Three Divalent Chalcogens Single Bonded Directly To Trivalent Phosphorus Patents (Class 508/441)
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Publication number: 20030073588Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: ApplicationFiled: August 6, 2001Publication date: April 17, 2003Inventors: Jon Lee Howell, Erik Williams Perez
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Publication number: 20030040443Abstract: Phosphate ester based functional fluids containing novel anti-erosion additives provides enhanced results in erosion control.Type: ApplicationFiled: April 12, 2002Publication date: February 27, 2003Inventors: Marc Andre Poirier, Shlomo Antika
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Patent number: 6489271Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.Type: GrantFiled: August 20, 1996Date of Patent: December 3, 2002Assignee: The Lubrizol CorporationInventor: Robert C. Richardson
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Patent number: 6468946Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a di or trihydrocarbyl phosphite, (B) at least one reaction product of a di or trihydrocarbyl phosphite and sulfur or a source of sulfur; at least one di or trihydrocarbyl monothiophosphate; or salt thereof, and (C) a salt of a hydrocarbyl phosphoric acid ester. In one embodiment, the lubricant composition contains less than 0.1% phosphorus or less than about 0.75% borated dispersant. This combination of phosphorus compounds provides antiwear and thermal stability to lubricants, even at low phosphorus levels. The lubricating compositions containing the combination of the phosphorus compounds has low corrosivity to copper and low odor as well.Type: GrantFiled: July 6, 1999Date of Patent: October 22, 2002Assignee: The Lubrizol CorporationInventor: James N. Vinci
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Publication number: 20020016266Abstract: The invention relates to improved compositions comprising thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters and oil additives from the group of the polyol partial esters, amines and epoxides, and also to the use of those lubricant compositions in improving the performance properties of lubricants, such as greases, metal-working fluids, gear fluids or hydraulic fluids. Thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters are present in the compositions preferably in a concentration of less than 400 ppm.Type: ApplicationFiled: August 17, 2001Publication date: February 7, 2002Inventors: Michael Fletschinger, Peter Rohrbach, Peter Collen Hamblin, Dudley Clark, Marc Ribeaud
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Publication number: 20020010102Abstract: New sulfur-containing organophosphorus compounds of general formulae (I) and (II) and processes for producing the same; additives for lubricating oils, which contain the sulfur-containing organophosphorus compounds; and lubricating oil compositions satisfying requirements of extreme-pressure lubrication and abrasion resistance under severe conditions of high loads imposed, on automatic or continuously variable transmissions or the like. In said formulae, R1 is a hydrocarbon group having 6 to 20 carbon atoms; R2 is a divalent hydrocarbon group having 1 to 6 carbon atoms; n is an integer of 1 to 3; p is an integer of 0 to 2; and q is an integer of 0 or 1, with the proviso that p and q cannot be 0 at the same time.Type: ApplicationFiled: April 4, 2000Publication date: January 24, 2002Inventors: HIROAKI KOSHIMA, HITOSHI HATA, NOBORU SONODA, IZUMI TERADA
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Publication number: 20020010103Abstract: The present invention relates to a lubricating oil composition for use in industrial oils such as hydraulic oils, bearing oils, industrial gear oils and sliding surface lubricating oils.Type: ApplicationFiled: March 29, 2001Publication date: January 24, 2002Inventors: Himiko Takayama, Katsumi Umehara
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Patent number: 6339049Abstract: This invention relates to grease compositions containing mineral oil and/or synthetic oil as base oil, (A) lithium stearate as thickener, and (B) one kind or two kinds of more of compounds selected from a group of oxidized paraffins and diphenyl hydrogenphosphite and displaying a worked penetration in the range 270-350 and also to bearings such a s linear guides, ball screws, and rolling bearings sealed with said grease compositions. This invention can provide grease compositions of low dust emission which perform with an excellent balance of low dust emission, low rolling characteristics and fretting resistance, extend the lubricating period, reduce the maintenance cost, and are suitable for use in a clean environment. This invention can also provide bearings sealed with said grease compositions of low dust emission suitable for use in a clean environment such as semiconductor manufacturing equipment, liquid crystal manufacturing equipment, and electronic computers.Type: GrantFiled: November 8, 2000Date of Patent: January 15, 2002Assignees: THK Co., Ltd., Nippon Mitsubushi Oil CorporationInventors: Hiroshi Funahashi, Yoshio Taki, Yoshiyuki Honjo, Tomonori Kaneko, Hirotugu Kinoshita, Kiyomi Sakamoto
