The -oh Group Is In Salt Form Patents (Class 508/586)
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Patent number: 8987178Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a calcium-containing detergent with a soap content of 0.06 wt % to 1.6 wt % of the lubricating composition. The lubricating composition is suitable for lubricating an internal combustion engine.Type: GrantFiled: December 17, 2008Date of Patent: March 24, 2015Assignee: The Lubrizol CorporationInventors: Mark C. Davies, Michael R. Sutton
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Patent number: 8969272Abstract: This invention relates to a hydroxyaromatic functionalized polyalpha-olefin comprising the product of the combination of: a) a polyalpha-olefin comprising one or more C3 to C20 linear alpha-olefins and having at least 10% vinylidene unsaturation, a viscosity index of 80 to 400, an Mn of 300 to about 20,000, and a pour point of 0° C. or less; and b) a hydroxyaromatic moiety; wherein the analine point of the functionalized polyalpha-olefin is at least 10° C. lower than the analine point of the polyalpha-olefin.Type: GrantFiled: April 23, 2008Date of Patent: March 3, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Abhimanyu Onkar Patil, Margaret May-Som Wu, Stephen Zushma, Anura Abhimanyu Patil
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Patent number: 8933002Abstract: Disclosed herein is a neutral or overbased salt of a sulfurized alkylhydroxyaromatic compound obtained by the process comprising the steps of (a) sulfurizing an alkylhydroxyaromatic compound derived from alkylation of a hydroxyaromatic compound with one or more olefins comprising C9 to C18 oligomers of monomers selected from propylene, butylene or mixtures thereof to provide a sulfurized alkylhydroxyaromatic reaction product; (b) removing any unsulfurized alkylhydroxyaromatic compound from the sulfurized alkylhydroxyaromatic reaction product of step (a) to obtain a sulfurized alkylhydroxyaromatic compound substantially free of the unsulfurized alkylhydroxyaromatic compound; and (c) neutralizing the sulfurized alkylhydroxyaromatic compound of step (b) to provide a salt of the sulfurized alkylhydroxyaromatic compound, wherein the overbased salt of the sulfurized alkylhydroxyaromatic compound contains less than about 2% by combined mass of the unsulfurized alkylhydroxyaromatic compound and its unsulfurized metalType: GrantFiled: November 10, 2011Date of Patent: January 13, 2015Assignees: Chevron Oronite Company LLC, Chevron Oronite SASInventors: Gilles Sinquin, Curt Campbell, Hélène Lecroq, Eugene E. Spala
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Patent number: 8759262Abstract: A lubricating oil composition for internal combustion engines, particularly heavy duty diesel (HDD) engines, having reduced phosphorus, sulfur and sulfated ash contents that provide excellent piston cleanliness performance and contain an amount of phenate detergent that introduces a relatively large amount of phenate soap into the lubricating oil composition.Type: GrantFiled: December 20, 2006Date of Patent: June 24, 2014Assignee: Infineum International LimitedInventors: Matthew D. Irving, Stephen Arrowsmith
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Patent number: 8748362Abstract: The present invention is directed to a method for improving the fuel efficiency of large engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 32 mm2/s, and, preferably, additizing the composition with a salicylate detergent, a mixture of salicylate-phenate detergents or a mixture of sulfonate and phenate detergents.Type: GrantFiled: January 28, 2011Date of Patent: June 10, 2014Assignee: ExxonMobile Research and Engineering CompanyInventors: Kathleen H. Tellier, Vincent M. Carey
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Patent number: 8728999Abstract: The present invention is directed to a method for improving the fuel efficiency of large low and medium speed engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using a blend consisting of one or more Group I base oils having a kinematic viscosity at 100° C. of from 2 to less than 12 mm2/s in combination with a Group IV base oil having a kinematic viscosity of at least 38, the difference in kinematic viscosity between the Group I and Group IV oils in the blend being at least 30 mm2/s in combination with a detergent.Type: GrantFiled: January 28, 2011Date of Patent: May 20, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Vincent M. Carey, Kevin L. Crouthamel
