Oxygen Is Attached Directly Or Indirectly To Carbon By Nonionic Bonding Patents (Class 507/244)
  • Publication number: 20140305649
    Abstract: Methods of stimulating a well comprising providing a stimulation fluid comprising at least one surfactant and submicron particles, the submicron particles having a particle size between about 200 nm and about 800 nm and a specific surface area greater than about 5 square meters per gram; and introducing the stimulation fluid into a wellbore. Additional methods to enhance oil recovery from subterranean reservoirs accessible via a well are described.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 16, 2014
    Inventors: Hongxin Tang, Zayne Hai Lu
  • Publication number: 20140309149
    Abstract: Proppants for use in fractured or gravel packed/frac packed oil and gas wells are provided with a contaminant removal component to remove one or more of the contaminants found in subterranean water/hydrocarbon from a production well. The water/hydrocarbon cleaning proppant solids may be used as discrete particles in a proppant formulation, as a coating on proppant solids in pores of a porous proppant solid or as part of the proppant's internal structure. The contaminant removal component removes contaminants, especially dissolved contaminants, in the subterranean water or hydrocarbon before the water/hydrocarbon leaves the well. For those contaminant removal components that can be regenerated, such as ion exchange resins, a measured quantity of an acidic regeneration solution can be injected into the fractured stratum for regeneration and recovered when the well resumes production.
    Type: Application
    Filed: June 25, 2014
    Publication date: October 16, 2014
    Applicant: PREFERRED TECHNOLOGY, LLC
    Inventors: Robert Ray McDaniel, Avis Lloyd McCrary
  • Publication number: 20140303049
    Abstract: The present invention relates to processes for consolidating an underground formation with a consolidating mineral. The consolidating material is a carbonate and is produced from an alkaline treatment fluid containing, in at least some embodiments, environmentally friendly and inexpensive components. In one embodiment, the process can be applied to consolidation of an underground formation during or following drilling. The present invention also provides a treatment fluid suitable for use in such processes.
    Type: Application
    Filed: October 31, 2012
    Publication date: October 9, 2014
    Applicant: Cleansorb Limited
    Inventor: Duncan Holdsworth
  • Publication number: 20140284056
    Abstract: A well fluid including: (i) an oleaginous continuous phase; (ii) an N-acyl amino acid alkylamide; and (iii) a solid particulate. A method of treating a portion of a well with a particulate, the method including the steps of: (A) forming the well fluid; and (B) introducing the well fluid into the well. In addition, the N-acyl amino acid alkylamide affords an invert emulsion with a high OWR ratio, that is, greater than 40% oil by volume, for example, 70:30. The invert emulsion has a low viscosity, but can still suspend gravel. In a gravel packing application, the low viscosity of the invert emulsion fluid eliminates the need to break the emulsion during flow-back.
    Type: Application
    Filed: March 20, 2013
    Publication date: September 25, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Dhanashree Gajanan Kulkarni, Vikrant Bhavanishankar Wagle
  • Publication number: 20140284059
    Abstract: A downhole fluid comprises a base fluid, for example a hydrocarbon base fluid, and a gelling agent. The gelling agent has an aromatic core of one or more aromatic rings, the gelling agent having two or more amide branches distributed about the aromatic core, each of the two or more amide branches having one or more organic groups. An example gelling agent is a pyromellitamide gelling agent. The pyromellitamide gelling agent may have the general formula of: with R1, R2, R3, R4, R5, R6, R7, and R8 each being a hydrogen or an organic group. Methods of use and composition are discussed.
    Type: Application
    Filed: March 22, 2013
    Publication date: September 25, 2014
    Inventors: Shaun T. Mesher, Olivia Steward, Daniel Firth
  • Patent number: 8841241
    Abstract: Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.
