Three Divalent Chalcogens Single Bonded Directly To Trivalent Phosphorus Patents (Class 508/441)
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Patent number: 11352584Abstract: A lubricating composition comprises an oil of lubricating viscosity, a metal-free pre-ceramic polymer and one or more co-additives. The metal-free pre-ceramic polymer comprises a plurality of repeat units which do not contain oxygen. The pre-ceramic polymers provide the lubricating oil composition with antiwear properties. Also described is a method of lubricating an internal combustion engine and the use of a lubricating oil composition containing a pre-ceramic polymers to inhibit wear in an internal combustion engine.Type: GrantFiled: February 21, 2018Date of Patent: June 7, 2022Assignee: Infineum International LimitedInventors: Nigel A. Male, Stuart A. Taylor, Russell M. Thompson, Anton Coulthurst
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Patent number: 10407633Abstract: The present invention relates to the use of a diesel fuel additive for removing deposits in a diesel engine.Type: GrantFiled: April 28, 2016Date of Patent: September 10, 2019Inventors: Edgar Volpert, William A. Batson
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Patent number: 9090846Abstract: The invention provides a lubricating composition containing an antiwear agent and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in a mechanical device such as an internal combustion engine, or a driveline device.Type: GrantFiled: August 24, 2011Date of Patent: July 28, 2015Assignee: The Lubrizol CorporationInventors: William R. S. Barton, Matthew D. Gieselman
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Patent number: 9029305Abstract: Provided is a lubricating oil composition containing a base oil which includes a mineral oil and/or a synthetic oil, and compounded therein, (A) at least one phosphorus-containing compound selected from phosphoric acid monoesters, phosphoric acid diesters and phosphorous acid monoesters, each having a C1 to C8 hydrocarbon group or groups and (B) a tertiary amine compound having C6 to C10 hydrocarbon groups as substituents thereof. The lubricating oil composition provides both a high metal to metal friction coefficient and an excellent wear resistance and is suitably used in a continuously variable transmission.Type: GrantFiled: January 9, 2009Date of Patent: May 12, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventor: Keiichi Narita
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Patent number: 8962540Abstract: To provide a lubricating oil composition including a base oil which is composed of a mineral oil and/or a synthetic oil and which has a viscosity index of 95 or higher, and (A) an alkenylsuccinimide in an amount of 0.1 to 2.0 mass %, (B) an acidic phosphite diester having a C6 to C10 hydrocarbon group in an amount of 0.1 to 2.0 mass %, and (C) at least one species selected from among a perbasic alkaline earth metal sulfonate, a perbasic alkaline earth metal phenate, and a perbasic alkaline earth metal salycilate, in an amount of 0.001 to 0.3 mass %, with respect to the total amount of the composition.Type: GrantFiled: April 21, 2009Date of Patent: February 24, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventor: Masatoshi Toda
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Patent number: 8691738Abstract: Lubricating oils of improved initial and long term metal corrosion inhibiting properties comprises a base stock containing one or more hydrodewaxate or hydroisomerate base stock(s) and/or base oil(s), GTL base stock(s) and/or base oil(s), or mixtures thereof, preferably GTL base stock(s) and/or base oil(s), boiling in the lubricating oil boiling range and an additive amount of an anti-corrosion additive.Type: GrantFiled: May 4, 2010Date of Patent: April 8, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: David J. Baillargeon, Marc-André Poirier
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Publication number: 20140018271Abstract: The present invention provides a lubricating oil composition that maintains properties necessary to lubricating a transmission and other devices and has more excellent insulation properties and anti-wear properties and more improved anti-seizure properties than the prior art and comprises (A) a lubricating oil base oil; (B) at least one type of phosphorus compound selected from the group consisting of phosphorus compounds having at least one hydroxyl group and/or at least one thiol group; and (C) an ashless dispersant having a functional group containing as a dispersion group in an amount of less than 0.001 percent by mass on the basis of nitrogen on the total composition mass basis or no such an ashless dispersant at all, the composition having a 80° C. volume resistivity of 5×108 ?·m or greater.Type: ApplicationFiled: September 13, 2011Publication date: January 16, 2014Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Yasushi Onumata, Noriko Abe
