The Chalcogen And The Carbon Of The -c(=o)o- Group Are Bonded To A Single Benzene Ring (e.g., Salicylic Acid Esters, Etc.) Patents (Class 508/502)
  • Patent number: 11987892
    Abstract: Disclosed are metal cleaning formulations and methods of use. A formulation of the present teachings comprises one or more furoate esters such as ethyl 5-methyl-2-furoate and methyl 5-methyl-2-furoate. The formulations further comprise a base oil, which can be, for example, a naphthenic oil, a synthetic oil or a combination thereof. In some embodiments, a formulation can further comprise a metal protection additive and a lubrication additive. A variety of base oils, metal protection additives, and lubrication additives are suitable for use in the present teachings. Formulations of the present teachings are especially useful for the cleaning of metal products such as firearms. The cleaning power of a formulation of the instant teachings can exceed that required for US Military Specifications.
    Type: Grant
    Filed: January 18, 2019
    Date of Patent: May 21, 2024
    Assignee: NORTH AMERICAN PRODUCTS GROUP, LLC
    Inventors: Michael Fatigati, William Farone, Rocio Rivera, Dawnell Haupt, David Mccreery, Devin Whipple
  • Patent number: 9657215
    Abstract: The invention provides a method, composition, and system for inhibiting the corrosion of metal that is exposed to aqueous acid, where the composition comprises a thietane compound, a thiirane compound, or a combination thereof.
    Type: Grant
    Filed: July 29, 2014
    Date of Patent: May 23, 2017
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Gong Chen, Juanita Cassidy, Jim L. Lane
  • Patent number: 9023775
    Abstract: A lubricating oil composition comprising a Group II basestock and a neutral or overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of less than 2.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: May 5, 2015
    Assignee: Infineum International Limited
    Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
  • Patent number: 8969273
    Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled engine, the method comprising lubricating the engine with a natural gas engine lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity; and (b) an alkali metal-containing detergent, wherein the natural gas engine lubricating oil composition is substantially free of each of any alkaline earth metal-containing detergents and lithium-containing detergents is disclosed.
    Type: Grant
    Filed: February 18, 2009
    Date of Patent: March 3, 2015
    Assignee: Chevron Oronite Company LLC
    Inventors: Melanie F. Tobias, Jon F. Von Staden
  • Patent number: 8841243
    Abstract: A natural gas engine lubricating oil composition is disclosed which comprises (a) a major amount of an oil of lubricating viscosity, (b) one or more phosphorus-containing anti-wear additives, (c) one or more ashless dispersants, (d) one or more alkaline earth metal salts of an alkyl-substituted hydroxyaromatic carboxylic acid, and (e) one or more antioxidants, wherein the natural gas engine lubricating oil composition contains no more than about 0.03 weight percent of phosphorus, based on the total weight of the natural gas engine lubricating oil composition, and further wherein the natural gas engine lubricating oil composition is substantially free of any alkali metal-containing detergents.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: September 23, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Melanie F. Tobias, Jon F. Von Staden
  • Patent number: 8796192
    Abstract: A natural gas engine lubricating oil composition is disclosed which comprises (a) a major amount of an oil of lubricating viscosity, (b) one or more phosphorus-containing anti-wear additives, (c) one or more oil soluble overbased alkaline earth metal-containing detergents; and (d) one or more oil soluble neutral alkali metal-containing detergents, wherein the natural gas engine lubricating oil composition contains no more than about 0.03 weight percent of phosphorus, based on the total weight of the natural gas engine lubricating oil composition.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: August 5, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Melanie F. Tobias, Jon F. Von Staden
  • Patent number: 8664170
    Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: March 4, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
  • Publication number: 20130172222
    Abstract: The invention provides a lubricating composition containing an aromatic compound and an oil of lubricating viscosity. The invention further relates to the use of the lubricating composition in an internal combustion engine. The invention further relates to the use of the aromatic compound as an antiwear agent.
