With Organic Chalcogen Compound That Does Not Contain Phosphorus Patents (Class 508/378)
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Patent number: 11932823Abstract: To provide a lubricant composition for shock absorbers, a friction adjusting additive for a lubricant for shock absorbers, and a lubricant additive, each capable of satisfying both operational stability and ride comfort and improving the ride comfort further. The lubricant composition for shock absorbers contains a base oil and a friction adjusting agent and the friction adjusting agent contains a first zinc dithiophosphate represented by the following formula 1: [in the formula 1, R11 to R14 are alkyl groups in which one or more and three or less is/are a primary alkyl group and the other(s) is/are a secondary alkyl group].Type: GrantFiled: April 10, 2020Date of Patent: March 19, 2024Assignee: KYB CORPORATIONInventor: Shinji Kato
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Patent number: 10954464Abstract: A lubricating oil composition including: at least one base oil selected from a mineral oil-based lubricating oil, a synthetic oil-based lubricating oil, or a mixed oil thereof, and zinc dialkyldithiophosphates X consisting of the compounds Z1 to Z3 represented by the formulae (1) to (3) are contained, in which a total content of the zinc dialkyldithiophosphates X is 0.02% by mass or more in terms of phosphorus concentration with respect to the total mass of the oil composition, and the zinc dialkyldithiophosphates X satisfy the formulae (a) to (c). In the formula (1), each of R1 to R4 independently represents a linear or branched primary alkyl group having from 10 to 20 carbon atoms. In the formula (2), each of R5 to R8 independently represents a linear or branched primary alkyl group having from 7 to 9 carbon atoms. In the formula (3), each of R9 to R12 independently represents a linear or branched primary or secondary alkyl group having from 3 to 6 carbon atoms.Type: GrantFiled: November 30, 2017Date of Patent: March 23, 2021Assignee: Cosmo Oil Lubricants Co., Ltd.Inventors: Koichi Sakamoto, Atsushi Akamatsu, Naoki Asami
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Patent number: 10117237Abstract: Provided are a base station, whereby the erroneous detection of control information can be reduced, thereby preventing the degradation of the system throughput. A base station maps a downstream allocation control information unit, which is addressed to a terminal, to a first resource region, which can be used for any of a downstream control channel region and a downstream data channel region, or to a second resource region, which can be used only for the downstream control channel, so as to transmit the downstream allocation control information unit. In the base station, a control unit establishes a scale of the PDCCH region, and a transmission region establishing unit establishes, on the basis of a scale value established by the control unit, a mapping region to which the DCI is mapped within the R-PDCCH region and the PDCCH region.Type: GrantFiled: February 1, 2017Date of Patent: October 30, 2018Assignee: Sun Patent TrustInventors: Akihiko Nishio, Seigo Nakao, Yasuaki Yuda, Ayako Horiuchi, Sujuan Feng, Michael Einhaus
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Publication number: 20140228265Abstract: A bridged dimeric or oligomeric phenolic compound comprising: at least one monomer unit (a) of phenol or an alkyl-substituted phenol wherein the alkyl group contains 1 to 8 carbon atoms, or mixtures thereof; at least one monomer unit (b) of an aliphatic hydrocar-byl-substituted phenol wherein the aliphatic hydrocarbyl group contains at least about 25 carbon atoms, or mixtures thereof; and at least one sulfur-containing or carbon-containing bridging group; or a salt of said oligomeric material; wherein the average number of carbon atoms in said alkyl groups and said aliphatic hydrocarbyl groups is 10 to 100.Type: ApplicationFiled: October 16, 2012Publication date: August 14, 2014Applicant: The Lubrizol CorporationInventors: Stephen J. Cook, Christopher L. Friend, Gary M. Walker
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Publication number: 20140057818Abstract: The invention provides a lubricating composition containing an antiwear agent and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in an internal combustion engine, or a driveline device.Type: ApplicationFiled: December 16, 2011Publication date: February 27, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: William R. S. Barton, Mark C. Davies, Christopher L. Friend, Ewan E. Delbridge, Patrick E. Mosier, Michael R. Sutton, Matthew D. Gieselman