    Type: Grant
    Filed: April 12, 2011
    Date of Patent: September 23, 2014
    Assignees: Board of Regents, The University of Texas System, BASF SE
    Inventors: Upali P. Weerasooriya, Gary A. Pope, Christian Bittner, Guenter Oetter, Jack F. Tinsley, Christian Spindler, Gabriela Alvarez-Jurgenson, Sophie Maitro-Vogel
  • Publication number: 20140262280
    Abstract: The present disclosure provides chemical compositions useful for minimizing or preventing the precipitation of sludge, such as asphaltenes, maltenes, or similar asphaltic components, during an acidizing treatment. Methods for preventing or minimizing sludge formation are also disclosed. The anti-sludge compositions can be added to an aqueous acidic solution before injecting the solution into a well for treatment. The compositions can include a formulated dodecylbenzene sulfonic acid, a cationic surfactant, a corrosion inhibitor, and an iron reducing agent, in addition to other additives.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: Ecolab USA Inc.
    Inventor: Donald G. Hill
  • Patent number: 8828238
    Abstract: A novel thermophilic bacterium is provided, which has a 16S rDNA sequence as set forth in SEQ ID NO. 1. The thermophilic bacterium excretes extracellular proteins having excellent metal-ion binding ability, being useful in the treatment of boiler equipment, pipelines, geothermal wells or industrial wastewater or hard water.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: September 9, 2014
    Assignee: Industrial Technology Research Instiute
    Inventors: Yin-Lung Han, Tai-Rong Guo, Jo-Shu Chang, I-Ju Chou
  • Publication number: 20140243246
    Abstract: A method for improving the performance of fracturing processes in oil production fields may rely on polymer coated particles carried in the fracturing fluid. The particles may include heavy substrates, such as sand, ceramic sand, or the like coated with polymers selected to absorb water, increasing the area and volume to travel more readily with the flow of fluid without settling out, or allowing the substrate to settle out. Ultimately, the substrate may become lodged in the fissures formed by the pressure or hydraulic fracturing, resulting in propping open of the fissures for improved productivity.
    Type: Application
    Filed: February 4, 2014
    Publication date: August 28, 2014
    Applicant: AQUASMART ENTERPRISES, LLC
    Inventor: Calder Hendrickson
  • Publication number: 20140224484
    Abstract: The present disclosure includes a nonionic surfactant and a method of providing the nonionic surfactant, where the nonionic surfactant is soluble in carbon dioxide and is used as part of a dispersion for enhanced crude oil recovery. The nonionic surfactant can be part of an emulsion that includes carbon dioxide and a diluent.
    Type: Application
    Filed: September 20, 2012
    Publication date: August 14, 2014
    Applicant: DOW Global Technologies LLC
    Inventors: Sayeed Abbas, Aaron W. Sanders, Debashis Chakraborty
  • Publication number: 20140224485
    Abstract: A gravel packing fluid and method for brine-sensitive formations. The fluid comprises an invert oil emulsion compatible with oil based drilling fluids and having a suspension agent comprising polyurea and dimer diamine. The fluid is capable of carrying gravel yet has a viscosity less than 100 cp, often eliminating the need for an emulsion breaker during flow-back of the fluid to the well surface after deposition of gravel in the well.
    Type: Application
    Filed: February 8, 2013
    Publication date: August 14, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Vikrant Bhavanishanker Wagle, Dhanashree Gajanan Kulkarni
  • Publication number: 20140213490
    Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a wellbore servicing fluid comprising a coupling agent, a hardenable resin and a hardening agent into the wellbore wherein the coupling agent comprises a multihydroxy phenyl, a dihydroxy phenyl, a trihydroxy phenyl, ascorbic acid, a hydroxymethylnaphthol, an oxidation product thereof, a derivative thereof, or combinations thereof. A wellbore servicing fluid comprising a coupling agent, a hardenable resin, a hardening agent and a proppant wherein the coupling agent comprises a multihydroxy phenyl, a dihydroxy phenyl, a trihydroxy phenyl, ascorbic acid, a hydroxymethylphenol, a hydroxymethylnaphthol, an oxidation product thereof, a derivative thereof, or combinations thereof.
