Organic Component Contains A Carbonyl Group (e.g., Aldehyde, Ketone, Etc.) Patents (Class 507/268)
  • Publication number: 20110284225
    Abstract: A method comprises providing a treatment fluid comprising a gelling agent, an aqueous base fluid, a buffer composition comprising a plurality of salts, and a crosslinking agent; and contacting a subterranean formation with the treatment fluid. The method may be used in subterranean formation having a temperature greater than about 200° F., and the treatment fluid useful with the method may have a high shear recovery greater than 100%.
    Type: Application
    Filed: May 20, 2010
    Publication date: November 24, 2011
    Inventors: Paul D. Lord, Ivan Suleiman, John M. Terracina, Rajendra A. Kalgaonkar
  • Patent number: 8062586
    Abstract: Methods and compositions are provided that inhibit the corrosion of metal surfaces by aqueous acid solutions. The inhibition is basically achieved by the addition of a reaction product of an alpha, beta-unsaturated aldehyde or ketone with a primary or secondary amine to the aqueous acid solution.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: November 22, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Juanita M. Cassidy, Keith A. Frost
  • Patent number: 8025099
    Abstract: A method of treating a hydrocarbon reservoir that is penetrated by a well is disclosed, the method comprising injecting into the well a water transfer system comprising liquefied petroleum gas (LPG) and an alcohol that is at least partially water and liquefied petroleum gas soluble. Further, a method of treating a hydrocarbon reservoir is disclosed, the method comprising introducing into the hydrocarbon reservoir a combination of LPG and a solvent system that is at least partially liquefied petroleum gas and water soluble.
    Type: Grant
    Filed: December 1, 2008
    Date of Patent: September 27, 2011
    Assignee: GasFrac Energy Services Inc.
    Inventor: Shaun T. Mesher
  • Patent number: 8017560
    Abstract: The present invention relates to hydrophobically modified hydroxyalkyl guar derivatives which dissolve rapidly in water, having a hydroxyalkyl molar substitution between 0.2 and 2.5 and containing hydrophobic groups comprising C10-C32 alkyl chains, to the procedure for their preparation and to their use in the formulation of well fluids.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: September 13, 2011
    Assignee: Lamberti SpA
    Inventors: Ugo Pfeiffer, Morano Gatto, Mauro Tenconi, Laura Vigano, Andrea Balestrini, Giuseppe Li Bassi
  • Patent number: 7994099
    Abstract: Provided herein are methods and compositions that include a method comprising contacting a metal surface with an acidic fluid comprising a corrosion inhibitor that comprises a reaction product formed from a direct or an indirect reaction of an aldehyde with a thiol and/or an amine functionalized ring structure. A composition provided includes an acidic treatment fluid that comprises an aqueous-base fluid, and acid, and a corrosion inhibitor that comprises a reaction product formed from a direct or an indirect reaction of an aldehyde with a thiol and/or an amine functionalized ring structure.
    Type: Grant
    Filed: April 14, 2009
    Date of Patent: August 9, 2011
    Assignee: Haliburton Energy Services, Inc.
    Inventors: Juanita M. Cassidy, Chad E. Kiser, Jim L. Lane
  • Patent number: 7994101
    Abstract: Many methods are presented herein including a method comprising: providing a metal surface; and contacting the metal surface with a treatment fluid comprising an aqueous base fluid, an acid, a corrosion inhibitor, and a corrosion inhibitor intensifier composition comprising a corrosion inhibitor compound that corresponds to a formula: PR1R2R3, wherein R1, R2, and R3 are chosen from the group consisting of C1-C20 alkyl, cycloalkyl, oxyalkyl, and aryl groups, and R1, R2, and R3 may or may not be equal. Corrosion inhibitor intensifier compositions also are provided.
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: August 9, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Juanita M. Cassidy, Chad E. Kiser, Jim L. Lane
  • Patent number: 7985717
    Abstract: Methods of treating a wellbore comprise displacing a drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage into the wellbore. Methods of drilling a wellbore comprise: applying torque to a bit within the wellbore and concurrently applying force to urge the bit to extend through the wellbore; and circulating a drilling fluid past the bit to remove cuttings therefrom, the drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. Methods of preparing a drilling fluid comprise: forming an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage; and combining the organophilic clay with an oil-based fluid.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: July 26, 2011
    Assignee: Halliburton Energy Services Inc.
