Divalent Chalcogen Double Bonded Directly To The Phosphorus Patents (Class 508/433)
  • Patent number: 6660696
    Abstract: Phosphorothionate derivatives derived from cashew nut shell liquid (CNSL) for use as an thermally stable antioxidant, antiwear, friction reducing and extreme pressure additive in a lubricant composition are synthesized by the steps of (a) partially hydrogenating distilled technical cashew nut shell liquid with palladium or nickel or platinum catalyst; to hydrogenate the olefinic chain; (b) reacting partially hydrogenated technical cashew nut shell liquid with phosphorus trihalide and sulphur, the reaction being carried out at a temperature ranging from 20 to 220° C. A lubricant containing a major proportion of a material selected from the group consisting of an oil of lubricating viscosity or a grease; and remainder an additive including CNSL phosphorothionate derivative, prepared by the foregoing process.
    Type: Grant
    Filed: June 20, 2002
    Date of Patent: December 9, 2003
    Assignee: Indian Oil Corporation Limited
    Inventors: Rajeev Ranjan, Ajay Kumar Arora, Rakesh Sarin, Deepak Kumar Tuli, Ram Prakash Verma, Akhilesh Kumar Bhatnagar
  • Patent number: 6660695
    Abstract: A power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure R1—X2—P(:X1)(R2X3)—X—R5 where R1, and R2 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen. R1 and R2 may also contain substituent hetero atoms, in addition to carbon and hydrogen, such as chlorine, sulfur, oxygen or nitrogen; wherein R5 is derived from a reactive olefin and can be either CH2—CHR—C(:O)O—R6; —CH2—CR7HR8; or R9—OC(:O)CH2—CH—C(:O)O—R10 where R is H or the same as R1, R6, R7, R9 and R10 are the same as R1 and R8 is a phenyl or alkyl or alkenyl substituted phenyl moiety, the moiety having from 6 to 30 carbon atoms, (b) a calcium detergent, and (c) a friction modifier.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: December 9, 2003
    Assignee: Infineum International Ltd.
    Inventors: Raymond F. Watts, Katherine M. Richard
  • Publication number: 20030220207
    Abstract: According to the invention, a self contained vibration resistant bearing is provided. The bearing is coated with a film formed from a rust preventive oil having an extreme-pressure additive content of 0.5 to 10% by weight. Desirably the extreme-pressure additive is an organometallic compound, an organofatty acid compound, organofatty acid derivative, an organophosphoric acid compound or a combination of two(2) or more of such compounds. When a rust preventive film that contains an extreme-pressure additive is formed all over bearing components during the assembling process, the bearing components are fully protected even from sudden vibrations from transportation.
    Type: Application
    Filed: May 16, 2003
    Publication date: November 27, 2003
    Inventors: Motoharu Akiyama, Noriyuki Yoshimura
  • Patent number: 6642187
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) at least one organic polysulfide comprising at least about 90% dihydrocarbyl trisulfide, from about 0.1% up to about 8% dihydrocarbyl disulfide, and less than about 5% dihydrocarbyl higher polysulfides, and (B) at least one overbased metal composition, at least one phosphorus or boron compound, or mixtures of two or more thereof. The invention also relates to concentrates and greases containing the above combination. The invention also relates to methods of making the organic polysulfide.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: November 4, 2003
    Assignee: The Lubrizol Corporation
    Inventors: James J. Schwind, Ross L. Beebe
  • Patent number: 6642188
    Abstract: The lubricating compositions of the present invention are designed for use in a four stroke outboard marine engine and contain an oil of lubricating viscosity, an ashless dispersant, a metal detergent, a rust inhibitor, a relatively high amount of ZDDP, and an amount of a molybdenum compound sufficient to provide the composition with 15-1,000 ppm by mass of molybdenum. An amount of about 15 ppm to 1,000 ppm by mass of molybdenum from a molybdenum compound has been found to be effective as an antiwear agent in combination with the high levels of ZDDP.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: November 4, 2003
    Assignee: Infineum International Ltd.
    Inventors: Rolfe J. Hartley, Salvatore Rea, Malcolm Waddoups
  • Publication number: 20030186821
    Abstract: A gas engine lubricating oil composition having a boron content of more than 95 ppm, the gas engine lubricating oil composition comprising: a major amount of a lubricating oil having a viscosity index of 80 to 120, and including at least 90 mass percent of saturates and 0.03 mass percent or less of sulphur; and at least one metal detergent.