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Publication number: 20130170777Abstract: The present invention provides a grease composition having an excellent fretting wear resistance in a wide temperature region from low to high temperatures and particularly even at low temperatures and a rolling bearing in which the grease composition is packed. A grease composition (7) is packed inside a grease-packed bearing (1). The grease composition (7) contains base oil, a thickener, and an additive. The additive contains at least, one kind selected from among a phosphite ester shown by a chemical formula (1) or a phosphite ester shown by a chemical formula (2). The content of the phosphite ester is 0.5 to 4 parts by weight for 100 parts by weight which is the total of the amount of the base oil and that of the thickener. (In the chemical formulas (1) and (2), R1, R2, R3, R4, and R5 denote a methyl group or an ethyl group respectively. R1 and R2 are the same group or different groups. R3, R4, and R5 are the same group or different groups).Type: ApplicationFiled: September 9, 2011Publication date: July 4, 2013Applicant: NTN CORPORATIONInventors: Motohiro Ito, Yoji Sato, Hidenobu Mikami
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Publication number: 20130040864Abstract: The invention relates to a composition comprising at least one microgel and at least one functional additive, to processes for the preparation thereof, to uses of the compositions, and to microgel-containing polymers, rubbers, lubricants, coatings, etc. prepared therefrom.Type: ApplicationFiled: October 18, 2012Publication date: February 14, 2013Applicants: RHEIN CHEMIE RHEINAU GMBH, LANXESS DEUTSCHLAND GMBHInventors: LANXESS Deutschland GmbH, Rhein Chemie Rheinau GmbH
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Patent number: 8318645Abstract: The lubricating oil composition of the invention includes a base oil composed of mineral oil and/or synthetic oil, an amine antioxidant (A-1) in an amount of 800 ppm or more as reduced to the total amount of nitrogen, and a compound containing phosphorus and/or sulfur (A-2). The invention provides a compressor oil which realizes thermal/oxidation stability, resistance to sludge formation, lubricity, long service life, and water separation at high levels.Type: GrantFiled: December 7, 2006Date of Patent: November 27, 2012Assignee: Idemitsu Kosan Co., Ltd.Inventor: Hideto Kamimura
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Publication number: 20110257053Abstract: [Object] To provide a lubrication kit which is capable of improving wear resistance and durability of a sliding portion mounted in a small electronic device and which is capable of reducing a sound generated during driving. [Solution] A lubrication kit used for a small electronic device having a sliding portion, according to the present invention comprises at least one lubricant selected from a lubricant (1) comprising an anti-wear agent and a base oil which contains a polyol ester oil and/or a paraffinic hydrocarbon oil and a lubricant (2) comprising an anti-wear agent, polytetrafluoroethylene particles, and a base oil which contains a polyol ester oil and/or a paraffinic hydrocarbon oil, and a surface-treating agent obtained from a fluorine type surfactant and a phosphoric ester having a hydrocarbon group in which a part or all of hydrogen atoms have been substituted with a fluorine atom.Type: ApplicationFiled: December 25, 2009Publication date: October 20, 2011Applicant: CITIZEN ELECTRONICS CO., LTDInventors: Yuji Akao, Masahiro Furuya
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Patent number: 7964542Abstract: Liquid compositions containing a specific hindered phenol or a hindered phenol in combination with an aromatic phosphite are provided which are used as a thermal interface between a heatsink and a chip during a test procedure for electronic components which compositions enhance the thermal conductivity between the heatsink and the chip, are easily removed from the heatsink and the chip after the test procedure without any deleterious residue and which allow the use of high temperatures for extended periods during the test procedure without any significant degradation of the composition. A method for using the compositions in electronic component test procedures such as burn-in procedures is also provided.Type: GrantFiled: January 12, 2006Date of Patent: June 21, 2011Assignee: International Business Machines CorporationInventors: Krishna G. Sachdev, Harbans Singh Sachdev, legal representative, Mark S. Chace, Normand Cote, David L. Gardell, Jeffrey D. Gelorme, Sushumna Iruvanti, G. John Lawson, Tuknekah M. Noble
