Chalcogen Attached Indirectly To The Phosphorus By Nonionic Bonding Patents (Class 508/429)
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Patent number: 9206375Abstract: The invention provides a lubricating grease composition containing the following components (a) and (b): (a) an ionic liquid having as an anion bis(trifluoromethylsulfonyl)imide; and (b) as a thickener a diurea compound of formula (1): R1NH—CO—NH—R2-NH—CO—NH—R3 (1) wherein R2 is an aromatic hydrocarbon group having 6 to 15 carbon atoms; and R1 and R3, which may be the same or different are each an aromatic hydrocarbon group having 6 to 12 carbon atoms, an alicyclic hydrocarbon group having 6 to 12 carbon atoms or a straight-chain alkyl group having 8 to 20 carbon atoms, with the groups represented by R1 and R3 containing the aromatic hydrocarbon group in an amount of 50 to 100 mol %. The lubricating grease composition of the invention can favorably be used under ultra-high vacuum, and under high temperatures of 200 to 300° C.Type: GrantFiled: July 23, 2012Date of Patent: December 8, 2015Assignee: KYODO YUSHI CO., LTD.Inventors: Makoto Hayama, Setsuo Sasaki
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Publication number: 20150051126Abstract: A lubricating oil composition for an air compressor according to the present invention contains a synthetic base oil, and one or more amine-based antioxidants selected from the group consisting of asymmetric diphenylamine-based compounds, phenylnaphthylamine-based compounds, asymmetric dinaphthylamine-based compounds, dialkyl monophenylamine-based compounds and dialkyl mononaphthylamine-based compounds.Type: ApplicationFiled: March 26, 2013Publication date: February 19, 2015Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Tokue Sato
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Patent number: 8835365Abstract: Provided is a lubricating oil composition for round die rolling, which is obtained by blending a base oil with: (A) 0.5 to 40 mass % of a monoester having 13 to 48 carbon atoms (a-1) and/or 0.5 to 30 mass % of a fatty dicarboxylate having 13 to 34 carbon atoms (a-2); (B) 0.01 to 10 mass % of a thiadiazole compound; (C) 0.01 to 15 mass % of a thiophosphite; and (D) 0.01 to 5 mass % of a triazole compound. The lubricating oil composition for round die rolling shows excellent processing performance without using any chlorine-based compound, and is able to improve lubricity in a bearing to lengthen the life of the bearing.Type: GrantFiled: March 25, 2009Date of Patent: September 16, 2014Assignees: Idemitsu Kosan Co., Ltd., Nissei Co., Ltd.Inventors: Akihiro Shishikura, Toshinaka Shinbutsu, Shuichi Amano
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Patent number: 8569216Abstract: A Group IV/Group V lubricating composition providing improved antioxidation performance comprises from 5 wt. % to 40 wt. % of a Group V base oil component, such as alkylated naphthalene, at least 30 wt. % of a Group IV base oil component, such as one or more polyalphaolefin base stocks, and from 0.25 wt. % to 1.5 wt. % of a trithiophosphate-containing compound. The trithiophosphate-containing compound is preferably C30H57O7PS3. The lubricating composition includes not greater than 5 wt. % of a Group I, Group II, or Group III base oil component, and, preferably not greater than 10 ppm heavy metal component. The lubricating composition preferably has a kinematic viscosity of from 20 cSt to 1,000 cSt at 40° C. and a viscosity index (VI) of from 130 to 200.Type: GrantFiled: June 16, 2011Date of Patent: October 29, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: David A. Blain, Liehpao Oscar Farng, Eugenio Sanchez, Michael R. Douglass, Angela S. Galiano-Roth, James T. Carey
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Patent number: 8188018Abstract: A lubricating oil composition for use in oil-impregnated sintered bearings together with a resin member having C?C bonds or C?O groups in the molecules, which comprises a base oil comprising a synthetic hydrocarbon oil as the main component, and 0.1-30% by weight of an ester-based oil on the basis of total composition, and free from zinc dialkyldithiophosphate and molybdenum dialkyldithiocarbamate, where the synthetic hydrocarbon oil as the main component of the base oil has substantially no adverse effect on resin, can minimize an adverse effect on various metal species of sintered materials by suppressing a mixing amount of a wear inhibitor or an extreme pressure agent to a minimum, without deteriorating a good lubricability required for the lubricating oil in oil-impregnated sintered bearings.Type: GrantFiled: April 18, 2007Date of Patent: May 29, 2012Assignee: NOK Kluber Co., Ltd.Inventors: Miyuki Hashida, Wataru Sawaguchi, Toshio Nitta