    Type: Application
    Filed: March 3, 2003
    Publication date: October 2, 2003
    Inventors: Yolanda Owen, Laurent Chambard
  • Patent number: 6627584
    Abstract: The present invention provides a power transmission lubricating composition containing a base oil, a dispersant, a lubricant additive produced by the reaction of a dihydrocarbyldithio-phosphoric acid and a hydrocarbyl acrylate, and optionally a viscosity index improver. Improved friction performances in automatic and continuously variable transmissions are achieved by utilizing the fluids of the present invention in ash-free lubricating oil compositions for transmissions and axles.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: September 30, 2003
    Assignee: Ethyl Corporation
    Inventor: Nubar Ozbalik
  • Publication number: 20030181339
    Abstract: An power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure: R1—X2—P(:X1)(R2X3)—X—R5 where R1, R2, R3, and R4 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen.
    Type: Application
    Filed: March 15, 2002
    Publication date: September 25, 2003
    Inventors: Raymond F. Watts, Katherine M. Richard
  • Publication number: 20030166478
    Abstract: A refrigerating machine oil composition according to the invention comprises an alicyclic polycarboxylic acid ester compound obtained from the following compounds (a) to (c):
    Type: Application
    Filed: January 23, 2003
    Publication date: September 4, 2003
    Inventors: Yuji Shimomura, Katsuya Takigawa
  • Publication number: 20030158052
    Abstract: To provide a pivot assembly bearing enable maintain it's capabilities longer under frequent quick start and quick stop, the pivot assembly bearing is dispensed a grease composition comprising a base oil, a thickener and an extreme-pressure agent.
    Type: Application
    Filed: February 12, 2003
    Publication date: August 21, 2003
    Inventor: Motoharu Akiyama
  • Publication number: 20030158050
    Abstract: Provided is a lubricant composition prepared by adding, to a base oil, (a) from 0.01 to 5% by mass, based on the composition, of a phosphate, (b) from 0.005 to 1% by mass of an amine salt of an acid phosphate and (c) from 0.01 to 1% by mass of a sulfur-containing extreme-pressure agent. The composition is favorable for non-zinc hydraulic oil, which has good oxidation resistance, sludge resistance and wear resistance and further has improved extreme pressure resistance and prolonged fatigue life.
    Type: Application
    Filed: December 10, 2002
    Publication date: August 21, 2003
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Hiroshi Kawasaki, Nobuaki Watanabe
  • Publication number: 20030153469
    Abstract: The present invention provides a power transmission lubricating composition containing a base oil, a dispersant, a lubricant additive produced by the reaction of a dihydrocarbyldithio-phosphoric acid and a hydrocarbyl acrylate, and optionally a viscosity index improver. Improved friction performances in automatic and continuously variable transmissions are achieved by utilizing the fluids of the present invention in ash-free lubricating oil compositions for transmissions and axles.
    Type: Application
    Filed: January 28, 2002
    Publication date: August 14, 2003
    Inventor: Nubar Ozbalik
  • Publication number: 20030139300
    Abstract: Fluorinated dialkyl dithiophosphoric acids according to formula (I) and metallic salts thereof: 1
    Type: Application
    Filed: December 4, 2002
    Publication date: July 24, 2003
    Inventor: Richard P. Beatty
  • Publication number: 20030125219
    Abstract: A lubricating oil composition which comprises at least one compound selected from specific cyclic organic phosphorus compounds is disclosed.
    Type: Application
    Filed: June 27, 2002
    Publication date: July 3, 2003
    Inventors: Toshinori Tazaki, Hideto Kamimura, Shuichi Sakanoue
  • Publication number: 20030109387
    Abstract: The peak-torque descending composition of the present invention contains a certain amount of an extreme pressure agent comprising at least neutral phosphate esters and/or neutral phosphite esters in a solvent comprising hydrocarbons and/or ethers. Further, a certain corrosion inhibitor maybe contained. The part having a sliding portion of the present invention is surface-treated with the above composition. The process for producing a component or precision machine having a sliding portion comprises immersing a part having a sliding portion in the above composition to adhere or absorb the composition onto the surface of the part, then immediately, taking out the part from the composition, followed by drying, and subsequently assembling a component or precision machine using the part.
