And Chalcogen Double Bonded Directly To The Other Ring Carbon Of The Hetero Ring Which Is Adjacent To The Ring Oxygen (e.g., Maleic Anhydride Copolymers, Etc.) Patents (Class 508/306)
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Patent number: 12146115Abstract: This disclosure describes low ash lubricating composition achieving passing steel corrosion, passing high temperature deposit formation, and emulsion stability. The lubricating compositions include one or more select corrosion or rust inhibitor chemistries having an oil-soluble acyclic structure with acidic, hydroxy, or amine moieties but being free of imine, imide, and/or amidine moieties.Type: GrantFiled: December 20, 2022Date of Patent: November 19, 2024Assignee: Afton Chemical CorporationInventor: Kenneth Garelick
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Patent number: 12024687Abstract: The present disclosure relates to lubricating compositions and, in particular, lubricating compositions suitable for motorcycle applications including select metal dihydrocarbyl dithiophosphates to achieve low copper corrosion, good TBN retention, and good sulfur retention applicable to motorcycle engines and transmissions.Type: GrantFiled: September 27, 2022Date of Patent: July 2, 2024Assignee: Afton Chemical CorporationInventors: David Edwards, Hidetaka Hoshino, Guillaume Carpentier
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Patent number: 11479736Abstract: The present disclosure describes lubricant compositions effective to minimize average engine sludge through selection of lubricant additives that control the total nitrogen as well as the origin of the nitrogen in the lubricant composition. In aspects, the lubricant compositions herein include at least a base oil of lubricating viscosity, a dispersant system, and at least one antioxidant.Type: GrantFiled: June 4, 2021Date of Patent: October 25, 2022Assignee: Afton Chemical CorporationInventors: Lisa Dingwell, Michael Rosana
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Patent number: 11299690Abstract: The use of polyalkylenyl succinic anhydrides to stabilise an additive concentrate which includes a salicylate detergent and a nitrogen-free ashless organic friction modifier.Type: GrantFiled: March 22, 2017Date of Patent: April 12, 2022Inventors: Philip J. Woodward, Adam P. Marsh
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Patent number: 11124593Abstract: A modified block copolymer according to the present invention is a modified block copolymer comprising a polymer block comprising a vinyl aromatic compound as a main constituent (A), a polymer block comprising a conjugate diene compound as a main constituent (B), and an atomic group having NHx (x=0 to 2) (C). In the modified block copolymer, the polymer block comprising a conjugate diene compound as a main constituent (B) is a hydrogenated product, the atomic group having NHx (x=0 to 2) (C) is contained in a side chain, and a compound forming the atomic group having NHx (x=0 to 2) (C).Type: GrantFiled: May 8, 2018Date of Patent: September 21, 2021Assignee: Asahi Kasei Kabushiki KaishaInventors: Takashi Sukegawa, Masashi Yamamoto, Yasuhiro Kusanose
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Patent number: 10513667Abstract: The present invention provides a lubricating composition comprising: an oil of lubricating viscosity; 3 wt % to 30 wt % of an alkaline earth or alkali metal sulphonate detergent; and an oil-soluble polyalkylene glycol having a distribution of molecular weight such that the molecules thereof have a weight of 2500 to less than 10,000 Daltons and comprise 0.05 wt % to 3 wt % of the lubricating composition. The invention further provides a method of lubricating a 2-stroke internal combustion engine cylinder liner (and piston) with the lubricating composition.Type: GrantFiled: April 7, 2014Date of Patent: December 24, 2019Assignee: THE LUBRIZOL CORPORATIONInventors: Shaun P. Carney, David M. Hobson
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Patent number: 9388333Abstract: Generally, assessing the properties of a plug comprising wellbore strengthening materials may enable the design of more efficient wellbore strengthening additives and fluids because the properties of the plug may translate to the near wellbore strengthening effect of the wellbore strengthening materials of the plug. Assessing such properties may involve applying a differential pressure to a plug formed in a passageway of a tool comprising at least one sensor proximal to the passageway plug, and then measuring at least one attribute selected from the group consisting of a normal plug pressure, a normal plug displacement, and any combination thereof with the at least one sensor.Type: GrantFiled: July 11, 2012Date of Patent: July 12, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Sharath Savari, Arunesh Kumar, Jason T. Scorsone