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Patent number: 7919440Abstract: A lubricating composition with improved storage stability comprising a major amount of an oil of lubricating viscosity, at least one alkali metal borate, at least one polysulfide mixture having at least 40% dihydrocarbyl tetrasulfide or higher sulfides, and at least one non-acidic phosphorus compound comprised of a trihydrocarbyl phosphate and a dihydrocarbyl dithiophosphate derivative is disclosed. In addition to improved storage stability, the composition has improved wear performance when the ratio of polysulfides is controlled.Type: GrantFiled: May 4, 2005Date of Patent: April 5, 2011Assignee: Chevron U.S.A. Inc.Inventors: John A. Zakarian, Michael J. Haire
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Patent number: 7879773Abstract: A lubricating oil composition having superior storage stability and load-carrying effect is disclosed. The composition comprises four components: (1) an alkali metal borate; (2) an oil-soluble sulfur compound; (3) a trialkyl hydrogen phosphite; and (4) a mixture of greater than 50% neutralized acidic phosphates that are essentially free of monothiophosphates.Type: GrantFiled: May 4, 2005Date of Patent: February 1, 2011Assignee: Chevron U.S.A., Inc.Inventors: John A. Zakarian, Michael J. Haire
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Patent number: 7833951Abstract: The invention provides a water-soluble metal working lubricant which is suitably employed particularly in press-working of aluminum material and which is excellent in both working properties and degreasing properties. The water-soluble metal working lubricant includes 85 mass % or less of water (A); 5 to 75 mass % of a metal salt of an organic carboxylic acid (B) wherein carboxylic acid residue has 8 or more carbon atoms in total and the acid/alkali ratio by mole is 1:0.5 to 1.1; 1 to 50 mass % of at least one metal salt (C) selected from among an organic phosphate ester metal salt, an organic phosphite ester metal salt, an organic phosphonate metal salt, and an organic borate ester metal salt, each having an alkyl group having 8 or more carbon atoms in total; and 10 to 80 mass % of a non-ionic surfactant (D).Type: GrantFiled: February 3, 2004Date of Patent: November 16, 2010Assignees: Honda Motor Co., Ltd., Idemitsu Kosan Co., Ltd.Inventors: Noboru Hayashi, Katsuhiko Shiotsuki, Mitsuru Osawa, Masato Kaneko, Hideo Kanamori
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Patent number: 7829511Abstract: A stabilized lubricant composition is disclosed that comprises lubricating oil and a mixture of (a) at least one organophosphite compound and (b) at least one aromatic secondary amine or one substituted phenol or mixtures thereof. The compositions have been found to be highly resistant to oxidation under demanding service conditions and to be useful as turbine lubricants.Type: GrantFiled: May 12, 2005Date of Patent: November 9, 2010Assignee: Chemtura CorporationInventors: Jun Dong, Cyril A. Migdal
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Patent number: 7786059Abstract: An anti-wear additive composition comprising at least one acid phosphite compound and at least one neutral phosphite compound, wherein the ratio of the acid phosphite to the neutral phosphite is from about 1.0:10.7 to about 2.0:1.0, and lubricating oil compositions containing the same.Type: GrantFiled: December 21, 2004Date of Patent: August 31, 2010Assignee: Chevron Oronite Company LLCInventor: Juan Alberto Buitrago
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Publication number: 20100205980Abstract: A PAG lubricant basefluid for use with a fluoroalkene refrigerant, the basefluid containing a PAG having the formula: RX(RaO)x(RbO)yRc, where R is selected from alkyl groups having from 1-10 carbon atoms, acyl groups having from 1-10 carbon atoms, aliphatic hydrocarbon groups having from 2-6 valencies, and substituents containing a heterocyclic ring in which the heteroatom(s) are oxygen; X is O or S; Ra is a C2 alkylene group; Rb is a C3 alkylene group; Rc is the same as R or is an H; x and y are each independently 0 or an integer?100; and the sum of x+y is an integer in the range of from about 5-100. Refrigeration and lubricant compositions containing the PAG lubricant basefluid and a method of operating a motor-integrated compressor of a refrigeration or air conditioning system with substantially no electrical leakage current are also provided.Type: ApplicationFiled: December 14, 2009Publication date: August 19, 2010Applicant: SHRIEVE CHEMICAL PRODUCTS, INC.Inventors: Elizabeth Dixon, Phil Beckler