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Patent number: 8680030Abstract: The present invention is directed to a lubricating oil for use in engines subjected to sustained severe load conditions, said lubricating oil comprising a base oil, and an additive package comprising one or more neutral/low TBN or a mixture of neutral/low TBN, and overbased/high TBN alkali or alkaline earth metal alkyl sulfonates, alkyl phenates, alkyl salicylates, an antioxidant selected from the group consisting of glycerine derivatives comprising glycerine grafted with a hindered phenol, hindered phenolic containing a thioether group, and mixtures thereof, optionally an additional conventional antioxidant and/or an organomolybdenum compound, and other additives, and to a method for enhancing the deposit formation resistance of a lubricating oil used in engines operated under sustained severe load comprising the addition to the lubricant of the aforesaid additive package.Type: GrantFiled: October 31, 2006Date of Patent: March 25, 2014Assignee: ExxonMobil Research and Engineering CompanyInventor: Stanley James Cartwright
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Patent number: 8598103Abstract: The present invention is directed to a method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient of the oil by formulating the oil using at least two base stocks of different kinematic viscosity wherein the differences in kinematic viscosity between the base stocks is at least 30 mm2/s, and additizing the composition with one or more detergents.Type: GrantFiled: January 28, 2011Date of Patent: December 3, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Vincent M. Carey, Kevin L. Crouthamel
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Publication number: 20130296208Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a compound obtained/obtainable by a process comprising reacting a glycolic acid, a 2-halo-acetic acid, or a lactic acid, or an alkali or alkaline metal salts thereof, (typically glycolic acid or a 2-halo-acetic acid) with at least one member selected from the group consisting of an amine, an alcohol, and an aminoalcohol. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: July 11, 2013Publication date: November 7, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: William R. S. Barton, Seth L. Crawley, Patrick E. Mosier, Matthew D. Gieselman, Daniel J. Saccomando
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Publication number: 20130165357Abstract: A lubricant composition including: (A) greater than 50 wt % of a base stock based on the total weight of the composition selected from the group consisting of that of a Group III base oil, a Group IV base oil, and a combination thereof; and (B) one or more additional components. The one or more additional components are selected from the group consisting of: (i) one or more high or medium base carboxylate detergents; (ii) one or more low base carboxylate detergents, wherein the low base carboxylate detergent is present at a level of 0.60 wt % or less based on the total weight of the composition; (iii) one or more low base carboxylate detergents and one or more aromatics-containing base stock(s); and (iv) one or more phenolic detergents.Type: ApplicationFiled: December 14, 2012Publication date: June 27, 2013Applicant: EXXONMOBIL RESEARCH & ENGINEERING COMPANYInventor: ExxonMobil Research & Engineering Company
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Patent number: 8377857Abstract: A method of lubricating a cylinder liner and a crankcase in a marine diesel crosshead engine with the same lubricating oil composition. The lubricating oil composition has a TBN, as measured using ASTM D 2896-98, of 10 to 55 mg KOH/g. The lubricating oil composition comprises: at least 40 mass % of an oil of lubricating viscosity; at least one detergent; at least one dispersant; and at least one anti-wear additive.Type: GrantFiled: May 24, 2006Date of Patent: February 19, 2013Assignee: Infineum International LimitedInventors: Laurent Chambard, Laura Kosidowski
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Patent number: 8377856Abstract: A method for maintaining a total base number (TBN) above about 3 mg KOH/g for a lubricant for a diesel engine for greater than about 184 days. The method includes supplying as the lubricant, a lubricant composition comprising a sulfonate detergent having a TBN ranging from about 20 to about 100 and a phenate detergent having a TBN ranging from about 200 to about 350 and an antioxidant selected from the group consisting essentially of hindered phenolic derivatives of C3 to C6 acids and C7 to C9 esters of hindered phenolic derivatives of C3 to C6 acids. The phenate detergent is present in an amount that is greater than 15 percent by weight of the total weight of detergents in the lubricant composition and the lubricant composition is substantially devoid of zinc dialkydithiophosphate compounds and has a sulfated ash content of less than 1.0 wt. %.Type: GrantFiled: September 14, 2010Date of Patent: February 19, 2013Assignee: Afton Chemical CorporationInventors: Cathy C. Devlin, David A. Hutchison
