Chalcogen Or Nitrogen Attached To The Hetero Ring Directly Or Indirectly By Acyclic Nonionic Bonding (e.g., Methylene Bis-benzotriazoles, Etc.) Patents (Class 508/281)
  • Patent number: 10612313
    Abstract: Embodiments relate to a polycrystalline diamond compact (“PDC”) including a polycrystalline diamond (“PCD”) table bonded to a cemented carbide substrate including tungsten carbide grains having a fine average grain size to provide one or more of enhanced wear resistance, corrosion resistance, or erosion resistance, and a PDC with enhanced impact resistance. In an embodiment, a PDC includes a cemented carbide substrate having a cobalt-containing cementing constituent cementing tungsten carbide grains together exhibiting an average grain size of about 1.5 ?m or less. The substrate includes an interfacial surface and a depletion zone depleted of the cementing constituent that extends inwardly from the interfacial surface to a depth of, for example, about 30 ?m to about 60 ?m. The PDC includes a PCD table bonded to the interfacial surface of the substrate. The PCD table includes diamond grains bonded together exhibiting an average grain size of about 40 ?m or less.
    Type: Grant
    Filed: July 13, 2017
    Date of Patent: April 7, 2020
    Assignee: US SYNTHETIC CORPORATION
    Inventor: Debkumar Mukhopadhyay
  • Patent number: 9994531
    Abstract: An antioxidant composition which comprises: (a) methylenebis(di-n-butyldithiocarbamate); and (b) an alkylated diphenylamine derivative of triazole wherein the alkyl group on at least one of the phenyl groups is C8 or higher. Lubricating compositions containing the antioxidant composition are also contemplated.
    Type: Grant
    Filed: August 2, 2016
    Date of Patent: June 12, 2018
    Assignee: VANDERBILT CHEMICALS, LLC
    Inventor: Vincent J. Gatto
  • Patent number: 9783759
    Abstract: A lubricating composition comprising at least 90% by weight of a base oil, and an antioxidant composition comprising the components, set forth as weight % of the lubricating composition: (1) solid alkylated-phenyl-alpha-naphthylamine at 0.01-0.3%, (2) an alkylated diphenylamine derivative of triazole, tolutriazole or benzotriazole, at 0.01-0.3%, and (3) methylenebis(di-n-butyldithiocarbamate), at 0.01-0.4%.
    Type: Grant
    Filed: August 14, 2015
    Date of Patent: October 10, 2017
    Assignee: VANDERBILT CHEMICALS, LLC
    Inventors: Junbing Yao, Vincent Gatto
  • Patent number: 9732563
    Abstract: Embodiments relate to a polycrystalline diamond compact (“PDC”) including a polycrystalline diamond (“PCD”) table bonded to a cemented carbide substrate including tungsten carbide grains having a fine average grain size to provide one or more of enhanced wear resistance, corrosion resistance, or erosion resistance, and a PDC with enhanced impact resistance. In an embodiment, a PDC includes a cemented carbide substrate having a cobalt-containing cementing constituent cementing tungsten carbide grains together exhibiting an average grain size of about 1.5 ?m or less. The substrate includes an interfacial surface and a depletion zone depleted of the cementing constituent that extends inwardly from the interfacial surface to a depth of, for example, about 30 ?m to about 60 ?m. The PDC includes a PCD table bonded to the interfacial surface of the substrate. The PCD table includes diamond grains bonded together exhibiting an average grain size of about 40 ?m or less.
