The Sulfur Is Part Of A Sulfonate Group Patents (Class 507/259)
  • Patent number: 10988709
    Abstract: Surfactants of general formula (I), in which R1 denotes a linear or branched alkyl residue having 6 to 20, and in particular 8 to 14 carbon atoms, R2 denotes H or CH3, and M denotes hydrogen, an alkali metal or an N+R3R4R5 grouping, in which R3, R4 and R5, independently of one another, denote hydrogen, an alkyl group having 1 to 6 carbon atoms or a hydroxyalkyl group having 2 to 6 carbon atom, can be easily incorporated into washing or cleaning agents, have outstanding application-related properties, and can be produced based on renewable resources.
    Type: Grant
    Filed: February 2, 2018
    Date of Patent: April 27, 2021
    Assignees: Henkel AG & Co. KGaA, Studiengesellschaft Kohle mbH
    Inventors: Christian Kropf, Alexander Schulz, Hendrik Hellmuth, Roberto Rinaldi, Hebert Jesus Estevez Rivera
  • Patent number: 10800962
    Abstract: Compositions suitable for enhanced oil recovery comprising a) a mixture of a-sulfocarbonyl compounds of formula (1) and (2) in a mixture ratio (1) to (2) of from 1:99 to 99:1 wherein R1, R3 and R5, which may be the same or different at each occurrence, are hydrogen or a linear or branched alkyl chain having 1 to 20 carbon atoms, R2 and R4, which may be the same or different at each occurrence, may be a linear or branched alkyl group having 4 to 24 carbon atoms and in which the alkyl chain may comprise one or more cycloaliphatic groups, and X is H or a metal forming a salt with the sulfonate group, and b) a salt containing aqueous solution.
    Type: Grant
    Filed: May 4, 2016
    Date of Patent: October 13, 2020
    Assignee: RHODIA OPERATIONS
    Inventors: Olivier Back, Remy Leroy, Mikel Morvan, Patrick Moreau, Philippe Marion
  • Patent number: 9815779
    Abstract: The present invention provides a method for producing a high-quality internal olefin sulfonate in which the content of any internal olefin and inorganic substance is small. This method for producing an internal olefin sulfonate, comprising: a sulfonating step of causing an internal olefin to react with sulfur trioxide to yield a sulfonated internal olefin; a neutralizing step of mixing the resultant sulfonated internal olefin with an aqueous alkaline solution at 40° C. or lower to yield a mixture, and applying shearing force to the mixture until the particle diameter of oil droplets of an oily product of the mixture turns to 10 ?m or less to yield a neutralized product; and a hydrolyzing step of hydrolyzing the resultant neutralized product.
    Type: Grant
    Filed: November 27, 2014
    Date of Patent: November 14, 2017
    Assignee: KAO CORPORATION
    Inventors: Hiroshi Hori, Yohei Yoshikawa, Yoshinori Mitsuda, Toku Fujioka, Yoshifumi Nishimoto
  • Patent number: 9587168
    Abstract: An alkylaromatic sulfonate is disclosed wherein the alkyl group contains a distribution of alkyl chain lengths which comprise greater than 15 weight percent and up to about 35 weight percent of C30 to C58. Also disclosed is a process for preparing an alkylaromatic sulfonate and its use in recovering crude oil from a subterranean hydrocarbon containing formation.
    Type: Grant
    Filed: September 27, 2013
    Date of Patent: March 7, 2017
    Assignee: Chevron Oronite Company LLC
    Inventors: Curt B. Campbell, Andrew Howes, Terri Denslow
  • Patent number: 9150780
    Abstract: The present invention includes processes to create wormholes in carbonate reservoirs by contacting a formation with a solution comprising glutamic acid N,N-diacetic acid (GLDA) and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention also includes processes to remove wellbore damage in a carbonate reservoir by contacting a damaged zone of the carbonate reservoir with a solution comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof. The present invention further includes solutions comprising a salt and further comprising GLDA and/or a salt thereof, methylglycine-N,N-diacetic acid (MGDA) and/or a salt thereof, or a combination thereof.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: October 6, 2015
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelia Adriana de Wolf, Hisham Nasr-El-Din, James N. LePage, Mohamed Ahmed Nasr-El-Din Mahmoud, Johanna Hendrika Bemelaar
  • Publication number: 20150129228
    Abstract: The present disclosure provides a surfactant formulation for use in treating and recovering fossil fluid from a subterranean formation. The surfactant formulation includes a primary surfactant, a formulation stability agent and injection water.
