The Chalcogen And The Carbon Of The -c(=o)o- Group Are Bonded To A Single Benzene Ring (e.g., Salicylic Acid Esters, Etc.) Patents (Class 508/502)
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Patent number: 11987892Abstract: Disclosed are metal cleaning formulations and methods of use. A formulation of the present teachings comprises one or more furoate esters such as ethyl 5-methyl-2-furoate and methyl 5-methyl-2-furoate. The formulations further comprise a base oil, which can be, for example, a naphthenic oil, a synthetic oil or a combination thereof. In some embodiments, a formulation can further comprise a metal protection additive and a lubrication additive. A variety of base oils, metal protection additives, and lubrication additives are suitable for use in the present teachings. Formulations of the present teachings are especially useful for the cleaning of metal products such as firearms. The cleaning power of a formulation of the instant teachings can exceed that required for US Military Specifications.Type: GrantFiled: January 18, 2019Date of Patent: May 21, 2024Assignee: NORTH AMERICAN PRODUCTS GROUP, LLCInventors: Michael Fatigati, William Farone, Rocio Rivera, Dawnell Haupt, David Mccreery, Devin Whipple
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Patent number: 9657215Abstract: The invention provides a method, composition, and system for inhibiting the corrosion of metal that is exposed to aqueous acid, where the composition comprises a thietane compound, a thiirane compound, or a combination thereof.Type: GrantFiled: July 29, 2014Date of Patent: May 23, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Gong Chen, Juanita Cassidy, Jim L. Lane
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Patent number: 9023775Abstract: A lubricating oil composition comprising a Group II basestock and a neutral or overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of less than 2.Type: GrantFiled: October 6, 2008Date of Patent: May 5, 2015Assignee: Infineum International LimitedInventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
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Patent number: 8969273Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled engine, the method comprising lubricating the engine with a natural gas engine lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity; and (b) an alkali metal-containing detergent, wherein the natural gas engine lubricating oil composition is substantially free of each of any alkaline earth metal-containing detergents and lithium-containing detergents is disclosed.Type: GrantFiled: February 18, 2009Date of Patent: March 3, 2015Assignee: Chevron Oronite Company LLCInventors: Melanie F. Tobias, Jon F. Von Staden
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Patent number: 8841243Abstract: A natural gas engine lubricating oil composition is disclosed which comprises (a) a major amount of an oil of lubricating viscosity, (b) one or more phosphorus-containing anti-wear additives, (c) one or more ashless dispersants, (d) one or more alkaline earth metal salts of an alkyl-substituted hydroxyaromatic carboxylic acid, and (e) one or more antioxidants, wherein the natural gas engine lubricating oil composition contains no more than about 0.03 weight percent of phosphorus, based on the total weight of the natural gas engine lubricating oil composition, and further wherein the natural gas engine lubricating oil composition is substantially free of any alkali metal-containing detergents.Type: GrantFiled: March 31, 2010Date of Patent: September 23, 2014Assignee: Chevron Oronite Company LLCInventors: Melanie F. Tobias, Jon F. Von Staden
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Patent number: 8796192Abstract: A natural gas engine lubricating oil composition is disclosed which comprises (a) a major amount of an oil of lubricating viscosity, (b) one or more phosphorus-containing anti-wear additives, (c) one or more oil soluble overbased alkaline earth metal-containing detergents; and (d) one or more oil soluble neutral alkali metal-containing detergents, wherein the natural gas engine lubricating oil composition contains no more than about 0.03 weight percent of phosphorus, based on the total weight of the natural gas engine lubricating oil composition.Type: GrantFiled: October 29, 2010Date of Patent: August 5, 2014Assignee: Chevron Oronite Company LLCInventors: Melanie F. Tobias, Jon F. Von Staden
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Patent number: 8664170Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.Type: GrantFiled: February 15, 2013Date of Patent: March 4, 2014Assignee: Chevron Oronite Company LLCInventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
