Abstract: A method of gravel packing a hole in a subterranean formation having a filter cake coated on the surface thereof that includes injecting into the hole a gravel pack composition comprising gravel and a carrier fluid comprising a base fluid and at least one iminodiacetic acid or salt thereof is disclosed.
Type:
Application
Filed:
June 27, 2008
Publication date:
August 26, 2010
Applicant:
M-I L.L.C.
Inventors:
Raul Navarro, Andrew G.K. Jones, Mark Luyster, Robert L. Horton
Abstract: Treatment fluids for and methods of treating subterranean formations are provided. In certain embodiments, a method is provided comprising providing a treatment fluid comprising a relative permeability modifier, a delayed filter cake breaker, and a carrier fluid, contacting at least a portion of a filter cake in a subterranean formation with the treatment fluid, and removing at least a portion of the filter cake.
Abstract: This invention relates to the use of alkyl amido quaternary ammonium salts, and formulations thereof, as thickening agents in aqueous based fluids, especially those used in oil field applications. The quaternary ammonium salts of the present invention exhibit improved gelling characteristics.
Abstract: A sand slurry composition and a method for making sand slurries are disclosed. The sand slurry composition is comprised of sand, an aqueous liquid and a chemical compound that renders the surface sand of hydrophobic. The method is comprised of rendering sand surface hydrophobic during or before making the slurry. This method and composition can find many applications in different industries, especially in various oil field applications.
Abstract: There is a viscoelastic fluid. The fluid has one or more cationic surfactants selected from the group consisting of certain quaternary salts, certain amines, and combinations thereof; one or more anionic polymers/anionic surfactants; one or more of certain zwitterionic/amphoteric surfactants; and water. There is also a method of fracturing a subterranean formation. The viscoelastic fluid is pumped through a wellbore and into a subterranean formation at a pressure sufficient to fracture the formation. There is also a method for gravel packing a subterranean formation.
Abstract: Pellets can be injected into oil and gas production equipment that may contain stagnant or slow moving system fluids to treat the stagnant or slow moving system fluids to prevent conditions such as corrosion. The pellets have a density such that they may be moved through the equipment by system fluids passing therethrough. When the pellets come into contact with the stagnant or slow moving system fluids, sufficient pellets enter the stagnant or slow moving system fluids to treat it. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
Type:
Grant
Filed:
August 30, 2007
Date of Patent:
August 10, 2010
Assignee:
Baker Hughes Incorporated
Inventors:
Michael Greaves, Steven Jeremy Weghorn, Hani S. Zaki
Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.
Abstract: A method of treating a medium for water fracturing is disclosed, the method comprises: introducing at least one biocide and at least one metabolic inhibitor in the medium, using the medium for water fracturing. In another aspect a method of controlling the post-fracture reservoir souring by the metabolic activities of sulfate reducing bacteria of a well is described: at least one biocide and at least one metabolic inhibitor are introduced in a medium made of water, the medium is used for fracturing the well, and the medium remains in the reservoir to kill and/or inhibit growth of sulfate reducing bacteria.
Type:
Application
Filed:
December 21, 2009
Publication date:
July 29, 2010
Inventors:
Syed Ali, Shawn McCleskey Rimassa, Francois M. Auzerais, Curtis L. Boney, Leiming Li
Abstract: Methods for servicing well bores with hardenable resin compositions are provided. In one embodiment, a method of servicing a well bore includes providing a hydrophobic well bore servicing composition comprising a liquid hardenable resin, a hardening agent, and a weighting material selected to impart a desired first density to the well bore servicing composition; introducing the well bore servicing composition into a well bore comprising a well bore fluid having a second density; allowing the well bore servicing composition to migrate through the well bore fluid to a desired location in the well bore based at least in part upon a difference between the first and second densities; and allowing the liquid hardenable resin to at least partially harden to form a well bore plug at the desired location in the well bore.
Type:
Application
Filed:
January 27, 2009
Publication date:
July 29, 2010
Inventors:
Rickey Lynn Morgan, D. Chad Brenneis, Jeffery Karcher
Abstract: A process to prepare a solution of zirconium-alkanolamine-hydroxycarboxylic acid complex is disclosed and use of the solution in oil field applications such as hydraulic fracturing and plugging of permeable zones. The process comprises contacting an alcohol solution of a zirconium complex with an alkanolamine, then with an ?-hydroxycarboxylic acid to produce a solution of zirconium-alkanolamine-hydroxycarboxylic acid complex. The solution is particularly suitable for use in a cross-linking composition in hydraulic fracturing and plugging of permeable zones of subterranean formations at temperatures of 275° F. (135° C.) and higher in the formation.