    Type: Application
    Filed: December 27, 2002
    Publication date: June 12, 2003
    Inventors: Yuji Akao, Masayuki Koike
  • Publication number: 20030087770
    Abstract: Emulsifier system containing a) ethoxylates/propoxylates of fatty alcohols with 8 to 18 C atoms in the alcohol with 2 to 6 ethylene oxide units and 4 to 8 propylene oxide units, b) fatty alcohols and/or fatty alcohol propoxylates with 12 to 24 C atoms in the alcohol and 0 to 3 propylene oxide units and/or distillation residue of these fatty alcohols and c) phosphates, selected from: c1) mono- and/or diesters of phosphoric acid with alkanols with 10-20 C atoms, c2) mono- and/or diesters of phosphoric acid with ethoxylated and/or propoxylated alkanols with 10-20 C atoms and/or c3) phosphates of polyethylene glycol ethers and/or polypropylene glycol ethers, and the water-soluble salts of each of these, in a weight ratio a:b:c=1:0.3:0.1 to 1:4:1; anti-corrosive and emulsifier system with these components, emulsion concentrate with these components, oil-in-water emulsion obtainable therefrom and use thereof as a cleaning, anti-corrosive and low-temperature lubricant emulsion.
    Type: Application
    Filed: October 31, 2002
    Publication date: May 8, 2003
    Inventors: Hans-Peter Oelscher, Juergen Geke
  • Publication number: 20030073589
    Abstract: The passage of a container along a conveyor is lubricated by applying to the container or conveyor a mixture of a water-miscible silicone material and a water-miscible lubricant. The mixture can be applied in relatively low amounts and with relatively low or no water content, to provide thin, substantially non-dripping lubricating films. In contrast to dilute aqueous lubricants, the lubricants of the invention provide drier lubrication of the conveyors and containers, a cleaner conveyor line and reduced lubricant usage, thereby reducing waste, cleanup and disposal problems.
    Type: Application
    Filed: November 1, 2002
    Publication date: April 17, 2003
    Inventors: Minyu Li, Keith Darrell Lokkesmoe
  • Publication number: 20030073588
    Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.
    Type: Application
    Filed: August 6, 2001
    Publication date: April 17, 2003
    Inventors: Jon Lee Howell, Erik Williams Perez
  • Patent number: 6541428
    Abstract: The invention concerns alkoxylated sulfur alcohol orthophosphate compositions. It also concerns a method for preparing said compositions by sulphurizing alcohol orthophosphate composition. It further concerns the use of said alkoxylated sulphur alcohol orthophosphate compositions as multifunctional additives in lubricating or detergent aqueous formulations.
    Type: Grant
    Filed: March 5, 2001
    Date of Patent: April 1, 2003
    Assignee: Rhodia Chimie
    Inventor: Jean-Luc Joye
  • Publication number: 20030060377
    Abstract: The present invention is a method for operating a hydraulic system at pressures of about 4000 psi or higher, preferably about 5000 psi or higher by using as the lubricant a phosphate ester hydraulic oil comprising a fire resistant phosphate esters base stock, a viscosity index improver, an anti erosion agent, an acid scavenger. The fluid used in the present method can also contain rust inhibitors and/or antioxidants.
    Type: Application
    Filed: August 3, 2001
    Publication date: March 27, 2003
    Inventors: Shlomo Antica, Marc-Andre Poirier, Jean-Michel Pascual, Gerard Dallemagne
  • Publication number: 20030050197
    Abstract: The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of −30 to 80° C. with one kind of a lubricating oil, and they are free from change of properties over a long period of time.
    Type: Application
    Filed: October 9, 2001
    Publication date: March 13, 2003
    Inventor: Yuji Akao
  • Patent number: 6531429
    Abstract: The invention relates to improved compositions comprising thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters and oil additives from the group of the polyol partial esters, amines and epoxides, and also to the use of those lubricant compositions in improving the performance properties of lubricants, such as greases, metal-working fluids, gear fluids or hydraulic fluids. Thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters are present in the compositions preferably in a concentration of less than 400 ppm.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: March 11, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Michael Fletschinger, Peter Rohrbach, Peter Collen Hamblin, Dudley Clark, Marc Ribeaud
  • Patent number: 6521142
    Abstract: The present invention relates to fire-resistant hydraulic fluids. More particularly, the invention relates to fire-resistant hydraulic fluid compositions comprising the combination of a trialkoxyalkyl-phosphate, a diluent selected from the group consisting of a natural triglyceride, a synthetic ester, and a polypropylene glycol, and a high molecular weight polymer.
