Organic Component Contains Nitrogen Attached Directly Or Indirectly To Carbon By Nonionic Bonding Patents (Class 507/239)
  • Publication number: 20100212896
    Abstract: A method of gravel packing a hole in a subterranean formation having a filter cake coated on the surface thereof that includes injecting into the hole a gravel pack composition comprising gravel and a carrier fluid comprising a base fluid and at least one iminodiacetic acid or salt thereof is disclosed.
    Type: Application
    Filed: June 27, 2008
    Publication date: August 26, 2010
    Applicant: M-I L.L.C.
    Inventors: Raul Navarro, Andrew G.K. Jones, Mark Luyster, Robert L. Horton
  • Publication number: 20100216672
    Abstract: Treatment fluids for and methods of treating subterranean formations are provided. In certain embodiments, a method is provided comprising providing a treatment fluid comprising a relative permeability modifier, a delayed filter cake breaker, and a carrier fluid, contacting at least a portion of a filter cake in a subterranean formation with the treatment fluid, and removing at least a portion of the filter cake.
    Type: Application
    Filed: February 24, 2009
    Publication date: August 26, 2010
    Inventor: Bradley L. Todd
  • Patent number: 7776798
    Abstract: This invention relates to the use of alkyl amido quaternary ammonium salts, and formulations thereof, as thickening agents in aqueous based fluids, especially those used in oil field applications. The quaternary ammonium salts of the present invention exhibit improved gelling characteristics.
    Type: Grant
    Filed: February 1, 2007
    Date of Patent: August 17, 2010
    Assignee: Akzo Nobel Surface Chemistry LLC
    Inventors: Shankar Subramanian, Cenk Burgazli, Yun-Peng Zhu, Shawn Zhu, Dave Feuerbacher
  • Publication number: 20100204071
    Abstract: A sand slurry composition and a method for making sand slurries are disclosed. The sand slurry composition is comprised of sand, an aqueous liquid and a chemical compound that renders the surface sand of hydrophobic. The method is comprised of rendering sand surface hydrophobic during or before making the slurry. This method and composition can find many applications in different industries, especially in various oil field applications.
    Type: Application
    Filed: April 11, 2008
    Publication date: August 12, 2010
    Applicant: TRICAN WELL SERVICE, LTD.
    Inventor: Kewei Zhang
  • Patent number: 7772164
    Abstract: There is a viscoelastic fluid. The fluid has one or more cationic surfactants selected from the group consisting of certain quaternary salts, certain amines, and combinations thereof; one or more anionic polymers/anionic surfactants; one or more of certain zwitterionic/amphoteric surfactants; and water. There is also a method of fracturing a subterranean formation. The viscoelastic fluid is pumped through a wellbore and into a subterranean formation at a pressure sufficient to fracture the formation. There is also a method for gravel packing a subterranean formation.
    Type: Grant
    Filed: February 9, 2007
    Date of Patent: August 10, 2010
    Assignee: Rhodia, Inc.
    Inventors: Fang Li, Manilal Dahanayake, Allwyn Colaco
  • Patent number: 7772160
    Abstract: Pellets can be injected into oil and gas production equipment that may contain stagnant or slow moving system fluids to treat the stagnant or slow moving system fluids to prevent conditions such as corrosion. The pellets have a density such that they may be moved through the equipment by system fluids passing therethrough. When the pellets come into contact with the stagnant or slow moving system fluids, sufficient pellets enter the stagnant or slow moving system fluids to treat it. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: August 10, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Michael Greaves, Steven Jeremy Weghorn, Hani S. Zaki
  • Publication number: 20100197531
    Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.
    Type: Application
    Filed: April 12, 2010
    Publication date: August 5, 2010
    Applicant: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Publication number: 20100190666
    Abstract: A method of treating a medium for water fracturing is disclosed, the method comprises: introducing at least one biocide and at least one metabolic inhibitor in the medium, using the medium for water fracturing. In another aspect a method of controlling the post-fracture reservoir souring by the metabolic activities of sulfate reducing bacteria of a well is described: at least one biocide and at least one metabolic inhibitor are introduced in a medium made of water, the medium is used for fracturing the well, and the medium remains in the reservoir to kill and/or inhibit growth of sulfate reducing bacteria.