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Publication number: 20140045733Abstract: The grease composition for a clean environment includes, a base oil, a thickener and a extreme-pressure agent, in which a kinetic viscosity of the base oil at 40° C. is 100˜300 mm2/s, the thickener comprising a lithium complex soap, a content of the thickener is 10˜40 mass % with respect to the total amount of the grease composition.Type: ApplicationFiled: April 11, 2012Publication date: February 13, 2014Applicants: IDEMITSU KOSAN CO., LTD., THK CO., LTD.Inventors: Akira Nogami, Terumoto Hayami, Hiroshi Sampei, Yukitoshi Fujinami, Kouji Takane
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Publication number: 20140038870Abstract: A sump-lubricated, spark-ignited engine is lubricated by supplying thereto a lubricant which comprises (a) an oil of lubricating viscosity; (b) a polyether; and (c) a metal-containing detergent. The lubricant has a total phosphorus content of less than 0.075 percent by weight.Type: ApplicationFiled: January 11, 2012Publication date: February 6, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: Patrick E. Mosier, Jonathan S. Vilardo
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Publication number: 20130345103Abstract: A gear oil composition is provided having fuel saving performance and providing gears or bearings with sufficient durability. The composition includes a base oil having a blend of (A) a mineral lubricating base oil having a 100° C. kinematic viscosity of 2 to 6 mm2/s, a % CA of 0.5 or less and a tertiary carbon content of 7% or more and (B) a solvent-refined mineral lubricating oil having a 100° C. kinematic viscosity of 10 to 70 mm2/s in an amount of 2 to 40 percent by mass based on the total base oil composition mass; (D) zinc dialkyldithiophosphate in an amount of 0.02 to 0.5 percent by mass based on the zinc amount; and (E) an alkaline earth metal detergent having a base number of 100 mgKOH/g or greater in an amount of 0.1 to 0.5 percent by mass, based on the metal amount, of the gear oil composition mass.Type: ApplicationFiled: September 13, 2011Publication date: December 26, 2013Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Hajime Nakao, Hitoshi Komatsubara
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Publication number: 20130137617Abstract: A method for improving fuel efficiency, while maintaining or improving wear protection, in an engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil having a HTHS viscosity of less than 2.6 cP at 150° C. In one form, the formulated oil has a composition that includes a lubricating oil base stock as a major component, and zinc dialkyl dithio phosphate, a mixture of (i) at least two alkali metal detergents, (ii) at least two alkaline earth metal detergents, or (iii) one or more alkali metal detergents and one or more alkaline earth metal detergents; and a viscosity index improver, as minor components. The lubricating oil has a HTHS viscosity of less than 2.6 cP at 150° C. The composition contains less than 2 weight percent of the viscosity index improver, based on the total weight of the formulated oil or lubricating engine oil.Type: ApplicationFiled: November 13, 2012Publication date: May 30, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventor: ExxonMobil Research and Engineering Company
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Patent number: 8278254Abstract: Lubricated surfaces, lubricant compositions for lubricating a surface, and methods for increasing antiwear properties in lubricants. The lubricated surface is provided by a lubricant composition including a base oil of lubricating viscosity, at least one metal salt of phosphorothioic acid, and an amount of at least one hydrocarbon soluble titanium compound effective to provide an increase in antiwear properties of the lubricant composition. A ratio of titanium metal to phosphorus in the antiwear agent ranges from about 0.3:1 to about 1.5:1.Type: GrantFiled: September 10, 2007Date of Patent: October 2, 2012Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Kenneth J. Garelick, Naresh C. Mathur, Jeffrey M. Guevremont
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Patent number: 8227389Abstract: A lubricant additive produced by various processes, including mixing an organophosphate and an organofluorine compound, reacting an organophosphate and an organofluorine compound, reacting a fluorinated organophosphate and an organofluorine compound (with or without molybendum disulfide), or reacting an organophosphate, a metal halide and an organofluorine compound (with or without molybendum disulfide), to produce a reaction mixture comprising the lubricant additive. Also, a lubricant produced by various processes, including mixing an organophosphate and an organofluorine compound, reacting an organophosphate and an organofluorine compound, reacting a fluorinated organophosphate and an organofluorine compound (with or without molybendum disulfide), or reacting an organophosphate, a metal halide and an organofluorine compound (with or without molybendum disulfide), and adding at least a portion of the reaction mixture to a lubricant base.Type: GrantFiled: October 11, 2007Date of Patent: July 24, 2012Inventors: Pranesh B. Aswath, Harold Shaub, Ramoun Mourhatch, Krupal Patel, David P. Owen, Ronald L. Elsenbaumer