    Type: Grant
    Filed: July 30, 2013
    Date of Patent: August 15, 2017
    Assignee: US SYNTHETIC CORPORATION
    Inventor: Debkumar Mukhopadhyay
  • Patent number: 8889606
    Abstract: 1-[Di(4-octylphenyl)aminomethyl]tolutriazole is prepared in a mineral oil wherein the reaction also contains between 0.1 and 5% by weight of a polyacrylate polymer dissolved in a mineral oil. The liquid product shows increased storage stability with respect to crystallization of the 1-[di(4-octylphenyl)aminomethyl]tolutriazole when the polyacrylate polymer is added during the reaction to prepare the 1-[Di(4-octylphenyl)aminomethyl]tolutriazole. This product can be utilized in a lubricant composition as an antioxidant and corrosion inhibitor.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: November 18, 2014
    Assignee: Vanderbilt Chemicals, LLC
    Inventors: Kevin J. Chase, William T. Wallack
  • Publication number: 20140162918
    Abstract: Provided is a micropitting corrosion resistant industrial gear lubricant composition, comprising: (A) at least a highly refined mineral oil, or synthetic oil or any combination of the above components; (B) at least a micropitting corrosion resistant additive; (C) at least an anti-wear additive; (D) at least a metal passivation additive; and (E) at least an anti-oxidation additive. The lubricant composition has excellent high and low temperature performance and meets 68, 100, 150, 220, 320, 460 and 680 industrial gear oil viscosity level requirement. The lubricant composition has excellent micropitting corrosion resistance, anti-wear performance and anti-oxidation performance, passes FVA 54 micropitting corrosion resistant test, FAG FE-8 bearing wear test and SKF EMCOR bearing corrosion test, and is suitable for many large-scale industrial transmission gears and some automobile transmission gears, especially suitable for a gear transmission system for wind power generation.
    Type: Application
    Filed: May 4, 2012
    Publication date: June 12, 2014
    Inventors: Xisheng Fu, Xiuling Hua, Jie Zhang
  • Publication number: 20140162919
    Abstract: Provided is a lubricant composition for a full transmission system, comprising: (A) at least an ashless dispersant; (B) at least a friction modifier; (C) at least a phosphorus-containing antiwear agent; (D) at least an antirust additive; (E) at least a sulfur-containing extreme-pressure additive; (F) at least a metal deactivation additive; (G) at least a viscosity index improver; (H) at least a pour-point depressant; and (I) at least a highly refined mineral oil with high viscosity index, or polyolefin synthetic oil, or ester synthetic oil, or any combination of the above components. The lubricant composition has excellent cleaning dispersity, frictional characteristic, antirust and anti-corrosive properties and extreme pressure abrasion resistance, meets US force standard MIL-PRF-2105E, and can be used for lubrication in various vehicle transmission systems.
    Type: Application
    Filed: May 4, 2012
    Publication date: June 12, 2014
    Applicant: PETROCHINA COMPANY LIMITED
    Inventors: Xisheng Fu, Liping Mi, Jing Xu
  • Patent number: 8722592
    Abstract: A method using one or more of certain triazoles in an amount effective to reduce cobalt leaching during a metal working process from a metal working tool comprising cobalt, such as tungsten carbide particles bonded by cobalt, wherein the one or more triazoles comprise at least butyl-benzotriazole, and optionally one or more other benzotriazoles. Also, a composition is provided which comprises a metal working fluid and one or more of these triazoles in an amount effective to reduce cobalt leaching from metal working tools comprising cobalt, such as tungsten carbide particles bonded by cobalt.
    Type: Grant
    Filed: July 25, 2008
    Date of Patent: May 13, 2014
    Assignee: Wincom, Inc.
    Inventors: William N. Matulewicz, Peter F. Vogt, Thomas J. Bobinger
  • Patent number: 8703873
    Abstract: The composition and preparation of multifunctional graft polymers useful as dispersants are described. The dispersants described are suitable for controlling sludge and varnish as well as soot, friction and wear. The product is useful as a lubricant additive.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: April 22, 2014
    Assignee: Castrol Limited
    Inventor: Richard P. Sauer
  • Publication number: 20140018268
    Abstract: The present invention relates to a lubricating composition containing (a) an oil of lubricating viscosity; and (b) a compound selected from the group consisting of: (i) an ester-containing heterocycle; (ii) an amide-containing heterocycle; and (iii) a pyrimidine, wherein the ester-containing heterocycle and the amide-containing heterocycle have a hydrocarbyl group containing 6 to 40 carbon atoms. The invention further provides for a method of supplying an internal combustion engine with the lubricating composition.
    Type: Application
    Filed: September 19, 2013
    Publication date: January 16, 2014
    Inventors: Patrick E. Mosier, Jason R. Brown, Matthew D. Gieselman, Calvin W. Schroeck, Seth L. Crawley, William R. S. Barton, William C. Ward, JR.