    Type: Application
    Filed: September 12, 2013
    Publication date: May 14, 2015
    Inventors: Luis C. Salazar, David C. Lewis, Guy Biesmans, Srinivasa S. Godavarthy, Farron W. Miller
  • Patent number: 9010423
    Abstract: A method for recovering oil from a fractured reservoir having an oil-wettable matrix and comprising at least one injection well and one production well. This method comprises the following steps in such order: a)injecting by an injection well a solution of viscosity-enhancing surfactants, capable of penetrating into the array of fractures, having limited interaction with the matrix, and creating a plug in situ to reduce the perviousness of the fractures and to promote the passage of the solution of step b) into the matrix; b) injecting by an injection well a solution of surfactants, capable of interacting with the matrix to make water-wettable and to extract the oil therefrom; c) injecting by an injection well an aqueous solution to increasing the surface tension, impregnating the matrix and, after the plug in step a) is dissolved by the oil, driving the oil toward the production well.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: April 21, 2015
    Assignee: Rhodia Operations
    Inventors: Max Chabert, Mikel Morvan
  • Publication number: 20150105301
    Abstract: Provided herein are inter alia novel compositions and methods having application in a variety of fields including the field of enhanced oil recovery, the cleaning industry as well as groundwater remediation. In particular, the alkoxy carboxylate compounds and mixtures thereof presented herein can be used, inter alia, for the recovery of a large range of crude oil compositions from challenging reservoirs.
    Type: Application
    Filed: May 19, 2014
    Publication date: April 16, 2015
    Applicant: Board of Regents, The University of Texas System
    Inventors: Upali P. Weerasooriya, Gary A. Pope
  • Publication number: 20150087561
    Abstract: Nitrate brine compositions reduce hydrate formation in flowlines under conditions conducive for hydrate formation in the absence of the nitrate brines, where the nitrate brines include compatible anti-corrosion system.
    Type: Application
    Filed: December 4, 2014
    Publication date: March 26, 2015
    Inventors: Olusegun Matthew Falana, Michael Morrow, Frank G. Zamora
  • Publication number: 20150060074
    Abstract: An operations fluid composition for operations on wells associated with the production of hydrocarbons, the fluid composition comprising: not less than 40 wt % of hydrocarbon fluid, based upon the total weight of the fluid composition; water; and from 0.1 to 10 wt % of a surfactant selected from alkyl acid surfactant, based upon the total weight of water in the fluid composition. Method for using the same are also disclosed.