    Type: Grant
    Filed: August 1, 2000
    Date of Patent: February 18, 2003
    Assignee: Houghton Technical Corp.
    Inventors: Rosauro V. Holgado, Richard Adams, Chan Talaty
  • Publication number: 20030027728
    Abstract: Grease composition for constant velocity joints, comprising a base oil and a urea-based thickener, which grease additionally contains, (A) molybdenum sulphide dialkyldithiocarbamate and (B) 5,5-dithiobis(1,3,4-thiadiazole-2-thiol); a method of lubricating a constant velocity joint comprising packing it with said grease; and a constant velocity joint packed with said grease.
    Type: Application
    Filed: August 27, 2002
    Publication date: February 6, 2003
    Inventors: Yasushi Kawamura, Kouichi Nakazawa, Noriaki Shinoda, Keiji Tanaka, Tetsuo Nimura, Kouji Saitou, Tomoyasu Wada
  • Patent number: 6495494
    Abstract: The passage of a container along a conveyor is lubricated by applying to the container or conveyor a mixture of a water-miscible silicone material and a water-miscible lubricant. The mixture can be applied in relatively low amounts and with relatively low or no water content, to provide thin, substantially non-dripping lubricating films. In contrast to dilute aqueous lubricants, the lubricants of the invention provide drier lubrication of the conveyors and containers, a cleaner conveyor line and reduced lubricant usage, thereby reducing waste, cleanup and disposal problems.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: December 17, 2002
    Assignee: Ecolab Inc.
    Inventors: Minyu Li, Keith Darrell Lokkesmoe
  • Patent number: 6489271
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: December 3, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Robert C. Richardson
  • Publication number: 20020173433
    Abstract: Novel non-symmetric, partially fluorinated compositions and method of manufacture which are useful as lubricants or as additives to lubricant formulations involving the molecular structure:
    Type: Application
    Filed: April 30, 2002
    Publication date: November 21, 2002
    Inventor: Richard P. Beatty
  • Publication number: 20020165102
    Abstract: There is disclosed a lubricating oil composition for cellulose base wet friction material which comprises a base oil blended with (A) a boron-containing imide base dispersant (e.g. boron treated polyalkenyl succinimide) having a weight-average molecular weight in the range of 500 to 3000 and having a ratio by weight of boron to nitrogen (B/N) in the range of 0.1 to 1.5 in such a blending amount that the boron content and the nitrogen content each derived from the component (A) are made to be at least 60 ppm by weight and at least 100 ppm by weight, respectively based on the base oil. The above lubricating oil composition enhances peeling resistant durability for a friction material, especially a cellulose base friction material without impairing the wear resistance or scoring resistance of a steel material element, and is well suited for use in a cellulose base friction material for a starting and running device and a transmission clutch that are used in an automatic transmission of an automobile.
    Type: Application
    Filed: May 7, 2002
    Publication date: November 7, 2002
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Hitoshi Hata, Hisashi Machida
  • Publication number: 20020151442
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; and a phosphorus-containing compound represented by the formulae 1
    Type: Application
    Filed: January 31, 2002
    Publication date: October 17, 2002
    Applicant: The Lubrizol Corporation
    Inventors: Ewa A. Bardasz, Virginia A. Carrick, William D. Abraham, Gordon D. Lamb
  • Publication number: 20020117648
    Abstract: Disclosed are phosphate ester base fluids and aircraft hydraulic fluids containing a novel combination of phosphate ester components. The disclosed aircraft hydraulic fluids contain from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-iso-butyl phosphate; from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-n-butyl phosphate; from about 10 to about 15 weight percent, based on the total weight of the fluid, of one or more triaryl phosphates; and an effective amount of a viscosity index improver, an acid control additive and an erosion inhibitor.