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Patent number: 8361940Abstract: A low sulfated ash, tow sulfur, low phosphorus, low zinc lubricating, oil composition preferably employable for internal combustion engines using a low sulfur hydrocarbon fuel comprises a base oil having a saturated component of 85 wt. % or more, a viscosity index of 110 or more, and a sulfur content of 0.01 wt. % or less; an alkaline earth metal-containing detergent; a nitrogen-containing ashless dispersant of a weight average molecular weight of 4,500 or more; a phenolic or amine oxidation inhibitor; and a basic nitrogen-containing compound-oxymolybdenum complex.Type: GrantFiled: September 12, 2007Date of Patent: January 29, 2013Assignee: Chevron Japan Ltd.Inventors: Morikuni Nakazato, Yoshitaka Takeuchi, Takahiro Muramatsu
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Patent number: 8299000Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.Type: GrantFiled: October 31, 2011Date of Patent: October 30, 2012Assignee: The Lubrizol CorporationInventors: James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
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Publication number: 20120245065Abstract: The invention provides a method of lubricating an aluminium-alloy surface of an internal combustion engine comprising supplying to the aluminium-alloy surface a lubricating composition comprising an oil of lubricating viscosity and an alkali or alkaline earth metal phenate detergent. The phenate disclosed herein may further provide antiwear performance on the aluminium-alloy surface.Type: ApplicationFiled: August 10, 2010Publication date: September 27, 2012Applicant: The Lubrizol CorporationInventor: Mark C. Davies
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Patent number: 8183192Abstract: An overbased salt of an oligomerized alkylhydroxyaromatic compound for use in a lubricating oil composition is disclosed, wherein the alkyl group of the alkylhydroxyaromatic compound is derived from an olefin mixture comprising propylene oligomers having an initial boiling point of at least about 195° C. and a final boiling point of greater than 325° C. and up to about 400° C. as measured by ASTM D86. Also disclosed is a propylene oligomer having an initial boiling point of at least about 195° C. and a final boiling point of greater than 325° C. and up to about 400° C. as measured by ASTM D8, wherein the propylene oligomer contains a distribution of carbon atoms that comprise at least about 50 weight percent of C14 to C20 carbon atoms.Type: GrantFiled: February 3, 2010Date of Patent: May 22, 2012Assignees: Chevron Oronite Company LLC, Chevron Oronite S.A.Inventors: Gilles P. Sinquin, Michael R. Adams
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Patent number: 8076274Abstract: A lubricating oil composition for a heavy duty diesel engine comprises a base oil, at least 0.6 mass % of an ash-free antioxidant and an overbased magnesium-containing detergent. The detergent provides greater than 0.05 mass % Mg based on the mass of the composition. Bore polishing in the engine is reduced for a given level of exhaust gas ash production.Type: GrantFiled: July 10, 2007Date of Patent: December 13, 2011Assignee: Infineum International LimitedInventors: Robin Howard Scott, Robert William Shaw
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Patent number: 8076273Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.Type: GrantFiled: August 23, 2010Date of Patent: December 13, 2011Assignee: The Lubrizol CorportionInventors: James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
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Publication number: 20110190185Abstract: An overbased salt of an oligomerized alkylhydroxyaromatic compound for use in a lubricating oil composition is disclosed, wherein the alkyl group of the alkylhydroxyaromatic compound is derived from an olefin mixture comprising propylene oligomers having an initial boiling point of at least about 195° C. and a final boiling point of greater than 325° C. and up to about 400° C. as measured by ASTM D86. Also disclosed is a propylene oligomer having an initial boiling point of at least about 195° C. and a final boiling point of greater than 325° C. and up to about 400° C. as measured by ASTM D8, wherein the propylene oligomer contains a distribution of carbon atoms that comprise at least about 50 weight percent of C14 to C20 carbon atoms.Type: ApplicationFiled: February 3, 2010Publication date: August 4, 2011Applicants: Chevron Oronite Company LLC, Chevron Oronite S.A.Inventors: Gilles P. Sinquin, Michael R. Adams
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Patent number: 7960324Abstract: An additive composition providing improved low temperature viscosity, corrosion and detergent properties when used in lubricating oils for internal combustion engines is presented. The additive composition comprises an unsulfurized carboxylate detergent-dispersant additive having been modified by incorporation of from about 3.2 wt % to 7.5 wt %, based on the total additive composition, of an alkaline earth metal salt of a linear, saturated carboxylic acid having from about 16 to about 20 carbon atoms and wherein the additive composition has a superalkalinization ratio of less than about 1.4:1, a TBN of less than about 200 and a sediment value of less than about 0.2% by volume.Type: GrantFiled: September 3, 2004Date of Patent: June 14, 2011Assignee: Chevron Oronite Company LLCInventors: Jean-Louis Le Coent, Amedee Guellec