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Patent number: 8076274Abstract: A lubricating oil composition for a heavy duty diesel engine comprises a base oil, at least 0.6 mass % of an ash-free antioxidant and an overbased magnesium-containing detergent. The detergent provides greater than 0.05 mass % Mg based on the mass of the composition. Bore polishing in the engine is reduced for a given level of exhaust gas ash production.Type: GrantFiled: July 10, 2007Date of Patent: December 13, 2011Assignee: Infineum International LimitedInventors: Robin Howard Scott, Robert William Shaw
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Patent number: 8058216Abstract: The present invention provides a grease composition capable of securely preventing an abnormal noise from being generated when it is cold and having a long life at a high temperature, and a rolling bearing in which this grease is enclosed. The grease composition having heat-resistant properties and performance of preventing the generation of a low-temperature abnormal noise contains a base oil, a thickener, and an additive, and is used for a rolling bearing. A worked penetration of the grease composition at 25° C. is 300 or less, and an unworked penetration thereof at ?20° C. is 200 or more. The grease-enclosed rolling bearing has an inner ring, an outer ring, rolling elements interposed between the inner ring and the outer ring, and the above-described grease composition enclosed on a periphery of the rolling elements. The grease-enclosed rolling bearing is used for an automotive electric auxiliary machine.Type: GrantFiled: December 15, 2005Date of Patent: November 15, 2011Assignee: NTN CorporationInventor: Takayuki Kawamura
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Patent number: 7790659Abstract: Disclosed are lubricating oil compositions excellent in friction reducing effect and long drain properties and particularly suitable for internal combustion engines, which comprise a lubricating base oil, a specific phosphorus compound in an amount of 0.005 to 0.5 percent by mass in terms of phosphorus based on the total mass of the composition, and at least one additive selected from the group consisting of (C) metallic detergents, (D) ashless dispersants, and (E) anti-oxidants, and further contains (F) a sulfur-containing organic molybdenum complex and (G) an ashless friction modifier and which satisfy prescribed requirements and have a sulfated ash content not exceeding a specified level.Type: GrantFiled: December 22, 2004Date of Patent: September 7, 2010Assignee: Nippon Oil CorporationInventors: Kazuhiro Yagishita, Akira Yaguchi
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Publication number: 20100173812Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.Type: ApplicationFiled: March 16, 2010Publication date: July 8, 2010Applicant: The Lubrizol CorporationInventors: Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
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Publication number: 20090093384Abstract: The invention relates to an industrial gear formulation containing a high TBN overbased detergent that results in decreasing micropitting for industrial gears.Type: ApplicationFiled: October 3, 2007Publication date: April 9, 2009Applicant: The Lubrizol CorporationInventors: William C. Ward, Brian M. O'Connor, James N. Vinci
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Publication number: 20080166080Abstract: The present invention provides a grease composition capable of securely preventing an abnormal noise from being generated when it is cold and having a long life at a high temperature, and a rolling bearing in which this grease is enclosed. The grease composition having heat-resistant properties and performance of preventing the generation of a low-temperature abnormal noise contains a base oil, a thickener, and an additive, and is used for a rolling bearing. A worked penetration of the grease composition at 25° C. is 300 or less, and an unworked penetration thereof at ?20° C. is 200 or more. The grease-enclosed rolling bearing has an inner ring, an outer ring, rolling elements interposed between the inner ring and the outer ring, and the above-described grease composition enclosed on a periphery of the rolling elements. The grease-enclosed rolling bearing is used for an automotive electric auxiliary machine.Type: ApplicationFiled: December 15, 2005Publication date: July 10, 2008Applicant: NTN CORPORATIONInventor: Takayuki Kawamura