    Type: Application
    Filed: December 21, 2009
    Publication date: July 29, 2010
    Inventors: Syed Ali, Shawn McCleskey Rimassa, Francois M. Auzerais, Curtis L. Boney, Leiming Li
  • Publication number: 20100186956
    Abstract: Methods for servicing well bores with hardenable resin compositions are provided. In one embodiment, a method of servicing a well bore includes providing a hydrophobic well bore servicing composition comprising a liquid hardenable resin, a hardening agent, and a weighting material selected to impart a desired first density to the well bore servicing composition; introducing the well bore servicing composition into a well bore comprising a well bore fluid having a second density; allowing the well bore servicing composition to migrate through the well bore fluid to a desired location in the well bore based at least in part upon a difference between the first and second densities; and allowing the liquid hardenable resin to at least partially harden to form a well bore plug at the desired location in the well bore.
    Type: Application
    Filed: January 27, 2009
    Publication date: July 29, 2010
    Inventors: Rickey Lynn Morgan, D. Chad Brenneis, Jeffery Karcher
  • Patent number: 7754660
    Abstract: A process to prepare a solution of zirconium-alkanolamine-hydroxycarboxylic acid complex is disclosed and use of the solution in oil field applications such as hydraulic fracturing and plugging of permeable zones. The process comprises contacting an alcohol solution of a zirconium complex with an alkanolamine, then with an ?-hydroxycarboxylic acid to produce a solution of zirconium-alkanolamine-hydroxycarboxylic acid complex. The solution is particularly suitable for use in a cross-linking composition in hydraulic fracturing and plugging of permeable zones of subterranean formations at temperatures of 275° F. (135° C.) and higher in the formation.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: July 13, 2010
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Donald Edward Putzig
  • Publication number: 20100160189
    Abstract: The current disclosure describes a multifunctional fluid that addresses a new concept in the removal of filter cake. A composition is disclosed comprising: a carrier fluid, a surfactant, a fluorine source and an organic stabilizer able to minimize precipitation of fluorine The associated method to remove the filter cake is also described.
    Type: Application
    Filed: December 19, 2008
    Publication date: June 24, 2010
    Inventors: Michael J. Fuller, Syed Ali, Laurent Pirolli, John W. Still
  • Patent number: 7741251
    Abstract: The present invention relates to well bore stabilization and, more particularly, to treatment fluids that may reduce the tendency of shales to swell and associated methods. In some embodiments, the present invention provides a method of stabilizing a subterranean formation that comprises a shale, the method comprising contacting the subterranean formation that comprises the shale with a treatment fluid, the treatment fluid comprising a base fluid, and a hydrophobically modified polymer. In other embodiments, the treatment fluids comprise a base fluid and a hydrophilically modified polymer. In yet other embodiments, the present invention provides shale-inhibiting components, treatment fluids, and methods of reducing the tendency of shale to swell when exposed to a treatment fluid.
    Type: Grant
    Filed: June 4, 2004
    Date of Patent: June 22, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Larry S. Eoff, B. Raghava Reddy, J. Michael Wilson
  • Publication number: 20100137168
    Abstract: Nanoemulsions have been discovered to be useful to the oil field. More particularly water-in-oil (W/O), oil-in-water (O/W) and other classes of nanoemulsions have found beneficial application in drilling, completion, well remediation and other oil and gas industry related operations. Additionally, nanoemulsions may reduce friction pressure losses, as well as reduce subsidence of solid weight material during oil and gas operations. New preparation methods for nanoemulsions have also been discovered.
    Type: Application
    Filed: November 25, 2009
    Publication date: June 3, 2010
    Applicant: Baker Hughes Incorporated
    Inventors: Lirio Quintero, David E. Clark, Alexander John McKellar
  • Patent number: 7723272
    Abstract: Viscoelastic surfactant (VES) gelled aqueous fluids containing water, a VES, an internal breaker, a VES stabilizer, a fluid loss control agent and a viscosity enhancer are useful as treating fluids and particularly as fracturing fluids for subterranean formations. These VES-based fluids have faster and more complete clean-up than polymer-based fracturing fluids. The use of an internal breaker permits ready removal of the unique VES micelle based pseudo-filter cake with several advantages including reducing the typical VES loading and total fluid volume since more VES fluid stays within the fracture, generating a more optimum fracture geometry for enhanced reservoir productivity, and treating reservoirs with permeability above the present VES limit of approximately 400 md to at least 2000 md.
