Polymer Derived From Acrylic Acid Monomer Or Derivative Patents (Class 507/224)
  • Publication number: 20080035344
    Abstract: A delayed gelling system useful in conformance control in the production of petroleum from subterranean formations is disclosed. The gelling system comprises an acidic aqueous solution of acid-soluble or cationic polyacrylamide, an at least partially neutralized acid aluminum salt, an activator comprising a hydroxyl donor, and an optional gel modifier. The gelling system may be pumped into formations with excessive water production and thermally activated in the formation at downhole conditions to form a co-gel of polyacrylamide interspersed in an inorganic gel network to reduce water production.
    Type: Application
    Filed: August 7, 2006
    Publication date: February 14, 2008
    Inventors: Nadir Odeh, Mathew Samuel, Philippe Enkababian, Keng Seng Chan
  • Patent number: 7300973
    Abstract: A composition comprising expandable cross linked polymeric microparticles having an unexpanded volume average particle size diameter of from about 0.05 to about 10 microns and a cross linking agent content of about 6,000 to less than about 9,000 ppm of labile cross linkers and from 0 to about 300 ppm of non-labile cross linkers, useful for modifying the permeability of subterranean formations and increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: November 27, 2007
    Assignee: Nalco Company
    Inventors: Kin-Tai Chang, Harry Frampton, James C. Morgan
  • Patent number: 7287586
    Abstract: The invention provides for a composition for treating a subterranean formation, the composition comprising a water-swellable agent and a sealing agent. Preferably, the water-swellable agent: i) absorbs greater than 100 weight % of water; and ii) swells to greater than 100 weight % as it absorbs water. Preferably the sealing agent: i) is greater than 0.01 weight % soluble in water; and ii) forms a three dimensional gel structure in water. The invention also provides for a method of treating a subterranean formation penetrated by a wellbore, the method comprising the steps of: a) introducing a sealing agent into the subterranean formation; and b) introducing a water-swellable agent into the subterranean formation.
    Type: Grant
    Filed: February 1, 2005
    Date of Patent: October 30, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Don M. Everett, Larry S. Eoff, Eldon D. Dalrymple
  • Patent number: 7279446
    Abstract: A method of treating a subterranean formation by injecting down a well an aqueous fluid containing a viscoelastic surfactant fluid comprising an enhanced shear recovery agent wherein shear recovery time of the viscoelastic surfactant fluid is reduced by the addition of the enhanced shear recovery agent, and a viscoelastic surfactant fluid composition thereof.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: October 9, 2007
    Assignees: Rhodia Inc., Schlumberger Technology Corporation
    Inventors: Allwyn Colaco, Jean-Pierre Marchand, Fang Li, Manilal S. Dahanayake
  • Patent number: 7276466
    Abstract: The present invention relates to improved methods and compositions for reducing the viscosity of subterranean servicing fluids where the servicing fluid has been cross-linked to increase its viscosity and that crosslinking can be reversed using a delayed release acid produced to reduce the fluid's pH.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: October 2, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Bradley L. Todd, Billy F. Slabaugh, Trinidad Munoz, Jr.
  • Patent number: 7270184
    Abstract: The invention provides a method of well treatment comprising introducing into the matrix surrounding a hydrocarbon well bore hole an emulsion the discontinuous phase of which comprises a non-polymerizable, water or oil miscible liquid carrier, a polymerizable monomer and a thermally activated polymerization initiator, said monomer constituting from 2 to 40% wt. of said discontinuous phase.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: September 18, 2007
    Assignee: Statoil ASA
    Inventors: Hans Kristian Kotlar, Birgitte Schilling, Johan Sjöblom
  • Patent number: 7271133
    Abstract: Methods for treating subterranean formations and aqueous treating fluid compositions are provided. The aqueous treating fluid compositions comprise water, a water soluble hydrophobically modified gelling agent polymer produced by grafting a low concentration of hydrophobic monomers thereon, and a low concentration of an ionic surfactant the hydrophobic chain portion of which is associated with the hydrophobic monomers grafted onto the gelling agent polymer resulting in gelling agent polymer molecules having increased radiuses of gyration.
