Abstract: A fracturing fluid may include a first surfactant and a second surfactant. The first surfactant may have a structure represented by formula (I): wherein m is an integer ranging from 2 to 3, and n, o, and k are each, independently, integers ranging from 2 to 10. The second surfactant having a structure represented by Formula (II): wherein R2 is a C15-C27 hydrocarbon group or a C15-C29 substituted hydrocarbon group, R3 is a C1-C10 hydrocarbon group, and p and q are each, independently, an integer ranging from 1 to 4. Methods of treating a hydrocarbon-bearing formation include injecting the fracturing fluid in the hydrocarbon-bearing formation, the fracturing fluid being configured to transport a proppant in fractures of the hydrocarbon-bearing formation.

Abstract: A wellbore fluid including a first surfactant, a second surfactant, an activator and an aqueous base fluid is provided. The first surfactant has a structure represented by Formula (I): where Y1, Y2, Y3, Y4 are each, independently, a sulfonate, a carboxylate, an ester or a hydroxyl group, m is an integer ranging from 2 to 3, and n, o, and k are each, independently, integers ranging from 2 to 10. The second surfactant has a structure represented by Formula (III): where R2 is a C15—C27 hydrocarbon group or a C15—C29 substituted hydrocarbon group, R3 is C1—C10 hydrocarbon group, and p and q are each, independently, an integer ranging from 1 to 4. A method of using the wellbore fluid for treating a hydrocarbon-containing formation is also provided.

Abstract: A wellbore fluid including a first surfactant, a second surfactant, an activator and an aqueous base fluid is provided. The first surfactant has a structure represented by Formula (I): where m is an integer ranging from 2 to 3, and n, o, and k are each, independently, integers ranging from 2 to 10. The second surfactant has a structure represented by Formula (III): where R2 is a C15-C27 hydrocarbon group or a C15-C29 substituted hydrocarbon group, R3 is a C1-C10 hydrocarbon group, and p and q are each, independently, an integer ranging from 1 to 4. A method for treating a hydrocarbon-containing formation with the wellbore fluid is also provided.

Abstract: A variety of methods, systems, and compositions are disclosed, including, in one embodiment, method of scale inhibition including: introducing a treatment fluid comprising a brine, a scale inhibitor in neutralized form, and a thermally activated acid precursor through a wellbore and into a producing formation; wherein the thermally activated acid precursor is heated to release an acid that enhances miscibility of the scale inhibitor in the brine.

Abstract: Methods are provided to inhibit scale formation in oil or gas production systems. In one embodiment, the scale inhibiting treatment comprises: A) an AAA terpolymer and B) a phosphonate. The treatment can be added to these systems in the well area itself, to the well annulus and its associated tubes, casings, etc., to the oil or gas bearing subterranean formation, to injection conduits for injecting steam or fracking fluid to the subterranean formation, to the produced water or to equipment in fluid flow contact with the produced water.

Abstract: The invention concerns bifunctional compositions usable in the field of extraction of hydrocarbons, oil and/or gas, said compositions being homogeneous, clear and stable and comprising at least one anti-mineral-deposit additive, at least one corrosion inhibitor, and at least one agent for compatibilizing between the anti-mineral-deposit additive and the corrosion inhibitor.

Abstract: Polymer-based drilling fluids may be used as an alternative to drilling fluids containing bentonite or other clay materials, although filter cake formation can often be inadequate when using polymer-based drilling fluids. As a result, drilling methods employing polymer-based drilling fluids may sometimes experience unacceptable fluid loss performance within a borehole. Drilling methods with enhanced fluid loss performance may comprise: providing a drilling fluid comprising a carrier fluid, a viscosity-enhancing polymer, and a plurality of non-biodegradable particulates, the non-biodegradable particulates comprising at least silica particulates; drilling a borehole in the presence of the drilling fluid; and forming a filter cake within the borehole, the filter cake comprising the non-biodegradable particulates.

Abstract: Spacer fluids that are stable at temperatures up to at least 300° C. comprise water, polystyrene sulfonate and a mixture of particulate materials. The particulate materials may be chosen such that the mixture has at least a trimodal particle-size distribution. The fluids may further comprise inorganic clays, mutual solvents and surfactants.