Abstract: The current disclosure describes a multifunctional fluid that addresses a new concept in the removal of filter cake. A composition is disclosed comprising: a carrier fluid, a surfactant, a fluorine source and an organic stabilizer able to minimize precipitation of fluorine The associated method to remove the filter cake is also described.
Type:
Application
Filed:
December 19, 2008
Publication date:
June 24, 2010
Inventors:
Michael J. Fuller, Syed Ali, Laurent Pirolli, John W. Still
Abstract: The present invention relates to well bore stabilization and, more particularly, to treatment fluids that may reduce the tendency of shales to swell and associated methods. In some embodiments, the present invention provides a method of stabilizing a subterranean formation that comprises a shale, the method comprising contacting the subterranean formation that comprises the shale with a treatment fluid, the treatment fluid comprising a base fluid, and a hydrophobically modified polymer. In other embodiments, the treatment fluids comprise a base fluid and a hydrophilically modified polymer. In yet other embodiments, the present invention provides shale-inhibiting components, treatment fluids, and methods of reducing the tendency of shale to swell when exposed to a treatment fluid.
Type:
Grant
Filed:
June 4, 2004
Date of Patent:
June 22, 2010
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Larry S. Eoff, B. Raghava Reddy, J. Michael Wilson
Abstract: Nanoemulsions have been discovered to be useful to the oil field. More particularly water-in-oil (W/O), oil-in-water (O/W) and other classes of nanoemulsions have found beneficial application in drilling, completion, well remediation and other oil and gas industry related operations. Additionally, nanoemulsions may reduce friction pressure losses, as well as reduce subsidence of solid weight material during oil and gas operations. New preparation methods for nanoemulsions have also been discovered.
Type:
Application
Filed:
November 25, 2009
Publication date:
June 3, 2010
Applicant:
Baker Hughes Incorporated
Inventors:
Lirio Quintero, David E. Clark, Alexander John McKellar
Abstract: Viscoelastic surfactant (VES) gelled aqueous fluids containing water, a VES, an internal breaker, a VES stabilizer, a fluid loss control agent and a viscosity enhancer are useful as treating fluids and particularly as fracturing fluids for subterranean formations. These VES-based fluids have faster and more complete clean-up than polymer-based fracturing fluids. The use of an internal breaker permits ready removal of the unique VES micelle based pseudo-filter cake with several advantages including reducing the typical VES loading and total fluid volume since more VES fluid stays within the fracture, generating a more optimum fracture geometry for enhanced reservoir productivity, and treating reservoirs with permeability above the present VES limit of approximately 400 md to at least 2000 md.
Type:
Grant
Filed:
February 26, 2007
Date of Patent:
May 25, 2010
Assignee:
Baker Hughes Incorporated
Inventors:
James B. Crews, Tianping Huang, Allen D. Gabrysch, James H. Treadway, John R. Willingham, Patrick A. Kelly, William R. Wood
Abstract: Compressible and resilient sealing compositions for injection into oil or gas wells are provided, which are capable of forming effective seals adjacent well casings even at elevated downhole temperatures. The compositions comprise an epoxy component present in a predominant weight percentage, including an epoxy resin and a glycidyl ether modifier, as well as additional components rendering the cured compositions both compressive and resilient. The compositions are used as a partial or complete substitute for casing cements, and can be used to good effect with expandable casing installations or for sealing casing breaks. High set-up temperature (220-300° F.) compositions preferably include an ethoxylated alkyl (C10-C20) monoamine or diamine, and alkyl pyridine quaternary ammonium components.
Abstract: Provided herein are organophilic clays that comprise a smectite clay modified by reaction with a protonated amphoteric surfactant. Also provided are fluids that comprise an oil and an organophilic clay comprising a smectite clay modified by reaction with a protonated amphoteric surfactant. Also provided are methods of preparing and using these organophilic clays.
Abstract: Biocidal compositions and their use in aqueous media, such as metalworking fluids, the compositions comprising a biocidal agent; and a non-biocidal primary amino alcohol compound of the formula (I); wherein R1, R2, R3, R4, and R5 are as defined herein.
Type:
Application
Filed:
December 13, 2007
Publication date:
April 15, 2010
Applicants:
ANGUS CHEMICAL COMPANY, DOW GLOBAL TECHNOLOGIES INC.
