The Nitrogen Heterocyclic Ring Has Chalcogen Bonded Directly To Ring Carbon Adjacent To Ring Nitrogen (e.g., Succinimide Compounds, Etc.) Patents (Class 508/192)
Abstract: A polysuccinimide composition is prepared by reacting a mixture of a copolymer of a first unsaturated acidic reagent and a 1,1-disubstituted olefin; a copolymer of a second unsaturated acidic reagent and a 1-olefin, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The two unsaturated acidic reagents can be the same or different. The mixture contains from 0.1 to 1.5 equivalents of polyamine per equivalent of acidic groups of the first and second copolymers.
Type:
Grant
Filed:
August 20, 1996
Date of Patent:
May 19, 1998
Assignee:
Chevron Chemical Company
Inventors:
James J. Harrison, William R. Ruhe, Jr.
Abstract: A succinimide composition is prepared by reacting a mixture of an alkenyl or alkylsuccinic acid derivative, an unsaturated acidic reagent copolymer, and a polyamine under reactive conditions; then treating the reaction product with either a cyclic carbonate or a linear mono- or polycarbonate or boron compound under reactive conditions. The alkenyl or alkyl substituent of the alkenyl or alkylsuccinic acid derivative has a Mn of from 1800 to 3000. The unsaturated acidic reagent copolymer has a Mn of from 2000 to 4800, and is a copolymer of an unsaturated acidic reagent and an olefin having an average of from 14 to 30 carbon atoms. The polyamine has at least three nitrogen atoms and 4 to 20 carbon atoms. The mixture contains from 1.5 to 10 equivalents of the alkenyl or alkylsuccinic acid derivative per equivalent of unsaturated acidic reagent copolymer and from 0.4 to 1.0 moles of polyamine per equivalent of alkenyl or alkylsuccinic acid derivative plus unsaturated acidic reagent copolymer.
Type:
Grant
Filed:
April 9, 1996
Date of Patent:
February 10, 1998
Assignee:
Chevron Chemical Company
Inventors:
James J. Harrison, William R. Ruhe, Jr.
Abstract: Disclosed are a lubricating oil composition for a diesel engine having a decreased ash content which can exert excellent engine detergency and deposit-resistant properties without impairing the performance of an exhaust gas post-treatment device such as a particulate exhaust matter trap or an oxidation catalyst, and a method for the lubrication of the diesel engine which comprises using this lubricating oil composition.The present invention provides a lubricating oil composition for a diesel engine which is obtained by blending a lubricant base oil with (A) 5 to 20% by weight of a boron-containing ashless dispersant and (B) 0.01 to 30% by weight of metal-type detergents having a total base number of 0 to 200 mg KOH/g, based on the total weight of the composition, a sulfated ash content in the composition being 1.0% by weight or less, a boron content being 0.
Abstract: A lubricating oil composition having improved fuel economy and fuel economy retention property which comprises a lubricating oil basestock, a boron containing alkenyl succinimide, molybdenum, di-thiocarbamate and/or molybdenum dithiophosphate, calcium and magnesium salicylate, and ethylene copolymer.
Abstract: This invention provides a composition and method for producing partial synthetic automatic transmission fluids having improved shear-stability and low temperature properties without the need to incorporate polymeric viscosity modifiers.
Type:
Grant
Filed:
July 17, 1995
Date of Patent:
July 8, 1997
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Raymond Frederick Watts, Ricardo Alfredo Bloch
Abstract: This invention provides compositions and methods for producing partial synthetic automatic transmission fluids capable of improved viscometric properties and capable of achieving -40.degree. C. Brookfield viscosities not greater than 15,000 centipoise.
Type:
Grant
Filed:
July 17, 1995
Date of Patent:
June 24, 1997
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Ricardo Altredo Bloch, Christopher William Cornish, Raymond Frederick Watts
Abstract: This invention provides compositions and methods for producing partial synthetic automatic transmission fluids capable of improved viscometric properties and capable of achieving -40.degree. C. Brookfield viscosities not greater than 15,000 centipoise.