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Publication number: 20130172222Abstract: The invention provides a lubricating composition containing an aromatic compound and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in an internal combustion engine. The invention further relates to the use of the aromatic compound as an antiwear agent.Type: ApplicationFiled: December 17, 2010Publication date: July 4, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: Matthew D. Gieselman, Seth L. Crawley, David J. Moreton, Paul R. Stevenson, Jeffry G. Dietz
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Publication number: 20130157914Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a compound obtained/obtainable by a process comprising reacting a glycolic acid, a 2-halo-acetic acid, or a lactic acid, or an alkali or alkaline metal salts thereof, (typically glycolic acid or a 2-halo-acetic acid) with at least one member selected from the group consisting of an amine, an alcohol, and an aminoalcohol. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: February 14, 2013Publication date: June 20, 2013Applicant: THE LUBRIZOL CORPORATIONInventor: The Lubrizol Corporation
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Patent number: 8404627Abstract: A detergent including one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, in which: (i) the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates is or includes one or more C10 to C40 hydrocarb-1-yl substituted hydroxybenzoates; or, (ii) greater than 50 mole % of the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, based on the total number of moles of said C10 to C40 hydrocarbyl substituted hydroxybenzoates, is or includes one or more C10 to C40 hydrocarb-2-yl substituted hydroxybenzoates.Type: GrantFiled: September 10, 2009Date of Patent: March 26, 2013Assignee: Infineum International LimitedInventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
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Patent number: 8399392Abstract: A method of reducing asphaltene precipitation or ‘black paint’ in an engine is disclosed. The method includes the step of lubricating the engine with a lubricating oil composition comprising: an oil of lubricating viscosity in a major amount; and, a salicylate detergent system in a minor amount comprising one or more neutral or overbased alkaline earth metal C22 hydrocarbyl substituted salicylates.Type: GrantFiled: September 10, 2009Date of Patent: March 19, 2013Assignee: Infineum International LimitedInventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
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Patent number: 8399388Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.Type: GrantFiled: July 1, 2009Date of Patent: March 19, 2013Assignee: Chevron Oronite Company LLCInventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
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Patent number: 8377859Abstract: The addition of alkyl salicylic acids and esters represented by Formula I where R1?H or C12 to C22 linear alkyl group; R2?H or linear C12 to C22 carbonyl group; and R3=linear C12 to C22 alkyl group reduces the pour point of a hydrocarbon base oil. Thus, both a method for reducing the pour point of hydrocarbon oils and lubricating composition containing pour point reducing salicylates are provided. The hydrocarbon base oil in such method and composition preferably is a Group III base oil.Type: GrantFiled: July 22, 2008Date of Patent: February 19, 2013Assignee: Exxonmobil Research and Engineering CompanyInventors: Marc-Andre Poirier, Jacob J. Habeeb, Chengrong X. Wang
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Patent number: 8377856Abstract: A method for maintaining a total base number (TBN) above about 3 mg KOH/g for a lubricant for a diesel engine for greater than about 184 days. The method includes supplying as the lubricant, a lubricant composition comprising a sulfonate detergent having a TBN ranging from about 20 to about 100 and a phenate detergent having a TBN ranging from about 200 to about 350 and an antioxidant selected from the group consisting essentially of hindered phenolic derivatives of C3 to C6 acids and C7 to C9 esters of hindered phenolic derivatives of C3 to C6 acids. The phenate detergent is present in an amount that is greater than 15 percent by weight of the total weight of detergents in the lubricant composition and the lubricant composition is substantially devoid of zinc dialkydithiophosphate compounds and has a sulfated ash content of less than 1.0 wt. %.Type: GrantFiled: September 14, 2010Date of Patent: February 19, 2013Assignee: Afton Chemical CorporationInventors: Cathy C. Devlin, David A. Hutchison
