Esterified Alcohol Is Polyhydroxy Alcohol (e.g., Pentaerythritol Tetraalkanoate, Etc.) Patents (Class 508/485)
- With organic nitrogen or phosphorus compound (Class 508/487)
- With carboxylic acid or carboxylic acid salt (Class 508/488)
- With organic non-carboxylic acid ester oxygen compound or halogen compound (Class 508/489)
- With hydrocarbon polymer (Class 508/490)
- Naturally occurring triglyceride (e.g., tallow, castor oil, corn oil, etc.) (Class 508/491)
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Patent number: 11549077Abstract: A refrigerating machine oil containing: a lubricating base oil; and a compound represented by the following formula (1): wherein R1 and R2 each independently represent a monovalent hydrocarbon group, R3 represents a divalent hydrocarbon group, and R4 represents hydrogen atom or a monovalent hydrocarbon group, and the refrigerating machine oil having a kinematic viscosity at 100° C. of 0.5 mm2/s or more and 2.5 mm2/s or less.Type: GrantFiled: February 6, 2019Date of Patent: January 10, 2023Assignee: ENEOS CORPORATIONInventors: Yohei Shono, Fumiyuki Nara, Takeshi Okido, Hidetoshi Ogata
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Patent number: 11377619Abstract: An aspect of the present invention relates to a refrigerating machine oil with a kinematic viscosity at 100° C. of 0.5 mm2/s or more and 1.5 mm2/s or less, a 90% distillation temperature in gas chromatography distillation of 280° C. or more and less than 360° C., and an aniline point of 70° C. or more.Type: GrantFiled: January 30, 2018Date of Patent: July 5, 2022Assignee: ENEOS CORPORATIONInventors: Fumiyuki Nara, Yohei Shono, Takeshi Okido, Hidetoshi Ogata
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Patent number: 11339346Abstract: The invention is related to a composition for use in hydraulic systems of an aircraft. The composition typically comprises an adipic acid-based polyester in a phosphate ester base stock substantially consisting of trialkyl phosphates.Type: GrantFiled: December 12, 2017Date of Patent: May 24, 2022Assignee: Evonik Operations GmbHInventors: Stefan Karl Maier, Nicolai Kolb, Michael Neusius
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Patent number: 11306053Abstract: [Problem] An ester compound having low viscosity, excellent fluidity even at low temperatures, and a high viscosity index; and a lubricating oil base oil containing said compound are provided. [Solution] The present invention provides an ester compound indicated by formula (I). Formula (I) (in formula (I), R1 is a hydrocarbon group having 1 to 35 carbon atoms and at least one hydrogen in the hydrocarbon group may be independently substituted with a group indicated by formula (II)). Formula (II) (in formula (II), R2 is a linear alkyl having 1 to 30 carbon atoms or a branched alkyl having 3 to 30 carbon atoms.Type: GrantFiled: January 31, 2019Date of Patent: April 19, 2022Assignees: DAISAN KASEI CO., LTD, JNC CORPORATIONInventors: Yasuo Urata, Tetsuya Isaka, Taichi Shimada
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Patent number: 11292978Abstract: The present invention relates to polyol esters that are particularly suitable for use as insulating oils in electrical equipment where an effective cooling action is required, such as electrical transformers. In particular the invention relates to esters of trimethylolpropane with monocarboxylic acids of nine and/or ten carbon atoms, wherein the monocarboxylic acids of nine and/or ten carbon atoms comprise 5-15 mol % of branched acids and 85-95 mol % of linear acids with respect to the total moles of the monocarboxylic acids.Type: GrantFiled: June 10, 2016Date of Patent: April 5, 2022Assignee: NOVAMONT S.P.A.Inventors: Luigi Capuzzi, Francesca Digioia, Angela Sagliano
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Patent number: 11230683Abstract: The invention relates to the use of an oil that does not include tricresyl phosphate and includes as an anti-wear additive at least one diphosphorus compound for the prophylaxis of aerotoxic syndrome, especially in case of fume event. It also relates to the oil as such.Type: GrantFiled: May 20, 2020Date of Patent: January 25, 2022Assignee: NYCOInventors: Djibril Faye, Marion Gay, Florence Severac, Jean-Louis Mansoux, Grégoire Herve
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Patent number: 11142718Abstract: The present invention discloses with the development of ecofriendly and biodegradable lubricant formulation useful for micro electro mechanical systems and process thereof. The new generation Mineral oil free lubricant formulations were developed by esterification of polyols such as 2,2-dimethyl, 1,3-Propanediol, 2,2-diethyl-1,3-propane diol, and aliphatic di carboxylic acids like adipic and azelaic and with mono alcohol, using heterogeneous catalyst Indion 140 with cation exchange properties. The said formulation has a viscosity in the range of 31 to 47 cSt at 40° C., a high viscosity index of 139-196, pour point of approximately <?39° C. with a multifunctional EP additive of recommended dose of 1.5-4%.Type: GrantFiled: April 26, 2018Date of Patent: October 12, 2021Assignee: Council of Scientific & Industrial ResearchInventors: Ponnekanti Nagendramma, Anjan Ray, Gananath Doulat Thakre, Neeraj Atray