Inventors:
Charles E. Coburn, John L. Pohlman, Bonnie A. Pyzowski, Patrick E. Brutto, George David Green, Raymond J. Swedo
Abstract: A composition comprising: (i) a chelating aminocarboxylic acid-C8-C22 amine complex; (ii) a C15-C21 bis(2-hydroxyethyl)amide; and (iii) a C15-C44 imidazoline compound.
Type:
Grant
Filed:
October 6, 2005
Date of Patent:
March 9, 2010
Assignee:
Rohm and Haas Company
Inventors:
Rajiv M. Banavali, Bharati Dinkar Chheda, Guido Mazza Manari
Abstract: The present invention relates generally to a method for treating hydrogen sulfide-containing fluids, more specifically to a method of treating hydrogen sulfide associated with petroleum and/or natural gas production.
Abstract: A composition for mitigating or preventing the formation of an emulsion between naphthenic acid and metal cations in a hydrocarbon body, the composition including at least one alkoxylated amine and at least one acid and/or alcohol is disclosed.
Type:
Application
Filed:
July 23, 2008
Publication date:
January 28, 2010
Inventors:
James Smith, C. Y. Khandekar, Rohan Wilson
Abstract: Methods and aqueous acid solutions for acidizing wells containing sludging and emulsifying oil are disclosed. An aqueous acid solution of the invention comprises water, hydrochloric acid, a cationic hydrochloric acid corrosion inhibitor and a conjugate ion pair of a cationic amine oxide surfactant and an anionic surfactant that does not react with the cationic hydrochloric acid corrosion inhibitor.
Type:
Grant
Filed:
August 21, 2004
Date of Patent:
January 26, 2010
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Juanita M. Cassidy, Chad E. Kiser, Jim L. Lane
Abstract: A process for recovering materials from a subterranean formation, for example in enhanced oil recovery, comprises: (A) (a) (i) selecting a first polymeric material having a repeat unit of formula (A) wherein A and B are the same or different, are selected from optionally-substituted aromatic and heteroaromatic groups and at least one comprises a relatively polar atom or group and R1 and R2 independently comprise relatively non-polar atoms or groups; or (ii) selecting a first polymeric material prepared or preparable by providing a compound of general formula (B) wherein A, B, R1 and R2 are as described above, in an aqueous solvent and causing the groups C?C in said compound to react with one another to form said first polymeric material; (b) selecting a second polymeric material which includes a functional group which is able to react in the presence of said first polymeric material to form a third polymeric material; (c) causing the formation of said third polymeric material by a reaction involving said firs
Type:
Grant
Filed:
March 28, 2003
Date of Patent:
January 26, 2010
Assignees:
Advanced Gel Technology Limited, Aubin Limited
Inventors:
Donald Eagland, Nicholas John Crowther, James Murray, Austin Tobin
Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a composition that contains at least one unsaturated fatty acid, such as a monoenoic acid and/or polyenoic acid. The unsaturated fatty acid may be contained in an oil-soluble internal phase of the fluid. The breaking composition is believed to act possibly by rearranging, disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid. In a specific, non-limiting instance, a brine fluid gelled with an amine oxide surfactant can have its viscosity broken with an oil such as flax (linseed) oil, soybean oil and/or fish oils containing relatively high amounts of unsaturated fatty acids. The unsaturated fatty acids are thought to auto-oxidize into products such as aldehydes, ketones and saturated fatty acids that break the VES gel.
Abstract: Methods of servicing a wellbore include generating gas in a plugging composition in situ within a permeable zone in the wellbore, thereby improving the ability of the plugging composition to seal the permeable zone. The gas may be generated via a chemical reaction by, for example, introducing first and second reactants to the plugging composition that can react at ambient temperatures in the wellbore. In an embodiment, the first and second reactants are concurrently pumped into the wellbore via separate flow paths within two concentric conduits to the permeable zone where they are allowed to contact each other in the presence of the plugging composition. In another embodiment, the first reactant, the second reactant, and a retarder for slowing the reaction between the two reactants are concurrently pumped to the permeable zone. In yet another embodiment, one of the reactants is encapsulated to delay a reaction between the two reactants.
Type:
Grant
Filed:
October 18, 2004
Date of Patent:
January 5, 2010
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Ashok K. Santra, B. Raghava Reddy, Frank Zamora, Giddo Antonio Ocana Gomez, Ronnie G. Morgan, Mark R. Savery
Abstract: Certain reversible surfactants, treatment fluids, and methods of use employing such reversible surfactants in subterranean applications are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a base fluid and a reversible surfactant that comprises a hydrophobic portion and a nitrogen-containing functional group that is capable of reacting with carbon dioxide to form a salt; and introducing the treatment fluid into at least a portion of a subterranean formation.