    Type: Application
    Filed: December 17, 2010
    Publication date: July 4, 2013
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Matthew D. Gieselman, Seth L. Crawley, David J. Moreton, Paul R. Stevenson, Jeffry G. Dietz
  • Publication number: 20130157914
    Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a compound obtained/obtainable by a process comprising reacting a glycolic acid, a 2-halo-acetic acid, or a lactic acid, or an alkali or alkaline metal salts thereof, (typically glycolic acid or a 2-halo-acetic acid) with at least one member selected from the group consisting of an amine, an alcohol, and an aminoalcohol. The invention further relates to the use of the lubricating composition in an internal combustion engine.
    Type: Application
    Filed: February 14, 2013
    Publication date: June 20, 2013
    Applicant: THE LUBRIZOL CORPORATION
    Inventor: The Lubrizol Corporation
  • Patent number: 8404627
    Abstract: A detergent including one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, in which: (i) the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates is or includes one or more C10 to C40 hydrocarb-1-yl substituted hydroxybenzoates; or, (ii) greater than 50 mole % of the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, based on the total number of moles of said C10 to C40 hydrocarbyl substituted hydroxybenzoates, is or includes one or more C10 to C40 hydrocarb-2-yl substituted hydroxybenzoates.
    Type: Grant
    Filed: September 10, 2009
    Date of Patent: March 26, 2013
    Assignee: Infineum International Limited
    Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
  • Patent number: 8399392
    Abstract: A method of reducing asphaltene precipitation or ‘black paint’ in an engine is disclosed. The method includes the step of lubricating the engine with a lubricating oil composition comprising: an oil of lubricating viscosity in a major amount; and, a salicylate detergent system in a minor amount comprising one or more neutral or overbased alkaline earth metal C22 hydrocarbyl substituted salicylates.
    Type: Grant
    Filed: September 10, 2009
    Date of Patent: March 19, 2013
    Assignee: Infineum International Limited
    Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
  • Patent number: 8399388
    Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: March 19, 2013
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
  • Patent number: 8377859
    Abstract: The addition of alkyl salicylic acids and esters represented by Formula I where R1?H or C12 to C22 linear alkyl group; R2?H or linear C12 to C22 carbonyl group; and R3=linear C12 to C22 alkyl group reduces the pour point of a hydrocarbon base oil. Thus, both a method for reducing the pour point of hydrocarbon oils and lubricating composition containing pour point reducing salicylates are provided. The hydrocarbon base oil in such method and composition preferably is a Group III base oil.
    Type: Grant
    Filed: July 22, 2008
    Date of Patent: February 19, 2013
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Marc-Andre Poirier, Jacob J. Habeeb, Chengrong X. Wang
  • Patent number: 8377856
    Abstract: A method for maintaining a total base number (TBN) above about 3 mg KOH/g for a lubricant for a diesel engine for greater than about 184 days. The method includes supplying as the lubricant, a lubricant composition comprising a sulfonate detergent having a TBN ranging from about 20 to about 100 and a phenate detergent having a TBN ranging from about 200 to about 350 and an antioxidant selected from the group consisting essentially of hindered phenolic derivatives of C3 to C6 acids and C7 to C9 esters of hindered phenolic derivatives of C3 to C6 acids. The phenate detergent is present in an amount that is greater than 15 percent by weight of the total weight of detergents in the lubricant composition and the lubricant composition is substantially devoid of zinc dialkydithiophosphate compounds and has a sulfated ash content of less than 1.0 wt. %.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: February 19, 2013
    Assignee: Afton Chemical Corporation
    Inventors: Cathy C. Devlin, David A. Hutchison
  • Patent number: 8188020
    Abstract: The present invention provides overbased detergents as lubricating additives effective for the lubrication of mechanical components in land and marine engines, such as, for example, hydraulic systems, transmissions, two-stroke and four-stroke vehicular engines, and trunk piston and two-stroke crosshead marine engines.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: May 29, 2012
    Assignee: Chevron Oronite S.A.