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Patent number: 11136524Abstract: The invention relates to a seal swell agent which is a substituted sulfonyldibenzene compound, and lubricating compositions containing the seal swell agent. The substituents on the benzene rings may be hydrocarbyl groups of 4 to 20 carbon atoms or alkylene groups of 1-2 carbon atoms with further functional groups.Type: GrantFiled: April 15, 2020Date of Patent: October 5, 2021Assignee: The Lubrizol CorporationInventors: Mariam Shamszad, Paul E. Adams, Mahmud M. Hussain, Peter Miatt
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Patent number: 11136527Abstract: A lubricant, including, by weight: 80-85 parts of a base oil; 1-2 parts of a methyl-silicone oil; 1-2 parts of polymethacrylate; 2-4 parts of pentaerythritol polyisobutylene succinate; 1-2 parts of di-n-butyl phosphite; 2-3 parts of butylhydroxytoluene; 2-4 parts of an ethylene-propylene copolymer; 1-2 parts of an alkenyl succinate; and 3-5 parts of copper nanoparticles. A method of preparing the lubricant includes: adding the base oil, the methyl-silicone oil, the polymethacrylate, the ethylene-propylene copolymer, the butylhydroxytoluene, the alkenyl succinate to a reactor, and stirring a resulting first mixture under normal temperature and pressure at 300-400 rpm for 3-4 hours, to yield a primary product; and adding the di-n-butyl phosphite, the pentaerythritol polyisobutylene succinate, and the copper nanoparticles to the primary product, and stirring a resulting second mixture at 150-250 rpm for 2-2.5 hours.Type: GrantFiled: November 14, 2019Date of Patent: October 5, 2021Assignee: HENAN UNIVERSITYInventors: Yujuan Zhang, Shengmao Zhang, Pingyu Zhang, Zhijun Zhang
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Patent number: 10954184Abstract: The present invention provides compounds of formula (I): wherein W is independently selected from the group consisting of H, F, Cl, Br and I; 10 X is independently selected from the group consisting of H, F, Cl, Br, I, CW3 and OR on the basis that at least one X is OR; R is independently selected from the group consisting of C(O) (CH2)m(CF2)nY and CW2C(CW2OC(O)(CH2)m(CF2)nY)3; m is an integer from 0 to 2; 15 n is an integer from 2 to 8; Y is C(Z)3; and Z is independently selected from the group consisting of H, F, Cl, Br and I. Such compounds may be utilised as lubricants, for example in heat transfer compositions.Type: GrantFiled: December 7, 2016Date of Patent: March 23, 2021Assignee: MEXICHEM FLUOR S.A. DE C.V.Inventors: Robert Elliot Low, Andrew Paul Sharratt, Emma Jane Hodgson
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Patent number: 10858563Abstract: Provided is a method for transferring a refrigerant composition containing three components (difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane) such that the compositional change of the liquid phase due to the phase transition that occurs in the supply source when transferring the refrigerant composition falls within a tolerance range. The method for transferring a refrigerant composition containing difluoromethane, pentafluoroethane, and 1,1,1,2-tetrafluoroethane includes transferring a refrigerant composition from a liquid phase in a supply source to a supply destination, wherein the liquid phase of the refrigerant composition in the supply source before the transfer contains 32.5 to 33.5 wt % of difluoromethane, 14.3 to 16.0 wt % of pentafluoroethane, and 50.5 to 53.2 wt % of 1,1,1,2-tetrafluoroethane.Type: GrantFiled: November 28, 2017Date of Patent: December 8, 2020Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Tatsumi Tsuchiya, Mitsushi Itano, Hitomi Kuroki, Yasufu Yamada
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Patent number: 10836973Abstract: A refrigerator oil that is excellent in thermal stability and oxidation stability is provided. The refrigerator oil contains at least one compound selected from the group consisting of a polyvinyl ether compound, a polyoxyalkylene glycol compound, and a polyol ester compound and has a Hazen color number according to ASTM D1209-05 of 0 to 10.Type: GrantFiled: October 7, 2016Date of Patent: November 17, 2020Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Masato Kaneko
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Patent number: 10604720Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by introducing to a combustion chamber of the engine from 0.1 to 5% by volume of the gasoline used a lubricating oil as a formulated oil, said formulated oil having a composition comprising (i) a major amount of a lubricating oil base stock comprising at least 80% by weight of one branched ester having at least 15% of the total carbons in the form of methyl groups, and (ii) a minor amount of at least one ashless amine phosphate antiwear additive.Type: GrantFiled: July 15, 2019Date of Patent: March 31, 2020Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Zhisheng Gao, Luca Salvi, Eugine Choi, Matthew W. Boland, Andrew E. Taggi, Andrew D. Satterfield