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: May 25, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang, Allen D. Gabrysch, James H. Treadway, John R. Willingham, Patrick A. Kelly, William R. Wood
  • Patent number: 7723273
    Abstract: Compressible and resilient sealing compositions for injection into oil or gas wells are provided, which are capable of forming effective seals adjacent well casings even at elevated downhole temperatures. The compositions comprise an epoxy component present in a predominant weight percentage, including an epoxy resin and a glycidyl ether modifier, as well as additional components rendering the cured compositions both compressive and resilient. The compositions are used as a partial or complete substitute for casing cements, and can be used to good effect with expandable casing installations or for sealing casing breaks. High set-up temperature (220-300° F.) compositions preferably include an ethoxylated alkyl (C10-C20) monoamine or diamine, and alkyl pyridine quaternary ammonium components.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: May 25, 2010
    Assignee: JaCam Chemical Company, Inc.
    Inventors: Gene H. Zaid, Beth Ann Wolf
  • Patent number: 7709420
    Abstract: Provided herein are organophilic clays that comprise a smectite clay modified by reaction with a protonated amphoteric surfactant. Also provided are fluids that comprise an oil and an organophilic clay comprising a smectite clay modified by reaction with a protonated amphoteric surfactant. Also provided are methods of preparing and using these organophilic clays.
    Type: Grant
    Filed: January 4, 2006
    Date of Patent: May 4, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Samuel J. Lewis, Michael J. Szymanski
  • Publication number: 20100093736
    Abstract: Biocidal compositions and their use in aqueous media, such as metalworking fluids, the compositions comprising a biocidal agent; and a non-biocidal primary amino alcohol compound of the formula (I); wherein R1, R2, R3, R4, and R5 are as defined herein.
    Type: Application
    Filed: December 13, 2007
    Publication date: April 15, 2010
    Applicants: ANGUS CHEMICAL COMPANY, DOW GLOBAL TECHNOLOGIES INC.
    Inventors: Charles E. Coburn, John L. Pohlman, Bonnie A. Pyzowski, Patrick E. Brutto, George David Green, Raymond J. Swedo
  • Patent number: 7674365
    Abstract: A composition comprising: (i) a chelating aminocarboxylic acid-C8-C22 amine complex; (ii) a C15-C21 bis(2-hydroxyethyl)amide; and (iii) a C15-C44 imidazoline compound.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: March 9, 2010
    Assignee: Rohm and Haas Company
    Inventors: Rajiv M. Banavali, Bharati Dinkar Chheda, Guido Mazza Manari
  • Publication number: 20100056404
    Abstract: The present invention relates generally to a method for treating hydrogen sulfide-containing fluids, more specifically to a method of treating hydrogen sulfide associated with petroleum and/or natural gas production.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 4, 2010
    Applicant: MICRO PURE SOLUTIONS, LLC
    Inventor: Charles Bullick Talley
  • Publication number: 20100022420
    Abstract: A composition for mitigating or preventing the formation of an emulsion between naphthenic acid and metal cations in a hydrocarbon body, the composition including at least one alkoxylated amine and at least one acid and/or alcohol is disclosed.
    Type: Application
    Filed: July 23, 2008
    Publication date: January 28, 2010
    Inventors: James Smith, C. Y. Khandekar, Rohan Wilson
  • Patent number: 7651982
    Abstract: Methods and aqueous acid solutions for acidizing wells containing sludging and emulsifying oil are disclosed. An aqueous acid solution of the invention comprises water, hydrochloric acid, a cationic hydrochloric acid corrosion inhibitor and a conjugate ion pair of a cationic amine oxide surfactant and an anionic surfactant that does not react with the cationic hydrochloric acid corrosion inhibitor.