    Inventors: Jean-Louis Le Coent, Amedee Guellec, Eugene E. Spala
  • Patent number: 8178478
    Abstract: An internal combustion engine crankcase lubricating oil composition is disclosed. The crankcase lubricating oil composition has a TBN no greater than 6 and contains the following additives: (B1) a metal detergent system having a metal ratio no greater than 3, as the sole detergent system; (B2) an organic ashless friction modifier; (B3) an oil-soluble molybdenum friction modifier; and (B4) a metal dihydrocarbyl dithiophosphate.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: May 15, 2012
    Assignee: Infineum International Limited
    Inventors: Brian Lawrence, Christopher Locke
  • Publication number: 20120034829
    Abstract: Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a Group II basestock, and respective minor amounts of an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent other than such a detergent having a basicity index of less than two and a degree of carbonation of 80% or greater and 5 to 500 mass %, based on the mass of the detergent, of an oil-soluble alkyl-substituted phenol other than a hindered phenol. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.
    Type: Application
    Filed: April 26, 2010
    Publication date: February 9, 2012
    Inventors: Richard Bertram, Peter Dowding, Joseph Peter Hartley, Peter Watts
  • Publication number: 20110306429
    Abstract: The present invention provides a grease composition or a lubricating oil composition which is capable of effectively preventing hydrogen brittleness-caused peeling from occurring on a rolling surface of a rolling bearing, is excellent in durability in a high temperature and speed operation, and can be used for a long time. A grease-packed bearing (1) has an inner ring (2), an outer ring (3), and a plurality of rolling elements (4). A sealing member (6) for sealing a grease composition (7) is provided at openings (8a) and (8b) disposed at both axial ends of the inner ring (2) and the outer ring (3). The grease composition (7) includes a base grease composed of a base oil and a thickener and an additive added to the base grease. The additive contains at least one compound selected from among plant-derived polyphenolic compounds and compounds formed by decomposition thereof.
    Type: Application
    Filed: February 24, 2010
    Publication date: December 15, 2011
    Applicant: NTE CORPORATION
    Inventors: Hidenobu Mikami, Yosuke Taguchi
  • Patent number: 8076276
    Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 5.5 or greater, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 2 or less. The ratio of the mass of metal in detergent (A) to the mass of metal in detergent (B) is 10 or less.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: December 13, 2011
    Assignee: Infineum International Limited
    Inventor: Laura Gregory
  • Patent number: 8071517
    Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 4.5 or less, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of greater than 4.5. The ratio of detergent (A) to detergent (B), both expressed as mass of active ingredient, is in the range from 0.5 to 15. The trunk piston marine engine lubricating oil composition has a TBN (using ASTM D2896) of 20 to 60.
    Type: Grant
    Filed: May 14, 2009
    Date of Patent: December 6, 2011
    Assignee: Infineum International Limited
    Inventors: James C. Dodd, Jeremy R. Spencer
  • Patent number: 8067348
    Abstract: A trunk piston marine engine lubricating oil composition for a medium-speed compression-ignited marine engine comprises, in a major amount, an oil of lubricating viscosity containing 50 mass % or more of a Group II basestock, and, in respective minor amounts, (A) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of 5.5 or greater, and (B) an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index in the range of 2.1 to 5.4. The ratio of the mass of metal in detergent (A) to the mass of metal in detergent (B) is 1 or less. The trunk piston marine engine lubricating oil composition has a TBN (using ASTM D2896) of 20 to 60.
    Type: Grant
    Filed: May 18, 2009
    Date of Patent: November 29, 2011
    Assignee: Infineum International Limited
    Inventor: Laura Gregory
  • Publication number: 20110275549
    Abstract: A lubricant composition is disclosed which can largely reduce abrasion, can exhibit a low friction coefficient steadily, and has a high corrosion resistance in the lubrication of an iron-based sliding member. The lubricant composition includes a lubricant base oil, a 3,4,5-trihydroxybenzoic acid ester in an amount of 0.01 to 10 mass % relative to the total amount of the lubricant composition, and a detergent dispersant in an amount of 0.1 to 20 mass % relative to the total amount of the lubricant composition.
    Type: Application
    Filed: January 6, 2010
    Publication date: November 10, 2011
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Tetsuya Nonaka, Yuji Shitara, Takashi Kaimai
  • Patent number: 8012918
    Abstract: An overbased metal hydrocarbyl-substituted hydroxybenzoate detergent having a basicity index of less than 2 and a degree of carbonation of 80% or greater is disclosed. The overbased metal hydrocarbyl-substituted hydroxybenzoate detergent reduces asphaltene precipitation or ‘black paint’ in a marine diesel engine.
