Chalcogen Or Nitrogen Attached To The Hetero Ring Directly Or Indirectly By Acyclic Nonionic Bonding (e.g., Methylene Bis-benzotriazoles, Etc.) Patents (Class 508/281)
-
Patent number: 10612313Abstract: Embodiments relate to a polycrystalline diamond compact (“PDC”) including a polycrystalline diamond (“PCD”) table bonded to a cemented carbide substrate including tungsten carbide grains having a fine average grain size to provide one or more of enhanced wear resistance, corrosion resistance, or erosion resistance, and a PDC with enhanced impact resistance. In an embodiment, a PDC includes a cemented carbide substrate having a cobalt-containing cementing constituent cementing tungsten carbide grains together exhibiting an average grain size of about 1.5 ?m or less. The substrate includes an interfacial surface and a depletion zone depleted of the cementing constituent that extends inwardly from the interfacial surface to a depth of, for example, about 30 ?m to about 60 ?m. The PDC includes a PCD table bonded to the interfacial surface of the substrate. The PCD table includes diamond grains bonded together exhibiting an average grain size of about 40 ?m or less.Type: GrantFiled: July 13, 2017Date of Patent: April 7, 2020Assignee: US SYNTHETIC CORPORATIONInventor: Debkumar Mukhopadhyay
-
Patent number: 9994531Abstract: An antioxidant composition which comprises: (a) methylenebis(di-n-butyldithiocarbamate); and (b) an alkylated diphenylamine derivative of triazole wherein the alkyl group on at least one of the phenyl groups is C8 or higher. Lubricating compositions containing the antioxidant composition are also contemplated.Type: GrantFiled: August 2, 2016Date of Patent: June 12, 2018Assignee: VANDERBILT CHEMICALS, LLCInventor: Vincent J. Gatto
-
Patent number: 9783759Abstract: A lubricating composition comprising at least 90% by weight of a base oil, and an antioxidant composition comprising the components, set forth as weight % of the lubricating composition: (1) solid alkylated-phenyl-alpha-naphthylamine at 0.01-0.3%, (2) an alkylated diphenylamine derivative of triazole, tolutriazole or benzotriazole, at 0.01-0.3%, and (3) methylenebis(di-n-butyldithiocarbamate), at 0.01-0.4%.Type: GrantFiled: August 14, 2015Date of Patent: October 10, 2017Assignee: VANDERBILT CHEMICALS, LLCInventors: Junbing Yao, Vincent Gatto
-
Patent number: 9732563Abstract: Embodiments relate to a polycrystalline diamond compact (“PDC”) including a polycrystalline diamond (“PCD”) table bonded to a cemented carbide substrate including tungsten carbide grains having a fine average grain size to provide one or more of enhanced wear resistance, corrosion resistance, or erosion resistance, and a PDC with enhanced impact resistance. In an embodiment, a PDC includes a cemented carbide substrate having a cobalt-containing cementing constituent cementing tungsten carbide grains together exhibiting an average grain size of about 1.5 ?m or less. The substrate includes an interfacial surface and a depletion zone depleted of the cementing constituent that extends inwardly from the interfacial surface to a depth of, for example, about 30 ?m to about 60 ?m. The PDC includes a PCD table bonded to the interfacial surface of the substrate. The PCD table includes diamond grains bonded together exhibiting an average grain size of about 40 ?m or less.Type: GrantFiled: July 30, 2013Date of Patent: August 15, 2017Assignee: US SYNTHETIC CORPORATIONInventor: Debkumar Mukhopadhyay
-
Patent number: 8889606Abstract: 1-[Di(4-octylphenyl)aminomethyl]tolutriazole is prepared in a mineral oil wherein the reaction also contains between 0.1 and 5% by weight of a polyacrylate polymer dissolved in a mineral oil. The liquid product shows increased storage stability with respect to crystallization of the 1-[di(4-octylphenyl)aminomethyl]tolutriazole when the polyacrylate polymer is added during the reaction to prepare the 1-[Di(4-octylphenyl)aminomethyl]tolutriazole. This product can be utilized in a lubricant composition as an antioxidant and corrosion inhibitor.Type: GrantFiled: October 11, 2012Date of Patent: November 18, 2014Assignee: Vanderbilt Chemicals, LLCInventors: Kevin J. Chase, William T. Wallack