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Patent number: 10562840Abstract: Levulinic-capped estolides having improved physical properties that make them more desirable and suitable as bio-based industrial or commercial products are disclosed. The physical properties of the disclosed estolide compositions have surprisingly low pour points that are substantially lower than previously known estolide compounds and superior to petroleum-based compounds designed for similar applications.Type: GrantFiled: September 24, 2018Date of Patent: February 18, 2020Assignee: The United States of America, as represented by the Secretary of AgricultureInventors: Steven C. Cermak, Terry Isbell, Amber L. Durham
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Patent number: 10435641Abstract: The mixed composition for a refrigerator of the present invention contains: a refrigerant containing at least one unsaturated fluorinated hydrocarbon compound selected from compounds represented by the following molecular formula (1): CpFrHs??(1) wherein p represents an integer of from 2 to 6; r represents an integer of from 1 to 11; and s represents an integer of from 1 to 11, provided that the compound has one or more carbon-carbon unsaturated bond in a molecule, and a refrigerator lubricating oil containing, as a major component, a polyol ester (A) of a fatty acid (a1) that is a fatty acid having a number of carbon atoms of from 9 to 16 and has a content of a fatty acid having a number of carbon atoms of 9 of 50% by mol or more based on the total amount of the fatty acid (a1), and a polyol (a2) that is pentaerythritol and/or dipentaerythritol.Type: GrantFiled: March 10, 2016Date of Patent: October 8, 2019Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Masato Kaneko, Tadashi Kisen, Takahiro Hoshida
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Patent number: 10377964Abstract: The invention provides a magneto-rheological grease composition which contains (a) a base oil including at least 30% by mass of an ether type synthetic oil; (b) an aliphatic diurea thickener; and (c) magnetic particles in an amount of 45 to 95% by mass based on the total mass of the composition. The magneto-rheological grease composition can show superior thermal stability, dispersion stability and magneto-rheological properties.Type: GrantFiled: November 16, 2012Date of Patent: August 13, 2019Assignees: KYODO YUSHI CO., LTD., YOKOHAMA NATIONAL UNIVERSITYInventors: Hiroshi Kimura, Shinya Kondo, Tetsuo Ogawa, Makoto Hayama, Koji Maesaka, Shin Morishita, Ken Nakano, Toshihiko Shiraishi
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Patent number: 10245002Abstract: For dose calibration in functional imaging, an amount of bias in a dose calibrator measurement of activity is determined using a spectroscopic detector. The bias may then be used to correct dose values for the same isotope used to determine a factory-based sensitivity of the functional imaging system. When local functional imaging systems are calibrated, any difference in sensitivity from the factory measured sensitivity may be due to local dose calibrator bias, so the difference in sensitivity is used to determine a local correction.Type: GrantFiled: August 1, 2017Date of Patent: April 2, 2019Assignee: Siemens Medical Solutions USA, Inc.Inventor: Manojeet Bhattacharya
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Patent number: 10030206Abstract: The use of a complex ester obtainable by esterification reaction between aliphatic linear or branched C2- to C12-dicarboxylic acids, aliphatic linear or branched polyhydroxy alcohols with 3 to 6 hydroxyl groups, and, as chain stopping agents, aliphatic linear or branched C1- to C30-monocarboxylic acids or aliphatic linear or branched monobasic Ci- to C30-alcohols, as an additive in a fuel.Type: GrantFiled: October 20, 2014Date of Patent: July 24, 2018Assignee: BASF SEInventors: Marc Walter, Dirk Rettemeyer, Markus Hansch, Ludwig Voelkel, Bjoern Thomas Hahn, Muriel Ecormier, Thomas Hayden
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Patent number: 9834736Abstract: A lubricating oil composition for internal combustion engines of passenger and commercial four-wheeled vehicles is provided which can exhibit excellent fuel efficiency performance and wear resistance reliability. The lubricating oil composition includes a base oil and a complex polyester mixture. The base oil includes at least one of poly-?-olefin, an ester-based base oil, or a partially hydrogenated mineral oil. The complex polyester mixture includes a polyester obtained by condensing a polyhydric alcohol, a polycarboxylic acid, and a monohydric alcohol having an oxyalkylene group. The content of the complex polyester mixture is 0.01% by mass or more with respect to the total mass of the lubricating oil composition, the high-temperature shear viscosity (HTHS viscosity) at 150° C. is 1.0 mPa·s to 2.6 mPa·s, and the NOACK evaporation amount is 40% or less.Type: GrantFiled: June 15, 2016Date of Patent: December 5, 2017Assignees: FUJIFILM Corporation, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Toshiki Fujiwara, Hiroyuki Suzuki, Saisuke Watanabe, Ippei Fukutomi, Motoichi Murakami, Tetsushi Suzuki