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Patent number: 8188020Abstract: The present invention provides overbased detergents as lubricating additives effective for the lubrication of mechanical components in land and marine engines, such as, for example, hydraulic systems, transmissions, two-stroke and four-stroke vehicular engines, and trunk piston and two-stroke crosshead marine engines.Type: GrantFiled: December 22, 2003Date of Patent: May 29, 2012Assignee: Chevron Oronite S.A.Inventors: Jean-Louis Le Coent, Amedee Guellec, Eugene E. Spala
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Patent number: 8178478Abstract: An internal combustion engine crankcase lubricating oil composition is disclosed. The crankcase lubricating oil composition has a TBN no greater than 6 and contains the following additives: (B1) a metal detergent system having a metal ratio no greater than 3, as the sole detergent system; (B2) an organic ashless friction modifier; (B3) an oil-soluble molybdenum friction modifier; and (B4) a metal dihydrocarbyl dithiophosphate.Type: GrantFiled: February 23, 2006Date of Patent: May 15, 2012Assignee: Infineum International LimitedInventors: Brian Lawrence, Christopher Locke
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Publication number: 20120034829Abstract: Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a Group II basestock, and respective minor amounts of an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent other than such a detergent having a basicity index of less than two and a degree of carbonation of 80% or greater and 5 to 500 mass %, based on the mass of the detergent, of an oil-soluble alkyl-substituted phenol other than a hindered phenol. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.Type: ApplicationFiled: April 26, 2010Publication date: February 9, 2012Inventors: Richard Bertram, Peter Dowding, Joseph Peter Hartley, Peter Watts
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Publication number: 20110306429Abstract: The present invention provides a grease composition or a lubricating oil composition which is capable of effectively preventing hydrogen brittleness-caused peeling from occurring on a rolling surface of a rolling bearing, is excellent in durability in a high temperature and speed operation, and can be used for a long time. A grease-packed bearing (1) has an inner ring (2), an outer ring (3), and a plurality of rolling elements (4). A sealing member (6) for sealing a grease composition (7) is provided at openings (8a) and (8b) disposed at both axial ends of the inner ring (2) and the outer ring (3). The grease composition (7) includes a base grease composed of a base oil and a thickener and an additive added to the base grease. The additive contains at least one compound selected from among plant-derived polyphenolic compounds and compounds formed by decomposition thereof.Type: ApplicationFiled: February 24, 2010Publication date: December 15, 2011Applicant: NTE CORPORATIONInventors: Hidenobu Mikami, Yosuke Taguchi
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Patent number: 8076276Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 5.5 or greater, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 2 or less. The ratio of the mass of metal in detergent (A) to the mass of metal in detergent (B) is 10 or less.Type: GrantFiled: May 18, 2009Date of Patent: December 13, 2011Assignee: Infineum International LimitedInventor: Laura Gregory
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Patent number: 8071517Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 4.5 or less, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of greater than 4.5. The ratio of detergent (A) to detergent (B), both expressed as mass of active ingredient, is in the range from 0.5 to 15. The trunk piston marine engine lubricating oil composition has a TBN (using ASTM D2896) of 20 to 60.Type: GrantFiled: May 14, 2009Date of Patent: December 6, 2011Assignee: Infineum International LimitedInventors: James C. Dodd, Jeremy R. Spencer
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Patent number: 8067348Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 5.5 or greater, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index in the range of 2.1 to 5.4. The ratio of the mass of metal in detergent (A) to the mass of metal in detergent (B) is 1 or less. The trunk piston marine engine lubricating oil composition has a TBN (using ASTM D2896) of 20 to 60.Type: GrantFiled: May 18, 2009Date of Patent: November 29, 2011Assignee: Infineum International LimitedInventor: Laura Gregory