    Type: Application
    Filed: September 28, 2001
    Publication date: August 29, 2002
    Inventors: Mark E. Okazaki, Adrian D'Souza, Shlomo Antika
  • Patent number: 6358895
    Abstract: Non-aqueous functional fluids are treated to avoid degradation or to recondition degraded fluids by a process which comprises contacting the fluid with an anionic ion-exchange resin and subsequently removing water by vacuum dehydration. The fluids can be restored and maintained at a water content of less than 0.1% w/w and an acid number of less than 0.2 mgKOH/gm. The fluid is preferably a triaryl phosphate based fluid. Treated fluids may exhibit improved properties especially increased resistivity.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: March 19, 2002
    Assignee: PABU Services, Inc.
    Inventor: William David Phillips
  • Publication number: 20020025912
    Abstract: Thermally formed thermoplastic articles can be protected from stress cracking in the presence of stress cracking promoting compounds by forming a shaped article comprising a thermoplastic and a liquid hydrocarbon oil composition. We have found that the liquid hydrocarbon oil composition prevents the stress cracking promoting materials from interacting with the polymeric structure of the stressed container to prevent or inhibit stress cracking in such materials. The methods and compositions of the invention are particularly useful in preventing stress cracking in polyethylene terephthalate beverage containers during bottling operations during which the bottle is contacted with aqueous and non-aqueous materials such as cleaners and lubricants that can interact with the polyester to cause stress cracking particularly in the container base.
    Type: Application
    Filed: April 23, 2001
    Publication date: February 28, 2002
    Inventors: Kimberly L. Person Hei, Joy G. Herdt, Minyu Li, Keith Darrell Lokkesmoe, Guang-Jong Jason Wei, Michael E. Besse
  • Publication number: 20020016266
    Abstract: The invention relates to improved compositions comprising thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters and oil additives from the group of the polyol partial esters, amines and epoxides, and also to the use of those lubricant compositions in improving the performance properties of lubricants, such as greases, metal-working fluids, gear fluids or hydraulic fluids. Thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters are present in the compositions preferably in a concentration of less than 400 ppm.
    Type: Application
    Filed: August 17, 2001
    Publication date: February 7, 2002
    Inventors: Michael Fletschinger, Peter Rohrbach, Peter Collen Hamblin, Dudley Clark, Marc Ribeaud
  • Publication number: 20020010103
    Abstract: The present invention relates to a lubricating oil composition for use in industrial oils such as hydraulic oils, bearing oils, industrial gear oils and sliding surface lubricating oils.
    Type: Application
    Filed: March 29, 2001
    Publication date: January 24, 2002
    Inventors: Himiko Takayama, Katsumi Umehara
  • Publication number: 20020010102
    Abstract: New sulfur-containing organophosphorus compounds of general formulae (I) and (II) and processes for producing the same; additives for lubricating oils, which contain the sulfur-containing organophosphorus compounds; and lubricating oil compositions satisfying requirements of extreme-pressure lubrication and abrasion resistance under severe conditions of high loads imposed, on automatic or continuously variable transmissions or the like. In said formulae, R1 is a hydrocarbon group having 6 to 20 carbon atoms; R2 is a divalent hydrocarbon group having 1 to 6 carbon atoms; n is an integer of 1 to 3; p is an integer of 0 to 2; and q is an integer of 0 or 1, with the proviso that p and q cannot be 0 at the same time.
    Type: Application
    Filed: April 4, 2000
    Publication date: January 24, 2002
    Inventors: HIROAKI KOSHIMA, HITOSHI HATA, NOBORU SONODA, IZUMI TERADA
  • Patent number: 6319880
    Abstract: A grease composition for constant velocity joints comprises the following components: (a) a base oil; (b) a diurea type thickening agent; (c) a molybdenum sulfurized dialkyl dithiocarbamate; (d) molybdenum disulfide; (e) at least one sulfur-phosphorus-containing extreme-pressure agent selected from the group consisting of zinc dithiophosphate compounds and thiophosphates; and (f) a fatty acid amide. The grease composition of the present invention has a high ability of reducing the induced thrust force and is excellent in the durability.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: November 20, 2001
    Assignees: Kyodo Yushi Co., Ltd., NTN Corporation
    Inventors: Takashi Okaniwa, Junichi Imai, Yukio Hasegawa, Shinichi Takabe
  • Patent number: 6306801
    Abstract: A lubricating oil composition having an excellent sludge formation inhibiting effect and being suitable for use as an engine oil is provided. The lubricating oil composition includes: a lubricating base oil, (A) 0.5 to 20% by mass of acylated bissuccinimide, (B) 0.05 to 0.3% by mass of zinc dithiophosphate in terms of the phosphorus content, and (C) 0.5 to 4.0% by mass of metallic detergent in terms of the sulfated ash content, based on the total mass of the composition.