-
Publication number: 20140162918Abstract: Provided is a micropitting corrosion resistant industrial gear lubricant composition, comprising: (A) at least a highly refined mineral oil, or synthetic oil or any combination of the above components; (B) at least a micropitting corrosion resistant additive; (C) at least an anti-wear additive; (D) at least a metal passivation additive; and (E) at least an anti-oxidation additive. The lubricant composition has excellent high and low temperature performance and meets 68, 100, 150, 220, 320, 460 and 680 industrial gear oil viscosity level requirement. The lubricant composition has excellent micropitting corrosion resistance, anti-wear performance and anti-oxidation performance, passes FVA 54 micropitting corrosion resistant test, FAG FE-8 bearing wear test and SKF EMCOR bearing corrosion test, and is suitable for many large-scale industrial transmission gears and some automobile transmission gears, especially suitable for a gear transmission system for wind power generation.Type: ApplicationFiled: May 4, 2012Publication date: June 12, 2014Inventors: Xisheng Fu, Xiuling Hua, Jie Zhang
-
Publication number: 20140162919Abstract: Provided is a lubricant composition for a full transmission system, comprising: (A) at least an ashless dispersant; (B) at least a friction modifier; (C) at least a phosphorus-containing antiwear agent; (D) at least an antirust additive; (E) at least a sulfur-containing extreme-pressure additive; (F) at least a metal deactivation additive; (G) at least a viscosity index improver; (H) at least a pour-point depressant; and (I) at least a highly refined mineral oil with high viscosity index, or polyolefin synthetic oil, or ester synthetic oil, or any combination of the above components. The lubricant composition has excellent cleaning dispersity, frictional characteristic, antirust and anti-corrosive properties and extreme pressure abrasion resistance, meets US force standard MIL-PRF-2105E, and can be used for lubrication in various vehicle transmission systems.Type: ApplicationFiled: May 4, 2012Publication date: June 12, 2014Applicant: PETROCHINA COMPANY LIMITEDInventors: Xisheng Fu, Liping Mi, Jing Xu
-
Patent number: 8722592Abstract: A method using one or more of certain triazoles in an amount effective to reduce cobalt leaching during a metal working process from a metal working tool comprising cobalt, such as tungsten carbide particles bonded by cobalt, wherein the one or more triazoles comprise at least butyl-benzotriazole, and optionally one or more other benzotriazoles. Also, a composition is provided which comprises a metal working fluid and one or more of these triazoles in an amount effective to reduce cobalt leaching from metal working tools comprising cobalt, such as tungsten carbide particles bonded by cobalt.Type: GrantFiled: July 25, 2008Date of Patent: May 13, 2014Assignee: Wincom, Inc.Inventors: William N. Matulewicz, Peter F. Vogt, Thomas J. Bobinger
-
Patent number: 8703873Abstract: The composition and preparation of multifunctional graft polymers useful as dispersants are described. The dispersants described are suitable for controlling sludge and varnish as well as soot, friction and wear. The product is useful as a lubricant additive.Type: GrantFiled: March 29, 2011Date of Patent: April 22, 2014Assignee: Castrol LimitedInventor: Richard P. Sauer
-
Publication number: 20140018268Abstract: The present invention relates to a lubricating composition containing (a) an oil of lubricating viscosity; and (b) a compound selected from the group consisting of: (i) an ester-containing heterocycle; (ii) an amide-containing heterocycle; and (iii) a pyrimidine, wherein the ester-containing heterocycle and the amide-containing heterocycle have a hydrocarbyl group containing 6 to 40 carbon atoms. The invention further provides for a method of supplying an internal combustion engine with the lubricating composition.Type: ApplicationFiled: September 19, 2013Publication date: January 16, 2014Inventors: Patrick E. Mosier, Jason R. Brown, Matthew D. Gieselman, Calvin W. Schroeck, Seth L. Crawley, William R. S. Barton, William C. Ward, JR.