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Publication number: 20110275549Abstract: A lubricant composition is disclosed which can largely reduce abrasion, can exhibit a low friction coefficient steadily, and has a high corrosion resistance in the lubrication of an iron-based sliding member. The lubricant composition includes a lubricant base oil, a 3,4,5-trihydroxybenzoic acid ester in an amount of 0.01 to 10 mass % relative to the total amount of the lubricant composition, and a detergent dispersant in an amount of 0.1 to 20 mass % relative to the total amount of the lubricant composition.Type: ApplicationFiled: January 6, 2010Publication date: November 10, 2011Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Tetsuya Nonaka, Yuji Shitara, Takashi Kaimai
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Patent number: 8012918Abstract: An overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of less than 2 and a degree of carbonation of 80% or greater is disclosed. The overbased metal hydrocarbyl-substituted hydroxybenzoate detergent reduces asphaltene precipitation or ‘black paint’ in a marine diesel engine.Type: GrantFiled: April 10, 2008Date of Patent: September 6, 2011Assignee: Infineum International LimitedInventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
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Patent number: 7906469Abstract: Lubricating oil compositions having a sulfated ash content of no more than 1.0 mass %, which contain a major amount of oil of lubricating viscosity, a minor amount of calcium salicylate detergent, an amount of a magnesium-based detergent providing the lubricating oil composition with at least 200 ppm of magnesium, an amount of a sulfur-containing molybdenum compound providing the lubricating oil composition with at least 20 ppm of molybdenum, and at least one nitrogen-containing dispersant providing the lubricating oil composition with at least 0.9 mass % nitrogen, which compositions provide improved top ring wear protection in internal combustion engines.Type: GrantFiled: November 29, 2005Date of Patent: March 15, 2011Assignee: Infineum International LimitedInventors: Stephen Arrowsmith, Matthew D. Irving
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Publication number: 20110003726Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.Type: ApplicationFiled: July 1, 2009Publication date: January 6, 2011Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, JR.
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Patent number: 7807610Abstract: An automotive lubricating oil composition containing: (A) an oil of lubricating viscosity in a major amount; and (B) as an additive component in a minor amount, an oil-soluble or oil-dispersible 4-oxobutanoic acid having the moiety —CO(CH2)COOH bonded to (i) a group OR1 where R1 is hydrocarbyl group having 10 to 30 carbon atoms; or (ii) a group X being an aromatic group substituted with at least one hydrocarbyl group having 10 to 30 carbon atoms; or (iii) a group NR2R3 where one or both of R2 and R3 is hydrocarbyl group having from 10 to 30 carbon atoms and one but not both of R2 and R3 may be a hydrogen atom, or a salt thereof.Type: GrantFiled: November 19, 2007Date of Patent: October 5, 2010Assignee: Infineum International LimitedInventors: Steve Harris, Peter Anthony Tasker
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Publication number: 20100210493Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled engine, the method comprising lubricating the engine with a natural gas engine lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity; and (b) an alkali metal-containing detergent, wherein the natural gas engine lubricating oil composition is substantially free of each of any alkaline earth metal-containing detergents and lithium-containing detergents is disclosed.Type: ApplicationFiled: February 18, 2009Publication date: August 19, 2010Applicant: Chevron Oronite Company LLCInventors: Melanie F. Tobias, Jon F. Von Staden
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Publication number: 20100137172Abstract: A lubricating oil composition according to the present invention is used in an internal combustion engine. The internal combustion engine uses a fuel that contains at least one fat and oil selected from a group consisting of natural fat and oil, hydrotreated natural fat and oil, transesterified natural fat and oil and hydrotreated transesterified natural fat and oil. The lubricating oil composition contains a component (A) that is an alkaline earth metal-based detergent. The component (A) is contained by a content of more than 0.35 mass % and 2 mass % or less of the total amount of the composition in terms of alkaline earth metal.Type: ApplicationFiled: March 24, 2008Publication date: June 3, 2010Applicant: Idemitsu Kosan Co., Ltd.Inventor: Hideki Kamano