    Type: Grant
    Filed: October 21, 1999
    Date of Patent: October 23, 2001
    Assignee: Nippon Mitsubishi Oil Corporation
    Inventors: Kazuhiro Yagishita, Yoko Matsuyama, Osamu Kurosawa
  • Patent number: 6251300
    Abstract: A refrigerator oil composition for use with an HFC refrigerant containing HFC-134a, HFC-125 or a mixture thereof, which comprises component (A) and component (B), said component (A) being 70 to 99% by weight of an alkylbenzene oil containing at least 60% by weight, based on the total weight of component (A), of alkylbenzenes having a molecular weight of 200 to 350 and said component (B) being 30 to 1% by weight of at least one synthetic oil containing oxygen selected from the group consisting of an ester, a polyalkylene glycol, an alkyl ether of the polyalkylene glycol, a modified compound of polyglycol, a ketone, a polyphenyl ether, a silicone, a polysiloxane and a perfluoro ether.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: June 26, 2001
    Assignee: Nippon Mitsubishi Oil Corporation
    Inventors: Katsuya Takigawa, Umekichi Sasaki, Satoshi Suda
  • Publication number: 20010003733
    Abstract: The invention relates to process for reducing the friction between new and/or freshly washed transport containers and conveyors, in which a composition containing at least one component with lubricating properties is applied to at least part of the surface of the container before it is placed on the conveyor, to containers of which at least part of the outer surface is finished with a film or a coating which contains lubricating components to reduce friction during transport on conveyors and to installations which are intended, and may advantageously be designed, for the transport of such containers.
    Type: Application
    Filed: December 6, 2000
    Publication date: June 14, 2001
    Applicant: Henkel-Ecolab GmbH & Co. OHG
    Inventors: Stefan Kupper, Michael Schneider, Walter Grobe Bowing, Alfred Laufenberg, Harald Kluschanzoff
  • Patent number: 6204227
    Abstract: Concentrated lubricant compositions that, upon dilution, produce emulsions that are useful as lubricants in metal working processes are described. The compositions comprise a substantially neutral phosphate ester and one or more non-ionic surfactants. By appropriate choice of surfactants both microemulsions and macroemulsions can be produced. The emulsions are stable for at least one month at room temperature and offer improved lubricity when used in metal working operations.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: March 20, 2001
    Assignee: PABU Services, Inc.
    Inventors: Arvind M. N. Rao, Douglas G. Placek
  • Patent number: 6165950
    Abstract: Concentrated lubricant compositions, dilutable for use in high temperature metal forming processes and containing a triaryl phosphate ester; a non-ionic and/or amphoteric surfactant, an organic sulfur-containing extreme pressure additive, an amine salt of an organic acid, and, optionally, sodium thiosulfate, exhibit improved performance in forming operations and produce parts with less part to part variation.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: December 26, 2000
    Assignee: PABU Services, Inc.
    Inventors: Arvind M. Rao, Douglas G. Placek
  • Patent number: 6156228
    Abstract: The present invention relates to fire-resistant hydraulic fluids. More particularly, the invention relates to fire-resistant hydraulic fluid compositions comprising the combination of a trialkoxyalkyl-phosphate, a diluent selected from the group consisting of a natural triglyceride, a synthetic ester, and a polypropylene glycol, and a high molecular weight polymer.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: December 5, 2000
    Assignee: Houghton International, Inc.
    Inventors: Rosauro V. Holgado, Richard Adams, Chan Talaty
  • Patent number: 6127323
    Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of alkyl phosphonates, ashless dispersants and metallic detergents.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: October 3, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Raymond Frederick Watts, David Edward Gindelberger
  • Patent number: 6103673
    Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: August 15, 2000
    Assignee: The Lubrizol Corporation
    Inventors: James L. Sumiejski, William C. Ward, Jr.