    Type: Grant
    Filed: September 24, 2003
    Date of Patent: September 18, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jimmie D. Weaver, Billy F. Slabaugn
  • Patent number: 7270180
    Abstract: A formulation containing a copolymer derived from a cationic monomer effectively inhibits and controls the formation of inorganic scales. The formulation has particular application in the removal of zinc sulfide and iron sulfide scales formed when zinc bromide brines are used as completion fluids. The copolymer exhibit high solubility in high-density brines, such as zinc bromide brines. The polymers may be introduced into an oil or gas well as a portion of a carrier fluid or with brine. The preferred copolymer for use in the invention contains an acrylamide unit and a diallyldimethylammonium salt and, optionally, an acrylic acid or a salt thereof. The weight average molecular weight of such inhibitor copolymers is generally between from about 500,000 to about 5,000,000.
    Type: Grant
    Filed: January 3, 2007
    Date of Patent: September 18, 2007
    Assignee: BJ Services Company
    Inventors: Mingjie Ke, Qi Qu
  • Publication number: 20070204989
    Abstract: Expandable and hydrophilic polymeric particles may be made in a non-emulsion system, and with controllable hardness and delay in their time to swell in a fresh or salt water environment. These particles are prepared from combining monomers, controlled monomers, stable cross-linkers, initiators, and other agents, in aqueous solution. The controlled monomers induce kinetically controllable decomposition, degrading over time, thus inducing a desired time delay in particle swelling. The delay and degree of the swelling of the particles is controlled by selection of controlled monomer, stable cross-linking agents, monomers, and process conditions. These preformed particle gels are made to an initial particle size of 0.1 micron in diameter or larger via different grinding techniques. This composition is used for modifying the permeability of subterranean formations and thereby increasing the recovery rate of hydrocarbon fluids present in the formation.
    Type: Application
    Filed: February 28, 2007
    Publication date: September 6, 2007
    Inventor: Hongxin Tang
  • Patent number: 7261157
    Abstract: Methods for controlling particulate segregation comprising providing a mixture of an aqueous tackifying composition with a treatment fluid; slurrying the mixture with a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; and, placing the slurry into a portion of a subterranean formation. Methods for controlling particulate segregation comprising providing a treatment fluid; at least partially coating with an aqueous tackifying composition: a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; slurrying the two types of particulates into the treatment fluid; and, placing the slurry into a portion of a subterranean formation.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: August 28, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Matthew E. Blauch, Thomas D. Welton
  • Patent number: 7244694
    Abstract: The present invention relates to viscoelastic fluids that contain nanotube structures that may be used advantageously as oilfield stimulation fluids in many different applications, most particularly as a fracturing fluid. Viscoelastic fluid compositions of the present invention include an aqueous medium, a viscoelastic surfactant, an organic or inorganic acids, or salt thereof, organic acid salts, inorganic salts, and a nanotube component. The invention is also called to a methods of treating a subterranean well bores in which the viscoelastic fluid is injected into the wellbore to perform operations such as fracturing, drilling, acid fracturing, gravel placement, removing scale, matrix acidizing, and removing mud cake. Further, a method of preparing a nanotube viscoelastic fluid comprising the steps of effectively mixing a carbon nanotube component into a viscoelastic fluid, and sonicating the mixture in order to incorporate the carbon nanotube component is claimed.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: July 17, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Diankui Fu, Keith Dismuke, Stephen Davies, Ann Wattana
  • Patent number: 7237609
    Abstract: A method of stimulating and stabilizing an area of a subterranean formation comprising placing an acid fluid into an area of a subterranean formation and allowing the acid to at least partially dissolve a portion of the area of the subterranean formation; placing a consolidation fluid into the area of the subterranean formation; and, placing an afterflush fluid into the area of the subterranean formation. A method of stimulating and stabilizing an area of a subterranean formation comprising placing an acid fluid into an area of a subterranean formation and allowing the acid to at least partially dissolve a portion of the area of the subterranean formation; placing a consolidation fluid into the area of the subterranean formation; and, placing a fracturing fluid into the area of the subterranean formation at a pressure sufficient to create or extend at least one fracture therein.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: July 3, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Philip D. Nguyen
  • Patent number: 7220708
    Abstract: A method and composition is provided for a relative permeability modifying polymer for use with drilling fluids that comprises a water soluble polymer formed from a hydrophobic or hydrophobically modified hydrophilic monomer and a hydrophilic monomer. In an alternative embodiment, a method is provided for producing a water soluble polymer formed from a hydrophilic monomer for use as a relative permeability modifying polymer.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: May 22, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Frank Zamora, Larry S. Eoff, Eldon Dwyann Dalrymple, B. Raghava Reddy