    Type: Grant
    Filed: August 21, 2004
    Date of Patent: January 26, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Juanita M. Cassidy, Chad E. Kiser, Jim L. Lane
  • Patent number: 7651981
    Abstract: A process for recovering materials from a subterranean formation, for example in enhanced oil recovery, comprises: (A) (a) (i) selecting a first polymeric material having a repeat unit of formula (A) wherein A and B are the same or different, are selected from optionally-substituted aromatic and heteroaromatic groups and at least one comprises a relatively polar atom or group and R1 and R2 independently comprise relatively non-polar atoms or groups; or (ii) selecting a first polymeric material prepared or preparable by providing a compound of general formula (B) wherein A, B, R1 and R2 are as described above, in an aqueous solvent and causing the groups C?C in said compound to react with one another to form said first polymeric material; (b) selecting a second polymeric material which includes a functional group which is able to react in the presence of said first polymeric material to form a third polymeric material; (c) causing the formation of said third polymeric material by a reaction involving said firs
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: January 26, 2010
    Assignees: Advanced Gel Technology Limited, Aubin Limited
    Inventors: Donald Eagland, Nicholas John Crowther, James Murray, Austin Tobin
  • Patent number: 7645724
    Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a composition that contains at least one unsaturated fatty acid, such as a monoenoic acid and/or polyenoic acid. The unsaturated fatty acid may be contained in an oil-soluble internal phase of the fluid. The breaking composition is believed to act possibly by rearranging, disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid. In a specific, non-limiting instance, a brine fluid gelled with an amine oxide surfactant can have its viscosity broken with an oil such as flax (linseed) oil, soybean oil and/or fish oils containing relatively high amounts of unsaturated fatty acids. The unsaturated fatty acids are thought to auto-oxidize into products such as aldehydes, ketones and saturated fatty acids that break the VES gel.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: January 12, 2010
    Assignee: Baker Hughes Incorporated
    Inventor: James B. Crews
  • Patent number: 7642223
    Abstract: Methods of servicing a wellbore include generating gas in a plugging composition in situ within a permeable zone in the wellbore, thereby improving the ability of the plugging composition to seal the permeable zone. The gas may be generated via a chemical reaction by, for example, introducing first and second reactants to the plugging composition that can react at ambient temperatures in the wellbore. In an embodiment, the first and second reactants are concurrently pumped into the wellbore via separate flow paths within two concentric conduits to the permeable zone where they are allowed to contact each other in the presence of the plugging composition. In another embodiment, the first reactant, the second reactant, and a retarder for slowing the reaction between the two reactants are concurrently pumped to the permeable zone. In yet another embodiment, one of the reactants is encapsulated to delay a reaction between the two reactants.
    Type: Grant
    Filed: October 18, 2004
    Date of Patent: January 5, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Ashok K. Santra, B. Raghava Reddy, Frank Zamora, Giddo Antonio Ocana Gomez, Ronnie G. Morgan, Mark R. Savery
  • Publication number: 20090286699
    Abstract: Certain reversible surfactants, treatment fluids, and methods of use employing such reversible surfactants in subterranean applications are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a base fluid and a reversible surfactant that comprises a hydrophobic portion and a nitrogen-containing functional group that is capable of reacting with carbon dioxide to form a salt; and introducing the treatment fluid into at least a portion of a subterranean formation.
    Type: Application
    Filed: May 15, 2008
    Publication date: November 19, 2009
    Inventors: Rajesh K. Saini, Narongsak Tonmukayakul
  • Publication number: 20090286701
    Abstract: A method of servicing a wellbore comprising providing a composition comprising a mutual solvent precursor, an acid precursor, and an aqueous fluid, and contacting the composition with oil wet solids in the wellbore. A method of servicing a wellbore comprising introducing an oil-based fluid into a wellbore, wherein the oil-based fluid forms oil wet solids in the wellbore, contacting the oil wet solids in the wellbore with a composition comprising a mutual solvent precursor; an acid precursor and an aqueous fluid, and allowing the oil wet solids to become water wet. A method of servicing a well bore comprising contacting a composition comprising a formate ester with oil wet solids in the well bore under conditions wherein the formate ester hydrolyzes to release formic acid, wherein the formic acid catalyzes the hydrolysis of additional formate ester, and wherein all or a portion of the formate ester converts at least a portion of the oil-wet solids to water-wet solids.
