Three Divalent Chalcogens Single Bonded Directly To Trivalent Phosphorus Patents (Class 508/441)
  • Publication number: 20030073588
    Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.
    Type: Application
    Filed: August 6, 2001
    Publication date: April 17, 2003
    Inventors: Jon Lee Howell, Erik Williams Perez
  • Publication number: 20030040443
    Abstract: Phosphate ester based functional fluids containing novel anti-erosion additives provides enhanced results in erosion control.
    Type: Application
    Filed: April 12, 2002
    Publication date: February 27, 2003
    Inventors: Marc Andre Poirier, Shlomo Antika
  • Patent number: 6489271
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: December 3, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Robert C. Richardson
  • Patent number: 6468946
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a di or trihydrocarbyl phosphite, (B) at least one reaction product of a di or trihydrocarbyl phosphite and sulfur or a source of sulfur; at least one di or trihydrocarbyl monothiophosphate; or salt thereof, and (C) a salt of a hydrocarbyl phosphoric acid ester. In one embodiment, the lubricant composition contains less than 0.1% phosphorus or less than about 0.75% borated dispersant. This combination of phosphorus compounds provides antiwear and thermal stability to lubricants, even at low phosphorus levels. The lubricating compositions containing the combination of the phosphorus compounds has low corrosivity to copper and low odor as well.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: October 22, 2002
    Assignee: The Lubrizol Corporation
    Inventor: James N. Vinci
  • Publication number: 20020016266
    Abstract: The invention relates to improved compositions comprising thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters and oil additives from the group of the polyol partial esters, amines and epoxides, and also to the use of those lubricant compositions in improving the performance properties of lubricants, such as greases, metal-working fluids, gear fluids or hydraulic fluids. Thiophosphoric acid esters and dithiophosphoric acid esters or phosphoric acid thioesters are present in the compositions preferably in a concentration of less than 400 ppm.
    Type: Application
    Filed: August 17, 2001
    Publication date: February 7, 2002
    Inventors: Michael Fletschinger, Peter Rohrbach, Peter Collen Hamblin, Dudley Clark, Marc Ribeaud
  • Publication number: 20020010102
    Abstract: New sulfur-containing organophosphorus compounds of general formulae (I) and (II) and processes for producing the same; additives for lubricating oils, which contain the sulfur-containing organophosphorus compounds; and lubricating oil compositions satisfying requirements of extreme-pressure lubrication and abrasion resistance under severe conditions of high loads imposed, on automatic or continuously variable transmissions or the like. In said formulae, R1 is a hydrocarbon group having 6 to 20 carbon atoms; R2 is a divalent hydrocarbon group having 1 to 6 carbon atoms; n is an integer of 1 to 3; p is an integer of 0 to 2; and q is an integer of 0 or 1, with the proviso that p and q cannot be 0 at the same time.
    Type: Application
    Filed: April 4, 2000
    Publication date: January 24, 2002
    Inventors: HIROAKI KOSHIMA, HITOSHI HATA, NOBORU SONODA, IZUMI TERADA
  • Publication number: 20020010103
    Abstract: The present invention relates to a lubricating oil composition for use in industrial oils such as hydraulic oils, bearing oils, industrial gear oils and sliding surface lubricating oils.
    Type: Application
    Filed: March 29, 2001
    Publication date: January 24, 2002
    Inventors: Himiko Takayama, Katsumi Umehara
  • Patent number: 6339049
    Abstract: This invention relates to grease compositions containing mineral oil and/or synthetic oil as base oil, (A) lithium stearate as thickener, and (B) one kind or two kinds of more of compounds selected from a group of oxidized paraffins and diphenyl hydrogenphosphite and displaying a worked penetration in the range 270-350 and also to bearings such a s linear guides, ball screws, and rolling bearings sealed with said grease compositions. This invention can provide grease compositions of low dust emission which perform with an excellent balance of low dust emission, low rolling characteristics and fretting resistance, extend the lubricating period, reduce the maintenance cost, and are suitable for use in a clean environment. This invention can also provide bearings sealed with said grease compositions of low dust emission suitable for use in a clean environment such as semiconductor manufacturing equipment, liquid crystal manufacturing equipment, and electronic computers.