    Type: Grant
    Filed: April 10, 2008
    Date of Patent: September 6, 2011
    Assignee: Infineum International Limited
    Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
  • Patent number: 7906469
    Abstract: Lubricating oil compositions having a sulfated ash content of no more than 1.0 mass %, which contain a major amount of oil of lubricating viscosity, a minor amount of calcium salicylate detergent, an amount of a magnesium-based detergent providing the lubricating oil composition with at least 200 ppm of magnesium, an amount of a sulfur-containing molybdenum compound providing the lubricating oil composition with at least 20 ppm of molybdenum, and at least one nitrogen-containing dispersant providing the lubricating oil composition with at least 0.9 mass % nitrogen, which compositions provide improved top ring wear protection in internal combustion engines.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: March 15, 2011
    Assignee: Infineum International Limited
    Inventors: Stephen Arrowsmith, Matthew D. Irving
  • Publication number: 20110003726
    Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.
    Type: Application
    Filed: July 1, 2009
    Publication date: January 6, 2011
    Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, JR.
  • Patent number: 7807610
    Abstract: An automotive lubricating oil composition containing: (A) an oil of lubricating viscosity in a major amount; and (B) as an additive component in a minor amount, an oil-soluble or oil-dispersible 4-oxobutanoic acid having the moiety —CO(CH2)COOH bonded to (i) a group OR1 where R1 is hydrocarbyl group having 10 to 30 carbon atoms; or (ii) a group X being an aromatic group substituted with at least one hydrocarbyl group having 10 to 30 carbon atoms; or (iii) a group NR2R3 where one or both of R2 and R3 is hydrocarbyl group having from 10 to 30 carbon atoms and one but not both of R2 and R3 may be a hydrogen atom, or a salt thereof.
    Type: Grant
    Filed: November 19, 2007
    Date of Patent: October 5, 2010
    Assignee: Infineum International Limited
    Inventors: Steve Harris, Peter Anthony Tasker
  • Publication number: 20100210493
    Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled engine, the method comprising lubricating the engine with a natural gas engine lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity; and (b) an alkali metal-containing detergent, wherein the natural gas engine lubricating oil composition is substantially free of each of any alkaline earth metal-containing detergents and lithium-containing detergents is disclosed.
    Type: Application
    Filed: February 18, 2009
    Publication date: August 19, 2010
    Applicant: Chevron Oronite Company LLC
    Inventors: Melanie F. Tobias, Jon F. Von Staden
  • Publication number: 20100137172
    Abstract: A lubricating oil composition according to the present invention is used in an internal combustion engine. The internal combustion engine uses a fuel that contains at least one fat and oil selected from a group consisting of natural fat and oil, hydrotreated natural fat and oil, transesterified natural fat and oil and hydrotreated transesterified natural fat and oil. The lubricating oil composition contains a component (A) that is an alkaline earth metal-based detergent. The component (A) is contained by a content of more than 0.35 mass % and 2 mass % or less of the total amount of the composition in terms of alkaline earth metal.
    Type: Application
    Filed: March 24, 2008
    Publication date: June 3, 2010
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventor: Hideki Kamano
  • Publication number: 20100099591
    Abstract: A method of lubricating a two-stroke, diesel crosshead engine comprises lubricating the engine with a cylinder oil and with a system oil, which oils are different from each other, in which the system oil is an SAE 20 or SAE 30 oil, has a total base number of at least 10 mg KOH/g and comprises: (a) a base oil; (b) at least one detergent additive in a total amount of detergent corresponding in performance, as measured by the Hot Filtration Test, to at least 1.5% by weight of the system oil, of a calcium alkyl salicylate detergent soap in which the alkyl group is a C12 to C30 alkyl group; and (c) at least one anti-wear additive. The method further comprising replenishing the system oil in the engine with a top-up system oil, in which the top-up system oil has the same additives as in the system oil previously charged to the engine but has a viscosity which is lower than that of the system oil previously charged to the engine.