    Type: Application
    Filed: January 31, 2013
    Publication date: July 31, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: James William OGLE, Philip D. NGUYEN, Feng LIANG
  • Patent number: 8791054
    Abstract: A method of converting an inactive biocide into an active biocide comprises: contacting the inactive biocide with an activating agent, wherein the activating agent is capable of chemically reacting with the inactive biocide; and causing or allowing a chemical reaction to take place between the inactive biocide and the activating agent, wherein the chemical reaction produces the active biocide. The methods can also include deactivating the active biocide via a chemical reaction between the active biocide and a deactivating agent.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: July 29, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Jay P. Deville
  • Publication number: 20140196898
    Abstract: A proppant includes a particle and a hybrid coating disposed about the particle. The particle is present in an amount of from about 90 to about 99.5 percent by weight based on the total weight of the proppant and the hybrid coating is present in an amount of from about 0.5 to about 10 percent by weight based on the total weight of the proppant. The hybrid coating comprises the reaction product of an isocyanate component and an alkali metal silicate solution including water and an alkali metal silicate. A method of forming the proppant includes the steps of providing the particle, the isocyanate composition, and the alkali metal silicate solution. The method also includes the steps of combining the isocyanate composition and the alkali metal silicate solution to react and form the hybrid coating and coating the particle with the hybrid coating to form the proppant.
    Type: Application
    Filed: April 25, 2012
    Publication date: July 17, 2014
    Inventors: Christopher Tanguay, Rajesh Kumar, Fikri Emrah Alemdaroglu
  • Patent number: 8772203
    Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: July 8, 2014
    Assignee: Clearwater International, LLC
    Inventor: Kevin M. Schwartz
  • Patent number: 8772204
    Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The Method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: July 8, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lewis R. Norman, Rajesh K. Saini
  • Patent number: 8757260
    Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.
    Type: Grant
    Filed: February 11, 2009
    Date of Patent: June 24, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Hongyu Luo, Dwight D. Fulton
  • Publication number: 20140151042
    Abstract: A breaker fluid may include a base fluid; and an inactive chelating agent. A process may include pumping a first wellbore fluid comprising an inactive chelating agent into a wellbore through a subterranean formation; and activating the inactive chelating agent to release an active chelating agent into the wellbore.
    Type: Application
    Filed: February 22, 2012
    Publication date: June 5, 2014
    Applicant: M-I L.L.C.
    Inventors: Lee Faugerstrom, Robert L. Horton, Mark Luyster, Chris Shepherd, Bethicia B. Prasek, James Lepage
  • Publication number: 20140116696
    Abstract: Trivalent-ion chelating agents may be useful in mitigating the formation aluminum and ferric precipitates in subterranean formations during acidizing operations. An acidizing operation may include introducing an acidizing fluid into a wellbore penetrating a subterranean formation, the acidizing fluid comprising an aqueous fluid, an acid source, and a trivalent-ion chelating agent, e.g., hydroxamates, 6,7-dihydroxyquinoline, 3-hydroxy-4-pyridinones, and any combination thereof. In some instances, trivalent-ion chelating agents with a pKa of less than about 7 may be particularly useful in acidizing operations.
    Type: Application
    Filed: October 30, 2012
    Publication date: May 1, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventor: Enrique A. Reyes
  • Publication number: 20140121137
    Abstract: Formulation for a natural product as a replacement for the use of traditional acidic chemical stimulation methods for the emulsification, removal and release of paraffin and asphaltenes from low producing or pumped off wells and reservoirs with the use of traditional methodologies. Also a method of use of formulation for stimulating an oil well consisting of introducing into the wellbore a biodegradable, non-reactive fluid system containing a water-miscible fatty acid solvent, a solution of fatty acids, an amino alcohol, and at least one non-ionic surfactant. The fluid system may be further in the form of a nanoemulsion that is formed by combining a colloidal solution with one or more emulsifiers, an alcohol, and water. The fluid system may be used in well remediation and stimulation as well as additional, alternative applications such as the cleaning of surface and/or downhole equipment.