  • Publication number: 20130143405
    Abstract: A silicon-wafer processing fluid used for processing a silicon wafer contains a friction modifier containing a nitrogen-containing compound, pH of the nitrogen-containing compound being in a range from 2 to 8 when a mass ratio with water (i.e. nitrogen-containing compound/water) is 1/99. The nitrogen-containing compound is preferably a heterocyclic compound. The silicon-wafer processing fluid restrains an abrasion of abrasive grains rigidly attached to a wire and generation of hydrogen.
    Type: Application
    Filed: August 23, 2011
    Publication date: June 6, 2013
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventor: Tomohiko Kitamura
  • Publication number: 20130123156
    Abstract: 1-[Di(4-octylphenyl)aminomethyl]tolutriazole is prepared in a mineral oil wherein the reaction also contains between 0.1 and 5% by weight of a polyacrylate polymer dissolved in a mineral oil. The liquid product shows increased storage stability with respect to crystallization of the 1-[di(4-octylphenyl)aminomethyl]tolutriazole when the polyacrylate polymer is added during the reaction to prepare the 1-[Di(4-octylphenyl)aminomethyl]tolutriazole.
    Type: Application
    Filed: October 11, 2012
    Publication date: May 16, 2013
    Applicant: R.T. VANDERBILT COMPANY, INC.
    Inventor: R.T. VANDERBILT COMPANY, INC.
  • Patent number: 8367591
    Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: February 5, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Hideki Kamano
  • Publication number: 20110212864
    Abstract: The invention relates to novel (benzo)triazole compositions comprising mixtures of benzotriazoles and N-substituted benzotriazoles in functional liquids, e.g. mineral oil. The mixtures can be prepared from readily obtainable starting materials, such as tolutriazole (TTA), alkyl aldehydes and cycloalkanols. The invention furthermore relates to a process for protecting metals, which are in contact with functional liquids comprising the mixtures.
    Type: Application
    Filed: February 2, 2011
    Publication date: September 1, 2011
    Inventors: Isabelle RAPENNE-JACOB, Samuel EVANS, Peter ROHRBACH, Martin VON BÜREN
  • Publication number: 20100029520
    Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.
    Type: Application
    Filed: October 19, 2007
    Publication date: February 4, 2010
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventor: Hideki Kamano
  • Publication number: 20100022424
    Abstract: A method using one or more of certain triazoles in an amount effective to reduce cobalt leaching during a metal working process from a metal working tool comprising cobalt, such as tungsten carbide particles bonded by cobalt, wherein the one or more triazoles comprise at least butyl-benzotriazole, and optionally one or more other benzotriazoles. Also, a composition is provided which comprises a metal working fluid and one or more of these triazoles in an amount effective to reduce cobalt leaching from metal working tools comprising cobalt, such as tungsten carbide particles bonded by cobalt.
    Type: Application
    Filed: July 25, 2008
    Publication date: January 28, 2010
    Applicant: Wincom, Inc.
    Inventors: Peter F. Vogt, William N. Matulewicz, Thomas J. Bobinger
  • Publication number: 20090137435
    Abstract: Electrical oil formulation comprising a base oil component and an additive, wherein (i) at least 80 wt % of the base oil component is a paraffin base oil having a paraffin content of greater than 80 wt % paraffins and a saturates content of greater than 98 wt % and comprising a series of iso-paraffins having n, n+1, n+2, n+3 and n+4 carbon atoms and wherein n is between 20 and 35; and (ii) an anti-oxidant additive; wherein the base oil component has a flash point of at least 170° C., as determined by ISO 2592.
    Type: Application
    Filed: June 22, 2006
    Publication date: May 28, 2009
    Inventors: Andree Hilker, Volker Klaus Null
  • Publication number: 20090105102
    Abstract: The invention relates to novel (benzo)triazole compositions comprising mixtures of benzotriazoles and N-substituted benzotriazoles in functional liquids, e.g. mineral oil. The mixtures can be prepared from readily obtainable starting materials, such as tolutriazole (TTA), alkyl aldehydes and cycloalkanols. The invention furthermore relates to a process for protecting metals, which are in contact with functional liquids comprising the mixtures.