Type:
Application
Filed:
May 15, 2008
Publication date:
November 19, 2009
Inventors:
Rajesh K. Saini, Narongsak Tonmukayakul
Abstract: A method of servicing a wellbore comprising providing a composition comprising a mutual solvent precursor, an acid precursor, and an aqueous fluid, and contacting the composition with oil wet solids in the wellbore. A method of servicing a wellbore comprising introducing an oil-based fluid into a wellbore, wherein the oil-based fluid forms oil wet solids in the wellbore, contacting the oil wet solids in the wellbore with a composition comprising a mutual solvent precursor; an acid precursor and an aqueous fluid, and allowing the oil wet solids to become water wet. A method of servicing a well bore comprising contacting a composition comprising a formate ester with oil wet solids in the well bore under conditions wherein the formate ester hydrolyzes to release formic acid, wherein the formic acid catalyzes the hydrolysis of additional formate ester, and wherein all or a portion of the formate ester converts at least a portion of the oil-wet solids to water-wet solids.
Abstract: A synergistic blend for foaming concentrated brines comprises at least one foaming agent (in an amount between from about 10 to about 90 weight percent of the blend) and a compound of the formula: CnH2n+1—N—[(CH2)mCOOM]2??(I) wherein n is 4 to 11, M is an alkali metal and m is 1 to 3. Especially suitable as foaming agent are quaternary ammonium salts, alkyl betaines, alkylamidopropyl betaines, sulfabetaines, hydroxysultaines, amphoteric perfluorohydrocarbons, as well as alkylether sulfates. Such synergistic blends are especially useful in the foaming of saturated or near saturated brines.
Abstract: A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds.
Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a composition that contains at least one metal ion source and optionally at least one second source. An optional second source may be a chelating agent where at least one reducing agent source may be additionally optionally used. Another optional component with the metal ion source includes a second, different metal ion source. The breaking composition is believed to directly attack the VES itself, possibly by disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid, and/or possibly by changing the chemical structure of the VES to give two or more products.
Abstract: A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The preferred hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of isopropylmethacrylamide derivatives which have a bimodal molecular weight distribution.
Type:
Grant
Filed:
June 15, 2004
Date of Patent:
September 8, 2009
Assignee:
ExxonMobil Upstream Research Company
Inventors:
Karla S. Colle, Larry D. Talley, John M. Longo
Abstract: A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid is composed of an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which R and R? independently selected from hydrogen, methyl, ethyl or propyl, and X has a value from 1 to 6. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art.
Abstract: Compositions and methods of treating high temperature subterranean formations of up to about 500° F. (260° C.) are provided. The compositions and methods utilize a high molecular weight synthetic copolymer and a pH buffer than maintains a pH in a range of about 4.5 to about 5.25 for the compositions.
Abstract: The invention provides a method for perforating a well with a perforating fluid comprising a viscoelastic surfactant that essentially stops fluid leak-off after perforation in an overbalanced condition. Another aspect of the invention provides the perforating fluid in itself. The well has a wellbore defined by a generally cylindrical casing in at least a portion of the wellbore (i.e., the wellbore is cased, although it is not necessary cased in its entire length). The wellbore passes through a subterranean formation that comprises hydrocarbon formation fluids (such as oil and/or gas), at least in certain strata. The method comprises placing a perforating device in a wellbore which includes at least one explosive perforating charge that can be detonated in order to perforate the casing and allow the formation fluids to enter the wellbore. The casing is located between the subterranean formation and the perforating device.
Type:
Application
Filed:
November 26, 2008
Publication date:
June 4, 2009
Inventors:
Mathew M. Samuel, Yerik Balabatyrov, Frank F. Chang, Martin Griffith, Liz Morris
Abstract: A method of fracturing a subterranean formation, the method including injecting a fracturing fluid into the well, wherein said fracturing fluid includes: an oleaginous fluid; and an amine surfactant having the structure wherein R is a C12-C22 aliphatic hydrocarbon; R? is an independently selectable from hydrogen or C1 to C3 alkyl; A is NH or O, and 1?x+y?3; and oil-wet proppant material. Additionally, the method includes pressurizing the fluid so as to cause the subterranean formation to fracture and allow the proppant materials to enter the crack, adding acid to the fluid so as to change the oil-wet proppant materials into water-wet proppant materials, and washing the well with an aqueous based wash solution.