  • Patent number: 7211550
    Abstract: An aqueous-based composition containing cesium formate and at least one chelating agent is described. Methods of removing scaling deposits, which may include alkaline earth metal sulfates, present on surfaces, including porous media, such as alkaline earth metal sulfate buildup in a well bore, is also described, wherein the method includes contacting the alkaline earth metal sulfate with the compositions of the present invention to remove the scaling deposits. A completion fluid containing at least one alkali metal formate, at least one acid and/or at least one chelating agent, and optionally at least one surfactant or mutual solvent is also described. Methods of removing a filter cake from a well bore surface, which may include weighting agents such as calcium carbonate, is also described, wherein the method includes contacting the filter cake with the completion fluid of the present invention.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: May 1, 2007
    Assignee: Cabot Corporation
    Inventors: William J. Benton, Neal F. Magri, James R. VonKrosigk, Michael T. Pelletier
  • Patent number: 7207387
    Abstract: The present invention relates to spacer fluids used in subterranean operations and, more particularly, to spacer fluids that comprise water-soluble relative permeability modifiers and methods of using the spacer fluids in subterranean operations. In one embodiment, the present invention provides a method of displacing a first fluid from a well bore that comprises introducing the first fluid into the well bore; and displacing the first fluid with a spacer fluid, the spacer fluid comprising water, and a water-soluble relative permeability modifier comprising a hydrophobically modified polymer or a hydrophilically modified polymer. In another embodiment, the present invention provides a spacer fluid that comprises water, and a water-soluble relative permeability modifier comprising a hydrophobically modified polymer or a hydrophilically modified polymer.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: April 24, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, B. Raghava Reddy, Eldon D. Dalrymple
  • Patent number: 7204311
    Abstract: Method of treating a portion of a subterranean formation comprising: placing a pre-pad fluid into a portion of a subterranean formation wherein the pre-pad fluid comprises a low-viscosity aqueous tackifying composition that comprises an aqueous tackifier compound and an aqueous fluid; placing a fracturing fluid into the portion of the subterranean formation at a pressure sufficient to create or extend at least one fracture therein; and, activating the aqueous tackifier compound with an activator so as to consolidate the unconsolidated particulates.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: April 17, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas D. Welton, Philip D. Nguyen, Matthew E. Blauch
  • Patent number: 7196040
    Abstract: A material and a device for releasing chemicals in a fluid environment is disclosed, and a method for releasing substances into downhole fluid environments. The invention also relates to materials for sand control and hydraulic fracturing. The substance release device typically comprises a polymeric material for releasing a substance into a downhole fluid environment in a well, and in preferred embodiments the material comprises a spherical, plastic chemical release capsule which is hard, permeable and may encapsulate a range of solids and/or liquids for subsequent release. These solids or liquids can include inhibitors such as scale inhibitors and other oilfield production chemicals for release into the wellbore of an oil or gas producing well or a water injection well.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: March 27, 2007
    Assignee: T R Oil Services Limited
    Inventors: Stephen Mark Heath, Hugh Malcolm Bourne
  • Patent number: 7182136
    Abstract: The present invention provides a method of stimulating a subterranean formation penetrated by a well. The formation has a water-bearing section and a hydrocarbon-bearing section. The method includes the steps of: (a) introducing into the formation an aqueous treatment fluid containing a hydrophobically-modified relative permeability modifier, and (b) introducing an acidizing treatment fluid into the formation. The hydrophobically-modified RPM can be formed and introduced into the formation in several ways. For example, the hydrophobically-modified RPM can be the reaction product of a hydrophilic polymer and a hydrophobic compound that are capable of reacting with each other. The hydrophilic polymer is a polymer containing reactive amino groups in the polymer backbone or as pendant groups, which are capable of reacting with a hydrophobic alkyl halide compound.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: February 27, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Eldon D. Dalrymple, Larry Eoff, B. Raghava Reddy, Jim Venditto
  • Patent number: 7159656
    Abstract: Methods of temporarily reducing the permeability of one or more selected sections of a subterranean formation penetrated by a horizontal well bore and the flow of water or water and hydrocarbons or hydrocarbons therefrom are provided. The methods comprise the steps of preparing or providing an aqueous treating fluid comprising water and a water-soluble formation permeability reducing agent, introducing the aqueous treating fluid into one or more selected sections and when required, contacting the one or more selected sections with an aqueous treating fluid comprising water and a formation permeability restoring chemical.