    Type: Application
    Filed: May 13, 2008
    Publication date: November 19, 2009
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventor: Eric Davidson
  • Patent number: 7618926
    Abstract: A synergistic blend for foaming concentrated brines comprises at least one foaming agent (in an amount between from about 10 to about 90 weight percent of the blend) and a compound of the formula: CnH2n+1—N—[(CH2)mCOOM]2??(I) wherein n is 4 to 11, M is an alkali metal and m is 1 to 3. Especially suitable as foaming agent are quaternary ammonium salts, alkyl betaines, alkylamidopropyl betaines, sulfabetaines, hydroxysultaines, amphoteric perfluorohydrocarbons, as well as alkylether sulfates. Such synergistic blends are especially useful in the foaming of saturated or near saturated brines.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: November 17, 2009
    Assignee: BJ Services Company
    Inventor: Marek K. Pakulski
  • Patent number: 7618925
    Abstract: A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds.
    Type: Grant
    Filed: March 12, 2009
    Date of Patent: November 17, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis
  • Patent number: 7595284
    Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a composition that contains at least one metal ion source and optionally at least one second source. An optional second source may be a chelating agent where at least one reducing agent source may be additionally optionally used. Another optional component with the metal ion source includes a second, different metal ion source. The breaking composition is believed to directly attack the VES itself, possibly by disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid, and/or possibly by changing the chemical structure of the VES to give two or more products.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: September 29, 2009
    Inventor: James B. Crews
  • Patent number: 7585816
    Abstract: A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The preferred hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of isopropylmethacrylamide derivatives which have a bimodal molecular weight distribution.
    Type: Grant
    Filed: June 15, 2004
    Date of Patent: September 8, 2009
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Karla S. Colle, Larry D. Talley, John M. Longo
  • Patent number: 7572756
    Abstract: A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid is composed of an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which R and R? independently selected from hydrogen, methyl, ethyl or propyl, and X has a value from 1 to 6. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: August 11, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis
  • Publication number: 20090192058
    Abstract: Compositions and methods of treating high temperature subterranean formations of up to about 500° F. (260° C.) are provided. The compositions and methods utilize a high molecular weight synthetic copolymer and a pH buffer than maintains a pH in a range of about 4.5 to about 5.25 for the compositions.
    Type: Application
    Filed: January 28, 2008
    Publication date: July 30, 2009
    Applicant: BJ Services Company
    Inventors: Paul S. Carman, Jeffrey C. Dawson
  • Publication number: 20090139766
    Abstract: The invention provides a method for perforating a well with a perforating fluid comprising a viscoelastic surfactant that essentially stops fluid leak-off after perforation in an overbalanced condition. Another aspect of the invention provides the perforating fluid in itself. The well has a wellbore defined by a generally cylindrical casing in at least a portion of the wellbore (i.e., the wellbore is cased, although it is not necessary cased in its entire length). The wellbore passes through a subterranean formation that comprises hydrocarbon formation fluids (such as oil and/or gas), at least in certain strata. The method comprises placing a perforating device in a wellbore which includes at least one explosive perforating charge that can be detonated in order to perforate the casing and allow the formation fluids to enter the wellbore. The casing is located between the subterranean formation and the perforating device.
    Type: Application
    Filed: November 26, 2008
    Publication date: June 4, 2009
    Inventors: Mathew M. Samuel, Yerik Balabatyrov, Frank F. Chang, Martin Griffith, Liz Morris
  • Patent number: 7527097
    Abstract: A method of fracturing a subterranean formation, the method including injecting a fracturing fluid into the well, wherein said fracturing fluid includes: an oleaginous fluid; and an amine surfactant having the structure wherein R is a C12-C22 aliphatic hydrocarbon; R? is an independently selectable from hydrogen or C1 to C3 alkyl; A is NH or O, and 1?x+y?3; and oil-wet proppant material. Additionally, the method includes pressurizing the fluid so as to cause the subterranean formation to fracture and allow the proppant materials to enter the crack, adding acid to the fluid so as to change the oil-wet proppant materials into water-wet proppant materials, and washing the well with an aqueous based wash solution.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: May 5, 2009
    Assignee: M-I L.L.C.