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Patent number: 9034809Abstract: The present invention relates to a method of driveline device by supplying to the driveline device a lubricating composition containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes: (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) a phosphorus compound. The invention further provides lubricating compositions containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) an amine or metal salt of a phosphorus compound that is either (i) a hydroxy-substituted di-ester of (thio)phosphoric acid, or (ii) a phosphorylated hydroxy-substituted di- or tri-ester of (thio)phosphoric acid.Type: GrantFiled: September 6, 2012Date of Patent: May 19, 2015Assignee: The Lubrizol CorporationInventor: Morey N. Najman
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Publication number: 20150083067Abstract: A trunk piston lubricating oil composition of TBN 20 to 60 comprising (A) a high saturates low sulphur oil of lubricating viscosity in a major amount; (B) an overbased metal hydroxybenzoate detergent additive; (C) a polyisobutene succinic anhydride additive (1-7 mass %); and (D) a meta-linear pentadecyl phenol additive (10.1 to 10 mass %), the weight ratio of (D) to (C) being less than 1 and the combined treat rate of (B), (C) and (D) being 5 to 30%. The composition is useful to improve asphaltene dispersancy when lubricating a medium-speed compression-ignited marine engine fueled by a heavy fuel oil.Type: ApplicationFiled: September 24, 2014Publication date: March 26, 2015Applicant: Infineum International LimitedInventor: Laura Gregory
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Publication number: 20150072909Abstract: The present invention relates to methods of lubricating a hydraulic motor by using a lubricating composition that contains a friction modifier selected from the group consisting of a fatty phosphite, a fatty imidazoline and combinations thereof and supplies improved motor efficiency performance. The invention further provides the lubricating compositions used therein.Type: ApplicationFiled: November 19, 2014Publication date: March 12, 2015Applicants: The Lubrizol Corporation, ExxonMobil Research and Engineering CompanyInventors: Tomasz M. Young, David G.L. Holt, Angela S. Galiano-Roth, Allan R. Barber, Brian B. Filippini
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Patent number: 8969266Abstract: The invention provides a lubricating composition comprising an oil of lubricating viscosity and an amine-functionalized additive, wherein the amine-functionalized additive is derived from an amine having at least 3 aromatic groups, at least one —NH2 functional group, and at least 2 secondary or tertiary amino groups. The invention further provides for the additive to have improved thermal and oxidative stability modifying properties. The lubricating composition may include circulating oils, turbine oils, hydraulic fluids, transformer oils and greases as well as others that require good oxidation stability and good rust inhibition properties.Type: GrantFiled: June 1, 2011Date of Patent: March 3, 2015Assignee: The Lubrizol CorporationInventors: Seth L. Crawley, Matthew R. Sivik, Betsy J. Butke
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Publication number: 20150057201Abstract: [Object] To provide lubricating thermoplastic resin compositions that can give formed articles exhibiting excellent lubricating properties and surface appearance and maintaining the lubricating properties permanently. [Solution] The lubricating thermoplastic resin composition includes an acid-modified copolymer (A) of a monomer mixture including an aromatic vinyl and a vinyl cyanide, the copolymer having a carboxyl group in the molecular chain, and a functionalized lubricant (B) having, in the molecule, a functional group (B1) capable of reacting with the carboxyl group and a lubricating segment (B2) having lubricating properties. The composition may further include a graft copolymer (C) and/or an additional thermoplastic resin (D) other than the acid-modified copolymer (A).Type: ApplicationFiled: April 5, 2013Publication date: February 26, 2015Applicant: UMG ABS, LTD.Inventors: Yoshitaka Naitoh, Kousaku Tao, Tomonori Takase, Risa Nii, Yoshiaki Shinohara, Keiichi Yagi, Nobutaka Hase
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Publication number: 20150045268Abstract: A lubricant composition containing a metal-containing detergent in an amount to provide at least about 2 TBN to the lubricant, and a dispersant comprising an oleophilic portion comprising at least about 40 carbon atoms and an acid-bearing portion, characterized in having a TAN:TBN ratio of at least about 0.8, exhibits good TBN retention.Type: ApplicationFiled: February 15, 2012Publication date: February 12, 2015Applicant: The Lubizol CorporationInventors: Mark C. Davies, Stephen J. Cook, Alexandra Mayhew
