Organic Component Is A Fat, Fatty Alcohol, Fatty Oil, Ester-type Wax, Fatty Still Residue, Or Higher Fatty Acid Or Salt Thereof Patents (Class 507/265)
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Patent number: 12168310Abstract: Embodiments disclosed herein include dissolvable and intentionally degradable objects that are useful for hydraulic fracking operations. Such objects are at least in part manufactured using materials that are soluble in certain fluids including water. The dissolvable and intentionally degradable fracking objects can be manufactured from one or more materials, including composite materials. In one embodiment, dissolvable fracking objects are manufactured from ceramic materials that are soluble in fluids such as water. Such dissolvable fracking objects include fracking balls and plugs. These fracking balls and plugs are arranged to seal a well for a predetermined period of time and dissolve over that predetermined period of time until the well is no longer sealed. In another embodiment, tools generally useful in fracking operations are manufactured to have desirable elastomeric properties.Type: GrantFiled: January 13, 2023Date of Patent: December 17, 2024Assignee: Victory Elements, LLCInventors: Robert Howard, Ajit Yeshwant Sane
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Patent number: 11898100Abstract: Disclosed herein are methods and composition for breaking foam, emulsions, or any combination thereof.Type: GrantFiled: December 14, 2020Date of Patent: February 13, 2024Assignee: CHEVRON U.S.A. INC.Inventors: Gayani W. Pinnawala, Sujeewa S. Palayangoda, Varadarajan Dwarakanath, Mohamad Salman, Mohsen S. Tagavifar
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Patent number: 11634625Abstract: A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent is preferably a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of terpene solvent based additives useful for the treatment of oil and gas wells. Methods of using the novel well treatment additives include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.Type: GrantFiled: March 13, 2020Date of Patent: April 25, 2023Assignee: Flotek Chemistry, LLCInventors: Glenn S. Penny, Keith Ingram Dismuke, Richard Nelson Fox, Andrei Zelenev, Randal M. Hill
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Patent number: 10246627Abstract: In a method of gravel packing a wellbore in a subterranean formation, the wellbore comprising a cased section and an uncased section, the method may include pumping into the wellbore a gravel pack composition comprising gravel and a carrier fluid comprising an invert emulsion fluid, where the invert emulsion fluid may comprise: an oleaginous external phase; a non-oleaginous internal phase, wherein a ratio of the oleaginous external phase and non-oleaginous internal phase is less than 50:50 and an emulsifier stabilizing the oleaginous external phase and the non-oleaginous internal phase.Type: GrantFiled: March 12, 2015Date of Patent: April 2, 2019Assignee: M-I L.L.C.Inventors: Mark Luyster, Arvind D. Patel, Sooi Kim Lim
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Patent number: 9115304Abstract: A wellbore servicing composition comprising a filter cake positioned within a wellbore, the filter cake comprising an invert emulsion fluid, the invert emulsion fluid comprising an oleaginous fluid, a non-oleaginous fluid, and an acid-sensitive surfactant, and an emulsion reversing fluid positioned within the wellbore in contact with the filter cake, the emulsion reversing fluid comprising an acid precursor, wherein the acid precursor is not an acid.Type: GrantFiled: April 9, 2012Date of Patent: August 25, 2015Assignee: Halliburton Energy Services, Inc.Inventor: Carl Joseph Thaemlitz
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Patent number: 9102863Abstract: According to one aspect of the inventions, emulsion compositions are provided. Emulsions according to this aspect include: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. According to another aspect of the inventions, methods are provided for treating a portion of a subterranean formation.Type: GrantFiled: February 14, 2013Date of Patent: August 11, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Ian D. Robb, Sherry G. Gaskins, Jimmie D. Weaver, Phillip D. Nguyen
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Patent number: 9034807Abstract: A spacer fluid comprises a fluid and a viscosity agent. The viscosity agent is a mixture of at least two polyvinylalcohol compositions. A first polyvinylalcohol composition comprises polyvinylalcohols having a first degree of hydrolysis and a second polyvinylalcohol composition comprises polyvinylalcohols having a second degree of hydrolysis. The first and second degrees of hydrolysis are substantially different such that the rheology of the spacer fluid is stable during temperatures changes.Type: GrantFiled: December 16, 2008Date of Patent: May 19, 2015Assignee: Schlumberger Technology CorporationInventor: Bruno Drochon
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Publication number: 20150057197Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.Type: ApplicationFiled: October 29, 2014Publication date: February 26, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: JAMES B. CREWS, TIANPING HUANG