-
Publication number: 20130143405Abstract: A silicon-wafer processing fluid used for processing a silicon wafer contains a friction modifier containing a nitrogen-containing compound, pH of the nitrogen-containing compound being in a range from 2 to 8 when a mass ratio with water (i.e. nitrogen-containing compound/water) is 1/99. The nitrogen-containing compound is preferably a heterocyclic compound. The silicon-wafer processing fluid restrains an abrasion of abrasive grains rigidly attached to a wire and generation of hydrogen.Type: ApplicationFiled: August 23, 2011Publication date: June 6, 2013Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Tomohiko Kitamura
-
Publication number: 20130123156Abstract: 1-[Di(4-octylphenyl)aminomethyl]tolutriazole is prepared in a mineral oil wherein the reaction also contains between 0.1 and 5% by weight of a polyacrylate polymer dissolved in a mineral oil. The liquid product shows increased storage stability with respect to crystallization of the 1-[di(4-octylphenyl)aminomethyl]tolutriazole when the polyacrylate polymer is added during the reaction to prepare the 1-[Di(4-octylphenyl)aminomethyl]tolutriazole.Type: ApplicationFiled: October 11, 2012Publication date: May 16, 2013Applicant: R.T. VANDERBILT COMPANY, INC.Inventor: R.T. VANDERBILT COMPANY, INC.
-
Patent number: 8367591Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.Type: GrantFiled: October 19, 2007Date of Patent: February 5, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventor: Hideki Kamano
-
Publication number: 20110212864Abstract: The invention relates to novel (benzo)triazole compositions comprising mixtures of benzotriazoles and N-substituted benzotriazoles in functional liquids, e.g. mineral oil. The mixtures can be prepared from readily obtainable starting materials, such as tolutriazole (TTA), alkyl aldehydes and cycloalkanols. The invention furthermore relates to a process for protecting metals, which are in contact with functional liquids comprising the mixtures.Type: ApplicationFiled: February 2, 2011Publication date: September 1, 2011Inventors: Isabelle RAPENNE-JACOB, Samuel EVANS, Peter ROHRBACH, Martin VON BÜREN
-
Publication number: 20100029520Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.Type: ApplicationFiled: October 19, 2007Publication date: February 4, 2010Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Hideki Kamano
-
Publication number: 20100022424Abstract: A method using one or more of certain triazoles in an amount effective to reduce cobalt leaching during a metal working process from a metal working tool comprising cobalt, such as tungsten carbide particles bonded by cobalt, wherein the one or more triazoles comprise at least butyl-benzotriazole, and optionally one or more other benzotriazoles. Also, a composition is provided which comprises a metal working fluid and one or more of these triazoles in an amount effective to reduce cobalt leaching from metal working tools comprising cobalt, such as tungsten carbide particles bonded by cobalt.Type: ApplicationFiled: July 25, 2008Publication date: January 28, 2010Applicant: Wincom, Inc.Inventors: Peter F. Vogt, William N. Matulewicz, Thomas J. Bobinger
-
Publication number: 20090137435Abstract: Electrical oil formulation comprising a base oil component and an additive, wherein (i) at least 80 wt % of the base oil component is a paraffin base oil having a paraffin content of greater than 80 wt % paraffins and a saturates content of greater than 98 wt % and comprising a series of iso-paraffins having n, n+1, n+2, n+3 and n+4 carbon atoms and wherein n is between 20 and 35; and (ii) an anti-oxidant additive; wherein the base oil component has a flash point of at least 170° C., as determined by ISO 2592.Type: ApplicationFiled: June 22, 2006Publication date: May 28, 2009Inventors: Andree Hilker, Volker Klaus Null
-
Publication number: 20090105102Abstract: The invention relates to novel (benzo)triazole compositions comprising mixtures of benzotriazoles and N-substituted benzotriazoles in functional liquids, e.g. mineral oil. The mixtures can be prepared from readily obtainable starting materials, such as tolutriazole (TTA), alkyl aldehydes and cycloalkanols. The invention furthermore relates to a process for protecting metals, which are in contact with functional liquids comprising the mixtures.Type: ApplicationFiled: November 14, 2005Publication date: April 23, 2009Inventors: Isabelle Rapenne-Jacob, Samuel Evans, Peter Rohrbach, Martin Von Buren