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Patent number: 8927469Abstract: An engine lubricant composition, a method for maintaining the soot or sludge handling capability of an engine lubricant while not adversely affecting elastomeric seal material in the engine and a method of operating an engine. The engine lubricant includes a base oil and a dispersant. The dispersant is a reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, B) a polyamine, C) a dicarboxyl-containing fused aromatic compound, and D) a non-aromatic dicarboxylic acid or anhydride.Type: GrantFiled: July 16, 2012Date of Patent: January 6, 2015Assignee: Afton Chemical CorporationInventors: Naresh Mathur, Jason A. Lagona
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Publication number: 20140371120Abstract: A sulphurised calcium phenate detergent is made by (i) reacting hydrogenated distlled CNSL with a calcium salt and sulphur in the presence of a promoter and process solvent; (ii) reacting the product of (i) with additional calcium salt and promoter, and with a co-surfactant, and then carbonating; and optionally (iii) further carbonating the reaction mixture to obtain overbased sulphurised calcium phenate.Type: ApplicationFiled: June 13, 2013Publication date: December 18, 2014Inventors: Adam P. Marsh, Dirk Schwaebisch, Oliver J. Delamore
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Patent number: 8778854Abstract: The disclosed invention relates to a composition comprising a grafted polymer. The polymer comprises a backbone with at least one olefin block and at least one vinyl aromatic block. The polymer is grafted with a pendant carbonyl containing group, the grafting being conducted by halogenating the vinyl aromatic carbon of the vinyl aromatic block and then grafting a carboxylic acid or derivative thereof on the halogenated vinyl aromatic carbon in the presence of an activating agent. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.Type: GrantFiled: July 6, 2010Date of Patent: July 15, 2014Assignee: The Lubrizol CorporationInventors: David Price, William R. S. Barton, Michael R. Sutton, Mark C. Davies
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Publication number: 20140165943Abstract: Trunk piston marine engine lubrication comprising a major amount of (A) an oil of lubricating viscosity that comprises an oil-soluble ester basestock, or that comprises greater than 0.1 to less than 90 mass % of an oil-soluble ester basestock and, as 50 mass % or more of the remainder of the oil of lubricating viscosity, a high saturates basestock; (B) a minor amount of a metal alkyl salicylate detergent; and (C) greater than 0.1 to less than 10 mass %, of an oil-soluble polyalkenyl-substituted carboxylic acid anhydride, wherein the or at least one polyalkenyl group is derived from a polyalkene having a number average molecular weight of from 200 to 3,000. Asphaltene precipitation in the lubricant composition, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.Type: ApplicationFiled: November 21, 2013Publication date: June 19, 2014Applicant: Infineum International LimitedInventors: James C. Dodd, Joshua L. Bradley-Shaw
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Publication number: 20140128301Abstract: Two-stroke cross-head marine compression-ignited engine system lubrication is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a basestock containing greater than or equal to 90% saturates and less than or equal to 0.03% sulphur or a mixture thereof, and respective minor amounts of an oil-soluble overbased metal alkyl salicylate detergent and an oil-soluble polyalkenyl-substituted carboxylic acid anhydride or an oil-soluble alkylated phenol. The presence of the anhydride or the phenol improves asphaltene dispersency in the lubricant.Type: ApplicationFiled: November 1, 2013Publication date: May 8, 2014Applicant: Infineum International LimitedInventors: Robert J. Glass, Helen Bishop, Agata Checinska
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Patent number: 8703664Abstract: The present invention provides a metal rolling oil composition excellent in both an emulsion stability and a plating-out property, wherein the metal rolling oil composition comprises: at least one base oil selected from the group consisting of a mineral oil, animal and vegetable fat and oil, and synthetic ester; a surfactant; and an elastomer.Type: GrantFiled: February 12, 2010Date of Patent: April 22, 2014Assignee: Yushiro Chemical Industry Co., Ltd.Inventors: Kouji Hosoda, Keiji Izawa, Hitoshi Hasegawa