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Patent number: 9719045Abstract: The invention provides a grease composition for rolling bearings of automotive electrical equipment or automotive auxiliaries, containing a base oil that includes as an essential component an alkyldiphenyl ether oil; a diurea thickener represented by formula (1); an anti-flaking additive including an organic sulfonate rust inhibitor and a load carrying additive; and an antioxidant. In the formula (1), R2 is a bivalent aromatic hydrocarbon group having 6 to 15 carbon atoms; and one of R1 or R3 represents cyclohexyl group and the other represents cyclohexyl group, an alkyl group having 8 to 22 carbon atoms or an aromatic hydrocarbon group having 6 to 12 carbon atoms.Type: GrantFiled: October 25, 2013Date of Patent: August 1, 2017Assignee: KYODO YUSHI CO., LTD.Inventors: Ryo Aida, Terasu Yoshinari, Junichi Imai
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Patent number: 9650328Abstract: Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R1, R3, and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein compositions comprising the compounds are characterized by particular combinations of values for estolide number, kinematic viscosity, and pour point. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.Type: GrantFiled: December 21, 2015Date of Patent: May 16, 2017Assignee: Biosynthetic Technologies, LLCInventor: Jakob Bredsguard
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Patent number: 9567545Abstract: A grease composition for EV/HEV driving motor bearing, containing a diurea thickener of the following formula (A): wherein R1, R2 and R3 are defined, with the ratio of the number of moles of the straight-chain or branched alkyl group having 16 to 20 carbon atoms to the total number of moles of the cyclohexyl group and the straight-chain or branched alkyl group having 16 to 20 carbon atoms, expressed as [((the number of alkyl group)/(the number of cyclohexyl group+the number of alkyl group))×100] being 60 to 80%, and a base oil which has a kinematic viscosity at 40° C. of 15 to 50 mm2/s and includes a trimethylolpropane ester oil in an amount of 80 mass % or more based on the total base oil mass. The grease composition can exhibit a long bearing lubrication life at high temperature and high speed, and satisfactory low-temperature flowability.Type: GrantFiled: July 27, 2012Date of Patent: February 14, 2017Assignees: NSK LTD., KYODO YUSHI CO., LTD.Inventors: Hironori Mizuki, Takeshi Maejima, Kenichi Iso, Kazunori Nakagawa, Yutaka Imai, Ryo Aida
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Patent number: 9404061Abstract: Provided is a grease composition containing a urea thickener represented by formula (1): R1—NHCONH—R2—NHCONH—R3??(1) (wherein R2 is a bivalent aromatic hydrocarbon group having 6 to 15 carbon atoms; and R1 and R3, which may be the same or different from each other, represent an alkyl group having 8 to 22 carbon atoms, cyclohexyl group or an aryl group having 6 to 12 carbon atoms); and a base oil containing at least one compound represented by formula (3): (wherein R6 and R7, which may be the same or different from each other, represent a branched alkyl group having 10 to 26 carbon atoms, with the ratio of the number of moles of the alkyl groups represented by R6 and R7 being defined; and m and n are real numbers of 0 or more so as to satisfy the condition of 1.0?m+n?3.0).Type: GrantFiled: June 5, 2014Date of Patent: August 2, 2016Assignee: KYODO YUSHI CO., LTD.Inventor: Terasu Yoshinari
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Patent number: 9328307Abstract: A novel, branched, saturated, primary fatty acid amide is disclosed. Application areas are as a slip and/or antiblocking agent or mold release agent. The branched, saturated, primary fatty acid has a formula R—CO—NH2 where R is a saturated, branched hydrocarbon chain having 11 to 23 carbon atoms, wherein at least 60% by weight of the R—CO—NH2 molecules have monoalkyl branches and less than 25% by weight of the R—CO—NH2 molecules have polyalkyl branches.Type: GrantFiled: September 18, 2014Date of Patent: May 3, 2016Assignee: CRODA INTERNATIONAL PLCInventors: Jonathan David Townend, John Latus, Philip John McCoy, Adam John Maltby, David Andrew Parker
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Patent number: 9243177Abstract: The working fluid composition for a refrigerating machine of the present invention comprises: a refrigerating machine oil comprising a mineral oil and an alkylbenzene in a mass ratio, the mineral oil/the alkylbenzene, of 85/15 to 15/85, wherein the mineral oil has a % CN by n-d-M ring analysis of 20 to 60, a pour point of ?15° C. or less and a kinematic viscosity at 40° C. of 1.5 to 15 mm2/s; and a hydrocarbon refrigerant having 2 to 4 carbon atoms, wherein the refrigerating machine oil having a kinematic viscosity at 40° C. of 2 to 12 mm2/s and a flash point of 120° C. or more.Type: GrantFiled: February 28, 2013Date of Patent: January 26, 2016Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Masanori Saito, Fumiyuki Nara, Tomonari Matsumoto, Kuniko Adegawa