    Type: Grant
    Filed: February 18, 2004
    Date of Patent: January 9, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, B. Raghava Reddy
  • Patent number: 7159655
    Abstract: A formulation containing a copolymer derived from a cationic monomer effectively inhibits and controls the formation of inorganic scales. The formulation has particular application in the removal of zinc sulfide and iron sulfide scales formed when zinc bromide brines are used as completion fluids. The copolymer exhibit high solubility in high-density brines, such as zinc bromide brines. The polymers may be introduced into an oil or gas well as a portion of a carrier fluid or with brine. The preferred copolymer for use in the invention contains an acrylamide unit and a diallyldimethylammonium salt and, optionally, an acrylic acid or a salt thereof. The weight average molecular weight of such inhibitor copolymers is generally between from about 500,000 to about 5,000,000.
    Type: Grant
    Filed: September 25, 2003
    Date of Patent: January 9, 2007
    Assignee: BJ Services Company
    Inventors: Mingjie Ke, Qi Qu
  • Patent number: 7151077
    Abstract: The present invention relates to methods and compositions for treating subterranean formations. More particularly, the present invention relates to polymersomes, viscosifying agents that comprise polymersomes, and associated methods of use. In some embodiments, the present invention discloses methods of treating a section of a subterranean formation that comprises the steps of providing a viscosified treatment fluid that comprises an aqueous-based component, and a viscosifying agent that comprises a polymersome; and treating the section of the subterranean formation. In other embodiments, the present invention discloses methods of viscosifying a treatment fluid, suspending particulates in a treatment fluid, fracturing a subterranean formation, providing sand control in a section of a subterranean formation, and encapsulating treatment fluid additives.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: December 19, 2006
    Assignees: Halliburton Energy Services, Inc., Princeton University
    Inventors: Robert K. Prud'homme, Lewis R. Norman, Douglas H. Adamson, Mustafa Erhan Yildiz, Ian D. Robb
  • Patent number: 7151078
    Abstract: A controlled-gelation aqueous solution is proposed. The solution contains a hydrophobically-aggregating gelling agent, and an effective amount of an inhibitor which suppresses hydrophobic aggregation of the gelling agent. The inhibitor is soluble in water so that when the controlled-gelation aqueous solution contacts aqueous media the inhibitor disperses and gelation occurs. However, the inhibitor is substantially insoluble in hydrocarbons so that when the controlled-gelation aqueous solution contacts hydrocarbon media the inhibitor continues to suppress said hydrophobic aggregation and gelation is suppressed. The solution may be used to control the flow of water into oil wells, making it possible to reduce the water cut.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: December 19, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Yury Dmitrievich Zaroslov, Olga Evgenievna Filippova, Inesa Vasilievna Blagodatskikh, Alexei Removich Khokhlov
  • Patent number: 7128148
    Abstract: The present invention provides a method and treatment fluid for blocking the permeability of an elevated-temperature zone in a reservoir of a subterranean formation penetrated by a wellbore, the method comprising the steps of: a) selecting the zone to be treated, wherein the upper limit of the temperature range of the zone is equal to or greater than 190° F. (88° C.); b) forming a well treatment fluid comprising: water; a water-soluble polymer comprising polymerized vinyl amine units; and an organic compound capable of crosslinking with the vinyl amine units of the water-soluble polymer; c) selecting the water-soluble polymer and the organic compound of the well treatment fluid such that the gel time of the well treatment fluid is at least 2 hours when measured at the upper limit of the temperature range of the zone; and d) injecting the well treatment fluid through the wellbore and into the zone.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: October 31, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, Michael J. Szymanski
  • Patent number: 7114568
    Abstract: A method and composition is provided for a relative permeability modifier for use with aqueous well treatment fluids that comprises a hydrophobically modified water soluble polymer or a hydrophilically modified water soluble polymer.
    Type: Grant
    Filed: April 15, 2004
    Date of Patent: October 3, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, Eldon D. Dalrympre, B. Raghava Reddy, Frank Zamora
  • Patent number: 7104327
    Abstract: The present invention provides methods of fracturing high temperature subterranean zones and viscous aqueous foamed fracturing fluids therefor. A fracturing fluid of this invention comprises water, a terpolymer of 2-acrylamido-2-methylpropane-sulfonic acid, acrylamide and acrylic acid or salts thereof, a gas, a foaming agent and a viscosity breaker for effecting a controlled reduction in the viscosity of the fracturing fluid.