    Type: Grant
    Filed: November 8, 2000
    Date of Patent: January 15, 2002
    Assignees: THK Co., Ltd., Nippon Mitsubushi Oil Corporation
    Inventors: Hiroshi Funahashi, Yoshio Taki, Yoshiyuki Honjo, Tomonori Kaneko, Hirotugu Kinoshita, Kiyomi Sakamoto
  • Publication number: 20020002120
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an antiwear improving amount of at least one molybdenum containing composition, (B) at least one phosphorus antiwear or extreme pressure agent, and (C) at least one dispersant, provided that the lubricating composition is free of polysulfurized olefins. The lubricating compositions have improved antiwear properties. When the lubricating composition is used in a manual transmission, the amount of brass wear is reduced.
    Type: Application
    Filed: December 22, 2000
    Publication date: January 3, 2002
    Inventor: Michael P. Gahagan
  • Patent number: 6232275
    Abstract: There is disclosed a lubricating oil composition for automatic transmissions which comprises a base oil comprising at least one oil selected from the group consisting of a mineral oil and a synthetic oil each having a specific kinematic viscosity and a % CA; (A) a non-boron based succinic acid imide (e.g. polybutenylsuccinic acid imide) and a boron based succinic acid imide each in an amount of 0.1 to 5% by weight based on the whole composition; (B) a condensation product of a branched chain fatty acid having 8 to 30 carbon atoms (e.g. isostearic acid) and an amine (e.g. tetraethylene-pentamine) in an amount of 0.05 to 2% by weight based on the same; and (C) a dialkyl hydrogenphosphite (e.g. dioleyl hydrogenphosphite) in an amount of 0.1 to 1% by weight based on the same, and optionally at least one member selected from viscosity index improvers, antioxidants, metal deactivators, defoaming agents, detergents, extreme pressure agents and rust preventives.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: May 15, 2001
    Assignees: Idemitsu Kosan Co., Ltd., Nissan Motor Co., Ltd.
    Inventors: Toshihiko Ichihashi, Masayuki Kato, Takao Ishikawa, Yasuhiro Murakami, Kazuo Umesato, Rika Yauchihara
  • Patent number: 6172014
    Abstract: Disclosed is an improved method of reducing compressor gas leakage by providing a compression cylinder with a lubricant comprising less than about 1% of a synergistic mixture of antioxidants.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: January 9, 2001
    Assignee: Pennzoil-Quaker State
    Inventor: Douglas Meyers
  • Patent number: 5997761
    Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species of an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: December 7, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Masato Kaneko
  • Patent number: 5958850
    Abstract: A rust preventive composition which is obtained by blending at least one base oil selected from the group consisting of a hydrocarbon solvent, a mineral oil and a synthetic oil with, as essential components,(A) an organophosphoric ester calcium salt represented by the following general formula (1) in an amount of 0.1 to 5.0% by mass based on the total mass of the composition ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group having 6 to 18 carbon atoms; and a and b are each an integer of 1 to 6,(B) water in an amount of 0.1 to 3.0 parts by weight based on 1 part by weight of the component (A), and(C) a rust inhibitor in an amount of 2.0 to 30% by mass based on the total mass of the composition.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: September 28, 1999
    Assignee: Nippon Oil., Ltd.