    Type: Application
    Filed: March 20, 2008
    Publication date: April 22, 2010
    Applicant: BP P.L.C.
    Inventors: Paul Andrew Harrold, John Philip Liddy, Kok-Chye Lim
  • Publication number: 20100062958
    Abstract: A detergent including one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, in which: (i) the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates is or includes one or more C10 to C40 hydrocarb-1-yl substituted hydroxybenzoates; or, (ii) greater than 50 mole % of the one or more neutral or overbased alkaline earth metal C10 to C40 hydrocarbyl substituted hydroxybenzoates, based on the total number of moles of said C10 to C40 hydrocarbyl substituted hydroxybenzoates, is or includes one or more C10 to C40 hydrocarb-2-yl substituted hydroxybenzoates.
    Type: Application
    Filed: September 10, 2009
    Publication date: March 11, 2010
    Inventors: Richard D. Bertram, Peter J. Dowding, Peter D. Watts
  • Publication number: 20100004148
    Abstract: The present invention relates to a lubricant composition having a sulphur content of from 0.01 to 0.3 wt. %, a phosphorus content of from 0.01 to 0.1 wt. % and a sulphated ash content of from 0.1 to 1.2 wt. %, based on the total weight of the lubricant composition, which comprises a base oil or base oil blend, wherein the lubricant composition has a kinematic viscosity at 100° C. of more than 5.0 mm2/s (cSt), a cold cranking simulated dynamic viscosity at ?15° C. according to ASTM D 5293 of less than 9500 mPas (cP) and a mini rotary viscosity test value of less than 60000 mPas at ?20° C. according to ASTM D 4684, and wherein the base oil or base oil blend comprises a continuous series of iso-paraffins having n, n+1, n+2, n+3 and n+4 carbon atoms. The invention relates further to the use of the lubricant composition, for the reduction of piston ring deposits in an internal combustion engine.
    Type: Application
    Filed: November 9, 2007
    Publication date: January 7, 2010
    Inventors: David Colbourne, David John Wedlock
  • Patent number: 7632900
    Abstract: A lubricating oil suitable for use in ?-olefin compressors and a high-pressure ethylene polymerization process is disclosed. The oil comprises a base fluid and a hindered C6-C30 alkyl 4-hydroxybenzoate. The hindered C6-C30 alkyl 4-hydroxybenzoate stabilizes the lubricating oil and does not interfere with the high-pressure ?-olefin polymerization.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: December 15, 2009
    Assignee: Equistar Chemicals, LP
    Inventors: Stephen M. Imfeld, Robert L. Sherman, Jr., Andrew W. Lake
  • Patent number: 7612025
    Abstract: Low sulfur lubricating oil compositions are provided which are extremely excellent in anti-wear properties for the valve train system of an internal combustion engine and are also excellent in long-drain properties, and thus is suitable for used in an internal combustion engine. The lubricating oil compositions comprises a lubricating base oil, (A) a specific alkali metal or alkaline earth metal salicylate and/or an overbased or basic salt of the salicylate, (B) a phosphorus-containing anti-wear agent, (C) an ashless dispersant, and (D) an ashless anti-oxidant, as the essential components, and contains boron in an amount of 0.01 to 0.15 percent by mass and sulfur in a total amount of 0.3 percent by mass or less, based on the total mass of the composition.
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: November 3, 2009
    Assignee: Nippon Oil Corporation
    Inventors: Isao Kurihara, Kazuhiro Yagishita, Shouzaburou Konishi
  • Publication number: 20090075853
    Abstract: A slow release liquid additive concentrate for use in an engine oil filter and a method for extending an oil drain interval for an engine. The additive concentrate has therein at least one detergent and at least one antioxidant. The additive concentrate has a tan delta of greater than about 5.
    Type: Application
    Filed: September 18, 2007
    Publication date: March 19, 2009
    Inventors: Naresh C. Mathur, Charles A. Passut, Carl K. Esche, JR.