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Patent number: 8946131Abstract: Curable adhesive compositions comprising a silane coupling agent; a polymer, the polymer having a reactive silicon end group; a catalyst operable to facilitate the curing of the polymer; and, a diluent and wherein the polymer comprises about 0.1% to about 30% by weight of the curable adhesive composition. The curable adhesive compositions may further comprise a dehydrating agent comprising a component selected from the group consisting of: vinyl trimethoxysilane, vinyl alkoxysilane, inorganic zeolites, and organic zeolites.Type: GrantFiled: August 20, 2013Date of Patent: February 3, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Richard D. Rickman, Jimmie D. Weaver, Bhadra Desai
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Patent number: 8940668Abstract: A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.Type: GrantFiled: April 14, 2010Date of Patent: January 27, 2015Assignee: Shell Oil CompanyInventors: Julian Richard Barnes, Kirk Herbert Raney, Thomas Carl Semple, Johan Paul Smit, Jasper Roelf Smit, Malcolm Shpakoff
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Patent number: 8940669Abstract: Of the many compositions and methods provided herein, an example method includes a method of treating a subterranean formation that comprises combining components comprising water and a density-matched suspension to prepare a treatment fluid, wherein the density-matched suspension comprises a suspending liquid and a solid particle suspended in the suspending liquid, and introducing the treatment fluid into a well bore. An example composition includes a suspension that comprises a suspending liquid comprising a hydrophobic liquid, wherein the hydrophobic liquid hydrolyzes when placed in contact with an aqueous fluid to form hydrophilic products, and a solid particle suspended in the suspending liquid, wherein the suspension is a density-matched suspension.Type: GrantFiled: February 8, 2013Date of Patent: January 27, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Sam Lewis, Michael Szymanski, Christopher Gordon
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Patent number: 8936084Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.Type: GrantFiled: April 27, 2012Date of Patent: January 20, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Hongyu Luo, Dwight D. Fulton
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Patent number: 8932999Abstract: A method of cleaning a wellbore prior to the production of oil or gas is disclosed, wherein the wellbore has been drilled with an invert emulsion drilling mud that forms an invert emulsion filter cake. The method may include the steps of circulating a breaker fluid into the wellbore, where the breaker fluid includes an aqueous fluid, and imino diacetic acid or salt thereof. Optionally an acid buffering agent, and a weighting age are also included. The breaker fluid is formulated such that after a predetermined period of time and the filter cake present in the wellbore or on the wellbore face is substantially degraded. Other methods may also include drilling the wellbore with a water-based drilling mud that forms a water-based filter cake, wherein the method may include the steps of circulating a breaker fluid into the wellbore, where the breaker fluid may include an aqueous fluid, and an iminodiacetic acid or a salt thereof.Type: GrantFiled: February 18, 2008Date of Patent: January 13, 2015Assignee: M-I L.L.C.Inventors: Andrew G. K. Jones, Mark Luyster, Raul Navarro
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Patent number: 8927468Abstract: Spray dried emulsifier compositions are described, which have desirable emulsifying and wetting characteristics. Among other advantages, the solid particulate emulsifier compositions greatly reduce transportation costs and simplify the logistics and environmental concerns associated with shipping large volumes of solvent-containing liquids. The emulsifier comprises (1) a carboxylic acid terminated fatty amine condensate or (2) a modified tall oil or (3) a blend of (1) and (2) that is converted to its alkali or alkaline earth metal salt and spray dried.Type: GrantFiled: August 1, 2012Date of Patent: January 6, 2015Assignee: Georgia-Pacific Chemicals LLCInventors: Phillip Wayne Hurd, Gary D. Fultz, Jalandar Y. Jadhav
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Patent number: 8927466Abstract: A pill for wellbore operations, that includes a base fluid; and at least two polymers that interact to form a gelatinous structure characterized as isolating and controllably transmitting hydrostatic pressure between a first wellbore fluid above the pill in a wellbore and a second wellbore fluid below the pill in the wellbore is disclosed.Type: GrantFiled: April 3, 2008Date of Patent: January 6, 2015Assignee: M-I LLCInventors: Ole Iacob Prebensen, Monica Norman, Anne-Marie Friestad, Egil Ronaes