    Type: Application
    Filed: October 24, 2013
    Publication date: May 1, 2014
    Inventor: Paul Andrecola
  • Patent number: 8709982
    Abstract: The invention relates to the use of quaternary polyamines having formula (I) for the recovery of oil from reservoirs formula (I), wherein n>=1 R1 represents H, CH3, CH2CH3, CnH2n+1 R2 represents H2CHOHCH2, CH2, CH2CH?CH2 R3 represents CH3, CH2CH3, CnH2n+1 R4 represents CH2, CH2CH?CH2 when R2 and R4 are allyl group, they can jointly form aliphatic cyclic structures, the ratio between the carbon atoms and nitrogen atoms (C/N) ranges from 2 to 30.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: April 29, 2014
    Assignee: ENI S.p.A.
    Inventors: Lucilla Del Gaudio, Thomas Paul Lockhart, Emanuele Vignati
  • Publication number: 20140107000
    Abstract: The present invention relates to functional fluid compositions containing antioxidants, and specifically stable compositions containing antioxidants with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and antioxidants containing a phenolic or benzoic group, where the antioxidant is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.
    Type: Application
    Filed: May 15, 2012
    Publication date: April 17, 2014
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Danielle N. Ivancic, James D. Burrington, Ewan E. Delbridge
  • Patent number: 8697754
    Abstract: Biocidal compositions and their use in aqueous media, such as metalworking fluids, the compositions comprising a biocidal agent; and a non-biocidal primary amino alcohol compound of the formula (I): wherein R1, R2, R3, R4, and R5 are as defined herein.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: April 15, 2014
    Inventors: Patrick E. Brutto, Charles E. Coburn, G. David Green, Bonnie A. Pyzowski, Raymond J. Swedo, John Pohlman
  • Patent number: 8697614
    Abstract: Chemical compounds that are N-lauroyl amino acids or derivatives thereof were found to have oil-releasing activity. Solutions containing these compounds may be introduced into oil reservoirs or onto oil-contaminated surface sites to release oil from oil-coated surfaces. The released oil may be recovered for further processing or waste disposal.
    Type: Grant
    Filed: November 17, 2011
    Date of Patent: April 15, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Eric R. Choban, Berardino D'Achille, Rachel L. Hardie, Michael P. Perry, Christina S. Stauffer, Bogdan Szostek
  • Patent number: 8691736
    Abstract: The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.
    Type: Grant
    Filed: June 14, 2010
    Date of Patent: April 8, 2014
    Assignees: ConocoPhillips Company, University of Kansas
    Inventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
  • Publication number: 20140090841
    Abstract: A method of recovering crude oil from a subterranean hydrocarbon-containing formation, comprises the steps: i) injecting into said formation an enhanced oil recovery composition comprising a) a surfactant having the general formula: R1-X—R2, wherein R1 is an open chain sugar alcohol, wherein X is one selected from NH, NCH3 and NCH2CH3, and wherein R2 is an aliphatic or aromatic group comprising at least 5 carbon atoms, b) water, and ii) recovering the crude oil, typically from one or more production wells. One advantage is that the composition is natural product-based. It has superior emulsification, wetting and dispersion capabilities. The composition functions well under heat, pressure, high salinity and high water hardness. The starting materials of the surfactant are renewable and inexpensive. The surfactant is non-toxic and degradable.
    Type: Application
    Filed: April 25, 2012
    Publication date: April 3, 2014
    Applicant: ORGANOPETROLEUM PSP AB
    Inventor: Peter S Piispanen
  • Publication number: 20140069644
    Abstract: A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising a snake-in-cage composition; and placing the wellbore servicing fluid into a wellbore wherein the snake dissociates from the cage and enters one or more permeable zones within the wellbore. A wellbore treatment composition comprising a snake disposed within a cage wherein the cage comprises a crosslinked polymer.