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Patent number: 8178004Abstract: A composition and method for forming a hydrophobic coating on a metallic substrate are disclosed. The composition comprises: (a) a perfluorinated acid, (b) a surfactant, (c) an organic solvent, and (d) water. The composition is applied to the metal surface, the organic solvent and water permitted to evaporate and coalesce to form a substantially continuous film that preferably is in the form of a self-assembled monolayer covalently bonded to the surface of the substrate.Type: GrantFiled: June 17, 2009Date of Patent: May 15, 2012Assignee: Aculon, Inc.Inventor: Eric L. Hanson
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Publication number: 20110017574Abstract: The present invention relates to a method of lubricating a conveyor belt wherein a lubricant concentrate containing at least one fatty acid is employed in a dry lubrication process at a pH-value of <4. Afterwards, a liquid composition having a pH-value >5 is applied to the surface of the conveyor belt on which the lubricant concentrate has been applied earlier.Type: ApplicationFiled: March 25, 2009Publication date: January 27, 2011Applicant: DIVERSEY, INC.Inventors: Holger Theyssen, Stefan Grober, Harry Kany, Markus Wloka
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Patent number: 7759294Abstract: Lubricant compositions having improved load carrying capacity comprising an extreme pressure compound comprising a sulfur-containing compound, a load carrying capacity enhancing combination comprising a hydrocarbylamine compound and an alkylphosphorothioate compound, a friction modifier compound, and a diluent or base oil as applicable. These lubricant compositions can be used as industrial oils well-suited for the demands of geared device applications, such as in wind turbine gear-boxes and automotive gears and axles.Type: GrantFiled: October 24, 2003Date of Patent: July 20, 2010Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Helen T. Ryan
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Patent number: 7741259Abstract: Environmentally safe and compatible fluids that are useful as lubricants, and especially as hydraulic fluids, in mobile machinery are formulated to be non-contaminating when accidentally contacted with surrounding vegetation, and removable from vegetation by simply washing the vegetation with tap water. The fluids of the invention are polyalkylene glycol-based and having an ethylene oxide to propylene oxide ratio of from about 68:32 to about 78:22.Type: GrantFiled: April 28, 2006Date of Patent: June 22, 2010Assignee: EnBio Industries, Inc.Inventor: Daniel M. da Costa
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Publication number: 20100152078Abstract: A lubricant additive composition having environmentally compatible characteristics as defined by European Council Directive 67/548/EEC is disclosed. Such a composition may include components selected from non-persistent materials, non-bioaccumulative materials, or non-toxic materials.Type: ApplicationFiled: February 12, 2010Publication date: June 17, 2010Inventors: Ian MacPherson, Ann Pettigrew
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Publication number: 20100093577Abstract: A non-aqueous lubricating oil composition comprises a major amount of a base oil and a minor amount of an additive which is present in solution in the base oil and is a non-halide, non-aromatic ionic liquid which is a salt of general formula C+A?, with the cation, C+, being a quaternary phosphonium or quaternary ammonium ion having four hydrocarbyl groups, optionally containing heteroatoms, which hydrocarbyl groups do not all have the same number of carbon atoms, there being at least one long chain hydrocarbyl group having greater than 4 carbon atoms and at least one short chain hydrocarbyl group having fewer carbon atoms than each of the long chain hydrocarbyl groups, and the anion, A?, comprising at least one oxygen atom and having an ionic head group attached to at least one alkyl or alicyclic hydrocarbyl group which has at least four carbon atoms and optionally at least one heteroatom. The ionic liquid may be used as an anti-wear component in a lubricating oil composition.Type: ApplicationFiled: December 17, 2007Publication date: April 15, 2010Inventors: Craig Ritchie, Kenneth Richard Seddon