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Publication number: 20140107000Abstract: The present invention relates to functional fluid compositions containing antioxidants, and specifically stable compositions containing antioxidants with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and antioxidants containing a phenolic or benzoic group, where the antioxidant is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.Type: ApplicationFiled: May 15, 2012Publication date: April 17, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: Danielle N. Ivancic, James D. Burrington, Ewan E. Delbridge
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Publication number: 20140087984Abstract: This disclosure relates to vinyl terminated macromer (VTM) based synthetic basestocks and their methods of preparation, lubricant compositions, methods of lubrication and products so lubricated. The VTM based synthetic basestocks useful for fuels and lubricants include oligomerization or polymerization products of one or more allylic vinyl terminated macromers (VTMs) having a molecular weight from 84 to 10080. The one or more allylic VTMs are oligomerized or polymerized in the presence of a catalyst under oligomerization or polymerization conditions sufficient to give the VTM based synthetic basestock. The catalyst can be a metallocene catalyst or an acid catalyst, e.g., Lewis acid. The one or more allylic vinyl terminated macromers (VTMs) can be one or more allylic vinyl terminated atactic polypropylene macromers (VTM aPP) having a molecular weight from 84 to 2250 and having a terminal allylic vinyl olefin content of at least 90%.Type: ApplicationFiled: September 4, 2013Publication date: March 27, 2014Applicant: ExxonMobil Research and Engineering CompanyInventors: Abhimanyu Onkar Patil, Satish Bodige
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Publication number: 20140038864Abstract: Provided are a lubricating engine oil and a method of improving nitrile seal compatibility with a lubricating oil in an engine lubricated with such lubricating oil. The method includes using as the lubricating oil a formulated oil comprising a lubricating oil base stock as a major component and one or more additives selected from the group consisting of (i) a sulfone, sulfolane, or derivative thereof; (ii) a borate ester, boron amide, or mixtures thereof; (iii) a sulfurized olefin; (iv) a thiadiazole or derivative thereof; and (v) a succinic anhydride or derivative thereof, as a minor component. Nitrile seal compatibility is improved as compared to nitrile seal compatibility achieved using a lubricating oil containing a minor component other than the one or more additives.Type: ApplicationFiled: July 22, 2013Publication date: February 6, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Anne M. Shough, David Joseph Baillargeon, Steven Michael Jetter, Douglas Edward Deckman
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Publication number: 20140031269Abstract: The disclosed invention relates to lubricant or functional fluid compositions containing viscosity index improvers in the form of self-healing polymers. The polymers may comprise one or more cleavable linkages, such as one or more disulfide bonds and/or one or more diene/dienophile linkages, to permit the polymer to reform if cleaved during use.Type: ApplicationFiled: January 9, 2012Publication date: January 30, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: David Price, William R.S. Barton
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Publication number: 20130281334Abstract: Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition of TBN in the range of 20 to 60 comprising a major amount of an oil of lubricating viscosity containing 50 mass % or more of a Group 1 basestock, and respective minor amounts of a calcium alkyl salicylate detergent system providing 40 to 90 mmol of calcium alkyl salicylate per kg of the composition, and 1 to 7 mass %, based on the mass of the composition, of an oil-soluble polyalkenyl-substituted carboxylic acid anhydride, wherein the or at least one polyalkenyl group is derived from a polyalkene having a number average molecular weight of from 200 to 3,000. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.Type: ApplicationFiled: March 28, 2013Publication date: October 24, 2013Inventors: James C. Dodd, Louise Renouf