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Publication number: 20080146473Abstract: Provided are formulations, methods of making, and methods of using one or more reaction products of polyisobutylenes and monounsaturated acylating agents of the present invention in a low sulfur, low sulfated ash, and low phosphorus lubricant to enhance piston cleanliness in internal combustion engines.Type: ApplicationFiled: December 19, 2006Publication date: June 19, 2008Inventors: Jeroen Van Leeuwen, Yoshitaka Takeuchi
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Patent number: 7183241Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.Type: GrantFiled: September 19, 2003Date of Patent: February 27, 2007Assignee: ExxonMobil Research and Engineering CompanyInventor: Stanley James Cartwright
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Patent number: 7148186Abstract: The present invention provides a lubricant oil composition, having enhanced wear-preventive characteristics for a diesel engine operating with large quantities of soot in the oil (soot content: 0.2 to 4.0 wt. %), and is especially suitable for a pressure-accumulating (common rail) type diesel engine equipped with an EGR system. The lubricant oil composition containing a base oil composed of a mineral and/or synthetic oil incorporated with at least three additives that are a sulfurized oxymolybdenum dithiocarbamate at 0.03 to 0.50 wt. % as Mo; a zinc dialkyl dithiophosphate at 0.04 to 0.50 wt. % as P; and at least one metallic salt of alkyl salicylate selected from the group consisting of a Ca salt of alkyl salicylate at 0.004 to 1.0 wt. % as Ca, Mg salt of alkyl salicylate at 0.002 to 0.60 wt. % as Mg, and Zn salt of alkyl salicylate at 0.006 to 1.60 wt. % as Zn, all percentages being based on the whole composition.Type: GrantFiled: March 7, 2003Date of Patent: December 12, 2006Assignee: TonenGeneral Sekiyu K.K.Inventors: Toshiaki Kuribayashi, Nobuchika Kawagoishi, Satoshi Ogano
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Patent number: 7053027Abstract: A trunk piston marine diesel engine lubricating oil composition is dispersant-free, has a TBN of 25 or greater, and comprises (A) an oil of lubricating viscosity, (B) an aromatic carboxylate as the sole overbased metal detergent, and (C) an antiwear additive.Type: GrantFiled: May 1, 2001Date of Patent: May 30, 2006Assignee: Infineum International LimitedInventors: Laurent Chambard, Terence Garner
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Patent number: 7018958Abstract: A lubricating oil composition having a total base number of at least about 8, comprising a major amount of oil of lubricating viscosity; an amount of one or more dihydrocarbyl dithiophosphate metal salt introducing into the lubricating oil composition no more than 0.06 wt. % of phosphorus; at least 1.2 wt. % of hindered phenol antioxidant; and boron, and/or a boron-containing compound or compounds in an amount providing the lubricating oil composition with at least 200 ppm by weight of boron, all weight percentages being based on the total weight of the lubricating oil composition.Type: GrantFiled: October 22, 2002Date of Patent: March 28, 2006Assignee: Infineum International LimitedInventors: Stephen Arrowsmith, Nancy Z. Diggs, Andrew J. D. Ritchie, Jorge O. Pain
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Publication number: 20040242435Abstract: A machine tool is used for machining a workpiece in the presence of a cutting oil composition. The machine tool includes a tool base and a hard carbon coating formed on the tool base. The hard carbon coating has 1 atomic % or less of hydrogen. The cutting oil composition contains a base oil and at least one of an ashless fatty-ester friction modifier and an ashless aliphatic-amine friction modifier.Type: ApplicationFiled: May 28, 2004Publication date: December 2, 2004Applicant: NISSAN MOTOR CO., LTD.Inventors: Kimio Nishimura, Yutaka Mabuchi, Tomohiro Kondo
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Publication number: 20040224858Abstract: The present invention provides a low sulfur, low ash, and low phosphorus oil soluble lubricant additive package comprising an overbased metal phenate. Also included in the present invention are lubricating oils comprising the inventive oil soluble lubricant additive package, as well as machines lubricated by such oils. Several methods for lubricating machinery are also disclosed.Type: ApplicationFiled: May 6, 2003Publication date: November 11, 2004Applicant: Ethyl CorporationInventor: Carl K. Esche
