Borated Or Boronated Carbonated Or Overbased Organic Acid Salts (e.g., Borated Overbased Carbonated Sulfonates, Etc.) Patents (Class 508/186)
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Patent number: 6559105Abstract: A composition of an antioxidant of the formula where R3 is an alkyl group of 2 to 6 carbon atoms, and a dispersant or a detergent, is a useful additive package for lubricant compositions.Type: GrantFiled: January 16, 2001Date of Patent: May 6, 2003Assignee: The Lubrizol CorporationInventors: William D. Abraham, Paul E. Adams, Gordon D. Lamb, Thomas J. Wolak, Richard A. Denis, Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Susan V. Cowling
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Patent number: 6492306Abstract: A composition comprising a hydrocarbon polymer having attached thereto pendant groups Aa and Bb wherein each A is independently selected from members of the group consisting of: groups of the formula and each B is independently selected from members of the group of formula: wherein each X is independently O, S, or NRb, and each Z is independently a group of the formula Ra is an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or wherein J is H, SH, NH2, or OH, and tautomers thereof; a is 0 or a number ranging from 1 to about 50, and b is a number ranging from 1 to about 30; wherein each of the groups is defined in greater detail herein.Type: GrantFiled: March 23, 2001Date of Patent: December 10, 2002Assignee: The Lubrizol CorporationInventors: Matthew R. Sivik, Richard M. Lange, Daniel M. Vargo, Paul E. Adams
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Patent number: 6489271Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.Type: GrantFiled: August 20, 1996Date of Patent: December 3, 2002Assignee: The Lubrizol CorporationInventor: Robert C. Richardson
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Patent number: 6486101Abstract: A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula —Q—Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k≧2, groups —K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarbType: GrantFiled: April 30, 2001Date of Patent: November 26, 2002Assignee: The Lubrizol CorporationInventors: Carmen V. Luciani, Richard M. Lange, Daniel M. Vargo
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Patent number: 6451745Abstract: Continuously variable transmission can be lubricated by supplying to them a composition of (a) an oil of lubricating viscosity; (b) a dispersant; and (c) a detergent. At least one of the dispersant (b) and the detergent (c) is a borated species, and the amount of boron present in the composition is sufficient to impart improved friction and anti-seizure properties to the composition when employed in said transmission.Type: GrantFiled: March 21, 2000Date of Patent: September 17, 2002Assignee: The Lubrizol CorporationInventor: William C. Ward
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Publication number: 20020119895Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) an antiwear improving amount of at least one molybdenum containing composition, and (B) at least one member selected from the group consisting of (i) at least one borated overbased metal salt of an acidic organic compound, provided that (A) and (Bi) are not the same, (ii) a combination of (a) at least one organic polysulfide or at least one ashless dithiocarbamate containing composition and (b) at least one component selected from the group consisting of a metal thiophosphate, a phosphoric acid ester or salt thereof, a phosphorus-containing carboxylic acid, ester, ether, or amide, a borated dispersant, an alkali metal borate, a borated fatty amine, a borated phospholipid, a borate ester, and mixtures thereof, and (iii) a combination of (i) and (ii).Type: ApplicationFiled: May 26, 1995Publication date: August 29, 2002Inventors: SUSAN P. COOK, JAMES J. SCHWIND, BERNARD CONSTANS, HENRI BOURGOGNON
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Patent number: 6362136Abstract: This invention relates to compositions containing a sulfur containing antiwear/extreme pressure agent, basic nitrogen compound or a mixture thereof together with a hydrocarbyl mercaptan. The composition may additionally contain a phosphorus or boron antiwear or extreme pressure agent, a dispersant or an overbased metal salt. The invention also relates to lubricants, functional fluids, and concentrates containing the same. Seals, e.g. nitrile, polyacrylate, and fluoroelastomer, in contact with these composition have reduced deterioration. With the use of these compositions, lubricants, and functional fluids, the seals' useful life is extended.Type: GrantFiled: March 26, 1996Date of Patent: March 26, 2002Assignee: The Lubrizol CorporationInventors: Robert C. Richardson, Donald J. Marn
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Publication number: 20020006878Abstract: A composition of an antioxidant of the formula 1Type: ApplicationFiled: January 16, 2001Publication date: January 17, 2002Applicant: Lubrizol CorporationInventors: William D. Abraham, Paul E. Adams, Gordon D. Lamb, Thomas J. Wolak, Richard A. Denis, Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Susan V. Cowling