    Inventor: Jeffrey J. Miller
  • Publication number: 20110160103
    Abstract: A method of servicing a wellbore comprising placing a composition comprising a surfactant, brine, an oleaginous fluid, and optionally a co-surfactant in an annular space of the wellbore, wherein the composition forms a microemulsion under low shear conditions.
    Type: Application
    Filed: December 30, 2009
    Publication date: June 30, 2011
    Applicant: HALLIBURTON ENERGY SERVICES, INC
    Inventors: Ryan van Zanten, Douglas J. Harrison
  • Patent number: 7943555
    Abstract: Wellbore treatment kits are provide that include a polymeric solution for placement in a wellbore that penetrates a subterranean formation and an activator for causing a polymer to precipitate out of the polymeric solution when it contacts the polymeric solution, wherein the resulting precipitate is capable of at least partially blocking a flow of a wellbore servicing fluid into the subterranean formation. The wellbore servicing fluid may be, for example, a drilling fluid, a cement composition, a workover fluid, or combinations thereof. The polymeric solution may comprise, for example, a poly vinyl pyrrolidone aqueous solution, and the activator may comprise, for example, a formate brine. When desirable, the precipitate may be easily and quickly removed from the subterranean formation by dissolving it in fresh water.
    Type: Grant
    Filed: April 19, 2005
    Date of Patent: May 17, 2011
    Assignee: Halliburton Energy Services Inc.
    Inventors: Kenneth W. Oyler, Carl J. Thaemlitz
  • Publication number: 20110100630
    Abstract: Acid-soluble cupric acetate may used in conjunction with potassium iodide to generate cuprous iodide (CuI) as an acid corrosion inhibition aid. A suitable corrosion inhibitor together with the aid protects steel surfaces in an acid environment, for instance, while acid fracturing or matrix acidizing subterranean formations. Cupric acetate monohydrate may be used with an alkali metal iodide salt such as potassium iodide or sodium iodide to generate cuprous iodide in situ in aqueous acid solutions. Use of cupric acetate provides a somewhat delayed reaction rate with potassium iodide to generate the desired product, cuprous iodide, which has very low solubility in acid systems. The method includes delayed and in situ production of cuprous iodide for enhancing performance of commercially available corrosion inhibitors, commonly referred to as intensifying the effect of the corrosion inhibitor (corrosion inhibitor intensifier or simply an intensifier).
    Type: Application
    Filed: October 25, 2010
    Publication date: May 5, 2011
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Brian A. Evans, Kushal Seth, Allen D. Gabrysch, Patrick A. Kelly, Donald Nelson Horner, JR.
  • Patent number: 7928040
    Abstract: A composition for treating a portion of a wellbore or a portion of a subterranean formation is provided, the composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted to be within an appropriate range for the type of activator. A method for treating a portion of a wellbore or a portion of a subterranean formation, the method comprising the steps of: forming or providing a composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted within an appropriate range for the type of activator; and introducing the composition through a wellbore to treat a portion of a wellbore or a portion of a subterranean formation. The activator can be a water-soluble alkanoyl-donor compound or a chelated transition metal. Preferably, the composition further comprises an iron chelating agent.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: April 19, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Michael W. Sanders, Jeffrey L. Mundy, Fong Fong Foo, Rajesh K. Saini
  • Patent number: 7923417
    Abstract: A composition for treating a portion of a wellbore or a portion of a subterranean formation is provided, the composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted to be within an appropriate range for the type of activator. A method for treating a portion of a wellbore or a portion of a subterranean formation, the method comprising the steps of: forming or providing a composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted within an appropriate range for the type of activator; and introducing the composition through a wellbore to treat a portion of a wellbore or a portion of a subterranean formation. The activator can be a water-soluble alkanoyl-donor compound or a chelated transition metal. Preferably, the composition further comprises an iron chelating agent.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: April 12, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Michael W. Sanders, Jeffrey L. Mundy, Fong Fong Foo, Rajesh K. Saini
  • Publication number: 20110065614
    Abstract: An oil well being subjected to an acid stimulation may be treated with a corrosion inhibitor including an Ammonium Iodide Ion Source, a first carbonyl containing compound having a general formula: and a second carbonyl containing compound having the general formula: wherein R1 is an alkyl or aromatic group, R2 is a hydrogen, alkyl or aromatic group, and R3 is a hydrogen or an alkyl group having from 1 to 6 carbons; and wherein the alkyl or aromatic groups of R1, R2, or R3 may further comprise a nitrogen, phosphorous, halogen or second oxygen moiety; and wherein the oil well being treated has zone being treated at a temperature of from about 90 to about 500° F. This abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    Type: Application
    Filed: September 9, 2010
    Publication date: March 17, 2011
    Applicant: BAKER HUGHES INCORPORATED
    Inventor: Michael L. Walker
  • Publication number: 20110065612
    Abstract: The invention relates to a class of novel surfactants that have utility in the recovery and/or extraction of oil.