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Publication number: 20100009878Abstract: The present invention aims to provide a lubricating oil composition capable of use in for example the bearings of a high-speed main shaft having ceramics ball antifrication bearings operating under severe conditions of high speed and high load. To this end the present invention provides a lubricating oil composition, in particular for lubrication of ceramics, comprising a base oil; and at least one additive selected from the group consisting of: (i) an acid amide obtainable by reacting an amine with a saturated monocarboxylic acid having from 12 to 30 carbons or an unsaturated monocarboxylic acid having from 18 to 24 carbons; (ii) sarcosinic acid; and (iii) an aspartic acid derivative.Type: ApplicationFiled: January 23, 2008Publication date: January 14, 2010Applicant: SHOWA SHELL SEKIYU K.K.Inventors: Yoshiharu Baba, Toru Ikai
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Publication number: 20090186785Abstract: The lubricating oil composition of the invention includes a base oil composed of mineral oil and/or synthetic oil, an amine antioxidant (A-1) in an amount of 800 ppm or more as reduced to the total amount of nitrogen, and a compound containing phosphorus and/or sulfur (A-2). The invention provides a compressor oil which realizes thermal/oxidation stability, resistance to sludge formation, lubricity, long service life, and water separation at high levels.Type: ApplicationFiled: December 7, 2006Publication date: July 23, 2009Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Hideto Kamimura
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Publication number: 20090048129Abstract: To provide a nanoparticle-containing lubricating oil composition which demonstrates a low friction coefficient and realizes a further fuel economy. A nanoparticle-containing lubricating oil composition comprising a base oil, an additive having hydroxyl group, and nanoparticle. A nanoparticle-containing lubricating oil composition comprising a base oil, an ashless friction modifier having hydroxyl group, and nanoparticle. A nanoparticle-containing lubricating oil composition comprising a base oil, an additive having hydroxyl group, and nanoparticle having a particle diameter of 1 to 100 nm. A nanoparticle-containing lubricating oil composition comprising a base oil, an ashless friction modifier having hydroxyl group, and nanoparticle having a particle diameter of 1 to 100 nm.Type: ApplicationFiled: August 7, 2008Publication date: February 19, 2009Inventors: Yutaka Mabuchi, Akira Nakagawa
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Publication number: 20090018037Abstract: [Object] To provide a nanoparticle-containing lubricating oil composition which demonstrates a low friction coefficient and realizes a further fuel economy. [Solving Means] A nanoparticle-containing lubricating oil composition comprising a base oil, an additive having hydroxyl group, and nanoparticle. A nanoparticle-containing lubricating oil composition comprising a base oil, an ashless friction modifier having hydroxyl group, and nanoparticle. A nanoparticle-containing lubricating oil composition comprising a base oil, an additive having hydroxyl group, and nanoparticle having a particle diameter of 1 to 100 nm. A nanoparticle-containing lubricating oil composition comprising a base oil, an ashless friction modifier having hydroxyl group, and nanoparticle having a particle diameter of 1 to 100 nm.Type: ApplicationFiled: July 27, 2006Publication date: January 15, 2009Inventors: Yutaka Mabuchi, Akira Nakagawa