    Type: Application
    Filed: July 14, 2014
    Publication date: March 5, 2015
    Inventors: Ramesh Varadaraj, Copper E. Haith, Barbara Carstensen, Cornelius H. Brons
  • Patent number: 8962536
    Abstract: The instant invention pertains to a composition which may be useful for enhancing oil recovery. The composition typically comprises the reaction mixture of at least (a) two or more compounds capable of generating at least about 20 kcal to about 150 kcal per mole when contacted; (b) one or more suitable surfactants or one or more suitable polymers or a mixture thereof; and (c) oil. The invention also pertains to a method for enhancing oil recovery wherein a suitable system is injected through a wellbore into a reservoir to enhance mobility of oil.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: February 24, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Gregory Winslow, Gabriel Prukop, Varadarajan Dwarakanath
  • Patent number: 8950494
    Abstract: A method of foaming a fluid for recovering gas from a gas well and enhancing oil production from a gas-lifted oil well penetrating a subterranean oil-bearing formation is disclosed and claimed. The method includes introducing into the fluid a foam-forming amount of a composition comprising at least one compound selected from the following: X+ alkyl benzene sulfonate; X+ alkylnapthalene sulfonate; alkyldiphenyloxide disulfonate; diallyldiphenyloxide disulfonate; X+ alkyl sulfate; naphthalene sulfonate formaldehyde condensate; and combinations thereof. The method of invention further provides foamers that are compatible with a reverse osmosis membrane.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: February 10, 2015
    Assignee: Nalco Company
    Inventors: Duy T. Nguyen, Fenfen Huang
  • Patent number: 8946132
    Abstract: A controlled release composition comprising an aqueous sulfonate solution; an anionic surfactant; and a salt selected from aluminum nitrate nanohydrate, calcium chloride dehydrate, magnesium chloride hexahydrate, cobalt chloride hexahydrate, and other metal salts. Methods of delivering a controlled release of surfactants composition, the method comprising the steps of: delivering a solution into a reservoir, the solution comprising an aqueous sulfonate solution; an anionic surfactant; and a salt selected from aluminum nitrate nanohydrate, calcium chloride dehydrate, magnesium chloride hexahydrate, cobalt chloride hexahydrate, and other metal salts; and delivering water to the reservoir.
    Type: Grant
    Filed: July 18, 2011
    Date of Patent: February 3, 2015
    Assignee: Saudi Arabian Oil Company
    Inventors: Yun Chea Chang, Mazen Kanj
  • Patent number: 8940668
    Abstract: A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: January 27, 2015
    Assignee: Shell Oil Company
    Inventors: Julian Richard Barnes, Kirk Herbert Raney, Thomas Carl Semple, Johan Paul Smit, Jasper Roelf Smit, Malcolm Shpakoff
  • Publication number: 20150011441
    Abstract: A mutual solvent for use in oil and gas well operations comprising an ethoxylated alcohol surfactant, having a six carbon backbone chained to three ethylene oxide groups with a hydrophilic lipophilic balance between 11 and 12 but more preferably of about 11.3. Such a mutual solvent may be used in an oil and gas well as a spacer system, in acid treatments to remove the spent acid, and in solvent systems to remove asphaltenic or paraffinic compounds.
    Type: Application
    Filed: July 3, 2013
    Publication date: January 8, 2015
    Inventors: Sarkis R. Kakadjian, Stephen Huber, Violeta Ramos, Frank Zamora
  • Publication number: 20140367096
    Abstract: The invention relates to a hydrocarbon recovery composition comprising an anionic surfactant, wherein said composition is in the solid state, and to a shaped article comprising said composition. Preferably, said composition is in the form of a powder. Further, the invention relates to a process for treating a hydrocarbon containing formation comprising the steps of a) transporting said composition or shaped article to the location of the hydrocarbon containing formation; b) dissolving said composition or shaped article in water thereby forming an aqueous fluid containing the hydrocarbon recovery composition; c) providing the aqueous fluid containing the hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation; and d) allowing the hydrocarbon recovery composition to interact with the hydrocarbons in the hydrocarbon containing formation.
    Type: Application
    Filed: May 25, 2012
    Publication date: December 18, 2014
    Inventors: Julian Richard Barnes, Hendrik Dirkzwager, Robert Moene, Reinaldo Conrado Navarrete, Kirk Herbert Raney
  • Publication number: 20140364347
    Abstract: The present invention describes the synthesis and use of cleavable di-functional anionic surfactants for enhanced oil recovery applications and/or the use of sacrificial surfactants.
    Type: Application
    Filed: June 7, 2013
    Publication date: December 11, 2014
    Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM
    Inventors: GARY A. POPE, UPALI P. WEERASOORIYA, QUOC P. NGUYEN, LARRY N. BRITTON
  • Publication number: 20140352962
    Abstract: Ampholyte polymeric compounds that comprise at least one nonionic monomer, at least one sulfonic acid-containing monomer, and at least one cationic monomer may be useful as friction reducing agents in treatment fluids for use in subterranean operations at a concentration of about 0.001 v/v % to about 0.5 v/v % of the treatment fluid. Such operations may involve introducing the treatment fluid into a wellbore penetrating a subterranean formation optionally at a rate and/or a pressure sufficient to create or extend at least one fracture in the subterranean formation.