Type:
Grant
Filed:
September 1, 1995
Date of Patent:
June 24, 1997
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Ricardo Alfredo Bloch, Christopher William Cornish, Raymond Frederick Watts
Abstract: Oil-soluble dispersant additives are disclosed. The additives comprise the reaction product of a functionalized 1-butene copolymer and at least one nucleophilic reactant selected from amines, amino alcohols, alcohols, and reactive metal compounds. The functionalized copolymer has within its structure at least one acyl functional group selected from the group consisting of C.sub.4 to C.sub.10 dicarboxylic acids and derivatives thereof and C.sub.3 to C.sub.10 monocarboxylic acids and derivatives thereof. The 1-butene copolymer is derived from 1-butene and at least one other .alpha.-olefin of formula CH.sub.2 .dbd.CHR', wherein R' is methyl or a C.sub.3 to C.sub.12 linear or branched alkyl group. The copolymer has a number average molecular weight of at least about 700, a molecular weight distribution of less than 5, and ethenylidene groups terminating at least about 30% of all polymer chains.
Type:
Grant
Filed:
June 9, 1994
Date of Patent:
June 17, 1997
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Albert Rossi, Jacob I. Emert, Warren A. Thaler
Abstract: A lubricating oil composition having improved fuel economy, wear resistance and antioxidancy properties which comprise a lubricating oil basestock, an oil-soluble copper salt, an oil-soluble molybdenum salt, a Group II metal salicylate and a borated polyalkenyl succinimide.
Abstract: An engine oil composition which comprises a metal-containing detergent, zinc dithiophosphate, and a boron-containing ashless dispersant dissolved or dispersed in a base oil; characterized by further containing an antiwear agent having an aliphatic amide compound and either a dithiocarbamate compound or an ester derived from a fatty acid and boric acid.
Abstract: Multifunctional additives having a variety of advantageous properties are described. They are formed by a process which comprises heating concurrently or in any sequence a) an oil-soluble ashless dispersant containing basic nitrogen with b) an alkoxylated alcohol of at least 8 carbon atoms c) a borating agent and optionally d) an inorganic oxyacid or anhydride of phosphorous. The reactants are in proportions on an active ingredient basis of about 0.03 to about 0.35 part by weight of b) per part by weight of a), and about 0.005 to about 0.06 part by weight of boron as c) per part by weight of a). The reaction temperature can range from about 50.degree. to about 150.degree. C. Water and/or solids present in the resultant mixture can be removed. Preferably, the optional phosphorous component is used in the formation of these additives. This phosphorous component can be an inorganic oxyacid or anhydride of phosphorous.
Type:
Grant
Filed:
March 27, 1996
Date of Patent:
March 18, 1997
Assignee:
Ethyl Corporation
Inventors:
Donald R. Bell, Rolfe J. Hartley, Andrew G. Papay
Abstract: This invention describes nitrogen containing compounds which are boronated in the presence of a protic material such as water or an alcohol or mixtures thereof.
Abstract: A "cold-clash" gear problem associated with vehicular manual transmissions exposed to the cold is overcome by use of a special all-synthetic gear oil composition. The composition is composed of base oil and specified additive components. The base oil is a blend of dialkyl ester of an aliphatic dicarboxylic acid having a maximum pour point of about -55.degree. C. and a maximum kinematic viscosity at 100.degree. C. of about 4 cSt, and three hydrogenated poly-.alpha.-olefin oligomers having kinematic viscosities at 100.degree. C. of about 40, about 4-8 cSt and about 2 cSt in specified proportions. The additive components comprise an organic sulfur-containing antiwear and/or extreme pressure agent, an organic phosphorus-containing antiwear and/or extreme pressure agent, a copper corrosion inhibitor, a rust inhibitor, a foam inhibitor, and an ashless dispersant. The gear oil has a boron content of about 0.0025 to about 0.07 wt %.
Abstract: An engine oil composition having a base oil, an ashless dispersant, a metal-containing detergent, zinc dithiophosphate and a sulfur-containing phenol derivative. Examples of sulfur-containing phenol derivative include 2,4-bis{(octylthio)methyl}-o-cresol, 2,2-thiodiethylenebis{3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate}, and tridecyl 2-(3,5-di-ti-butyl-4-hydroxybenzylthio)acetate.
Abstract: A biodegradable two-cycle oil composition which comprises a C.sub.13 oxo alcohol adipate in admixture with a dispersant and a lubricity agent; it is especially useful for outboard marine engines.
Type:
Grant
Filed:
June 28, 1995
Date of Patent:
October 8, 1996
Assignee:
Exxon Chemical Patents Inc
Inventors:
George M. Tiffany, III, Beth A. Morgan, George C. L'Heureux, Lewis H. Gaines, William H. Stover