    Type: Grant
    Filed: August 19, 2003
    Date of Patent: September 12, 2006
    Assignee: Halliburton Engery Services, Inc.
    Inventors: Phillip C. Harris, Stanley J. Heath, Gary P. Funkhouser
  • Patent number: 7091160
    Abstract: Methods and compositions for reducing the permeabilities of subterranean formations or zones are provided. The methods of the invention are basically comprised of introducing an aqueous composition into the formation or zone comprised of water, a water soluble organic polymer, an organic gelling agent for cross-linking the organic polymer and a gel retarder comprised of a chemical compound that hydrolyzes or thermolyzes to produce one or more acids in the composition and then allowing the aqueous composition to form a cross-linked gel in the formation or zone.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: August 15, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Bach Dao, Marco Verlaan, Ron Bouwmeester, Ewout Biezen, B. Raghava Reddy
  • Patent number: 7091159
    Abstract: A composition of matter for use in stablizing shale formations in earth boreholes comprising polymeric products, e.g., polymers of a dialkyl aminoalkyl methacrylate, which can optionally be quaternized with an alkyl halide to produce drilling fluid additives which stablize borehole formations containing reactive clays in the presence of an aqueous medium.
    Type: Grant
    Filed: September 6, 2002
    Date of Patent: August 15, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, B. Raghava Reddy, J. Michael Wilson
  • Patent number: 7084094
    Abstract: A process for treating a hydrocarbon-bearing formation having at least one hydrocarbon bearing zone and at least one water bearing zone wherein the ratio of the permeability of the hydrocarbon bearing zone(s) to the permeability of the water bearing zone(s) is in the range of from 1:20 to 3:1 comprising: a) sequentially injecting into the formation: (i) an aqueous polymer solution comprising 0.01 to 0.5 weight percent of a water-soluble polymer having from 0.01 to 7.5 mole % of crosslinkable carboxylate and/or phosphonate groups and a molecular weight in the range of 250,000 to 12,000,000; and (ii) an aqueous solution of a crosslinking agent; and b) back-producing the aqueous polymer solution over the crosslinking agent so that the polymer crosslinks within the formation to form a gel which is collapsible to allow hydrocarbon flow.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: August 1, 2006
    Assignee: TR Oil Services Limited
    Inventors: Alistair Manson Gunn, James Charles Morgan
  • Patent number: 7084096
    Abstract: A non-aqueous suspension including boron-containing particulates, a low molecular weight polyalkylene glycol and a suspension stabilizer is provided. Methods of crosslinking water soluble polymers and of fracturing a subterranean formation are also provided.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: August 1, 2006
    Assignee: Benchmark Research & Technology, LLC
    Inventors: William Franklin Harris, Jr., David Nigel Harry, Xiaoping Qiu
  • Patent number: 7021378
    Abstract: A method for retaining a treatment chemical in a subterranean formation containing hydrocarbons is disclosed. The method includes first preparing an emulsion. The emulsion contains an oil continuous phase and first and second aqueous phases. The first aqueous phase includes a treatment chemical, such as a scale inhibitor. The second aqueous phase comprises a retention enhancing chemical which is to be reacted with the treatment chemical in the subterranean formation. Preferably, the first and second aqueous phases remain generally separately dispersed and stable within the oil continuous phase prior to being introduced into the subterranean formation. The emulsion is then placed down a well bore and into the subterranean formation.
    Type: Grant
    Filed: December 31, 2003
    Date of Patent: April 4, 2006
    Assignee: Chevron U.S.A.
    Inventor: Gabriel Prukop
  • Patent number: 6986391
    Abstract: The present invention provides improved methods of fracturing subterranean zones penetrated by well bores and improved fracturing fluids. The fracturing fluids are basically comprised of water, a terpolymer of 2-acrylamido-2-methylpropane sulfonic acid, acrylamide and acrylic acid, or its salts, a cross-linking agent for the terpolymer and a delayed viscosity breaker for effecting a controlled reduction in the viscosity of the fracturing fluid.