  • Publication number: 20090029889
    Abstract: The addition of alkyl salicylic acids and esters represented by Formula I where R1?H or C12 to C22 linear alkyl group; R2?H or linear C12 to C22 carbonyl group; and R3=linear C12 to C22 alkyl group reduces the pour point of a hydrocarbon base oil. Thus, both a method for reducing the pour point of hydrocarbon oils and lubricating composition containing pour point reducing salicylates are provided. The hydrocarbon base oil in such method and composition preferably is a Group III base oil.
    Type: Application
    Filed: July 22, 2008
    Publication date: January 29, 2009
    Inventors: Marc-Andre Poirier, Jacob J. Habeeb, Chengrong X. Wang
  • Publication number: 20080182768
    Abstract: A diesel engine operating on a fuel containing from about 5 to about 100 wt. % bio-diesel components and being lubricated with a lubricating oil composition including a major amount of oil of lubricating viscosity, and a minor amount of at least one highly grafted, multi-functional olefin copolymer. The olefin copolymer is made by reacting an acylating agent with an olefin copolymer having a number average molecular weight greater than about 1,000 in the present of a free radical initiator to provide an acylated olefin copolymer having a degree of grafting (DOG) of the acylating agent on the olefin copolymer of at least 0.5 wt. %, and reacting the acylated olefin copolymer with an amine to provide the highly grafted, multi-functional olefin copolymer. As used, the highly grafted, multi-functional olefin copolymer is effective to reduce a viscosity increase in the lubricating oil composition for the engine.
    Type: Application
    Filed: December 20, 2007
    Publication date: July 31, 2008
    Inventors: Cathy C. DEVLIN, Charles A. PASSUT
  • Patent number: 7285516
    Abstract: Lubricating oils containing an additive formulation including at least one sulphonate, saligenin and salixarate detergent provide improved wear performance and decreased sulphur and phosphorus emissions.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: October 23, 2007
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, R. Ian Wilby, James P Roski
  • Patent number: 6828285
    Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: December 7, 2004
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Eiichi Nakamura
  • Patent number: 6815401
    Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: November 9, 2004
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Eiichi Nakamura
  • Publication number: 20040142827
    Abstract: A lubricating oil comprising a major amount of at least one of Group II, III, and IV base oil and a minor amount of 2-(4-hydroxy-3,5-di-t-butyl benzyl thiol) acetate. A method of making this lubricating oil and a method of lubricating a natural gas engine with this lubricating oil.
    Type: Application
    Filed: November 29, 2001
    Publication date: July 22, 2004
    Inventors: John D. Palazzotto, Mark R. Logan
  • Patent number: 6756348
    Abstract: This invention is directed to an antioxidant system for use in lubricating oils comprising sulfurized isobutylene and hindered phenols that provides enhanced oxidation resistance and is particularly useful in natural gas fueled engines, the method for making this antioxidant system, lubricating oils comprising the antioxidant system and methods for lubricating engines using lubricating oil comprising this antioxidant system.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: June 29, 2004
    Assignee: Chevron Oronite Company LLC
    Inventors: John D. Palazzotto, Mark R. Logan
  • Patent number: 6720293
    Abstract: A low viscosity lubricating oil composition having a CCS viscosity less than 3500 mPa.s at −25° C. and having no more than 0.16 mass % of phosphorus which comprises a dispersant, and a detergent of calcium or magnesium or both; and optionally a zinc dihydrocarbyldithiophosphate, a viscosity modifier, a pour point depressant and an antioxidant. The oil satisfies the Cummins M11 cross-head wear engine test specification in a low phosphorus and low viscosity formulation.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: April 13, 2004
    Assignee: Infineum International Ltd.