    Type: Application
    Filed: September 13, 2012
    Publication date: March 13, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: B. Raghava REDDY, Jeremy HOLTSCLAW, James William OGLE, Jimmie WEAVER, Rajesh Kumar SAINI, Aaron BEUTERBAUGH, Michael Wayne SANDERS
  • Patent number: 8669212
    Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: March 11, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lewis R. Norman, Rajesh K. Saini
  • Patent number: 8669214
    Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: March 11, 2014
    Assignees: ConocoPhillips Company, University of Kansas
    Inventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
  • Patent number: 8653009
    Abstract: The invention relates to the use of compounds comprising three hydrophobic groups as additives to a stream of crude oil containing carboxylic acids, in particular naphthenic acids, and salt water, to prevent the formation of calcium carboxylates when the fluid is exposed to shear forces. Preferably, the compounds are added to a crude oil/water stream containing organic acids Ca2+ ions at a point between the well and the pressure reduction valve in the crude oil receiving station.
    Type: Grant
    Filed: June 18, 2008
    Date of Patent: February 18, 2014
    Assignee: AKZO Nobel N.V.
    Inventors: Martin Hellsten, Ingemar Uneback
  • Patent number: 8653011
    Abstract: A gelled organic-based fluid system and method of forming and using the system. The fluid system is prepared by gelling an organic solvent, a viscoelastic surfactant, and a nitrogen compound having a free electron pair such as urea in an amount effective to both increase viscosity and increase a rate of breaking the viscosity, relative to the gelled system without the nitrogen compound. In a further aspect, the method is used to treat a well penetrating a subterranean formation, for example, in a coiled tubing cleanout, or the like.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: February 18, 2014
    Assignee: Schlumberger Technology Corporation
    Inventors: Mathew M. Samuel, Leiming Li, Juliet Edwena Juel
  • Patent number: 8653012
    Abstract: Solid, particulate dicarboxylic acids may be fluid loss control agents and/or viscosifying agents for viscoelastic surfactant (VES) fluids in treatments such as well completion or stimulation in hydrocarbon recovery operations. The fluid loss control agents may include, but not be limited to, dodecanedioic acid, undecanedioic acid, decanedioic acid, azelaic acid, suberic acid, and mixtures thereof having a mesh size of from about 20 mesh to about 400 mesh (about 841 to about 38 microns). A mutual solvent or a blend of at least two alcohols subsequently added to the aqueous viscoelastic surfactant treating fluid will at least partially dissolve the solid, particulate dicarboxylic acid fluid loss control agents, and optionally also “break” or reduce the viscosity of the aqueous viscoelastic surfactant treating fluid.
    Type: Grant
    Filed: April 5, 2012
    Date of Patent: February 18, 2014
    Assignee: Baker Hughes Incorporated
    Inventor: Tianping Huang
  • Publication number: 20140041690
    Abstract: Glycine is an organic compound that can be used in the making of a synthetic acid that obviates all the drawbacks of strong acids such as hydrochloric acid. The new compound is made by dissolving glycine in water, in a weight ratio of approximately 1:1 to 1:1.5. The solution is mixed until the glycine is essentially fully dissolved in the water. Once dissolution is complete, hydrogen chloride gas is dissolved in the solution to produce the new compound, which can be referred to as hydrogen glycine.
    Type: Application
    Filed: May 18, 2011
    Publication date: February 13, 2014
    Applicant: GREEN PRODUCTS & TECHNOLOGIES, L.L.C.
    Inventors: John T. MacDonald, II, John Thomas MacDonald, III
  • Publication number: 20140038858
    Abstract: An enhanced oil recovery formulation composition containing a sacrificial agent and a surfactant dispersed in a fluid is provided. The sacrificial agent reduces the amount of surfactant required to enhance oil recovery from a petroleum-bearing formation. The sacrificial agent is selected from the group consisting of a compound comprising a single carboxylic acid, a single carboxylic acid derivative, or a single carboxylate salt, or a compound lacking a carboxylic acid group, a carboxylate group, a sulfonic acid group, or a sulfonate group that is a pheol, a sulphonamide, or a thiol, or a compound having a molecular weight of 1000 or less that comprises one or more hydroxyl groups.