    Type: Grant
    Filed: November 26, 2002
    Date of Patent: January 17, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Gary P. Funkhouser, Lewis R. Norman
  • Patent number: 6936574
    Abstract: The present invention provides a cement composition and a process for using the cement composition to inhibit gas migration from a subterranean zone into the cement. The process comprises displacing a gelling additive, preferably comprised within a cement composition, into a well bore such that the gelling additive passes into the subterranean zone, and allowing the gelling additive to form a crosslinked gel in the subterranean zone to inhibit gas migration from the subterranean zone. The crosslinked gel acts as a barrier to gas in the subterranean zone and thereby inhibits the gas from passing into the cement and forming flow channels therein before the cement can set.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: August 30, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Bach Dao, Ewout Biezen, Jan Pieter Vijn, Thien Pham
  • Patent number: 6927194
    Abstract: For well kill treatment to prevent the intrusion of formation fluids into the wellbore while the well is open, a well kill additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, filter aid, and optionally, a reinforcing material of fibers and/or comminuted plant materials. The method of forming a well kill fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the wellbore.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: August 9, 2005
    Inventor: Boyce Donald Burts, III
  • Patent number: 6894007
    Abstract: The invention relates to the use of compounds of the formula (1) in which R1 is C1- to C24-alkyl, C2- to C24-alkenyl or a C6- to C18-aryl radical which may be substituted by a C1- to C24-alkyl group, R2, R3 independently of one another, are hydrogen, C1- to C18-alkyl, or C8- to C7-cycloalkyl, or R2 and R3, including the nitrogen atom to which they are bonded, form a ring of 4 to 8 ring atoms, in which oxygen or nitrogen atoms may also be present in addition to carbon. A are identical or different C2- to C4-alkylene radicals, B is C1- to C7-alkylene, and n is an integer from 1-40, as gas hydrate inhibitors.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: May 17, 2005
    Assignee: Clariant GmbH
    Inventors: Peter Klug, Uwe Dahlmann, Michael Feustel
  • Patent number: 6875729
    Abstract: A method and sealing composition is provided for sealing a subterranean zone penetrated by a well bore, wherein the sealing composition comprises a mixture of cementitious material, cross-linkable material, and sufficient water to form a slurry.
    Type: Grant
    Filed: June 4, 2002
    Date of Patent: April 5, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Marco L. Verlaan, Niels van der Werff
  • Patent number: 6855672
    Abstract: Disclosed is a copolymer useful for preparing acid gels comprising a copolymer having a copolymer backbone, the copolymer having a general formula: wherein: (a) A is an H or other terminating group; (b) R1 is an OH or NH2; (c) R2 is an O or NH; (d) Z is an integer having a value of from 1 to 4; (e) X and Y are present in a ratio (X:Y) of from 3:2 to 4:1; (f) structures I and II are present as blocks or randomly distributed along the copolymer backbone; and wherein the copolymer has a molecular weight of from about 1,000,000 to about 10,000,000.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: February 15, 2005
    Assignee: Baker Hughes Incorporated
    Inventors: David J. Poelker, JoAnn McMahon, Dee Harkey
  • Patent number: 6852676
    Abstract: Well completion foamed spacer fluids and methods of using the foamed spacer fluids are provided. A method of the invention for displacing a first fluid from a well bore with an incompatible second fluid comprises the following steps. A foamed spacer fluid is placed between the first and second fluids to separate the first and second fluids and to remove the first fluid from the walls of the well bore. Thereafter, the first fluid and the foamed spacer fluid are displaced from the well bore with the second fluid.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: February 8, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, James E. Griffith, Bobby J. King
  • Patent number: 6837316
    Abstract: Methods of consolidating formations include drilling a well bore with a drilling fluid that comprises water, a polymeric cationic catalyst which is adsorbed on minerals and rocks in weak unconsolidated zones or formations and then further contacting the unconsolidated formation with a treating fluid comprising a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, and a water soluble or dispersible thermoset resin which cross-links the polymer, is catalyzed and cured by the catalyst and consolidates the weak zone or formation so that sloughing is prevented.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: January 4, 2005
    Assignee: Halliburtn Energy Services, Inc.