    Type: Application
    Filed: June 28, 2013
    Publication date: December 4, 2014
    Inventors: HsinChen Chung, Yuntao Thomas Hu, Xiangnan Ye, Narongsak Tonmukayakul, Michael A. McCabe, Kevin Walter Frederick, Shih-Ruey Tom Chen, Randy Jack Loeffler
  • Patent number: 8895484
    Abstract: Biphenylmono- and polysulphonic acids and salts thereof, fluorenemono- and polysulphonic acids and salts thereof as well as p-terphenylmono- and polysulphonic acids and salts thereof may be used successfully as tracers for surveying, monitoring and/or measuring movements of aqueous fluids in aqueous and/or non-aqueous media. Said substances are especially suited for surveying or monitoring movements of fluids in oil wells or reservoirs as well as for fluid movements in hydrothermal reservoirs.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: November 25, 2014
    Assignee: Restrack AS
    Inventor: Helge Stray
  • Publication number: 20140342950
    Abstract: Methods of treating a subterranean formation including providing a treatment fluid comprising an oil-based fluid component and an oil-soluble weighting agent that comprises a metal, wherein the oil-soluble weighting agent has a density in the range of from about 1.1 g/cm3 to about 22 g/cm3; solubilizing the oil-soluble weighting agent in the oil-based fluid component of the treatment fluid, wherein the oil-soluble weighting agent increases the density of the oil-based fluid component of the treatment fluid; introducing the oil-based treatment fluid into a wellbore in a subterranean formation.
    Type: Application
    Filed: May 20, 2013
    Publication date: November 20, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Cato Russell McDaniel, Dale E. Jamison
  • Patent number: 8889600
    Abstract: A process for recovering oil from an oil-bearing formation comprises introducing into said formation an aqueous composition comprising at least one sulfonated derivative of one or more internal olefins, said internal olefins being characterized by having low amounts of tri-substitution on the olefin bond, said sulfonated derivative being obtained by sulfonating a composition comprising internal olefins of the formula: R1R2C?CR3R4 wherein R1, R2, R3 and R4 are the same or different and are hydrogen or straight- or branched-chain, saturated hydrocarbyl groups and the total number of carbon atoms of R1, R2, R3 and R4 is 6 to 44 with the proviso that at least about 96 mole percent of R1 and R3 are straight- or branched-chain, saturated hydrocarbyl groups and at least about 96 mole percent of R2 and R4 are hydrogen. Further provided are compositions for use in recovering oil from an oil bearing formation.
    Type: Grant
    Filed: May 20, 2011
    Date of Patent: November 18, 2014
    Assignee: Stepan Company
    Inventors: John C. Hutchison, Patrick Shane Wolfe
  • Patent number: 8877693
    Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: November 4, 2014
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Patent number: 8871695
    Abstract: Nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both (Winsor III) or single phase microemulsions (Winsor IV) may be formed in situ during hydrocarbon recovery operations after drilling with OBM or SBM using one or more fluid pills. The nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both or single phase microemulsions remove oil and solids from the well and wellbore surfaces. In one non-limiting embodiment, a single phase microemulsion (SPME) or other in situ-formed fluid may be created from a polar phase, a nonpolar phase, at least one viscosifier, and at least one surfactant.