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Patent number: 8921285Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil slurried together in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil having the particulate fluid loss control agents slurried within it may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the slurry is added to the fluid after it has been substantially gelled. The mineral oil/particulate slurry may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.Type: GrantFiled: August 28, 2012Date of Patent: December 30, 2014Assignee: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews
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Publication number: 20140367100Abstract: A treatment fluid for use in a combined acidizing and proppant fracturing treatment, the treatment fluid comprising: (A) an emulsion comprising: (i) a continuous oil phase; (ii) an internal aqueous phase comprising: (a) water; and (b) a source of an acid; and (iii) an emulsifier; and (B) a proppant. A method of fracturing a treatment zone of a well, the method comprising the steps of: (I) forming a treatment fluid according to the invention; and (II) introducing the treatment fluid into the zone at a rate and pressure greater than the fracture gradient of the zone.Type: ApplicationFiled: June 17, 2013Publication date: December 18, 2014Inventors: Humberto Almeida Oliveira, Weiming Li, Narongsak Tonmukayakul
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Publication number: 20140332212Abstract: Compositions of and methods of using a fluid formulation for increasing flow, production, and/or recovery of oil and gas hydrocarbons from a subterranean formation.Type: ApplicationFiled: November 30, 2011Publication date: November 13, 2014Applicant: VERUTEK TECHNOLOGIES, INC.Inventors: Jeffrey T. Ayers, George E. Hoag, Douglas K. Anderson, John B. Collins
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Patent number: 8877693Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of an internal breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, at least one saturated fatty acid and/or at least one unsaturated fatty acid. The internal breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the internal breaker, e.g. mineral oil, is added to the fluid after it has been substantially gelled. An oil-soluble surfactant is present to enhance or accelerate the reduction of viscosity of the gelled aqueous fluid.Type: GrantFiled: April 12, 2010Date of Patent: November 4, 2014Assignee: Baker Hughes IncorporatedInventors: James B. Crews, Tianping Huang
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Patent number: 8871689Abstract: A method of drilling is disclosed and includes pumping a wellbore fluid into a wellbore through an earth formation, wherein the wellbore fluid comprises a base fluid and a surface active agent capable of altering wettability of fines located in the earth formation, and allowing filtration of at least a portion of the wellbore fluid into the earth formation.Type: GrantFiled: November 27, 2008Date of Patent: October 28, 2014Assignees: Schlumberger Norge AS, Statoil ASAInventors: Russell B. Watson, Patrick Viste, Niall Fleming, Kari Ramstad, Anne Mette Mathisen, Nils Kaageson-Loe
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Publication number: 20140299326Abstract: Relatively high viscosity materials and methods for introducing them as discrete bodies or masses into relatively low viscosity fluids, such as brine, give fracturing fluids that help control the diversion and distribution of fluids as they are pumped downhole against a subterranean formation, particularly shale, to fracture it. A wide range of relatively viscous materials may be used, including polymers, crosslinked polymers and/or surfactant gels, for instance gels created with viscoelastic surfactants (VESs). Once the fracturing fluids containing these bodies or masses are within the hydraulic fracture, the processes of paths of least resistance, flow deviation, viscous material flow displacement, total fluid diversion, in situ fluid viscosity generation and distribution of delayed release treatment additives may be deployed.Type: ApplicationFiled: March 26, 2014Publication date: October 9, 2014Applicant: Baker Hughes IncorporatedInventor: James B. Crews
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Patent number: 8846583Abstract: The present disclosure relates to a biodegradable lubricant composition, notably intended to be incorporated as an oil phase with high lubricating power in a drilling fluid or mud. This composition may be in a drilling fluid or as a fluid for fracture of underground formations. These muds or fluids contained in the composition of the present disclosure are particularly suitable for very deep drillings, offshore in deep water and/or sidetracked drillings or with a long shift.Type: GrantFiled: December 14, 2010Date of Patent: September 30, 2014Assignee: Total Marketing ServicesInventors: Bernard Jean-Luc Espagne, Samia Lamrani-Kern, Hél éne Rodeschini
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Patent number: 8822387Abstract: A waxy oil-external emulsion is provided for injection into a selected zone of a subsurface formation. The selected zone is typically a high permeability zone. The emulsion generally comprises oil, added wax, and water. The emulsion may also include an emulsifying agent and a solvent. The emulsion is formulated to be a liquid at a temperature greater than a targeted temperature in the subsurface formation, but a solid at the targeted temperature. The targeted temperature is typically the maximum operating temperature for the formation. A method of formulating the emulsion is also provided. Further, a method of plugging a high permeability zone using the emulsion is disclosed.Type: GrantFiled: February 21, 2012Date of Patent: September 2, 2014Assignee: ExxonMobil Upstream Research CompanyInventors: James R. Bragg, Joseph P. Lederhos, Sergio A. Leonardi, Scott E. Hommema, Amy L. Chen, Shan H. Yang