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Patent number: 6750184Abstract: The present invention relates to improved lubricant compositions highly resistant to oxidative degradation comprising selected 5-tert.-butyl-4hydroxy-3-methylphenyl substituted fatty acid esters, diphenylamines and zinc dithiophosphates. The compositions as defined above are characterized by superior antioxidative properties. This can be demonstrated in various standard tests such as Deposit and Oxidation Panel Test (DOPT) and Pressurized Differential Scanning Calorimetry (PDSC).Type: GrantFiled: September 19, 2001Date of Patent: June 15, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Marc Ribeaud, Paul Dubs, Serge Laemlin
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Publication number: 20040106527Abstract: This invention relates to a lubricating oil composition used in conjunction with a gasoline fuel having a sulphur content of less than 10 ppm by weight, characterised in that said oil composition has a phosphorus content of no more than 0.05% by weight. The feature of the invention is that the use of a low sulphur fuel enables the amount of anti-wear agents containing phosphorus such as eg ZDDP to be halved without any adverse effect on the anti-wear performance of the lubricating oil.Type: ApplicationFiled: July 25, 2003Publication date: June 3, 2004Inventors: Stuart Pace, Medi Mostafa Hafez, Maria-Laura Kosidowski, Robert Barbour, Alan Mark Schilowitz
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Publication number: 20040077506Abstract: A lubricating oil composition having a total base number of at least about 8, comprising a major amount of oil of lubricating viscosity; an amount of one or more dihydrocarbyl dithiophosphate metal salt introducing into the lubricating oil composition no more than 0.06 wt. % of phosphorus; at least 1.2 wt. % of hindered phenol antioxidant; and boron, and/or a boron-containing compound or compounds in an amount providing the lubricating oil composition with at least 200 ppm by weight of boron, all weight percentages being based on the total weight of the lubricating oil composition.Type: ApplicationFiled: October 22, 2002Publication date: April 22, 2004Inventors: Stephen Arrowsmith, Nancy Z. Diggs, Andrew J. D. Ritchie, Jorge O. Pain
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Publication number: 20040038836Abstract: The lubricating oil of the present invention has a viscosity suitable for use in a diesel engine and includes at least one functionalized olefin polymer, and at least one zinc dialkyl dithiophosphate (ZDDP). The ZDDP is made from a mixture of primary alcohols or a mixture of primary and secondary alcohols, wherein the lubricant has a high boundary film value greater than or equal to 15, and preferably greater than 60, as measured by using a High Frequency Reciprocating Rig (HFRR).Type: ApplicationFiled: August 21, 2002Publication date: February 26, 2004Inventors: Mark Thomas Devlin, Charles A. Passut, Carl K. Esche, John T. Loper
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Patent number: 6656887Abstract: Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: wherein R2, R1, R3 and R4 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X1, X2, X3 and X4 are each independently oxygen or sulfur, but at least one of them is oxygen, and Y1 is a metal atom; and wherein R11 and R12 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X11 and X12are each independently oxygen or sulfur, but at least one of them is oxygen, U is a monovalent metal ion, an ammonium ion or a proton, and k1 is an integer of 1 to 20. Lubricating oil compositions have excellent anti-wear properties and base number maintaining properties.Type: GrantFiled: January 23, 2002Date of Patent: December 2, 2003Assignee: Nippon Mitsubishi Oil CorporationInventors: Kazuhiro Yagishita, Jinichi Igarashi, Takeo Koizumi
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Publication number: 20030216266Abstract: A lubricating oil composition employable in combination with a low sulfur content fuel oil is preferably composed of a base oil having a sulfur content of at most 0.2 wt. %, an ashless dispersant comprising an alkenyl- or alkyl-succinimide or a derivative thereof, a metal-containing detergent containing an organic acid metal salt, a zinc dialkyldithiophosphate, a zinc dialkylaryldithiophosphate, and an oxidation inhibitor selected from the group consisting of a phenol compound, an amine compound, and a molybdenum-containing compound, wherein a ratio of the phosphorus content of the zinc dialkyldithiophosphate to the phosphorus content of the zinc dialkylaryldithiophosphate is in the range of 20:1 to 2:1.Type: ApplicationFiled: May 6, 2003Publication date: November 20, 2003Inventors: Satoshi Hirano, Shigeru Iwamoto, Morikuni Nakazato