    Type: Grant
    Filed: April 22, 2008
    Date of Patent: October 28, 2014
    Assignee: Baker Hughes Incorporated
    Inventors: Lirio Quintero, Chad F. Christian, Alexander McKellar, Cristina Torres, David E. Clark, Thomas A. Jones
  • Publication number: 20140305649
    Abstract: Methods of stimulating a well comprising providing a stimulation fluid comprising at least one surfactant and submicron particles, the submicron particles having a particle size between about 200 nm and about 800 nm and a specific surface area greater than about 5 square meters per gram; and introducing the stimulation fluid into a wellbore. Additional methods to enhance oil recovery from subterranean reservoirs accessible via a well are described.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 16, 2014
    Inventors: Hongxin Tang, Zayne Hai Lu
  • Patent number: 8853136
    Abstract: A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one alkylpolyalkoxysulfate comprising propoxy groups, and at least one further surfactant differing therefrom is used, is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells. The alkylpolyalkoxysulfate comprising propoxy groups is prepared in this case by sulfating an alkoxylated alcohol, the alkoxylated alcohol being prepared by alkoxylating an alcohol using double metal cyanide catalysts or double hydroxide clays.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: October 7, 2014
    Assignee: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
  • Publication number: 20140290953
    Abstract: A hydrocarbon recovery composition comprising vinylidene olefin sulfonates is described. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
    Type: Application
    Filed: December 9, 2011
    Publication date: October 2, 2014
    Inventors: Julian Richard Barnes, Robert Hardy Ellison, Maura Puerto, Kirk Herbert Raney, Johan Paul Smit
  • Publication number: 20140262286
    Abstract: Aspects of the invention relate to compositions and methods that are used for remediation of near-wellbore damage. A specific aspect is a composition comprising an olefin sulfonate, a sulfosuccinate, and a chemical selected from the group consisting of an alcohol alkoxylated sulfate, an alcohol alkoxylated carboxylate, or a combination thereof.
    Type: Application
    Filed: March 13, 2014
    Publication date: September 18, 2014
    Applicant: Chevron U.S.A. Inc.
    Inventors: Varadarajan Dwarakanath, Robert Matthew Dean, Will S. Slaughter, Dustin Luke Walker, Sophany Thach
  • Patent number: 8822391
    Abstract: Provided herein are inter alia novel compositions and methods having application in a variety of fields including the field of enhanced oil recovery, the cleaning industry as well as groundwater remediation. In particular, the alkoxy carboxylate compounds and mixtures thereof presented herein can be used, inter alia, for the recovery of a large range of crude oil compositions from challenging reservoirs.
    Type: Grant
    Filed: August 29, 2011
    Date of Patent: September 2, 2014
    Assignee: Board of Regents, The University of Texas System
    Inventors: Upali P. Weerasooriya, Gary A. Pope
  • Publication number: 20140224490
    Abstract: The invention relates to a method of treating a hydrocarbon containing formation, comprising: (a) providing a composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises water and an anionic surfactant which is an internal olefin sulfonate (IOS), which has a weight ratio of branched IOS molecules to linear IOS molecules N which is greater than 0 to smaller than 11:89; and (b) allowing the composition to interact with the hydrocarbons in the hydrocarbon containing formation. Further, the invention relates to a hydrocarbon recovery composition which comprises the composition used in said method, and to a hydrocarbon containing composition produced from a hydrocarbon containing formation which in addition to hydrocarbons contains the composition used in said method.
    Type: Application
    Filed: August 27, 2012
    Publication date: August 14, 2014
    Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    Inventors: Julian Richard Barnes, Michael Joseph Doll, Khrystyna Groen, Quoc An On, Thomas Carl Semple
  • Patent number: 8785355
    Abstract: The present invention provides aqueous viscoelastic compositions comprising a cleavable anionic surfactant which is a sulphonate and possibly also an electrolyte. The cleavable surfactants useful in the present invention comprise a chemical bond, which is capable of being broken under appropriate conditions, to produce oil soluble and water soluble products typically having no interfacial properties and surface activity compared with the original surfactant molecule. Further, the rheological properties of the aqueous viscoelastic composition are usually altered upon cleavage of the cleavable surfactant generally resulting in the elimination of the viscosifying, viscoelastic and surfactant properties of the composition. Aqueous viscoelastic compositions in accordance with the present invention are suitable for use in oil-field applications, particularly for hydraulic fracturing of subterranean formations.