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Patent number: 7385880Abstract: A grease composition for a precision instrument comprising a lithium soap grease or a urea grease, and an anti-wear agent, wherein the lithium soap grease and the urea grease are each a grease having no hydroxyl group in a molecule, and the anti-wear agent is contained in an amount of 0.1 to 20% by weight based on the total amount of the grease composition. By the use of the grease composition for a sliding mechanism of a precision instrument such as a watch, an appropriate slip torque can be obtained, and the precision instrument such as a watch can operate stably.Type: GrantFiled: August 19, 2003Date of Patent: June 10, 2008Assignee: Citizen Holdings Co., Ltd.Inventor: Yuji Akao
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Publication number: 20080119377Abstract: The lubricant compositions of the present disclosure comprises a base oil and an additive composition comprising, for example, a detergent and an additive chosen from a phosphorus-containing compound, a friction modifier, and a dispersant, wherein the additive composition exhibits at least one of reduced thin-film friction and increased fuel efficiency as compared to an additive composition that is devoid of the detergent and the additive. As a further example, the additive composition can comprise a friction modifier and a dispersant, wherein the additive composition exhibits at least one of reduced thin-film friction and increased fuel efficiency as compared to an additive composition that is devoid of the friction modifier and the dispersant. Methods of using the additive and lubricant compositions are also disclosed.Type: ApplicationFiled: November 22, 2006Publication date: May 22, 2008Inventors: Mark T. DEVLIN, Tze-chi Jao
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Patent number: 6828284Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: GrantFiled: August 6, 2001Date of Patent: December 7, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Jon Lee Howell, Erik William Perez
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Patent number: 6797679Abstract: Provided is a lubricant composition prepared by adding, to a base oil, (a) from 0.01 to 5% by mass, based on the composition, of a phosphate, (b) from 0.005 to 1% by mass of an amine salt of an acid phosphate and (c) from 0.01 to 1% by mass of a sulfur-containing extreme-pressure agent. The composition is favorable for non-zinc hydraulic oil, which has good oxidation resistance, sludge resistance and wear resistance and further has improved extreme pressure resistance and prolonged fatigue life.Type: GrantFiled: December 10, 2002Date of Patent: September 28, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hiroshi Kawasaki, Nobuaki Watanabe
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Patent number: 6638898Abstract: A process for the preparation of multi-functional additive, amino di(alkylcyclohexyl) phosphorodithioate, for use as an additive in a lubricant composition so as to impart improved coefficient of friction, wear reduction, antioxidant and extreme pressure properties, including the steps of (a) hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to fully hydrogenate the olefinic chain and aromatic ring of the precursor; (b) reacting fully hydrogenated technical cashew nut shell liquid with phosphorus pentasulfide to obtain unpolymerized hydrogenated cashew nut shell liquid phosphorodithioic acid, the reaction being carried out at a temperature ranging from 20 to 140° C. ; and (c) condensing the unpolymerized fully saturated cashew nut shell liquid phosphorodithioic acid with at least one amine to obtain the amino di(alkylcyclohexyl) phosphorodithioate.Type: GrantFiled: March 30, 2001Date of Patent: October 28, 2003Assignee: Indian Oil Corporation LimitedInventors: Krishan Kumar Swami, Shanti Parkash, Rakesh Sarin, Deepak Kumar Tuli, Akhilesh Kumar Bhatnagar
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Publication number: 20030073588Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: ApplicationFiled: August 6, 2001Publication date: April 17, 2003Inventors: Jon Lee Howell, Erik Williams Perez
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Patent number: 6548455Abstract: The invention relates to a chain lubricant for conveyor and transport systems which is comprised of water, surfactants, disinfecting agents as well as conventional auxiliary agents and additives. According to the invention, an anionic surfactant is used as the surfactant and chlorine dioxide is used as the disinfecting agent.Type: GrantFiled: June 26, 2001Date of Patent: April 15, 2003Assignee: Bactria Industriehygiene-Service GmbH & Co. KGInventors: Michael Sperling, Guenter Stroh, Heinrich Hix, Juergen Gutknecht
