Sulfur Or Halogen Bonded Indirectly To Boron Patents (Class 508/197)
  • Patent number: 7851418
    Abstract: The present invention is directed to ashless detergents comprising the products resulting from the reaction of a salicylic acid, organic group substituted salicylic acid, sulfonic acid or organic groups substituted sulfur acid with thiadiazole or organic group substituted thiadiazole or an alkyl primary or secondary amine, and to formulated lubricating oils containing said ashless detergents.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: December 14, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jacob Joseph Habeeb, William H. Buck, Douglas Edward Deckman, William L. Maxwell
  • Patent number: 7026273
    Abstract: A crankcase lubricating oil composition comprises an oil of lubricating viscosity, in a major amount, and, in respective minor amounts, a boron-containing additive and one or more co-additives, wherein the lubricating oil composition has greater than 200 ppm by mass of boron, less than 600 ppm by mass of phosphorus and less than 4000 ppm by mass of sulfur, based on the mass of the oil composition. Such compositions demonstrate provide improved wear performance.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: April 11, 2006
    Assignee: Infineum International Limited
    Inventors: Robert Robson, Roger W. Glyde, Alisdair J. Brown, Simon S. M. Chung, Stephen Arrowsmith
  • Patent number: 6903055
    Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X?O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: June 7, 2005
    Assignee: Cognis Performance Chemicals UK Limited
    Inventors: Simon Lawford, John Robert Moxey, Andrew Small
  • Publication number: 20030153470
    Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X=O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.
    Type: Application
    Filed: October 28, 2002
    Publication date: August 14, 2003
    Inventors: Simon Lawford, John Robert Moxey, Andrew Small
  • Publication number: 20030013623
    Abstract: Oil soluble viscosity index improver composition comprising a mixture of: (A) at least one molecular weight degraded copolymer of ethylene and at least one other alpha-olefin monomer; and (B) at least one substantially undegraded copolymer of ethylene and at least one other alpha-olefin monomer. The ethylene alpha-olefin copolymers before degradation can be polymerized by a variety of available technologies including Ziegler-Natta, metallocene and diimine catalysis, as well as batch, continuous stirred tank and tubular reactors to produce copolymers having both broad or narrow molecular weight and compositional distributions. Use of degraded/non-degraded copolymer mixtures facilitates the preparation of viscosity index improvers for oils having targeted levels of shear stability index.
    Type: Application
    Filed: May 1, 2001
    Publication date: January 16, 2003
    Inventors: Kwok-Leung Tse, Stuart Briggs
  • Publication number: 20010003734
    Abstract: A marine diesel engine lubricant composition having a TBN of at least 10 and preferably a VI of at least 90, comprises a major amount of oil of lubricating viscosity, and admixed therewith, minor amounts of an ashless antiwear additive and a metal detergent in the form of
    Type: Application
    Filed: December 15, 2000
    Publication date: June 14, 2001
    Applicant: Infineum USA L.P.
    Inventor: Adrian Dunn
  • Patent number: 6124247
    Abstract: The invention relates to the use of an effective quantity of borated compounds having the following general formula I: ##STR1## in which X is S or O, and R is a hydrocarbyl group containing at least 3 carbon atoms, in particular between 3 and 50 carbon atoms and preferably between 3 and 17 carbon atoms, as an additive improving the compatibility of a lubricating oil composition, comprising dispersants containing basic nitrogen atoms, with fluorocarbon elastomers. In a preferred fashion, the compound of general formula I is borated glycerol monooleate and the concentration of the compound of general formula I is such that the % Boron/% basic N ratio of the lubricating composition varies from 0.25 to 5.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: September 26, 2000
    Assignee: Chevron Chemical S.A.
    Inventors: Jacques Cazin, Pierre Tequi, William M. Kleiser, Peter Kleijwegt
  • Patent number: 5962380
    Abstract: The use of an effective amount of a compound as an additive improving the compatibility of a lubricating oil formulation having dispersants containing basic nitrogen atoms, with fluorocarbon elastomer seals. That compound has the formula: ##STR1## wherein R and R.sup.1 are independently alkoxycarbonyl, alkenyloxycarbonyl, aryloxycarbonyl, alkylcarbonyl, alkenylcarbonyl, arylcarbonyl, or arylalkyl, or together form a carbocycle, and R.sup.2 and R.sup.3 are independently sulfurized alkyl, alkoxycarbonylalkyl, arylalkyl, or borated hydroxyalkyl, with the proviso that R, R.sup.1, R.sup.2 and R.sup.3 together contain sufficient carbon atoms to render the compound oil soluble in an oil of lubricating viscosity.
    Type: Grant
    Filed: July 16, 1997
    Date of Patent: October 5, 1999
    Assignee: Chevron Chemical Company LLC
    Inventors: Pierre Tequi, Jacques Cazin, Andrew W. Ho
  • Patent number: 5885943
    Abstract: Sulfur-containing boroester compounds useful as antiwear additives for oleaginous compositions including alicyclic borate thioesters having the general formula (I): ##STR1## wherein R.sub.1 is a hydrocarbyl radical having 4 to 12 carbon atoms, R.sub.2 and R.sub.3 are independently selected from --(OR.sub.4).sub.n SR.sub.1 and --(OR.sub.4).sub.n SR.sub.1 OH; R.sub.4 is a hydrocarbyl radical having 1 to 6 carbon atoms; n is an integer of from 1 to 4; and l and m are independently 0, 1 or 2; thioalkyl-substituted cyclic meta borate esters having the general formula (II): ##STR2## wherein n, R.sub.1 and R.sub.4 are defined as in formula (I); and mixtures of the alicyclic compounds of formula (I) and the cyclic compounds of formula (II).
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: March 23, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Raymond F Watts, Ricardo A. Bloch, Jack Ryer, deceased, Roger K. Nibert, James S. Puckace