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Publication number: 20030171222Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one organic polysulfide comprising less than about 88% dihydrocarbyl trisulfide, from up to about 5% dihydrocarbyl disulfide, and more than about 7 wt. % dihydrocarbyl higher polysulfides, and at least one phosphorus or boron compound, or mixtures of two or more thereof. The invention also relates to concentrates and greases containing the above combination. The invention also relates to methods of making the organic polysulfide.Type: ApplicationFiled: March 5, 2002Publication date: September 11, 2003Inventors: William T. Sullivan, Percy Rohinton Kanga, Thomas Smith Coolbaugh
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Patent number: 6605574Abstract: Disclosed is a grease sealed bearing for automobile that has the high temperature resistance as well as shear stability, and prevents the noise at low temperature as well as the brittle flaking under high speed rotation and high load. The grease comprises a base oil containing a synthesized hydrocarbon oil and one or more ester oils at a weight ratio of 0.1 to 0.49:0.9 to 0.51; 5 to 30% by weight of a urea based thickener, and 0.1 to 10% by weight of dithiozinc phosphate based on the whole grease. The grease sealed bearing for automobile is obtained by sealing a bearing used in a device driven by an automobile engine with the grease.Type: GrantFiled: January 16, 2002Date of Patent: August 12, 2003Assignee: NTN CorporationInventors: Mitsunari Asao, Hidenobu Mikami, Takayuki Kawamura, Takahiro Koremoto, Kunio Takemura
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Patent number: 6583092Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; (B) an alkali or alkaline earth metal salt of a saligenin derivative; (C) an alkali or alkaline earth metal salt of a hydrocarbon-substituted salicylic acid, and (D) a metal salt of a phosphorus-containing compound.Type: GrantFiled: September 12, 2001Date of Patent: June 24, 2003Assignee: The Lubrizol CorporationInventors: Virginia A. Carrick, Gordon D. Lamb, Ewa A. Bardasz, William D. Abraham
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Patent number: 6569818Abstract: A lubricating oil composition having a low P content of 0.01 to 0.1 wt. %, and a sulfated ash of 0.1 to 1 wt. %, which is composed of a) a major amount of mineral base oil having a low S content of at most 0.1 wt. %; b) an ashless alkenyl or alkyl-succinimide dispersant; c) a metal-containing detergent (non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid and/or non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure); d) Zn-DTP; e) an oxidation inhibitor (phenol compound and/or amine compound) and wherein the sulfur content is 0.01 to 0.3 wt %. The lubricating oil composition shows good high temperature detergency notwithstanding its low S, P, and sulfated ash content, and is favorably employable in diesel engines using fuel of an extremely low sulfur content.Type: GrantFiled: May 30, 2001Date of Patent: May 27, 2003Assignee: Chevron Oronite Company, LLCInventors: Morikuni Nakazato, Shigeru Iwamoto, Satoshi Hirano
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Patent number: 6551965Abstract: A lubricating oil composition containing a base oil of lubricating viscosity, overbased sulfurized alkylphenate detergent or its calcium salt, an overbased alkylsulfonate detergent or its calcium salt, an ashless dispersant, and a zinc dialkyldithiophosphate and/or zinc diaryidithiophosphate is described. The lubricating oil composition provides improved heat stability and anti-wear performance in marine diesel engines operated under severe conditions where the cylinder liner temperature may reach 200 to 260° C.Type: GrantFiled: November 14, 2001Date of Patent: April 22, 2003Assignee: Chevron Oronite Company LLCInventors: Hiroyuki Nagamatsu, Shigeru Iwamoto, Hirokazu Fujita
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Patent number: 6531428Abstract: A low phosphorous lubricating oil composition for internal combustion engines comprising an alkylthiocarbamate compound of the formula: wherein each of R1, R2, R3, and R4 independently represents an alkyl group of 1-18 carbon atoms, and (X) represents S, S—S, S—CH2—S, S—CH2CH2—S, S—CH2CH2CH2—S, or S—CH2CH(CH3)—S, and additive compositions and additive packages utilizing the above compound.Type: GrantFiled: April 4, 1994Date of Patent: March 11, 2003Assignee: Chevron Oronite Company LLCInventors: Morikuni Nakazato, Jiro Magarifuchi, Akihiro Mochizuki, Hiroshi Tanabe
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Patent number: 6503872Abstract: This invention relates to a manual transmission lubricants comprising a major amount of an oil of lubricating viscosity, (A) at least one metal thiophosphate, (B) at least one phosphite, and (C) at least one basic salt of an acidic organic compound. In another embodiment, the manual transmission further comprises at least metal salt of a phenol. The lubricants provide the antiwear and extreme pressure protection needed for the manual transmission without harming the manual transmission components.Type: GrantFiled: August 22, 2000Date of Patent: January 7, 2003Assignee: The Lubrizol CorporationInventor: Joseph A. Tomaro