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Patent number: 6531429Abstract: The invention relates to improved compositions comprising thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters and oil additives from the group of the polyol partial esters, amines and epoxides, and also to the use of those lubricant compositions in improving the performance properties of lubricants, such as greases, metal-working fluids, gear fluids or hydraulic fluids. Thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters are present in the compositions preferably in a concentration of less than 400 ppm.Type: GrantFiled: August 17, 2001Date of Patent: March 11, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Fletschinger, Peter Rohrbach, Peter Collen Hamblin, Dudley Clark, Marc Ribeaud
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Patent number: 6486102Abstract: An emulsion used to lubricate the surface of a steel sheet, comprising an additive corresponding to one of the following formulae: (R1-2—O—)1-2—PSS—(CH2)n—COO—(CH2)m—CH3, (R1-2—O—)1,2—PSS—CH2-&phgr;-O—H, (R1,2—O—)1,2—PSS—CH2-&phgr;-O—(CH2)n, —COO—(CH2)m, —CH3, where PSS designates a dithiophosphate function. The naked sheets of steel that are treated with said emulsion have very good tribological properties even when the density of the emulsion thus applied is less than or equal to 1 g/m2 when dry. The invention enables dry-looking oiled sheets to be obtained, whereby no re-oiling is required before forming even by die stamping.Type: GrantFiled: September 28, 2001Date of Patent: November 26, 2002Assignee: UnisorInventors: Hervé Derule, Hubert Jacobs, Amadou Dicko, Peggy Guinet
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Publication number: 20020165102Abstract: There is disclosed a lubricating oil composition for cellulose base wet friction material which comprises a base oil blended with (A) a boron-containing imide base dispersant (e.g. boron treated polyalkenyl succinimide) having a weight-average molecular weight in the range of 500 to 3000 and having a ratio by weight of boron to nitrogen (B/N) in the range of 0.1 to 1.5 in such a blending amount that the boron content and the nitrogen content each derived from the component (A) are made to be at least 60 ppm by weight and at least 100 ppm by weight, respectively based on the base oil. The above lubricating oil composition enhances peeling resistant durability for a friction material, especially a cellulose base friction material without impairing the wear resistance or scoring resistance of a steel material element, and is well suited for use in a cellulose base friction material for a starting and running device and a transmission clutch that are used in an automatic transmission of an automobile.Type: ApplicationFiled: May 7, 2002Publication date: November 7, 2002Applicant: Idemitsu Kosan Co., Ltd.Inventors: Hitoshi Hata, Hisashi Machida
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Publication number: 20020128159Abstract: A process for the preparation of multi-functional additive, amino di(alkylcyclohexyl0) phosphorodithioate, for use as an additive in a lubricant composition so as to impart improved coefficient of friction, wear reduction, antioxidant and extreme pressure properties, including the steps of (a) hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to fully hydrogenate the olefinic chain and aromatic ring of the precursor; (b) reacting fully hydrogenated technical cashew nut shell liquid with phosphorus pentasulfide to obtain unpolymerized hydrogenated cashew nut shell liquid phosphorodithioic acid, the reaction being carried out at a temperature ranging from 20 to 140° C. ; and (c) condensing the unpolymerized fully saturated cashew nut shell liquid phosphorodithioic acid with at least one amine to obtain the amino di(alkylcyclohexyl) phosphorodithioate.Type: ApplicationFiled: March 30, 2001Publication date: September 12, 2002Inventors: Krishan Kumar Swami, Shanti Parkash, Rakesh Sarin, Deepak Kumar Tuli, Akhilesh Kumar Bhatnagar