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Publication number: 20010044387Abstract: An engine oil composition characterized by containing a major amount of lubricating base oil and (a) 0.01 to 30% by weight of an overbasic oil-soluble metal salt prepared by use of an alkaline-earth metal borate, (b) 0.01 to 5% by weight of a molybdenum dithiocarbamate, and (c) 0.01 to 5% by weight of an antioxidant as essential components, on the basis of the total amount of the composition.Type: ApplicationFiled: January 30, 2001Publication date: November 22, 2001Applicant: Nippon Mitsubishi Oil CorporationInventors: Kiyoshi Inoue, Jinichi Igarashi, Mituaki Ishimaru, Mineo Kagaya, Masakuni Hirata
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Patent number: 6310009Abstract: A saligenin derivative such as the magnesium salt represented by the formula is useful as an additive for a lubricating composition. Preferably X is —CHO or —CH2OH, and Y is —CH2— or —CH2OCH2—. R1 is a hydrocarbyl group containing 1 to 60 carbon atoms and m is 0 to 10. At least one aromatic ring should contain an R1 substituent and the total number of carbon atoms in all R1 groups should be at least 7.Type: GrantFiled: January 16, 2001Date of Patent: October 30, 2001Assignee: The Lubrizol CorporationInventors: Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Richard A. Denis, Thomas J. Wolak, Gordon D. Lamb, Paul E. Adams, William D. Abraham, Susan V Cowling
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Patent number: 6288013Abstract: A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently selected from members of the group consisting of: groups of the formula wherein R3 is H or hydrocarbyl, R4 is a divalent hydrocarbylene group, n=0 or 1, and each of R9 and R10 is independently H, alkoxyhydrocarbyl, hydroxyhydrocarbyl, hydrocarbyl, aminohydrocarbyl, N-alkoxyalkyl- or hydroxyalkyl-substituted aminohydrocarbyl, or a group of the formula &Parenopenst;Y&Parenclosest;cR11—M, wherein each Y is independently a group of the formula each R11 is a divalent hydrocarbyl group, R12 is as defined above for R9 and R10, and M is H, hydrocarbyl, amino, an amide group, an amide-containing group, an acylamino group, an imide group, or an imide-contaType: GrantFiled: December 3, 1997Date of Patent: September 11, 2001Assignee: The Lubrizol CorporationInventors: Matthew R. Sivik, Richard M. Lange, Paul E. Adams, Daniel M. Vargo
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Patent number: 6103673Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.Type: GrantFiled: September 14, 1998Date of Patent: August 15, 2000Assignee: The Lubrizol CorporationInventors: James L. Sumiejski, William C. Ward, Jr.
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Patent number: 6090757Abstract: A process of preparing an overbased composition by the reaction of oil soluble organic acids with oxides or hydroxides of, e.g., zinc, copper, cadmium, transition metals, etc. to form a salt. Additional oxides or hydroxides are added along with boric acid and promoters. These overbased metal borates are useful in lubricating oils and fuels.Type: GrantFiled: May 26, 1993Date of Patent: July 18, 2000Assignee: The Lubrizol CorporationInventor: Thomas Frier Steckel
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Patent number: 5958286Abstract: An automatic transmission fluid composition is provided which has significantly higher coefficients of dynamic friction (.mu.d) and static friction (.mu.s) than those of the conventional automatic transmission fluid. In addition, the composition has a .mu.o/.mu.d ratio close to 1.0, and a small change with the passage of time in frictional properties. The automatic transmission fluid composition comprises 0.01 to 20% by weight of an overbasic oil-soluble metal salt (a) prepared by use of an alkaline-earth metal borate, and 0.01 to 15% by weight of a compound (b) having a long-chain alkyl group and an amino group in the same molecular structure on the basis of the total amount of composition as essential components, the balance being lubricating base oil.Type: GrantFiled: November 24, 1992Date of Patent: September 28, 1999Assignee: Nippon Oil Company, Ltd.Inventor: Masanobu Kitanaka
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Patent number: 5854182Abstract: Magnesium borate overbased metallic detergent having magnesium borate uniformally dispersed in an extremely fine particle size is prepared by using magnesium alkoxide and boric acid. The process for preparation involves reacting neutral sulphonate of an alkaline earth metal with magnesium alkoxide and boric acid under anhydrous conditions in the presence of a dilution solvent followed by distillation to remove alcohol and part of dilution solvent therefrom. The borated mixture is then cooled, filtered to recover magnesium borated metal detergent. The magnesium borated metal detergent exhibited excellent cleaning and dispersing performance, very good hydrolytic and oxidation stability, good extreme pressure and antiwear properties. Such a detergent can advantageously be used in a hydrocarbon composition.Type: GrantFiled: October 9, 1996Date of Patent: December 29, 1998Assignee: Indian Oil Corporation Ltd.Inventors: Krishan Kumar Swami, Anurag Ateet Gupta, Shanti Parkash, Madan Mohan Rai, Akhilesh Kumar Bhatnagar
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Patent number: 5767044Abstract: This is invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an hydrocarbyl phosphite, wherein each hydrocarbyl group is saturated and independently contains from about 12 to about 24 carbon atoms, (B) an organic polysulfide, and (C) (i) a borated overbased metal salt of an acidic organic compound, (ii) a combination of a borated dispersant and a phosphorus antiwear or extreme pressure agent selected from the group consisting of a phosphoric acid ester or salt thereof, a lower alkyl phosphite, and a phosphorus-containing carboxylic acid, ester, ether, or amide, or (iii) a mixture of (i) and (ii). These compositions provide improved frictional properties to lubricating composition while maintaining the extreme pressure protection of the lubricant. The lubricating compositions have good thermal stability.Type: GrantFiled: November 12, 1996Date of Patent: June 16, 1998Assignee: The Lubrizol CorporationInventors: Sean S. Bigelow, Richard E. Gapinski, Syed Q. A. Rizvi