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Publication number: 20020183210Abstract: Continuously variable transmissions are lubricated by supplying to the transmission a composition of an oil of lubricating viscosity and an oil-soluble zinc salt containing at least one hydrocarbyl group of at least 4 carbon atoms. The amount of the zinc salt is sufficient to provide an increased steel-on-steel dynamic coefficient of friction for the composition, being at least 0.125. The composition is substantially free from thiophosphate salts and exhibits a copper corrosion rating of 1B or better (ASTM-130).Type: ApplicationFiled: June 10, 2002Publication date: December 5, 2002Inventors: Roger L. Sowerby, Craig D. Tipton, James L. Sumiejski
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Publication number: 20020142923Abstract: Hindered tert-butylphenolic antioxidant compositions characterized by a low level of volatile and undesirable single-ring tert-butylphenolic antioxidants and a high level of non-volatile multi-ring (or methylene bridged) tert-butylphenolic antioxidants are obtained by reacting a specific mixture of ultra pure ortho-tert-butylphenol (OTBP), ultra pure 2,6-di-tert-butylphenol (DTBP) and formaldehyde in a solvent in the presence of catalyst. These antioxidants are further characterized by having a low level of 2,6-di-tert-butylphenol, low levels of ortho-tert-butylphenol, and trace levels of 2,4,6-tri-tert-butylphenol.Type: ApplicationFiled: March 8, 2002Publication date: October 3, 2002Inventor: Vincent J. Gatto
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Publication number: 20020107152Abstract: A low-phosphorus lubricant comprises:Type: ApplicationFiled: December 5, 2001Publication date: August 8, 2002Inventor: Robert Robson
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Patent number: 6426323Abstract: To provide a lubricating oil composition for continuously variable transmission which ensures both a high coefficient of friction between metals required for a push belt-type CTV oil and an excellent wear preventing property relative to a belt and a pulley. A lubricating oil composition for continuously variable transmission is provided, which comprises a lubricating base oil made of a mineral oil and/or a synthetic oil formulated with a metal detergent and a phosphorus-based wear preventive characterized in that a ratio between a content (ppm) of a metal derived from said metal detergent and based on the total weight of the lubricating oil composition and a total base number (mg KOH/g) ranges 0.75-4.5 (ppm/mg KOH/g), and a ratio between the content (ppm) of the metal derived from said metal detergent and a content of phosphorus derived from said phosphorus-based wear preventive ranges 0.5-2.0 (ppm/ppm).Type: GrantFiled: June 5, 2001Date of Patent: July 30, 2002Assignee: TonenGeneral Sekiyu K.K.Inventors: Takehisa Sato, Takanori Kugimiya
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Publication number: 20020082176Abstract: A trunk piston marine diesel engine lubricating oil composition is dispersant-free, has a TBN of 25 or greater, and comprisesType: ApplicationFiled: May 1, 2001Publication date: June 27, 2002Inventors: Laurent Chambard, Terence Garner
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Patent number: 6362136Abstract: This invention relates to compositions containing a sulfur containing antiwear/extreme pressure agent, basic nitrogen compound or a mixture thereof together with a hydrocarbyl mercaptan. The composition may additionally contain a phosphorus or boron antiwear or extreme pressure agent, a dispersant or an overbased metal salt. The invention also relates to lubricants, functional fluids, and concentrates containing the same. Seals, e.g. nitrile, polyacrylate, and fluoroelastomer, in contact with these composition have reduced deterioration. With the use of these compositions, lubricants, and functional fluids, the seals' useful life is extended.Type: GrantFiled: March 26, 1996Date of Patent: March 26, 2002Assignee: The Lubrizol CorporationInventors: Robert C. Richardson, Donald J. Marn
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Publication number: 20020006879Abstract: This invention relates to a fretting-resisting roller bearing of which the various characteristics are not adversely affected and which achieves a higher temperature and a higher speed as well as a longer life. In a roller bearing comprised of a plurality of rolling elements held between inner and outer races with a cage interposed therebetween, the oil film of lubricating oil of which the dynamic viscosity at 40° C. is 20 to 150 mm2/s is formed on the raceway surfaces of the inner and outer races, the cage and the rolling elements and grease is enclosed.Type: ApplicationFiled: November 25, 1998Publication date: January 17, 2002Inventors: YASUNOBU FUJITA, KEISUKE KIMURA, MICHIHARU NAKA