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Patent number: 7759294Abstract: Lubricant compositions having improved load carrying capacity comprising an extreme pressure compound comprising a sulfur-containing compound, a load carrying capacity enhancing combination comprising a hydrocarbylamine compound and an alkylphosphorothioate compound, a friction modifier compound, and a diluent or base oil as applicable. These lubricant compositions can be used as industrial oils well-suited for the demands of geared device applications, such as in wind turbine gear-boxes and automotive gears and axles.Type: GrantFiled: October 24, 2003Date of Patent: July 20, 2010Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Helen T. Ryan
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Publication number: 20100162981Abstract: A multigrade lubricating oil composition with enhanced anti-wear properties for use in an internal combustion engine comprises (a) a base oil comprising at least 90% by weight of the base oil, of one or more basestocks selected from the group consisting of base stocks derived from Fischer-Tropsch synthesised, waxy, paraffinic hydrocarbon material by processes comprising hydrocracking and/or hydroisomerisation, Group II basestocks, Group III basestocks and mixtures thereof; (b) one or more dispersant viscosity modifiers in a total amount of 0.15 to 0.8% by weight of the composition; (c) one or more dispersants in a total amount of active dispersants of 1.5 to 3% by weight of the composition; (d) one or more detergents; and (e) one or more metal dihydrocarbyl dithiophosphates.Type: ApplicationFiled: May 1, 2008Publication date: July 1, 2010Inventors: Ieuan Stephen Adams, Asha Bhaskaran, Gordon David Lamb
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Patent number: 7723276Abstract: An oil for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester, and is used as a lubricating oil for cutting and grinding suitable for a cutting and grinding method by minimal quantity lubrication system, and also used as a lubricating oil for sliding surface.Type: GrantFiled: April 5, 2002Date of Patent: May 25, 2010Assignee: Nippon Oil CorporationInventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
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Patent number: 7683016Abstract: The inventive composition comprises compatible combinations of methyl esters of fatty acids or triglycerides and polar non-chlorine extreme pressure additives, the composition being either (a) a working strength straight oil, (b) a soluble oil concentrate dilutable to a working strength soluble oil, the composition when at working strength effectively lubricating metal parts during high performance metalworking, and providing environmental and safety advantages.Type: GrantFiled: August 13, 2002Date of Patent: March 23, 2010Assignee: United Soybean BoardInventors: James P. King, Neil M. Canter
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Publication number: 20090298727Abstract: A lubricant composition for a final drive axle oil comprising an oil of lubricating viscosity, one or more dispersants and one or more phosphorus compounds wherein the kinematic viscosity of the lubricant composition at 100° C. is greater than 10 mm2/s and wherein the amount by weight of the dispersant is greater than the amount by weight of the phosphorus compounds and any sulfur compounds which may optionally be present.Type: ApplicationFiled: December 15, 2006Publication date: December 3, 2009Applicant: The Lubrizol CorporationInventors: Craig D. Tipton, Thomas A. Tagliamonte
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Publication number: 20090209440Abstract: The invention provides a lubricating composition containing (a) 0.1 to 15 wt % of a polymer with (i) a weight average molecular weight of 100,000 to 500,000; and (ii) a shear stability index of 10 to 60; (b) a phosphorus-containing acid, salt, or ester; (c) a dispersant; and (d) an oil of lubricating viscosity. The invention further provides a method for lubricating a mechanical device with the lubricating composition.Type: ApplicationFiled: April 12, 2007Publication date: August 20, 2009Applicant: The Lubrizol CorporationInventors: Craig D. Tipton, Marina Baum, Barton J. Schober