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Publication number: 20130274161Abstract: An additive package for an internal combustion engine crankcase lubricating oil composition, which additive package comprises or is made by admixing: (A) 5-99.4 mass % based on the mass of the additive package, of a diluent oil of lubricating viscosity; and (B) the following additives: (B1) 0.1-10 mass % of a polymeric friction modifier, on an active matter basis, based on the mass of the additive package, which polymeric friction modifier is the reaction product of (a) a functionalised polyolefin, (b) a polyether, (c) a polyol, and (d) a monocarboxylic acid chain terminating group (B2) 0.5 to 10 mass % on an active matter basis, based on the mass of the additive package of one or more ashless organic friction modifiers that include a polar terminal group covalently bonded to a monomeric oleophilic hydrocarbon chain.Type: ApplicationFiled: April 12, 2012Publication date: October 17, 2013Inventors: Philip J. Woodward, Wangkan Lin, Erika M. Vela
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Publication number: 20130203638Abstract: The invention provides a lubricating composition comprising an oil of lubricating viscosity and an amine-functionalised additive, wherein the amine-functionalised additive is derived from an amine having at least 3 aromatic groups, at least one —NH2 functional group, and at least 2 secondary or tertiary amino groups. The invention further provides for the additive to have improved thermal and oxidative stability modifying properties. The lubricating composition may include circulating oils, turbine oils, hydraulic fluids, transformer oils and greases as well as others that require good oxidation stability and good rust inhibition properties.Type: ApplicationFiled: June 1, 2011Publication date: August 8, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: Seth L. Crawley, Matthew R. Sivik, Betsy J. Butke
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Publication number: 20130150273Abstract: A lubricating composition comprising an oil of lubricating viscosity, 1 to 1000 parts per million by weight of titanium in the form of an oil-soluble titanium-containing material, and at least one additional lubricant additive provides beneficial effects on properties such as deposit control, oxidation, and filterability in engine oils.Type: ApplicationFiled: February 28, 2011Publication date: June 13, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: Mark C. Davies, Virginia A. Carrick, Jody A. Kocsis, Patrick E. Mosier, Matthew D. Gieselman, John K. Pudelski, Brent R. Dohner, Jonathan S. Vilardo
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Publication number: 20130143781Abstract: The invention provides a lubricating composition containing a copolymer comprising units derived from monomers (i) ?-olefin and (ii) an ethylenically unsaturated carboxylic acid or derivatives thereof esterified and amidated with an alcohol and an aromatic amine respectively, and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: May 19, 2011Publication date: June 6, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: William R.S. Barton, David Price, Patrick E. Mosier
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Publication number: 20130040866Abstract: An engine lubricant composition, a method for maintaining the soot or sludge handling capability of an engine lubricant while not adversely affecting elastomeric seal material in the engine and a method of operating an engine. The engine lubricant includes a base oil and a dispersant. The dispersant is a reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, B) a polyamine, C) a dicarboxyl-containing fused aromatic compound, and D) a non-aromatic dicarboxylic acid or anhydride.Type: ApplicationFiled: July 16, 2012Publication date: February 14, 2013Applicant: AFTON CHEMICAL CORPORATIONInventors: Naresh MATHUR, Jason A. LAGONA
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Publication number: 20120295826Abstract: The present invention relates to a method of lubricating an internal combustion engine with a power output of at least 1600 kilowatts by supplying to the internal combustion engine a lubricating composition containing an oil of lubricating viscosity and at least 0.5 wt % of a hydrocarbyl-substituted carboxylic acid or anhydride thereof. The invention further provides a lubricating composition suitable for the method.Type: ApplicationFiled: August 1, 2012Publication date: November 22, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Alexandra Mayhew, Stephen J. Cook
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Publication number: 20120264662Abstract: This invention relates to functionalized monomers. The functionalized monomer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized monomer. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents, functional compositions (e.g., food products, cleaners, etc.), and the like.Type: ApplicationFiled: March 23, 2012Publication date: October 18, 2012Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