    Type: Application
    Filed: August 1, 2013
    Publication date: February 6, 2014
    Inventors: Jeffrey George SOUTHWICK, Marten Marten BUIJSE, Diederik Willem VAN BATENBURG, Carolus Hendricus Theodorus VAN RIJN
  • Publication number: 20140005080
    Abstract: A method of servicing a wellbore comprising placing a wellbore servicing fluid comprising a modified friction reducer into the wellbore. A modified friction reducer comprising a degradable polymer having functional degradable moieties, a polymer having a molecular weight of from about 5M to about 30M, a polymer having a PDI of from about 1.0 to about 2.5, a weakly crosslinked polymer, or combinations thereof.
    Type: Application
    Filed: June 29, 2012
    Publication date: January 2, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: James William OGLE, Xiangnan YE, Pinmanee BOONTHEUNG, Rajesh Kumar SAINI, Narongsak TONMUKAYAKUL
  • Patent number: 8618027
    Abstract: A corrosion inhibitor composition and method of inhibiting corrosion on a surface in an oil or gas application is disclosed and claimed. The corrosion inhibitor includes at least one fatty acid; at least one alkanolamine; at least one alkylamine; and at least one organic sulfonic acid. The method of inhibiting corrosion includes on a surface in an oil or gas application comprises contacting an effective dosage of the corrosion inhibitor with the surface.
    Type: Grant
    Filed: December 8, 2010
    Date of Patent: December 31, 2013
    Assignee: Nalco Company
    Inventors: G. Richard Meyer, Keith Allen Monk
  • Patent number: 8618025
    Abstract: Disclosed and claimed is a composition and method of inhibiting the formation of hydrate agglomerates in a fluid comprising water, gas, and optionally liquid hydrocarbon comprising adding to the fluid an effective anti-agglomerant amount of the following formula and optionally salts thereof: wherein each R1 is independently absent, C1-C10 alkyl, benzyl, or H; wherein R2 is C1-C10 alkyl; wherein R3 C1-C10 alkyl; and wherein R4 is C4-C22 alkyl or alkenyl.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: December 31, 2013
    Assignee: Nalco Company
    Inventor: Peter A. Webber
  • Patent number: 8614170
    Abstract: A method of treating a medium for water fracturing is disclosed, the method comprises: introducing at least one biocide and at least one metabolic inhibitor in the medium, using the medium for water fracturing. In another aspect a method of controlling the post-fracture reservoir souring by the metabolic activities of sulfate reducing bacteria of a well is described: at least one biocide and at least one metabolic inhibitor are introduced in a medium made of water, the medium is used for fracturing the well, and the medium remains in the reservoir to kill and/or inhibit growth of sulfate reducing bacteria.
    Type: Grant
    Filed: December 21, 2009
    Date of Patent: December 24, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Syed Ali, Shawn McCleskey Rimassa, Francois M. Auzerais, Curtis L. Boney, Leiming Li
  • Publication number: 20130327524
    Abstract: The present invention relates to a method for oil recovery from a reservoir which comprises the following phases: a) injecting a volume of a micro (nano)-structured fluid with released control of barrier substances into at least a portion of an underground reservoir containing oil, said micro (nano)-structured fluid comprising an aqueous dispersion of microcapsules composed of a core comprising a modifying substance of the absolute permeability of the rock formation which houses said reservoir, a protective shell insoluble in water which coats said core; b) clogging the porous intergranular spaces of said rock formation with said modifying substance with a reduction or inhibition of the absolute permeability of said rock formation, c) recovering said oil from the remaining portion of said reservoir by the further injection of a displacing fluid, preferably water.
    Type: Application
    Filed: December 27, 2011
    Publication date: December 12, 2013
    Applicant: ENI S.p.A.
    Inventors: Marco Sangermano, Francesca Verga, Laura Montanaro
  • Publication number: 20130323818
    Abstract: A novel thermophilic bacterium is provided, which has a 16S rDNA sequence as set forth in SEQ ID NO. 1. The thermophilic bacterium excretes extracellular proteins having excellent metal-ion binding ability, being useful in the treatment of boiler equipment, pipelines, geothermal wells or industrial wastewater or hard water.