    Type: Application
    Filed: November 14, 2005
    Publication date: April 23, 2009
    Inventors: Isabelle Rapenne-Jacob, Samuel Evans, Peter Rohrbach, Martin Von Buren
  • Patent number: 6946429
    Abstract: A bearing for an electronically controlled throttle motor in an automobile filled with a grease composition with a kinetic viscosity between 40 and 150 mm2/sec (at 40° C.) containing (a) a straight-chain perfluoropolyether oil with a kinetic viscosity less than 25 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 25 and 45), (b) a base oil containing a straight-chain perfluoropolyether oil with a kinetic viscosity greater than 250 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 80 and 200) and (c) a polytetrafluoroethylene filler.
    Type: Grant
    Filed: April 7, 2003
    Date of Patent: September 20, 2005
    Assignee: Minebea Co., Ltd.
    Inventor: Motoharu Akiyama
  • Patent number: 6800595
    Abstract: A grease composition having a base oil and a thickener, which grease additionally has from 0.05% to 30% by weight of sodium thiosulphate and at least 0.1% by weight of one or more additives selected from the group of: calcium salicylate, magnesium salicylate, calcium phenate, and calcium sulphonate, based on the total grease composition, and use of the grease composition to improve rust prevention and abrasion resistance. The invention also relates to a method for preparing the grease composition.
    Type: Grant
    Filed: February 10, 2003
    Date of Patent: October 5, 2004
    Assignee: Shell Oil Company
    Inventors: Takahiro Ozaki, Noriaki Shinoda, Kouichi Nakazawa
  • Publication number: 20040147411
    Abstract: A synthetic ester comprising a reaction product of: (a) a polyol corresponding to formula I: 1
    Type: Application
    Filed: March 12, 2004
    Publication date: July 29, 2004
    Inventors: Frank Bongardt, Ralf Christoph
  • Patent number: 6743759
    Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: June 1, 2004
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
  • Patent number: 6669872
    Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: December 30, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
  • Publication number: 20030195125
    Abstract: A bearing for an electronically controlled throttle motor in an automobile filled with a grease composition with a kinetic viscosity between 40 and 150 mm2/sec (at 40° C.) containing (a) a straight-chain perfluoropolyether oil with a kinetic viscosity less than 25 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 25 and 45), (b) a base oil containing a straight-chain perfluoropolyether oil with a kinetic viscosity greater than 250 mm2/sec (at 40° C.) expressed by the formula RfO(CF2O)p(C2F4O)q(C3F6O)rRf (where Rf is a perfluoro lower alkyl group, and p, q and r are integers whose total is between 80 and 200) and (c) a polytetrafluoroethylene filler.
    Type: Application
    Filed: April 7, 2003
    Publication date: October 16, 2003
    Inventor: Motoharu Akiyama
  • Publication number: 20030176295
    Abstract: A grease composition comprising a base oil and a thickener, which grease additionally comprises from 0.05% to 30% by weight of sodium thiosulphate and at least 0.1% by weight of one or more additives (A) selected from the group comprising calcium salicylate, magnesium salicylate, calcium phenate and/or calcium sulphonate, based on the total grease composition; use of said grease composition to improve rust prevention and abrasion resistance, and a method for preparing said grease composition.
    Type: Application
    Filed: February 10, 2003
    Publication date: September 18, 2003
    Inventors: Takahiro Ozaki, Noriaki Shinoda, Kouichi Nakazawa
  • Publication number: 20030134753
    Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.
    Type: Application
    Filed: November 19, 2002
    Publication date: July 17, 2003
    Applicant: R.T. Vanderbilt Company, Inc.
    Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
  • Patent number: 6410490
    Abstract: The instant invention relates to a lubricant composition stabilized against the deleterious effects of heat and oxygen. The composition comprises a hydrotreated or hydrodewaxed oil and an effective antioxidant stabilizing amount of a mixture of a phenolic antioxidant; an N,N-disubstituted aminomethyl-1,2,4-triazole; an aromatic amine antioxidant; an alkyl phenoxy alkanoic acid; and an N-acyl sarcosine derivative. Optionally, further additives are added to the subject lubricant compositions.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: June 25, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jose L. Reyes-Gavilan, Frederick T. Lichtenberg, Adesola O. Oshode, Miles J. Hutchings, Peter Collen Hamblin, Michael Fletschinger, Peter Rohrbach
  • Patent number: 6315920
    Abstract: An electrical oil having reduced gassing tendency includes a major amount of a paraffinic or naphthenic basestock and a blend of certain hindered phenols, especially a blend of 2,6-di-t-butyl phenol and 2,6-di-t-butyl cresol. A further enhanced gassing tendency can be provided to the electrical oil by including a tolyltriazole derivative.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: November 13, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Christopher Jeffrey Still Kent, Jacob B. Angelo
  • Patent number: 6214776
    Abstract: An oil composition useful as a high stress electrical oil and especially as a transformer load tap changer oil is provided. The composition comprises a major amount of a paraffinic oil having a low viscosity of less than about 20 cSt @ 40° C. and an effective amount of an additive system including at least one hindered phenolic antioxidant and a benzotriazole metal deactivator.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: April 10, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Jacob B. Angelo, Christopher Jeffrey Still Kent, Frederick Michael Gragg
  • Patent number: 6207623
    Abstract: A lubricating oil formulation containing a major amount of a base oil of lubricating viscosity and a minor amount of additives comprising a combination of phenyl naphthyl amine, dimercaptothiadiazole or derivative thereof, and triazole or benzotriazole or derivative thereof, exhibiting enhanced resistance to oxidation.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: March 27, 2001
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Kevin David Butler, Alison Fiona Miller, Todd Timothy Nadasdi
  • Patent number: 6083889
    Abstract: An oil composition useful as an electrical or transformer oil is provided. The composition comprises a major amount of a paraffinic oil having a Cleveland open cup flash point of more than about 200.degree. C. and an effective amount of an additive system including at least one hindered phenolic antioxidant and a tolyltriazole metal deactivator.
    Type: Grant
    Filed: February 5, 1999
    Date of Patent: July 4, 2000
    Assignee: Exxon Research and Engineering Company
    Inventors: Jacob Ben Angelo, Christopher Jeffrey Still Kent
  • Patent number: 5714442
    Abstract: A description is given of compounds of the formula I, and mixtures thereof, ##STR1## (I), in which Y and Z independently of one another are a radical of the formula ##STR2## (III) R and R.sub.1 independently of one another are hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl or C.sub.1 -C.sub.4 alkyl-substituted phenyl,R.sub.2 is C.sub.2 -C.sub.20 alkylene, C.sub.5 -C.sub.8 cycloalkylene, a radical of the formula ##STR3## The compounds/mixtures are particularly suitable as metal deactivators for use in lubricants.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: February 3, 1998
    Assignee: Ciba Speciality Chemicals Corporation
    Inventor: Jean-Pierre Wolf
  • Patent number: 5580482
    Abstract: The instant invention relates to a lubricant composition stabilized against the deleterious effects of heat and oxygen. The composition comprises a triglyceride oil or an oil which is an ester wherein unsaturation is present in either the alcohol moiety or the acid moiety and an effective stabilizing amount of either an N,N-disubstituted aminomethyl-1,2,4-triazole or an N,N-disubstituted aminomethylbenzotriazole; a higher alkyl substituted amide of dodecylene succinic acid; a phenolic antioxidant; and an aromatic amine antioxidant. Further additives can be added to these lubricant formulations.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: December 3, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: David E. Chasan, Patricia R. Wilson
  • Patent number: 5560854
    Abstract: A working fluid composition for a compression type refrigerator, comprising:(A) a refrigerant composed of ammonia or at least one hydrofluorocarbon having the number of carbon being not more than 2 and containing no chlorine; and(B) a lubricant for the refrigerator, said lubricant comprising 100 parts by weight of a synthetic oil and 0.5 to 10.0 parts by weight of at least one benzotriazole derivative expressed by the following formula (I). ##STR1## in which R.sup.1 is hydrogen or an alkyl group having the number of carbons being 1-10, and R.sup.2 and R.sup.3 independently indicate an alkyl group having the number of carbons being 4-18.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 1, 1996
    Assignees: Nissan Motor Co., Ltd., Japan Energy Corporation
    Inventors: Takashi Kaimai, Hiroki Tawaki, Sumio Yokoo