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Patent number: 8236741Abstract: Haze formation in heavy Gas-to-Liquids (GTL) base stock is mitigated by the addition to said GTL base stock of one or more particular additives.Type: GrantFiled: November 14, 2008Date of Patent: August 7, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc-André Poirier, Charles Lambert Baker, Jr., Nicholas Anthony Hilder, Chung-Lai Wong, Dorothy Wong, legal representative, James William Gleeson, Vera Minak-Bernero
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Publication number: 20120178659Abstract: The disclosed invention relates to a composition comprising a grafted polymer. The polymer comprises a backbone with at least one olefin block and at least one vinyl aromatic block. The polymer is grafted with a pendant carbonyl containing group, the grafting being conducted by halogenating the vinyl aromatic carbon of the vinyl aromatic block and then grafting a carboxylic acid or derivative thereof on the halogenated vinyl aromatic carbon in the presence of an activating agent. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.Type: ApplicationFiled: July 6, 2010Publication date: July 12, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: David Price, William R.S. Barton, Michael R. Sutton, Mark C. Davies
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Publication number: 20120101016Abstract: The present invention provides a metal rolling oil composition excellent in both an emulsion stability and a plating-out property, wherein the metal rolling oil composition comprises: at least one base oil selected from the group consisting of a mineral oil, animal and vegetable fat and oil, and synthetic ester; a surfactant; and an elastomer.Type: ApplicationFiled: February 12, 2010Publication date: April 26, 2012Applicant: YUSHIRO CHEMICAL INDUSTRY CO., LTD.Inventors: Kouji Hosoda, Keiji Izawa, Hitoshi Hasegawa
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Publication number: 20120046206Abstract: The invention provides an oil of lubricating viscosity, a dispersant and an amine-functionalised additive, wherein the amine-functionalised additive is derived from an amine having at least 3 or 4 aromatic groups. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: February 24, 2010Publication date: February 23, 2012Applicant: The Lubrizol CorporationInventors: Matthew D. Gieselman, John K. Pudeiski, Mary Galic Raguz, Thomas Derevjanik
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Publication number: 20120028522Abstract: Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a basestock containing greater than or equal to 90% saturates and less than or equal to 0.03% sulphur or a mixture thereof, and respective minor amounts of an over-based metal hydrocarbyl-substituted hydroxybenzoate detergent other than such a detergent having a basicity index of less than two and a degree of carbonation of 80% or greater and at least 1 mass % of a hydrocarbyl-substituted carboxylic acid, anhydride, ester or amide thereof. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.Type: ApplicationFiled: March 31, 2010Publication date: February 2, 2012Inventors: Terence Garner, Laury Gregory, Joseph Peter Hartley, Peter Watts
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Publication number: 20120028521Abstract: Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a Group II basestock, and respective minor amounts of an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent other than such a detergent having a basicity index of less than two and a degree of carbonation of 80% or greater and at least 1 mass % of a hydrocarbyl-substituted carboxylic acid, anhydride, ester or amide thereof. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.Type: ApplicationFiled: March 31, 2010Publication date: February 2, 2012Inventors: Terence Garner, Laura Gregory, Joseph Peter Hartley, Peter Watts
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Publication number: 20110306528Abstract: The invention provides a lubricating composition comprising an oil of lubricating viscosity and an amine-functionalised additive, wherein the amine-functionalised additive is derived from an amine having at least 3 aromatic groups, at least one —NH2 functional group, and at least 2 secondary or tertiary amino groups. The invention further provides for the additive to have dispersant and/or dispersant viscosity modifying properties. The lubricating composition is suitable for lubricating an internal combustion engine.Type: ApplicationFiled: November 23, 2009Publication date: December 15, 2011Applicant: THE LUBRIZOL CORPORATIONInventors: Matthew D. Gieselman, Adam J. Preston