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Patent number: 9219197Abstract: A micro-light-emitting diode (micro-LED) includes a first type semiconductor layer, a second type semiconductor layer, a first edge isolation structure, a first electrode, and a second electrode. The second type semiconductor layer and the first edge isolation structure are joined with the first type semiconductor layer. The first electrode is electrically coupled with the first type semiconductor layer. At least a part of a vertical projection of an edge of the first type semiconductor layer on the first electrode overlaps with the first electrode. The first edge isolation structure is at least partially located on the part of the first type semiconductor layer. The second electrode is electrically coupled with the second type semiconductor layer.Type: GrantFiled: May 21, 2015Date of Patent: December 22, 2015Assignee: MIKRO MESA TECHNOLOGY CO., LTD.Inventors: Li-Yi Chen, Pei-Yu Chang, Chih-Hui Chan, Chun-Yi Chang, Shih-Chyn Lin, Hsin-Wei Lee
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Patent number: 9200188Abstract: The present invention relates to an ester for refrigerator oils having less remaining by-products in the ester and having high thermal stability, and a method for producing the ester for refrigerator oils. The ester for refrigerator oils is obtained by treating a crude ester product, which is obtained by reacting a neopentyl polyol having a carbon number of 5 to 10 with an aliphatic carboxylic acid having a carbon number of 4 to 12, with one or more kinds of salts selected from the group consisting of sulfite, bisulfite, and pyrosulfite.Type: GrantFiled: April 25, 2013Date of Patent: December 1, 2015Assignee: NOF CORPORATIONInventors: Akio Itoh, Takeshi Kajiki
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Patent number: 9133380Abstract: Mixtures of select neopentyl polyol esters are found to be highly miscible with the refrigerant R-32 over a wide temperature range. Working fluids are provided comprising R-32 and a lubricant containing these select neopentyl polyol esters and having a kinematic viscosity at 40° C. of 32 cSt or higher. Specifically, the lubricant composition of the invention comprises a mixture of alkylcarboxy esters of neopentyl polyols, wherein at least 10 wt % of all neopentyl polyol esters are esters of pentaerythritol oligomers of 4 or more pentaerythritol monomer groups, and wherein a majority of the alkylcarboxylate groups of the alkylcarboxy esters of neopentyl polyols are pentanoyl groups wherein at least 15% of the pentanoyl groups are branched.Type: GrantFiled: February 14, 2013Date of Patent: September 15, 2015Assignee: Chemtura CorporationInventors: Travis Benanti, Edward T. Hessell
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Publication number: 20150072911Abstract: An object of this invention is to provide a lubricating base oil that has a small rate of change in viscosity (a high viscosity index) over a wide temperature range, low viscosity at low temperatures, and good low-temperature fluidity and evaporation resistance, and that allows reduced decomposition thereof. To achieve the object, methylpentanediol diesters obtained by using specific aliphatic monocarboxylic acids are used as a lubricating base oil.Type: ApplicationFiled: May 24, 2013Publication date: March 12, 2015Applicant: NEW JAPAN CHEMICAL CO., LTD.Inventors: Shinya Tsujimoto, Yasuyuki Kawahara, Hiroshi Ishida
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Publication number: 20140364551Abstract: The instant invention relates to the use of waxlike esters as lubricants for halogen containing thermoplastics. The waxlike esters are prepared by A) metathetic oligomerization of esters of polyols and fatty acids, and B) subsequent hydrogenation of the resultant reaction mixture, at least some of the fatty acid units present in the polyol esters being singly or multiply unsaturated.Type: ApplicationFiled: June 30, 2012Publication date: December 11, 2014Applicant: Elevance Renewable Sciences, Inc.Inventors: Gerd Hohner, Timo Herrlich, Beate Treffler, Rainer Fell
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Patent number: 8889607Abstract: A lubricating oil base oil includes, as a major component, a diester represented by the following formula (1), and a lubricating oil composition including the lubricating oil base oil. In the formula, R1 and R2 each independently represent a 1-ethylpentyl group, an n-heptyl group, or a n-hexyl group. When the diester in which both of R1 and R2 each represent an n-heptyl group or an n-hexyl group is defined as A, the diester in which one of R1 and R2 represents a 1-ethylpentyl group is B, and the diester in which both of R1 and R2 each represent a 1-ethylpentyl group is defined as C, the molar ratio of the diesters falls within a range of A:B:C=25 to 65:30 to 50:3 to 25. The lubricating oil base oil is suitable for a fluid dynamic pressure bearing, an oil-impregnated porous bearing, or a dynamic pressure-type oil-impregnated porous bearing.Type: GrantFiled: March 31, 2011Date of Patent: November 18, 2014Assignee: Nippon Steel & Sumikin Chemical Co., Ltd.Inventors: Tadashi Kuratomi, Katsumi Nagano