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Publication number: 20090137436Abstract: The present invention provides a multifunctional lubricant additive package or composition for improving load-carrying capacity, pressure resistance, surface fatigue life, and other performance characteristics of a lubricant or base oil. The composition typically includes four components: (a) an alkyl or aryl neutral phosphate, (b) a long-chain organic partial ester, (c) an aryl or alkyl phosphite, and (d) a phenol compound. The present invention further provides a multifunctional lubricant having improved performance characteristics, which are obtained by mixing a lubricant with the above-described multifunctional lubricant additive package or composition.Type: ApplicationFiled: November 4, 2005Publication date: May 28, 2009Inventors: Hongmei Wen, Clark V. Cooper
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Patent number: 7407917Abstract: An additive compound comprising a non-borated and/or borated reaction product, in which the reaction product is obtained by reacting a linear or branched, saturated or unsaturated monovalent aliphatic acid having 8 to 22 carbon atoms, urea, and polyalkylenepolyamine, when employed in a lubricating oil composition is favorably employable as an automatic transmission fluid of internal combustion engines.Type: GrantFiled: November 16, 2004Date of Patent: August 5, 2008Assignee: Chevron Oronite Company LLCInventors: Michio Shiga, Tomotusgu Shiroi
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Patent number: 7385880Abstract: A grease composition for a precision instrument comprising a lithium soap grease or a urea grease, and an anti-wear agent, wherein the lithium soap grease and the urea grease are each a grease having no hydroxyl group in a molecule, and the anti-wear agent is contained in an amount of 0.1 to 20% by weight based on the total amount of the grease composition. By the use of the grease composition for a sliding mechanism of a precision instrument such as a watch, an appropriate slip torque can be obtained, and the precision instrument such as a watch can operate stably.Type: GrantFiled: August 19, 2003Date of Patent: June 10, 2008Assignee: Citizen Holdings Co., Ltd.Inventor: Yuji Akao
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Publication number: 20080015125Abstract: A lubricant composition comprising a phosphorus-containing compound and a base oil comprising less than about 3% by weight of tetracycloparaffins is disclosed. Methods of making and using the lubricant composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Roger M. Sheets, Gregory H. Guinther
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Patent number: 7122508Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: GrantFiled: October 31, 2002Date of Patent: October 17, 2006Assignee: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Patent number: 6995121Abstract: A data/information storage and retrieval medium comprises: (a) a substrate having a layer stack thereon, the layer stack including an outer surface and comprising at least one magnetic or magneto-optical (“MO”) recording layer; and (b) a thin film or layer of a lubricant on the outer surface of the layer stack and comprised of a derivatized perfluoropolyether-based material including at least one generally linear perfluoropolyether chain and at least one phosphite antioxidant/stabilizer moiety attached to at least one end of at least one the chain.Type: GrantFiled: December 23, 2002Date of Patent: February 7, 2006Assignee: Seagate Technology LLCInventors: Jianwei Liu, Michael Joseph Stirniman, Jing Gui
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Patent number: 6962895Abstract: This invention relates to a lubricating composition comprising at least about 30% by weight at least one mineral oil, having a kinematic viscosity of less than about 8 cSt at 100° C., (A) from about 15% to about 40% by weight of at least one polymer, and (B) up to about 30% by weight of at least one fluidizing agent, provided that when the fluidizing agent is a poly?-olefin having a kinematic viscosity from about 2 to about 30 cSt at 100° C., then the poly?-olefin is present in an amount up to about 12% by weight, wherein the lubricating composition has a shear loss of less than about 15% in the 20 hour taper bearing shear test. The invention also relates to concentrates used in preparing lubricating compositions. The present combination of components provides good low and high temperature properties especially when used in combination with one or more mineral oils. In one aspect, the compositions provide improved oxidation resistance.Type: GrantFiled: July 7, 1997Date of Patent: November 8, 2005Assignee: The Lubrizol CorporationInventors: Curtis R. Scharf, Robert C. Richardson, Bernard C. Roell, Jr.