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Patent number: 7943796Abstract: An overbased salt of an oligomerized alkylhydroxyaromatic compound is disclosed, wherein the alkyl group of the alkylhydroxyaromatic compound is derived from an olefin mixture comprising propylene oligomers having an initial boiling point of at least about 195° C. and a final boiling point of no more than about 325° C. as measured by ASTM D86. Also disclosed is a lubricating oil composition containing at least (a) a major amount of an oil of lubricating viscosity and (b) the overbased salt of the oligomerized alkylhydroxyaromatic compound.Type: GrantFiled: July 31, 2008Date of Patent: May 17, 2011Assignee: Chevron Oronise Company LLCInventors: Curtis B. Campbell, Charles Michael Cisson
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Patent number: 7910526Abstract: The present invention provides a grease composition for use in constant velocity joints, which comprises the following components (a) to (g) and a constant velocity joint comprising the grease composition sealed or encapsulated therein: (a) a base oil; (b) a diurea thickener represented by the following general formula: R1NH—CO—NH—C6H4-p-CH2—C6H4-p-NH—CO—NHR2 wherein R1 and R2 each independently represents an alkyl group having 8 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms or a cycloalkyl group having 6 to 12 carbon atoms; (c) a molybdenum dialkyl dithiocarbamate insoluble in the base oil; (d) a molybdenum dialkyl dithiocarbamate soluble in the base oil; (e) molybdenum disulfide; (f) at least one member selected from the group consisting of calcium phenate and calcium sulfonate; and (g) a sulfur-containing extreme-pressure agent free of phosphorus.Type: GrantFiled: December 21, 2006Date of Patent: March 22, 2011Assignees: Kyodo Yushi Co., Ltd., NTN CorporationInventors: Mitsuhiro Kakizaki, Takashi Okaniwa, Minoru Ishijima, Shinichi Takabe
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Patent number: 7838475Abstract: A composition is disclosed which comprises an aryl perfluoropolyether, optionally a halogenated oil, and further optionally a thickening agent. The composition can be used as a lubricant itself or as an additive to an oil or grease lubricant and can withstand temperatures higher than 300° C. without decomposition. The halogenated oil can be a perfluoropolyether, a fluorosilicone, a polytrifluorochloroethylene, or combinations of two or more thereof. The thickening agent can be finely divided silica, boron nitride, clay, soap, poly(tetrafluoroethylene), clay, talc, silica, titanium dioxide, polydimethylsiloxane, polyurea, polyurethane, or combinations of two or more thereof.Type: GrantFiled: September 1, 2005Date of Patent: November 23, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Jon Lee Howell, Alice Elizabeth Van Der Ende, Erik William Perez, Krista Lynn Laugesen
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Patent number: 7799745Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.Type: GrantFiled: May 28, 2008Date of Patent: September 21, 2010Assignee: The Lubrizol CorporationInventors: James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
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Publication number: 20100204073Abstract: Lubricant formulations and methods for producing lubricant formulations are described that provide improved wear protection in engines operated using ethanol-based fuels. The improved wear protection may be provided by an increased amount of overbased calcium detergent present in the formulation.Type: ApplicationFiled: April 8, 2010Publication date: August 12, 2010Applicant: AFTON CHEMICAL CORPORATIONInventors: Gregory H. GUINTHER, Roger M. SHEETS
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Patent number: 7585821Abstract: A modified lubricating oil detergent that is the reaction product of an oil soluble detergent comprising an alkali- or alkaline earth metal hydrocarbyl phenate, carboxylate or sulfonate and an ?, ?-unsaturated carbonyl compound; and lubricating oil compositions containing a combination of such a modified detergent and a nitrogen-containing dispersant.Type: GrantFiled: August 6, 2002Date of Patent: September 8, 2009Assignee: Infineum International LimitedInventors: Jacob Emert, Antonio Gutierrez