Abstract: A method of using a water-base wellbore fluid in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. Further the shale hydration inhibition agent may be present in the form of a free-base or in the form of an acid salt of the disclosed amine compounds.
Abstract: A viscoelastic gelled oil, for example gelled diesel or paraffin oil, is made with a gelling agent, for example a phosphate ester, a metal carboxylate, for example an aluminum carboxylate, and a gel-enhancing surfactant, for example a zwitterionic surfactant, for example erucylamidopropyl betaine. The gel-enhancing surfactant makes the gel viscoelastic, increases the stability and decreases the sensitivity to the concentrations of the gelling agent and the metal carboxylate. The enhanced viscoelastic gelled oils are used, as examples, in hydraulic fracturing, frac packing, gravel packing, diversion, fluid loss control, lost circulation control, sand control, wellbore cleanout, wellbore or pipeline sweeping, organic scale dissolution, organic scale removal, and drilling.
Abstract: A water-base wellbore fluid for use in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. The shale hydration inhibition agent may be present in the form of a free-base or preferably in the form of an acid salt of the disclosed amine compounds.
Abstract: A water based drilling fluid for use in drilling a subterranean well through a subterranean formation that swells in the presence of water, the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R? and R? are independently selectable C1-C3 alkyl; and B? is a charge balancing anion to the quatenary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water.
Type:
Grant
Filed:
September 1, 2004
Date of Patent:
April 7, 2009
Assignee:
M-I L.L.C.
Inventors:
Arvind D. Patel, Emanuel Stamatakis, Steven Young
Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles; and treating the subterranean formation.
Type:
Grant
Filed:
March 12, 2004
Date of Patent:
March 24, 2009
Assignee:
Halliburton Energy Services, Inc.
Inventors:
William W. Shumway, Kenneth W. Pober, Jeff Kirsner
Abstract: A method of forming a subterranean well and a method of reducing the swelling of shale clay during the drilling of the subterranean well. The method features the use of a water based drilling fluid, wherein the drilling fluid is formulated to include: an aqueous based continuous phase; a weight material; an optional shale hydration inhibition agent and a shale encapsulator. The shale encapsulator has the formula: in which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1-C6 alkyl, C2-C6 ether or C2-C6 amide; R, R?and R?are independently selectable C1-C3 alkyl; and B?is a charge balancing anion to the quaternary amine. The shale hydration inhibition agent and the shale encapsulator may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water.
Type:
Grant
Filed:
February 8, 2007
Date of Patent:
March 3, 2009
Assignee:
M-I L.L.C.
Inventors:
Arvind D. Patel, Emanuel Stamatakis, Steve Young
Abstract: A water-base wellbore fluid for use in subterranean wells that penetrate through a subterranean formation containing a shale which swells in the presence of water. The well bore fluid includes, an aqueous based continuous phase, and a shale hydration inhibition agent. One illustrative shale hydration inhibition agent is preferably the reaction product of a hydrogenation reaction of the product of the reaction of an aromatic amine with an aldehyde, preferably formaldehyde. Alternatively the shale hydration inhibition agent may be the reaction product of a hydrogenation reaction of the product of the reaction of aniline and formaldehyde. In one illustrative embodiment, the shale hydration inhibition agent is selected from the class of compounds known as polycycloaliphatic amines. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the fluid.
Abstract: The present invention relates to proppants which can be used to prop open subterranean formation fractions. Proppant formulations are further disclosed which use one or more proppants of the present invention. Methods to prop open subterranean formation fractions are further disclosed. In addition, other uses for the proppants of the present invention are further disclosed, as well as methods of making the proppants.
Type:
Application
Filed:
July 18, 2008
Publication date:
February 12, 2009
Applicant:
OXANE MATERIALS, INC.
Inventors:
Robert D. Skala, John R. Loscutova, Christopher E. Coker
Abstract: A method of removing metal scale from surfaces that includes contacting the surfaces with a first aqueous solution of a chelating agent, allowing the chelating agent to dissolve the metal scale, acidifying the solution to form a precipitant of the chelating agent and a precipitant of the metal from the metal scale, isolating the precipitant of the chelating agent and the precipitant of the metal from the first solution, selectively dissolving the precipitated chelating agent in a second aqueous solution, and removing the precipitated metal from the second solution is disclosed.