    Type: Grant
    Filed: May 15, 2009
    Date of Patent: July 22, 2014
    Assignee: Schlumberger Technology Corporation
    Inventors: Robert Seth Hartshorne, Trevor Lloyd Hughes, Timothy Gareth John Jones, Gary John Tustin, Jian Zhou
  • Publication number: 20140194327
    Abstract: By including a chemical additive in the well treatment fluid system design the cost and environmental impact of hydraulic fracturing may be substantially reduced. By adding a weak base to the well treatment fluid, water having a high, heterogeneous concentration of dissolved solids, such as water produced by oil and gas wells, may be utilized as the base fluid for hydraulic fracturing or other stimulation processes without adversely affecting the various components of the well treatment fluid. The well treatment fluid typically includes a base fluid, in this case produced water, a gelling agent, a weak base, and other additives useful for treating a well such as friction reducers, buffering agents, clay control agents, biocides, scale inhibitors, chelating agents, gel-breakers, oxygen scavengers, antifoamers, crosslinkers, wax inhibitors, corrosion inhibitors, de-emulsifiers, foaming agents, or tracers.
    Type: Application
    Filed: January 4, 2013
    Publication date: July 10, 2014
    Inventors: Nathan R. Hutchings, Sarkis R. Kakadjian, Mark H. Olive, William J. Childs, Amanda Rodriguez, Joseph Earl Thompson
  • Patent number: 8772204
    Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The Method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: July 8, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lewis R. Norman, Rajesh K. Saini
  • Patent number: 8759261
    Abstract: The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: June 24, 2014
    Assignee: Shell Oil Company
    Inventors: Julian Richard Barnes, Kirk Herbert Raney, Thomas Carl Semple, Paul Gregory Shpakoff, Johan Paul Smit, Jasper Roelf Smit
  • Publication number: 20140116690
    Abstract: The present invention relates to a surfactant mixture comprising at least one secondary alkanesulfonate having 14 to 17 carbon atoms of the general formula (I) and at least one anionic surfactant of the general formula (II) where R1, R2, R3, R4, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and production thereof, and to aqueous surfactant formulations comprising the surfactant mixture, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected through injection wells into a mineral oil deposit and crude oil is withdrawn through production wells from the deposit.
    Type: Application
    Filed: October 25, 2013
    Publication date: May 1, 2014
    Applicant: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez-Juergenson, Sophie Maitro-Vogel
  • Publication number: 20140107000
    Abstract: The present invention relates to functional fluid compositions containing antioxidants, and specifically stable compositions containing antioxidants with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and antioxidants containing a phenolic or benzoic group, where the antioxidant is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.
    Type: Application
    Filed: May 15, 2012
    Publication date: April 17, 2014
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Danielle N. Ivancic, James D. Burrington, Ewan E. Delbridge
  • Publication number: 20140096967
    Abstract: The present invention includes compositions and methods for using an anionic surfactant composition for treating a hydrocarbon-bearing formation or a reservoir, of formula (I): wherein R1 and R2 are identical or different and may independently be alkyl, alkenyl, alkynyl, alkylene, aryl, propylene oxide, ethylene oxide or hydrogen groups in a straight or branched chain with 16 or more carbon atoms, X1 and X2 are identical or different and are selected from the group consisting of phosphate, sulfate, carboxylate, sulfonate or other suitable anionic groups, S is a spacer group selected from short or long arkyl, alkenyl, alkynyl, alkylene, stilbene, polyethers, and other suitable aliphatic or aromatic groups comprising 2 to 12 carbon atoms.
    Type: Application
    Filed: August 9, 2013
    Publication date: April 10, 2014
    Applicant: Board of Regents, The University of Texas System
    Inventors: Mukul M. Sharma, Bo Gao
  • Publication number: 20140090838
    Abstract: An alkylaromatic sulfonate is disclosed wherein the alkyl group contains a distribution of alkyl chain lengths which comprise greater than 15 weight percent and up to about 35 weight percent of C30 to C58. Also disclosed is a process for preparing an alkylaromatic sulfonate and its use in recovering crude oil from a subterranean hydrocarbon containing formation.