    Inventors: B. Raghava Reddy, Larry S. Eoff, Donald L. Whitfill, J. Michael Wilson, Denise Berryhill, Russel M. Fitzgerald, Thomas E. Becker, Jimmie D. Weaver
  • Patent number: 6838417
    Abstract: Compositions and methods are provided for reducing the permeability of subterranean zones. More particularly, water-soluble polymeric compositions which form cross-linked gels in the zones. In general, the composition comprises (a) at least one water-soluble polymer; (b) at least one organic gelling agent capable of cross-linking the water-soluble polymer; and (c) at least one water-soluble formate. More preferably, the water-soluble polymer is a copolymer of (i) at least one non-acidic ethylenically unsaturated polar monomer, and (ii) at least one copolymerisable ethylenically unsaturated ester. The gelling agent is preferably selected from the group consisting of a polyalkyleneimine, polyfunctional aliphatic amine, an aralkylamine, and a heteroaralkylamine. The preferred water-soluble formate is selected from the group consisting of ammonium formate, lithium formate, sodium formate, potassium formate, rubidium formate, cesium formate, and francium formate.
    Type: Grant
    Filed: June 5, 2002
    Date of Patent: January 4, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ron C. M. Bouwmeester, Klaas A. W. Van Gijtenbeek
  • Patent number: 6838418
    Abstract: There is described a fracturing fluid comprising a polar base, 0.1-5.0% of a mid-molecular weight polyacrylate, and an activator for ionizing the polyacrylate to a hydroscopic state.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: January 4, 2005
    Assignees: Calfrac Well Services Ltd., Chemergy Ltd.
    Inventors: Travis L. Allan, Junad Amin, Alan K. Olson, Ronald G. Pierce, Dwight M. Bobier
  • Patent number: 6823940
    Abstract: Methods of consolidating unconsolidated weak zones or formations and forming chemical casings include drilling a well bore with a drilling fluid having a pH in the range of from about 6 to 10 and that comprises water, a polymeric cationic catalyst which is adsorbed on the mineral surfaces in the weak zone, a particulate curable solid thermoset resin and a delay acid catalyst for curing the solid resin, and forming a filter cake on the walls of the well bore. The filter cake is then contacted with a treating fluid comprising a water soluble or water dispersible polymer which is capable of being cross-linked by a thermoset resin and causing the resin to be hard and tough when cured, and a water soluble or dispersible thermoset resin, whereby the treating fluid components deposit on the filter cake and the thermoset resin cures into a hard and tough cross-linked chemical casing thereon.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: November 30, 2004
    Assignee: Halliburton Energy Services, Inc.
    Inventors: B. Raghava Reddy, Larry S. Eoff, Donald L. Whitfill, J. Michael Wilson, Denise Berryhill, Russel M. Fitzgerald, Thomas E. Becker, Jimmie D. Weaver
  • Patent number: 6818597
    Abstract: Liquid water soluble polymer suspensions in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed water soluble polymer. The suspensions enable a user to rapidly add the suspension to water, being mixed at low speeds, without the formation of lumps or fisheyes and without generating fugitive dust in the process. The suspensions are environmentally safe and biodegradable. Unlike many other liquid polymer suspensions, the suspensions exhibit minimal oil or grease upon dilution. They contain no surfactants that can add to the oil and grease determination. The suspensions and the fluids produced by diluting the fluids to a working concentration of the water soluble polymer exhibit low toxicity to marine organisms and to humans. The suspensions can be manufactured from ingredients suitable for use in personal care applications such as cosmetics, shampoos and the like.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: November 16, 2004
    Assignee: Benchmark Research & Technology, Inc.
    Inventor: William Franklin Harris
  • Patent number: 6806232
    Abstract: Well-working fluid compositions containing certain processed inorganic, oil and water wettable ground elastomeric crumb rubber materials to decrease the seepage loss of various fluids to subterranean formations in which these well working fluids are required and utilized are disclosed. Also disclosed is a method of reducing the seepage and whole mud loss of these well working fluids utilizing such ground elastomeric crumb rubber materials.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: October 19, 2004
    Inventor: Steve Cart
  • Patent number: 6803348
    Abstract: The use of a hydrophobically modified water soluble polymer is described capable of being chemically cross-linked so as to produce a stable gel for blocking a water-bearing formation from a hydrocarbon-producing well. The polymer is essentially linear having hydrophilic side groups located at random positions along its backbone.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: October 12, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Timothy G. J. Jones, Gary J. Tustin
  • Patent number: 6784140
    Abstract: A method of treating a well including injecting a thermally stable, substantially water-free well-treating fluid into the well, wherein the well-treating fluid comprises a polymer, a glycol compound, and a salt is disclosed. In another embodiment, a thermally stable, substantially water-free well fluid including a polymer, a diol compound, and a salt is disclosed.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: August 31, 2004
    Assignee: M-I L.L.C.