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Publication number: 20020002120Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an antiwear improving amount of at least one molybdenum containing composition, (B) at least one phosphorus antiwear or extreme pressure agent, and (C) at least one dispersant, provided that the lubricating composition is free of polysulfurized olefins. The lubricating compositions have improved antiwear properties. When the lubricating composition is used in a manual transmission, the amount of brass wear is reduced.Type: ApplicationFiled: December 22, 2000Publication date: January 3, 2002Inventor: Michael P. Gahagan
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Patent number: 6232275Abstract: There is disclosed a lubricating oil composition for automatic transmissions which comprises a base oil comprising at least one oil selected from the group consisting of a mineral oil and a synthetic oil each having a specific kinematic viscosity and a % CA; (A) a non-boron based succinic acid imide (e.g. polybutenylsuccinic acid imide) and a boron based succinic acid imide each in an amount of 0.1 to 5% by weight based on the whole composition; (B) a condensation product of a branched chain fatty acid having 8 to 30 carbon atoms (e.g. isostearic acid) and an amine (e.g. tetraethylene-pentamine) in an amount of 0.05 to 2% by weight based on the same; and (C) a dialkyl hydrogenphosphite (e.g. dioleyl hydrogenphosphite) in an amount of 0.1 to 1% by weight based on the same, and optionally at least one member selected from viscosity index improvers, antioxidants, metal deactivators, defoaming agents, detergents, extreme pressure agents and rust preventives.Type: GrantFiled: November 24, 1999Date of Patent: May 15, 2001Assignees: Idemitsu Kosan Co., Ltd., Nissan Motor Co., Ltd.Inventors: Toshihiko Ichihashi, Masayuki Kato, Takao Ishikawa, Yasuhiro Murakami, Kazuo Umesato, Rika Yauchihara
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Patent number: 6172014Abstract: Disclosed is an improved method of reducing compressor gas leakage by providing a compression cylinder with a lubricant comprising less than about 1% of a synergistic mixture of antioxidants.Type: GrantFiled: June 30, 1999Date of Patent: January 9, 2001Assignee: Pennzoil-Quaker StateInventor: Douglas Meyers
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Patent number: 5997761Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species of an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate.Type: GrantFiled: October 28, 1998Date of Patent: December 7, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventor: Masato Kaneko
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Patent number: 5958850Abstract: A rust preventive composition which is obtained by blending at least one base oil selected from the group consisting of a hydrocarbon solvent, a mineral oil and a synthetic oil with, as essential components,(A) an organophosphoric ester calcium salt represented by the following general formula (1) in an amount of 0.1 to 5.0% by mass based on the total mass of the composition ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group having 6 to 18 carbon atoms; and a and b are each an integer of 1 to 6,(B) water in an amount of 0.1 to 3.0 parts by weight based on 1 part by weight of the component (A), and(C) a rust inhibitor in an amount of 2.0 to 30% by mass based on the total mass of the composition.Type: GrantFiled: April 10, 1997Date of Patent: September 28, 1999Assignee: Nippon Oil., Ltd.Inventors: Yukio Matsuzaki, Yoshihiro Iwamura, Yoshitaka Natsume
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Patent number: 5872085Abstract: Lubricant or lubricant concentrate on mineral oil and/or synthetic oil basis having improved lubricating properties, in particular improved load bearing, sliding and corrosion inhibiting properties, which containsa) one or more mineral oils and/or synthetic oils as base oil andb) at least one compound A containing in its molecule at least one quaternary carbon atom and at least one ester bond and/or ether bond, as well asc) further usual additives.Type: GrantFiled: May 24, 1995Date of Patent: February 16, 1999Inventor: Erasmus Froeschmann
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Patent number: 5858266Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species selected from the group consisting of a metallic salt of an inorganic phosphoric acid, e.g. potassium phosphate, an amine salt of an inorganic phosphoric acid, e.g. octylamine phosphate, a metallic salt of an organic phosphoric acid, e.g. dipotassium lauryl phosphate, an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate, a metallic salt of an organic phosphonic acid, e.g. dipotassium oleyl phosphonate, an amine salt of an organic phosphonic acid, e.g. octylamine dilauryl phosphonate, a metallic salt of an organic phosphorous acid, e.g. sodium dioleyl phoshite, and an amine salt of an organic phosphorous acid, e.g. octylamene dioleyl phosphate.Type: GrantFiled: April 7, 1997Date of Patent: January 12, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventor: Masato Kaneko