    Type: Application
    Filed: December 10, 2009
    Publication date: March 17, 2011
    Inventors: Kristoffer K. Stokes, Michael C. Berg, David Soane, Kevin T. Petersen, John H. Dise, Atul C. Thakrar, Rosa Casado
  • Patent number: 7906462
    Abstract: A method of acidizing and cleaning up a formation is disclosed, the formation being above 150 degrees C. The formation is treated with a mutual solvent system comprising a mutual solvent of oil and water, an aqueous acid, a corrosion inhibitor, and an iron control agent. In some embodiments, the iron control agent is present in an amount of less than 1% by weight of the mutual solvent system. In some embodiments, the corrosion inhibitor may be present in an amount of less than 10% by weight of the mutual solvent system. In some embodiments, the mutual solvent system further comprises an intensifier.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: March 15, 2011
    Assignee: SynOil Fluids Holdings Inc.
    Inventors: Shaun T. Mesher, David L. Edwards
  • Patent number: 7902124
    Abstract: A method of treating a subterranean formation penetrated by a wellbore of a well having iron-containing components is carried out by introducing a treatment fluid into the wellbore of the well. The treatment fluid is formed from an aqueous solution, a mineral acid, a viscoelastic surfactant gelling agent and corrosion inhibitor system containing at least one of an alkyl, alkenyl, alicyclic or aromatic substituted aliphatic ketone and aliphatic or aromatic aldehyde. The treatment fluid is substantially free of any formic acid or precursor formic acid. In certain embodiments, the corrosion inhibitor system comprises a mixture of at least one of an alkenyl phenone or ?,?-unsaturated aldehyde, an unsaturated ketone or unsaturated aldehyde other than the alkenyl phenone and ?,?-unsaturated aldehyde, a dispersing agent, an extender and an alcohol solvent. A corrosion inhibitor intensifier may also be used in certain embodiments, which may include a mixture of cuprous iodide and cuprous chloride.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: March 8, 2011
    Assignee: Schlumberger Technology Corporation
    Inventors: Syed Ali, Javier Sanchez Reyes, Mathew M. Samuel, Francois M. Auzerais
  • Patent number: 7893009
    Abstract: The invention relates to polymers with a mean molecular weight of between 500 and 500,000 g/mol that can be produced as follows: A) reaction of a compound of formula 1, in which n stands for 0, 1 or 2 and A for an arbitrarily substituted C1-C40 group with a compound of the formula 2 B(OH)m in which m is from 2 to 10 and B is a represents an arbitrarily substituted C2-C40 group, B) subsequently reaction of the product thus obtained with a nitrogen-containing carboxylic acid which comprises from 1 to 20 carbon atoms, where the molar ratio between the number of free OH groups of the polyester obtained in step A and the nitrogen-containing carboxylic acid is between 1:0.1 and 1:1. The polymers are used to inhibit gas hydrate formation.
