Sulfur Or Halogen Bonded Indirectly To Boron Patents (Class 508/197)
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Patent number: 7851418Abstract: The present invention is directed to ashless detergents comprising the products resulting from the reaction of a salicylic acid, organic group substituted salicylic acid, sulfonic acid or organic groups substituted sulfur acid with thiadiazole or organic group substituted thiadiazole or an alkyl primary or secondary amine, and to formulated lubricating oils containing said ashless detergents.Type: GrantFiled: June 1, 2006Date of Patent: December 14, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob Joseph Habeeb, William H. Buck, Douglas Edward Deckman, William L. Maxwell
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Patent number: 7026273Abstract: A crankcase lubricating oil composition comprises an oil of lubricating viscosity, in a major amount, and, in respective minor amounts, a boron-containing additive and one or more co-additives, wherein the lubricating oil composition has greater than 200 ppm by mass of boron, less than 600 ppm by mass of phosphorus and less than 4000 ppm by mass of sulfur, based on the mass of the oil composition. Such compositions demonstrate provide improved wear performance.Type: GrantFiled: October 22, 2002Date of Patent: April 11, 2006Assignee: Infineum International LimitedInventors: Robert Robson, Roger W. Glyde, Alisdair J. Brown, Simon S. M. Chung, Stephen Arrowsmith
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Patent number: 6903055Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X?O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.Type: GrantFiled: January 23, 2001Date of Patent: June 7, 2005Assignee: Cognis Performance Chemicals UK LimitedInventors: Simon Lawford, John Robert Moxey, Andrew Small
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Publication number: 20030153470Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X=O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.Type: ApplicationFiled: October 28, 2002Publication date: August 14, 2003Inventors: Simon Lawford, John Robert Moxey, Andrew Small
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Publication number: 20030013623Abstract: Oil soluble viscosity index improver composition comprising a mixture of: (A) at least one molecular weight degraded copolymer of ethylene and at least one other alpha-olefin monomer; and (B) at least one substantially undegraded copolymer of ethylene and at least one other alpha-olefin monomer. The ethylene alpha-olefin copolymers before degradation can be polymerized by a variety of available technologies including Ziegler-Natta, metallocene and diimine catalysis, as well as batch, continuous stirred tank and tubular reactors to produce copolymers having both broad or narrow molecular weight and compositional distributions. Use of degraded/non-degraded copolymer mixtures facilitates the preparation of viscosity index improvers for oils having targeted levels of shear stability index.Type: ApplicationFiled: May 1, 2001Publication date: January 16, 2003Inventors: Kwok-Leung Tse, Stuart Briggs
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Publication number: 20010003734Abstract: A marine diesel engine lubricant composition having a TBN of at least 10 and preferably a VI of at least 90, comprises a major amount of oil of lubricating viscosity, and admixed therewith, minor amounts of an ashless antiwear additive and a metal detergent in the form ofType: ApplicationFiled: December 15, 2000Publication date: June 14, 2001Applicant: Infineum USA L.P.Inventor: Adrian Dunn
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Patent number: 6124247Abstract: The invention relates to the use of an effective quantity of borated compounds having the following general formula I: ##STR1## in which X is S or O, and R is a hydrocarbyl group containing at least 3 carbon atoms, in particular between 3 and 50 carbon atoms and preferably between 3 and 17 carbon atoms, as an additive improving the compatibility of a lubricating oil composition, comprising dispersants containing basic nitrogen atoms, with fluorocarbon elastomers. In a preferred fashion, the compound of general formula I is borated glycerol monooleate and the concentration of the compound of general formula I is such that the % Boron/% basic N ratio of the lubricating composition varies from 0.25 to 5.Type: GrantFiled: September 2, 1999Date of Patent: September 26, 2000Assignee: Chevron Chemical S.A.Inventors: Jacques Cazin, Pierre Tequi, William M. Kleiser, Peter Kleijwegt
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Patent number: 5962380Abstract: The use of an effective amount of a compound as an additive improving the compatibility of a lubricating oil formulation having dispersants containing basic nitrogen atoms, with fluorocarbon elastomer seals. That compound has the formula: ##STR1## wherein R and R.sup.1 are independently alkoxycarbonyl, alkenyloxycarbonyl, aryloxycarbonyl, alkylcarbonyl, alkenylcarbonyl, arylcarbonyl, or arylalkyl, or together form a carbocycle, and R.sup.2 and R.sup.3 are independently sulfurized alkyl, alkoxycarbonylalkyl, arylalkyl, or borated hydroxyalkyl, with the proviso that R, R.sup.1, R.sup.2 and R.sup.3 together contain sufficient carbon atoms to render the compound oil soluble in an oil of lubricating viscosity.Type: GrantFiled: July 16, 1997Date of Patent: October 5, 1999Assignee: Chevron Chemical Company LLCInventors: Pierre Tequi, Jacques Cazin, Andrew W. Ho
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Patent number: 5885943Abstract: Sulfur-containing boroester compounds useful as antiwear additives for oleaginous compositions including alicyclic borate thioesters having the general formula (I): ##STR1## wherein R.sub.1 is a hydrocarbyl radical having 4 to 12 carbon atoms, R.sub.2 and R.sub.3 are independently selected from --(OR.sub.4).sub.n SR.sub.1 and --(OR.sub.4).sub.n SR.sub.1 OH; R.sub.4 is a hydrocarbyl radical having 1 to 6 carbon atoms; n is an integer of from 1 to 4; and l and m are independently 0, 1 or 2; thioalkyl-substituted cyclic meta borate esters having the general formula (II): ##STR2## wherein n, R.sub.1 and R.sub.4 are defined as in formula (I); and mixtures of the alicyclic compounds of formula (I) and the cyclic compounds of formula (II).Type: GrantFiled: December 18, 1997Date of Patent: March 23, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Raymond F Watts, Ricardo A. Bloch, Jack Ryer, deceased, Roger K. Nibert, James S. Puckace