Abstract: Liquid hydrocarbons are gelled by the introduction of a phosphate ester and a crosslinking agent. Gelling times and viscosities are improved through the use of an enhancer which is, preferably, an oxyalkylated amine or a blend of an oxyalkylated amine with another amine or a non-nitrogen-containing component. Preferred phosphate esters are ether phosphate esters.

Abstract: This invention is directed to a gelling agent composition comprising the reaction product of a high molecular weight gelling agent additive, a low molecular weight phosphate diester acid, and a Group II or Group III metal salt, to methods of preparing the gelling agent composition, to a gelled hydrocarbon liquid comprising the gelling agent composition and to a method of fracturing subterranean formations using the gelled hydrocarbon liquid.

Abstract: Method and composition for gel formation in hydrocarbon recovery, in which an organic phosphate ester is gelled by a novel activator composition comprising iron sulfate, dibutylaminoethanol, and a phosphate surfactant.

Abstract: Method and composition for gel formation in hydrocarbon recovery, in which an organic phosphate ester is gelled by a novel activator composition comprising iron sulfate, dibutylaminoethanol, and a phosphate surfactant.

Abstract: A gelling agent for viscosifying liquid hydrocarbon fracturing fluids is an aluminum salt of a phosphate ester made by forming the ester by reacting P.sub.2 O.sub.5 with a mixture of organic alcohols which include high molecular weight alcohols or diols selected from hydroxy functional homopolymers, copolymer or terpolymer made from olefins and diolefins selected from the group consisting of ethylene, propylene, butene, butadiene, isoprene, and selected styrenes. The oil based fracturing fluid containing the gelling agent in sufficient concentration to provide a viscosity of between 50 cp and 350 cp at 100.degree. F.

Abstract: Oil degradable encapsulated breaker particles are used in fracturing operations to break hydro-carbon liquid gelled with salts of alkyl phosphate esters. The preferred breaker chemical is particulate urea coated with sulfonated EPDM.

Abstract: Hydrocarbon fracturing fluids are made by combining organic phosphate esters with polyvalent metal salts in hydrocarbon carriers to form gels; breaking of the gel is retarded or otherwise controlled over a wide range of water concentrations through the use of slowly soluble alkaline earth metal compounds, preferably hard burned magnesium oxide, which may be added along with the gel component.

Abstract: A process for fixing of a scale inhibitor in a subterranean formation, which comprises:a) injecting into the formation a solution comprising a polymeric scale inhibitor, a metal cation, a precursor and a weak organic acid, wherein the polymeric scale inhibitor and metal cation are slightly soluble in water in the formation and wherein the precursor reacts in the formation to produce an alkaline compound which causes the polymeric scale inhibitor to precipitate in the formation; andb) allowing the polymeric scale inhibitor to precipitate in the formation in an amount which is effective in inhibiting scale formation for a given period of time.

Abstract: Hydrocarbon fracturing fluids are made by combining organic phosphate esters with polyvalent metal salts in hydrocarbon carriers to form gels; breaking of the gel is retarded or otherwise controlled over a wide range of water concentrations, through the use of slowly soluble alkaline earth metal compounds, preferably hard burned magnesium oxide, which may be added along with the gel component. The slowly soluble alkaline earth metal compound is employed together with an oily acid breaker retarding agent such as tall oil.

Abstract: A novel method for inhibiting oxygen corrosion in an oil well, and an emulsion useful therein. The method comprises introducing into the well a pourable emulsion comprising about 50 to about 95 volume percent discontinuous aqueous phase, about 5 to about 50 volume percent continuous oil phase, and a corrosion inhibiting amount of a composition comprising a corrosion inhibitor selected from among thiophosphates containing both oxygen and sulfur, pyrophosphates containing both oxygen and sulfur and mixtures thereof.

Abstract: Odorant depletion is reduced by passivating the internal surface of LP-gas transportation and storage vessels by the addition of passivating agents comprising mixtures of corrosion inhibitors such as phosphate esters, fatty amines, poly amides, imidazolines, poly imidazolines, quaternary amines, poly quats, dimer acids, trimer acids, polymeric acids, ethoxylated fatty amines, ethoxylated polyamides, ethoxylated alcohols and mixtures thereof in one or more solvents. In a preferred embodiment, the passivating agents contain one or more phosphate esters defined by the equation:?R--X--?C.sub.m H.sub.2m O).sub.n !.sub.k --PO(OH).sub.