    Type: Grant
    Filed: February 1, 2006
    Date of Patent: February 22, 2011
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Michael Feustel
  • Patent number: 7867953
    Abstract: Methods of treating a wellbore comprise displacing a drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage into the wellbore. Methods of drilling a wellbore comprise: applying torque to a bit within the wellbore and concurrently applying force to urge the bit to extend through the wellbore; and circulating a drilling fluid past the bit to remove cuttings therefrom, the drilling fluid comprising an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. Methods of preparing a drilling fluid comprise: forming an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage; and combining the organophilic clay with an oil-based fluid.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: January 11, 2011
    Assignee: Halliburton Energy Services Inc.
    Inventor: Jeffrey J. Miller
  • Patent number: 7855168
    Abstract: The current disclosure describes a multifunctional fluid that addresses a new concept in the removal of filter cake. A composition is disclosed comprising: a carrier fluid, a surfactant, a fluorine source and an organic stabilizer able to minimize precipitation of fluorine The associated method to remove the filter cake is also described.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: December 21, 2010
    Assignee: Schlumberger Technology Corporation
    Inventors: Michael J. Fuller, Syed Ali, Laurent Pirolli, John W. Still
  • Patent number: 7846877
    Abstract: Methods are provided for treating a portion of a well and include the steps of: (a) forming a treatment fluid comprising an aqueous solution, wherein the aqueous solution comprises: (i) water; (ii) a water-soluble polysaccharide; (iii) one or more water-soluble salts, wherein the one or more salts are selected and are in at least a sufficient concentration such that the water-salt solution has a density of at least 10 ppg; and (iv) urea; and (b) introducing the treatment fluid into the portion of the well. According to the inventions, the concentration of the urea in the water is in at least a sufficient concentration such that aqueous solution: (1) has a G? of at least 2 Pa, or (2) is filterable. According to the inventions, an identical aqueous solution except with less than the sufficient concentration of the urea would not satisfy the above conditions.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: December 7, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Ian D. Robb
  • Publication number: 20100294499
    Abstract: The present invention discloses an enhanced oil recovery method that contacts a gas and an alkylene carbonate with a subterranean formation.
    Type: Application
    Filed: January 15, 2009
    Publication date: November 25, 2010
    Applicant: Huntsman Petrochemical LLC
    Inventors: David C. Lewis, Luis C. Salazar, James R. Machac, JR.
  • Patent number: 7833949
    Abstract: A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from an aqueous medium, a diutan heteropolysaccharide having a tetrasaccharide repeating unit in the polymer backbone and a peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore may be carried out by introducing the treatment fluid into the formation through the wellbore. Breaking aids or catalysts may also be used with the treatment fluid.
    Type: Grant
    Filed: July 25, 2008
    Date of Patent: November 16, 2010
    Assignee: Schlumberger Technology Corporation
    Inventors: Leiming Li, Curtis L. Boney, Cody Hanzik, Lijun Lin, Syed Ali, Oscar Bustos
  • Publication number: 20100286000
    Abstract: A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines.
    Type: Application
    Filed: May 10, 2010
    Publication date: November 11, 2010
    Applicant: Baker Hughes Incorporated
    Inventors: Tianping Huang, James B. Crews, John R. Willingham, James R. Pace, Christopher K. Belcher
  • Publication number: 20100270020
    Abstract: Methods of treating a hydrocarbon-bearing formation having brine and liquid hydrocarbons and treated hydrocarbon-bearing formations. The methods include contacting the hydrocarbon-bearing formation with a composition comprising solvent and a fluorinated anionic surfactant. In some embodiments, the solvent solubilizes the brine in the hydrocarbon-bearing formation without causing the fluorinated anionic surfactant to precipitate. In some embodiments, the solvent includes at least one of a polyol or polyol ether independently having from 2 to 25 carbon atoms and at least one of water, a monohydroxy alcohol, an ether, or a ketone, wherein the monohydroxy alcohol, the ether, and the ketone each independently have up to 4 carbon atoms.