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Patent number: 8889608Abstract: Provided are a lubricating oil base oil having characteristics of low volatility and excellent low-temperature fluidity and capable of providing long-lasting lubrication property in a wide temperature range from low temperature to high temperature, and a lubricating oil composition using the same. The lubricating oil base oil includes a diester obtained through a reaction between a diol component formed of 1,12-dodecanediol and a carboxylic acid component formed of 2-methylpentanoic acid or 2-methylpentanoic acid and 2-ethylhexanoic acid. The diester is represented by R2COOR1OOCR3, where R1 represents an alkylene derived from the diol component and R2 and R3 each represent an alkyl derived from the carboxylic acid component, and includes 45 to 100 mol % of a diester in which both of R2 and R3 represent C5 alkyls.Type: GrantFiled: March 31, 2011Date of Patent: November 18, 2014Assignee: Nippon Steel & Sumikin Chemical Co., Ltd.Inventors: Tadashi Kuratomi, Katsumi Nagano
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FLUID DYNAMIC PRESSURE BEARING OIL, FLUID DYNAMIC PRESSURE BEARING USING THE SAME, AND SPINDLE MOTOR
Publication number: 20140314351Abstract: It is provided a long life spindle motor that is excellent in startup characteristic in low-temperature environments such as 0° C., and that startup problems due to the evaporation or deterioration of lubricating oil can be avoided in high-temperature environments. The spindle motor includes a fluid dynamic bearing filled with a lubricating oil, containing a methyl pentanediol diester obtained by esterifying 3-methyl-1,5-pentanediol with n-decanoic acid and n-undecanoic acid at a molar ratio ranging from 90:10 to 20:80, and having a water content of not more than 1000 ppm.Type: ApplicationFiled: March 28, 2014Publication date: October 23, 2014Inventors: Hideo FUJIURA, Jun HATCHO -
Patent number: 8865015Abstract: A poly(neopentylpolyol) ester composition is produced by reacting a neopentylpolyol having the formula: wherein each R is independently selected from the group consisting of CH3, C2H5 and CH2OH and n is a number from 1 to 4, with at least one monocarboxylic acid having 2 to 15 carbon atoms in the presence of an acid catalyst and at an initial mole ratio of carboxyl groups to hydroxyl groups of greater than 0.5:1 to 0.95:1 to form a partially esterified poly(neopentylpolyol) composition. Then the partially esterified poly(neopentylpolyol) composition is reacted with additional monocarboxylic acid having 2 to 15 carbon atoms to form a final poly(neopentylpolyol) ester composition.Type: GrantFiled: October 9, 2012Date of Patent: October 21, 2014Assignee: Chemtura CorporationInventors: Dale Carr, Jeffrey Hutter, Richard Kelley, Edward T. Hessell, Roberto Urrego
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Patent number: 8859471Abstract: The present invention relates to a lubricating composition containing (a) an ester-containing viscosity index improver; and (b) a polyoxyalkylene polyol. The invention further provides a method for lubricating a mechanical device with the lubricating composition.Type: GrantFiled: January 24, 2008Date of Patent: October 14, 2014Assignee: The Lubrizol CorporationInventors: James H. Bush, James N. Vinci, David Price
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Patent number: 8852449Abstract: Lubricant compositions comprising certain mixtures of esters of pentaerythritol, di-pentaerythritol, tri-pentaerythritol and higher pentaerythritol oligomers are ideally suited for use with CO2 as refrigerant in heat transfer devices provided that at least 30% by weight of the esters are esters of pentaerythritol oligomers containing 4 or more pentaerythritol monomer units and wherein a majority of the alkylcarboxylate groups are straight chain C3-6 alkanoyl groups, such as n-pentanoyl. Said mixture of alkylcarboxylate esters are shown to not only have higher than expected viscosity and exceptional CO2 miscibility, but also possess excellent lubricity, film building properties and load bearing properties even as part of a lubricant/CO2 solution.Type: GrantFiled: April 6, 2011Date of Patent: October 7, 2014Assignee: Chemtura CorporationInventors: Dale Carr, Jeffrey Hutter, Richard Kelley, Robert Urrego, Edward T. Hessell
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Publication number: 20140296114Abstract: There is provided a lubricating oil composition for a hydrodynamic bearing including: 95 to 99 wt % of an ester-based base oil; and 1.0 to 5.0 wt % of mixed oil containing at least two kinds of ester-based oils different from the ester-based base oil. According to the present invention, a hard disk drive (HDD) motor is manufactured using the lubricating oil composition for a hydrodynamic bearing having a low viscosity, a small evaporation loss, and improved oxidation stability at a room temperature, whereby the impact resistance and low-temperature operation stability of the hydrodynamic bearing motor may be improved.Type: ApplicationFiled: July 17, 2013Publication date: October 2, 2014Inventors: Ha Yong JUNG, Hyung Kyu Kim