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Patent number: 5759965Abstract: This invention relates to a composition, comprising: (A) a boron-containing overbased material; (B) a phosphorus acid, ester or derivative thereof; and (C) a borated epoxide or borated fatty acid ester of glycerol. In one embodiment the inventive composition further comprises (D) a thiocarbamate. These compositions are useful in providing lubricants and functional fluids, particularly automatic transmission fluids, with enhanced antiwear properties. In one embodiment these compositions also provide such lubricants and functional fluids with enhanced extreme-pressure and/or friction-modifying.Type: GrantFiled: October 17, 1996Date of Patent: June 2, 1998Assignee: The Lubrizol CorporationInventor: James L. Sumiejski
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Patent number: 5739088Abstract: An improvement in a method of lubricating an alcohol-based fuel engine with an engine oil composition, the improvement which comprises using as said composition an engine oil composition comprising a lubricating base oil and about 0.01 to 10% by weight based on the total weight of the engine oil composition of an alkaline-earth metal borate. Thus prepared engine oil compositions for alcohol-based fuel engines of the present invention are superior to the prior art compositions in capacity for neutralizing formic acid, wear resistance, and stability against hydrolysis.Type: GrantFiled: July 19, 1994Date of Patent: April 14, 1998Assignee: Nippon Oil Co., Ltd.Inventors: Kiyoshi Inoue, Takashi Mito, Masakuni Hirata
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Patent number: 5719107Abstract: Thus, the instant invention is directed toward an oil for diesel engines comprising an admixture of (A) a major amount of an oil of lubricating viscosity, (B) at least 4 mass % dispersant, (C) at least 0.3 mass % of a metal phenate, (D) less than 0.1 mass % friction modifier, (E) less than 0.3 mass % of sulfurized phenols and, (F) less than 0.12 mass % neutral calcium sulfonate.Type: GrantFiled: August 9, 1996Date of Patent: February 17, 1998Assignee: Exxon Chemical Patents IncInventors: Edward Francis Outten, Andrew James Dalziel Ritchie
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Patent number: 5691283Abstract: In a motor vehicle, especially a heavy duty motor vehicle, having a transmission equipped with at least one cone-type synchronizer and an axle or differential gearing, the same lubricant is used for both such mechanisms. The lubricant has a viscosity grade level of from SAE 75W90 to SAE 85W140 and comprises base oil containing at least (i) Mannich base ashless dispersant; (ii) metal-free, sulphur-containing antiwear and/or extreme pressure agent; (iii) metal-free, phosphorus-containing and nitrogen-containing antiwear and/or extreme pressure agent; and (iv) overbased alkali or alkaline earth metal carboxylate, sulphonate or sulphurized phenate having a TBN of at least 145. The lubricant contains at most, if any, 100 ppm of metal as one or more metal-containing additive components other than (iv).Type: GrantFiled: June 7, 1995Date of Patent: November 25, 1997Assignee: Ethyl Petroleum Additives LimitedInventors: Julia C. Poat, Graeme M. Wallace, David Kenvyn Walters, Ian Macpherson
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Patent number: 5635459Abstract: A functional fluid composition having improved gear performance comprises an oil of lubricating viscosity, and added thereto(a) an alkali or alkaline earth metal salt complex in the form of borated and/or non-borated salts;(b) an EP/antiwear agent comprising a mixture of zinc salts of dialkylphosphorodithioic acid and 2-ethylhexanoic acid heated with triphenyl phosphite or an olefin; and(c) a borated epoxide.The oil of lubricating viscosity has a kinematic viscosity of at least 4 cSt and 100.degree. C. and a -40.degree. C. Brookfield viscosity of less than 20,000.Type: GrantFiled: October 27, 1995Date of Patent: June 3, 1997Assignee: The Lubrizol CorporationInventors: John V. Stoffa, Richard E. Gapinski
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Patent number: 5622923Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 are oxygen or sulfur, provided that at least one of X.sub.1, X.sub.2, and X.sub.3 is sulfur; R.sub.1 is a hydrocarbyl group; R.sub.2 is an alkylene group; R.sub.3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester.Type: GrantFiled: June 16, 1995Date of Patent: April 22, 1997Assignee: The Lubrizol CorporationInventors: Naresh C. Mathur, Mary G. Raguz
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Patent number: 5595961Abstract: Grease compositions, wherein the grease is thickened with a metal hydroxy-containing soap grease thickener are provided. Other essential ingredients of the compositions include borated hydroxyhydrocarbyl esters and phosphorus and/or sulfur compounds.Type: GrantFiled: June 7, 1995Date of Patent: January 21, 1997Assignee: Mobil Oil CorporationInventors: John P. Doner, Andrew G. Horodysky, John A. Keller, Jr.