Type:
Grant
Filed:
March 23, 2007
Date of Patent:
December 30, 2008
Assignees:
M-1 Production Chemicals UK Limited, Oilfield Mineral Solutions Limited
Abstract: The present invention provides a method of forming a viscosified treatment fluid comprising: providing a treatment fluid that comprises water and a gelling agent; contacting the treatment fluid with a boronic acid crosslinking agent so as to form a crosslinked gelling agent, wherein the boronic acid crosslinking agent comprises a compound having the formula: The present invention also provides methods of crosslinking gelling agent molecules, methods of treating a subterranean formation, methods of reusing viscosified treatment fluids, methods of fracturing subterranean formations, and methods of placing a gravel pack in subterranean formations. The present invention also provides boronic acid crosslinking agents and viscosified treatment fluids that comprise crosslinked gelling agents, the crosslinked gelling agent being formed from a reaction comprising a gelling agent and a boronic acid crosslinking agent.
Abstract: A method of reducing the viscosity of oil-based drilling fluids and well service fluids at low temperatures and a thinner compound for use in such drilling fluids and well service fluids is disclosed. The method comprises adding to said drilling fluids or well service fluids a thinner having the formula: R—(C2H4O)n(C3H6O)m(C4H8O)k-H where R is a saturated or unsaturated, linear or branched alkyl radical having about 8 to about 24 carbon atoms, n is a number ranging from about 1 to about 10, m is a number ranging form about 0 to about 10, and k is a number ranging from about 0 to about 10.
Type:
Grant
Filed:
December 29, 2000
Date of Patent:
October 14, 2008
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Heinz Mueller, Jeff Kirsner, Kimberly Burrows
Abstract: A cross-linking composition which comprises (a) an aqueous liquid, (b) a cross-linkable organic polymer, and (c) a solution comprising a zirconium cross-linking agent which comprises a zirconium complex having a molar ratio of 1:2 to 1:4 of zirconium to triethanolamine and a molar ratio of 1:0.1 to 1:1 of zirconium to N,N,N?,N?-tetrakis-(2-hydroxypropyl)-ethylene diamine. The composition can be used in oil field applications for hydraulic fracturing and plugging of permeable zones and leaks in subterranean formations.
Abstract: Among other things, corrosion-inhibiting additives that comprise certain surfactants, and associated treatment fluids and methods of use are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises a base fluid, an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; and introducing the treatment fluid into a subterranean formation. In another embodiment, the methods comprise: providing a corrosion-inhibiting additive that comprises an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; contacting a surface with the corrosion-inhibiting additive; and allowing the corrosion-inhibiting additive to interact with the surface, whereby corrosion of the surface is at least partially inhibited or a portion of an undesirable substance on the surface is removed.
Abstract: Among other things, corrosion-inhibiting additives that comprise certain surfactants, and associated treatment fluids and methods of use are provided. In one embodiment, the methods comprise: providing a treatment fluid that comprises a base fluid, an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; and introducing the treatment fluid into a subterranean formation. In another embodiment, the methods comprise: providing a corrosion-inhibiting additive that comprises an ?,?-unsaturated aldehyde, a sulfur-containing compound, and at least one nitrogen-containing surfactant that is anionic, nonionic, amphoteric, or zwitterionic; contacting a surface with the corrosion-inhibiting additive; and allowing the corrosion-inhibiting additive to interact with the surface, whereby corrosion of the surface is at least partially inhibited or a portion of an undesirable substance on the surface is removed.
Abstract: The invention concerns an aqueous viscoelastic fluid for use in the recovery of hydrocarbons. According to the invention, the aqueous viscoelastic fluid comprises a monomer, a dimer or an oligomer of a viscoelastic surfactant able to form a viscoelastic gel under downhole conditions, said surfactant comprising a hydrophobic tail and a hydrophilic head, and being of the following formulae: R—X—Y-Z where R is the hydrophobic tail of the surfactant, Z is the hydrophilic head of the surfactant, said hydrophilic head being charged, X is a stabilising group and Y chain is a linear, saturated or unsaturated, hydrocarbon chain of 1, 2 or 3 carbon atoms or a branched, saturated or unsaturated hydrocarbon chain wherein the main chain is of 1, 2 or 3 carbon atoms, possibly incorporating an aromatic ring.
Type:
Grant
Filed:
February 13, 2002
Date of Patent:
August 12, 2008
Assignee:
Schlumberger Technology Corporation
Inventors:
Trevor Hughes, Timothy Gareth John Jones, Gary John Tustin, Jian Zhou
Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.