Abstract: The present invention includes the use of anhydride compositions, including alkyl and aryl anhydrides, for use as a demulsifier in resolving emulsions of water and oil. In particular, the anhydride composition can be used alone or in a blend with other demulsifiers. Suitable anhydrides suitable for the present invention include acetic and propionic, with acetic anhydride being preferred. The anhydride composition can be added directly to crude oil or other compositions to be resolved. As such, the demulsifier composition includes an anhydride, such as acetic anhydride, alone or in combination with other demulsifiers. The anhydride can be used in an amount ranging between trace and 100% by weight of the demulsifier composition.

Abstract: Methods and systems are disclosed for well completion and/or production, where an aggregating, agglomerating or conglomerating composition is injected into a producible formation, zone or interval thereof to alter an aggregation or zeta potential of formation surfaces and particulate to increase a maximum sand free production rate.

Abstract: Methods are disclosed for improved sand control, fines control, load recovery and well productivity, where the compositions comprise reaction products of an amine and a phosphate-containing compound.

Abstract: A method for drilling through a producing zone in a subterranean formation or for completing a wellbore in a subterranean formation, using a drill-in and completion fluid comprising a blend of a phosphate brine and water.

Abstract: This invention relates to a process for inhibiting scaling in a subterranean oil or gas producing formation, comprising adding to the formation a composition comprising a metal chelant, a scale inhibitor and divalent metal cations, wherein the stability constant of the metal chelant—metal cation chelate at ambient temperature is equal to or higher than the stability constant of the chelate formed from the metal cations and the scale inhibitor, and wherein the solubility of the chelate formed from the metal cations and the scale inhibitor decreases with increasing temperature.

Abstract: A gelling agent for a hydrocarbon fracturing fluid is disclosed, comprising the general formula of: in which X is an OR1, NR1R2, or SR1 group, R1 is an organic group having 2-24 carbon atoms, and R2 is an organic group or a hydrogen. Y is an NR3R4 or SR3 group, R3 is an organic group having 2-24 carbon atoms, and R4 is an organic group or a hydrogen. A method of making a gelling agent for a hydrocarbon fracturing fluid is also disclosed. Phosphorus oxyhalide is reacted with a chemical reagent to produce substantially only diester phosphorus oxyhalide, the chemical reagent comprising at least one of an organic alcohol having 2-24 carbon atoms, an organic amine with an organic group having 2-24 carbon atoms, and an organic sulfide having 2-24 carbon atoms. The diester phosphorus oxyhalide is then hydrolyzed to produce diester phosphoric acid.

Abstract: Compositions comprise an amine component, an aminephosphate component and may also include a solvent component. The compositions are adapted to coat solid materials, substrates and/or surfaces of producing of reservoirs and formations and methods for making and using same, where the coating agents modify surface properties of the solid materials, substrates and/or surfaces of producing formations decreasing residual oil saturation.

Abstract: A composition and method for hydraulically fracturing an oil or gas well to improve the production rates and ultimate recovery using a porous ceramic proppant infused with a chemical treatment agent is provided. The chemical treatment agent may be a tracer material that provides diagnostic information about the production performance of a hydraulic fracture stimulation by the use of distinguishable both water soluble and hydrocarbon soluble tracers. The tracer can be a biological marker, such as DNA. The porous ceramic proppant can be coated with a polymer which provides for controlled release of the chemical treatment agent into a fracture or well bore area over a period of time.

Abstract: A corrosion control system is disclosed including an anionic oxygen inhibitor, a cationic acid inhibitor or dispersant, and a noxious species inhibitor or scavenger for use in a fluid in contact with a metallic surface at low temperature, moderate temperature and especially at high temperature. A drilling fluid, a completion fluid, a production fluid and a geothermal fluid including an effective amount of the corrosion control system is also disclosed as well as methods for making and using same.

Abstract: The invention relates to the use of compounds comprising three hydrophobic groups as additives to a stream of crude oil containing carboxylic acids, in particular naphthenic acids, and salt water, to prevent the formation of calcium carboxylates when the fluid is exposed to shear forces. Preferably, the compounds are added to a crude oil/water stream containing organic acids Ca2+ ions at a point between the well and the pressure reduction valve in the crude oil receiving station.