-
Patent number: 6946429Abstract: A bearing for an electronically controlled throttle motor in an automobile filled with a grease composition with a kinetic viscosity between 40 and 150 mm2/sec (at 40° C.) containing (a) a straight-chain perfluoropolyether oil with a kinetic viscosity less than 25 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 25 and 45), (b) a base oil containing a straight-chain perfluoropolyether oil with a kinetic viscosity greater than 250 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 80 and 200) and (c) a polytetrafluoroethylene filler.Type: GrantFiled: April 7, 2003Date of Patent: September 20, 2005Assignee: Minebea Co., Ltd.Inventor: Motoharu Akiyama
-
Patent number: 6800595Abstract: A grease composition having a base oil and a thickener, which grease additionally has from 0.05% to 30% by weight of sodium thiosulphate and at least 0.1% by weight of one or more additives selected from the group of: calcium salicylate, magnesium salicylate, calcium phenate, and calcium sulphonate, based on the total grease composition, and use of the grease composition to improve rust prevention and abrasion resistance. The invention also relates to a method for preparing the grease composition.Type: GrantFiled: February 10, 2003Date of Patent: October 5, 2004Assignee: Shell Oil CompanyInventors: Takahiro Ozaki, Noriaki Shinoda, Kouichi Nakazawa
-
Publication number: 20040147411Abstract: A synthetic ester comprising a reaction product of: (a) a polyol corresponding to formula I: 1Type: ApplicationFiled: March 12, 2004Publication date: July 29, 2004Inventors: Frank Bongardt, Ralf Christoph
-
Patent number: 6743759Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.Type: GrantFiled: November 19, 2002Date of Patent: June 1, 2004Assignee: R.T. Vanderbilt Company, Inc.Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
-
Patent number: 6669872Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.Type: GrantFiled: July 13, 2001Date of Patent: December 30, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
-
Publication number: 20030195125Abstract: A bearing for an electronically controlled throttle motor in an automobile filled with a grease composition with a kinetic viscosity between 40 and 150 mm2/sec (at 40° C.) containing (a) a straight-chain perfluoropolyether oil with a kinetic viscosity less than 25 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 25 and 45), (b) a base oil containing a straight-chain perfluoropolyether oil with a kinetic viscosity greater than 250 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 80 and 200) and (c) a polytetrafluoroethylene filler.Type: ApplicationFiled: April 7, 2003Publication date: October 16, 2003Inventor: Motoharu Akiyama
-
Publication number: 20030176295Abstract: A grease composition comprising a base oil and a thickener, which grease additionally comprises from 0.05% to 30% by weight of sodium thiosulphate and at least 0.1% by weight of one or more additives (A) selected from the group comprising calcium salicylate, magnesium salicylate, calcium phenate and/or calcium sulphonate, based on the total grease composition; use of said grease composition to improve rust prevention and abrasion resistance, and a method for preparing said grease composition.Type: ApplicationFiled: February 10, 2003Publication date: September 18, 2003Inventors: Takahiro Ozaki, Noriaki Shinoda, Kouichi Nakazawa
-
Publication number: 20030134753Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.Type: ApplicationFiled: November 19, 2002Publication date: July 17, 2003Applicant: R.T. Vanderbilt Company, Inc.Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
-
Patent number: 6410490Abstract: The instant invention relates to a lubricant composition stabilized against the deleterious effects of heat and oxygen. The composition comprises a hydrotreated or hydrodewaxed oil and an effective antioxidant stabilizing amount of a mixture of a phenolic antioxidant; an N,N-disubstituted aminomethyl-1,2,4-triazole; an aromatic amine antioxidant; an alkyl phenoxy alkanoic acid; and an N-acyl sarcosine derivative. Optionally, further additives are added to the subject lubricant compositions.Type: GrantFiled: May 18, 2000Date of Patent: June 25, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Jose L. Reyes-Gavilan, Frederick T. Lichtenberg, Adesola O. Oshode, Miles J. Hutchings, Peter Collen Hamblin, Michael Fletschinger, Peter Rohrbach