    Inventors: Yukio Matsuzaki, Yoshihiro Iwamura, Yoshitaka Natsume
  • Patent number: 5872085
    Abstract: Lubricant or lubricant concentrate on mineral oil and/or synthetic oil basis having improved lubricating properties, in particular improved load bearing, sliding and corrosion inhibiting properties, which containsa) one or more mineral oils and/or synthetic oils as base oil andb) at least one compound A containing in its molecule at least one quaternary carbon atom and at least one ester bond and/or ether bond, as well asc) further usual additives.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: February 16, 1999
    Inventor: Erasmus Froeschmann
  • Patent number: 5858266
    Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species selected from the group consisting of a metallic salt of an inorganic phosphoric acid, e.g. potassium phosphate, an amine salt of an inorganic phosphoric acid, e.g. octylamine phosphate, a metallic salt of an organic phosphoric acid, e.g. dipotassium lauryl phosphate, an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate, a metallic salt of an organic phosphonic acid, e.g. dipotassium oleyl phosphonate, an amine salt of an organic phosphonic acid, e.g. octylamine dilauryl phosphonate, a metallic salt of an organic phosphorous acid, e.g. sodium dioleyl phoshite, and an amine salt of an organic phosphorous acid, e.g. octylamene dioleyl phosphate.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: January 12, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Masato Kaneko
  • Patent number: 5840663
    Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of low potency friction modifiers, alkyl phosphites, specific ashless dispersants and a corrosion inhibitor. The anti-shudder durability of these fluids may be further enhanced by inclusion of a metallic detergent.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: November 24, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Roger K. Nibert, Manoj Tandon, Raymond F. Watts
  • Patent number: 5792731
    Abstract: A lubricant composition for continuous variable transmissions which comprises a base oil and auxiliaries incorporated therein which are a sulfur-based extreme pressure additive (A), a phosphorus-based extreme pressure additive (B), and an alkaline earth metal-based detergent (C) It is superior in wear resistance and extreme pressure properties and keeps the coefficient of friction high for a long period of time, so that it is capable of transmitting a large capacity of torque when it is applied to an continuous variable transmission. It is particularly suitable for a transmission of metal belt type.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: August 11, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshihiko Ichihashi, Hideo Igarashi, Noboru Sonoda
  • Patent number: 5792733
    Abstract: A composition of an oil of lubricating viscosity, a phosphorus compound represented by the formula ##STR1## and tautomers thereof, where each X is independently O or S, and an olefin of about 6 to about 30 carbon atoms exhibits improved antiwear performance.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: August 11, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Ichiro Minami, Hyun-Soo Hong, Naresh C. Mathur
  • Patent number: 5712230
    Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 27, 1998
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5693598
    Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 2, 1997
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5583100
    Abstract: A water-dispersible oil composition for hot rolling aluminum or aluminum alloys having excellent lubricity and emulsion stability and which minimizes heat deterioration over prolonged periods of time contains the following components (a) to (d): (a) a mineral oil, (b) 3 to 30% by weight of a fatty acid or its monoesters, or oils and fats, (c) 0.5 to 10% by weight of a C.sub.4 -C.sub.18 alkyl or alkenyl phosphoric (or phosphorous) acid ester, and (d) 0.1 to 10% by weight of a salt between a polymer and an organic acid salt, wherein the polymer has an average molecular weight of 10,000 to 1,000,000 and is a copolymer of a monomer represented by formula (1): ##STR1## wherein R.sup.1 is H or Me, R.sup.2 and R.sup.3 are independently H or C.sub.1 -C.sub.3 alkyl, m is an integer of 0 or 1, and n is an integer of 1, 2 or 3, and (meth) acrylamide and/or a (meth) acrylic acid salt. Rolled aluminum or aluminum alloy products having excellent surface quality can be obtained using this composition.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: December 10, 1996
    Assignees: Kabushiki Kaisha Kobe Seiko Sho, Kao Corporation
    Inventors: Yoshio Okamoto, Yukio Sugishita, Hiroyuki Andoh, Kuniaki Matsui, Takehiko Ichimoto, Masataka Negishi
  • Patent number: 5547593
    Abstract: Disclosed is a lubricant oil composition comprising: (A) a fluorine-containing aromatic compound, and(B) an alkyl- or alkyl derivative-substituted aromatic compound having a kinetic viscosity of from 0.1 to 500 cSt as measured at 40 .degree. C., wherein:the compound (A) is represented by the formula:R(XR.sub.f).sub.n (A)wherein X represents an oxygen or a sulfur atom; n is an integer of from 1 to 4; R represents an n-valent, unsubstituted or substituted aromatic group having from 6 to 60 carbon atoms; and R.sub.f represents an unsubstituted or partially substituted fluorocarbon group having from 1 to 25 carbon atoms; andthe compound (B) comprises at least one substituted aromatic nucleus, wherein a substituent is an unsubstituted or substituted alkyl group having from 1 to 30 carbon atoms, or a derivative thereof. The lubricant oil composition having a kinetic viscosity of from 2 to 500 cSt as measured at 40.degree. C.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: August 20, 1996
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Kenichi Sanechika, Hiroyuki Fukui, Masanori Ikeda