Abstract: Disclosed herein is a well treatment method comprising the steps of injecting into a well a fluid loss control agent comprising a chelating agent, a viscosity increasing agent, and a plurality of at least partially insoluble bridging solid particles dispersed therein, wherein the chelating agent is effective to at least partially solubilize at least a portion of the bridging solid particles over a solubilizing period of time for thereafter substantially dissolving the bridging solid particles, wherein the solubilizing period of time is controlled by the concentration of the viscosity increasing agent, the concentration of the chelating agent, the composition of the metal salt, the pH of the fluid loss control agent, or a combination thereof. A fluid loss control agent is also disclosed.

Abstract: Clay is stabilized in methods for drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.

Abstract: Novel aminoacid alkylphosphonic acid compounds are disclosed. These compounds can be used in multiple applications, in particular in a scale inhibitor functionality in aqueous systems, including in marine oil recovery.

Abstract: The composition includes a pH adjusting agent and a precipitation-control agent. The pH adjusting agent provides the hydrolysis of degradable fibers at a temperature of no more than 50° C. and comprises substances that may provide and maintain a high pH environment. The precipitation-control agent allows maximally delaying or completely suppressing the formation and deposition of precipitate during the hydrolysis of the degradable components in the treatment fluid A method of treating an subterranean formations penetrated by a wellbore with the additives described herein comprises providing a treatment fluid comprising a base mixture and a degradable substance, with additionally added degradable materials, and injecting the prepared treatment fluid into the subterranean formation.

Abstract: A well servicing fluid is disclosed. The well servicing fluid is formulated by combining ingredients comprising: an aqueous based fluid comprising sulfate ions at a concentration greater than 50 mg/l; a chelating agent; and an acid in an amount sufficient to result in the well servicing fluid having a pH of 4.5 or less. A method of servicing a well is also disclosed.

Abstract: This invention relates to a process for inhibiting scaling in a subterranean oil or gas producing formation, comprising adding to the formation a composition comprising a metal chelant, a scale inhibitor and divalent metal cations, wherein the stability constant of the metal chelant—metal cation chelate at ambient temperature is equal to or higher than the stability constant of the chelate formed from the metal cations and the scale inhibitor, and wherein the solubility of the chelate formed from the metal cations and the scale inhibitor decreases with increasing temperature.

Abstract: A method of secondary oil recovery is disclosed wherein from 0.1 to 100 000 ppm of a medium soluble aminoalkylene phosphonic acid amine salt are used wherein both the aminoalkylene phosphonic acid moiety and the amine moiety are selected from a specifically defined class of compounds. The substantially medium soluble aminoalkylene amine phosphonates exhibit a significantly improved compatibility with the recovery medium and thus can propagate fairly freely into the medium and consequently cover a largely extended rock surface before being subject to precipitation in the form of a medium insoluble scale inhibitor. The amine compound is represented by combinations of structurally different compounds.

Abstract: A water-in-oil emulsion composition and method of production is disclosed. The composition may comprise a monomer phase, an organic phase, at least one initiator, and an inverting phase. The monomer phase may further comprise at least one monomer, water, ammonium chloride, sodium 2-acrylamido-2-methyl-1-propanesulfonate, tetrasodium ethylenediaminetetraacetate, and at least one water soluble ethylenically unsaturated monomer. The organic phase may further comprise at least one hydrophobic solvent, lecithin, and a polyoxyethylene derivative of a sorbitan ester. The at least one monomer may be selected from the group consisting of an acrylic monomer, an acrylamide monomer, and combinations thereof.

Abstract: A low toxicity composition and method of reducing the swelling of clay in well comprising circulating in the well a water-based fluid comprising a functionally effective concentration of the additive formed from the following reaction of a tertiary amine of the following general formula: wherein R1 and R2 are alkyl or hydroxyalkyl groups with one to three carbon atoms or combinations thereof, and R3 is a hydroxyalkyl group with one to three carbon atoms, with an alkylating agent of the following general formula: R-A wherein R is an alkyl radical with one to three carbon atoms, and A is an organic or inorganic anion selected from the group consisting of sulfate, phosphate, carbonate, and combinations thereof.

Abstract: Non-settable spacer fluids for use in subterranean operations comprising: a base liquid; vitrified shale; a chelating agent; a clay weighting agent; and a viscosifying agent. The chelating agent includes one or more of nitrilotriacetic acid, ethylene diamine tetracetic acid (EDTA), ethylene glycol tetraacetic acid (EGTA), tartaric acid, a polycarboxylic acid, a lignosulphonate, hydroxyethylidene diphoshponic acid (HEDP), diethylene triamine penta (methylene phosphonic) acid (DETMP), amino-tri-methylene phosphonic acid (ATMP), ethylene diamine tetra (methylene phosphonic) acid (EDTMP), or salts thereof. The clay weighting agent is present in the range of about 0.01% to about 85% by weight of the spacer fluid. The viscosifying agent is present in the range of about 1% to about 10% by weight of the spacer fluid.