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Publication number: 20100099591Abstract: A method of lubricating a two-stroke, diesel crosshead engine comprises lubricating the engine with a cylinder oil and with a system oil, which oils are different from each other, in which the system oil is an SAE 20 or SAE 30 oil, has a total base number of at least 10 mg KOH/g and comprises: (a) a base oil; (b) at least one detergent additive in a total amount of detergent corresponding in performance, as measured by the Hot Filtration Test, to at least 1.5% by weight of the system oil, of a calcium alkyl salicylate detergent soap in which the alkyl group is a C12 to C30 alkyl group; and (c) at least one anti-wear additive. The method further comprising replenishing the system oil in the engine with a top-up system oil, in which the top-up system oil has the same additives as in the system oil previously charged to the engine but has a viscosity which is lower than that of the system oil previously charged to the engine.Type: ApplicationFiled: March 20, 2008Publication date: April 22, 2010Applicant: BP P.L.C.Inventors: Paul Andrew Harrold, John Philip Liddy, Kok-Chye Lim
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Publication number: 20100062958Abstract: A detergent including one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, in which: (i) the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates is or includes one or more C10 to C40 hydrocarb-1-yl substituted hydroxybenzoates; or, (ii) greater than 50 mole % of the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, based on the total number of moles of said C10 to C40 hydrocarbyl substituted hydroxybenzoates, is or includes one or more C10 to C40 hydrocarb-2-yl substituted hydroxybenzoates.Type: ApplicationFiled: September 10, 2009Publication date: March 11, 2010Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
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Publication number: 20100004148Abstract: The present invention relates to a lubricant composition having a sulphur content of from 0.01 to 0.3 wt. %, a phosphorus content of from 0.01 to 0.1 wt. % and a sulphated ash content of from 0.1 to 1.2 wt. %, based on the total weight of the lubricant composition, which comprises a base oil or base oil blend, wherein the lubricant composition has a kinematic viscosity at 100° C. of more than 5.0 mm2/s (cSt), a cold cranking simulated dynamic viscosity at ?15° C. according to ASTM D 5293 of less than 9500 mPas (cP) and a mini rotary viscosity test value of less than 60000 mPas at ?20° C. according to ASTM D 4684, and wherein the base oil or base oil blend comprises a continuous series of iso-paraffins having n, n+1, n+2, n+3 and n+4 carbon atoms. The invention relates further to the use of the lubricant composition, for the reduction of piston ring deposits in an internal combustion engine.Type: ApplicationFiled: November 9, 2007Publication date: January 7, 2010Inventors: David Colbourne, David John Wedlock
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Patent number: 7632900Abstract: A lubricating oil suitable for use in ?-olefin compressors and a high-pressure ethylene polymerization process is disclosed. The oil comprises a base fluid and a hindered C6-C30 alkyl 4-hydroxybenzoate. The hindered C6-C30 alkyl 4-hydroxybenzoate stabilizes the lubricating oil and does not interfere with the high-pressure ?-olefin polymerization.Type: GrantFiled: December 18, 2008Date of Patent: December 15, 2009Assignee: Equistar Chemicals, LPInventors: Stephen M. Imfeld, Robert L. Sherman, Jr., Andrew W. Lake
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Patent number: 7612025Abstract: Low sulfur lubricating oil compositions are provided which are extremely excellent in anti-wear properties for the valve train system of an internal combustion engine and are also excellent in long-drain properties, and thus is suitable for used in an internal combustion engine. The lubricating oil compositions comprises a lubricating base oil, (A) a specific alkali metal or alkaline earth metal salicylate and/or an overbased or basic salt of the salicylate, (B) a phosphorus-containing anti-wear agent, (C) an ashless dispersant, and (D) an ashless anti-oxidant, as the essential components, and contains boron in an amount of 0.01 to 0.15 percent by mass and sulfur in a total amount of 0.3 percent by mass or less, based on the total mass of the composition.Type: GrantFiled: August 3, 2006Date of Patent: November 3, 2009Assignee: Nippon Oil CorporationInventors: Isao Kurihara, Kazuhiro Yagishita, Shouzaburou Konishi
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Publication number: 20090075853Abstract: A slow release liquid additive concentrate for use in an engine oil filter and a method for extending an oil drain interval for an engine. The additive concentrate has therein at least one detergent and at least one antioxidant. The additive concentrate has a tan delta of greater than about 5.Type: ApplicationFiled: September 18, 2007Publication date: March 19, 2009Inventors: Naresh C. Mathur, Charles A. Passut, Carl K. Esche, JR.