    Type: Application
    Filed: December 18, 2008
    Publication date: October 28, 2010
    Inventors: Jimmie R. Baran, Jr., Michael S. Terrazas, Rudolf J. Dams
  • Patent number: 7799741
    Abstract: The present invention relates to the use of at least one hydrophobin or at least one hydrophobin derivative in a drilling mud.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: September 21, 2010
    Assignee: BASF SE
    Inventors: Marcus Guzmann, Yaqian Liu, Ulf Baus
  • Publication number: 20100197527
    Abstract: Treatments fluids relating to the hydrolysis of water-hydrolysable materials are provided. In one embodiment, provided is a treatment fluid that comprises an aqueous liquid, a water-miscible solvent, and a water-hydrolysable material. Also provided is a hydrolysis retarder composition that comprises an aqueous liquid and a water-miscible solvent.
    Type: Application
    Filed: April 14, 2010
    Publication date: August 5, 2010
    Inventors: Bradley L. Todd, Karen Savery
  • Publication number: 20100190666
    Abstract: A method of treating a medium for water fracturing is disclosed, the method comprises: introducing at least one biocide and at least one metabolic inhibitor in the medium, using the medium for water fracturing. In another aspect a method of controlling the post-fracture reservoir souring by the metabolic activities of sulfate reducing bacteria of a well is described: at least one biocide and at least one metabolic inhibitor are introduced in a medium made of water, the medium is used for fracturing the well, and the medium remains in the reservoir to kill and/or inhibit growth of sulfate reducing bacteria.
    Type: Application
    Filed: December 21, 2009
    Publication date: July 29, 2010
    Inventors: Syed Ali, Shawn McCleskey Rimassa, Francois M. Auzerais, Curtis L. Boney, Leiming Li
  • Publication number: 20100152071
    Abstract: The present invention includes compositions and methods for treating a hydrocarbon-bearing formation by contacting the hydrocarbon-bearing formation with a fluid that includes at least one of a polyol or polyol ether, wherein the polyol and polyol ether independently have from 2 to 25 carbon atoms; and at least one of a monohydroxy alcohol, ether, or ketone, wherein the monohydroxy alcohol, ether, and ketone independently have from 1 to 4 carbon atoms, and wherein the at least one of a polyol or polyol ether is present in the fluid at at least 50 weight percent, based on the total weight of the fluid.
    Type: Application
    Filed: December 30, 2007
    Publication date: June 17, 2010
    Applicants: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM, 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Gary A. Pope, Jimmie R. Baran, Vishal Bang, John D. Skildum, Mukul M. Shama
  • Patent number: 7732380
    Abstract: Drilling fluids are provided that comprise an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. The quaternary ammonium surfactant may comprise a compound generally represented by the following formula: where M? is an anion such as a chloride, methyl sulfate, bromide, acetate, or iodide ion; R1 is an alkyl group such as a saturated hydrocarbon with 10 or more carbons; R2, R3, and R4 are the same or different alkyl groups such as a methyl, ethyl, or benzyl group, and x is greater than or equal to 1. The organophilic clay treated in this manner is substantially biodegradable. In embodiments, the drilling fluids comprise the foregoing organophilic clay, an oil-based fluid and a weighting agent. In still more embodiments, the drilling fluids comprise the foregoing organophilic clay, an invert emulsion, an emulsifier, and a weighting agent.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: June 8, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Jeffrey J. Miller
  • Patent number: 7673686
    Abstract: The invention provides a method for treating a subterranean formation penetrated by a wellbore. The method comprises the steps of: (a) introducing a composition through the wellbore into the subterranean formation, wherein the composition comprises: (i) a solvent consisting essentially of an aqueous dissolvable solvent comprising any solvent that is at least 25% by weight soluble in water, wherein the solvent is from about 90% to about 99.9% by weight of the composition; and (ii) a curable resin, wherein the curable resin is from about 0.01% to about 10% by weight of the composition; wherein the curable resin and the solvent are mutually selected such that, for the ratio of the curable resin to the solvent, the curable resin is soluble in the solvent; and (b) installing a mechanical sand control device into the wellbore either before or after introducing the composition into the wellbore.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: March 9, 2010
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Richard D. Rickman, Ronald G. Dusterhoft
  • Patent number: 7651981
    Abstract: A process for recovering materials from a subterranean formation, for example in enhanced oil recovery, comprises: (A) (a) (i) selecting a first polymeric material having a repeat unit of formula (A) wherein A and B are the same or different, are selected from optionally-substituted aromatic and heteroaromatic groups and at least one comprises a relatively polar atom or group and R1 and R2 independently comprise relatively non-polar atoms or groups; or (ii) selecting a first polymeric material prepared or preparable by providing a compound of general formula (B) wherein A, B, R1 and R2 are as described above, in an aqueous solvent and causing the groups C?C in said compound to react with one another to form said first polymeric material; (b) selecting a second polymeric material which includes a functional group which is able to react in the presence of said first polymeric material to form a third polymeric material; (c) causing the formation of said third polymeric material by a reaction involving said firs
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: January 26, 2010
    Assignees: Advanced Gel Technology Limited, Aubin Limited
    Inventors: Donald Eagland, Nicholas John Crowther, James Murray, Austin Tobin
  • Publication number: 20090229827
    Abstract: Methods and compositions that include a method comprising providing a treatment fluid that comprises an aqueous base fluid, a biocide, a biocide enhancer, a friction reducer, and a compatibility aid, and introducing the treatment fluid into a subterranean formation. A composition provided includes a treatment fluid comprising an aqueous base fluid, a biocide, a biocide enhancer, a friction reducer, and a compatibility aid.