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Patent number: 6887295Abstract: The present invention relates to improved metallurgical powder compositions that incorporate solid lubricants, methods for preparing and using the same, and methods of making compacted parts. Ejection properties, such as stripping pressure and sliding pressure, of compacted parts can be improved by using the solid lubricants. The solid lubricants contain functionalized polyalkylene glycol lubricants that contain a phosphate group, phosphite group, hypophosphate group, hypophosphite group, polyphosphate group, thiophosphate group, dithiophosphate group, thiocarbamate group, dithiocarbamate group, borate group, thiosulfate group, sulfate group, a sulfonate group or combinations thereof.Type: GrantFiled: October 25, 2002Date of Patent: May 3, 2005Assignee: Hoeganaes CorporationInventors: George Poszmik, Sydney Luk
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Patent number: 6872693Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.Type: GrantFiled: May 24, 2000Date of Patent: March 29, 2005Assignee: The Lubrizol CorporationInventor: Robert W. Cain
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Publication number: 20040248745Abstract: An ashless natural gas engine lubricating composition which has enhanced resistance to oxidation, nitration and viscosity increase employs as additives in a lubricating oil basestock a combination of phenolic and alkylthiocarbamoyl antioxidants and an ashless phosphorous antiwear additive.Type: ApplicationFiled: April 23, 2004Publication date: December 9, 2004Inventor: S. James Cartwright
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Patent number: 6828285Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: February 14, 2003Date of Patent: December 7, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6828284Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: GrantFiled: August 6, 2001Date of Patent: December 7, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Jon Lee Howell, Erik William Perez
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Patent number: 6825154Abstract: Lubricating oil formulations comprising base oil, sulfur-phosphorous anti-wear/extreme pressure agents and hindered phenol antioxidants which anti-wear/extreme-pressure agents and hindered phenolic antioxidants are prone to crystal formation wherein the base oil is characterized as having a saturates content of less than 99% are stabilized against crystal formation by the addition of a minor amount of a high molecular weight di- or polycarboxylic acid anhydride, or mixture thereof.Type: GrantFiled: July 22, 2002Date of Patent: November 30, 2004Assignee: ExxonMobil Research and Engineering CompanyInventor: David Gary Lawton Holt
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Publication number: 20040214729Abstract: A gear oil additive composition and gear oil composition comprising a organic polysulfide having at least 30 wt % of a dialkyl polysulfide compound or mixture of dialkyl polysulfide compounds, a thiadiazole; and at least one ashless phosphorus-containing wear inhibitor compound is disclosed as having low yellow corrosion in axles and transmissions.Type: ApplicationFiled: April 25, 2003Publication date: October 28, 2004Inventor: Juan A. Buitrago
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Publication number: 20040192562Abstract: A lubricating oil composition which comprises (A) a base oil, (B) calcium salicylate having a base number of 50 to 300 mgKOH/g in an amount of 0.005 to 0.07 percent by mass in terms of calcium, (C) an SP type extreme pressure additive in an amount of 0.005 to 0.07 percent by mass in terms of phosphorous, (D) a specific succinimide compound in an amount of 0.1 to 6 percent by mass, and (E) a boron-containing ashless dispersant in an amount of 0.001 to 0.05 percent by mass in terms of boron, based on the total mass of the composition. The lubricating oil composition can prevent pitching of a transmission, resulting in the extended fatigue life thereof, and exhibits excellent and long-lasting anti-shudder properties.Type: ApplicationFiled: April 1, 2004Publication date: September 30, 2004Applicant: Nippon Oil CorporationInventor: Eitaro Morita