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Publication number: 20090203563Abstract: The invention provides a process for preparing a neutral or an overbased detergent, the process by: reacting (a) a pre-prepared suspension comprising (i) a metal base with a mean particle size of 10 micrometres or less; (ii) a surfactant; and (iii) an organic medium in which the metal base is suspended typically by a physical process. An overbased detergent may be formed with a further reaction with acidifying overbasing agent. The invention further provides a lubricant composition containing said neutral and overbased detergent.Type: ApplicationFiled: December 20, 2006Publication date: August 13, 2009Applicant: The Lubrizol CorporationInventors: Elisa Seddon, Claire Hollingshurst, Brian R. Cunningham, Alexander F. Psaila, David Hobson, Mohamed G. Fahmy, Willis P. Nichols, John W. Dunkerley
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Publication number: 20090111722Abstract: Lubricant formulations and methods for producing lubricant formulations are described that provide improved wear protection in engines operated using ethanol-based fuels. The improved wear protection may be provided by an increased amount of overbased calcium detergent present in the formulation.Type: ApplicationFiled: October 25, 2007Publication date: April 30, 2009Inventors: Gregory H. GUINTHER, Roger M. Sheets
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Publication number: 20090075853Abstract: A slow release liquid additive concentrate for use in an engine oil filter and a method for extending an oil drain interval for an engine. The additive concentrate has therein at least one detergent and at least one antioxidant. The additive concentrate has a tan delta of greater than about 5.Type: ApplicationFiled: September 18, 2007Publication date: March 19, 2009Inventors: Naresh C. Mathur, Charles A. Passut, Carl K. Esche, JR.
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Patent number: 7435709Abstract: Disclosed is a lubricating oil composition displaying reduced endocrine disruption response, comprising a major amount of an oil of lubricating viscosity; and a detergent comprising an unsulfurized alkali or alkaline earth metal salt of a reaction product of (1) an olefin having at least 10 carbon atoms, wherein greater than 80 mole % of the olefin is a linear C20-C30 n-alpha olefin, wherein less than 10 mole % of the olefin is a linear olefin of less than 20 carbon atoms, and wherein less than 5 mole % of the olefin is branched chain olefin of 18 carbons or less, and (2) a hydroxyaromatic compound.Type: GrantFiled: September 1, 2005Date of Patent: October 14, 2008Assignee: Chevron Oronite Company LLCInventors: Peter Michael Stonebraker, Curtis B. Campbell, Linda Susan Gordon Roberts
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Patent number: 7417012Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.Type: GrantFiled: October 13, 2004Date of Patent: August 26, 2008Assignee: The Lubrizol CorporationInventors: James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
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Publication number: 20080194439Abstract: A non-chlorine type lubricant in which a sulfur type extreme pressure additive, an organic zinc compound, a calcium type additive, and an ester compound are blended with a base oil for the lubricant, and having a kinetic viscosity from 5 to 50 mm2/s at 40° C.Type: ApplicationFiled: February 1, 2008Publication date: August 14, 2008Applicant: TOYOTA BOSHOKU KABUSHIKI KAISHAInventors: Mami KATO, Teruo FUKAYA
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Publication number: 20080090741Abstract: The lubricant composition of the present disclosure comprises a major amount of a base oil and a minor amount of an additive composition comprising an overbased detergent and a low-base detergent, wherein the lubricant composition has a salt to metal ratio ranging from about 3.0 to about 8.0.Type: ApplicationFiled: October 16, 2006Publication date: April 17, 2008Inventor: William Y. Lam
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Patent number: 7358217Abstract: Quenching oil compositions comprising (1) an oil having kinematic viscosity (ASTM Test Method D-445) at 40° C. ranging from about 4 to about 45 mm2sec?1 (about 40 to about 210 Saybolt Universal Seconds (SUS)) and having a saturated content from about 80% to about 100%; and (2) an alkali metal salt of saligenin derivative and optionally, further comprising at least one of (3) an aliphatic polyolefin having Mn ranging from about 300 to about 10,000; (4) at least one member selected from the group consisting of metal salts of hydrocarbyl substituted phenols, salicylic acids, carboxylic acids, and sulfonic acids; and (5) at least one member selected from the group consisting of hydrocarbyl substituted succinic esters, amides, ester-amides, imides, amine salts, acid-esters, acid-amides ester-amine salts, amide-amine-salts and acid-amine salts, and methods of heat treating metals comprising employing said quenching oils.Type: GrantFiled: December 16, 2002Date of Patent: April 15, 2008Assignee: The Lubrizol CorporationInventors: William R. Sweet, Sanjay Kalhan