    Type: Application
    Filed: March 14, 2008
    Publication date: September 17, 2009
    Inventors: Jason E. Bryant, David E. McMechan, Michael A. McCabe, J. Michael Wilson, Karen L. King
  • Patent number: 7521399
    Abstract: Drilling fluids are provided that comprise an organophilic clay treated with a quaternary ammonium surfactant having an amide linkage. The quaternary ammonium surfactant may comprise a compound generally represented by the following formula: where M? is an anion such as a chloride, methyl sulfate, bromide, acetate, or iodide ion; R1 is an alkyl group such as a saturated hydrocarbon with 10 or more carbons; R2, R3, and R4 are the same or different alkyl groups such as a methyl, ethyl, or benzyl group, and x is greater than or equal to 1. The organophilic clay treated in this manner is substantially biodegradable. In embodiments, the drilling fluids comprise the foregoing organophilic clay, an oil-based fluid and a weighting agent. In still embodiments, the drilling fluids comprise the foregoing organophilic clay, an invert emulsion, an emulsifier, and a weighting agent.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: April 21, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Jeffrey J. Miller
  • Patent number: 7507694
    Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles; and treating the subterranean formation.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: March 24, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: William W. Shumway, Kenneth W. Pober, Jeff Kirsner
  • Patent number: 7448451
    Abstract: Methods of controlling particulate migration in a portion of a subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into the portion of the subterranean formation; wherein the portion of a subterranean formation being treated has a regain permeability of at least about 70%. Methods of creating a stabilized region around a portion of a subterranean formation around a well bore having a screen or liner in place in that portion of the subterranean formation comprising placing a pre-flush fluid into the portion of the subterranean formation; and then, placing a low-viscosity adhesive substance diluted with an aqueous dissolvable solvent into that portion of the subterranean formation; wherein the portion of a subterranean formation being treated has regain permeability of at least about 70%.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: November 11, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Richard D. Rickman, Ronald G. Dusterhoft, Johnny A. Barton
  • Publication number: 20080173452
    Abstract: A composition for treating a portion of a wellbore or a portion of a subterranean formation is provided, the composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted to be within an appropriate range for the type of activator. A method for treating a portion of a wellbore or a portion of a subterranean formation, the method comprising the steps of: forming or providing a composition comprising: (a) water; (b) a source of hydrogen peroxide, and (c) an activator for the source of hydrogen peroxide; wherein the pH of the composition is adjusted within an appropriate range for the type of activator; and introducing the composition through a wellbore to treat a portion of a wellbore or a portion of a subterranean formation. The activator can be a water-soluble alkanoyl-donor compound or a chelated transition metal. Preferably, the composition further comprises an iron chelating agent.