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Patent number: 6794341Abstract: The peak-torque descending composition of the present invention contains a certain amount of an extreme pressure agent comprising at least neutral phosphate esters and/or neutral phosphite esters in a solvent comprising hydrocarbons and/or ethers. Further, a certain corrosion inhibitor may be contained. The part having a sliding portion of the present invention is surface-treated with the above composition. The process for producing a component or precision machine having a sliding portion, including immersing a part having a sliding portion in the above composition to adhere or absorb the composition onto the surface of the part. The press fit method of the present invention includes preliminarily immersing the metal plate or the metal shaft in the peak-torque descending composition to adhere or absorb the composition onto an inner surface of a hole.Type: GrantFiled: December 27, 2002Date of Patent: September 21, 2004Assignee: Citizen Watch Co., Ltd.Inventors: Yuji Akao, Masayuki Koike
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Publication number: 20040167041Abstract: A lubricating oil composition for automatic transmissions wherein the mass ratio of phosphorus:calcium:boron:sulfur determined by elemental analysis is 1:(0.1 to 2):(0.06 to 2):(0.2 to 20), the concentration of phosphorus is from 0.01 to 0.06 percent by mass, the concentration of the sulfur derived from a base oil is from 0 to 0.1 percent by mass, and the concentration of the sulfur derived from sulfur-based additives is from 0.01 to 0.15 percent by mass, based on the total amount of the composition. The lubricating oil composition can prevent the occurrence of scratch phenomenon even over a long period of time when used in a metal belt type continuously variable automatic transmission.Type: ApplicationFiled: February 6, 2004Publication date: August 26, 2004Applicant: Nippon Oil CorporationInventor: Naozumi Arimoto
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Patent number: 6764982Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; and a phosphorus-containing compound represented by the formulae wherein in Formulae (B-I) and (B-II), R1, R2 and R3 are independently hydrogen or hydrocarbyl groups, and a, b and c are independently zero or 1; the lubricating oil composition being characterized by a sulfur content of about 0.01 to about 0.25% by weight.Type: GrantFiled: January 31, 2002Date of Patent: July 20, 2004Assignee: The Lubrizol CorporationInventors: Ewa A. Bardasz, Virginia A. Carrick, William D. Abraham, Gordon D. Lamb
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Publication number: 20040087450Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: ApplicationFiled: October 31, 2002Publication date: May 6, 2004Inventor: Alexander B. Boffa
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Patent number: 6689726Abstract: Lubricating oil formulations comprising base oil, sulfur-phosphorous anti-wear/extreme pressure agent and hindered phenol antioxidant, which combination of extreme pressure agent and hindered phenol antioxidant produces crystals and containing antioxidants, wherein the base oil is characterized as having a saturates content of 99 wt % or more is stabilized against crystal formation by the addition of a minor amount of high molecular weigh di- or polycarboxylic acid, or anhydride and an ester.Type: GrantFiled: June 17, 2002Date of Patent: February 10, 2004Assignee: ExxonMobil Research and Engineering CompanyInventor: David Gary Lawton Holt