Abstract: This invention relates to improved hydrocarbon gels which find use in the fracturing of petroleum producing formations. In particular it relates to the use of a defined class of gelling agents for hydrocarbons which provide excellent results in such fracturing. The gelling agents comprise combinations of selected orthophosphate esters and ferric ammonium citrate or lower alkyl amine derivative thereof. The lower alkyl amine derivatives are referred to as ferric alkylamine citrates.

Abstract: Oil degradable granules containing particulate breaker chemical is used in fracturing operations to break hydrocarbon liquid gelled with salts of alkyl phosphate esters. The preferred breaker chemical is powdered Ca(OH).sub.2.

Abstract: This invention relates to improved hydrocarbon gels which find use in the fracturing of petroleum producing formations. In particular it relates to the use of a define class of gelling agents for hydrocarbons which provide excellent results in such fracturing. The gelling agents comprise combinations of (1) selected orthophosphate esters and (2) a composition comprising a source of ferric ions, an amine, and a polycarboxylic acid or salt thereof.

Abstract: A method is shown for fracturing a subterranean formation in which a hydratable polymer, crosslinking agent and breaker are combined in an aqueous carrier to form a gelled fracturing fluid. The breaker is comprised of a substantially insoluble oxidant which is granulated and formed into a pellet or prill with a suitable binder. The pellet so formed can also contain a chelating agent and an activator in order to enhance the rate of breaking. The substantially insoluble oxidant is selected from the group consisting of alkaline earth and zinc salts of peroxide, perphosphate, perborate, and percarbonate.

Abstract: The present invention relates to blends of individual corrosion inhibitors with phosphate esters for protection of ferrous metals against attack by a corrosive environment. These blends are synergistically more effective than each of the individual corrosion inhibitors. The phosphate esters of the present invention are the reaction products of ethoxylated, propoxylated, or butoxylated alcohols or phenols with phosphating agents. Other corrosion inhibitors suitable for blending with the phosphate esters include fatty amines, poly amides, imidazolines, poly imidazolines, quaternary amines, poly quats and dimer, trimer, and polymeric acids. Phosphate esters may comprise any portion of the total amount of corrosion inhibitors in the blend, but the preferred concentration is from about 5 to about 50 weight percent phosphate ester. The corrosion inhibitor blends may be diluted to any concentration with solvents or other fluids as necessary for particular applications.

Abstract: The present invention relates to a specific type of phosphate ester that is as effective or more effective than corrosion inhibitors available in the past. In accordance with the invention, these corrosion inhibitors are highly effective alone or when blended with other specific compounds for protection of ferrous metals against attack by a corrosive environment. More particularly, the inhibitors of the present invention are the reaction products of ethoxylated, propoxylated, or butoxylated alcohols or phenols with phosphating agents.

Abstract: This invention relates to improved hydrocarbon gels which find use in the fracturing of petroleum producing formations. In particular it relates to the use of a define class of gelling agents for hydrocarbons which provide excellent results in such fracturing. The gelling agents comprise combinations of selected orthophosphate esters and ferric ammonium citrate or lower alkyl amine derivative thereof. The lower alkyl amine derivatives are referred to as ferric alkylamine citrates.

Abstract: An improved method for preventing iron precipitation from a spent oil well acidizing solution is disclosed. The acidizing solution is preceded into the tubular goods and formation by the injection of an iron sensitive, acid insensitive acidified surfactant solution.

Abstract: The present invention provides a method of treating a subterranean formation by rapidly viscosifying a normally liquid hydrocarbon. The method is accomplished by admixing (i) an alkyl orthophosphate acid ester and (ii) an alkali metal hydroxide present in an amount sufficient to at least partially neutralize said ester and (iii) a reaction product resulting from the reaction of a source of aluminum or ferric ions with a C.sub.8 -C.sub.18 surface active amine solubilized in the presence of an organic solvent such as a C.sub.2 -C.sub.4 monohydric alcohol with the normally liquid hydrocarbon. The mixture rapidly viscosifies to a level sufficient to transport proppant and then can be introduced into a subterranean formation to treat the formation in a desired manner.

Abstract: This invention relates to improved hydrocarbon gels which find use in the fracturing of petroleum producing formations. In particular it relates to the use of a defined class of gelling agents for hydrocarbons which provide excellant results in such fracturing. The gelling agents comprise combinations of ferric salts and selected orthophosphate esters.