    Type: Application
    Filed: September 27, 2013
    Publication date: April 3, 2014
    Applicant: CHEVRON U.S.A. INC.
    Inventors: Curt B. Campbell, Andrew Howes, Terri Denslow
  • Publication number: 20140083705
    Abstract: A microemulsion is formulated with a surfactant, a co-surfactant and brine, for recovery of heavy and extra-heavy crude oils by reducing the viscosity of such crude oils and improving their rheological properties for production and pipeline transportation.
    Type: Application
    Filed: September 19, 2013
    Publication date: March 27, 2014
    Inventors: Persi SCHACHT HERNANDEZ, Felipe de Jesus ORTEGA GARCIA, Jose Manuel DOMINGUEZ ESQUIVEL, Elizabeth MAR JUAREZ, Jesus Ricardo RAMIREZ LOPEZ
  • Patent number: 8669212
    Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: March 11, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lewis R. Norman, Rajesh K. Saini
  • Patent number: 8669214
    Abstract: The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: March 11, 2014
    Assignees: ConocoPhillips Company, University of Kansas
    Inventors: Ahmad Moradi-Araghi, James H. Hedges, David R. Zornes, Riley B. Needham, Huili Guan, Jenn-Tai Liang, Cory Berkland, James P. Johnson, Min Cheng, Faye L. Scully
  • Publication number: 20140041875
    Abstract: A surfactant composition includes an alkaryl sulphonate compound (a) and an alkaryl sulphonate compound (b). The difference between the optimum salinity of compound (a) and the optimum salinity of compound (b) is greater than or equal to 3 g/L. The surfactant composition can easily be adapted to various operating conditions, and in particular to various conditions of salinity, in order to provide optimum enhanced oil recovery.
    Type: Application
    Filed: April 13, 2012
    Publication date: February 13, 2014
    Applicant: TOTAL S.A.
    Inventors: Maurice Bourrel, Manuel Chamerois, Nicolas Agenet
  • Publication number: 20140038858
    Abstract: An enhanced oil recovery formulation composition containing a sacrificial agent and a surfactant dispersed in a fluid is provided. The sacrificial agent reduces the amount of surfactant required to enhance oil recovery from a petroleum-bearing formation. The sacrificial agent is selected from the group consisting of a compound comprising a single carboxylic acid, a single carboxylic acid derivative, or a single carboxylate salt, or a compound lacking a carboxylic acid group, a carboxylate group, a sulfonic acid group, or a sulfonate group that is a pheol, a sulphonamide, or a thiol, or a compound having a molecular weight of 1000 or less that comprises one or more hydroxyl groups.
    Type: Application
    Filed: August 1, 2013
    Publication date: February 6, 2014
    Inventors: Jeffrey George SOUTHWICK, Marten Marten BUIJSE, Diederik Willem VAN BATENBURG, Carolus Hendricus Theodorus VAN RIJN
  • Patent number: 8584751
    Abstract: A process for mineral oil production especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 11 to 40 ethoxy units and a hydrophobic radical having 8 to 32 carbon atoms and at least one further surfactant differing therefrom is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
  • Patent number: 8584750
    Abstract: A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 8 to 30 ethoxy units, which has a polydispersity of from 1.01 to 1.12, and at least one further surfactant is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Christian Bittner, Oetter Günter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
  • Publication number: 20130296201
    Abstract: An injectable fluid for treating a hydrocarbon containing formation is described. The injectable fluid includes ((i) when the salinity of the brine is from about 2 wt % to about 4 wt %, a composition that comprises a blend of a C20-24 internal olefin sulfonate and a C24-28 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C24-28 internal olefin sulfonate is from about 90:10 to about 70:30 and (ii) when the salinity of the brine is greater than about 4 wt % up to about 13 wt %, a composition comprises a blend of a C20-24 internal olefin sulfonate and a C15-18 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C15-18 internal olefin sulfonate is from about 90:10 to about 70:30.