    Type: Application
    Filed: January 23, 2007
    Publication date: July 24, 2008
    Inventors: Michael W. Sanders, Jeffrey L. Mundy, Fong Fong Foo, Rajesh K. Saini
  • Patent number: 7345011
    Abstract: The present invention relates to treatment operations in subterranean zones, and more particularly, to consolidation compositions and methods of using these consolidation compositions to mitigate water production from subterranean formations. The present invention provides methods for mitigating the production of water from a subterranean formation by injecting consolidation compositions comprising a furan-based resin into an interval in the subterranean formation.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: March 18, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, David L. Brown, Bhadra D. Desai
  • Patent number: 7343976
    Abstract: One embodiment of the present invention provides methods of treating a subterranean formation with a viscosified treatment fluid comprising combining water, a carbonyl-containing first compound, and an amine-containing second compound; wherein the carbonyl-containing first compound comprises at least one carbonyl moiety and is either a gelling agent or a derivatizing agent, and wherein the amine-containing second compound comprises at least one amine moiety and is a gelling agent when the carbonyl-containing first compound is a derivatizing agent and is a derivatizing agent when the carbonyl-containing first compound is a gelling agent; allowing at least one carbonyl moiety from the first compound and at least one amine moiety from the second compound to form a derivatizing linkage and create a derivatized gelling agent; and, placing the viscosified treatment fluid into a portion of a subterranean formation.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: March 18, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Michael J. R. Segura
  • Patent number: 7326670
    Abstract: A well service fluid comprising one or more anionic viscoelastic surfactants and one or more polymers is described. The fluids can contain an aqueous or non-aqueous fluid and/or a buffer for adjusting the pH of the fracturing fluid. The well service fluid can be used as a fracturing fluid in order to control water production from a well, while simultaneously increasing the oil production from the well.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: February 5, 2008
    Assignee: BJ Services Company
    Inventors: Gino F. DiLullo, Philip J. Rae, Atikah J. K. Ahmad
  • Patent number: 7216710
    Abstract: Methods of inhibiting corrosion comprising providing a corrosive environment; adding a corrosion inhibitor comprising a reaction product of a thiol compound and an aldehyde compound. Methods of acidizing a near well bore region of a subterranean formation comprising isolating a zone of interest along a well bore; and placing an acidizing solution in the zone of interest wherein the acidizing solution comprises an acid and a corrosion inhibiting compound comprising the reaction product of a thiol compound and an aldehyde compound.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: May 15, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas D. Welton, Juanita M. Cassidy
  • Patent number: 7201227
    Abstract: Disclosed herein is a method of treating a subterranean formation utilizing a fluid having a splittable foamer, i.e., a fluid that creates a stable foam when it contacts the formation but that loses its ability to foam as it remains in contact with the formation for extended time. The present method has the advantage that the fluid can be recovered from the well unhindered by the difficulties involved with recovering a foamed fluid from a well. The present method does not require the use of breakers, though the splitting of the foam can be accelerated by introducing an organic or inorganic acid into the well, if so desired.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: April 10, 2007
    Assignee: BJ Services Company
    Inventors: D. V. Satyanarayana Gupta, Barry T. Hlidek
  • Patent number: 7115546
    Abstract: A process for stimulating a formation is disclosed wherein a diverting fluid is used to divert an acid treatment package from a high permeability or damaged portion of a formation to a low permeability or undamaged portion of a formation. The fluid, which preferably forms vesicles, comprises at least one surfactant, at least one quaternary amine polyelectrolyte, water, and a non-aqueous solvent.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: October 3, 2006
    Assignee: BJ Services Company
    Inventors: Qi Qu, David Alleman
  • Patent number: 7063176
    Abstract: A method of increasing shale formation stability with a water based drilling fluid, the method including: delivering to the shale formation a drilling fluid formulated to include an aqueous fluid; a first reactant which is a soluble monomer, oligomer, or polymer with exposed ketone, aldehyde, or aldol groups or with groups which can be shifted to ketone or aldehyde functionality; and, a second reactant which is a primary amine, diamine, or polyamine which by condensation reaction forms a semi-soluble or precipitated filming product with the first reactant.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: June 20, 2006
    Assignee: M-I L.L.C.
