibility is evidenced for a given surfactant concentration either by formation and maintenance of a foam under conditions at which the foam could not otherwise have been formed or maintained, or by either higher viscosity of the foamed fluid at a given temperature or longer foam life at a given temperature or a higher temperature at which useful fluid viscosity can be generated or maintained for a useful time. The aqueous carbon dioxide foamed fluids may be used in acidizing, acid fracturing, gravel packing, diversion, and well cleanout.