    Type: Application
    Filed: March 18, 2013
    Publication date: December 5, 2013
    Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Yin-Lung HAN, Tai-Rong GUO, Jo-Shu CHANG, I-Ju CHOU
  • Publication number: 20130306321
    Abstract: The present invention is a cryogenic subterranean fracturing fluid, comprising a liquefied industrial gas and a first additive. The liquefied industrial gas may be liquefied carbon dioxide, liquefied nitrogen, or a blend of the two. The liquefied industrial gas mixture should be substantially free of water. In this context, substantially free of water means less than 10% water by volume, or preferably less than 5% water by volume. In addition to the first additive, a proppant may be added to the fracturing fluid. In addition to the biocide and/or proppant additional additives may be added to the liquefied industrial gas as required. Non-limiting examples of such additives include ozone, a friction reducer, an acid, a gelling agent, a breaker, a scale inhibitor, a clay stabilizer, a corrosion inhibitor, an iron controller, an oxygen scavenger, a surfactant, a cross-linker, a non-emulsifier, a Ph Adjusting agent, or any combination thereof.
    Type: Application
    Filed: May 17, 2012
    Publication date: November 21, 2013
    Inventors: Camille LANCTOT-DOWNS, Michel EPINEY, Fabrice LABERGE, Vasuhi RASANAYAGAM, Meenakshi SUNDARAM
  • Patent number: 8586510
    Abstract: A method comprising: providing at least one encaged treatment chemical that comprises a treatment chemical and a polymer carrier; placing the encaged treatment chemical into a portion of a subterranean formation; and allowing the treatment chemical to diffuse out of the encaged treatment chemical and into a portion of the subterranean formation or an area adjacent thereto.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: November 19, 2013
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Michael A. McCabe, Jim D. Weaver, Robert E. Hanes, Billy F. Slabaugh
  • Patent number: 8580047
    Abstract: A composition including HCl, urea, complex substituted keto-amine-hydrochloride, an alcohol, an ethoxylate, and a ketone is provided for performing hydraulic fracturing or oil or gas wells, solubilizing calcium carbonate, or lowering salt and bicarbonate levels in irrigation systems.
    Type: Grant
    Filed: April 4, 2013
    Date of Patent: November 12, 2013
    Assignee: Green Products & Technologies, LLC
    Inventor: John T. MacDonald
  • Publication number: 20130296200
    Abstract: The present invention relates to the application of geminals zwitterionics liquids based on bis-N-alkyl or bis-N-alkenyl or N-cycloalkyl or N-aryl bis-beta aminoacids or its salts thereof as wettability modifiers of rocks such as limestone, dolomite, sand, quartz or heterogeneous lithologies, in the presence of brines with high content of divalent ions such as calcium, magnesium, barium and strontium, high temperature and pressure in processes of enhanced oil recovery. Wettability modifier comprises a geminal zwitterionic liquid based on bis-N-alkyl or bis-N-alkenyl or N-cycloalkyl or N-aryl bis-beta aminoacids or its salts, using as solvent distilled or brine with a high content of divalent ions such as calcium and magnesium or organic solvents compounds derived from alcohols like methanol, ethanol, isopropanol or mixtures thereof, or aromatic as isomers of xylene, toluene, or diesel, gasoline or mixtures thereof.