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Publication number: 20140228263Abstract: Provided is a turbine oil formulation comprised of a base oil selected from the group consisting of Group II, III and IV base oils and mixtures thereof, and an ester component comprised of at least one diester or triester species having ester links on adjacent carbons. The formulation exhibits less than 6 mg of sludge/100 ml of turbine oil, and is imminently suitable for use as a turbine oil.Type: ApplicationFiled: April 18, 2014Publication date: August 14, 2014Applicant: CHEVRON U.S.A. INC.Inventors: Mark Edward Okazaki, Nicole A. Ketterer
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Publication number: 20140228267Abstract: The use of certain polyol ester (POE) based fluids has been found to be surprisingly effective in, e.g., automotive automatic transmissions, such as, for example, racing automotive automatic transmissions. The use of select POE based fluids has been found to lower operating temperatures, improve torque convertor engagement and torque convertor lock-up due to improved efficiency, performance and friction properties, allowing improved efficiency in high stress applications.Type: ApplicationFiled: February 4, 2014Publication date: August 14, 2014Applicant: Chemtura CorporationInventors: Salvatore Rea, David Cooper, Robert Vinson
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Publication number: 20140194331Abstract: A biohydraulic fluid which has high performance attributes and which is environmentally acceptable includes trimethylolpropane (TMP) esterified to monounsaturated fatty acids of unsaturated vegetable oils or vegetable oil blends. The process for making the TMP esters can be accomplished in a manner similar to biodiesel production wherein methyl oleates obtained from reacting methanol with the vegetable oils or vegetable oil blends are reacted with TMP. Production of the TMP esters can be achieved without the use of catalysts.Type: ApplicationFiled: January 10, 2014Publication date: July 10, 2014Applicant: Washington State UniversityInventor: Thomas Q. Chastek
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Patent number: 8759266Abstract: A lubricant composition for improving electrical properties in lubricant systems to reduce the formation of sludge and varnish is disclosed. The lubricant composition comprises a base oil and an effective amount of antistatic additive to provide the composition with an electrical conductivity of at least about 50 pS/m at 25° C. and a dielectric strength of at least 300 V/mil.Type: GrantFiled: March 20, 2007Date of Patent: June 24, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Andrea B. Wardlow, Marc-Andre Poirier
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Publication number: 20140142012Abstract: A grease composition for EV/HEV driving motor bearing, containing a diurea thickener of the following formula (A): wherein R1, R2 and R3 are defined, with the ratio of the number of moles of the straight-chain or branched alkyl group having 16 to 20 carbon atoms to the total number of moles of the cyclohexyl group and the straight-chain or branched alkyl group having 16 to 20 carbon atoms, expressed as [((the number of alkyl group)/(the number of cyclohexyl group+the number of alkyl group))×100] being 60 to 80%, and a base oil which has a kinematic viscosity at 40° C. of 15 to 50 mm2/s and includes a trimethylolpropane ester oil in an amount of 80 mass % or more based on the total base oil mass. The grease composition can exhibit a long bearing lubrication life at high temperature and high speed, and satisfactory low-temperature flowability.Type: ApplicationFiled: July 27, 2012Publication date: May 22, 2014Applicants: KYODO YUSHI CO., LTD., NSK LTD.Inventors: Hironori Mizuki, Takeshi Maejima, Kenichi Iso, Kazunori Nakagawa, Yutaka Imai, Ryo Aida
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Publication number: 20140135241Abstract: The present invention is able to provide a lubricating oil composition for compression refrigerating machine having excellent thermal/chemical stability even when used for a compression refrigerating machine using a saturated fluorinated hydrocarbon refrigerant having a low carbon number and a low global warming potential, by using a refrigerant containing a saturated fluorinated hydrocarbon having from 1 to 3 carbon atoms, which uses, as a base oil, an oxygen-containing organic compound composed of at least one member selected from a polyoxyalkylene glycol, a polyvinyl ether, a copolymer of a poly(oxy)alkylene glycol and a polyvinyl ether, a copolymer of a poly(oxy)alkylene glycol monoether and a polyvinyl ether, and a polyol ester, each having a hydroxyl value of not more than 15 mgKOH/g.Type: ApplicationFiled: June 28, 2012Publication date: May 15, 2014Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Tomoya Matsumoto