    Type: Application
    Filed: July 9, 2013
    Publication date: November 7, 2013
    Inventors: Julian Richard BARNES, Kirk Herbert RANEY, Thomas Carl SEMPLE, Paul Gregory SHIPAKOFF, Johan Paul SMIT
  • Publication number: 20130281330
    Abstract: A composition and method are disclosed. The composition includes a carrier fluid and a solids mixture combined to form a slurry, wherein the solids mixture comprises a plurality of volume-averaged particle size distribution (PSD) modes, wherein a first PSD mode comprises solids having a volume-average median size at least three times larger than the volume-average median size of a second PSD mode such that a packed volume fraction of the solids mixture exceeds 0.75, and wherein the solids mixture comprises a degradable material and includes a reactive solid. The method includes circulating the slurry through a wellbore to form a pack in a fracture and/or a screen-wellbore annulus; degrading the degradable material to increase porosity and permeability of the pack; and producing a reservoir fluid through the permeable pack.
    Type: Application
    Filed: June 24, 2013
    Publication date: October 24, 2013
    Inventors: Mohan K.R. Panga, Peter J. Photos, Bruno Drochon, John W. Still, Balkrishna Gadiyar
  • Patent number: 8550161
    Abstract: A well treatment composition is formed from a fluid mixture of a viscoelastic surfactant and a liquid carrier fluid. The fluid mixture has rheological properties wherein the mixture exhibits shear-thickening behavior when the shear rate is increased from a first shear rate to a second higher shear rate. The fluid mixture may further include a shear activation additive that interacts with the viscoelastic surfactant to facilitate the shear-thickening behavior. The method is accomplished by introducing the fluid mixture into a wellbore formed in a subterranean formation. In certain applications, the fluid mixture may be recycled by bringing the fluid mixture to the surface and reintroducing the fluid into the same or a different wellbore.
    Type: Grant
    Filed: August 14, 2012
    Date of Patent: October 8, 2013
    Assignee: Schlumberger Technology Corporation
    Inventors: Yiyan Chen, Oscar Bustos, Philip F. Sullivan
  • Publication number: 20130261030
    Abstract: A fluid may contain nanoparticles and a base fluid where the base fluid may be a non-aqueous fluid. The base fluid may be, but is not limited to a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid. The fluid may have at least one property, such as but not limited to a dielectric constant ranging from about 5 to about 10,000, an electrical conductivity ranging from about 1×10?6 S/m to about 1 S/m, and combinations thereof. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion, and combinations thereof. The addition of nanoparticles to the base fluid may modify the electrical properties of the fluid.
    Type: Application
    Filed: May 28, 2013
    Publication date: October 3, 2013
    Inventors: Othon Monteiro, Daniel R. Ellis
  • Publication number: 20130252855
    Abstract: Aqueous compositions including a mild alkaline agent (i.e. compound of formula (I) or (V)) and a surfactant are provided. The compositions and methods of using the same are particularly useful in the field of enhanced oil recovery.
    Type: Application
    Filed: March 26, 2013
    Publication date: September 26, 2013
    Inventors: Upali P. Weerasooriya, Gary A. Pope, Mojdeh Delshad
  • Patent number: 8524642
    Abstract: There is a viscoelastic fluid. The fluid has one or more cationic surfactants selected from the group consisting of certain quaternary salts, certain amines, and combinations thereof; one or more anionic polymers/anionic surfactants; one or more of certain zwitterionic/amphoteric surfactants; and water. There is also a method of fracturing a subterranean formation. The viscoelastic fluid is pumped through a wellbore and into a subterranean formation at a pressure sufficient to fracture the formation. There is also a method for gravel packing a subterranean formation.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: September 3, 2013
    Assignee: Rhodia Operations
    Inventors: Fang Li, Manilal Dahanayake, Allwyn Colaco