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Patent number: 6673750Abstract: Disclosed is a lubricating composition such as a lubricant, a lubricating grease, or a rust preventive oil for use in a torque limiter and a ball-and-roller bearing; the lubricating composition having chemical attack resistance for a synthetic resin molded product. The lubricating composition comprises as a base oil at least one synthetic saturated hydrocarbon oil selected from the group consisting of a poly-&agr;-olefin, and an ethylene-&agr;-olefin copolymer. When a phosphoric acid ester is used as a compounding agent, or at lease one lubricating grease selected from the group consisting of an urea compound, silica powder, and bentonite powder is mixed therein, the lubricating composition is a rust preventive oil using a metal salt of sulfonic acid and the like. The lubricating composition is suitably used for machine parts of a business machine including the synthetic resin molded product.Type: GrantFiled: February 19, 2002Date of Patent: January 6, 2004Assignee: NTN CorporationInventors: Masakazu Hirata, Atsushi Morooka, Hidenobu Mikami, Toshiyuki Mizutani, Seiichi Takada, Masaaki Honda, Yoshihiko Oeda, Katsumi Nagano
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Patent number: 6660695Abstract: A power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure R1—X2—P(:X1)(R2X3)—X—R5 where R1, and R2 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen. R1 and R2 may also contain substituent hetero atoms, in addition to carbon and hydrogen, such as chlorine, sulfur, oxygen or nitrogen; wherein R5 is derived from a reactive olefin and can be either CH2—CHR—C(:O)O—R6; —CH2—CR7HR8; or R9—OC(:O)CH2—CH—C(:O)O—R10 where R is H or the same as R1, R6, R7, R9 and R10 are the same as R1 and R8 is a phenyl or alkyl or alkenyl substituted phenyl moiety, the moiety having from 6 to 30 carbon atoms, (b) a calcium detergent, and (c) a friction modifier.Type: GrantFiled: March 15, 2002Date of Patent: December 9, 2003Assignee: Infineum International Ltd.Inventors: Raymond F. Watts, Katherine M. Richard
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Publication number: 20030181339Abstract: An power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure: R1—X2—P(:X1)(R2X3)—X—R5 where R1, R2, R3, and R4 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen.Type: ApplicationFiled: March 15, 2002Publication date: September 25, 2003Inventors: Raymond F. Watts, Katherine M. Richard
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Patent number: 6613722Abstract: A lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphite; (b) at least one amine salt of an organic phosphate; and (c) one or more friction modifiers selected from the group consisting of selected (1) amides, (2) succinimides, and (3) ethoxylated amines.Type: GrantFiled: March 7, 1997Date of Patent: September 2, 2003Assignee: Exxon Chemical Patents Inc.Inventors: Raymond F. Watts, Philip Reeve
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Publication number: 20030109387Abstract: The peak-torque descending composition of the present invention contains a certain amount of an extreme pressure agent comprising at least neutral phosphate esters and/or neutral phosphite esters in a solvent comprising hydrocarbons and/or ethers. Further, a certain corrosion inhibitor maybe contained. The part having a sliding portion of the present invention is surface-treated with the above composition. The process for producing a component or precision machine having a sliding portion comprises immersing a part having a sliding portion in the above composition to adhere or absorb the composition onto the surface of the part, then immediately, taking out the part from the composition, followed by drying, and subsequently assembling a component or precision machine using the part.Type: ApplicationFiled: December 27, 2002Publication date: June 12, 2003Inventors: Yuji Akao, Masayuki Koike
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Patent number: RE44475Abstract: A lubricating composition with improved storage stability comprising a major amount of an oil of lubricating viscosity, at least one alkali metal borate, at least one polysulfide mixture having at least 40% dihydrocarbyl tetrasulfide or higher sulfides, and at least one non-acidic phosphorus compound comprised of a trihydrocarbyl phosphate and a dihydrocarbyl dithiophosphate derivative is disclosed. In addition to improved storage stability, the composition has improved wear performance when the ratio of polysulfides is controlled.Type: GrantFiled: February 24, 2012Date of Patent: September 3, 2013Assignee: Chevron U.S.A. Inc.Inventors: John A. Zakarian, Michael J. Haire