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Publication number: 20140228259Abstract: According to one aspect of the inventions, emulsion compositions are provided. Emulsions according to this aspect include: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. According to another aspect of the inventions, methods are provided for treating a portion of a subterranean formation.Type: ApplicationFiled: February 14, 2013Publication date: August 14, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Ian D. Robb, Sherry G. Gaskins, Jimmie D. Weaver, Phillip D. Nguyen
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Publication number: 20140228260Abstract: According to one aspect of the inventions, emulsion compositions are provided. Emulsions according to this aspect include: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. According to another aspect of the inventions, methods are provided for treating a portion of a subterranean formation.Type: ApplicationFiled: February 14, 2013Publication date: August 14, 2014Applicant: Halliburton Energy Services, Inc.Inventors: Ian D. Robb, Sherry G. Gaskins, Jimmie D. Weaver, Phillip D. Nguyen
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Publication number: 20140213490Abstract: A method of servicing a wellbore in a subterranean formation comprising placing a wellbore servicing fluid comprising a coupling agent, a hardenable resin and a hardening agent into the wellbore wherein the coupling agent comprises a multihydroxy phenyl, a dihydroxy phenyl, a trihydroxy phenyl, ascorbic acid, a hydroxymethylnaphthol, an oxidation product thereof, a derivative thereof, or combinations thereof. A wellbore servicing fluid comprising a coupling agent, a hardenable resin, a hardening agent and a proppant wherein the coupling agent comprises a multihydroxy phenyl, a dihydroxy phenyl, a trihydroxy phenyl, ascorbic acid, a hydroxymethylphenol, a hydroxymethylnaphthol, an oxidation product thereof, a derivative thereof, or combinations thereof.Type: ApplicationFiled: January 31, 2013Publication date: July 31, 2014Applicant: Halliburton Energy Services, Inc.Inventors: James William OGLE, Philip D. NGUYEN, Feng LIANG
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Patent number: 8778850Abstract: Formulation for a natural product as a replacement for the use of traditional acidic chemical stimulation methods for the emulsification, removal and release of paraffin and asphaltenes from low producing or pumped off wells and reservoirs with the use of traditional methodologies. Also a method of use of formulation for stimulating an oil well consisting of introducing into the wellbore a biodegradable, non-reactive fluid system containing a water-miscible fatty acid solvent, a solution of fatty acids, an amino alcohol, and at least one non-ionic surfactant. The fluid system may be further in the form of a nanoemulsion that is formed by combining a colloidal solution with one or more emulsifiers, an alcohol, and water. The fluid system may be used in well remediation and stimulation as well as additional, alternative applications such as the cleaning of surface and/or downhole equipment.Type: GrantFiled: October 24, 2013Date of Patent: July 15, 2014Assignee: Green Earth Technologies, Inc.Inventor: Paul Andrecola
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Patent number: 8772204Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The Method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.Type: GrantFiled: March 9, 2012Date of Patent: July 8, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Lewis R. Norman, Rajesh K. Saini
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Patent number: 8772203Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.Type: GrantFiled: September 7, 2012Date of Patent: July 8, 2014Assignee: Clearwater International, LLCInventor: Kevin M. Schwartz
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Patent number: 8757260Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.Type: GrantFiled: February 11, 2009Date of Patent: June 24, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Hongyu Luo, Dwight D. Fulton
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Patent number: 8728989Abstract: New hydrocarbon based slurry compositions and drilling, fracturing, completion and production fluids including the hydrocarbon based slurry composition are disclosed, where the composition includes a hydrocarbon soluble polymer adapted to decrease particle settling rates of particulate materials present in the fluids and in the case of fluids that include hydratable materials to increase hydration properties of such materials.Type: GrantFiled: June 19, 2007Date of Patent: May 20, 2014Assignee: Clearwater InternationalInventors: Sarkis R. Kakadjian, Sr., Joseph Earl Thompson, Sr.