    Inventor: Robert Schlemmer
  • Patent number: 6951250
    Abstract: A method of isolating a subterranean zone using a sealant composition comprising a partially polymerized furfuryl compound selected from the group consisting of furfuryl alcohol, furfuryl aldehyde, and combinations thereof, and pumping the sealant composition into a well bore positioned adjacent to the subterranean zone. A conduit is placed in the well bore to allow the sealant composition to be pumped into the well bore. The sealant composition is pumped down through the conduit and up through an annulus disposed between the conduit and walls of the well bore. After the sealant composition has cured in the annulus, it isolates the interior of the conduit from the subterranean zone and attaches the conduit to the walls of the well bore. In an embodiment, the weight ratio of the polymerized furfuryl compound to the non-polymerized furfuryl compound in the sealant composition ranges from about 1:1 to about 10:1.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: October 4, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventors: B. Raghava Reddy, Philip D. Nguyen
  • Patent number: 6939833
    Abstract: For tubing/casing annulus plug treatment to plug a well, a tubing/casing annulus plug additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, a filter aid, and an optional reinforcing material, preferably of fibers and/or comminuted plant materials. The method of forming a tubing/casing annulus plug fluid includes contacting the additive with water or an aqueous solution, with a method of plugging the tubing/casing annulus of a well further including the step of injecting the fluid into the annulus.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: September 6, 2005
    Inventor: Boyce Donald Burts, III
  • Patent number: 6927194
    Abstract: For well kill treatment to prevent the intrusion of formation fluids into the wellbore while the well is open, a well kill additive including a dry mixture of water soluble crosslinkable polymer, a crosslinking agent, filter aid, and optionally, a reinforcing material of fibers and/or comminuted plant materials. The method of forming a well kill fluid includes contacting the additive with water or an aqueous solution, with a method of conforming the formation further including the step of injecting the fluid into the wellbore.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: August 9, 2005
    Inventor: Boyce Donald Burts, III
  • Patent number: 6924254
    Abstract: Viscous well treating fluids and methods of treating subterranean zones penetrated by well bores are provided. The viscous fluids are basically comprised of water, a gelling agent and a delayed viscosity breaker comprising pentanedione peroxide.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: August 2, 2005
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Bradley L. Todd
  • Patent number: 6887840
    Abstract: An iron sulfide cleaning composition is described, along with a process for using the iron sulfide cleaning composition. The iron sulfide cleaning composition is simple to use and effective in removing deposits of iron sulfide from hydrocarbon wells. The iron sulfide cleaning composition consists of formaldehyde or glutaraldehyde, methanol, 2-butoxyethanol, isopropyl alcohol, hydrochloric acid, Surfactant Intermediate, Surfactant/Corrosion Inhibitor, glacial acetic acid and water.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: May 3, 2005
    Assignee: Milborn Enterprises LLC
    Inventor: Andy R. Miller
  • Publication number: 20040200616
    Abstract: Fracturing fluids and methods of fracturing a subterranean formation using such fluids are provided. A fracturing fluid having a first pH is foamed by introducing a gas to the fluid. The fracturing fluid comprises a surfactant that facilitates formation of the foam at the first pH. The foamed fracturing fluid is subsequently pumped to the subterranean formation to fracture it. The pH of the fracturing fluid is then changed to a second pH at which the surfactant facilitates reduction of the foam. The fracturing fluid releases proppant contained in the fluid to the subterranean formation. The fracturing fluid is then allowed to flow back to the surface. It can be recycled by changing the pH of the fracturing fluid back to the first pH and adding a gas to the fluid, causing it to foam again.
    Type: Application
    Filed: March 25, 2003
    Publication date: October 14, 2004
    Inventors: Jiten Chatterji, Bobby J. King, Karen L. King
  • Patent number: 6787507
    Abstract: A method of stabilizing a clayey geological formation surrounding a hydrocarbon well is described. It comprises the step of treating the formation with a first reactant and a second reactant, characterized in that a reaction of said first and said second reactant is essentially initiated in the presence of clayey material. The reaction can be characterized by substrate intercalation or condensation stabilization with no pH adjustment or stabilization through reaction of glycol with a carbonyl group containing second reactant or a reaction involving an epoxide ring opening under neutral or acidic conditions.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: September 7, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Peter V. Coveney, Michael Watkinson, Andrew Whiting, Edo S. Boek