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Publication number: 20110218129Abstract: In accordance with the present invention, it has been discovered that an additive which is substantially insoluble in, has low solubility in and/or is otherwise incompatible with a functional fluid, may be supplied to the functional fluid by use of a gel composition and/or a solid additive composition containing the additive, such that the functional fluid can receive the benefit of the supplied additive and/or contain levels of the additive not otherwise achievable by conventional delivery method due to the incompatibility of the additive with the functional fluid.Type: ApplicationFiled: September 23, 2009Publication date: September 8, 2011Applicant: THE LUBRIZOL CORPORATIONInventors: Calvin W. Schroeck, Michael R. Sutton, James D. Burrington, John K. Pudelski, Ewan E. Delbridge, Jody A. Kocsis, Deborah A. Langer, Matthew D. Gieselman
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Publication number: 20110177988Abstract: The present invention relates to a method of driveline device by supplying to the driveline device a lubricating composition containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes: (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) a phosphorus compound. The invention further provides lubricating compositions containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) an amine or metal salt of a phosphorus compound that is either (i) a hydroxy-substituted di-ester of (thio)phosphoric acid, or (ii) a phosphorylated hydroxy-substituted di- or tri-ester of (thio)phosphoric acid.Type: ApplicationFiled: March 10, 2009Publication date: July 21, 2011Applicant: THE LUBRIZOL CORPORATIONInventor: Morey N. Najman
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Publication number: 20110130314Abstract: A crankcase lubricating oil composition comprising (A) an oil of lubricating viscosity; and (B) as an additive component one or more oil-soluble organic acid anhydrides, the or each anhydride carrying at least one linear (unbranched) aliphatic hydrocarbyl substituent having 12 to 36 carbon atoms.Type: ApplicationFiled: November 29, 2010Publication date: June 2, 2011Inventor: Mark D. Andrews
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Patent number: 7947634Abstract: A process to make a lubricant, comprising: blending together: a) about 0.001 to about 2 wt % of a mixture of amine phosphates; b) about 0.001 to about 0.5 wt % of an alkenyl succinic compound selected from the group consisting of an acid half ester, an anhydride, an acid, and mixtures thereof; c) about 0.10 to about 20 wt % of a solubility improver having an aniline point less than 20° C.; and d) about 60 to about 98.5 wt % of a lubricating base oil selected from the group consisting of an API Group II or Group III base oil having greater than 65% paraffinic chain carbons by ASTM D 3238, an API Group IV base oil, a polyinternal olefin base oil, a hydroisomerized Fischer-Tropsch wax, a Fischer-Tropsch oligomerized olefin base oil, and mixtures thereof; wherein the lubricant passes the 4 hour TORT B rust test.Type: GrantFiled: September 24, 2009Date of Patent: May 24, 2011Assignee: Chevron U.S.A. Inc.Inventor: Mark E. Okazaki
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Publication number: 20110059878Abstract: The present disclosure relates to lubricant oil compositions formed from base stock oils to optimize internal combustion engine performance. Base stock oils are identified that have selected cetane number characteristics and relatively reduced reactivity to improve their associated combustion characteristics and reduce engine knock without the need to modify the engine fuel or engine parameters such as compression ratio and/or ignition timing. The base stocks may specifically include esters of dicarboxylic acids, esters of trimellitic anhydride and/or alklyated naphthalene compounds.Type: ApplicationFiled: September 10, 2009Publication date: March 10, 2011Applicant: SOUTHWEST RESEARCH INSTITUTEInventors: Manfred AMANN, Terrence Francis ALGER, II, Thomas W. RYAN, III
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Publication number: 20110059879Abstract: A lubricating grease composition is disclosed. In one embodiment, the lubricating grease comprises at least one Group I oil, at least one Group II oil, a hydrophilic copolymer, and a soap thickener. The thickener is dispersed into at least one Group I oil during a cooking phase and the at least one Group II oil is introduced during a finishing phase. A method for making a lubricating grease is also disclosed. The method comprises obtaining at least one Group I oil, obtaining at least one Group II oil, obtaining a hydrophilic copolymer, obtaining a soap thickener, and mixing the at least one Group I oil, the least one Group II oil, the polymer and the soap thickener to form a grease wherein the thickener is dispersed into the at least one Group I oil during a cooking phase and at least one Group II oil is introduced during a finishing phase.Type: ApplicationFiled: December 4, 2009Publication date: March 10, 2011Inventors: Carol A. Barnes, Kamilah N. Smith, Alan G. Blahey, Douglas C. MacLaren