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Publication number: 20090029889Abstract: The addition of alkyl salicylic acids and esters represented by Formula I where R1?H or C12 to C22 linear alkyl group; R2?H or linear C12 to C22 carbonyl group; and R3=linear C12 to C22 alkyl group reduces the pour point of a hydrocarbon base oil. Thus, both a method for reducing the pour point of hydrocarbon oils and lubricating composition containing pour point reducing salicylates are provided. The hydrocarbon base oil in such method and composition preferably is a Group III base oil.Type: ApplicationFiled: July 22, 2008Publication date: January 29, 2009Inventors: Marc-Andre Poirier, Jacob J. Habeeb, Chengrong X. Wang
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Publication number: 20080182768Abstract: A diesel engine operating on a fuel containing from about 5 to about 100 wt. % bio-diesel components and being lubricated with a lubricating oil composition including a major amount of oil of lubricating viscosity, and a minor amount of at least one highly grafted, multi-functional olefin copolymer. The olefin copolymer is made by reacting an acylating agent with an olefin copolymer having a number average molecular weight greater than about 1,000 in the present of a free radical initiator to provide an acylated olefin copolymer having a degree of grafting (DOG) of the acylating agent on the olefin copolymer of at least 0.5 wt. %, and reacting the acylated olefin copolymer with an amine to provide the highly grafted, multi-functional olefin copolymer. As used, the highly grafted, multi-functional olefin copolymer is effective to reduce a viscosity increase in the lubricating oil composition for the engine.Type: ApplicationFiled: December 20, 2007Publication date: July 31, 2008Inventors: Cathy C. DEVLIN, Charles A. PASSUT
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Patent number: 7285516Abstract: Lubricating oils containing an additive formulation including at least one sulphonate, saligenin and salixarate detergent provide improved wear performance and decreased sulphur and phosphorus emissions.Type: GrantFiled: November 25, 2002Date of Patent: October 23, 2007Assignee: The Lubrizol CorporationInventors: Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, R. Ian Wilby, James P Roski
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Patent number: 6828285Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: February 14, 2003Date of Patent: December 7, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6815401Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: October 23, 2001Date of Patent: November 9, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Sulfur containing lubricating oil additive system particularly useful for natural gas fueled engines
Publication number: 20040142827Abstract: A lubricating oil comprising a major amount of at least one of Group II, III, and IV base oil and a minor amount of 2-(4-hydroxy-3,5-di-t-butyl benzyl thiol) acetate. A method of making this lubricating oil and a method of lubricating a natural gas engine with this lubricating oil.Type: ApplicationFiled: November 29, 2001Publication date: July 22, 2004Inventors: John D. Palazzotto, Mark R. Logan -
Patent number: 6756348Abstract: This invention is directed to an antioxidant system for use in lubricating oils comprising sulfurized isobutylene and hindered phenols that provides enhanced oxidation resistance and is particularly useful in natural gas fueled engines, the method for making this antioxidant system, lubricating oils comprising the antioxidant system and methods for lubricating engines using lubricating oil comprising this antioxidant system.Type: GrantFiled: November 29, 2001Date of Patent: June 29, 2004Assignee: Chevron Oronite Company LLCInventors: John D. Palazzotto, Mark R. Logan
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Patent number: 6720293Abstract: A low viscosity lubricating oil composition having a CCS viscosity less than 3500 mPa.s at −25° C. and having no more than 0.16 mass % of phosphorus which comprises a dispersant, and a detergent of calcium or magnesium or both; and optionally a zinc dihydrocarbyldithiophosphate, a viscosity modifier, a pour point depressant and an antioxidant. The oil satisfies the Cummins M11 cross-head wear engine test specification in a low phosphorus and low viscosity formulation.Type: GrantFiled: September 24, 2001Date of Patent: April 13, 2004Assignee: Infineum International Ltd.Inventors: Charles H. Bovington, Christopher J. Locke, Terence Kelly