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Patent number: 8709983Abstract: A substantially liquid gellant formed as one or more reaction products of a metal carboxylate or metal carboxylate amine salt, one or more organic acids, an ester which drives the reaction so that the reaction products are asymmetrical in structure, and a rheology modifier which preferentially interacts between the reaction products for prevent solidifying of the gellant reaction products until such time as the gellant is mixed with the fracturing fluid containing an activator after which the reaction products preferentially interact with the activator to gel the fracturing fluid. The resulting gellant is capable of gelling a hydrocarbon base fluid in less than about 30 seconds.Type: GrantFiled: February 4, 2011Date of Patent: April 29, 2014Assignee: Weatherford Canada PartnershipInventors: Clayton Smith, Simon John Michael Levey
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Patent number: 8669212Abstract: The present invention relates to fluids useful for subterranean operations, and more particularly, to fluorosurfactants useful for the reduction of water blocks, gas blocks, and/or gas condensates and their associated treatment fluids and methods. Provided is a method of treating a subterranean formation. The method may comprise contacting the subterranean formation with a fluorosurfactant. The fluorosurfactant may comprise an amine group, wherein the amine group comprises at least one substituent selected from the group consisting of a fluoroalkyl group, a fluoroalkenyl group, and combinations thereof, wherein the at least one substituent comprises about 3 carbons to about 22 carbons. Also provided are polymeric surfactants and treatment fluids that comprise fluorosurfactants.Type: GrantFiled: September 3, 2009Date of Patent: March 11, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Lewis R. Norman, Rajesh K. Saini
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Patent number: 8653011Abstract: A gelled organic-based fluid system and method of forming and using the system. The fluid system is prepared by gelling an organic solvent, a viscoelastic surfactant, and a nitrogen compound having a free electron pair such as urea in an amount effective to both increase viscosity and increase a rate of breaking the viscosity, relative to the gelled system without the nitrogen compound. In a further aspect, the method is used to treat a well penetrating a subterranean formation, for example, in a coiled tubing cleanout, or the like.Type: GrantFiled: November 12, 2009Date of Patent: February 18, 2014Assignee: Schlumberger Technology CorporationInventors: Mathew M. Samuel, Leiming Li, Juliet Edwena Juel
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Publication number: 20140045732Abstract: A process for increasing mobility of heavy oil includes: disposing a solvating composition comprising a paraffinic solvent and a multifunctional solvent in a heavy oil environment including a heavy oil, the heavy oil comprising asphaltene; contacting the heavy oil with the solvating composition; and stabilizing asphaltene in the heavy oil with the solvating composition to increase mobility of the heavy oil and to form a stabilized heavy oil which includes the heavy oil and solvating composition. A method for making stabilized heavy oil includes separating resin from an oil; combining the resin and a paraffinic solvent to form a solvating composition; disposing the solvating composition in a heavy oil environment which includes heavy oil comprising asphaltene; and contacting the asphaltene with the solvating composition to make stabilized heavy oil, wherein the stabilized heavy oil comprises the solvating composition and heavy oil.Type: ApplicationFiled: August 8, 2012Publication date: February 13, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Oleg A. Mazyar, Michael H. Johnson
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Patent number: 8618025Abstract: Disclosed and claimed is a composition and method of inhibiting the formation of hydrate agglomerates in a fluid comprising water, gas, and optionally liquid hydrocarbon comprising adding to the fluid an effective anti-agglomerant amount of the following formula and optionally salts thereof: wherein each R1 is independently absent, C1-C10 alkyl, benzyl, or H; wherein R2 is C1-C10 alkyl; wherein R3 C1-C10 alkyl; and wherein R4 is C4-C22 alkyl or alkenyl.Type: GrantFiled: December 16, 2010Date of Patent: December 31, 2013Assignee: Nalco CompanyInventor: Peter A. Webber