Abstract: The present invention relates to a method of using threshold scale inhibitors of the formula: wherein n is 2 or 3 and M is hydrogen or an alkali metal cation, for preventing calcium carbonate, iron carbonate, and calcium sulfate scale formation in oilwell brines containing dissolved iron.

Abstract: Scale inhibiting particulates formed from a mixture of fly ash and a phosphonic acid curing agent; wherein the fly ash is cured into a solid material by the contact with the phosphonic acid curing agent. The mixture may also contain a multivalent ion and the particulates may be coated with a coating material in an amount from about 0.1% to about 40% coating material by weight of the scale inhibiting particulate to delay the release of the scale inhibitor.

Abstract: Scale inhibiting particulates formed from a mixture of fly ash and a phosphonic acid curing agent; wherein the fly ash is cured into a solid material by the contact with the phosphonic acid curing agent. The mixture may also contain a multivalent ion and the particulates may be coated with a coating material in an amount from about 0.1% to about 40% coating material by weight of the scale inhibiting particulate to delay the release of the scale inhibitor.

Abstract: The present invention relates to a method for inhibiting scale and corrosion in aqueous systems, for example, under high temperature and pressure conditions such as temperatures up to 250° C. and/or pressures up to 10000 psi (i.e., about 68.9 MPa). The method involves providing polymer compositions comprising 1% to 100% by weight of a phosphorus-containing amide monomer to such aqueous systems, which arise, for example, in connection with oilfield operations and some water treatment applications.

Abstract: Scale-inhibiting particulates formed from a mixture of fly ash and a phosphonic acid curing agent wherein the fly ash is cured into a solid material by the contact with the phosphonic acid curing agent. Methods of using scale-inhibiting particulates to inhibit scale formation in a subterranean formation.

Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.

Abstract: A composition useful for crosslinking phosphate esters in hydrocarbon gels used in formation fracturing performs especially well in cold temperatures, such as temperatures lower than (?)20° C. Methods of making the crosslinking composition and the gel are described; also methods of fracturing subterranean formations. Specific forms of ferric sulfate and ferric ammonium citrate are useful as ingredients of the crosslinking composition.

Abstract: This invention relates to an aqueous-swellable and degradable diverting system and the use of the system in treating a subterranean formation penetrated by a wellbore. The diverting system comprises a carrier fluid and a partially dehydrated or anhydrous borate source material that does not swell or does not swell substantially when placed in contact with the carrier fluid. The carrier fluid is capable of carrying and placing the borate source material into a stimulation network substantially distanced from a wellbore. The carrier fluid may be a non-aqueous fluid, or when the average size of the borate source material is sufficient large, the carrier fluid may also be an aqueous fluid. Exposure of the diverting composition to sufficient amount of aqueous fluid swells the borate source material, bridges a desired portion of the stimulation network and then dissolves at least a portion of the diverting composition.

Abstract: An aqueous composition for treating hydrocarbon wells contains (a) a scale inhibitor and (b) a viscoelastic surfactant, and further contains from 0 to less than 1% by weight of acid selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, citric acid, maleic acid, hydrofluoric acid, and mixtures thereof.

Abstract: A gelling agent for a hydrocarbon fracturing fluid is disclosed, comprising the general formula of: in which X is an OR1, NR1R2, or SR1 group, R1 is an organic group having 2-24 carbon atoms, and R2 is an organic group or a hydrogen. Y is an NR3R4 or SR3 group, R3 is an organic group having 2-24 carbon atoms, and R4 is an organic group or a hydrogen. A method of making a gelling agent for a hydrocarbon fracturing fluid is also disclosed. Phosphorus oxyhalide is reacted with a chemical reagent to produce substantially only diester phosphorus oxyhalide, the chemical reagent comprising at least one of an organic alcohol having 2-24 carbon atoms, an organic amine with an organic group having 2-24 carbon atoms, and an organic sulfide having 2-24 carbon atoms. The diester phosphorus oxyhalide is then hydrolyzed to produce diester phosphoric acid.

Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.

Abstract: A method of secondary oil recovery is disclosed wherein from 0.1 to 100 000 ppm of a medium soluble aminoalkylene phosphonic acid amine salt are used wherein both the aminoalkylene phosphonic acid moiety and the amine moiety are selected from a specifically defined class of compounds. The substantially medium soluble aminoalkylene amine phosphonates exhibit a significantly improved compatibility with the recovery medium and thus can propagate fairly freely into the medium and consequently cover a largely extended rock surface before being subject to precipitation in the form of a medium insoluble scale inhibitor. The amine compound is represented by combinations of structurally different compounds.

Abstract: A low toxicity composition and method of reducing the swelling of clay in well comprising circulating in the well a water-based fluid comprising a functionally effective concentration of the additive formed from the following reaction of a tertiary amine of the following general formula: wherein R1 and R2 are alkyl or hydroxyalkyl groups with one to three carbon atoms or combinations thereof, and R3 is a hydroxyalkyl group with one to three carbon atoms, with an alkylating agent of the following general formula: R-A wherein R is an alkyl radical with one to three carbon atoms, and A is an organic or inorganic anion selected from the group consisting of sulfate, phosphate, carbonate, and combinations thereof.

Abstract: Unwanted heat loss from production tubing or uncontrolled heat transfer to outer annuli is inhibited by introduction into the annuli a thermal insulating packer fluid or a riser fluid containing a zwitterionic surfactant, an alcohol and a brine. The viscosity of the composition is sufficient to reduce the convection flow velocity within the annulus. The invention has particular applicability with high density brines.

Abstract: An aqueous composition for treating hydrocarbon wells contains (a) a scale inhibitor and (b) a viscoelastic surfactant, and further contains from 0 to less than 1% by weight of acid selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, citric acid, maleic acid, hydrofluoric acid, and mixtures thereof.

Abstract: Improved methods of placing and/or diverting treatment fluids in subterranean formations are provided. In one embodiment, the methods comprise introducing a treatment fluid into a subterranean formation penetrated by a well bore, wherein the treatment fluid comprises: a base fluid, and a plurality of solid particulates comprising at least one selected from the group consisting of: a scale inhibitor, a chelating agent, and a combination thereof, wherein the solid particulates are substantially insoluble in the base fluid; and allowing at least a portion of the solid particulates to form a barrier or at partially divert a subsequent fluid.

Abstract: Compositions and methods for their use are disclosed, where the compositions comprise an amine component, an amine/phosphate ester component and optionally a solvent component. The compositions are adapted to coat solid materials, substrates and/or surfaces of producing of reservoirs and formations and methods for making and using same, where the coating agents modify surface properties of the solid materials, substrates and/or surfaces of producing formations decreasing residual oil saturation.

Abstract: A method for plugging a permeable zone or leak in a subterranean formation comprises introducing into the formation a cross-linkable organic polymer and a cross-linking composition which comprises a zirconium triethanolamine complex, a tetra(hydroxyalkyl)ethylenediamine, water and optionally, a polyol. The method can be used for cross-linking organic polymers over a wide range of pH. By varying the composition and optionally adding a delay agent, the method provides flexibility in rate of cross-linking.

Abstract: The present disclosure is directed to a method comprising introducing into a well bore a fluid comprising a zwitterionic polymer. The polymer is prepared by inverse emulsion polymerization of at least one monomer Ab comprising a betaine group and optionally one or more nonionic monomers Ba. The well bore is chosen from a natural gas well bore and an oil well bore.

Abstract: Disclosed is a composition comprising a chemical formulation useful for creating geosynthetic composites in-situ that includes a melamine-formaldehyde resin in a non-aqueous drilling fluid.

Abstract: Stabilized sulfide control compositions for oil well and related uses are provided which include a first ingredient selected from the group consisting of tetra (hydroxymethyl) phosphine (THP) or a salt thereof (THPS) and an amino phosophono chelant. The compositions are stabilized against cold-weather crystal formation and deposition by the presence of a morpholine-based stabilizing agent. Preferred compositions include the sulfate salt of THP, diethylenetriamine penta (methylenephosophonic acid) sodium salt, and morpholine.

Abstract: Methods are disclosed for improved sand control, fines control, load recovery and well productivity, where the compositions comprise reaction products of an amine and a phosphate-containing compound.