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Publication number: 20040014618Abstract: A cyclic compound comprising m units of formula Ia and n units of formula (Ib) joined together to form a ring, wherein Y is a divalent bridging group which may be the same or different in each unit; R0 is H, a C1-C6 alkyl or a metal or ammonium cation; R5 is H or a C1-C6 alkyl; and j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the proviso that at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3; and with the proviso that at least one of the conditions a) to e) below is satisfied: (a) the cyclic compound comprises at least one formula (Ia) unit in the form of a carboxylate anion, (b) the caclic compound comprises at least one formula (Ia) unit in the form of an alkaline earth metal or alkali metal carboxylate salt, (c) the cyclic compound comprises at least 2 units of formula (Ia) (d) the cyclic coType: ApplicationFiled: August 24, 2002Publication date: January 22, 2004Inventor: Spencer Edwin Taylor
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Publication number: 20030220206Abstract: Lubricant compositions comprises a lubricant base oil and one or more compounds resulting the modification of a succinimide represented by formula (1) or (2) 1Type: ApplicationFiled: April 10, 2003Publication date: November 27, 2003Applicant: Nippon Mitsubishi Oil CorporationInventors: Kenichi Komiya, Naozumi Arimoto, Noboru Ishida, Shinichi Shirahama, Eitaro Morita
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Publication number: 20030139304Abstract: This invention is directed to an antioxidant system for use in lubricating oils comprising sulfurized isobutylene and hindered phenols that provides enhanced oxidation resistance and is particularly useful in natural gas fueled engines, the method for making this antioxidant system, lubricating oils comprising the antioxidant system and methods for lubricating engines using lubricating oil comprising this antioxidant system.Type: ApplicationFiled: November 29, 2001Publication date: July 24, 2003Inventors: John D. Palazzotto, Mark R. Logan
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Patent number: 6583093Abstract: A cyclic compound comprising m units of the formula Ia: and n units of the formula (Ib): joined together to form a ring, wherein Y and Y2 are divalent bridging groups which may be the same or different in each unit; R0 is H or (C1-C6) alkyl or is a metal or ammonium cation; R5 is H or (C1-C60) alkyl or OH group; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the provisos that i) at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3, and ii) in formula Ia at least one OH group is in the meta or para position to the COOR0 group and/or at least one R5 group is OH.Type: GrantFiled: April 1, 2002Date of Patent: June 24, 2003Assignee: BP Oil International LimitedInventors: Spencer Edwin Taylor, Michael John Wilson
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Patent number: 6569819Abstract: Lubricant compositions comprise a lubricant base oil, and (A) a mono substituted amide type bissuccinimide in an amount from 0.5 to 20 percent by mass, (B) zinc dithiophosphate in an amount from 0.05 to 0.3 percent by mass of phosphorus, and (C) a metal-based detergent in an amount form 0.5 to 4.0 percent by mass of sulfated ash, based on the total mass of the composition. Lubricant compositions preferably further comprises (D) a dispersant type viscosity index improver in an amount from 0.1 to 20 percent by mass, based on the total mass of the composition.Type: GrantFiled: September 27, 2001Date of Patent: May 27, 2003Assignee: Nippon Mitsubishi Oil CorporationInventors: Kazuhiro Yagishita, Jinichi Igarashi, Osamu Kurosawa
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Publication number: 20030096714Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals.Type: ApplicationFiled: October 23, 2001Publication date: May 22, 2003Applicant: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6521571Abstract: A lubricant suitable for use in a trunk piston diesel engine characterised by a power output of 200 kW or greater. The trunk piston diesel engine may be for use in marine, power generation or rail traction applications. The lubricant comprises a basestock of lubricating viscosity, an overbased metal detergent, preferably having an ash content of at least 0.85% sulfated ash, and an ashless or metal-free auxiliary additive comprising at least one of: an oil-soluble sulfurized alkylphenol, a phosphorosulfurized or sulfurized hydrocarbon, a sulfide of an oil, a fat or a polyolefin, or an amine phosphate.Type: GrantFiled: September 20, 2001Date of Patent: February 18, 2003Assignee: Infineum International Ltd.Inventors: Terence Garner, Laurent Chambard, Adrian Dunn
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Publication number: 20020142922Abstract: Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: 1Type: ApplicationFiled: January 23, 2002Publication date: October 3, 2002Applicant: Nippon Mitsubishi Oil CorporationInventors: Kazuhiro Yagishita, Jinichi Igarashi, Takeo Koizumi