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Publication number: 20130341028Abstract: Properties of a base fluid may be controllably tuned to a pre-determined range of measurements by adding modified nanoparticles to a base fluid. The property to be modified may be or include, but is not limited to, electrical conductivity, dielectric strength, thermal conductivity, and combinations thereof. The modified nanoparticles may be or include modified graphene nanoparticles, modified graphene platelets, modified electrically-conductive nanotubes, modified electrically-conductive nanorods, nanospheres, single-walled nanotubes, double walled nanotubes, multiwalled nanotubes, nano-onions, fullerenes, nanodiamonds, and combinations thereof. The base fluid may be or include, but is not limited to a non-aqueous based fluid, an aqueous fluid, and combinations thereof.Type: ApplicationFiled: August 23, 2013Publication date: December 26, 2013Applicant: Baker Hughes IncorporatedInventors: Chad F. Christian, Ashley D. Leonard
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Patent number: 8598090Abstract: A method of cleaning a wellbore prior to the production of oil or gas, wherein the wellbore has been drilled with an invert emulsion drilling mud that forms an invert emulsion filter cake is disclosed. The method may include circulating a breaker fluid into the wellbore, where the breaker fluid includes a non-oleaginous internal phase and an oleaginous external phase, where the non-oleaginous phase includes a water soluble polar organic solvent, a hydrolysable ester of a carboxylic acid, and a weighting agent, and the oleaginous external phase includes an oleaginous fluid and an emulsifier, and where the hydrolysable ester is selected so that upon hydrolysis an organic acid is released and the invert emulsion of the filter cake breaks.Type: GrantFiled: March 31, 2010Date of Patent: December 3, 2013Assignee: M-I L.L.C.Inventors: Charles Svoboda, Raymond D. Ravitz, Mark Luyster
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Patent number: 8592354Abstract: A method of cleaning a wellbore prior to the production of oil or gas is disclosed, wherein the wellbore has been drilled with an invert emulsion drilling mud that forms an invert emulsion filter cake. The method may include the steps of circulating a breaker fluid into the wellbore, where the breaker fluid includes an aqueous fluid, a water soluble polar organic solvent, a hydrolysable ester of a carboxylic acid, and a weighting age, and where the hydrolysable ester is selected so that upon hydrolysis an organic acid is released and the invert emulsion of the filter cake breaks.Type: GrantFiled: December 22, 2011Date of Patent: November 26, 2013Assignee: M-I L.L.C.Inventors: Charles Svoboda, Raymond D. Ravitz, Mark Luyster
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Patent number: 8575072Abstract: A non-aqueous wellbore servicing fluid comprising a fluid loss additive wherein the fluid loss additive comprises the reaction product of (i) a functional polymer and (ii) an oligomerized fatty acid. A method of conducting an oil-field operation comprising placing a non-aqueous wellbore servicing fluid downhole wherein the non-aqueous wellbore servicing fluid comprises a fluid loss additive comprising the reaction product of (i) a functional polymer and (ii) an oligomerized fatty acid.Type: GrantFiled: September 29, 2011Date of Patent: November 5, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Jeffery R. Harris, Frank E. Evans
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Patent number: 8563482Abstract: Processes for producing alkyl esters useful as base fluids in oil-based mud compositions. The alkyl esters are produced from raw material waste oil that include vegetable oil. The raw material waste oil can be obtained from the food industry, such as from food chains. The raw material waste oil is purified by removing impurities from it. The raw material waste oil is then esterified with an alcohol in the presence of a catalyst. The resulting alkyl ester products are then separated from triglycerides. The alkyl ester products are then washed and dried.Type: GrantFiled: September 22, 2010Date of Patent: October 22, 2013Assignee: Saudi Arabian Oil CompanyInventor: Md. Amanullah
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Patent number: 8546310Abstract: Of the many compositions and methods provided herein, an example method includes a method of treating a subterranean formation that comprises combining components comprising water and a density-matched suspension to prepare a treatment fluid, wherein the density-matched suspension comprises a suspending liquid and a solid particle suspended in the suspending liquid, and introducing the treatment fluid into a well bore. An example composition includes a suspension that comprises a suspending liquid comprising a hydrophobic liquid, wherein the hydrophobic liquid hydrolyzes when placed in contact with an aqueous fluid to form hydrophilic products, and a solid particle suspended in the suspending liquid, wherein the suspension is a density-matched suspension.Type: GrantFiled: June 2, 2010Date of Patent: October 1, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Sam Lewis, Michael Szymanski, Christopher Gordon