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Publication number: 20020032129Abstract: Transmission fluid compositions comprising a zinc detergent and at least one phosphorus-containing additive have enhanced performance capabilities. The use of the zinc detergent and the phosphorus-containing additive provide transmission fluids that exhibit high steel-on-steel coefficients of friction, particularly useful in continuously variable transmissions (CVT).Type: ApplicationFiled: August 11, 1999Publication date: March 14, 2002Inventors: SAMUEL H. TERSIGNI, SANJAY SRINIVASAN, DAVID L. STRAIT
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Patent number: 6316394Abstract: A synthetic aqueous machining fluid admixture, that is free of sulfur containing and chlorine containing lubricants, and usable in heavy duty machining (e.g. stamping, punching and drawing) operations comprises a) water, b) a water soluble or dispersible fatty acid or water soluble or dispersible fatty acid salt, c) a water soluble or dispersible ethylene oxide propylene oxide copolymer having at least one terminal hydroxyl group or water soluble or dispersible derivative of an ethylene oxide propylene oxide copolymer and d) a water soluble or dispersible organic phosphate ester. Methods for heavy duty machining comprise the steps of applying a force to a workpiece by a tool contacting the workpiece and applying the synthetic aqueous fluid admixture to the interface between the tool and workpiece. The fluid exhibits safety and environmental advantages in use compared to prior art fluids comprising vanishing oils while providing equal or superior lubricity.Type: GrantFiled: January 29, 2001Date of Patent: November 13, 2001Assignee: Milacron Inc.Inventors: Myrna J. Morgan, Deli Gong
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Patent number: 6103675Abstract: The invention relates to the use of mixtures of one or more phosphoric esters of the formula (I) with one or more amines of the formula (II) as extreme pressure additives in water-immiscible cooling lubricants ##STR1## in which the substituents have the meaning defined in the description.Type: GrantFiled: March 11, 1998Date of Patent: August 15, 2000Assignee: Clariant GmbHInventors: Peter Pyka, Barbara Vollnhals, Bernd Pomrehn
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Patent number: 6100226Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one sulfur and phosphorus containing composition, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and an aliphatic group substituted carboxylic acid or anhydride thereof, wherein the aliphatic group contains at least about 12 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C., the phosphorus and sulfur compound being described in detail herein.Type: GrantFiled: May 20, 1998Date of Patent: August 8, 2000Assignee: The Lubrizol CorporationInventors: Edward J. Konzman, Gary W. Wiggins
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Patent number: 6066602Abstract: The lubricant of this invention is a combination of a PLURONIC.RTM. polyol and a phospholipid. The lubricant is applied to the surface to be lubricated by forming a solution of water and the lubricant. This solution may also include Vitamin E or its derivative. In addition, a solution stabilizer and an antimicrobial agent may be used to clarify the solution and to inhibit microbial growth in the solution.Type: GrantFiled: August 7, 1997Date of Patent: May 23, 2000Assignee: Becton Dickinson and CompanyInventors: Mohammad A. Khan, Azhar J. Khan
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Patent number: 6063742Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one metal salt of a sulfur and phosphorus containing acid, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and optionally, an aliphatic group substituted carboxylic acid, anhydride thereof and aliphatic group substituted lactone, wherein the aliphatic group contains at least about 8 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C.Type: GrantFiled: March 1, 1999Date of Patent: May 16, 2000Assignee: The Lubrizol CorporationInventor: Edward J. Konzman