-
Patent number: 6315920Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.Type: GrantFiled: September 10, 1999Date of Patent: November 13, 2001Assignee: Exxon Research and Engineering CompanyInventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
-
Patent number: 6214776Abstract: An oil composition useful as a high stress electrical oil and especially as a transformer load tap changer oil is provided. The composition comprises a major amount of a paraffinic oil having a low viscosity of less than about 20 cSt @ 40° C. and an effective amount of an additive system including at least one hindered phenolic antioxidant and a benzotriazole metal deactivator.Type: GrantFiled: May 21, 1999Date of Patent: April 10, 2001Assignee: Exxon Research and Engineering CompanyInventors: Jacob B. Angelo, Christopher Jeffrey Still Kent, Frederick Michael Gragg
-
Patent number: 6207623Abstract: A lubricating oil formulation containing a major amount of a base oil of lubricating viscosity and a minor amount of additives comprising a combination of phenyl naphthyl amine, dimercaptothiadiazole or derivative thereof, and triazole or benzotriazole or derivative thereof, exhibiting enhanced resistance to oxidation.Type: GrantFiled: January 14, 2000Date of Patent: March 27, 2001Assignee: ExxonMobil Research and Engineering CompanyInventors: Kevin David Butler, Alison Fiona Miller, Todd Timothy Nadasdi
-
Patent number: 6083889Abstract: An oil composition useful as an electrical or transformer oil is provided. The composition comprises a major amount of a paraffinic oil having a Cleveland open cup flash point of more than about 200.degree. C. and an effective amount of an additive system including at least one hindered phenolic antioxidant and a tolyltriazole metal deactivator.Type: GrantFiled: February 5, 1999Date of Patent: July 4, 2000Assignee: Exxon Research and Engineering CompanyInventors: Jacob Ben Angelo, Christopher Jeffrey Still Kent
-
Patent number: 5714442Abstract: A description is given of compounds of the formula I, and mixtures thereof, ##STR1## (I), in which Y and Z independently of one another are a radical of the formula ##STR2## (III) R and R.sub.1 independently of one another are hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl or C.sub.1 -C.sub.4 alkyl-substituted phenyl,R.sub.2 is C.sub.2 -C.sub.20 alkylene, C.sub.5 -C.sub.8 cycloalkylene, a radical of the formula ##STR3## The compounds/mixtures are particularly suitable as metal deactivators for use in lubricants.Type: GrantFiled: April 8, 1996Date of Patent: February 3, 1998Assignee: Ciba Speciality Chemicals CorporationInventor: Jean-Pierre Wolf
-
Patent number: 5580482Abstract: The instant invention relates to a lubricant composition stabilized against the deleterious effects of heat and oxygen. The composition comprises a triglyceride oil or an oil which is an ester wherein unsaturation is present in either the alcohol moiety or the acid moiety and an effective stabilizing amount of either an N,N-disubstituted aminomethyl-1,2,4-triazole or an N,N-disubstituted aminomethylbenzotriazole; a higher alkyl substituted amide of dodecylene succinic acid; a phenolic antioxidant; and an aromatic amine antioxidant. Further additives can be added to these lubricant formulations.Type: GrantFiled: January 13, 1995Date of Patent: December 3, 1996Assignee: Ciba-Geigy CorporationInventors: David E. Chasan, Patricia R. Wilson
-
Patent number: 5560854Abstract: A working fluid composition for a compression type refrigerator, comprising:(A) a refrigerant composed of ammonia or at least one hydrofluorocarbon having the number of carbon being not more than 2 and containing no chlorine; and(B) a lubricant for the refrigerator, said lubricant comprising 100 parts by weight of a synthetic oil and 0.5 to 10.0 parts by weight of at least one benzotriazole derivative expressed by the following formula (I). ##STR1## in which R.sup.1 is hydrogen or an alkyl group having the number of carbons being 1-10, and R.sup.2 and R.sup.3 independently indicate an alkyl group having the number of carbons being 4-18.Type: GrantFiled: June 6, 1995Date of Patent: October 1, 1996Assignees: Nissan Motor Co., Ltd., Japan Energy CorporationInventors: Takashi Kaimai, Hiroki Tawaki, Sumio Yokoo