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Patent number: 8703677Abstract: Provided herein are lubricating oil compositions for high performance engines comprising a Group III base oil and a combination of ester base stocks, wherein the combination comprises (i) an ester base stock having a kinematic viscosity at 100° C. of about 2-10 cSt, (ii) an ester base stock having a kinematic viscosity at 100° C. of about 10 to 50 cSt, and (iii) an ester base stock having a kinematic viscosity at 100° C. of greater than about 100 cSt. The lubricating oil composition can further comprise at least one additive. Methods of making and using the lubricating oil compositions are also described.Type: GrantFiled: December 21, 2007Date of Patent: April 22, 2014Assignees: Chevron Japan Ltd, Chevron Oronite Company LLCInventors: Alexander B. Boffa, Satoshi Hirano, Mark Louis Sztenderowicz, Kenji Takeoka
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Patent number: 8633143Abstract: Provided herein are compositions comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.Type: GrantFiled: January 30, 2013Date of Patent: January 21, 2014Assignee: Biosynthetic Technologies, LLCInventors: Travis Thompson, Jakob Bredsguard, Jeremy Forest
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Patent number: 8609596Abstract: To provide a gear oil composition containing a base oil, and compounded therein, (A) an ashless dithiocarbamate compound and (B) an ester of pentaerythritol and a C12 to C20 branched fatty acid, the ester having a hydroxyl value of 20 to 100 mg KOH/g. The gear oil composition has a high transmission efficiency and shows both of resistance to sludge formation and extreme pressure property.Type: GrantFiled: March 19, 2008Date of Patent: December 17, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tahei Okada, Shigeo Hara
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Publication number: 20130296209Abstract: The present invention is generally directed to diester-based lubricant compositions comprising one or more isomeric mixtures of diester species. The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor material from which mono-unsaturated free lipid species can be provided or otherwise generated, wherein such mono-unsaturated free lipid species are converted to isomeric diol species en route to the synthesis of diester species for use as/in the diester-based lubricant compositions.Type: ApplicationFiled: July 10, 2013Publication date: November 7, 2013Applicant: Chevron U.S.A. Inc.Inventors: Saleh Ali Elomari, Stephen Joseph Miller, Zhen Zhou
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Patent number: 8507423Abstract: The present invention is generally directed to diester-based lubricant compositions comprising one or more isomeric mixtures of diester species wherein the kinematic viscosity of the composition at temperature of 100 C is at least 3 mm2/s The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor material from which mono-unsaturated free lipid species can be provided or otherwise generated, wherein such mono-unsaturated free lipid species are converted to isomeric diol species en route to the synthesis of diester species for use as/in the diester-based lubricant compositions.Type: GrantFiled: July 19, 2012Date of Patent: August 13, 2013Assignee: Chevron U.S.A. Inc.Inventors: Saleh A. Elomari, Stephen Joseph Miller, Zhen Zhou
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Patent number: 8482420Abstract: A method of monitoring oil in a vehicle having an internal combustion engine is provided. The method includes measuring a sump temperature of the engine and measuring a power output of the engine. Oil consumption is calculated as a function of the measured sump temperature and the measured power output. Remaining oil life is calculated as a function of the calculated consumption. The method may include alerting a receiver of the calculated remaining oil life.Type: GrantFiled: August 17, 2010Date of Patent: July 9, 2013Assignee: GM Global Technology Operations LLCInventors: Daniel H. Blossfeld, Matthew J. Snider
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Patent number: 8481465Abstract: The present invention is generally directed to diester-based lubricant compositions comprising one or more isomeric mixtures of diester species. The present invention is also directed to methods of making these and other similar lubricant compositions. In some embodiments, the methods for making such diester-based lubricants utilize a biomass precursor material from which mono-unsaturated free lipid species can be provided or otherwise generated, wherein such mono-unsaturated free lipid species are converted to isomeric diol species en route to the synthesis of diester species for use as/in the diester-based lubricant compositions.Type: GrantFiled: July 19, 2012Date of Patent: July 9, 2013Assignee: Chevron U.S.A. Inc.Inventors: Saleh A. Elomari, Stephen Joseph Miller, Zhen Zhou