    Inventors: Charles H. Bovington, Christopher J. Locke, Terence Kelly
  • Publication number: 20040014618
    Abstract: A cyclic compound comprising m units of formula Ia and n units of formula (Ib) joined together to form a ring, wherein Y is a divalent bridging group which may be the same or different in each unit; R0 is H, a C1-C6 alkyl or a metal or ammonium cation; R5 is H or a C1-C6 alkyl; and j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the proviso that at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3; and with the proviso that at least one of the conditions a) to e) below is satisfied: (a) the cyclic compound comprises at least one formula (Ia) unit in the form of a carboxylate anion, (b) the caclic compound comprises at least one formula (Ia) unit in the form of an alkaline earth metal or alkali metal carboxylate salt, (c) the cyclic compound comprises at least 2 units of formula (Ia) (d) the cyclic co
    Type: Application
    Filed: August 24, 2002
    Publication date: January 22, 2004
    Inventor: Spencer Edwin Taylor
  • Publication number: 20030220206
    Abstract: Lubricant compositions comprises a lubricant base oil and one or more compounds resulting the modification of a succinimide represented by formula (1) or (2) 1
    Type: Application
    Filed: April 10, 2003
    Publication date: November 27, 2003
    Applicant: Nippon Mitsubishi Oil Corporation
    Inventors: Kenichi Komiya, Naozumi Arimoto, Noboru Ishida, Shinichi Shirahama, Eitaro Morita
  • Publication number: 20030139304
    Abstract: This invention is directed to an antioxidant system for use in lubricating oils comprising sulfurized isobutylene and hindered phenols that provides enhanced oxidation resistance and is particularly useful in natural gas fueled engines, the method for making this antioxidant system, lubricating oils comprising the antioxidant system and methods for lubricating engines using lubricating oil comprising this antioxidant system.
    Type: Application
    Filed: November 29, 2001
    Publication date: July 24, 2003
    Inventors: John D. Palazzotto, Mark R. Logan
  • Patent number: 6583093
    Abstract: A cyclic compound comprising m units of the formula Ia: and n units of the formula (Ib): joined together to form a ring, wherein Y and Y2 are divalent bridging groups which may be the same or different in each unit; R0 is H or (C1-C6) alkyl or is a metal or ammonium cation; R5 is H or (C1-C60) alkyl or OH group; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the provisos that i) at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3, and ii) in formula Ia at least one OH group is in the meta or para position to the COOR0 group and/or at least one R5 group is OH.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 24, 2003
    Assignee: BP Oil International Limited
    Inventors: Spencer Edwin Taylor, Michael John Wilson
  • Patent number: 6569819
    Abstract: Lubricant compositions comprise a lubricant base oil, and (A) a mono substituted amide type bissuccinimide in an amount from 0.5 to 20 percent by mass, (B) zinc dithiophosphate in an amount from 0.05 to 0.3 percent by mass of phosphorus, and (C) a metal-based detergent in an amount form 0.5 to 4.0 percent by mass of sulfated ash, based on the total mass of the composition. Lubricant compositions preferably further comprises (D) a dispersant type viscosity index improver in an amount from 0.1 to 20 percent by mass, based on the total mass of the composition.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: May 27, 2003
    Assignee: Nippon Mitsubishi Oil Corporation
    Inventors: Kazuhiro Yagishita, Jinichi Igarashi, Osamu Kurosawa
  • Publication number: 20030096714
    Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals.
    Type: Application
    Filed: October 23, 2001
    Publication date: May 22, 2003
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventor: Eiichi Nakamura
  • Patent number: 6521571
    Abstract: A lubricant suitable for use in a trunk piston diesel engine characterised by a power output of 200 kW or greater. The trunk piston diesel engine may be for use in marine, power generation or rail traction applications. The lubricant comprises a basestock of lubricating viscosity, an overbased metal detergent, preferably having an ash content of at least 0.85% sulfated ash, and an ashless or metal-free auxiliary additive comprising at least one of: an oil-soluble sulfurized alkylphenol, a phosphorosulfurized or sulfurized hydrocarbon, a sulfide of an oil, a fat or a polyolefin, or an amine phosphate.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: February 18, 2003
    Assignee: Infineum International Ltd.
    Inventors: Terence Garner, Laurent Chambard, Adrian Dunn
  • Publication number: 20020142922
    Abstract: Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: 1
    Type: Application
    Filed: January 23, 2002
    Publication date: October 3, 2002
    Applicant: Nippon Mitsubishi Oil Corporation
    Inventors: Kazuhiro Yagishita, Jinichi Igarashi, Takeo Koizumi