    Type: Application
    Filed: November 9, 2011
    Publication date: November 7, 2013
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Raùl Hernández Altamirano, Luis Silvestre Zamudio Rivera, Violeta Yasmín Mena Cervantes, Hiram Isaac Beltrán Conde, Cecilia de los Ángeles Durán Valencia, Simón López Ramírez, Eduardo Buenrostro González, José Luis Mendoza De La Cruz, Jorge Alberto García Martínez, Erick Emanuel Luna Rojero, David Aarón Nieto Álvarez
  • Patent number: 8575073
    Abstract: A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore is carried out by forming treatment fluid comprising water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. The treatment fluid is introduced into the formation through the wellbore at a pressure above the fracture pressure of the formation.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: November 5, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Syed Ali, Leiming Li, Lijun Lin, Paul R. Howard, Curtis L. Boney, Carlos Abad
  • Publication number: 20130281330
    Abstract: A composition and method are disclosed. The composition includes a carrier fluid and a solids mixture combined to form a slurry, wherein the solids mixture comprises a plurality of volume-averaged particle size distribution (PSD) modes, wherein a first PSD mode comprises solids having a volume-average median size at least three times larger than the volume-average median size of a second PSD mode such that a packed volume fraction of the solids mixture exceeds 0.75, and wherein the solids mixture comprises a degradable material and includes a reactive solid. The method includes circulating the slurry through a wellbore to form a pack in a fracture and/or a screen-wellbore annulus; degrading the degradable material to increase porosity and permeability of the pack; and producing a reservoir fluid through the permeable pack.
    Type: Application
    Filed: June 24, 2013
    Publication date: October 24, 2013
    Inventors: Mohan K.R. Panga, Peter J. Photos, Bruno Drochon, John W. Still, Balkrishna Gadiyar
  • Publication number: 20130274153
    Abstract: The present invention relates to proppants and the manufacture of proppants by contacting a substrate with an alkali-activated composition that cures to form a continuous polymer coating.
    Type: Application
    Filed: October 28, 2011
    Publication date: October 17, 2013
    Applicant: GEOPROPPANTS INC.
    Inventor: Thomas Urbanek
  • Publication number: 20130274152
    Abstract: A stable polysaccharide particle suspension composition comprising: a carrier; an activator solvent comprising a) at least one dibasic methyl or ethyl ester; b) at least one compound of the formula R3OOC-A-CONR4R5 (IIa), wherein R3 represents a C1-C36 alkyl group; wherein R4 and R5 individually represents a C1-C36 alkyl group, wherein R4 and R5 can optionally together form a ring; and wherein A is a linear or branched divalent C2-C6 alkyl group; or c) a combination a) and b); an organo clay compound; and optionally, a surfactant; the composition being stable and capable of suspending polysaccharide particles. Slurries of polysaccharide particles in such suspension composition and methods of making the compositions and the slurries.
    Type: Application
    Filed: April 17, 2013
    Publication date: October 17, 2013
    Applicant: RHODIA OPERATIONS
    Inventors: Amit SEHGAL, Subramanian Kesavan, Ruela Pabalan, Charles Aymes
  • Publication number: 20130264055
    Abstract: A method of fracturing a subterranean formation comprising at least in part shale formation, comprises providing a carrier fluid; providing a particulate blend including a first amount of particulates having a first average particle size between about 100 and 2000 microns and a second amount of particulates having a second average particle size between about three and twenty times smaller than the first average particle size, such that a packed volume fraction of the particulate blend exceeds 0.75; combining the carrier fluid and the particulate blend into a fracturing slurry; fracturing the formation with the fracturing slurry to create at least a fracture; and removing the second amount of particulates from the fracture.
    Type: Application
    Filed: June 6, 2013
    Publication date: October 10, 2013
    Inventors: Ryan Hartman, Mohan K.R. Panga, Bruno Drochon, John W. Still
  • Patent number: 8550161
    Abstract: A well treatment composition is formed from a fluid mixture of a viscoelastic surfactant and a liquid carrier fluid. The fluid mixture has rheological properties wherein the mixture exhibits shear-thickening behavior when the shear rate is increased from a first shear rate to a second higher shear rate. The fluid mixture may further include a shear activation additive that interacts with the viscoelastic surfactant to facilitate the shear-thickening behavior. The method is accomplished by introducing the fluid mixture into a wellbore formed in a subterranean formation. In certain applications, the fluid mixture may be recycled by bringing the fluid mixture to the surface and reintroducing the fluid into the same or a different wellbore.
    Type: Grant
    Filed: August 14, 2012
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Yiyan Chen, Oscar Bustos, Philip F. Sullivan