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Patent number: 8541348Abstract: Emulsions for use in a well including: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. Methods include the steps of: (a) forming an emulsion described above; and (b) introducing the emulsion into a portion of a subterranean formation.Type: GrantFiled: March 29, 2012Date of Patent: September 24, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Ian D. Robb, Sherry Gale Gaskins, Jimmy D. Weaver, Phillip D. Nguyen
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Patent number: 8513168Abstract: A method of treating a hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein (i) when the salinity of the brine is from about 2 wt % to about 4 wt %, the composition comprises a blend of a C20-24 internal olefin sulfonate and a C24-28 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C24-28 internal olefin sulfonate is from about 90:10 to about 70:30 and (ii) when the salinity of the brine is greater than about 4 wt % up to about 13 wt % the composition comprises a blend of a C20-24 internal olefin sulfonate and a C15-18 internal olefin sulfonate wherein the weight ratio of the C20-24 internal olefin sulfonate to the C15-18 internal olefin sulfonate is from about 90:10 to about 70:30; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.Type: GrantFiled: February 5, 2009Date of Patent: August 20, 2013Assignee: Shell Oil CompanyInventors: Julian Richard Barnes, Kirk Herbert Raney, Thomas Carl Semple, Paul Gregory Shpakoff, Johan Paul Smit
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Patent number: 8499835Abstract: A method of agglomerating coal particles in a subterranean formation having a coal seam, comprising the steps of providing (a) a fluid having an aqueous medium and a first collector and/or a frother; (b) pumping the fluid into the formation and (c) contacting coal particles in the formation thereby agglomerating the contacted coal particles.Type: GrantFiled: June 13, 2008Date of Patent: August 6, 2013Assignee: Trican Well Services, Ltd.Inventors: Kewei Zhang, Chris Wiggins
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Publication number: 20130178400Abstract: Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.Type: ApplicationFiled: February 28, 2013Publication date: July 11, 2013Applicant: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews, John R. Willingham, Richard A. Mitchell, Kushal Seth
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Patent number: 8481463Abstract: A grouting composition for use in insulating a portion of a tubular located inside an enclosed conduit comprises: (A) an oil-swellable binding material comprising a organophilic clay; and (B) a hydrocarbon liquid, wherein the hydrocarbon liquid is the continuous phase of the grouting composition; and (C) an insulating material comprising a hollow microsphere, wherein after the grouting composition has set, the grouting composition has a thermal conductivity of less than 0.3 BTU/hr·ft·° F.Type: GrantFiled: June 22, 2012Date of Patent: July 9, 2013Assignee: Halliburton Energy Services, Inc.Inventor: Eric B. Frantz
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Patent number: 8455405Abstract: The use of a solvent for bitumen extraction, either from mined oil sands or in situ. The solvent includes (a) a polar component, the polar component being a compound comprising a non-terminal carbonyl group; and (b) a non-polar component, the non-polar component being a substantially aliphatic substantially non-halogenated alkane. The solvent has a Hansen hydrogen bonding parameter of 0.3 to 1.7 and/or a volume ratio of (a):(b) in the range of 10:90 to 50:50.Type: GrantFiled: October 26, 2009Date of Patent: June 4, 2013Assignee: ExxonMobil Upstream Research CompanyInventor: Tapantosh Chakrabarty
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Publication number: 20130130943Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a viscoelastic surfactant (VES) includes: providing an aqueous fluid; adding to the aqueous fluid, in any order, components comprising: a VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles, an unsaturated fatty acid comprising a monoenoic acid or a polyenoic acid; or a combination thereof; and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles in the gelled aqueous fluid. The method also includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of metal ions and heating the gelled aqueous fluid to a temperature sufficient to cause the unsaturated fatty acid to auto-oxidize to products present in an amount effective to reduce the viscosity.Type: ApplicationFiled: November 18, 2011Publication date: May 23, 2013Applicant: BAKER HUGHES INCORPORATEDInventor: James B. Crews
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Publication number: 20130130946Abstract: Emulsions for use in a well including: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. Methods include the steps of: (a) forming an emulsion described above; and (b) introducing the emulsion into a portion of a subterranean formation.Type: ApplicationFiled: March 29, 2012Publication date: May 23, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Ian D. Robb, Sherry G. Gaskins, Jimmie D. Weaver, Phillip D. Nguyen