    Inventor: Arvind D. Patel
  • Patent number: 7521398
    Abstract: A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: April 21, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis
  • Patent number: 7521400
    Abstract: A viscoelastic gelled oil, for example gelled diesel or paraffin oil, is made with a gelling agent, for example a phosphate ester, a metal carboxylate, for example an aluminum carboxylate, and a gel-enhancing surfactant, for example a zwitterionic surfactant, for example erucylamidopropyl betaine. The gel-enhancing surfactant makes the gel viscoelastic, increases the stability and decreases the sensitivity to the concentrations of the gelling agent and the metal carboxylate. The enhanced viscoelastic gelled oils are used, as examples, in hydraulic fracturing, frac packing, gravel packing, diversion, fluid loss control, lost circulation control, sand control, wellbore cleanout, wellbore or pipeline sweeping, organic scale dissolution, organic scale removal, and drilling.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: April 21, 2009
    Assignee: Schlumberger Technology Corporation
    Inventor: Mathew Samuel
  • Patent number: 7514392
    Abstract: A water-base wellbore fluid for use in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. The shale hydration inhibition agent may be present in the form of a free-base or preferably in the form of an acid salt of the disclosed amine compounds.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: April 7, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis
  • Patent number: 7514389
    Abstract: A water based drilling fluid for use in drilling a subterranean well through a subterranean formation that swells in the presence of water, the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R? and R? are independently selectable C1-C3 alkyl; and B? is a charge balancing anion to the quatenary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water.
    Type: Grant
    Filed: September 1, 2004
    Date of Patent: April 7, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis, Steven Young
  • Patent number: 7507694
    Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles; and treating the subterranean formation.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: March 24, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: William W. Shumway, Kenneth W. Pober, Jeff Kirsner
  • Patent number: 7497262
    Abstract: A method of forming a subterranean well and a method of reducing the swelling of shale clay during the drilling of the subterranean well. The method features the use of a water based drilling fluid, wherein the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R?and R?are independently selectable C1-C3 alkyl; and B?is a charge balancing anion to the quaternary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: March 3, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis, Steve Young
  • Patent number: 7494958
    Abstract: A water-base wellbore fluid for use in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the fluid.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: February 24, 2009
    Assignee: M-I L.L.C.
    Inventors: Arvind D. Patel, Emanuel Stamatakis
  • Publication number: 20090038797
    Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.
    Type: Application
    Filed: July 18, 2008
    Publication date: February 12, 2009
    Applicant: OXANE MATERIALS, INC.
    Inventors: Robert D. Skala, John R. Loscutova, Christopher E. Coker
  • Patent number: 7470330
    Abstract: A method of removing metal scale from surfaces that includes contacting the surfaces with a first aqueous solution of a chelating agent, allowing the chelating agent to dissolve the metal scale, acidifying the solution to form a precipitant of the chelating agent and a precipitant of the metal from the metal scale, isolating the precipitant of the chelating agent and the precipitant of the metal from the first solution, selectively dissolving the precipitated chelating agent in a second aqueous solution, and removing the precipitated metal from the second solution is disclosed.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: December 30, 2008
    Assignees: M-1 Production Chemicals UK Limited, Oilfield Mineral Solutions Limited
    Inventor: Richard Keatch
  • Publication number: 20080300152
    Abstract: The present invention provides a method of forming a viscosified treatment fluid comprising: providing a treatment fluid that comprises water and a gelling agent; contacting the treatment fluid with a boronic acid crosslinking agent so as to form a crosslinked gelling agent, wherein the boronic acid crosslinking agent comprises a compound having the formula: The present invention also provides methods of crosslinking gelling agent molecules, methods of treating a subterranean formation, methods of reusing viscosified treatment fluids, methods of fracturing subterranean formations, and methods of placing a gravel pack in subterranean formations. The present invention also provides boronic acid crosslinking agents and viscosified treatment fluids that comprise crosslinked gelling agents, the crosslinked gelling agent being formed from a reaction comprising a gelling agent and a boronic acid crosslinking agent.