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Patent number: 5985803Abstract: Disclosed is a metal working composition comprising a major amount of water and a minor amount of an additive comprising(A) at least one carboxylic ester characterized by the formula ##STR1## wherein R.sup.0 is hydrogen, methyl, ethyl, --CH.sub.2 COOR.sup.2 or --CH.sub.2 CO(OCHR.sup.5 CH.sub.2).sub.n OR.sup.6, R.sup.1 is hydrogen, methyl or ethyl, R.sup.2 is an alkyl group containing from 1 to 12 carbon atoms, R.sup.3 is hydrogen or --CO(OCHR.sup.5 CH.sub.2).sub.n OR.sup.6, R.sup.5 is hydrogen or a methyl group, R.sup.6 is an aliphatic group containing from 4 to 30 carbon atoms or a phenyl or aliphatic substituted phenyl group wherein the aliphatic substituent contains from 1 to 8 carbon atoms, R.sup.4 is --COOR.sup.2, or --CO(OCHR.sup.5 CH.sub.2).sub.n OR.sup.6 and n is an integer of from 1 to 30; with the proviso that when R.sup.0 does not equal hydrogen, methyl or ethyl that R.sup.1 and R.sup.Type: GrantFiled: December 5, 1997Date of Patent: November 16, 1999Assignee: The Lubrizol CorporationInventors: Syed Q. A. Rizvi, Carmen V. Luciani
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Patent number: 5968880Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 are oxygen or sulfur, provided that at least one of X.sub.1, X.sub.2, and X.sub.3 is sulfur; R.sub.1 is a hydrocarbyl group; R.sub.2 is an alkylene group; R.sub.3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester.Type: GrantFiled: October 23, 1997Date of Patent: October 19, 1999Assignee: The Lubrizol CorporationInventors: Naresh Chand Mathur, Mary Galic Raguz
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Patent number: 5916850Abstract: A process for the preparation of amino di(alkylaryl) phosphorodithioate for use as an additive in a lubricant composition so as to impart improved coefficient of friction, wear reduction, antioxidant and extreme pressure properties, including the steps of(a) reacting a starting material selected from the group consisting of distilled cashew nut shell liquid and distilled hydrogenated cashew nut shell liquid with phosphorus pentasulfide to obtain unpolymerized cashew nut shell liquid phosphorodithioic acid, the reacting being carried out at a temperature ranging from 40 to 80.degree. C. when the starting material is distilled cashew nut shell liquid and at a temperature ranging up to 140.degree. C. and above when the starting material is distilled hydrogenated cashew nut shell liquid; and(b) condensing the unpolymerized cashew nut shell liquid phosphorodithioic acid with at least one amine to obtain the amino di(alkylaryl) phosphorodithioate.Type: GrantFiled: November 6, 1997Date of Patent: June 29, 1999Assignee: Indian Oil Corporaton LimitedInventors: Deepak Kumar Tuli, Rakesh Sarin, Madan Mohan Rai, Akhilesh Kumar Bhatnagar
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Patent number: 5763371Abstract: Improved lubricating oil for high pressure polyethylene compressors contains white mineral oil or synthetic oil blended with oleic acid in an amount less than 15 wt %, and preferably 0.5-5 wt. %, an EP additive such as a phosphorus containing compound made by phosphating mono or diglycerides derived from vegetable oils and having one or two neutralized acid sites, and no more than 1.0 wt. %, and preferably no more than 0.1 wt. %, of an antioxidant of the phenolic type, and a polybutene viscosity builder in the amount necessary to achieve the expected or desired viscosity. The lubricating compressor oil according to the invention has improved lubricity and gives wear protection over the whole range of lubricating regimes including EP conditions.Type: GrantFiled: October 18, 1996Date of Patent: June 9, 1998Assignee: Witco CorporationInventors: Anna Debska-Chwaja, Albert Benson, Paul G. Tietze
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Patent number: 5667349Abstract: An improved process for making metallic pull tabs is provided. In accordance with the improved pull tab making process comprising the steps of feeding a strip of metal into a pull tab forming die and forming the metallic pull tab the step of forming the pull tab is carried out in the presence of an aqueous based lubricant composition comprising water, an alkaline pH producing substance selected from the group consisting of alkali metal hydroxides, water soluble or dispersible aliphatic amines and water soluble or dispersible hydroxyl substituted aliphatic amines, an emulsifier, a water soluble or dispersible alpha (p-nonylphenyl) omega hydroxypoly (oxyethylene) phosphate ester and a water soluble or dispersible aliphatic diol.Type: GrantFiled: April 26, 1995Date of Patent: September 16, 1997Assignee: Cincinnati Milacron Inc.Inventors: Henry Turchin, Cindy S. Dinevski, Kevin H. Tucker