Abstract: A low emissions, high oxidative stability crankcase lubricating oil formulation which is prepared from a base stock which comprises at least one synthetic ester selected from the group consisting of: polyol esters, synthetic esters having between 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the polyol, and synthetic esters combined with at least one additional functional group which is capable of increasing the polarity of the functionalized synthetic ester, wherein the base stock has an oxygen, nitrogen or halogen content of at least 15 wt. %, based on the total weight of the base stock; and a lubricant additive package.
Type:
Grant
Filed:
September 21, 1995
Date of Patent:
October 7, 1997
Assignee:
Exxon Chemical Patents Inc
Inventors:
Richard Henry Schlosberg, Walter Weissman, Maciej Radosz, Gerald Dennis Dupre', Ralph Donald Gray, Jr., John Eric Johnston, Patrick Edward Godici, Richard Samuel Polizzotti, Lawrence Harold Kaplan
Abstract: A synthetic ester composition exhibiting thermal and oxidative stability which comprises the reaction product of: a branched or linear alcohol having the general formula K(OH).sub.n, wherein R is an aliphatic or cyclo-aliphatic group having from about 2 to 20 carbon atoms and n is at least 2; and at least one branched mono-carboxylic acid which has a carbon number in the range between about C.sub.5 to C.sub.13 ; wherein the synthetic ester composition has between 5-35% unconverted hydroxyl groups, based on the total amount of hydroxyl groups in the branched or linear alcohol.
Type:
Grant
Filed:
March 14, 1995
Date of Patent:
September 9, 1997
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Richard Henry Schlosberg, Lavonda Denise Sherwood-Williams, Haven S. Aldrich, John S. Szobota
Abstract: The objective of the present invention resides in providing a lubricant for refrigerators that reacts rapidly with free acids and contains a stabilizer that has good compatibility with a chlorine-free Flon-thpe coolant such as Flon 134a and the like whose molecules do not contain chlorine. The lubricant for refrigerators employing a chlorine-free Flon-type coolant in accordance with the present invention 100 parts by weight of a synthetic oil and is compounded with 0.05 to 15 parts by weight of an alicyclic epoxy compound having one or more functional groups represented by the following formula: ##STR1## (wherein R.sub.1 and R.sub.2 independently represent a hydrogen or methyl group, and may be the same or different).