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Publication number: 20080026962Abstract: The pour points of lubricating compositions are significantly improved when Group III and GTL base stocks are formulated with alkyl alkaline earth metal detergents. In a preferred embodiment, calcium alkyl salicylate detergents are used.Type: ApplicationFiled: July 24, 2007Publication date: January 31, 2008Inventor: Marc-Andre Poirier
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Publication number: 20080020951Abstract: A lubricating oil composition for a heavy duty diesel engine comprises a base oil, at least 0.6 mass % of an ash-free antioxidant and an overbased magnesium-containing detergent. The detergent provides greater than 0.05 mass % Mg based on the mass of the composition. Bore polishing in the engine is reduced for a given level of exhaust gas ash production.Type: ApplicationFiled: July 10, 2007Publication date: January 24, 2008Inventors: Robin Howard Scott, Robert William Shaw
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Publication number: 20080015130Abstract: A lubricant composition comprising a detergent and a base oil comprising less than about 3% by weight of tetracycloparaffins is disclosed. Methods of making and using the composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: Mark T. Devlin, Tze-chi Jao
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Patent number: 7285516Abstract: Lubricating oils containing an additive formulation including at least one sulphonate, saligenin and salixarate detergent provide improved wear performance and decreased sulphur and phosphorus emissions.Type: GrantFiled: November 25, 2002Date of Patent: October 23, 2007Assignee: The Lubrizol CorporationInventors: Virginia A. Carrick, William D. Abraham, Gordon D. Lamb, R. Ian Wilby, James P Roski
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Patent number: 7163911Abstract: The present invention provides a novel unsulfurized, carboxylate-containing additive for lubricating oils, comprising a mixture of alkaline earth metal salts (hydrocarbyl phenate/hydrocarbyl salicylate) and a reduced amount of unreacted hydrocarbyl phenols, as well as additive packages, concentrates and finished oil compositions comprising the same. Specifically, it relates to additives comprising said mixture in which said hydrocarbyl salicylate is primarily single-aromatic-ring hydrocarbyl salicylate. The invention also provides a method for producing said additive.Type: GrantFiled: May 22, 2003Date of Patent: January 16, 2007Assignees: Chevron Oronite Company LLC, Cherov Oronite Technology B.V.Inventors: Cornelius Hendrikus Boons, Eugene Spala, Willem Van Dam
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Patent number: 6869919Abstract: Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines equipped with EGR systems can be ameliorated by selection of viscosity modifier, lubricating oil flow improvers, detergents and/or dispersants.Type: GrantFiled: September 10, 2002Date of Patent: March 22, 2005Assignee: Infineum International Ltd.Inventors: Andrew J. D. Ritchie, Jai G. Bansal, Jacob Emert, Glen P. Fetterman, Antonio Gutierrez, Matthew D. Irving, Christopher J. Locke, Michael T. Minotti
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Patent number: 6828285Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: February 14, 2003Date of Patent: December 7, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6828286Abstract: Lubricant compositions comprises a lubricant base oil and one or more compounds resulting the modification of a succinimide represented by formula (1) or (2) wherein R1 and R2 may be the same or different and are each independently a hydrocarbon group having 8 to 30 carbon atoms, R3 and R4 may be the same or different and are each independently a hydrocarbon group having 1 to 4 carbon atoms, R5 is hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, n is an integer from 1 to 7. The lubricant compositions have a long-lasting anti-shudder property, an enhanced transmission capacity for a wet clutch, and an excellent shifting property.Type: GrantFiled: April 10, 2003Date of Patent: December 7, 2004Assignee: Nippon Mitsubishi Oil CorporationInventors: Kenichi Komiya, Naozumi Arimoto, Noboru Ishida, Shinichi Shirahama, Eitaro Morita