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Patent number: 5840663Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of low potency friction modifiers, alkyl phosphites, specific ashless dispersants and a corrosion inhibitor. The anti-shudder durability of these fluids may be further enhanced by inclusion of a metallic detergent.Type: GrantFiled: December 18, 1996Date of Patent: November 24, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Roger K. Nibert, Manoj Tandon, Raymond F. Watts
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Patent number: 5792731Abstract: A lubricant composition for continuous variable transmissions which comprises a base oil and auxiliaries incorporated therein which are a sulfur-based extreme pressure additive (A), a phosphorus-based extreme pressure additive (B), and an alkaline earth metal-based detergent (C) It is superior in wear resistance and extreme pressure properties and keeps the coefficient of friction high for a long period of time, so that it is capable of transmitting a large capacity of torque when it is applied to an continuous variable transmission. It is particularly suitable for a transmission of metal belt type.Type: GrantFiled: June 5, 1997Date of Patent: August 11, 1998Assignee: Idemitsu Kosan Co., Ltd.Inventors: Toshihiko Ichihashi, Hideo Igarashi, Noboru Sonoda
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Patent number: 5792733Abstract: A composition of an oil of lubricating viscosity, a phosphorus compound represented by the formula ##STR1## and tautomers thereof, where each X is independently O or S, and an olefin of about 6 to about 30 carbon atoms exhibits improved antiwear performance.Type: GrantFiled: August 14, 1997Date of Patent: August 11, 1998Assignee: The Lubrizol CorporationInventors: Ichiro Minami, Hyun-Soo Hong, Naresh C. Mathur
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Patent number: 5712230Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.Type: GrantFiled: March 10, 1997Date of Patent: January 27, 1998Assignee: The Lubrizol CorporationInventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5693598Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.Type: GrantFiled: September 3, 1996Date of Patent: December 2, 1997Assignee: The Lubrizol CorporationInventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5583100Abstract: A water-dispersible oil composition for hot rolling aluminum or aluminum alloys having excellent lubricity and emulsion stability and which minimizes heat deterioration over prolonged periods of time contains the following components (a) to (d): (a) a mineral oil, (b) 3 to 30% by weight of a fatty acid or its monoesters, or oils and fats, (c) 0.5 to 10% by weight of a C.sub.4 -C.sub.18 alkyl or alkenyl phosphoric (or phosphorous) acid ester, and (d) 0.1 to 10% by weight of a salt between a polymer and an organic acid salt, wherein the polymer has an average molecular weight of 10,000 to 1,000,000 and is a copolymer of a monomer represented by formula (1): ##STR1## wherein R.sup.1 is H or Me, R.sup.2 and R.sup.3 are independently H or C.sub.1 -C.sub.3 alkyl, m is an integer of 0 or 1, and n is an integer of 1, 2 or 3, and (meth) acrylamide and/or a (meth) acrylic acid salt. Rolled aluminum or aluminum alloy products having excellent surface quality can be obtained using this composition.Type: GrantFiled: September 28, 1994Date of Patent: December 10, 1996Assignees: Kabushiki Kaisha Kobe Seiko Sho, Kao CorporationInventors: Yoshio Okamoto, Yukio Sugishita, Hiroyuki Andoh, Kuniaki Matsui, Takehiko Ichimoto, Masataka Negishi
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Patent number: 5547593Abstract: Disclosed is a lubricant oil composition comprising: (A) a fluorine-containing aromatic compound, and(B) an alkyl- or alkyl derivative-substituted aromatic compound having a kinetic viscosity of from 0.1 to 500 cSt as measured at 40 .degree. C., wherein:the compound (A) is represented by the formula:R(XR.sub.f).sub.n (A)wherein X represents an oxygen or a sulfur atom; n is an integer of from 1 to 4; R represents an n-valent, unsubstituted or substituted aromatic group having from 6 to 60 carbon atoms; and R.sub.f represents an unsubstituted or partially substituted fluorocarbon group having from 1 to 25 carbon atoms; andthe compound (B) comprises at least one substituted aromatic nucleus, wherein a substituent is an unsubstituted or substituted alkyl group having from 1 to 30 carbon atoms, or a derivative thereof. The lubricant oil composition having a kinetic viscosity of from 2 to 500 cSt as measured at 40.degree. C.Type: GrantFiled: August 11, 1994Date of Patent: August 20, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kenichi Sanechika, Hiroyuki Fukui, Masanori Ikeda