  • Patent number: 6096691
    Abstract: The concentrates comprise specified proportions of diluent oil, an organic sulfur-containing antiwear and/or extreme pressure agent, an ashless dispersant, a dimethyl ester of an aliphatic phosphonic acid in which the aliphatic group has an average in the range of about 12 to about 24 carbon atoms, and a 3-hydrocarbyl-2,5-diketopyrrolidine in which the hydrocarbyl group is an alkyl or alkenyl group having an average in the range of about 12 to about 30 carbon atoms. By using weight ratios of diketopyrrolidine to the dimethyl phosphonate of at least 3:1, the concentrate remains homogeneous at temperatures at least as low as 12.degree. C. When utilized as a top treat in gear oils formulated with conventional GL-4 and GL-5 gear additive packages substantial improvements in limited slip axle performance can be realized.
    Type: Grant
    Filed: April 9, 1993
    Date of Patent: August 1, 2000
    Assignee: Ethyl Corporation
    Inventors: Gregory S. Conary, Rolfe J. Hartley
  • Patent number: 6048825
    Abstract: A lubricant composition suitable as a helicopter transmission lubricant comprises a synthetic base stock of viscosity in the range 5.0 to 10.0 cSt at 100.degree. C., an antioxidant component, a neutral organic phosphate component, a dicarboxylic acid component, a monocarboxylic acid component, a triazole component and a phosphorus containing extreme pressure additive.
    Type: Grant
    Filed: March 3, 1999
    Date of Patent: April 11, 2000
    Assignee: Castrol Limited
    Inventors: Andrew J. Markson, John W. A. Pragnell, Mark A. Edwards
  • Patent number: 5994278
    Abstract: A lubricating oil comprising an add mixture of the following components: (A) a complex alcohol ester basestock which comprises the reaction product of an add mixture of the following: (1) a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; (2) a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and (3) a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Carolyn Boggus Duncan, David Wayne Turner
  • Patent number: 5972854
    Abstract: Disclosed is a lubricating oil composition for automatic transmissions, which comprises a base oil and additives of (A) a sulfur-containing antioxidant or an amine-type antioxidant, (B) a phosphate or its amine salt, and (C) a reaction product of a carboxylic acid and an amine. The composition has an excellent ability to prevent the brake lining of the clutch of automatic transmissions from shuddering, and can maintain the shudder-preventing ability for a long period of time.
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: October 26, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshihiko Ichihashi, Hideo Igarashi, Junichi Deshimaru, Toshiki Ikeda
  • Patent number: 5955403
    Abstract: A sulfur free lubricating composition comprises a major portion of a synthetic base lubricating oil and a minor portion of a tri(alkyl phenyl) phosphate or di(alkylphenyl)phosphoric acid antiwear agent, an amine antioxidant a substituted succinamide rust inhibitor and a tolytriazole. The tri(alkylphenyl)phosphate antiwear agent is incorporated in the oil in an amount ranging between about 0.1 to 2.0 wt % and the amine antioxidant in amount ranging from about 0.1 to 5 wt %. The succinamide is present in an amount ranging from about 0.01 to 0.5 wt % and the tolytriazole, from about 0.01 to 0.5 wt %. In the foregoing, the wt % is based on the weight of oil.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: September 21, 1999
    Assignee: Exxon Research and Engineering Company
    Inventor: Chung-Lai Wong
  • Patent number: RE37101
    Abstract: A fluid composition suitable for use as an aircraft hydraulic fluid is disclosed. The fluid composition comprises a fire resistant phosphate ester base stock comprising between about 10% and about 100% by weight of a trialkyl phosphate, between about 0% and about 70% by weight of a dialkyl aryl phosphate, and from about 0% to about 25% by weight of an alkyl diaryl phosphate, with the proviso that the sum of the proportionate amount of each base stock component must equal 100%. The alkyl substituents of the trialkyl phosphate, the dialkyl aryl phosphate, and the alkyl diaryl phosphate contain between 3 and 8 carbon atoms, preferably between 4 and 8 carbon atoms, more preferably between 4 and 5 carbon atoms, and are bonded to the phosphate moiety via a primary carbon. It is still further preferred that the alkyl substituents of the trialkyl phosphate, the dialkyl aryl phosphate, and the alkyl diaryl phosphate are isoalkyl groups.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: March 20, 2001
    Assignee: Solutia Inc.
    Inventor: Gerbrand Deetman