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Publication number: 20040235682Abstract: The present invention provides engine lubricants for low emission diesel engines featuring low levels of ash, sulfur and phosphorus. Specifically, this invention provides a low emission diesel lubricant comprising from about 0 wt. % to about 1.2 wt. % ash; from about 0.1 wt. % to about 0.5 wt. % sulfur; and from about 0.02 wt. % to about 0.1 wt. % phosphorus. Said lubricant may also comprise a novel unsulfurized, carboxylate-containing additive for lubricating oils, comprising a mixture of alkaline earth metal salts (hydrocarbyl phenate/hydrocarbyl salicylate) and a reduced amount of unreacted hydrocarbyl phenols, in which said hydrocarbyl salicylate is primarily single-aromatic-ring hydrocarbyl salicylate. The invention also provides a method for producing said additive and said LEDL.Type: ApplicationFiled: May 22, 2003Publication date: November 25, 2004Applicants: Chevron Oronite Company LLC, Chevron Oronite Technology B.V.Inventors: Willem Van Dam, Eugene Spala, Peter Kleijwegt, Jeroen Van Leeuwen
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Publication number: 20040235686Abstract: The present invention provides a novel unsulfurized, carboxylate-containing additive for lubricating oils, comprising a mixture of alkaline earth metal salts (hydrocarbyl phenate/hydrocarbyl salicylate) and a reduced amount of unreacted hydrocarbyl phenols, as well as additive packages, concentrates and finished oil compositions comprising the same. Specifically, it relates to additives comprising said mixture in which said hydrocarbyl salicylate is primarily single-aromatic-ring hydrocarbyl salicylate. The invention also provides a method for producing said additive.Type: ApplicationFiled: May 22, 2003Publication date: November 25, 2004Applicants: Chevron Oronite Company LLC, Chevron Oronite Technology B.V.Inventors: Cornelius Hendrikus Maria Boons, Eugene Spala, Willem Van Dam
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Publication number: 20040235688Abstract: The use, in a minor amount, of a detergent composition comprising one or more metal detergents which comprises metal salts of organic acids, wherein the detergent composition comprises more than 50 mole %, based on the moles of the metal salts of organic acids in the detergent composition, of:Type: ApplicationFiled: June 22, 2004Publication date: November 25, 2004Inventors: Christopher J. Locke, Mark G. Stevens, Peter Wrench, Stephen Arrowsmith, Rebecca C. Castle, Jane R. Galsworthy
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Patent number: 6815401Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: October 23, 2001Date of Patent: November 9, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6809069Abstract: A lubricating oil composition which comprises a lubricating base oil and a sulfonate, phenate or salicylate of an alkaline earth metal and has a friction coefficient between metals of 0.12 or higher at −20° C. as measured in accordance with a block-on-disk test. The friction coefficient between metals in the use of a metal belt can be kept high within a wide range of temperature from low temperatures to high temperatures. In particular, the lubricating oil exhibits a high performance of &mgr;=0.12 or higher at a low temperature of −20° C. in accordance with a block-on-disk test.Type: GrantFiled: October 24, 2002Date of Patent: October 26, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventors: Junichi Deshimaru, Yutaka Takakura
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Publication number: 20040209783Abstract: This invention relates to lubricating oil compositions that have surprisingly been shown to reduce the formation of lacquer deposits in engines. More specifically, this invention relates to a lubricating oil for natural gas engines that reduces siloxane-related cylinder liner lacquer deposits.Type: ApplicationFiled: April 18, 2003Publication date: October 21, 2004Inventors: Paul P. Wells, Vincent Mark Carey, Kevin John Kelly
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Patent number: 6800595Abstract: A grease composition having a base oil and a thickener, which grease additionally has from 0.05% to 30% by weight of sodium thiosulphate and at least 0.1% by weight of one or more additives selected from the group of: calcium salicylate, magnesium salicylate, calcium phenate, and calcium sulphonate, based on the total grease composition, and use of the grease composition to improve rust prevention and abrasion resistance. The invention also relates to a method for preparing the grease composition.Type: GrantFiled: February 10, 2003Date of Patent: October 5, 2004Assignee: Shell Oil CompanyInventors: Takahiro Ozaki, Noriaki Shinoda, Kouichi Nakazawa
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Patent number: RE39648Abstract: Thus, the instant invention is directed toward an oil for diesel engines comprising an admixture of (A) a major amount of an oil of lubricating viscosity, (B) at least 4 mass % dispersant, (C) at least 0.3 mass % of a metal phenate, (D) less than 0.1 mass % friction modifier, (E) less than 0.3 mass % of ashless sulfurized phenols and, (F) less than 0.12 mass % neutral calcium sulfonate.Type: GrantFiled: July 24, 2001Date of Patent: May 22, 2007Assignee: Infineum USA L.P.Inventors: Edward Francis Outten, Andrew James Dalziel Ritchie