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Publication number: 20100311624Abstract: Reaction of a carboxylic acid-containing polymer with certain aromatic amines results in dispersant viscosity modifiers with improved soot handling performance in heavy-duty diesel engines, compared with reaction with non-aromatic amines.Type: ApplicationFiled: August 18, 2010Publication date: December 9, 2010Inventors: Michael J. Covitch, John K. Pudelski, Christopher Friend, Matt D. Gieselman, Renee A. Eveland, Mary Galic Raguz, Barton J. Schober
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Patent number: 7709424Abstract: A lubricating oil composition, which comprises a perfluoropolyether base oil, and a fluorine-containing polyether diphosphonic acid ester, represented by the following general formula: (R2O)(R1O)P(O)(CH2)aCF(CF3)[OCF2CF(CF3)]bO(CF2)cO[CF(CF3)CF2O]dCF(CF3)(CH2)eP(O)(OR3)(OR4) (where R1, R2, R3, and R4 are hydrogen atoms, alkyl groups, cycloalkyl groups, aryl groups, alkylaryl groups, aralkyl groups, or any of the foregoing groups can be halogen atom-substituted groups, subscripts a, b, c, d, and e are in conditions of 2?a+e?8, b+d?28, and 1?c?10, and b and d can be 0), and a grease composition which further contains a thickening agent in addition to the lubricating oil composition, have distinguished abrasion resistance and rust preventiveness without deteriorating the heat resistance inherent in the lubricating oil and the grease containing a perfluoropolyether oil as a base oil.Type: GrantFiled: November 24, 2005Date of Patent: May 4, 2010Assignee: NOK Kluber Co., Ltd.Inventors: Akihiko Shimura, Tatsuya Hashimoto
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Publication number: 20100105587Abstract: A process to make a lubricant, comprising: blending together: a) about 0.001 to about 2 wt % of a mixture of amine phosphates; b) about 0.001 to about 0.5 wt % of an alkenyl succinic compound selected from the group consisting of an acid half ester, an anhydride, an acid, and mixtures thereof; c) about 0.10 to about 20 wt % of a solubility improver having an aniline point less than 20° C.; and d) about 60 to about 98.5 wt % of a lubricating base oil selected from the group consisting of an API Group II or Group III base oil having greater than 65% paraffinic chain carbons by ASTM D 3238, an API Group IV base oil, a polyinternal olefin base oil, a hydroisomerized Fischer-Tropsch wax, a Fischer-Tropsch oligomerized olefin base oil, and mixtures thereof; wherein the lubricant passes the 4 hour TORT B rust test.Type: ApplicationFiled: September 24, 2009Publication date: April 29, 2010Inventor: Mark E. Okazaki
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Publication number: 20100093575Abstract: The invention relates to a graft copolymer comprising the reaction product of maleic anhydride and a backbone polymer wherein said graft copolymer comprises between 0.50 and 5.0 weight percent of maleic anhydride, wherein said backbone polymer is selected from the group consisting of poly-olefins and copolymers of ethylene and ?-olefins with 3 to 8 carbon atoms, the graft copolymer has a MFI of more than 50 dg/min (@190° C., 2.16 kg), and more than 25% of the graft copolymer chains have a chain-end unsaturation. These graft copolymers are suitable as processing aids in e.g. extrusion of high molecular weight polymers.Type: ApplicationFiled: February 18, 2008Publication date: April 15, 2010Inventor: Patric Meessen
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Publication number: 20090305924Abstract: The present invention relates to a method of lubricating an internal combustion engine with a power output of at least 1600 kilowatts by supplying to the internal combustion engine a lubricating composition containing an oil of lubricating viscosity and at least 0.5 wt % of a hydrocarbyl-substituted carboxylic acid or anhydride thereof. The invention further provides a lubricating composition suitable for the method.Type: ApplicationFiled: August 2, 2007Publication date: December 10, 2009Inventors: Alexandra Mayhew, Stephen J. Cook
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Patent number: 7585821Abstract: A modified lubricating oil detergent that is the reaction product of an oil soluble detergent comprising an alkali- or alkaline earth metal hydrocarbyl phenate, carboxylate or sulfonate and an ?, ?-unsaturated carbonyl compound; and lubricating oil compositions containing a combination of such a modified detergent and a nitrogen-containing dispersant.Type: GrantFiled: August 6, 2002Date of Patent: September 8, 2009Assignee: Infineum International LimitedInventors: Jacob Emert, Antonio Gutierrez