    Inventors: David P. Kippie, William E. Foxenberg
  • Patent number: 6777377
    Abstract: A composition for sealing porous subterranean formations comprises a mixture of a water-swellable clay and a water insoluble, water absorbent, water-swellable polymer, wherein the mixture is coated with a material that is resistant to penetration by water. The water penetration resistant material helps the delay the onset of swelling of the clay and polymer until it reaches the formations intended for sealing. Mixing the clay with the water-swellable polymer prior to coating assists in coating of the water-swellable polymer with the water penetration resistant material. The coated mixture can be suspended in an aqueous liquid, and then pumped into a subterranean cavity to seal porous formations therein.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: August 17, 2004
    Assignee: Wyo-Ben, Inc.
    Inventors: Kent R. Myers, Richard K. Brown, Stewart W. Krause, Shobha B. Parekh, Robert W. Stichman
  • Patent number: 6770604
    Abstract: A high temperature viscosifying and fluid loss controlling additive for use in well cements, well cement compositions including the additive and methods of using the compositions are provided. The well cement compositions of this invention are comprised of a hydraulic cement, water and a viscosifying and fluid loss controlling additive comprising a mixture of a polymer comprised of at least one monomer which is calcium tolerant, anionic and disperses basic cement slurries, at least one monomer which hydrolyzes in basic cement slurries to generate anionic carboxylate groups that bind with calcium and viscosify the slurries and at least one monomer which generates non-ionic pendant groups on the polymer upon hydrolyzing in basic cement slurries to prevent polymer precipitation and a homopolymer of a monomer which hydrolyzes in basic cement slurries to generate anionic carboxylate groups that bind with calcium, viscosify the slurries and prevent settling in the slurries.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: August 3, 2004
    Assignee: Halliburton Energy Services, Inc.
    Inventors: B. Raghava Reddy, Wendell D. Riley
  • Patent number: 6767869
    Abstract: A well fracturing fluid comprising one or more anionic viscoelastic surfactants and one or more polymers is described. The fluids can contain an aqueous or non-aqueous fluid and/or buffer for adjusting the pH of the fracturing fluid. The well service fluid can used as a fracturing fluid in order to control water production from a well, while simultaneously increasing the oil production from the well.
    Type: Grant
    Filed: April 9, 2002
    Date of Patent: July 27, 2004
    Assignee: BJ Services Company
    Inventors: Gino F. DiLullo, Philip J. Rae, Atikah J. K. Ahmad
  • Patent number: 6764980
    Abstract: An oil field production chemical, especially a scale inhibitor, is in the form of particles thereof carrying a coating e.g. of a dispersing agent. The coating may be polymeric such as an oligomeric polyacid polyester, a polymeric alkoxylated alcohol or a fatty acid polyamine condensate or it may also be a surfactant and may be used in the form of a suspension in an inert oil, such as diesel oil or kerosene which may be injected into a subterranean formation to inhibit the formation of deposits, e.g. scale in oil wells over a longer period than compounds free of the coating.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: July 20, 2004
    Assignee: BP Exploration Operating Company Limited
    Inventors: Christopher Ian Bates, Ian Ralph Collins, Paul Derek Ravenscroft
  • Patent number: 6743756
    Abstract: Liquid suspensions of particles in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed particles. The suspensions enable a user to rapidly add the suspension to water and to mix at low speeds without generating fugitive dust in the process. In addition, a liquid dispersion can provide an easy to use liquid containing higher concentrations of the active dispersed phase than can be accomplished by simply preparing an aqueous solution of the dispersed phase. Alternatively, highly water-soluble particles may also be suspended which have poor storage, freeze/thaw, or heat/cool stability. In some cases, liquid dispersions can yield controlled release of the dispersed phase because the dispersed phase is not in aqueous solution. The suspensions are environmentally safe and biodegradable and may be used in environmentally sensitive applications, such as for oil well treating fluids for offshore areas.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 1, 2004
    Assignee: Benchmark Research and Technology, Inc.
    Inventor: William Franklin Harris, Jr.