    Type: Application
    Filed: July 10, 2008
    Publication date: December 4, 2008
    Inventor: Robert E. Hanes, JR.
  • Patent number: 7435706
    Abstract: A method of reducing the viscosity of oil-based drilling fluids and well service fluids at low temperatures and a thinner compound for use in such drilling fluids and well service fluids is disclosed. The method comprises adding to said drilling fluids or well service fluids a thinner having the formula: R—(C2H4O)n(C3H6O)m(C4H8O)k-H where R is a saturated or unsaturated, linear or branched alkyl radical having about 8 to about 24 carbon atoms, n is a number ranging from about 1 to about 10, m is a number ranging form about 0 to about 10, and k is a number ranging from about 0 to about 10.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: October 14, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Heinz Mueller, Jeff Kirsner, Kimberly Burrows
  • Publication number: 20080242563
    Abstract: A cross-linking composition which comprises (a) an aqueous liquid, (b) a cross-linkable organic polymer, and (c) a solution comprising a zirconium cross-linking agent which comprises a zirconium complex having a molar ratio of 1:2 to 1:4 of zirconium to triethanolamine and a molar ratio of 1:0.1 to 1:1 of zirconium to N,N,N?,N?-tetrakis-(2-hydroxypropyl)-ethylene diamine. The composition can be used in oil field applications for hydraulic fracturing and plugging of permeable zones and leaks in subterranean formations.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 2, 2008
    Inventor: Donald Edward Putzig
  • Publication number: 20080227668
    Abstract: Among other things, corrosion-inhibiting additives that comprise certain surfactants, and associated treatment fluids and methods of use are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises a base fluid, an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; and introducing the treatment fluid into a subterranean formation. In another embodiment, the methods comprise: providing a corrosion-inhibiting additive that comprises an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; contacting a surface with the corrosion-inhibiting additive; and allowing the corrosion-inhibiting additive to interact with the surface, whereby corrosion of the surface is at least partially inhibited or a portion of an undesirable substance on the surface is removed.
    Type: Application
    Filed: March 12, 2007
    Publication date: September 18, 2008
    Inventor: Thomas D. Welton
  • Publication number: 20080227669
    Abstract: Among other things, corrosion-inhibiting additives that comprise certain surfactants, and associated treatment fluids and methods of use are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises a base fluid, an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; and introducing the treatment fluid into a subterranean formation. In another embodiment, the methods comprise: providing a corrosion-inhibiting additive that comprises an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; contacting a surface with the corrosion-inhibiting additive; and allowing the corrosion-inhibiting additive to interact with the surface, whereby corrosion of the surface is at least partially inhibited or a portion of an undesirable substance on the surface is removed.
    Type: Application
    Filed: March 12, 2007
    Publication date: September 18, 2008
    Inventor: Thomas D. Welton
  • Patent number: 7410934
    Abstract: The invention concerns an aqueous viscoelastic fluid for use in the recovery of hydrocarbons. According to the invention, the aqueous viscoelastic fluid comprises a monomer, a dimer or an oligomer of a viscoelastic surfactant able to form a viscoelastic gel under downhole conditions, said surfactant comprising a hydrophobic tail and a hydrophilic head, and being of the following formulae: R—X—Y-Z where R is the hydrophobic tail of the surfactant, Z is the hydrophilic head of the surfactant, said hydrophilic head being charged, X is a stabilising group and Y chain is a linear, saturated or unsaturated, hydrocarbon chain of 1, 2 or 3 carbon atoms or a branched, saturated or unsaturated hydrocarbon chain wherein the main chain is of 1, 2 or 3 carbon atoms, possibly incorporating an aromatic ring.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: August 12, 2008
    Assignee: Schlumberger Technology Corporation
    Inventors: Trevor Hughes, Timothy Gareth John Jones, Gary John Tustin, Jian Zhou
  • Publication number: 20080182763
    Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.
    Type: Application
    Filed: April 3, 2008
    Publication date: July 31, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Ronald G. BLAND, Lirio QUINTERO