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Publication number: 20020002118Abstract: An additive for lubricating oil, especially motor oil for internal combustion engines, uses a mixture of overbased zinc alhyl-dithiophosphate, a chlorinated paraffin and a glycol ether. The additive preferable is used in a mineral oil base for reduced wear and lower oil operating temperatures.Type: ApplicationFiled: May 18, 2001Publication date: January 3, 2002Inventor: M. Karl Brandt
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Patent number: 6329328Abstract: The present invention provides for a lubricant oil composition for internal combustion engines for automobiles with enhanced friction loss reduction and is especially suitable for a pressure-accumulating (common rail) type diesel engine equipped with an EGR system. The lubricant oil composition contains a base oil composed of a mineral and/or synthetic oil incorporated with at least four additives of (A) at least one type of organomolybdenum compound selected from the group consisting of sulfurized oxymolybdenum dithiocarbamate, sulfurized oxymolybdenum dithiophosphate, molybdenum phosphate and molybdenum-amine complex at 0.01 to 0.20 wt. % as Mo, (B) zinc dialkyl dithiophosphate at 0.01 to 0.50 wt. % as P, (C) one of Ca and Mg salts of alkyl salicylate at 0.05 to 1.0 wt. % as Ca or Mg and (D) Zn salt of alkyl salicylate at 0.005 to 0.2 wt.Type: GrantFiled: May 30, 2000Date of Patent: December 11, 2001Assignee: Tonen General Sekiyu K. K.Inventors: Katsuya Koganei, Satoshi Ogano, Toshiaki Kuribayashi
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Publication number: 20010044391Abstract: A lubricating oil composition comprising a zinc dithiophosphate and a zinc saturated aliphatic monocarboxylate dissolved in a base oil, wherein the zinc dithiophosphate and zinc saturated aliphatic monocarboxylate are in the ratio of equivalents from 6:1 to 45:1.Type: ApplicationFiled: February 12, 1998Publication date: November 22, 2001Inventors: MICHIO SHIGA, TAKAHIRO MURAMATSU, HIROMICHI MATSUURA
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Patent number: 6187723Abstract: A lubricant composition is described, particularly for engine oils, comprising a base oil of viscosity from 3 to 26 cSt (mm2/s) at 100° C. and an antiwear additive combination comprising (a) an oil soluble or oil dispersible phosphorus-free organo-molybdenum compound, (b) an ashless, sulfur-containing organo-phosphorus compound, and optionally (c) a zinc thiophosphate compound selected from one or more of zinc dialkyldithiophosphate, zinc diaiyldithiophosphate, zinc alkylaiyldithiophosphate and zinc arylalkyldithiophosphate. The molybdenum compound may be a carbamate, e.g., MoDTC but is preferably nitrogen-free, e.g., a carboxylate.Type: GrantFiled: December 12, 1997Date of Patent: February 13, 2001Assignee: Exxon Research and Engineering CompanyInventors: David Gary Lawton Holt, Patrick Desmond Fraser Vernon, John Ian Atherton
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Patent number: 6172012Abstract: A lubricating grease composition includes from 2 to 20% by weight of titanium alkoxide; from 2 to 20% by weight of carboxylic acid other than fatty acid; from 5.0 to 35.0% by weight of fatty acids; from 0.0 to 5.0% by weight of water; from 20 to 90% by weight of oil selected from the group consisting of mineral and synthetic oil; and from 0.01 to 50% of performance additives.Type: GrantFiled: November 9, 1998Date of Patent: January 9, 2001Assignee: Indian Oil Corporation LimitedInventors: Anoop Kumar, S. C. Nagar, Kanta Prasad Naithani, M. M. Rai, Akhilesh Kumar Bhatnagar
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Patent number: RE39382Abstract: The present invention relates to a lubricant composition for a high temperature of which the amount evaporated in a thin film at a high temperature is controlled and of which the fluidity is maintained for a long period of time, and it is a lubricant composition for a high temperature which is obtained by mixing a base oil composition comprising (a) 20 to 100% by weight of a specific aromatic ester and (b) 0 to 80% by weight of another base oil with (c) 0.1 to 10% by weight, based on the total amount of the lubricant composition, of an antioxidant.Type: GrantFiled: December 22, 1999Date of Patent: November 7, 2006Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hideto Kamimura, Hiroshi Nagakawa